#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/12/7111254.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7111254
loop_
_publ_author_name
'Wan, Shuang-Yi'
'Fan, Jian'
'Okamura, Taka-aki'
'Zhu, Hui-Fang'
'Ouyang, Xing-Mei'
'Sun, Wei-Yin'
'Ueyama, Norikazu'
_publ_section_title
;
 2D 4.82 Network with threefold parallel interpenetration from
 nanometer-sized tripodal ligand and lead(ii) nitrateElectronic
 supplementary information available: Fig. 1S. See
 http://www.rsc.org/suppdata/cc/b2/b207568g/
;
_journal_issue                   21
_journal_name_full               'Chemical Communications'
_journal_page_first              2520
_journal_paper_doi               10.1039/b207568g
_journal_year                    2002
_chemical_formula_moiety         'C34.67 H31.50 N11 O6.58 Pb '
_chemical_formula_sum            'C34.67 H31.5 N11 O6.58 Pb'
_chemical_formula_weight         914.73
_chemical_name_systematic
; 
[Pb(timpt)(NO3)](NO3)-0.417(Et2O)-0.167(H2O) 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             'Sat Sep  7 18:45:43 2002'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.0144(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   33.6859(7)
_cell_length_b                   7.7447(2)
_cell_length_c                   30.8578(10)
_cell_measurement_reflns_used    21554
_cell_measurement_temperature    200
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      1.3
_cell_volume                     7234.8(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare, 1994)'
_diffrn_ambient_temperature      200
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.1331
_diffrn_reflns_av_sigmaI/netI    0.1731
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            28746
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.39
_exptl_absorpt_coefficient_mu    4.727
_exptl_absorpt_correction_T_max  0.910
_exptl_absorpt_correction_T_min  0.637
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.680
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3609
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.020
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.018
_refine_diff_density_min         -1.067
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.887
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     488
_refine_ls_number_reflns         8120
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      0.889
_refine_ls_R_factor_all          0.1504
_refine_ls_R_factor_gt           0.0558
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0351P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0871
_refine_ls_wR_factor_ref         0.1027
_reflns_number_gt                3918
_reflns_number_total             8120
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b207568gsup1.cif
_cod_data_source_block           shelxl
_cod_original_formula_sum        'C34.67 H31.50 N11 O6.58 Pb'
_cod_database_code               7111254
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pb1 Pb 0.073835(9) -0.21845(4) 0.162811(12) 0.04933(12) Uani 1 1 d .
O6 O 0.0000 -0.042(2) 0.2500 0.232(13) Uani 0.833(11) 2 d SPD
O7 O 0.1000(14) -0.087(6) 0.3400(16) 0.115(19) Uiso 0.167(11) 1 d P
O41 O 0.05176(18) -0.4860(7) 0.1097(2) 0.0651(17) Uani 1 1 d .
O42 O -0.00648(19) -0.4107(9) 0.1159(2) 0.085(2) Uani 1 1 d .
O43 O -0.0062(2) -0.6469(10) 0.0793(3) 0.102(3) Uani 1 1 d .
O51 O 0.1662(2) -0.8361(8) 0.2614(2) 0.0763(19) Uani 1 1 d .
O52 O 0.12288(18) -1.0547(8) 0.2491(2) 0.0698(17) Uani 1 1 d .
O53 O 0.12538(19) -0.9257(7) 0.1897(2) 0.0659(17) Uani 1 1 d .
N1 N 0.21354(18) 0.3903(7) -0.0490(2) 0.0358(15) Uani 1 1 d .
N2 N 0.28447(17) 0.5162(7) -0.0207(2) 0.0371(15) Uani 1 1 d .
N3 N 0.24514(18) 0.5276(7) 0.0276(2) 0.0349(14) Uani 1 1 d .
N4 N 0.0129(3) -0.5161(12) 0.1009(3) 0.066(2) Uani 1 1 d .
N5 N 0.1393(3) -0.9395(10) 0.2346(3) 0.058(2) Uani 1 1 d .
N11 N 0.05785(17) 0.1069(8) 0.0318(2) 0.0399(15) Uani 1 1 d .
N12 N 0.07165(19) -0.0951(9) 0.0847(2) 0.0484(17) Uani 1 1 d .
N21 N 0.20287(18) -0.4954(8) 0.1969(2) 0.0425(15) Uani 1 1 d .
N22 N 0.14303(18) -0.3321(7) 0.1736(2) 0.0438(16) Uani 1 1 d .
N31 N 0.0744(2) -0.5413(11) 0.2900(3) 0.064(2) Uani 1 1 d .
N32 N 0.0821(2) -0.4600(10) 0.2247(3) 0.062(2) Uani 1 1 d .
C1 C 0.2126(2) 0.4414(9) -0.0083(3) 0.0365(18) Uani 1 1 d .
C2 C 0.2502(2) 0.4309(8) -0.0537(3) 0.0375(18) Uani 1 1 d .
C3 C 0.2809(2) 0.5608(8) 0.0198(3) 0.0345(18) Uani 1 1 d .
C11 C 0.1716(2) 0.4003(9) -0.0031(3) 0.0378(18) Uani 1 1 d .
C12 C 0.1392(2) 0.3021(9) -0.0371(3) 0.0438(18) Uani 1 1 d .
H1 H 0.1431 0.2590 -0.0638 0.053 Uiso 1 1 calc R
C13 C 0.1008(2) 0.2648(9) -0.0332(3) 0.050(2) Uani 1 1 d .
H2 H 0.0787 0.1952 -0.0568 0.060 Uiso 1 1 calc R
C14 C 0.0948(2) 0.3294(9) 0.0056(3) 0.0389(18) Uani 1 1 d .
C15 C 0.1271(2) 0.4271(9) 0.0393(3) 0.045(2) Uani 1 1 d .
H3 H 0.1233 0.4695 0.0662 0.055 Uiso 1 1 calc R
C16 C 0.1657(2) 0.4661(9) 0.0352(3) 0.046(2) Uani 1 1 d .
H4 H 0.1877 0.5371 0.0585 0.055 Uiso 1 1 calc R
C17 C 0.0535(2) 0.2782(10) 0.0106(3) 0.0468(19) Uani 1 1 d .
H5 H 0.0479 0.3637 0.0311 0.056 Uiso 1 1 calc R
H6 H 0.0278 0.2794 -0.0216 0.056 Uiso 1 1 calc R
C18 C 0.0684(2) 0.0706(11) 0.0772(3) 0.052(2) Uani 1 1 d .
H7 H 0.0731 0.1546 0.1014 0.062 Uiso 1 1 calc R
C19 C 0.0626(2) -0.1685(11) 0.0416(3) 0.056(2) Uani 1 1 d .
H8 H 0.0623 -0.2890 0.0357 0.067 Uiso 1 1 calc R
C20 C 0.0541(2) -0.0440(11) 0.0087(3) 0.051(2) Uani 1 1 d .
H9 H 0.0468 -0.0591 -0.0245 0.062 Uiso 1 1 calc R
C21 C 0.2465(2) -0.8711(9) 0.0970(3) 0.0395(18) Uani 1 1 d .
C22 C 0.2807(2) -0.7826(11) 0.1323(3) 0.068(3) Uani 1 1 d .
H10 H 0.3074 -0.7691 0.1295 0.082 Uiso 1 1 calc R
C23 C 0.2776(2) -0.7125(12) 0.1717(3) 0.066(2) Uani 1 1 d .
H11 H 0.3019 -0.6522 0.1957 0.080 Uiso 1 1 calc R
C24 C 0.2386(2) -0.7315(9) 0.1759(3) 0.0464(19) Uani 1 1 d .
C25 C 0.2049(2) -0.8277(9) 0.1421(3) 0.045(2) Uani 1 1 d .
H12 H 0.1787 -0.8477 0.1458 0.054 Uiso 1 1 calc R
C26 C 0.2089(2) -0.8951(10) 0.1028(3) 0.048(2) Uani 1 1 d .
H13 H 0.1851 -0.9592 0.0793 0.058 Uiso 1 1 calc R
C27 C 0.2323(2) -0.6392(10) 0.2164(3) 0.052(2) Uani 1 1 d .
H14 H 0.2198 -0.7207 0.2319 0.062 Uiso 1 1 calc R
H15 H 0.2611 -0.5980 0.2412 0.062 Uiso 1 1 calc R
C28 C 0.1637(2) -0.4724(10) 0.1973(3) 0.049(2) Uani 1 1 d .
H16 H 0.1519 -0.5486 0.2129 0.059 Uiso 1 1 calc R
C29 C 0.1717(2) -0.2577(9) 0.1579(3) 0.051(2) Uani 1 1 d .
H17 H 0.1667 -0.1527 0.1404 0.062 Uiso 1 1 calc R
C30 C 0.2073(3) -0.3572(10) 0.1714(3) 0.050(2) Uani 1 1 d .
H18 H 0.2317 -0.3362 0.1645 0.061 Uiso 1 1 calc R
C31 C 0.1813(2) -0.8498(9) 0.4424(3) 0.0398(18) Uani 1 1 d .
C32 C 0.1836(2) -0.8019(10) 0.4003(3) 0.056(2) Uani 1 1 d .
H19 H 0.2085 -0.8343 0.3953 0.067 Uiso 1 1 calc R
C33 C 0.1494(3) -0.7057(11) 0.3649(3) 0.060(2) Uani 1 1 d .
H20 H 0.1509 -0.6721 0.3361 0.072 Uiso 1 1 calc R
C34 C 0.1131(2) -0.6606(10) 0.3729(3) 0.056(2) Uani 1 1 d .
C35 C 0.1111(2) -0.7149(10) 0.4142(3) 0.055(2) Uani 1 1 d .
H21 H 0.0856 -0.6888 0.4187 0.066 Uiso 1 1 calc R
C36 C 0.1450(2) -0.8057(9) 0.4491(3) 0.0439(19) Uani 1 1 d .
H22 H 0.1433 -0.8382 0.4780 0.053 Uiso 1 1 calc R
C37 C 0.0767(3) -0.5448(13) 0.3369(3) 0.080(3) Uani 1 1 d .
H23 H 0.0479 -0.5847 0.3346 0.096 Uiso 1 1 calc R
H24 H 0.0814 -0.4256 0.3498 0.096 Uiso 1 1 calc R
C38 C 0.0892(3) -0.4190(11) 0.2692(4) 0.066(3) Uani 1 1 d .
H25 H 0.1031 -0.3150 0.2848 0.079 Uiso 1 1 calc R
C39 C 0.0635(3) -0.6197(13) 0.2161(4) 0.072(3) Uani 1 1 d .
H26 H 0.0552 -0.6847 0.1873 0.087 Uiso 1 1 calc R
C40 C 0.0587(3) -0.6721(12) 0.2570(4) 0.073(3) Uani 1 1 d .
H27 H 0.0467 -0.7786 0.2610 0.088 Uiso 1 1 calc R
C61 C 0.0153(6) -0.119(2) 0.2942(3) 0.28(2) Uani 0.833(11) 1 d PD
H28 H 0.0438 -0.1746 0.3010 0.334 Uiso 0.833(11) 1 calc PR
H29 H -0.0057 -0.2114 0.2922 0.334 Uiso 0.833(11) 1 calc PR
C62 C 0.0225(6) 0.0008(19) 0.3392(7) 0.38(3) Uani 0.833(11) 1 d PD
H30 H 0.0380 -0.0649 0.3691 0.452 Uiso 0.833(11) 1 calc PR
H31 H -0.0062 0.0388 0.3365 0.452 Uiso 0.833(11) 1 calc PR
H32 H 0.0402 0.1018 0.3395 0.452 Uiso 0.833(11) 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N22 Pb1 O41 77.28(19) . .
N22 Pb1 N12 83.8(2) . .
O41 Pb1 N12 79.5(2) . .
N22 Pb1 N32 81.3(2) . .
O41 Pb1 N32 78.1(2) . .
N12 Pb1 N32 155.3(2) . .
N22 Pb1 O52 84.21(19) . 1_565
O41 Pb1 O52 151.81(18) . 1_565
N12 Pb1 O52 119.7(2) . 1_565
N32 Pb1 O52 78.2(2) . 1_565
N22 Pb1 O53 79.19(17) . 1_565
O41 Pb1 O53 146.39(17) . 1_565
N12 Pb1 O53 74.4(2) . 1_565
N32 Pb1 O53 121.4(2) . 1_565
O52 Pb1 O53 45.33(17) 1_565 1_565
C61 O6 C61 128.3(18) 2 .
N4 O41 Pb1 106.0(5) . .
N5 O52 Pb1 99.0(5) . 1_545
N5 O53 Pb1 98.3(5) . 1_545
C1 N1 C2 115.9(6) . .
C2 N2 C3 115.7(6) . .
C1 N3 C3 114.6(6) . .
O43 N4 O41 121.7(8) . .
O43 N4 O42 120.2(8) . .
O41 N4 O42 118.1(8) . .
O51 N5 O52 123.1(8) . .
O51 N5 O53 119.9(8) . .
O52 N5 O53 116.8(8) . .
C18 N11 C20 107.3(7) . .
C18 N11 C17 126.8(7) . .
C20 N11 C17 125.8(7) . .
C18 N12 C19 106.1(7) . .
C18 N12 Pb1 120.0(6) . .
C19 N12 Pb1 132.0(6) . .
C28 N21 C30 104.9(6) . .
C28 N21 C27 126.9(7) . .
C30 N21 C27 128.1(6) . .
C28 N22 C29 104.9(6) . .
C28 N22 Pb1 128.9(5) . .
C29 N22 Pb1 126.1(5) . .
C38 N31 C40 105.5(8) . .
C38 N31 C37 129.2(9) . .
C40 N31 C37 125.2(9) . .
C38 N32 C39 106.3(8) . .
C38 N32 Pb1 120.1(6) . .
C39 N32 Pb1 128.3(7) . .
N1 C1 N3 125.2(6) . .
N1 C1 C11 116.4(6) . .
N3 C1 C11 118.4(7) . .
N2 C2 N1 124.3(7) . .
N2 C2 C21 117.9(6) . 7_545
N1 C2 C21 117.7(6) . 7_545
N3 C3 N2 124.2(6) . .
N3 C3 C31 118.7(7) . 4_565
N2 C3 C31 117.1(6) . 4_565
C12 C11 C16 119.9(6) . .
C12 C11 C1 120.0(7) . .
C16 C11 C1 120.1(7) . .
C11 C12 C13 120.8(7) . .
C11 C12 H1 119.6 . .
C13 C12 H1 119.6 . .
C12 C13 C14 119.7(7) . .
C12 C13 H2 120.1 . .
C14 C13 H2 120.1 . .
C15 C14 C13 119.3(7) . .
C15 C14 C17 121.9(7) . .
C13 C14 C17 118.7(6) . .
C14 C15 C16 121.0(7) . .
C14 C15 H3 119.5 . .
C16 C15 H3 119.5 . .
C11 C16 C15 119.2(7) . .
C11 C16 H4 120.4 . .
C15 C16 H4 120.4 . .
N11 C17 C14 111.5(5) . .
N11 C17 H5 109.3 . .
C14 C17 H5 109.3 . .
N11 C17 H6 109.3 . .
C14 C17 H6 109.3 . .
H5 C17 H6 108.0 . .
N12 C18 N11 111.2(8) . .
N12 C18 H7 124.4 . .
N11 C18 H7 124.4 . .
C20 C19 N12 108.9(7) . .
C20 C19 H8 125.5 . .
N12 C19 H8 125.5 . .
C19 C20 N11 106.5(8) . .
C19 C20 H9 126.7 . .
N11 C20 H9 126.7 . .
C26 C21 C22 117.7(7) . .
C26 C21 C2 121.4(7) . 7_545
C22 C21 C2 120.9(7) . 7_545
C21 C22 C23 122.6(7) . .
C21 C22 H10 118.7 . .
C23 C22 H10 118.7 . .
C22 C23 C24 118.8(7) . .
C22 C23 H11 120.6 . .
C24 C23 H11 120.6 . .
C25 C24 C23 119.3(7) . .
C25 C24 C27 120.3(7) . .
C23 C24 C27 120.3(7) . .
C24 C25 C26 120.3(7) . .
C24 C25 H12 119.9 . .
C26 C25 H12 119.9 . .
C21 C26 C25 121.1(7) . .
C21 C26 H13 119.4 . .
C25 C26 H13 119.4 . .
N21 C27 C24 109.7(6) . .
N21 C27 H14 109.7 . .
C24 C27 H14 109.7 . .
N21 C27 H15 109.7 . .
C24 C27 H15 109.7 . .
H14 C27 H15 108.2 . .
N22 C28 N21 112.7(7) . .
N22 C28 H16 123.7 . .
N21 C28 H16 123.7 . .
C30 C29 N22 108.8(7) . .
C30 C29 H17 125.6 . .
N22 C29 H17 125.6 . .
C29 C30 N21 108.7(7) . .
C29 C30 H18 125.7 . .
N21 C30 H18 125.7 . .
C36 C31 C32 119.8(7) . .
C36 C31 C3 121.2(7) . 4_535
C32 C31 C3 119.0(7) . 4_535
C31 C32 C33 120.4(7) . .
C31 C32 H19 119.8 . .
C33 C32 H19 119.8 . .
C34 C33 C32 118.7(7) . .
C34 C33 H20 120.6 . .
C32 C33 H20 120.6 . .
C35 C34 C33 119.4(7) . .
C35 C34 C37 120.2(7) . .
C33 C34 C37 120.4(8) . .
C36 C35 C34 121.7(7) . .
C36 C35 H21 119.1 . .
C34 C35 H21 119.1 . .
C35 C36 C31 119.9(7) . .
C35 C36 H22 120.1 . .
C31 C36 H22 120.1 . .
N31 C37 C34 114.7(7) . .
N31 C37 H23 108.6 . .
C34 C37 H23 108.6 . .
N31 C37 H24 108.6 . .
C34 C37 H24 108.6 . .
H23 C37 H24 107.6 . .
N32 C38 N31 112.7(8) . .
N32 C38 H25 123.6 . .
N31 C38 H25 123.6 . .
N32 C39 C40 108.2(9) . .
N32 C39 H26 125.9 . .
C40 C39 H26 125.9 . .
N31 C40 C39 107.2(8) . .
N31 C40 H27 126.4 . .
C39 C40 H27 126.4 . .
O6 C61 C62 117.6(15) . .
O6 C61 H28 107.9 . .
C62 C61 H28 107.9 . .
O6 C61 H29 107.9 . .
C62 C61 H29 107.9 . .
H28 C61 H29 107.2 . .
C61 C62 H30 109.5 . .
C61 C62 H31 109.5 . .
H30 C62 H31 109.5 . .
C61 C62 H32 109.5 . .
H30 C62 H32 109.5 . .
H31 C62 H32 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pb1 N22 2.374(5) .
Pb1 O41 2.543(6) .
Pb1 N12 2.564(6) .
Pb1 N32 2.600(7) .
Pb1 O52 2.751(6) 1_565
Pb1 O53 2.753(5) 1_565
O6 C61 1.365(10) 2
O6 C61 1.365(10) .
O41 N4 1.237(8) .
O42 N4 1.254(8) .
O43 N4 1.228(9) .
O51 N5 1.221(8) .
O52 N5 1.234(8) .
O52 Pb1 2.751(6) 1_545
O53 N5 1.256(8) .
O53 Pb1 2.753(5) 1_545
N1 C1 1.330(8) .
N1 C2 1.343(8) .
N2 C2 1.332(8) .
N2 C3 1.355(8) .
N3 C1 1.345(8) .
N3 C3 1.350(8) .
N11 C18 1.317(9) .
N11 C20 1.345(9) .
N11 C17 1.458(9) .
N12 C18 1.300(9) .
N12 C19 1.351(9) .
N21 C28 1.338(8) .
N21 C30 1.374(9) .
N21 C27 1.436(9) .
N22 C28 1.324(9) .
N22 C29 1.381(9) .
N31 C38 1.356(10) .
N31 C40 1.368(11) .
N31 C37 1.418(10) .
N32 C38 1.322(10) .
N32 C39 1.359(10) .
C1 C11 1.495(9) .
C2 C21 1.461(9) 7_545
C3 C31 1.469(9) 4_565
C11 C12 1.366(9) .
C11 C16 1.378(9) .
C12 C13 1.380(9) .
C12 H1 0.9500 .
C13 C14 1.391(10) .
C13 H2 0.9500 .
C14 C15 1.360(9) .
C14 C17 1.519(9) .
C15 C16 1.395(9) .
C15 H3 0.9500 .
C16 H4 0.9500 .
C17 H5 0.9900 .
C17 H6 0.9900 .
C18 H7 0.9500 .
C19 C20 1.338(10) .
C19 H8 0.9500 .
C20 H9 0.9500 .
C21 C26 1.370(9) .
C21 C22 1.372(10) .
C21 C2 1.461(9) 7_545
C22 C23 1.375(11) .
C22 H10 0.9500 .
C23 C24 1.383(10) .
C23 H11 0.9500 .
C24 C25 1.378(10) .
C24 C27 1.534(10) .
C25 C26 1.380(9) .
C25 H12 0.9500 .
C26 H13 0.9500 .
C27 H14 0.9900 .
C27 H15 0.9900 .
C28 H16 0.9500 .
C29 C30 1.330(9) .
C29 H17 0.9500 .
C30 H18 0.9500 .
C31 C36 1.373(9) .
C31 C32 1.385(10) .
C31 C3 1.469(9) 4_535
C32 C33 1.405(10) .
C32 H19 0.9500 .
C33 C34 1.392(10) .
C33 H20 0.9500 .
C34 C35 1.372(10) .
C34 C37 1.532(10) .
C35 C36 1.371(10) .
C35 H21 0.9500 .
C36 H22 0.9500 .
C37 H23 0.9900 .
C37 H24 0.9900 .
C38 H25 0.9500 .
C39 C40 1.400(12) .
C39 H26 0.9500 .
C40 H27 0.9500 .
C61 C62 1.595(17) .
C61 H28 0.9900 .
C61 H29 0.9900 .
C62 H30 0.9800 .
C62 H31 0.9800 .
C62 H32 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N22 Pb1 O41 N4 164.0(5) . .
N12 Pb1 O41 N4 -110.1(5) . .
N32 Pb1 O41 N4 80.4(5) . .
O52 Pb1 O41 N4 113.8(5) 1_565 .
O53 Pb1 O41 N4 -149.4(5) 1_565 .
Pb1 O41 N4 O43 -173.6(7) . .
Pb1 O41 N4 O42 4.6(9) . .
Pb1 O52 N5 O51 -176.2(7) 1_545 .
Pb1 O52 N5 O53 7.6(7) 1_545 .
Pb1 O53 N5 O51 176.1(6) 1_545 .
Pb1 O53 N5 O52 -7.6(7) 1_545 .
N22 Pb1 N12 C18 -121.1(5) . .
O41 Pb1 N12 C18 160.7(6) . .
N32 Pb1 N12 C18 -174.1(5) . .
O52 Pb1 N12 C18 -41.4(6) 1_565 .
O53 Pb1 N12 C18 -40.7(5) 1_565 .
N22 Pb1 N12 C19 77.4(6) . .
O41 Pb1 N12 C19 -0.8(6) . .
N32 Pb1 N12 C19 24.5(9) . .
O52 Pb1 N12 C19 157.1(6) 1_565 .
O53 Pb1 N12 C19 157.9(7) 1_565 .
O41 Pb1 N22 C28 -71.5(7) . .
N12 Pb1 N22 C28 -152.1(7) . .
N32 Pb1 N22 C28 8.2(7) . .
O52 Pb1 N22 C28 87.1(7) 1_565 .
O53 Pb1 N22 C28 132.7(7) 1_565 .
O41 Pb1 N22 C29 112.0(6) . .
N12 Pb1 N22 C29 31.4(6) . .
N32 Pb1 N22 C29 -168.3(6) . .
O52 Pb1 N22 C29 -89.4(6) 1_565 .
O53 Pb1 N22 C29 -43.8(6) 1_565 .
N22 Pb1 N32 C38 110.5(6) . .
O41 Pb1 N32 C38 -170.8(6) . .
N12 Pb1 N32 C38 163.9(5) . .
O52 Pb1 N32 C38 24.6(6) 1_565 .
O53 Pb1 N32 C38 38.9(7) 1_565 .
N22 Pb1 N32 C39 -99.1(7) . .
O41 Pb1 N32 C39 -20.4(7) . .
N12 Pb1 N32 C39 -45.7(9) . .
O52 Pb1 N32 C39 175.0(7) 1_565 .
O53 Pb1 N32 C39 -170.7(6) 1_565 .
C2 N1 C1 N3 -0.4(10) . .
C2 N1 C1 C11 178.7(5) . .
C3 N3 C1 N1 -0.3(9) . .
C3 N3 C1 C11 -179.5(5) . .
C3 N2 C2 N1 0.7(9) . .
C3 N2 C2 C21 -176.6(6) . 7_545
C1 N1 C2 N2 0.2(10) . .
C1 N1 C2 C21 177.5(6) . 7_545
C1 N3 C3 N2 1.3(9) . .
C1 N3 C3 C31 -178.3(6) . 4_565
C2 N2 C3 N3 -1.5(9) . .
C2 N2 C3 C31 178.1(6) . 4_565
N1 C1 C11 C12 5.5(9) . .
N3 C1 C11 C12 -175.2(6) . .
N1 C1 C11 C16 -172.4(6) . .
N3 C1 C11 C16 6.9(9) . .
C16 C11 C12 C13 -1.3(11) . .
C1 C11 C12 C13 -179.2(6) . .
C11 C12 C13 C14 0.8(11) . .
C12 C13 C14 C15 -0.7(11) . .
C12 C13 C14 C17 -176.6(6) . .
C13 C14 C15 C16 1.2(11) . .
C17 C14 C15 C16 177.0(6) . .
C12 C11 C16 C15 1.8(11) . .
C1 C11 C16 C15 179.6(6) . .
C14 C15 C16 C11 -1.8(11) . .
C18 N11 C17 C14 98.7(8) . .
C20 N11 C17 C14 -77.5(8) . .
C15 C14 C17 N11 -95.8(8) . .
C13 C14 C17 N11 80.0(8) . .
C19 N12 C18 N11 0.0(8) . .
Pb1 N12 C18 N11 -165.8(4) . .
C20 N11 C18 N12 -0.1(8) . .
C17 N11 C18 N12 -176.8(6) . .
C18 N12 C19 C20 0.1(8) . .
Pb1 N12 C19 C20 163.5(5) . .
N12 C19 C20 N11 -0.2(8) . .
C18 N11 C20 C19 0.1(8) . .
C17 N11 C20 C19 176.9(6) . .
C26 C21 C22 C23 -2.6(13) . .
C2 C21 C22 C23 174.8(8) 7_545 .
C21 C22 C23 C24 -0.2(14) . .
C22 C23 C24 C25 3.5(13) . .
C22 C23 C24 C27 -173.5(8) . .
C23 C24 C25 C26 -4.1(11) . .
C27 C24 C25 C26 173.0(7) . .
C22 C21 C26 C25 2.0(12) . .
C2 C21 C26 C25 -175.4(7) 7_545 .
C24 C25 C26 C21 1.3(12) . .
C28 N21 C27 C24 118.5(8) . .
C30 N21 C27 C24 -57.4(10) . .
C25 C24 C27 N21 -71.5(9) . .
C23 C24 C27 N21 105.5(8) . .
C29 N22 C28 N21 -1.5(9) . .
Pb1 N22 C28 N21 -178.6(4) . .
C30 N21 C28 N22 0.7(9) . .
C27 N21 C28 N22 -175.9(7) . .
C28 N22 C29 C30 1.7(9) . .
Pb1 N22 C29 C30 178.9(5) . .
N22 C29 C30 N21 -1.3(9) . .
C28 N21 C30 C29 0.4(8) . .
C27 N21 C30 C29 176.9(7) . .
C36 C31 C32 C33 1.2(11) . .
C3 C31 C32 C33 -175.5(7) 4_535 .
C31 C32 C33 C34 -0.4(12) . .
C32 C33 C34 C35 -1.8(12) . .
C32 C33 C34 C37 175.5(8) . .
C33 C34 C35 C36 3.2(13) . .
C37 C34 C35 C36 -174.2(8) . .
C34 C35 C36 C31 -2.3(12) . .
C32 C31 C36 C35 0.1(11) . .
C3 C31 C36 C35 176.8(7) 4_535 .
C38 N31 C37 C34 -101.9(10) . .
C40 N31 C37 C34 73.6(11) . .
C35 C34 C37 N31 -161.2(8) . .
C33 C34 C37 N31 21.6(13) . .
C39 N32 C38 N31 -2.7(10) . .
Pb1 N32 C38 N31 153.5(5) . .
C40 N31 C38 N32 2.8(10) . .
C37 N31 C38 N32 178.9(7) . .
C38 N32 C39 C40 1.4(9) . .
Pb1 N32 C39 C40 -152.1(6) . .
C38 N31 C40 C39 -1.8(9) . .
C37 N31 C40 C39 -178.1(7) . .
N32 C39 C40 N31 0.3(10) . .
C61 O6 C61 C62 -168.6(19) 2 .
