#------------------------------------------------------------------------------
#$Date: 2016-03-26 12:46:26 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180215 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/01/7110166.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7110166
loop_
_publ_author_name
'Pengfei Ai'
'Andreas A. Danopoulos'
'Pierre Braunstein'
'Kirill Yu. Monakhovc'
_publ_section_title
;
 A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear
 complexes of d10 coinage metals
;
_journal_name_full               Chem.Commun.
_journal_page_first              103
_journal_paper_doi               10.1039/c3cc47370h
_journal_volume                  50
_journal_year                    2013
_chemical_formula_moiety
'C38 H76 Ag3 N4 P4, 3(C F3 O3 S), 2(C H2 Cl2)'
_chemical_formula_sum            'C43 H80 Ag3 Cl4 F9 N4 O9 P4 S3'
_chemical_formula_weight         1653.58
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.5334(6)
_cell_length_b                   15.6264(5)
_cell_length_c                   25.5667(7)
_cell_measurement_reflns_used    8880
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.95
_cell_measurement_theta_min      2.40
_cell_volume                     6605.3(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  triumph
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0382
_diffrn_reflns_av_sigmaI/netI    0.0495
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            34171
_diffrn_reflns_theta_full        31.02
_diffrn_reflns_theta_max         31.02
_diffrn_reflns_theta_min         1.53
_exptl_absorpt_coefficient_mu    1.308
_exptl_absorpt_correction_T_max  0.7798
_exptl_absorpt_correction_T_min  0.7272
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3344
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.765
_refine_diff_density_min         -1.403
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         10868
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0973
_refine_ls_R_factor_gt           0.0454
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0308P)²+20.4278P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0904
_refine_ls_wR_factor_ref         0.1137
_reflns_number_gt                6629
_reflns_number_total             10868
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c3cc47370h.txt
_cod_data_source_block           pbad130425
_cod_database_code               7110166
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
'x-1/2, y, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2371(3) 0.2500 0.49981(17) 0.0194(5) Uani 1 2 d S . .
C2 C 0.2510(2) 0.2074(2) 0.41703(13) 0.0267(8) Uani 1 1 d . . .
H2 H 0.2561 0.1713 0.3873 0.032 Uiso 1 1 calc R . .
C3 C 0.1534(2) 0.0263(3) 0.45221(14) 0.0280(8) Uani 1 1 d . . .
C4 C 0.1334(4) -0.0582(3) 0.47944(19) 0.0546(15) Uani 1 1 d . . .
H4A H 0.0844 -0.0828 0.4639 0.082 Uiso 1 1 calc R . .
H4B H 0.1243 -0.0478 0.5168 0.082 Uiso 1 1 calc R . .
H4C H 0.1785 -0.0982 0.4750 0.082 Uiso 1 1 calc R . .
C5 C 0.1685(3) 0.0076(3) 0.39435(15) 0.0372(10) Uani 1 1 d . . .
H5A H 0.2109 -0.0360 0.3910 0.056 Uiso 1 1 calc R . .
H5B H 0.1858 0.0601 0.3767 0.056 Uiso 1 1 calc R . .
H5C H 0.1185 -0.0135 0.3782 0.056 Uiso 1 1 calc R . .
C6 C 0.0814(3) 0.0880(4) 0.4575(2) 0.0529(15) Uani 1 1 d . . .
H6A H 0.0935 0.1414 0.4391 0.079 Uiso 1 1 calc R . .
H6B H 0.0716 0.1001 0.4946 0.079 Uiso 1 1 calc R . .
H6C H 0.0331 0.0616 0.4422 0.079 Uiso 1 1 calc R . .
C7 C 0.3406(2) 0.0338(3) 0.47806(15) 0.0295(8) Uani 1 1 d . . .
C8 C 0.3435(3) -0.0568(3) 0.5013(2) 0.0544(14) Uani 1 1 d . . .
H8A H 0.3098 -0.0952 0.4803 0.082 Uiso 1 1 calc R . .
H8B H 0.3230 -0.0555 0.5373 0.082 Uiso 1 1 calc R . .
H8C H 0.3994 -0.0775 0.5013 0.082 Uiso 1 1 calc R . .
C9 C 0.3686(3) 0.0315(3) 0.42111(17) 0.0461(11) Uani 1 1 d . . .
H9A H 0.3663 0.0893 0.4063 0.069 Uiso 1 1 calc R . .
H9B H 0.3332 -0.0065 0.4010 0.069 Uiso 1 1 calc R . .
H9C H 0.4243 0.0101 0.4195 0.069 Uiso 1 1 calc R . .
C10 C 0.3967(3) 0.0927(4) 0.5094(2) 0.0499(13) Uani 1 1 d . . .
H10A H 0.4520 0.0703 0.5080 0.075 Uiso 1 1 calc R . .
H10B H 0.3785 0.0949 0.5459 0.075 Uiso 1 1 calc R . .
H10C H 0.3954 0.1503 0.4944 0.075 Uiso 1 1 calc R . .
C11 C 0.2142(3) 0.2500 0.66781(17) 0.0166(9) Uani 1 2 d S . .
C12 C 0.2048(3) 0.2077(3) 0.75038(15) 0.0392(11) Uani 1 1 d . . .
H12 H 0.2015 0.1717 0.7803 0.047 Uiso 1 1 calc R . .
C13 C 0.3291(3) 0.0492(3) 0.69993(16) 0.0328(9) Uani 1 1 d . . .
C14 C 0.3542(3) -0.0341(3) 0.6738(2) 0.0565(14) Uani 1 1 d . . .
H14A H 0.3456 -0.0296 0.6359 0.085 Uiso 1 1 calc R . .
H14B H 0.3217 -0.0812 0.6877 0.085 Uiso 1 1 calc R . .
H14C H 0.4116 -0.0450 0.6808 0.085 Uiso 1 1 calc R . .
C15 C 0.3375(4) 0.0388(5) 0.7592(2) 0.074(2) Uani 1 1 d . . .
H15A H 0.3947 0.0317 0.7682 0.112 Uiso 1 1 calc R . .
H15B H 0.3072 -0.0117 0.7706 0.112 Uiso 1 1 calc R . .
H15C H 0.3160 0.0897 0.7767 0.112 Uiso 1 1 calc R . .
C16 C 0.3827(3) 0.1209(4) 0.6801(3) 0.0683(19) Uani 1 1 d . . .
H16A H 0.4395 0.1064 0.6866 0.102 Uiso 1 1 calc R . .
H16B H 0.3692 0.1741 0.6984 0.102 Uiso 1 1 calc R . .
H16C H 0.3741 0.1284 0.6424 0.102 Uiso 1 1 calc R . .
C17 C 0.1429(3) 0.0097(3) 0.70819(17) 0.0340(10) Uani 1 1 d . . .
C18 C 0.1635(9) -0.0850(11) 0.6966(5) 0.043(2) Uani 0.55 1 d P A 1
H18A H 0.2079 -0.1035 0.7194 0.064 Uiso 0.55 1 calc PR A 1
H18B H 0.1798 -0.0909 0.6600 0.064 Uiso 0.55 1 calc PR A 1
H18C H 0.1158 -0.1206 0.7033 0.064 Uiso 0.55 1 calc PR A 1
C19 C 0.1247(11) 0.0187(11) 0.7660(9) 0.057(4) Uani 0.55 1 d P A 1
H19A H 0.0991 0.0743 0.7724 0.086 Uiso 0.55 1 calc PR A 1
H19B H 0.1751 0.0149 0.7859 0.086 Uiso 0.55 1 calc PR A 1
H19C H 0.0880 -0.0271 0.7769 0.086 Uiso 0.55 1 calc PR A 1
C20 C 0.0634(10) 0.0323(12) 0.6760(4) 0.055(4) Uani 0.55 1 d P A 1
H20A H 0.0189 -0.0047 0.6875 0.083 Uiso 0.55 1 calc PR A 1
H20B H 0.0733 0.0232 0.6386 0.083 Uiso 0.55 1 calc PR A 1
H20C H 0.0489 0.0923 0.6821 0.083 Uiso 0.55 1 calc PR A 1
C18B C 0.1447(12) -0.0766(15) 0.6802(6) 0.043(2) Uani 0.45 1 d P A 2
H18D H 0.1990 -0.1013 0.6829 0.064 Uiso 0.45 1 calc PR A 2
H18E H 0.1307 -0.0685 0.6433 0.064 Uiso 0.45 1 calc PR A 2
H18F H 0.1054 -0.1153 0.6965 0.064 Uiso 0.45 1 calc PR A 2
C19B C 0.1540(14) -0.0066(16) 0.7686(11) 0.057(4) Uani 0.45 1 d P A 2
H19D H 0.1602 0.0483 0.7867 0.086 Uiso 0.45 1 calc PR A 2
H19E H 0.2023 -0.0416 0.7744 0.086 Uiso 0.45 1 calc PR A 2
H19F H 0.1064 -0.0365 0.7823 0.086 Uiso 0.45 1 calc PR A 2
C20B C 0.0665(13) 0.0556(15) 0.6995(5) 0.055(4) Uani 0.45 1 d P A 2
H20D H 0.0211 0.0190 0.7098 0.083 Uiso 0.45 1 calc PR A 2
H20E H 0.0616 0.0704 0.6624 0.083 Uiso 0.45 1 calc PR A 2
H20F H 0.0660 0.1080 0.7205 0.083 Uiso 0.45 1 calc PR A 2
C21 C 0.4156(5) 0.7500 0.7970(3) 0.058(2) Uani 1 2 d S . .
C22 C -0.0459(4) 0.2500 0.6386(2) 0.0353(14) Uani 1 2 d S . .
C23 C 0.4279(4) 0.7500 0.3948(3) 0.0428(16) Uani 1 2 d S . .
C24 C 0.6690(6) 0.7500 0.9434(3) 0.071(3) Uani 1 2 d S . .
H24A H 0.6695 0.6989 0.9663 0.085 Uiso 0.50 1 calc PR . .
H24B H 0.6695 0.8011 0.9663 0.085 Uiso 0.50 1 calc PR . .
C25 C 0.5228(9) 0.2500 0.3577(6) 0.155(7) Uani 1 2 d S . .
H25A H 0.5523 0.1990 0.3449 0.186 Uiso 0.50 1 calc PR . .
H25B H 0.5523 0.3010 0.3449 0.186 Uiso 0.50 1 calc PR . .
N1 N 0.24206(19) 0.18097(18) 0.46910(10) 0.0194(5) Uani 1 1 d . . .
N2 N 0.2105(2) 0.1809(2) 0.69819(11) 0.0269(7) Uani 1 1 d . . .
O1 O 0.2799(2) 0.82731(19) 0.79712(11) 0.0432(8) Uani 1 1 d . . .
O2 O 0.3196(3) 0.7500 0.71891(15) 0.0440(12) Uani 1 2 d S . .
O3 O 0.06278(18) 0.17196(19) 0.58467(11) 0.0361(7) Uani 1 1 d . . .
O4 O -0.0420(3) 0.2500 0.53780(18) 0.0471(12) Uani 1 2 d S . .
O5 O 0.2988(2) 0.82779(18) 0.36895(11) 0.0372(7) Uani 1 1 d . . .
O6 O 0.2982(3) 0.7500 0.45098(15) 0.0436(12) Uani 1 2 d S . .
F1 F 0.4554(2) 0.8179(3) 0.77974(16) 0.0908(13) Uani 1 1 d . . .
F2 F 0.4197(3) 0.7500 0.84892(18) 0.096(2) Uani 1 2 d S . .
F3 F -0.09225(18) 0.18118(19) 0.64090(13) 0.0603(9) Uani 1 1 d . . .
F4 F -0.0004(3) 0.2500 0.68134(14) 0.0528(11) Uani 1 2 d S . .
F5 F 0.4588(2) 0.8186(2) 0.41805(14) 0.0718(10) Uani 1 1 d . . .
F6 F 0.4557(3) 0.7500 0.34564(18) 0.0652(13) Uani 1 2 d S . .
P1 P 0.23668(6) 0.07514(6) 0.49066(3) 0.01948(18) Uani 1 1 d . . .
P2 P 0.22412(6) 0.07504(6) 0.67707(3) 0.02249(19) Uani 1 1 d . A .
S1 S 0.31181(10) 0.7500 0.77475(5) 0.0297(3) Uani 1 2 d S . .
S2 S 0.01597(8) 0.2500 0.57947(5) 0.0270(3) Uani 1 2 d S . .
S3 S 0.31773(10) 0.7500 0.39620(5) 0.0272(3) Uani 1 2 d S . .
Ag1 Ag 0.22386(2) 0.2500 0.583520(13) 0.01931(8) Uani 1 2 d S . .
Ag2 Ag 0.211368(19) 0.073876(16) 0.583389(10) 0.02618(7) Uani 1 1 d . A .
Cl1 Cl 0.75366(19) 0.7500 0.90767(13) 0.1475(19) Uani 1 2 d S . .
Cl2 Cl 0.58248(18) 0.7500 0.90955(11) 0.1419(18) Uani 1 2 d S . .
Cl3 Cl 0.4283(3) 0.2500 0.32940(16) 0.166(2) Uani 1 2 d S . .
Cl4 Cl 0.5276(3) 0.2500 0.42188(19) 0.186(2) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 N1 107.6(4) . 7_565
N1 C1 Ag1 126.19(19) . .
N1 C1 Ag1 126.19(19) 7_565 .
C2 C2 N1 107.12(18) 7_565 .
C2 C2 H2 126.4 7_565 .
N1 C2 H2 126.4 . .
C5 C3 C4 108.1(3) . .
C5 C3 C6 109.4(4) . .
C4 C3 C6 109.5(4) . .
C5 C3 P1 118.0(3) . .
C4 C3 P1 105.9(3) . .
C6 C3 P1 105.7(3) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C3 C5 H5A 109.5 . .
C3 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C3 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C3 C6 H6A 109.5 . .
C3 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C3 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C9 C7 C10 109.2(4) . .
C9 C7 C8 109.7(4) . .
C10 C7 C8 109.3(4) . .
C9 C7 P1 116.9(3) . .
C10 C7 P1 105.1(3) . .
C8 C7 P1 106.3(3) . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C7 C9 H9A 109.5 . .
C7 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C7 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C7 C10 H10A 109.5 . .
C7 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C7 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N2 C11 N2 108.4(4) 7_565 .
N2 C11 Ag1 125.8(2) 7_565 .
N2 C11 Ag1 125.8(2) . .
C12 C12 N2 107.4(2) 7_565 .
C12 C12 H12 126.3 7_565 .
N2 C12 H12 126.3 . .
C16 C13 C14 109.0(4) . .
C16 C13 C15 110.9(5) . .
C14 C13 C15 108.7(4) . .
C16 C13 P2 106.1(3) . .
C14 C13 P2 107.4(3) . .
C15 C13 P2 114.5(4) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C20B C17 C19 86.1(8) . .
C20B C17 C18B 112.2(11) . .
C19 C17 C18B 122.9(10) . .
C20B C17 C18 128.9(11) . .
C19 C17 C18 108.6(8) . .
C20B C17 C19B 109.1(9) . .
C18B C17 C19B 108.3(11) . .
C18 C17 C19B 90.4(10) . .
C19 C17 C20 108.6(8) . .
C18B C17 C20 88.3(9) . .
C18 C17 C20 107.2(8) . .
C19B C17 C20 129.7(9) . .
C20B C17 P2 106.7(9) . .
C19 C17 P2 120.5(9) . .
C18B C17 P2 105.7(8) . .
C18 C17 P2 106.5(7) . .
C19B C17 P2 115.0(10) . .
C20 C17 P2 104.6(6) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
C17 C20 H20A 109.5 . .
C17 C20 H20B 109.5 . .
C17 C20 H20C 109.5 . .
C17 C18B H18D 109.5 . .
C17 C18B H18E 109.5 . .
H18D C18B H18E 109.5 . .
C17 C18B H18F 109.5 . .
H18D C18B H18F 109.5 . .
H18E C18B H18F 109.5 . .
C17 C19B H19D 109.5 . .
C17 C19B H19E 109.5 . .
H19D C19B H19E 109.5 . .
C17 C19B H19F 109.5 . .
H19D C19B H19F 109.5 . .
H19E C19B H19F 109.5 . .
C17 C20B H20D 109.5 . .
C17 C20B H20E 109.5 . .
H20D C20B H20E 109.5 . .
C17 C20B H20F 109.5 . .
H20D C20B H20F 109.5 . .
H20E C20B H20F 109.5 . .
F1 C21 F1 106.5(7) . 7_575
F1 C21 F2 107.9(5) . .
F1 C21 F2 107.9(5) 7_575 .
F1 C21 S1 111.5(4) . .
F1 C21 S1 111.5(4) 7_575 .
F2 C21 S1 111.2(6) . .
F3 C22 F3 108.9(5) 7_565 .
F3 C22 F4 107.0(4) 7_565 .
F3 C22 F4 107.0(4) . .
F3 C22 S2 111.2(3) 7_565 .
F3 C22 S2 111.2(3) . .
F4 C22 S2 111.3(4) . .
F5 C23 F5 107.7(6) 7_575 .
F5 C23 F6 106.8(4) 7_575 .
F5 C23 F6 106.8(4) . .
F5 C23 S3 112.0(4) 7_575 .
F5 C23 S3 112.0(4) . .
F6 C23 S3 111.2(5) . .
Cl2 C24 Cl1 115.6(5) . .
Cl2 C24 H24A 108.4 . .
Cl1 C24 H24A 108.4 . .
Cl2 C24 H24B 108.4 . .
Cl1 C24 H24B 108.4 . .
H24A C24 H24B 107.4 . .
Cl4 C25 Cl3 117.6(8) . .
Cl4 C25 H25A 107.9 . .
Cl3 C25 H25A 107.9 . .
Cl4 C25 H25B 107.9 . .
Cl3 C25 H25B 107.9 . .
H25A C25 H25B 107.2 . .
C1 N1 C2 109.1(3) . .
C1 N1 P1 125.2(2) . .
C2 N1 P1 125.7(2) . .
C11 N2 C12 108.4(3) . .
C11 N2 P2 125.4(2) . .
C12 N2 P2 125.7(3) . .
N1 P1 C3 105.07(17) . .
N1 P1 C7 103.11(17) . .
C3 P1 C7 116.75(18) . .
N1 P1 Ag2 109.12(9) . .
C3 P1 Ag2 112.91(12) . .
C7 P1 Ag2 109.13(13) . .
N2 P2 C17 107.03(18) . .
N2 P2 C13 103.04(18) . .
C17 P2 C13 114.57(18) . .
N2 P2 Ag2 107.61(10) . .
C17 P2 Ag2 110.94(15) . .
C13 P2 Ag2 112.94(14) . .
O2 S1 O1 115.43(15) . 7_575
O2 S1 O1 115.43(15) . .
O1 S1 O1 114.4(3) 7_575 .
O2 S1 C21 103.2(3) . .
O1 S1 C21 102.9(2) 7_575 .
O1 S1 C21 102.9(2) . .
O4 S2 O3 115.15(15) . 7_565
O4 S2 O3 115.15(15) . .
O3 S2 O3 114.4(3) 7_565 .
O4 S2 C22 103.9(3) . .
O3 S2 C22 102.90(17) 7_565 .
O3 S2 C22 102.90(17) . .
O5 S3 O5 115.7(2) . 7_575
O5 S3 O6 115.09(15) . .
O5 S3 O6 115.09(15) 7_575 .
O5 S3 C23 102.04(19) . .
O5 S3 C23 102.04(19) 7_575 .
O6 S3 C23 104.1(3) . .
C1 Ag1 C11 178.4(2) . .
C1 Ag1 Ag2 90.368(14) . 7_565
C11 Ag1 Ag2 89.754(14) . 7_565
C1 Ag1 Ag2 90.368(14) . .
C11 Ag1 Ag2 89.754(14) . .
Ag2 Ag1 Ag2 171.41(2) 7_565 .
P2 Ag2 P1 164.93(4) . .
P2 Ag2 Ag1 89.12(3) . .
P1 Ag2 Ag1 88.85(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.337(4) .
C1 N1 1.337(4) 7_565
C1 Ag1 2.152(4) .
C2 C2 1.332(7) 7_565
C2 N1 1.402(4) .
C2 H2 0.9500 .
C3 C5 1.529(5) .
C3 C4 1.530(6) .
C3 C6 1.537(6) .
C3 P1 1.856(4) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 C9 1.529(6) .
C7 C10 1.533(6) .
C7 C8 1.537(6) .
C7 P1 1.863(4) .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 N2 1.332(4) 7_565
C11 N2 1.332(4) .
C11 Ag1 2.161(4) .
C12 C12 1.321(8) 7_565
C12 N2 1.402(5) .
C12 H12 0.9500 .
C13 C16 1.516(6) .
C13 C14 1.520(7) .
C13 C15 1.529(6) .
C13 P2 1.876(4) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C20B 1.47(2) .
C17 C19 1.51(2) .
C17 C18B 1.53(2) .
C17 C18 1.547(19) .
C17 C19B 1.58(3) .
C17 C20 1.590(16) .
C17 P2 1.866(4) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C18B H18D 0.9800 .
C18B H18E 0.9800 .
C18B H18F 0.9800 .
C19B H19D 0.9800 .
C19B H19E 0.9800 .
C19B H19F 0.9800 .
C20B H20D 0.9800 .
C20B H20E 0.9800 .
C20B H20F 0.9800 .
C21 F1 1.325(6) .
C21 F1 1.325(6) 7_575
C21 F2 1.329(8) .
C21 S1 1.808(8) .
C22 F3 1.321(4) 7_565
C22 F3 1.321(4) .
C22 F4 1.328(7) .
C22 S2 1.826(6) .
C23 F5 1.328(5) 7_575
C23 F5 1.328(5) .
C23 F6 1.338(8) .
C23 S3 1.822(7) .
C24 Cl2 1.672(10) .
C24 Cl1 1.673(9) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 Cl4 1.642(15) .
C25 Cl3 1.722(16) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
N1 P1 1.745(3) .
N2 P2 1.754(3) .
O1 S1 1.437(3) .
O2 S1 1.433(4) .
O3 S2 1.450(3) .
O4 S2 1.433(4) .
O5 S3 1.436(3) .
O6 S3 1.437(4) .
P1 Ag2 2.4076(9) .
P2 Ag2 2.4046(9) .
S1 O1 1.437(3) 7_575
S2 O3 1.450(3) 7_565
S3 O5 1.436(3) 7_575
Ag1 Ag2 2.7599(3) 7_565
Ag1 Ag2 2.7599(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 N1 C2 0.4(6) 7_565 .
Ag1 C1 N1 C2 -179.5(3) . .
N1 C1 N1 P1 -178.73(16) 7_565 .
Ag1 C1 N1 P1 1.4(6) . .
C2 C2 N1 C1 -0.3(4) 7_565 .
C2 C2 N1 P1 178.9(2) 7_565 .
N2 C11 N2 C12 -0.4(6) 7_565 .
Ag1 C11 N2 C12 179.9(3) . .
N2 C11 N2 P2 -172.71(16) 7_565 .
Ag1 C11 N2 P2 7.6(6) . .
C12 C12 N2 C11 0.3(4) 7_565 .
C12 C12 N2 P2 172.5(2) 7_565 .
C1 N1 P1 C3 124.6(4) . .
C2 N1 P1 C3 -54.4(4) . .
C1 N1 P1 C7 -112.7(4) . .
C2 N1 P1 C7 68.3(3) . .
C1 N1 P1 Ag2 3.2(4) . .
C2 N1 P1 Ag2 -175.8(3) . .
C5 C3 P1 N1 72.6(4) . .
C4 C3 P1 N1 -166.2(3) . .
C6 C3 P1 N1 -50.1(3) . .
C5 C3 P1 C7 -40.9(4) . .
C4 C3 P1 C7 80.3(3) . .
C6 C3 P1 C7 -163.6(3) . .
C5 C3 P1 Ag2 -168.6(3) . .
C4 C3 P1 Ag2 -47.4(3) . .
C6 C3 P1 Ag2 68.8(3) . .
C9 C7 P1 N1 -62.9(4) . .
C10 C7 P1 N1 58.4(3) . .
C8 C7 P1 N1 174.3(3) . .
C9 C7 P1 C3 51.7(4) . .
C10 C7 P1 C3 173.0(3) . .
C8 C7 P1 C3 -71.1(3) . .
C9 C7 P1 Ag2 -178.8(3) . .
C10 C7 P1 Ag2 -57.5(3) . .
C8 C7 P1 Ag2 58.4(3) . .
C11 N2 P2 C17 -135.5(4) . .
C12 N2 P2 C17 53.5(4) . .
C11 N2 P2 C13 103.3(4) . .
C12 N2 P2 C13 -67.7(4) . .
C11 N2 P2 Ag2 -16.2(4) . .
C12 N2 P2 Ag2 172.8(3) . .
C20B C17 P2 N2 48.4(8) . .
C19 C17 P2 N2 -46.9(7) . .
C18B C17 P2 N2 168.0(6) . .
C18 C17 P2 N2 -171.1(4) . .
C19B C17 P2 N2 -72.7(8) . .
C20 C17 P2 N2 75.6(7) . .
C20B C17 P2 C13 162.0(7) . .
C19 C17 P2 C13 66.6(7) . .
C18B C17 P2 C13 -78.5(6) . .
C18 C17 P2 C13 -57.5(5) . .
C19B C17 P2 C13 40.9(9) . .
C20 C17 P2 C13 -170.9(7) . .
C20B C17 P2 Ag2 -68.7(7) . .
C19 C17 P2 Ag2 -164.0(6) . .
C18B C17 P2 Ag2 50.8(6) . .
C18 C17 P2 Ag2 71.8(5) . .
C19B C17 P2 Ag2 170.2(8) . .
C20 C17 P2 Ag2 -41.5(7) . .
C16 C13 P2 N2 -51.6(4) . .
C14 C13 P2 N2 -168.1(3) . .
C15 C13 P2 N2 71.1(4) . .
C16 C13 P2 C17 -167.5(4) . .
C14 C13 P2 C17 76.1(4) . .
C15 C13 P2 C17 -44.7(5) . .
C16 C13 P2 Ag2 64.2(4) . .
C14 C13 P2 Ag2 -52.3(3) . .
C15 C13 P2 Ag2 -173.1(4) . .
F1 C21 S1 O2 59.5(5) . .
F1 C21 S1 O2 -59.5(5) 7_575 .
F2 C21 S1 O2 180.000(2) . .
F1 C21 S1 O1 179.9(4) . 7_575
F1 C21 S1 O1 60.9(5) 7_575 7_575
F2 C21 S1 O1 -59.59(14) . 7_575
F1 C21 S1 O1 -60.9(5) . .
F1 C21 S1 O1 -179.9(4) 7_575 .
F2 C21 S1 O1 59.59(14) . .
F3 C22 S2 O4 -60.8(4) 7_565 .
F3 C22 S2 O4 60.8(4) . .
F4 C22 S2 O4 180.000(1) . .
F3 C22 S2 O3 59.6(4) 7_565 7_565
F3 C22 S2 O3 -178.8(4) . 7_565
F4 C22 S2 O3 -59.60(14) . 7_565
F3 C22 S2 O3 178.8(4) 7_565 .
F3 C22 S2 O3 -59.6(4) . .
F4 C22 S2 O3 59.60(14) . .
F5 C23 S3 O5 -179.4(4) 7_575 .
F5 C23 S3 O5 59.4(5) . .
F6 C23 S3 O5 -59.97(13) . .
F5 C23 S3 O5 -59.4(5) 7_575 7_575
F5 C23 S3 O5 179.4(4) . 7_575
F6 C23 S3 O5 59.97(13) . 7_575
F5 C23 S3 O6 60.6(4) 7_575 .
F5 C23 S3 O6 -60.6(4) . .
F6 C23 S3 O6 180.0 . .
N1 C1 Ag1 Ag2 -175.8(4) . 7_565
N1 C1 Ag1 Ag2 4.3(4) 7_565 7_565
N1 C1 Ag1 Ag2 -4.3(4) . .
N1 C1 Ag1 Ag2 175.8(4) 7_565 .
N2 C11 Ag1 Ag2 -4.1(4) 7_565 7_565
N2 C11 Ag1 Ag2 175.5(4) . 7_565
N2 C11 Ag1 Ag2 -175.5(4) 7_565 .
N2 C11 Ag1 Ag2 4.1(4) . .
N2 P2 Ag2 P1 95.90(17) . .
C17 P2 Ag2 P1 -147.33(17) . .
C13 P2 Ag2 P1 -17.1(2) . .
N2 P2 Ag2 Ag1 13.59(13) . .
C17 P2 Ag2 Ag1 130.36(15) . .
C13 P2 Ag2 Ag1 -99.44(15) . .
N1 P1 Ag2 P2 -86.87(17) . .
C3 P1 Ag2 P2 156.69(17) . .
C7 P1 Ag2 P2 25.1(2) . .
N1 P1 Ag2 Ag1 -4.53(12) . .
C3 P1 Ag2 Ag1 -120.96(15) . .
C7 P1 Ag2 Ag1 107.45(14) . .
C1 Ag1 Ag2 P2 169.18(14) . .
C11 Ag1 Ag2 P2 -9.19(14) . .
C1 Ag1 Ag2 P1 4.11(14) . .
C11 Ag1 Ag2 P1 -174.26(14) . .
