#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:07:49 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180223 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/09/7110982.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7110982
loop_
_publ_author_name
'Antolini, Floria'
'Hitchcock, Peter B.'
'Lappert, Michael F.'
'Merle, Philippe'
_publ_section_title
;
 Unusual alkali metal α- or β-phenyl(trimethylsilyl)amides
;
_journal_issue                   14
_journal_name_full               'Chemical Communications'
_journal_page_first              1301
_journal_paper_doi               10.1039/b003169k
_journal_year                    2000
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C9 H14 Li1 N1 Si1'
_chemical_formula_structural     'C9 H14 N LI SI'
_chemical_formula_sum            'C36 H56 Li4 N4 Si4'
_chemical_formula_weight         684.97
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core2.1beta.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1beta3
_audit_creation_date             1999-05-09T13:50:08-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                99.82(3)
_cell_angle_beta                 91.76(3)
_cell_angle_gamma                113.16(3)
_cell_formula_units_Z            2
_cell_length_a                   10.103(4)
_cell_length_b                   10.873(5)
_cell_length_c                   20.223(7)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      10
_cell_measurement_theta_min      7.6
_cell_measurement_wavelength     0.71073
_cell_volume                     2000.8(15)
_computing_cell_refinement       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_collection       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_reduction        'XCAD4 (Harms & Wocadlo, 1995)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1998)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector                 'scintillation LiI'
_diffrn_detector_dtime           1.195
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Enraf Nonius TurboCAD4'
_diffrn_measurement_method       'non-profiled omega/2theta scans'
_diffrn_orient_matrix_type
;
  x-axis points to radiation source
  the matrix is specified in reciprocal space
;
_diffrn_orient_matrix_UB_11      0.37083E-1
_diffrn_orient_matrix_UB_12      -0.45033E-1
_diffrn_orient_matrix_UB_13      -0.37876E-1
_diffrn_orient_matrix_UB_21      -0.36436E-1
_diffrn_orient_matrix_UB_22      0.42772E-1
_diffrn_orient_matrix_UB_23      -0.32282E-1
_diffrn_orient_matrix_UB_31      0.95027E-1
_diffrn_orient_matrix_UB_32      0.81098E-1
_diffrn_orient_matrix_UB_33      0.8641E-2
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0
_diffrn_reflns_av_sigmaI/netI    0.1182
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            7003
_diffrn_reflns_theta_full        24.97
_diffrn_reflns_theta_max         24.97
_diffrn_reflns_theta_min         2.06
_diffrn_source                   'Enraf Nonius FR590'
_diffrn_standards_decay_%        3
_diffrn_standards_interval_time  60
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    0.178
_exptl_absorpt_correction_T_max  0.9653
_exptl_absorpt_correction_T_min  0.9487
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.137
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.404
_refine_diff_density_min         -0.387
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         7003
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.1398
_refine_ls_R_factor_gt           0.0729
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1604
_refine_ls_wR_factor_ref         0.1944
_reflns_number_gt                4136
_reflns_number_total             7003
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b003169ksup1.cif
_cod_data_source_block           B003169K-4
_cod_original_cell_volume        2000.7(14)
_cod_database_code               7110982
#BEGIN Tags that were not found in dictionaries:
_diffrn_standards_decay_corr_max 1.244
_diffrn_standards_decay_corr_min 0.972
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Li1 Li 0.5513(9) 0.2813(8) 0.3182(4) 0.0288(19) Uani 1 1 d . . .
Li2 Li 0.5611(9) 0.2604(8) 0.1886(4) 0.0266(18) Uani 1 1 d . . .
Li3 Li 0.3578(10) 0.4188(9) 0.3866(5) 0.036(2) Uani 1 1 d . . .
Li4 Li 0.3488(10) -0.0128(9) 0.0967(4) 0.035(2) Uani 1 1 d . . .
M1 C 0.3677 0.5054 0.2958 0 Uiso 0 1 d P A 1
M2 C 0.3263 -0.1044 0.1851 0 Uiso 0 1 d P B 1
Si1 Si 0.76745(15) 0.55403(14) 0.25169(7) 0.0247(3) Uani 1 1 d . A 2
Si2 Si 0.72885(14) 0.11455(13) 0.27829(6) 0.0209(3) Uani 1 1 d . B 2
Si3 Si 0.29957(15) 0.13192(14) 0.41577(7) 0.0239(3) Uani 1 1 d . A 2
Si4 Si 0.32716(15) 0.24146(14) 0.06059(7) 0.0250(3) Uani 1 1 d . B 2
N1 N 0.5987(4) 0.4336(4) 0.25958(19) 0.0230(9) Uani 1 1 d . A 2
N2 N 0.5711(4) 0.1264(4) 0.25035(18) 0.0205(9) Uani 1 1 d . B 2
N3 N 0.4344(4) 0.2829(4) 0.40603(18) 0.0218(9) Uani 1 1 d . A 2
N4 N 0.4489(4) 0.1795(4) 0.08660(18) 0.0228(9) Uani 1 1 d . B 2
C1 C 0.4892(5) 0.4719(5) 0.2783(2) 0.0212(10) Uani 1 1 d . A 2
C2 C 0.5065(5) 0.5973(5) 0.3191(2) 0.0261(11) Uani 1 1 d . A 2
H2 H 0.6016 0.6618 0.3363 0.031 Uiso 1 1 calc R A 2
C3 C 0.3907(6) 0.6300(5) 0.3348(3) 0.0339(13) Uani 1 1 d . A 2
H3 H 0.408 0.7167 0.3616 0.041 Uiso 1 1 calc R A 2
C4 C 0.2507(6) 0.5389(6) 0.3124(3) 0.0393(14) Uani 1 1 d . A 2
H4 H 0.1715 0.5617 0.3236 0.047 Uiso 1 1 calc R A 2
C5 C 0.2273(6) 0.4134(6) 0.2731(3) 0.0323(12) Uani 1 1 d . A 2
H5 H 0.1313 0.3498 0.2569 0.039 Uiso 1 1 calc R A 2
C6 C 0.3420(5) 0.3803(5) 0.2575(2) 0.0256(11) Uani 1 1 d . A 2
H6 H 0.3224 0.2923 0.2316 0.031 Uiso 1 1 calc R A 2
C7 C 0.8679(6) 0.4629(6) 0.2035(3) 0.0360(13) Uani 1 1 d . A 2
H7A H 0.8776 0.3962 0.2282 0.054 Uiso 1 1 calc R A 2
H7B H 0.9643 0.529 0.198 0.054 Uiso 1 1 calc R A 2
H7C H 0.8145 0.4155 0.159 0.054 Uiso 1 1 calc R A 2
C8 C 0.8860(6) 0.6564(5) 0.3326(3) 0.0370(13) Uani 1 1 d . A 2
H8A H 0.8372 0.7063 0.3596 0.055 Uiso 1 1 calc R A 2
H8B H 0.9783 0.7213 0.322 0.055 Uiso 1 1 calc R A 2
H8C H 0.904 0.5947 0.3582 0.055 Uiso 1 1 calc R A 2
C9 C 0.7530(6) 0.6795(5) 0.2021(3) 0.0399(14) Uani 1 1 d . A 2
H9A H 0.7003 0.7291 0.226 0.06 Uiso 1 1 calc R A 2
H9B H 0.7008 0.6308 0.1575 0.06 Uiso 1 1 calc R A 2
H9C H 0.8502 0.7442 0.1968 0.06 Uiso 1 1 calc R A 2
C10 C 0.4539(5) 0.0114(5) 0.2179(2) 0.0214(10) Uani 1 1 d . B 2
C11 C 0.4609(6) -0.1075(5) 0.1809(3) 0.0306(12) Uani 1 1 d . B 2
H11 H 0.5528 -0.1112 0.177 0.037 Uiso 1 1 calc R B 2
C12 C 0.3379(6) -0.2191(5) 0.1500(3) 0.0412(14) Uani 1 1 d . B 2
H12 H 0.3469 -0.2976 0.1255 0.049 Uiso 1 1 calc R B 2
C13 C 0.2020(6) -0.2178(6) 0.1543(3) 0.0470(16) Uani 1 1 d . B 2
H13 H 0.1178 -0.2955 0.1339 0.056 Uiso 1 1 calc R B 2
C14 C 0.1906(6) -0.1017(6) 0.1888(3) 0.0366(13) Uani 1 1 d . B 2
H14 H 0.0982 -0.0986 0.1915 0.044 Uiso 1 1 calc R B 2
C15 C 0.3125(5) 0.0086(5) 0.2188(2) 0.0273(11) Uani 1 1 d . B 2
H15 H 0.3019 0.0877 0.2415 0.033 Uiso 1 1 calc R B 2
C16 C 0.6896(6) -0.0266(5) 0.3258(3) 0.0326(12) Uani 1 1 d . B 2
H16A H 0.6313 -0.114 0.2957 0.049 Uiso 1 1 calc R B 2
H16B H 0.636 -0.0121 0.3638 0.049 Uiso 1 1 calc R B 2
H16C H 0.7808 -0.0279 0.3428 0.049 Uiso 1 1 calc R B 2
C17 C 0.8475(5) 0.0905(5) 0.2115(2) 0.0306(12) Uani 1 1 d . B 2
H17A H 0.8707 0.1637 0.1857 0.046 Uiso 1 1 calc R B 2
H17B H 0.7962 0.0021 0.181 0.046 Uiso 1 1 calc R B 2
H17C H 0.9372 0.0934 0.233 0.046 Uiso 1 1 calc R B 2
C18 C 0.8395(5) 0.2774(5) 0.3395(2) 0.0311(12) Uani 1 1 d . B 2
H18A H 0.8633 0.3546 0.3165 0.047 Uiso 1 1 calc R B 2
H18B H 0.9291 0.2733 0.3568 0.047 Uiso 1 1 calc R B 2
H18C H 0.7839 0.2891 0.3771 0.047 Uiso 1 1 calc R B 2
C19 C 0.5640(5) 0.3393(5) 0.4489(2) 0.0236(11) Uani 1 1 d . A 2
C20 C 0.6509(5) 0.4801(5) 0.4620(3) 0.0308(12) Uani 1 1 d . A 2
H20 H 0.6171 0.5381 0.4432 0.037 Uiso 1 1 calc R A 2
C21 C 0.7838(6) 0.5384(6) 0.5013(3) 0.0372(13) Uani 1 1 d . . 2
H21 H 0.8385 0.6342 0.5086 0.045 Uiso 1 1 calc R . 2
C22 C 0.8368(6) 0.4578(6) 0.5298(3) 0.0416(15) Uani 1 1 d . A 2
H22 H 0.9276 0.4971 0.5566 0.05 Uiso 1 1 calc R A 2
C23 C 0.7553(6) 0.3201(6) 0.5184(3) 0.0428(15) Uani 1 1 d . A 2
H23 H 0.7908 0.2636 0.5375 0.051 Uiso 1 1 calc R A 2
C24 C 0.6224(6) 0.2614(6) 0.4797(3) 0.0333(13) Uani 1 1 d . A 2
H24 H 0.5685 0.1656 0.4737 0.04 Uiso 1 1 calc R A 2
C25 C 0.1304(5) 0.1140(5) 0.3668(3) 0.0337(12) Uani 1 1 d . A 2
H25A H 0.1112 0.1955 0.3816 0.05 Uiso 1 1 calc R A 2
H25B H 0.0488 0.0333 0.3746 0.05 Uiso 1 1 calc R A 2
H25C H 0.1427 0.1037 0.3186 0.05 Uiso 1 1 calc R A 2
C26 C 0.3301(6) -0.0269(5) 0.3855(3) 0.0335(12) Uani 1 1 d . A 2
H26A H 0.4181 -0.0207 0.4103 0.05 Uiso 1 1 calc R A 2
H26B H 0.3409 -0.0366 0.3372 0.05 Uiso 1 1 calc R A 2
H26C H 0.2471 -0.1065 0.3933 0.05 Uiso 1 1 calc R A 2
C27 C 0.2607(6) 0.1298(6) 0.5059(3) 0.0390(14) Uani 1 1 d . A 2
H27A H 0.3469 0.1384 0.5332 0.059 Uiso 1 1 calc R A 2
H27B H 0.1801 0.0437 0.5083 0.059 Uiso 1 1 calc R A 2
H27C H 0.2347 0.2062 0.5233 0.059 Uiso 1 1 calc R A 2
C28 C 0.5817(5) 0.2140(5) 0.0601(2) 0.0252(11) Uani 1 1 d . B 2
C29 C 0.6567(6) 0.3363(6) 0.0373(3) 0.0370(13) Uani 1 1 d . B 2
H29 H 0.6117 0.3981 0.0365 0.044 Uiso 1 1 calc R B 2
C30 C 0.7929(6) 0.3698(7) 0.0161(3) 0.0485(16) Uani 1 1 d . B 2
H30 H 0.8405 0.4543 0.0023 0.058 Uiso 1 1 calc R B 2
C31 C 0.8608(6) 0.2806(7) 0.0149(3) 0.0467(16) Uani 1 1 d . B 2
H31 H 0.954 0.3029 -0.0001 0.056 Uiso 1 1 calc R B 2
C32 C 0.7915(5) 0.1600(6) 0.0358(3) 0.0374(14) Uani 1 1 d . . 2
H32 H 0.8377 0.099 0.0358 0.045 Uiso 1 1 calc R . 2
C33 C 0.6545(5) 0.1260(5) 0.0570(2) 0.0276(11) Uani 1 1 d . B 2
H33 H 0.6079 0.0404 0.0698 0.033 Uiso 1 1 calc R B 2
C34 C 0.1499(5) 0.1400(6) 0.0900(3) 0.0361(13) Uani 1 1 d . B 2
H34A H 0.1617 0.1508 0.1393 0.054 Uiso 1 1 calc R B 2
H34B H 0.1182 0.0434 0.0692 0.054 Uiso 1 1 calc R B 2
H34C H 0.0772 0.1727 0.0771 0.054 Uiso 1 1 calc R B 2
C35 C 0.3698(6) 0.4269(5) 0.0937(3) 0.0358(13) Uani 1 1 d . B 2
H35A H 0.3853 0.446 0.1432 0.054 Uiso 1 1 calc R B 2
H35B H 0.2887 0.4477 0.0794 0.054 Uiso 1 1 calc R B 2
H35C H 0.4575 0.4835 0.0759 0.054 Uiso 1 1 calc R B 2
C36 C 0.2983(6) 0.2173(6) -0.0338(3) 0.0368(13) Uani 1 1 d . B 2
H36A H 0.3894 0.2694 -0.0507 0.055 Uiso 1 1 calc R B 2
H36B H 0.2246 0.2496 -0.046 0.055 Uiso 1 1 calc R B 2
H36C H 0.2657 0.1202 -0.054 0.055 Uiso 1 1 calc R B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
0 3 -5
-1 4 -2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N2 Li1 N1 100.6(4) .
N2 Li1 N3 132.8(4) .
N1 Li1 N3 122.3(4) .
N1 Li2 N2 101.1(4) .
N1 Li2 N4 134.1(4) .
N2 Li2 N4 120.0(4) .
N3 Li3 M1 128.8(5) .
N3 Li3 C6 101.9(4) .
M1 Li3 C6 32.24(17) .
N3 Li3 C2 118.0(4) .
M1 Li3 C2 32.22(17) .
C6 Li3 C2 55.2(2) .
N3 Li3 C5 126.5(5) .
M1 Li3 C5 32.25(17) .
C6 Li3 C5 30.90(18) .
C2 Li3 C5 64.5(3) .
N3 Li3 C3 148.9(5) .
M1 Li3 C3 32.02(17) .
C6 Li3 C3 64.3(3) .
C2 Li3 C3 31.03(18) .
C5 Li3 C3 54.6(2) .
N3 Li3 C4 156.6(5) .
M1 Li3 C4 32.48(17) .
C6 Li3 C4 55.1(2) .
C2 Li3 C4 55.2(2) .
C5 Li3 C4 30.83(19) .
C3 Li3 C4 30.69(19) .
N3 Li3 C1 97.0(4) .
M1 Li3 C1 33.49(16) .
C6 Li3 C1 31.89(18) .
C2 Li3 C1 31.45(18) .
C5 Li3 C1 56.3(2) .
C3 Li3 C1 56.0(2) .
C4 Li3 C1 66.0(3) .
N4 Li4 M2 131.1(5) .
N4 Li4 C15 103.2(4) .
M2 Li4 C15 33.01(17) .
N4 Li4 C14 127.5(4) .
M2 Li4 C14 32.85(17) .
C15 Li4 C14 31.40(19) .
N4 Li4 C10 98.9(4) .
M2 Li4 C10 34.09(16) .
C15 Li4 C10 32.48(18) .
C14 Li4 C10 57.2(2) .
N4 Li4 C11 120.1(4) .
M2 Li4 C11 32.38(17) .
C15 Li4 C11 56.0(2) .
C14 Li4 C11 65.2(3) .
C10 Li4 C11 31.77(18) .
N4 Li4 C12 151.0(5) .
M2 Li4 C12 31.70(17) .
C15 Li4 C12 64.7(3) .
C14 Li4 C12 54.9(3) .
C10 Li4 C12 56.2(2) .
C11 Li4 C12 30.91(19) .
N4 Li4 C13 157.9(5) .
M2 Li4 C13 32.10(18) .
C15 Li4 C13 55.3(3) .
C14 Li4 C13 30.9(2) .
C10 Li4 C13 66.2(3) .
C11 Li4 C13 55.1(2) .
C12 Li4 C13 30.6(2) .
N1 Si1 C7 107.6(2) .
N1 Si1 C9 111.2(2) .
C7 Si1 C9 107.3(3) .
N1 Si1 C8 116.6(2) .
C7 Si1 C8 106.7(3) .
C9 Si1 C8 106.8(3) .
N1 Si1 Li2 39.8(2) .
C7 Si1 Li2 69.7(2) .
C9 Si1 Li2 112.1(2) .
C8 Si1 Li2 140.2(2) .
N2 Si2 C16 111.4(2) .
N2 Si2 C18 107.5(2) .
C16 Si2 C18 106.7(2) .
N2 Si2 C17 116.2(2) .
C16 Si2 C17 107.4(2) .
C18 Si2 C17 107.3(2) .
N2 Si2 Li1 40.4(2) .
C16 Si2 Li1 111.8(2) .
C18 Si2 Li1 68.8(2) .
C17 Si2 Li1 140.0(2) .
N3 Si3 C25 107.0(2) .
N3 Si3 C26 116.3(2) .
C25 Si3 C26 107.5(2) .
N3 Si3 C27 112.9(2) .
C25 Si3 C27 107.1(2) .
C26 Si3 C27 105.6(2) .
N3 Si3 Li3 36.6(2) .
C25 Si3 Li3 74.0(2) .
C26 Si3 Li3 143.1(2) .
C27 Si3 Li3 109.0(3) .
N3 Si3 Li1 34.87(19) .
C25 Si3 Li1 101.5(2) .
C26 Si3 Li1 86.6(2) .
C27 Si3 Li1 143.4(2) .
Li3 Si3 Li1 57.8(2) .
N4 Si4 C34 106.4(2) .
N4 Si4 C36 112.8(2) .
C34 Si4 C36 107.6(3) .
N4 Si4 C35 117.0(2) .
C34 Si4 C35 107.1(3) .
C36 Si4 C35 105.5(2) .
N4 Si4 Li4 37.1(2) .
C34 Si4 Li4 72.8(2) .
C36 Si4 Li4 109.0(2) .
C35 Si4 Li4 143.7(2) .
C1 N1 Si1 120.8(3) .
C1 N1 Li2 121.9(4) .
Si1 N1 Li2 107.8(3) .
C1 N1 Li1 95.6(4) .
Si1 N1 Li1 127.0(3) .
Li2 N1 Li1 77.2(3) .
C10 N2 Si2 120.5(3) .
C10 N2 Li1 123.2(4) .
Si2 N2 Li1 106.6(3) .
C10 N2 Li2 98.0(3) .
Si2 N2 Li2 124.7(3) .
Li1 N2 Li2 77.3(3) .
C19 N3 Si3 119.8(3) .
C19 N3 Li3 114.5(4) .
Si3 N3 Li3 112.7(3) .
C19 N3 Li1 91.0(3) .
Si3 N3 Li1 118.1(3) .
Li3 N3 Li1 96.8(4) .
C28 N4 Si4 119.7(3) .
C28 N4 Li4 116.4(4) .
Si4 N4 Li4 111.2(3) .
C28 N4 Li2 90.1(3) .
Si4 N4 Li2 118.9(3) .
Li4 N4 Li2 96.9(4) .
N1 C1 C2 125.8(4) .
N1 C1 C6 120.0(4) .
C2 C1 C6 114.1(4) .
N1 C1 Li3 123.7(3) .
C2 C1 Li3 72.2(3) .
C6 C1 Li3 71.6(3) .
N1 C1 Li1 53.1(3) .
C2 C1 Li1 125.7(4) .
C6 C1 Li1 92.2(3) .
Li3 C1 Li1 72.9(3) .
C3 C2 C1 122.6(5) .
C3 C2 Li3 75.2(4) .
C1 C2 Li3 76.3(3) .
C4 C3 C2 120.9(5) .
C4 C3 Li3 75.3(4) .
C2 C3 Li3 73.7(4) .
C3 C4 C5 118.9(5) .
C3 C4 Li3 74.0(4) .
C5 C4 Li3 73.9(4) .
C6 C5 C4 120.4(5) .
C6 C5 Li3 73.4(3) .
C4 C5 Li3 75.3(4) .
C5 C6 C1 123.0(5) .
C5 C6 Li3 75.7(3) .
C1 C6 Li3 76.5(3) .
N2 C10 C11 125.5(4) .
N2 C10 C15 119.8(4) .
C11 C10 C15 114.7(4) .
N2 C10 Li4 122.2(3) .
C11 C10 Li4 74.3(3) .
C15 C10 Li4 70.7(3) .
N2 C10 Li2 51.2(3) .
C11 C10 Li2 127.0(4) .
C15 C10 Li2 92.2(3) .
Li4 C10 Li2 73.1(3) .
C12 C11 C10 121.9(5) .
C12 C11 Li4 76.1(4) .
C10 C11 Li4 73.9(3) .
C11 C12 C13 120.9(5) .
C11 C12 Li4 73.0(4) .
C13 C12 Li4 75.3(4) .
C14 C13 C12 119.0(5) .
C14 C13 Li4 71.6(4) .
C12 C13 Li4 74.1(4) .
C15 C14 C13 119.8(5) .
C15 C14 Li4 71.7(4) .
C13 C14 Li4 77.5(4) .
C14 C15 C10 123.6(5) .
C14 C15 Li4 76.9(4) .
C10 C15 Li4 76.8(3) .
Si2 C18 Li1 74.7(2) .
N3 C19 C20 121.6(4) .
N3 C19 C24 124.0(4) .
C20 C19 C24 114.4(5) .
N3 C19 Li1 56.4(3) .
C20 C19 Li1 101.0(4) .
C24 C19 Li1 111.5(4) .
N3 C19 Li3 39.3(3) .
C20 C19 Li3 83.5(3) .
C24 C19 Li3 160.8(4) .
Li1 C19 Li3 69.2(3) .
C21 C20 C19 123.1(5) .
C22 C21 C20 120.4(5) .
C22 C21 Li3 92.6(4) 2_666
C20 C21 Li3 88.8(4) 2_666
C23 C22 C21 118.4(5) .
C22 C23 C24 121.6(5) .
C23 C24 C19 122.2(5) .
N4 C28 C29 125.1(4) .
N4 C28 C33 120.1(4) .
C29 C28 C33 114.7(5) .
N4 C28 Li2 57.4(3) .
C29 C28 Li2 111.4(4) .
C33 C28 Li2 100.3(3) .
N4 C28 Li4 38.0(3) .
C29 C28 Li4 160.9(4) .
C33 C28 Li4 83.2(3) .
Li2 C28 Li4 69.2(3) .
C30 C29 C28 122.6(5) .
C29 C30 C31 120.4(6) .
C32 C31 C30 119.1(5) .
C31 C32 C33 120.7(5) .
C31 C32 Li4 93.9(4) 2_655
C33 C32 Li4 87.4(4) 2_655
C32 C33 C28 122.4(5) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Li1 N2 2.062(9) .
Li1 N1 2.112(9) .
Li1 N3 2.164(9) .
Li2 N1 2.057(9) .
Li2 N2 2.103(8) .
Li2 N4 2.183(9) .
Li3 N3 2.004(9) .
Li3 M1 2.189(9) .
Li3 C6 2.563(10) .
Li3 C2 2.573(10) .
Li3 C5 2.591(10) .
Li3 C3 2.592(10) .
Li3 C4 2.609(10) .
Li3 C1 2.626(10) .
Li4 N4 1.983(10) .
Li4 M2 2.164(8) .
Li4 C15 2.492(10) .
Li4 C14 2.556(10) .
Li4 C10 2.569(9) .
Li4 C11 2.575(9) .
Li4 C12 2.615(10) .
Li4 C13 2.629(11) .
Si1 N1 1.726(4) .
Si1 C7 1.867(5) .
Si1 C9 1.871(5) .
Si1 C8 1.887(5) .
Si2 N2 1.734(4) .
Si2 C16 1.866(5) .
Si2 C18 1.878(5) .
Si2 C17 1.886(5) .
Si3 N3 1.720(4) .
Si3 C25 1.873(5) .
Si3 C26 1.877(5) .
Si3 C27 1.879(5) .
Si4 N4 1.725(4) .
Si4 C34 1.875(5) .
Si4 C36 1.880(5) .
Si4 C35 1.881(5) .
N1 C1 1.369(6) .
N2 C10 1.379(6) .
N3 C19 1.400(6) .
N4 C28 1.395(6) .
C1 C2 1.410(6) .
C1 C6 1.427(6) .
C2 C3 1.382(7) .
C3 C4 1.376(7) .
C4 C5 1.382(7) .
C5 C6 1.373(7) .
C10 C11 1.408(7) .
C10 C15 1.418(7) .
C11 C12 1.384(7) .
C12 C13 1.384(8) .
C13 C14 1.383(8) .
C14 C15 1.367(7) .
C19 C20 1.405(7) .
C19 C24 1.416(7) .
C20 C21 1.388(7) .
C21 C22 1.381(8) .
C21 Li3 2.787(10) 2_666
C22 C23 1.369(8) .
C23 C24 1.382(7) .
C28 C29 1.411(7) .
C28 C33 1.413(7) .
C29 C30 1.380(8) .
C30 C31 1.388(8) .
C31 C32 1.367(8) .
C32 C33 1.387(7) .
C32 Li4 2.876(10) 2_655
