#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:05:57 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180222 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/08/7110869.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7110869
loop_
_publ_author_name
'Zhang, Lei'
'Cheng, Peng'
'Tang, Liang-Fu'
'Jiang, Zong-Hui'
'Liao, Dai-Zheng'
'Yan, Shi-Ping'
'Wang, Geng-Lin'
'Weng, Lin-Hong'
_publ_section_title
;
 Two dimensional stair-shaped coordination polymer exhibiting
 three-dimensional structure with cavities
;
_journal_issue                   8
_journal_name_full               'Chemical Communications'
_journal_page_first              717
_journal_paper_doi               10.1039/b000588f
_journal_year                    2000
_chemical_formula_sum            'C35 H28 Cr2 N8 Na2 O18'
_chemical_formula_weight         998.63
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.259(3)
_cell_angle_beta                 95.649(3)
_cell_angle_gamma                95.673(3)
_cell_formula_units_Z            2
_cell_length_a                   9.3366(15)
_cell_length_b                   9.5519(15)
_cell_length_c                   22.527(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1975.1(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0434
_diffrn_reflns_av_sigmaI/netI    0.0678
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            11435
_diffrn_reflns_theta_full        26.44
_diffrn_reflns_theta_max         26.44
_diffrn_reflns_theta_min         2.21
_exptl_absorpt_coefficient_mu    0.664
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1016
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.389
_refine_diff_density_min         -0.395
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.973
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     581
_refine_ls_number_reflns         7968
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.973
_refine_ls_R_factor_all          0.0783
_refine_ls_R_factor_gt           0.0442
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w==1/[σ²(Fo²)+(0.0488P)²+0.0000P] where P==(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0950
_refine_ls_wR_factor_ref         0.1066
_reflns_number_gt                5230
_reflns_number_total             7968
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b000588fsup1.cif
_cod_data_source_block           990629b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1975.1(5)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7110869
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cr2 Cr 0.19342(5) 0.75462(5) 0.38752(2) 0.02905(13) Uani 1 1 d .
Na2 Na 0.37184(13) 0.24149(12) 0.28392(5) 0.0391(3) Uani 1 1 d .
O9 O 0.1681(2) 0.63253(19) 0.31005(8) 0.0323(5) Uani 1 1 d .
O13 O 0.3724(2) 0.8533(2) 0.36866(9) 0.0341(5) Uani 1 1 d .
O10 O 0.2999(2) 0.6013(2) 0.41448(9) 0.0370(5) Uani 1 1 d .
N4 N 0.2020(2) 0.8583(2) 0.47294(10) 0.0324(5) Uani 1 1 d .
N3 N 0.0024(3) 0.6687(3) 0.41451(11) 0.0349(6) Uani 1 1 d .
O11 O 0.2391(2) 0.4344(2) 0.26723(9) 0.0424(5) Uani 1 1 d .
O15 O 0.4506(2) 1.0428(2) 0.32656(12) 0.0505(6) Uani 1 1 d .
O12 O 0.4043(2) 0.4169(2) 0.37503(10) 0.0473(6) Uani 1 1 d .
C28 C 0.2016(3) 1.0134(3) 0.34616(13) 0.0310(6) Uani 1 1 d .
O16 O 0.1795(2) 1.1336(2) 0.33800(10) 0.0436(5) Uani 1 1 d .
C27 C 0.3558(3) 0.9687(3) 0.34550(13) 0.0323(7) Uani 1 1 d .
C26 C 0.3240(3) 0.5094(3) 0.37129(13) 0.0324(7) Uani 1 1 d .
C25 C 0.2385(3) 0.5236(3) 0.31010(13) 0.0308(6) Uani 1 1 d .
C20 C 0.0901(3) 0.8202(3) 0.50431(13) 0.0330(7) Uani 1 1 d .
C19 C -0.0191(3) 0.7095(3) 0.47206(14) 0.0356(7) Uani 1 1 d .
C24 C 0.3016(3) 0.9649(3) 0.49758(14) 0.0420(8) Uani 1 1 d .
H24A H 0.3788 0.9902 0.4764 0.050 Uiso 1 1 calc R
C23 C 0.2942(4) 1.0380(4) 0.55287(15) 0.0476(8) Uani 1 1 d .
H23A H 0.3643 1.1122 0.5687 0.057 Uiso 1 1 calc R
C21 C 0.0785(4) 0.8901(4) 0.55988(14) 0.0453(8) Uani 1 1 d .
H21A H 0.0013 0.8635 0.5809 0.054 Uiso 1 1 calc R
C22 C 0.1810(4) 0.9993(4) 0.58440(15) 0.0501(9) Uani 1 1 d .
H22A H 0.1739 1.0468 0.6221 0.060 Uiso 1 1 calc R
C15 C -0.0981(4) 0.5768(4) 0.38058(16) 0.0504(9) Uani 1 1 d .
H15A H -0.0849 0.5505 0.3407 0.060 Uiso 1 1 calc R
C18 C -0.1391(4) 0.6542(4) 0.49650(17) 0.0554(10) Uani 1 1 d .
H18A H -0.1517 0.6819 0.5364 0.067 Uiso 1 1 calc R
C17 C -0.2403(4) 0.5573(4) 0.4609(2) 0.0707(12) Uani 1 1 d .
H17A H -0.3213 0.5181 0.4767 0.085 Uiso 1 1 calc R
C16 C -0.2203(4) 0.5197(4) 0.40254(19) 0.0671(11) Uani 1 1 d .
H16A H -0.2885 0.4561 0.3778 0.081 Uiso 1 1 calc R
Cr1 Cr 0.28666(5) 0.17661(5) 0.10587(2) 0.03083(13) Uani 1 1 d .
O6 O 0.2687(2) 0.1085(2) 0.18449(9) 0.0367(5) Uani 1 1 d .
O5 O 0.1894(2) -0.0127(2) 0.07558(9) 0.0392(5) Uani 1 1 d .
O2 O 0.1037(2) 0.2593(2) 0.10388(9) 0.0362(5) Uani 1 1 d .
O1 O 0.3667(2) 0.3690(2) 0.13910(9) 0.0343(5) Uani 1 1 d .
N2 N 0.4924(3) 0.1190(2) 0.10247(11) 0.0337(6) Uani 1 1 d .
N1 N 0.3280(3) 0.2277(3) 0.02263(11) 0.0338(6) Uani 1 1 d .
O3 O 0.2988(2) 0.5857(2) 0.15875(10) 0.0410(5) Uani 1 1 d .
O4 O 0.0139(2) 0.4608(2) 0.13277(10) 0.0434(5) Uani 1 1 d .
C12 C 0.1148(3) 0.3914(3) 0.12577(13) 0.0313(6) Uani 1 1 d .
C5 C 0.4669(3) 0.2241(3) 0.01099(14) 0.0356(7) Uani 1 1 d .
C11 C 0.2731(3) 0.4596(3) 0.14336(13) 0.0314(6) Uani 1 1 d .
C6 C 0.5599(3) 0.1601(3) 0.05536(14) 0.0352(7) Uani 1 1 d .
O8 O 0.1789(3) -0.0826(2) 0.22310(10) 0.0581(7) Uani 1 1 d .
C14 C 0.2009(3) -0.0169(3) 0.18098(14) 0.0361(7) Uani 1 1 d .
C13 C 0.1479(3) -0.0858(3) 0.11641(13) 0.0339(7) Uani 1 1 d .
O7 O 0.0742(3) -0.2004(2) 0.10818(11) 0.0508(6) Uani 1 1 d .
C10 C 0.5681(3) 0.0551(3) 0.14322(15) 0.0430(8) Uani 1 1 d .
H10A H 0.5229 0.0262 0.1755 0.052 Uiso 1 1 calc R
C1 C 0.2357(3) 0.2769(3) -0.01673(15) 0.0432(8) Uani 1 1 d .
H1A H 0.1396 0.2767 -0.0092 0.052 Uiso 1 1 calc R
C9 C 0.7088(4) 0.0304(4) 0.13938(17) 0.0544(9) Uani 1 1 d .
H9A H 0.7575 -0.0152 0.1683 0.065 Uiso 1 1 calc R
C3 C 0.4173(4) 0.3289(4) -0.07872(17) 0.0625(11) Uani 1 1 d .
H3A H 0.4478 0.3648 -0.1127 0.075 Uiso 1 1 calc R
C2 C 0.2758(4) 0.3280(4) -0.06778(16) 0.0553(10) Uani 1 1 d .
H2A H 0.2083 0.3612 -0.0944 0.066 Uiso 1 1 calc R
C7 C 0.7016(4) 0.1397(4) 0.04991(17) 0.0504(9) Uani 1 1 d .
H7A H 0.7465 0.1702 0.0178 0.060 Uiso 1 1 calc R
C8 C 0.7769(4) 0.0735(4) 0.09257(19) 0.0595(10) Uani 1 1 d .
H8A H 0.8730 0.0585 0.0894 0.071 Uiso 1 1 calc R
C4 C 0.5153(4) 0.2760(4) -0.03888(16) 0.0528(9) Uani 1 1 d .
H4A H 0.6118 0.2756 -0.0458 0.063 Uiso 1 1 calc R
Na1 Na 0.09108(12) 0.67529(12) 0.20020(5) 0.0395(3) Uani 1 1 d .
N5 N -0.1609(3) 0.6744(3) 0.22959(11) 0.0354(6) Uani 1 1 d .
N6 N -0.2882(2) 0.5896(3) 0.22229(11) 0.0326(6) Uani 1 1 d .
N7 N -0.2552(2) 0.3468(2) 0.23305(11) 0.0345(6) Uani 1 1 d .
N8 N -0.3530(3) 0.2841(3) 0.26556(12) 0.0416(6) Uani 1 1 d .
C29 C -0.1217(3) 0.3072(3) 0.24589(15) 0.0419(8) Uani 1 1 d .
H29A H -0.0386 0.3372 0.2291 0.050 Uiso 1 1 calc R
C32 C -0.2971(3) 0.4466(3) 0.19304(14) 0.0359(7) Uani 1 1 d .
H32A H -0.3958 0.4175 0.1751 0.043 Uiso 1 1 calc R
H32B H -0.2352 0.4448 0.1609 0.043 Uiso 1 1 calc R
C33 C -0.3932(3) 0.6542(4) 0.24679(15) 0.0463(8) Uani 1 1 d .
H33A H -0.4886 0.6157 0.2471 0.056 Uiso 1 1 calc R
C35 C -0.1913(4) 0.7940(3) 0.25919(15) 0.0445(8) Uani 1 1 d .
H35A H -0.1244 0.8735 0.2706 0.053 Uiso 1 1 calc R
C31 C -0.2751(3) 0.2059(4) 0.29786(16) 0.0499(9) Uani 1 1 d .
H31A H -0.3131 0.1492 0.3249 0.060 Uiso 1 1 calc R
C34 C -0.3345(4) 0.7862(4) 0.27107(16) 0.0507(9) Uani 1 1 d .
H34A H -0.3804 0.8561 0.2913 0.061 Uiso 1 1 calc R
C30 C -0.1307(3) 0.2168(4) 0.28742(16) 0.0501(9) Uani 1 1 d .
H30A H -0.0568 0.1716 0.3052 0.060 Uiso 1 1 calc R
O18 O 0.4903(4) 0.2595(4) 0.47384(18) 0.1137(12) Uani 1 1 d .
O17 O 0.1314(5) -0.4081(5) 0.0128(2) 0.1450(16) Uani 1 1 d .
O14 O 0.1071(2) 0.9149(2) 0.35770(9) 0.0321(4) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O13 Cr2 O14 83.64(8) . .
O13 Cr2 O10 90.23(8) . .
O14 Cr2 O10 173.82(9) . .
O13 Cr2 O9 92.02(8) . .
O14 Cr2 O9 96.39(8) . .
O10 Cr2 O9 82.93(8) . .
O13 Cr2 N4 95.54(9) . .
O14 Cr2 N4 88.07(9) . .
O10 Cr2 N4 93.39(9) . .
O9 Cr2 N4 171.61(9) . .
O13 Cr2 N3 173.70(9) . .
O14 Cr2 N3 93.62(9) . .
O10 Cr2 N3 92.55(9) . .
O9 Cr2 N3 93.92(9) . .
N4 Cr2 N3 78.66(10) . .
O11 Na2 O15 160.25(9) . 1_545
O11 Na2 O16 91.33(8) . 1_545
O15 Na2 O16 70.17(8) 1_545 1_545
O11 Na2 O12 69.94(8) . .
O15 Na2 O12 99.61(9) 1_545 .
O16 Na2 O12 81.63(8) 1_545 .
O11 Na2 O6 91.89(8) . .
O15 Na2 O6 95.96(9) 1_545 .
O16 Na2 O6 93.49(8) 1_545 .
O12 Na2 O6 160.94(8) . .
O11 Na2 N8 114.13(9) . 1_655
O15 Na2 N8 82.36(8) 1_545 1_655
O16 Na2 N8 150.55(9) 1_545 1_655
O12 Na2 N8 93.05(9) . 1_655
O6 Na2 N8 99.88(8) . 1_655
O11 Na2 C27 140.94(9) . 1_545
O15 Na2 C27 21.05(7) 1_545 1_545
O16 Na2 C27 49.64(7) 1_545 1_545
O12 Na2 C27 98.61(8) . 1_545
O6 Na2 C27 91.98(8) . 1_545
N8 Na2 C27 103.41(8) 1_655 1_545
O11 Na2 C25 20.58(7) . .
O15 Na2 C25 144.54(9) 1_545 .
O16 Na2 C25 86.32(8) 1_545 .
O12 Na2 C25 49.44(7) . .
O6 Na2 C25 112.10(8) . .
N8 Na2 C25 112.12(8) 1_655 .
C27 Na2 C25 131.72(8) 1_545 .
O11 Na2 C28 112.49(8) . 1_545
O15 Na2 C28 49.88(7) 1_545 1_545
O16 Na2 C28 21.57(7) 1_545 1_545
O12 Na2 C28 93.10(8) . 1_545
O6 Na2 C28 88.56(8) . 1_545
N8 Na2 C28 132.19(8) 1_655 1_545
C27 Na2 C28 28.87(7) 1_545 1_545
C25 Na2 C28 107.61(8) . 1_545
C25 O9 Cr2 113.83(17) . .
C25 O9 Na1 109.67(16) . .
Cr2 O9 Na1 133.51(9) . .
C27 O13 Cr2 114.01(18) . .
C26 O10 Cr2 113.78(18) . .
C24 N4 C20 118.7(3) . .
C24 N4 Cr2 125.4(2) . .
C20 N4 Cr2 115.69(19) . .
C15 N3 C19 118.6(3) . .
C15 N3 Cr2 125.7(2) . .
C19 N3 Cr2 115.6(2) . .
C25 O11 Na2 116.41(19) . .
C27 O15 Na2 114.66(19) . 1_565
C26 O12 Na2 112.38(19) . .
O16 C28 O14 126.2(3) . .
O16 C28 C27 120.0(3) . .
O14 C28 C27 113.8(2) . .
O16 C28 Na2 48.32(15) . 1_565
O14 C28 Na2 163.5(2) . 1_565
C27 C28 Na2 74.57(16) . 1_565
C28 O16 Na2 110.11(18) . 1_565
O15 C27 O13 125.5(3) . .
O15 C27 C28 120.7(3) . .
O13 C27 C28 113.7(3) . .
O15 C27 Na2 44.28(15) . 1_565
O13 C27 Na2 169.7(2) . 1_565
C28 C27 Na2 76.56(16) . 1_565
O12 C26 O10 126.3(3) . .
O12 C26 C25 119.9(3) . .
O10 C26 C25 113.8(2) . .
O11 C25 O9 125.1(3) . .
O11 C25 C26 120.4(3) . .
O9 C25 C26 114.5(2) . .
O11 C25 Na2 43.02(14) . .
O9 C25 Na2 167.9(2) . .
C26 C25 Na2 77.38(16) . .
N4 C20 C21 120.7(3) . .
N4 C20 C19 114.9(2) . .
C21 C20 C19 124.2(3) . .
N3 C19 C18 121.3(3) . .
N3 C19 C20 114.9(3) . .
C18 C19 C20 123.8(3) . .
N4 C24 C23 122.6(3) . .
C24 C23 C22 118.6(3) . .
C22 C21 C20 119.9(3) . .
C21 C22 C23 119.5(3) . .
N3 C15 C16 122.4(3) . .
C19 C18 C17 119.1(3) . .
C16 C17 C18 119.4(3) . .
C17 C16 C15 119.2(4) . .
O2 Cr1 O1 82.95(8) . .
O2 Cr1 O5 92.24(9) . .
O1 Cr1 O5 174.61(8) . .
O2 Cr1 O6 93.90(9) . .
O1 Cr1 O6 95.00(8) . .
O5 Cr1 O6 82.87(8) . .
O2 Cr1 N1 94.13(9) . .
O1 Cr1 N1 88.29(9) . .
O5 Cr1 N1 94.50(9) . .
O6 Cr1 N1 171.64(9) . .
O2 Cr1 N2 170.62(9) . .
O1 Cr1 N2 90.25(9) . .
O5 Cr1 N2 94.80(9) . .
O6 Cr1 N2 93.13(9) . .
N1 Cr1 N2 79.15(9) . .
C14 O6 Cr1 113.67(18) . .
C14 O6 Na2 121.04(18) . .
Cr1 O6 Na2 125.25(9) . .
C13 O5 Cr1 114.49(19) . .
C12 O2 Cr1 114.59(18) . .
C11 O1 Cr1 115.12(17) . .
C10 N2 C6 117.9(3) . .
C10 N2 Cr1 127.0(2) . .
C6 N2 Cr1 114.94(19) . .
C1 N1 C5 118.7(3) . .
C1 N1 Cr1 125.9(2) . .
C5 N1 Cr1 114.99(19) . .
C11 O3 Na1 109.72(18) . .
C12 O4 Na1 110.83(19) . .
O4 C12 O2 125.5(3) . .
O4 C12 C11 120.6(3) . .
O2 C12 C11 113.9(2) . .
O4 C12 Na1 47.40(15) . .
O2 C12 Na1 165.41(19) . .
C11 C12 Na1 74.78(16) . .
N1 C5 C4 121.4(3) . .
N1 C5 C6 115.0(3) . .
C4 C5 C6 123.6(3) . .
O3 C11 O1 126.6(3) . .
O3 C11 C12 120.4(3) . .
O1 C11 C12 113.1(2) . .
O3 C11 Na1 48.37(15) . .
O1 C11 Na1 159.65(19) . .
C12 C11 Na1 75.88(16) . .
N2 C6 C7 121.6(3) . .
N2 C6 C5 114.5(3) . .
C7 C6 C5 124.0(3) . .
C14 O8 Na1 117.0(2) . 1_545
O8 C14 O6 125.9(3) . .
O8 C14 C13 119.5(3) . .
O6 C14 C13 114.6(3) . .
O8 C14 Na1 42.59(16) . 1_545
O6 C14 Na1 165.8(2) . 1_545
C13 C14 Na1 77.44(16) . 1_545
O7 C13 O5 126.2(3) . .
O7 C13 C14 119.9(3) . .
O5 C13 C14 113.9(3) . .
C13 O7 Na1 111.4(2) . 1_545
N2 C10 C9 122.8(3) . .
N1 C1 C2 123.1(3) . .
C8 C9 C10 119.2(3) . .
C2 C3 C4 119.7(3) . .
C3 C2 C1 118.4(3) . .
C6 C7 C8 119.3(3) . .
C9 C8 C7 119.2(3) . .
C5 C4 C3 118.7(3) . .
O8 Na1 O4 153.99(9) 1_565 .
O8 Na1 O3 99.90(9) 1_565 .
O4 Na1 O3 70.25(8) . .
O8 Na1 O7 68.95(8) 1_565 1_565
O4 Na1 O7 85.76(8) . 1_565
O3 Na1 O7 83.53(8) . 1_565
O8 Na1 N5 101.42(9) 1_565 .
O4 Na1 N5 89.31(8) . .
O3 Na1 N5 158.54(9) . .
O7 Na1 N5 101.94(9) 1_565 .
O8 Na1 O9 90.44(8) 1_565 .
O4 Na1 O9 114.05(8) . .
O3 Na1 O9 95.88(8) . .
O7 Na1 O9 158.83(8) 1_565 .
N5 Na1 O9 86.36(8) . .
O8 Na1 C11 121.81(9) 1_565 .
O4 Na1 C11 50.67(8) . .
O3 Na1 C11 21.91(7) . .
O7 Na1 C11 91.98(8) 1_565 .
N5 Na1 C11 136.69(9) . .
O9 Na1 C11 95.17(8) . .
O8 Na1 C12 147.19(9) 1_565 .
O4 Na1 C12 21.77(7) . .
O3 Na1 C12 50.17(7) . .
O7 Na1 C12 91.66(8) 1_565 .
N5 Na1 C12 108.57(8) . .
O9 Na1 C12 104.24(8) . .
C11 Na1 C12 29.34(8) . .
O8 Na1 C14 20.41(8) 1_565 1_565
O4 Na1 C14 133.58(9) . 1_565
O3 Na1 C14 91.26(8) . 1_565
O7 Na1 C14 49.16(8) 1_565 1_565
N5 Na1 C14 108.10(8) . 1_565
O9 Na1 C14 109.82(8) . 1_565
C11 Na1 C14 111.87(8) . 1_565
C12 Na1 C14 130.73(8) . 1_565
C35 N5 N6 103.9(2) . .
C35 N5 Na1 115.9(2) . .
N6 N5 Na1 140.02(19) . .
C33 N6 N5 111.9(3) . .
C33 N6 C32 127.8(3) . .
N5 N6 C32 120.3(2) . .
C29 N7 N8 111.6(2) . .
C29 N7 C32 127.6(3) . .
N8 N7 C32 120.8(2) . .
C31 N8 N7 103.3(2) . .
C31 N8 Na2 110.2(2) . 1_455
N7 N8 Na2 146.25(19) . 1_455
C30 C29 N7 107.6(3) . .
N7 C32 N6 113.3(2) . .
N6 C33 C34 107.3(3) . .
N5 C35 C34 111.9(3) . .
N8 C31 C30 113.1(3) . .
C33 C34 C35 105.0(3) . .
C29 C30 C31 104.5(3) . .
C28 O14 Cr2 113.28(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cr2 O13 1.9436(19) .
Cr2 O14 1.9512(19) .
Cr2 O10 1.9657(19) .
Cr2 O9 1.9703(19) .
Cr2 N4 2.056(2) .
Cr2 N3 2.063(2) .
Na2 O11 2.362(2) .
Na2 O15 2.366(2) 1_545
Na2 O16 2.472(2) 1_545
Na2 O12 2.478(2) .
Na2 O6 2.504(2) .
Na2 N8 2.642(3) 1_655
Na2 C27 3.080(3) 1_545
Na2 C25 3.102(3) .
Na2 C28 3.108(3) 1_545
O9 C25 1.284(3) .
O9 Na1 2.595(2) .
O13 C27 1.287(3) .
O10 C26 1.290(3) .
N4 C24 1.340(4) .
N4 C20 1.360(4) .
N3 C15 1.336(4) .
N3 C19 1.352(4) .
O11 C25 1.217(3) .
O15 C27 1.218(3) .
O15 Na2 2.366(2) 1_565
O12 C26 1.218(3) .
C28 O16 1.217(3) .
C28 O14 1.290(3) .
C28 C27 1.543(4) .
C28 Na2 3.108(3) 1_565
O16 Na2 2.472(2) 1_565
C27 Na2 3.080(3) 1_565
C26 C25 1.550(4) .
C20 C21 1.373(4) .
C20 C19 1.469(4) .
C19 C18 1.381(4) .
C24 C23 1.372(4) .
C23 C22 1.373(5) .
C21 C22 1.372(5) .
C15 C16 1.376(5) .
C18 C17 1.381(5) .
C17 C16 1.361(5) .
Cr1 O2 1.950(2) .
Cr1 O1 1.953(2) .
Cr1 O5 1.961(2) .
Cr1 O6 1.969(2) .
Cr1 N1 2.051(2) .
Cr1 N2 2.056(2) .
O6 C14 1.289(3) .
O5 C13 1.281(3) .
O2 C12 1.294(3) .
O1 C11 1.292(3) .
N2 C10 1.339(4) .
N2 C6 1.360(4) .
N1 C1 1.331(4) .
N1 C5 1.351(4) .
O3 C11 1.210(3) .
O3 Na1 2.424(2) .
O4 C12 1.217(3) .
O4 Na1 2.416(2) .
C12 C11 1.550(4) .
C12 Na1 3.068(3) .
C5 C4 1.374(4) .
C5 C6 1.481(4) .
C11 Na1 3.053(3) .
C6 C7 1.372(4) .
O8 C14 1.216(4) .
O8 Na1 2.360(3) 1_545
C14 C13 1.542(4) .
C14 Na1 3.107(3) 1_545
C13 O7 1.220(3) .
O7 Na1 2.498(3) 1_545
C10 C9 1.367(4) .
C1 C2 1.368(4) .
C9 C8 1.364(5) .
C3 C2 1.368(5) .
C3 C4 1.388(5) .
C7 C8 1.380(5) .
Na1 O8 2.360(3) 1_565
Na1 O7 2.498(3) 1_565
Na1 N5 2.505(3) .
Na1 C14 3.107(3) 1_565
N5 C35 1.329(4) .
N5 N6 1.355(3) .
N6 C33 1.341(4) .
N6 C32 1.442(4) .
N7 C29 1.352(4) .
N7 N8 1.359(3) .
N7 C32 1.438(4) .
N8 C31 1.318(4) .
N8 Na2 2.642(3) 1_455
C29 C30 1.344(4) .
C33 C34 1.358(5) .
C35 C34 1.386(4) .
C31 C30 1.387(4) .
