#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:55:00 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180202 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/96/7109635.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7109635
loop_
_publ_author_name
'Yingle Liu'
'Jiawang Liu'
'Yangen Huang'
'Feng-Ling Qing'
_publ_section_title
;
 Lewis acid-catalyzed regioselective synthesis of chiral alpha-fluoroalkyl
 amines via asymmetric addition of silyl dienolates to fluorinated
 sulfinylimines
;
_journal_name_full               Chem.Commun.
_journal_page_first              7492
_journal_paper_doi               10.1039/c3cc43741h
_journal_volume                  49
_journal_year                    2013
_chemical_absolute_configuration ad
_chemical_formula_sum            'C10 H14 F3 N O3 S'
_chemical_formula_weight         285.28
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.722(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.331(3)
_cell_length_b                   9.435(4)
_cell_length_c                   9.034(4)
_cell_measurement_reflns_used    2657
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      56.406
_cell_measurement_theta_min      4.821
_cell_volume                     664.2(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_av_sigmaI/netI    0.0359
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            4001
_diffrn_reflns_theta_full        25.98
_diffrn_reflns_theta_max         25.98
_diffrn_reflns_theta_min         2.41
_exptl_absorpt_coefficient_mu    0.279
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79802
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.427
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             296
_exptl_crystal_size_max          0.265
_exptl_crystal_size_mid          0.175
_exptl_crystal_size_min          0.123
_refine_diff_density_max         0.172
_refine_diff_density_min         -0.187
_refine_diff_density_rms         0.045
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.09(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     170
_refine_ls_number_reflns         2345
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0331
_refine_ls_R_factor_gt           0.0323
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0532P)²+0.0394P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0839
_refine_ls_wR_factor_ref         0.0850
_reflns_number_gt                2282
_reflns_number_total             2345
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3cc43741h.txt
_cod_data_source_block           cd213246
_cod_original_cell_volume        664.1(5)
_cod_original_sg_symbol_H-M      P2(1)
_cod_database_code               7109635
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
S1 S 0.01038(5) 0.92912(5) 0.44050(5) 0.04382(14) Uani 1 1 d .
F1 F 0.10195(19) 0.9288(2) 0.81039(16) 0.0824(4) Uani 1 1 d .
F2 F 0.3410(3) 1.0379(2) 0.8752(2) 0.0963(6) Uani 1 1 d .
F3 F 0.3323(3) 0.8262(3) 0.95388(18) 0.1002(6) Uani 1 1 d .
N1 N 0.21974(17) 0.9439(2) 0.54645(16) 0.0420(3) Uani 1 1 d .
O1 O 0.6238(2) 0.7425(2) 0.4155(2) 0.0742(5) Uani 1 1 d .
O2 O 0.49546(18) 0.73615(17) 0.59384(18) 0.0547(4) Uani 1 1 d .
O3 O -0.07481(19) 1.06515(19) 0.44761(19) 0.0623(4) Uani 1 1 d .
C1 C 0.5950(3) 0.7996(2) 0.5207(3) 0.0535(5) Uani 1 1 d .
C2 C 0.6511(2) 0.9370(3) 0.5959(2) 0.0547(4) Uani 1 1 d .
H2 H 0.7194 1.0020 0.5681 0.066 Uiso 1 1 calc R
C3 C 0.5883(2) 0.9533(3) 0.7100(2) 0.0528(5) Uani 1 1 d .
H3 H 0.6068 1.0317 0.7764 0.063 Uiso 1 1 calc R
C4 C 0.4835(2) 0.8272(2) 0.7163(2) 0.0508(4) Uani 1 1 d .
H4 H 0.5350 0.7801 0.8190 0.061 Uiso 1 1 calc R
C5 C 0.2918(2) 0.8552(2) 0.6843(2) 0.0437(4) Uani 1 1 d .
H5 H 0.2324 0.7638 0.6608 0.052 Uiso 1 1 calc R
C6 C 0.2671(3) 0.9144(3) 0.8311(2) 0.0627(6) Uani 1 1 d .
C7 C 0.0215(2) 0.9227(3) 0.2405(2) 0.0532(4) Uani 1 1 d .
C8 C 0.1130(4) 1.0523(3) 0.2109(3) 0.0732(7) Uani 1 1 d .
H8A H 0.2333 1.0456 0.2719 0.110 Uiso 1 1 calc R
H8B H 0.0667 1.1358 0.2416 0.110 Uiso 1 1 calc R
H8C H 0.0969 1.0578 0.1004 0.110 Uiso 1 1 calc R
C9 C 0.1113(4) 0.7851(3) 0.2291(3) 0.0688(7) Uani 1 1 d .
H9A H 0.1025 0.7698 0.1214 0.103 Uiso 1 1 calc R
H9B H 0.0581 0.7077 0.2632 0.103 Uiso 1 1 calc R
H9C H 0.2301 0.7907 0.2954 0.103 Uiso 1 1 calc R
C10 C -0.1671(3) 0.9188(5) 0.1316(3) 0.0922(9) Uani 1 1 d .
H10A H -0.2218 1.0061 0.1414 0.138 Uiso 1 1 calc R
H10B H -0.2238 0.8412 0.1613 0.138 Uiso 1 1 calc R
H10C H -0.1740 0.9068 0.0240 0.138 Uiso 1 1 calc R
H1 H 0.258(3) 1.030(3) 0.550(2) 0.038(5) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O3 S1 N1 108.79(10)
O3 S1 C7 105.23(11)
N1 S1 C7 99.19(8)
C5 N1 S1 118.48(13)
C5 N1 H1 118.3(14)
S1 N1 H1 113.3(14)
C1 O2 C4 109.31(17)
O1 C1 O2 121.1(2)
O1 C1 C2 130.7(2)
O2 C1 C2 108.21(18)
C3 C2 C1 108.5(2)
C3 C2 H2 125.8
C1 C2 H2 125.8
C2 C3 C4 109.7(2)
C2 C3 H3 125.2
C4 C3 H3 125.2
O2 C4 C3 104.33(16)
O2 C4 C5 107.98(16)
C3 C4 C5 115.98(18)
O2 C4 H4 109.4
C3 C4 H4 109.4
C5 C4 H4 109.4
N1 C5 C6 113.38(19)
N1 C5 C4 110.39(14)
C6 C5 C4 110.54(16)
N1 C5 H5 107.4
C6 C5 H5 107.4
C4 C5 H5 107.4
F2 C6 F1 107.7(3)
F2 C6 F3 106.9(2)
F1 C6 F3 106.06(18)
F2 C6 C5 113.42(19)
F1 C6 C5 111.62(17)
F3 C6 C5 110.7(2)
C8 C7 C9 112.81(19)
C8 C7 C10 111.8(2)
C9 C7 C10 110.7(3)
C8 C7 S1 110.47(17)
C9 C7 S1 106.95(16)
C10 C7 S1 103.53(16)
C7 C8 H8A 109.5
C7 C8 H8B 109.5
H8A C8 H8B 109.5
C7 C8 H8C 109.5
H8A C8 H8C 109.5
H8B C8 H8C 109.5
C7 C9 H9A 109.5
C7 C9 H9B 109.5
H9A C9 H9B 109.5
C7 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C7 C10 H10A 109.5
C7 C10 H10B 109.5
H10A C10 H10B 109.5
C7 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
S1 O3 1.4790(18)
S1 N1 1.6721(15)
S1 C7 1.843(2)
F1 C6 1.328(3)
F2 C6 1.312(3)
F3 C6 1.339(3)
N1 C5 1.443(2)
N1 H1 0.86(2)
O1 C1 1.189(3)
O2 C1 1.367(3)
O2 C4 1.432(3)
C1 C2 1.462(3)
C2 C3 1.319(3)
C2 H2 0.9300
C3 C4 1.489(3)
C3 H3 0.9300
C4 C5 1.542(3)
C4 H4 0.9800
C5 C6 1.518(3)
C5 H5 0.9800
C7 C8 1.514(4)
C7 C9 1.520(4)
C7 C10 1.531(3)
C8 H8A 0.9600
C8 H8B 0.9600
C8 H8C 0.9600
C9 H9A 0.9600
C9 H9B 0.9600
C9 H9C 0.9600
C10 H10A 0.9600
C10 H10B 0.9600
C10 H10C 0.9600
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1 O1 0.86(2) 2.21(3) 3.072(3) 173.8(19) 2_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O3 S1 N1 C5 116.52(16)
C7 S1 N1 C5 -133.84(16)
C4 O2 C1 O1 179.4(2)
C4 O2 C1 C2 -0.1(2)
O1 C1 C2 C3 -178.9(2)
O2 C1 C2 C3 0.5(2)
C1 C2 C3 C4 -0.8(2)
C1 O2 C4 C3 -0.3(2)
C1 O2 C4 C5 123.60(17)
C2 C3 C4 O2 0.7(2)
C2 C3 C4 C5 -117.9(2)
S1 N1 C5 C6 -83.2(2)
S1 N1 C5 C4 152.11(15)
O2 C4 C5 N1 -70.0(2)
C3 C4 C5 N1 46.6(2)
O2 C4 C5 C6 163.77(19)
C3 C4 C5 C6 -79.6(2)
N1 C5 C6 F2 -61.4(2)
C4 C5 C6 F2 63.2(3)
N1 C5 C6 F1 60.5(3)
C4 C5 C6 F1 -175.0(2)
N1 C5 C6 F3 178.38(18)
C4 C5 C6 F3 -57.0(3)
O3 S1 C7 C8 55.9(2)
N1 S1 C7 C8 -56.5(2)
O3 S1 C7 C9 179.06(16)
N1 S1 C7 C9 66.59(18)
O3 S1 C7 C10 -63.9(2)
N1 S1 C7 C10 -176.4(2)
