#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:34:12 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180227 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/13/7111362.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7111362
loop_
_publ_author_name
'Villanueva, Luis'
'Arroyo, Maribel'
'Bern�s, Sylvain'
'Torrens, Hugo'
_publ_section_title
;
 Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4)
 through carbon?fluorine bond activation to
 [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral
 [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information
 (ESI) available: experimental procedures and spectral data for all new
 compounds and crystallographic data for 5, 8 and 10.
 http://www.rsc.org/suppdata/cc/b4/b407328b/
;
_journal_issue                   17
_journal_name_full               'Chemical Communications'
_journal_page_first              1942
_journal_page_last               1943
_journal_paper_doi               10.1039/b407328b
_journal_year                    2004
_chemical_formula_moiety         'C60 H14 F36 P2 Pt2 S4'
_chemical_formula_sum            'C60 H14 F36 P2 Pt2 S4'
_chemical_formula_weight         1999.07
_space_group_IT_number           176
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-P 6c'
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2003-03-26
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   25.675(2)
_cell_length_b                   25.675(2)
_cell_length_c                   19.115(2)
_cell_measurement_reflns_used    84
_cell_measurement_temperature    296(1)
_cell_measurement_theta_max      12.29
_cell_measurement_theta_min      4.68
_cell_volume                     10912.5(17)
_computing_cell_refinement       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_collection       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_reduction        'XSCAnS 2.21 (Fait, 1996)'
_computing_molecular_graphics    'SHELXTL 5.10 (Sheldrick, 1998)'
_computing_publication_material  'SHELX97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELX97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL 5.10 (Sheldrick, 1998)'
_diffrn_ambient_temperature      296(1)
_diffrn_detector                 'Scintillation counter'
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0667
_diffrn_reflns_av_sigmaI/netI    0.0847
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       1
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -1
_diffrn_reflns_number            13877
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.83
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30
_diffrn_source_power             1.5
_diffrn_source_voltage           50
_diffrn_standards_decay_%        1
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.129
_exptl_absorpt_correction_T_max  0.769
_exptl_absorpt_correction_T_min  0.197
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '18 psi scans with XSCAnS 2.21 (Fait, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.825
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       hexagonal_plate
_exptl_crystal_F_000             5688
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.741
_refine_diff_density_min         -0.798
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     502
_refine_ls_number_reflns         6577
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.1180
_refine_ls_R_factor_gt           0.0542
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0710P)²+1.6475P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1255
_refine_ls_wR_factor_ref         0.1528
_reflns_number_gt                3631
_reflns_number_total             6577
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b407328bsup1.cif
_cod_data_source_block           lv103-2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        10912.5(18)
_cod_original_sg_symbol_H-M      P6(3)/m
_cod_database_code               7111362
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.901861(15) 0.656198(16) 0.34365(2) 0.05543(16) Uani 1 1 d .
P1 P 0.96855(13) 0.68596(14) 0.43326(16) 0.0695(8) Uani 1 1 d .
S1 S 0.82862(13) 0.63397(14) 0.42844(16) 0.0772(8) Uani 1 1 d .
S2 S 0.96961(15) 0.67823(16) 0.2500 0.0618(9) Uani 1 2 d S
S3 S 0.83202(16) 0.62169(17) 0.2500 0.0663(10) Uani 1 2 d S
C1 C 0.9745(4) 0.7454(5) 0.4884(6) 0.067(3) Uani 1 1 d .
C2 C 0.9330(5) 0.7649(5) 0.4864(7) 0.094(4) Uani 1 1 d .
H2A H 0.9007 0.7470 0.4556 0.113 Uiso 1 1 calc R
C3 C 0.9390(6) 0.8104(6) 0.5295(8) 0.113(5) Uani 1 1 d .
H3A H 0.9120 0.8244 0.5252 0.136 Uiso 1 1 calc R
C4 C 0.9828(6) 0.8352(6) 0.5776(7) 0.101(4) Uani 1 1 d .
H4A H 0.9840 0.8635 0.6090 0.122 Uiso 1 1 calc R
C5 C 1.0243(6) 0.8188(5) 0.5799(6) 0.091(4) Uani 1 1 d .
H5A H 1.0560 0.8373 0.6113 0.109 Uiso 1 1 calc R
C6 C 1.0205(5) 0.7739(5) 0.5351(6) 0.074(3) Uani 1 1 d .
H6A H 1.0501 0.7632 0.5373 0.089 Uiso 1 1 calc R
C7 C 0.9514(5) 0.6227(5) 0.4921(7) 0.079(3) Uani 1 1 d .
C8 C 0.9476(10) 0.5715(7) 0.4643(10) 0.153(7) Uani 1 1 d .
C9 C 0.9319(12) 0.5215(8) 0.5036(11) 0.188(10) Uani 1 1 d .
C10 C 0.9190(11) 0.5184(9) 0.5736(10) 0.169(9) Uani 1 1 d .
C11 C 0.9226(7) 0.5678(7) 0.6017(9) 0.107(5) Uani 1 1 d .
C12 C 0.9387(5) 0.6183(6) 0.5609(7) 0.078(3) Uani 1 1 d .
C13 C 1.0465(6) 0.7148(8) 0.4084(7) 0.105(5) Uani 1 1 d D
C14 C 1.0736(7) 0.7699(8) 0.3749(8) 0.142(8) Uani 1 1 d D
C15 C 1.1341(8) 0.8079(12) 0.3554(11) 0.217(18) Uani 1 1 d D
C16 C 1.1669(10) 0.7811(8) 0.3732(11) 0.170(12) Uani 1 1 d D
C17 C 1.1461(7) 0.7261(9) 0.4044(9) 0.170(11) Uani 1 1 d D
C18 C 1.0873(7) 0.6961(8) 0.4272(8) 0.106(5) Uani 1 1 d D
C19 C 0.7652(5) 0.5656(6) 0.4018(6) 0.086(3) Uani 1 1 d .
C20 C 0.7096(6) 0.5637(6) 0.3960(7) 0.086(4) Uani 1 1 d .
C21 C 0.6592(7) 0.5114(9) 0.3792(9) 0.128(6) Uani 1 1 d .
C22 C 0.6577(9) 0.4616(8) 0.3611(12) 0.168(9) Uani 1 1 d .
H22A H 0.6232 0.4282 0.3443 0.202 Uiso 1 1 calc R
C23 C 0.7114(10) 0.4632(7) 0.3690(12) 0.154(8) Uani 1 1 d .
C24 C 0.7645(8) 0.5131(6) 0.3847(10) 0.120(5) Uani 1 1 d .
C25 C 0.9846(6) 0.6157(7) 0.2500 0.078(5) Uani 1 2 d SD
C26 C 1.0452(7) 0.6319(9) 0.2500 0.099(6) Uani 1 2 d SD
C27 C 1.0576(11) 0.5848(10) 0.2500 0.127(9) Uani 1 2 d SD
C28 C 1.0124(11) 0.5248(10) 0.2500 0.154(13) Uani 1 2 d SD
H28A H 1.0219 0.4943 0.2500 0.185 Uiso 1 2 calc SR
C29 C 0.9529(11) 0.5111(9) 0.2500 0.111(7) Uani 1 2 d SD
C30 C 0.9377(9) 0.5559(7) 0.2500 0.098(6) Uani 1 2 d SD
C31 C 0.7997(8) 0.6685(12) 0.2500 0.107(7) Uani 1 2 d SD
C32 C 0.7368(9) 0.6369(12) 0.2500 0.117(9) Uani 1 2 d SD
C33 C 0.7065(13) 0.6688(13) 0.2500 0.22(2) Uani 1 2 d SD
C34 C 0.7370(15) 0.7307(13) 0.2500 0.26(4) Uani 1 2 d SD
H34A H 0.7178 0.7533 0.2500 0.313 Uiso 1 2 calc SR
C35 C 0.7988(15) 0.7563(13) 0.2500 0.32(4) Uani 1 2 d SD
C36 C 0.8354(14) 0.7306(12) 0.2500 0.18(2) Uani 1 2 d SD
F8 F 0.9574(6) 0.5698(5) 0.3952(5) 0.192(6) Uani 1 1 d .
F9 F 0.9303(10) 0.4736(6) 0.4705(6) 0.332(12) Uani 1 1 d .
F10 F 0.9077(8) 0.4704(5) 0.6074(6) 0.240(7) Uani 1 1 d .
F11 F 0.9110(5) 0.5666(4) 0.6690(5) 0.139(3) Uani 1 1 d .
F12 F 0.9379(3) 0.6635(3) 0.5958(4) 0.108(2) Uani 1 1 d .
F14 F 1.0402(4) 0.7951(3) 0.3570(5) 0.123(3) Uani 1 1 d .
F15 F 1.1548(7) 0.8564(7) 0.3216(10) 0.298(13) Uani 1 1 d .
F16 F 1.2258(4) 0.8048(8) 0.3610(8) 0.266(9) Uani 1 1 d .
F17 F 1.1783(5) 0.6982(8) 0.4242(7) 0.259(8) Uani 1 1 d .
F18 F 1.0653(5) 0.6413(7) 0.4564(6) 0.176(5) Uani 1 1 d .
F20 F 0.7054(3) 0.6131(4) 0.4085(4) 0.109(2) Uani 1 1 d .
F21 F 0.6059(4) 0.5135(4) 0.3725(6) 0.171(4) Uani 1 1 d .
F23 F 0.7172(6) 0.4144(4) 0.3537(9) 0.266(8) Uani 1 1 d .
F24 F 0.8165(4) 0.5119(4) 0.3909(6) 0.159(4) Uani 1 1 d .
F26 F 1.0901(4) 0.6905(6) 0.2500 0.102(3) Uani 1 2 d S
F27 F 1.1180(7) 0.6028(8) 0.2500 0.184(7) Uani 1 2 d S
F29 F 0.9126(8) 0.4549(6) 0.2500 0.180(7) Uani 1 2 d S
F30 F 0.8820(5) 0.5399(4) 0.2500 0.101(3) Uani 1 2 d S
F32 F 0.7023(6) 0.5786(11) 0.2500 0.217(10) Uani 1 2 d S
F33 F 0.6425(10) 0.6349(15) 0.2500 0.331(16) Uani 1 2 d S
F35 F 0.8247(15) 0.8157(11) 0.2500 0.291(16) Uani 1 2 d SD
F36 F 0.8921(9) 0.7581(7) 0.2500 0.172(8) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
3 -6 1
-6 5 0
-6 3 -1
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Pt1 S1 86.44(11) . .
P1 Pt1 S2 98.65(10) . .
S1 Pt1 S2 174.71(10) . .
P1 Pt1 S3 177.94(12) . .
S1 Pt1 S3 93.83(10) . .
S2 Pt1 S3 81.13(9) . .
C1 P1 C13 101.5(6) . .
C1 P1 C7 105.9(5) . .
C13 P1 C7 104.4(6) . .
C1 P1 Pt1 117.3(4) . .
C13 P1 Pt1 115.6(4) . .
C7 P1 Pt1 110.9(4) . .
C19 S1 Pt1 105.8(4) . .
C25 S2 Pt1 104.1(3) . 10_556
C25 S2 Pt1 104.1(3) . .
Pt1 S2 Pt1 98.71(13) 10_556 .
C31 S3 Pt1 105.7(5) . .
C31 S3 Pt1 105.7(5) . 10_556
Pt1 S3 Pt1 98.11(13) . 10_556
C6 C1 C2 116.0(10) . .
C6 C1 P1 121.5(8) . .
C2 C1 P1 122.4(8) . .
C3 C2 C1 120.8(11) . .
C3 C2 H2A 119.6 . .
C1 C2 H2A 119.6 . .
C4 C3 C2 121.6(12) . .
C4 C3 H3A 119.2 . .
C2 C3 H3A 119.2 . .
C5 C4 C3 119.2(12) . .
C5 C4 H4A 120.4 . .
C3 C4 H4A 120.4 . .
C4 C5 C6 120.3(12) . .
C4 C5 H5A 119.8 . .
C6 C5 H5A 119.8 . .
C1 C6 C5 121.8(11) . .
C1 C6 H6A 119.1 . .
C5 C6 H6A 119.1 . .
C12 C7 C8 113.5(13) . .
C12 C7 P1 127.8(10) . .
C8 C7 P1 118.6(11) . .
F8 C8 C9 118.7(14) . .
F8 C8 C7 119.0(14) . .
C9 C8 C7 122.3(17) . .
F9 C9 C8 117.1(18) . .
F9 C9 C10 120.2(16) . .
C8 C9 C10 122.7(16) . .
F10 C10 C11 125.5(18) . .
F10 C10 C9 118.4(18) . .
C11 C10 C9 116.0(16) . .
F11 C11 C10 117.5(15) . .
F11 C11 C12 122.0(13) . .
C10 C11 C12 120.5(16) . .
C7 C12 F12 121.2(11) . .
C7 C12 C11 125.0(13) . .
F12 C12 C11 113.7(12) . .
C14 C13 C18 113.0(15) . .
C14 C13 P1 115.2(11) . .
C18 C13 P1 130.9(14) . .
F14 C14 C13 119.5(13) . .
F14 C14 C15 110.2(18) . .
C13 C14 C15 130(2) . .
F15 C15 C16 124.2(19) . .
F15 C15 C14 126(2) . .
C16 C15 C14 109(2) . .
F16 C16 C15 124.7(17) . .
F16 C16 C17 108(2) . .
C15 C16 C17 127(2) . .
C16 C17 C18 117.9(17) . .
C16 C17 F17 128.5(19) . .
C18 C17 F17 113.2(17) . .
F18 C18 C17 119.1(14) . .
F18 C18 C13 117.9(15) . .
C17 C18 C13 121.7(15) . .
C24 C19 C20 115.4(12) . .
C24 C19 S1 126.5(11) . .
C20 C19 S1 118.1(10) . .
F20 C20 C21 119.3(14) . .
F20 C20 C19 120.7(11) . .
C21 C20 C19 120.0(13) . .
C22 C21 C20 125.4(17) . .
C22 C21 F21 117.5(18) . .
C20 C21 F21 116.6(17) . .
C21 C22 C23 113.9(19) . .
C21 C22 H22A 123.0 . .
C23 C22 H22A 123.0 . .
C24 C23 C22 125.0(16) . .
C24 C23 F23 113.2(19) . .
C22 C23 F23 121.4(19) . .
F24 C24 C23 122.2(15) . .
F24 C24 C19 118.0(14) . .
C23 C24 C19 119.5(15) . .
C26 C25 C30 123.1(16) . .
C26 C25 S2 115.5(12) . .
C30 C25 S2 121.4(10) . .
F26 C26 C25 122.1(14) . .
F26 C26 C27 121.5(15) . .
C25 C26 C27 116.4(17) . .
F27 C27 C28 123.2(16) . .
F27 C27 C26 114.5(19) . .
C28 C27 C26 122.2(19) . .
C29 C28 C27 119(2) . .
C29 C28 H28A 120.5 . .
C27 C28 H28A 120.5 . .
F29 C29 C30 122(2) . .
F29 C29 C28 116.8(17) . .
C30 C29 C28 121(2) . .
F30 C30 C29 118.0(16) . .
F30 C30 C25 124.2(13) . .
C29 C30 C25 117.8(19) . .
C36 C31 C32 125(2) . .
C36 C31 S3 121.1(15) . .
C32 C31 S3 113.8(18) . .
F32 C32 C33 115(2) . .
F32 C32 C31 126(2) . .
C33 C32 C31 119(2) . .
C34 C33 C32 121(3) . .
C34 C33 F33 122(2) . .
C32 C33 F33 117(2) . .
C33 C34 C35 114(3) . .
C33 C34 H34A 123.1 . .
C35 C34 H34A 123.1 . .
F35 C35 C34 110(3) . .
F35 C35 C36 119(3) . .
C34 C35 C36 132(3) . .
F36 C36 C31 124(2) . .
F36 C36 C35 127(3) . .
C31 C36 C35 109(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P1 2.268(3) .
Pt1 S1 2.327(3) .
Pt1 S2 2.359(2) .
Pt1 S3 2.370(2) .
P1 C1 1.798(11) .
P1 C13 1.817(14) .
P1 C7 1.839(12) .
S1 C19 1.770(12) .
S2 C25 1.829(15) .
S2 Pt1 2.359(2) 10_556
S3 C31 1.769(19) .
S3 Pt1 2.370(2) 10_556
C1 C6 1.364(14) .
C1 C2 1.387(14) .
C2 C3 1.373(15) .
C2 H2A 0.9300 .
C3 C4 1.342(16) .
C3 H3A 0.9300 .
C4 C5 1.328(16) .
C4 H4A 0.9300 .
C5 C6 1.398(15) .
C5 H5A 0.9300 .
C6 H6A 0.9300 .
C7 C12 1.347(15) .
C7 C8 1.375(16) .
C8 F8 1.350(19) .
C8 C9 1.36(2) .
C9 F9 1.365(17) .
C9 C10 1.37(3) .
C10 F10 1.289(16) .
C10 C11 1.34(2) .
C11 F11 1.317(17) .
C11 C12 1.386(17) .
C12 F12 1.349(12) .
C13 C14 1.383(9) .
C13 C18 1.400(9) .
C14 F14 1.351(18) .
C14 C15 1.409(10) .
C15 F15 1.26(3) .
C15 C16 1.369(10) .
C16 F16 1.34(2) .
C16 C17 1.373(10) .
C17 C18 1.377(9) .
C17 F17 1.390(19) .
C18 F18 1.347(16) .
C19 C24 1.376(16) .
C19 C20 1.410(16) .
C20 F20 1.346(13) .
C20 C21 1.357(18) .
C21 C22 1.30(2) .
C21 F21 1.402(17) .
C22 C23 1.37(2) .
C22 H22A 0.9300 .
C23 C24 1.36(2) .
C23 F23 1.366(18) .
C24 F24 1.356(15) .
C25 C26 1.394(9) .
C25 C30 1.399(10) .
C26 F26 1.363(18) .
C26 C27 1.397(10) .
C27 F27 1.38(2) .
C27 C28 1.390(10) .
C28 C29 1.384(10) .
C28 H28A 0.9300 .
C29 F29 1.29(2) .
C29 C30 1.386(10) .
C30 F30 1.276(19) .
C31 C36 1.387(10) .
C31 C32 1.397(10) .
C32 F32 1.30(3) .
C32 C33 1.383(10) .
C33 C34 1.378(10) .
C33 F33 1.42(3) .
C34 C35 1.381(10) .
C34 H34A 0.9300 .
C35 F35 1.33(2) .
C35 C36 1.389(10) .
C36 F36 1.26(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
S1 Pt1 P1 C1 -59.0(4) . .
S2 Pt1 P1 C1 119.5(4) . .
S3 Pt1 P1 C1 -157(3) . .
S1 Pt1 P1 C13 -178.7(6) . .
S2 Pt1 P1 C13 -0.2(6) . .
S3 Pt1 P1 C13 84(3) . .
S1 Pt1 P1 C7 62.7(4) . .
S2 Pt1 P1 C7 -118.7(4) . .
S3 Pt1 P1 C7 -35(3) . .
P1 Pt1 S1 C19 -139.8(5) . .
S2 Pt1 S1 C19 56.0(14) . .
S3 Pt1 S1 C19 38.2(5) . .
P1 Pt1 S2 C25 78.2(4) . .
S1 Pt1 S2 C25 -117.7(13) . .
S3 Pt1 S2 C25 -99.7(4) . .
P1 Pt1 S2 Pt1 -174.80(12) . 10_556
S1 Pt1 S2 Pt1 -10.7(13) . 10_556
S3 Pt1 S2 Pt1 7.28(13) . 10_556
P1 Pt1 S3 C31 160(3) . .
S1 Pt1 S3 C31 62.2(6) . .
S2 Pt1 S3 C31 -116.1(6) . .
P1 Pt1 S3 Pt1 -91(3) . 10_556
S1 Pt1 S3 Pt1 171.13(13) . 10_556
S2 Pt1 S3 Pt1 -7.24(13) . 10_556
C13 P1 C1 C6 -40.8(11) . .
C7 P1 C1 C6 67.9(10) . .
Pt1 P1 C1 C6 -167.7(8) . .
C13 P1 C1 C2 139.5(11) . .
C7 P1 C1 C2 -111.8(10) . .
Pt1 P1 C1 C2 12.6(12) . .
C6 C1 C2 C3 0.1(19) . .
P1 C1 C2 C3 179.8(11) . .
C1 C2 C3 C4 -4(2) . .
C2 C3 C4 C5 6(2) . .
C3 C4 C5 C6 -3(2) . .
C2 C1 C6 C5 2.0(16) . .
P1 C1 C6 C5 -177.7(9) . .
C4 C5 C6 C1 -0.4(19) . .
C1 P1 C7 C12 7.1(13) . .
C13 P1 C7 C12 113.7(12) . .
Pt1 P1 C7 C12 -121.1(11) . .
C1 P1 C7 C8 -176.4(12) . .
C13 P1 C7 C8 -69.8(13) . .
Pt1 P1 C7 C8 55.4(13) . .
C12 C7 C8 F8 177.9(16) . .
P1 C7 C8 F8 1(2) . .
C12 C7 C8 C9 1(3) . .
P1 C7 C8 C9 -176.4(17) . .
F8 C8 C9 F9 3(3) . .
C7 C8 C9 F9 -179.3(19) . .
F8 C8 C9 C10 -178(2) . .
C7 C8 C9 C10 0(4) . .
F9 C9 C10 F10 3(4) . .
C8 C9 C10 F10 -176(2) . .
F9 C9 C10 C11 179.1(19) . .
C8 C9 C10 C11 0(4) . .
F10 C10 C11 F11 -3(3) . .
C9 C10 C11 F11 -179(2) . .
F10 C10 C11 C12 175.9(19) . .
C9 C10 C11 C12 0(3) . .
C8 C7 C12 F12 -177.2(13) . .
P1 C7 C12 F12 -0.5(18) . .
C8 C7 C12 C11 -1(2) . .
P1 C7 C12 C11 175.9(10) . .
F11 C11 C12 C7 179.7(13) . .
C10 C11 C12 C7 1(2) . .
F11 C11 C12 F12 -4(2) . .
C10 C11 C12 F12 177.3(16) . .
C1 P1 C13 C14 -58.1(10) . .
C7 P1 C13 C14 -168.0(9) . .
Pt1 P1 C13 C14 70.0(10) . .
C1 P1 C13 C18 109.7(13) . .
C7 P1 C13 C18 -0.2(15) . .
Pt1 P1 C13 C18 -122.3(12) . .
C18 C13 C14 F14 -176.5(13) . .
P1 C13 C14 F14 -6.5(15) . .
C18 C13 C14 C15 2.4(15) . .
P1 C13 C14 C15 172.4(11) . .
F14 C14 C15 F15 -5(2) . .
C13 C14 C15 F15 176(2) . .
F14 C14 C15 C16 -179.2(17) . .
C13 C14 C15 C16 1.8(17) . .
F15 C15 C16 F16 5(4) . .
C14 C15 C16 F16 179.0(15) . .
F15 C15 C16 C17 -174(2) . .
C14 C15 C16 C17 1(3) . .
F16 C16 C17 C18 174.4(13) . .
C15 C16 C17 C18 -7(3) . .
F16 C16 C17 F17 3(3) . .
C15 C16 C17 F17 -178.7(17) . .
C16 C17 C18 F18 178.3(16) . .
F17 C17 C18 F18 -9(2) . .
C16 C17 C18 C13 12(2) . .
F17 C17 C18 C13 -175.5(13) . .
C14 C13 C18 F18 -176.1(13) . .
P1 C13 C18 F18 16(2) . .
C14 C13 C18 C17 -9(2) . .
P1 C13 C18 C17 -177.2(12) . .
Pt1 S1 C19 C24 52.3(14) . .
Pt1 S1 C19 C20 -126.6(10) . .
C24 C19 C20 F20 -177.2(12) . .
S1 C19 C20 F20 1.8(17) . .
C24 C19 C20 C21 4(2) . .
S1 C19 C20 C21 -176.7(12) . .
F20 C20 C21 C22 174.9(19) . .
C19 C20 C21 C22 -7(3) . .
F20 C20 C21 F21 3(2) . .
C19 C20 C21 F21 -178.3(13) . .
C20 C21 C22 C23 8(3) . .
F21 C21 C22 C23 179.9(18) . .
C21 C22 C23 C24 -9(4) . .
C21 C22 C23 F23 178.8(19) . .
C22 C23 C24 F24 -179(2) . .
F23 C23 C24 F24 -6(3) . .
C22 C23 C24 C19 8(3) . .
F23 C23 C24 C19 -179.5(16) . .
C20 C19 C24 F24 -178.5(13) . .
S1 C19 C24 F24 3(2) . .
C20 C19 C24 C23 -5(2) . .
S1 C19 C24 C23 176.3(14) . .
Pt1 S2 C25 C26 128.54(13) 10_556 .
Pt1 S2 C25 C26 -128.54(13) . .
Pt1 S2 C25 C30 -51.46(13) 10_556 .
Pt1 S2 C25 C30 51.46(13) . .
C30 C25 C26 F26 180.0 . .
S2 C25 C26 F26 0.0 . .
C30 C25 C26 C27 0.0 . .
S2 C25 C26 C27 180.0 . .
F26 C26 C27 F27 0.0 . .
C25 C26 C27 F27 180.0 . .
F26 C26 C27 C28 180.0 . .
C25 C26 C27 C28 0.0 . .
F27 C27 C28 C29 180.0 . .
C26 C27 C28 C29 0.0 . .
C27 C28 C29 F29 180.0 . .
C27 C28 C29 C30 0.0 . .
F29 C29 C30 F30 0.0 . .
C28 C29 C30 F30 180.0 . .
F29 C29 C30 C25 180.0 . .
C28 C29 C30 C25 0.0 . .
C26 C25 C30 F30 180.0 . .
S2 C25 C30 F30 0.0 . .
C26 C25 C30 C29 0.0 . .
S2 C25 C30 C29 180.0 . .
Pt1 S3 C31 C36 51.69(19) . .
Pt1 S3 C31 C36 -51.7(2) 10_556 .
Pt1 S3 C31 C32 -128.31(19) . .
Pt1 S3 C31 C32 128.31(19) 10_556 .
C36 C31 C32 F32 180.0 . .
S3 C31 C32 F32 0.0 . .
C36 C31 C32 C33 0.0 . .
S3 C31 C32 C33 180.0 . .
F32 C32 C33 C34 180.0 . .
C31 C32 C33 C34 0.0 . .
F32 C32 C33 F33 0.0 . .
C31 C32 C33 F33 180.0 . .
C32 C33 C34 C35 0.0 . .
F33 C33 C34 C35 180.0 . .
C33 C34 C35 F35 180.0 . .
C33 C34 C35 C36 0.0 . .
C32 C31 C36 F36 180.0 . .
S3 C31 C36 F36 0.0 . .
C32 C31 C36 C35 0.0 . .
S3 C31 C36 C35 180.0 . .
F35 C35 C36 F36 0.0 . .
C34 C35 C36 F36 180.0 . .
F35 C35 C36 C31 180.0 . .
C34 C35 C36 C31 0.0 . .
