#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:47:40 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180196 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/92/7109285.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7109285
loop_
_publ_author_name
'Andres Tasada'
'Francisca M. Alberti'
'Antonio Bauza'
'Miquel Barcelo-Oliver'
'Angel Garcia-Raso'
'Juan J. Fiol'
'Elies Molins'
'Amparo Caubet'
'Antonio Frontera'
_publ_section_title
;
 Metallomacrocycles as anion receptors: combining hydrogen bonding and ion
 pair based hosts formed from Ag(I) salts and flexible bis- and
 tris-pyrimidine ligands
;
_journal_name_full               Chem.Commun.
_journal_page_first              4944
_journal_paper_doi               10.1039/c3cc40772a
_journal_volume                  49
_journal_year                    2013
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C16 H19 Ag3 N12 O9'
_chemical_formula_sum            'C16 H19 Ag3 N12 O9'
_chemical_formula_weight         847.04
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2013-03-26T22:43:37-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                101.53(6)
_cell_angle_beta                 96.20(5)
_cell_angle_gamma                104.51(6)
_cell_formula_units_Z            2
_cell_length_a                   7.310(4)
_cell_length_b                   10.068(7)
_cell_length_c                   17.074(13)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      16.83
_cell_measurement_theta_min      12.78
_cell_measurement_wavelength     0.71073
_cell_volume                     1175.3(15)
_computing_cell_refinement       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_collection       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_reduction        'XCAD4 (Harms & Wocadlo, 1995)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2002 (Giacovazzo et al, 2003)'
_diffrn_ambient_temperature      294(2)
_diffrn_detector                 'scintillation LiI'
_diffrn_detector_dtime           1.195
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Enraf Nonius CAD4'
_diffrn_measurement_method       'non-profiled omega scans'
_diffrn_orient_matrix_type
;
x-axis points to radiation source
the matrix is specified in reciprocal space
;
_diffrn_orient_matrix_UB_11      -0.111693
_diffrn_orient_matrix_UB_12      0.040287
_diffrn_orient_matrix_UB_13      -0.003444
_diffrn_orient_matrix_UB_21      0.00644
_diffrn_orient_matrix_UB_22      0.015193
_diffrn_orient_matrix_UB_23      0.060046
_diffrn_orient_matrix_UB_31      0.08954
_diffrn_orient_matrix_UB_32      0.096514
_diffrn_orient_matrix_UB_33      0.007581
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_unetI/netI     0.0128
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            4280
_diffrn_reflns_theta_full        24.98
_diffrn_reflns_theta_max         24.98
_diffrn_reflns_theta_min         1.23
_diffrn_source                   'Enraf Nonius FR590'
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.553
_exptl_absorpt_correction_T_max  0.499
_exptl_absorpt_correction_T_min  0.062
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
(See: Walker, N. & Stuart, D. (1983) Acta Cryst. A39, 158-166)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.394
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             824
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.41
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.436
_refine_diff_density_min         -1.61
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         4127
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.0524
_refine_ls_R_factor_gt           0.049
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0715P)²+6.5637P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1312
_refine_ls_wR_factor_ref         0.1343
_reflns_number_gt                3882
_reflns_number_total             4127
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c3cc40772a.txt
_cod_data_source_block           pm79
_cod_original_cell_volume        1175.3(14)
_cod_database_code               7109285
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C2 C 0.6159(8) 0.4035(6) 0.5707(4) 0.0303(12) Uani 1 1 d .
C4 C 0.7803(9) 0.5170(7) 0.4848(4) 0.0344(13) Uani 1 1 d .
H4 H 0.8124 0.5175 0.4336 0.041 Uiso 1 1 calc R
C5 C 0.8618(10) 0.6363(7) 0.5467(4) 0.0417(15) Uani 1 1 d .
H5 H 0.9411 0.718 0.538 0.05 Uiso 1 1 calc R
C6 C 0.8184(9) 0.6265(7) 0.6215(4) 0.0383(14) Uani 1 1 d .
H6 H 0.8748 0.7031 0.6651 0.046 Uiso 1 1 calc R
C7 C 0.3882(9) 0.2840(7) 0.6487(4) 0.0338(13) Uani 1 1 d .
H7A H 0.2519 0.2414 0.6301 0.041 Uiso 1 1 calc R
H7B H 0.4063 0.3786 0.681 0.041 Uiso 1 1 calc R
C8 C 0.4662(8) 0.1965(6) 0.7011(4) 0.0330(12) Uani 1 1 d .
H8A H 0.4457 0.1014 0.669 0.04 Uiso 1 1 calc R
H8B H 0.6031 0.238 0.7185 0.04 Uiso 1 1 calc R
C9 C 0.4653(8) 0.2630(6) 0.8469(4) 0.0302(12) Uani 1 1 d .
C11 C 0.7467(9) 0.4009(7) 0.9260(4) 0.0394(14) Uani 1 1 d .
H11 H 0.8725 0.4552 0.9309 0.047 Uiso 1 1 calc R
C12 C 0.6774(10) 0.3798(8) 0.9951(4) 0.0458(16) Uani 1 1 d .
H12 H 0.7536 0.4135 1.046 0.055 Uiso 1 1 calc R
C13 C 0.4904(10) 0.3068(7) 0.9844(4) 0.0402(14) Uani 1 1 d .
H13 H 0.4358 0.2977 1.0305 0.048 Uiso 1 1 calc R
C15 C 0.1840(8) 0.0882(6) 0.7568(4) 0.0324(12) Uani 1 1 d .
H15A H 0.1742 0.041 0.8011 0.039 Uiso 1 1 calc R
H15B H 0.173 0.0171 0.7076 0.039 Uiso 1 1 calc R
C16 C 0.0170(9) 0.1523(7) 0.7484(4) 0.0360(13) Uani 1 1 d .
H16A H 0.0144 0.2129 0.7999 0.043 Uiso 1 1 calc R
H16B H 0.0327 0.2091 0.7086 0.043 Uiso 1 1 calc R
C17 C -0.2784(8) -0.0094(6) 0.7720(4) 0.0291(12) Uani 1 1 d .
C19 C -0.3587(9) -0.0044(7) 0.8973(4) 0.0397(14) Uani 1 1 d .
H19 H -0.3291 0.0297 0.9532 0.048 Uiso 1 1 calc R
C20 C -0.5358(9) -0.0984(8) 0.8646(4) 0.0418(15) Uani 1 1 d .
H20 H -0.6259 -0.1259 0.897 0.05 Uiso 1 1 calc R
C21 C -0.5722(9) -0.1491(6) 0.7828(4) 0.0345(13) Uani 1 1 d .
H21 H -0.6887 -0.215 0.7591 0.041 Uiso 1 1 calc R
N1 N 0.6992(7) 0.5127(5) 0.6351(3) 0.0345(11) Uani 1 1 d .
N2 N 0.4848(8) 0.2916(5) 0.5795(3) 0.0349(11) Uani 1 1 d .
H2 H 0.4548 0.2171 0.5405 0.042 Uiso 1 1 calc R
N3 N 0.6582(7) 0.4016(5) 0.4949(3) 0.0319(11) Uani 1 1 d .
N4 N 1.1958(9) 0.5209(6) 0.7780(4) 0.0427(13) Uani 1 1 d .
N5 N 0.0474(7) 0.2101(5) 1.1119(3) 0.0336(11) Uani 1 1 d .
N6 N 0.7808(9) 0.0630(6) 0.5231(4) 0.0443(13) Uani 1 1 d .
N9 N 0.3738(7) 0.1906(5) 0.7717(3) 0.0322(10) Uani 1 1 d .
N10 N 0.6441(7) 0.3480(5) 0.8524(3) 0.0336(11) Uani 1 1 d .
N14 N 0.3787(7) 0.2468(5) 0.9123(3) 0.0336(11) Uani 1 1 d .
N17 N -0.1609(7) 0.0403(6) 0.7231(3) 0.0374(11) Uani 1 1 d .
H17 H -0.194 0.0022 0.6721 0.045 Uiso 1 1 calc R
N18 N -0.2288(7) 0.0398(5) 0.8529(3) 0.0347(11) Uani 1 1 d .
N22 N -0.4463(7) -0.1073(5) 0.7356(3) 0.0312(10) Uani 1 1 d .
O1 O 1.0697(8) 0.4930(7) 0.8213(4) 0.0609(14) Uani 1 1 d .
O2 O 1.3661(8) 0.5390(7) 0.8072(4) 0.0640(15) Uani 1 1 d .
O3 O 1.1520(9) 0.5325(7) 0.7089(3) 0.0640(15) Uani 1 1 d .
O4 O -0.0549(8) 0.1125(5) 1.0549(3) 0.0538(13) Uani 1 1 d .
O5 O 0.1698(9) 0.3060(6) 1.0965(5) 0.0761(19) Uani 1 1 d .
O6 O 0.0230(9) 0.2112(6) 1.1815(3) 0.0592(14) Uani 1 1 d .
O7 O 0.7264(11) 0.0559(7) 0.4512(3) 0.077(2) Uani 1 1 d .
O8 O 0.7487(8) -0.0491(6) 0.5488(3) 0.0556(13) Uani 1 1 d .
O9 O 0.8702(10) 0.1775(6) 0.5685(4) 0.0673(16) Uani 1 1 d .
Ag1 Ag 0.74900(9) 0.50448(6) 0.76762(3) 0.0531(2) Uani 1 1 d .
Ag2 Ag 0.07516(7) 0.14506(6) 0.92799(3) 0.04856(19) Uani 1 1 d .
Ag3 Ag 0.54021(8) 0.21995(6) 0.39207(3) 0.04666(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
2 1 11
3 0 7
1 2 8
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N2 C2 N1 120.2(6) .
N2 C2 N3 116.8(5) .
N1 C2 N3 123.0(5) .
N3 C4 C5 123.1(6) .
C6 C5 C4 115.8(6) .
N1 C6 C5 123.3(6) .
N2 C7 C8 111.0(5) .
N9 C8 C7 111.6(5) .
N9 C9 N10 116.5(5) .
N9 C9 N14 120.1(5) .
N10 C9 N14 123.4(6) .
N10 C11 C12 123.5(6) .
C13 C12 C11 115.5(6) .
N14 C13 C12 124.6(6) .
N9 C15 C16 114.3(5) .
N17 C16 C15 109.4(5) .
N17 C17 N18 119.8(6) .
N17 C17 N22 116.7(5) .
N18 C17 N22 123.4(5) .
N18 C19 C20 123.2(6) .
C21 C20 C19 116.8(6) .
N22 C21 C20 122.1(6) .
C6 N1 C2 117.5(6) .
C6 N1 Ag1 111.6(4) .
C2 N1 Ag1 127.3(4) .
C2 N2 C7 125.8(5) .
C4 N3 C2 117.0(5) .
C4 N3 Ag3 119.5(4) .
C2 N3 Ag3 123.4(4) .
O3 N4 O2 120.8(6) .
O3 N4 O1 120.4(6) .
O2 N4 O1 118.8(6) .
O6 N5 O5 120.7(6) .
O6 N5 O4 120.0(6) .
O5 N5 O4 119.2(6) .
O9 N6 O7 119.8(6) .
O9 N6 O8 120.8(6) .
O7 N6 O8 119.3(6) .
C9 N9 C8 121.9(5) .
C9 N9 C15 122.6(5) .
C8 N9 C15 115.2(5) .
C11 N10 C9 116.8(5) .
C11 N10 Ag1 109.0(4) .
C9 N10 Ag1 127.1(4) .
C13 N14 C9 115.4(5) .
C13 N14 Ag2 110.5(4) .
C9 N14 Ag2 134.0(4) .
C17 N17 C16 125.9(6) .
C19 N18 C17 116.7(6) .
C19 N18 Ag2 113.1(4) .
C17 N18 Ag2 128.2(4) .
C21 N22 C17 117.5(5) .
C21 N22 Ag3 113.0(4) 2_556
C17 N22 Ag3 129.4(4) 2_556
N4 O1 Ag1 115.8(4) .
N5 O4 Ag2 107.3(4) .
N5 O5 Ag1 101.5(5) 2_667
N1 Ag1 N10 139.31(19) .
N1 Ag1 O1 115.98(19) .
N10 Ag1 O1 83.70(19) .
N1 Ag1 O5 133.8(2) 2_667
N10 Ag1 O5 82.8(2) 2_667
O1 Ag1 O5 78.7(2) 2_667
N14 Ag2 N18 140.66(19) .
N14 Ag2 O4 129.40(18) .
N18 Ag2 O4 89.92(18) .
N3 Ag3 N22 156.93(18) 2_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C2 N2 1.330(8) .
C2 N1 1.351(8) .
C2 N3 1.360(8) .
C4 N3 1.330(8) .
C4 C5 1.383(10) .
C5 C6 1.364(10) .
C6 N1 1.332(8) .
C7 N2 1.445(8) .
C7 C8 1.536(8) .
C8 N9 1.448(8) .
C9 N9 1.350(8) .
C9 N10 1.353(8) .
C9 N14 1.359(8) .
C11 N10 1.325(8) .
C11 C12 1.367(10) .
C12 C13 1.353(10) .
C13 N14 1.336(8) .
C15 N9 1.468(8) .
C15 C16 1.523(8) .
C16 N17 1.449(8) .
C17 N17 1.338(8) .
C17 N18 1.346(8) .
C17 N22 1.360(8) .
C19 N18 1.324(8) .
C19 C20 1.379(10) .
C20 C21 1.359(10) .
C21 N22 1.333(8) .
N1 Ag1 2.274(5) .
N3 Ag3 2.184(6) .
N4 O3 1.225(8) .
N4 O2 1.243(8) .
N4 O1 1.255(8) .
N5 O6 1.219(7) .
N5 O5 1.234(8) .
N5 O4 1.250(7) .
N6 O9 1.229(8) .
N6 O7 1.232(8) .
N6 O8 1.269(8) .
N10 Ag1 2.390(5) .
N14 Ag2 2.268(5) .
N18 Ag2 2.317(6) .
N22 Ag3 2.192(5) 2_556
O1 Ag1 2.462(6) .
O4 Ag2 2.506(6) .
O5 Ag1 2.597(7) 2_667
Ag1 O5 2.597(7) 2_667
Ag3 N22 2.192(5) 2_556
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O8 0.86 2.15 2.939(8) 152.6 2_656
N17 H17 O8 0.86 2.03 2.882(8) 168.9 1_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N3 C4 C5 C6 3.8(9) .
C4 C5 C6 N1 -2.7(9) .
N2 C7 C8 N9 178.7(5) .
N10 C11 C12 C13 -3.6(11) .
C11 C12 C13 N14 5.5(11) .
N9 C15 C16 N17 172.3(5) .
N18 C19 C20 C21 1.8(10) .
C19 C20 C21 N22 -2.0(9) .
C5 C6 N1 C2 -1.2(9) .
C5 C6 N1 Ag1 158.9(5) .
N2 C2 N1 C6 -174.9(5) .
N3 C2 N1 C6 4.5(8) .
N2 C2 N1 Ag1 28.5(7) .
N3 C2 N1 Ag1 -152.0(4) .
N1 C2 N2 C7 14.0(8) .
N3 C2 N2 C7 -165.5(5) .
C8 C7 N2 C2 -105.5(6) .
C5 C4 N3 C2 -0.8(8) .
C5 C4 N3 Ag3 -179.8(5) .
N2 C2 N3 C4 175.9(5) .
N1 C2 N3 C4 -3.6(8) .
N2 C2 N3 Ag3 -5.1(7) .
N1 C2 N3 Ag3 175.5(4) .
N10 C9 N9 C8 3.7(7) .
N14 C9 N9 C8 -175.2(5) .
N10 C9 N9 C15 176.2(5) .
N14 C9 N9 C15 -2.7(8) .
C7 C8 N9 C9 -107.1(6) .
C7 C8 N9 C15 79.9(6) .
C16 C15 N9 C9 87.2(7) .
C16 C15 N9 C8 -99.8(6) .
C12 C11 N10 C9 -3.5(10) .
C12 C11 N10 Ag1 149.1(6) .
N9 C9 N10 C11 -169.1(5) .
N14 C9 N10 C11 9.8(8) .
N9 C9 N10 Ag1 43.8(7) .
N14 C9 N10 Ag1 -137.3(5) .
C12 C13 N14 C9 0.1(10) .
C12 C13 N14 Ag2 -177.8(6) .
N9 C9 N14 C13 170.8(5) .
N10 C9 N14 C13 -8.1(8) .
N9 C9 N14 Ag2 -12.1(8) .
N10 C9 N14 Ag2 169.1(4) .
N18 C17 N17 C16 -4.0(8) .
N22 C17 N17 C16 174.9(5) .
C15 C16 N17 C17 96.2(7) .
C20 C19 N18 C17 1.4(9) .
C20 C19 N18 Ag2 -164.0(5) .
N17 C17 N18 C19 174.2(5) .
N22 C17 N18 C19 -4.6(8) .
N17 C17 N18 Ag2 -23.0(7) .
N22 C17 N18 Ag2 158.2(4) .
C20 C21 N22 C17 -0.9(8) .
C20 C21 N22 Ag3 175.9(5) 2_556
N17 C17 N22 C21 -174.4(5) .
N18 C17 N22 C21 4.4(8) .
N17 C17 N22 Ag3 9.4(7) 2_556
N18 C17 N22 Ag3 -171.8(4) 2_556
O3 N4 O1 Ag1 -10.0(8) .
O2 N4 O1 Ag1 168.7(5) .
O6 N5 O4 Ag2 -174.0(4) .
O5 N5 O4 Ag2 7.5(7) .
O6 N5 O5 Ag1 -13.7(7) 2_667
O4 N5 O5 Ag1 164.8(4) 2_667
C6 N1 Ag1 N10 -173.2(4) .
C2 N1 Ag1 N10 -15.5(6) .
C6 N1 Ag1 O1 -60.8(4) .
C2 N1 Ag1 O1 96.8(5) .
C6 N1 Ag1 O5 38.7(5) 2_667
C2 N1 Ag1 O5 -163.6(4) 2_667
C11 N10 Ag1 N1 173.0(4) .
C9 N10 Ag1 N1 -37.9(6) .
C11 N10 Ag1 O1 49.8(4) .
C9 N10 Ag1 O1 -161.1(5) .
C11 N10 Ag1 O5 -29.6(4) 2_667
C9 N10 Ag1 O5 119.5(5) 2_667
N4 O1 Ag1 N1 13.9(6) .
N4 O1 Ag1 N10 156.5(5) .
N4 O1 Ag1 O5 -119.6(5) 2_667
C13 N14 Ag2 N18 171.2(4) .
C9 N14 Ag2 N18 -6.1(7) .
C13 N14 Ag2 O4 -6.9(5) .
C9 N14 Ag2 O4 175.9(5) .
C19 N18 Ag2 N14 179.1(4) .
C17 N18 Ag2 N14 15.8(6) .
C19 N18 Ag2 O4 -2.4(4) .
C17 N18 Ag2 O4 -165.7(5) .
N5 O4 Ag2 N14 28.1(5) .
N5 O4 Ag2 N18 -150.7(4) .
C4 N3 Ag3 N22 -26.7(7) 2_556
C2 N3 Ag3 N22 154.3(4) 2_556
