#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/15/7111571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7111571
loop_
_publ_author_name
'Liu, C. W.'
'Chang, How-Wei'
'Fang, Ching-Shiang'
'Sarkar, Bijay'
'Wang, Ju-Chun'
_publ_section_title
;
 Anion-templated syntheses of octanuclear silver clusters from a silver
 dithiophosphate chain
;
_journal_issue                   25
_journal_name_full               'Chemical Communications'
_journal_page_first              4571
_journal_page_last               4573
_journal_paper_doi               10.1039/b923388a
_journal_volume                  46
_journal_year                    2010
_chemical_formula_sum            'C24 H61 Ag8 Cl F6 O12.5 P7 S12'
_chemical_formula_weight         2163.65
_chemical_name_systematic
;
?
;
_space_group_IT_number           167
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3 2"c'
_symmetry_space_group_name_H-M   'R -3 c :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            12
_cell_length_a                   17.6921(8)
_cell_length_b                   17.6921(8)
_cell_length_c                   73.951(4)
_cell_measurement_reflns_used    3820
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      21.47
_cell_measurement_theta_min      2.30
_cell_volume                     20046.3(17)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0480
_diffrn_reflns_av_sigmaI/netI    0.0307
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       87
_diffrn_reflns_limit_l_min       -81
_diffrn_reflns_number            25198
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.73
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.936
_exptl_absorpt_correction_T_max  0.5393
_exptl_absorpt_correction_T_min  0.4883
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.160
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             12648
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.24
_refine_diff_density_max         1.439
_refine_diff_density_min         -0.978
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     207
_refine_ls_number_reflns         3941
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0560
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0601P)²+231.2577P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1413
_refine_ls_wR_factor_ref         0.1620
_reflns_number_gt                2546
_reflns_number_total             3941
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            B923388Asup1.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        20046.1(16)
_cod_original_sg_symbol_H-M      R-3c
_cod_original_formula_sum        'C24 H61 Ag8 Cl F6 O12.50 P7 S12'
_cod_database_code               7111571
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.3333 0.6667 0.12693(2) 0.1018(5) Uani 1 3 d S . .
Ag2 Ag 0.17357(5) 0.53335(6) 0.100289(12) 0.0878(3) Uani 1 1 d . . .
Ag3 Ag 0.29334(6) 0.48765(6) 0.075484(12) 0.0932(3) Uani 1 1 d . . .
Ag4 Ag 0.3333 0.6667 0.049401(17) 0.0655(3) Uani 1 3 d S . .
Cl1 Cl 0.3333 0.6667 0.08774(5) 0.0600(9) Uani 1 3 d S . .
S1 S 0.27978(15) 0.77403(14) 0.04702(3) 0.0644(6) Uani 1 1 d . . .
S2 S 0.08738(15) 0.54476(18) 0.07445(3) 0.0785(7) Uani 1 1 d . . .
S3 S 0.2099(2) 0.41288(17) 0.10362(4) 0.0903(8) Uani 1 1 d . A .
S4 S 0.1725(2) 0.6110(2) 0.12919(4) 0.0975(9) Uani 1 1 d . . .
P1 P 0.39023(16) 0.88568(15) 0.05123(3) 0.0666(6) Uani 1 1 d . . .
P2 P 0.2948(2) 0.4413(2) 0.12385(4) 0.0918(9) Uani 1 1 d D . .
P3 P 0.3333 0.6667 0.35711(11) 0.157(3) Uani 1 3 d S . .
F1 F 0.3878(14) 0.7433(14) 0.3455(3) 0.393(14) Uani 1 1 d . . .
F2 F 0.3154(13) 0.7253(11) 0.3668(3) 0.310(9) Uani 1 1 d . . .
O1 O 0.3634(5) 0.9565(4) 0.04757(11) 0.097(2) Uani 1 1 d D . .
O2 O 0.4594(4) 0.8960(4) 0.03671(9) 0.0842(19) Uani 1 1 d . . .
O3 O 0.3146(13) 0.3719(12) 0.1149(3) 0.166(8) Uiso 0.50 1 d PD A 1
O3' O 0.3331(12) 0.3797(11) 0.1282(2) 0.129(6) Uiso 0.50 1 d PD A 2
O4 O 0.2445(6) 0.3954(8) 0.14157(10) 0.158(4) Uani 1 1 d D A .
C1 C 0.4286(12) 1.0493(12) 0.0469(3) 0.112(4) Uiso 0.67 1 d PD B 1
H1A H 0.4762 1.0588 0.0389 0.134 Uiso 0.67 1 calc PR B 1
H1B H 0.4521 1.0703 0.0589 0.134 Uiso 0.67 1 calc PR B 1
C2 C 0.3832(16) 1.0973(16) 0.0397(3) 0.137(8) Uiso 0.67 1 d PD B 1
H2A H 0.4177 1.1583 0.0426 0.205 Uiso 0.67 1 calc PR B 1
H2B H 0.3267 1.0737 0.0453 0.205 Uiso 0.67 1 calc PR B 1
H2C H 0.3767 1.0903 0.0269 0.205 Uiso 0.67 1 calc PR B 1
C1' C 0.401(3) 1.0367(14) 0.0590(4) 0.112(4) Uiso 0.33 1 d PD B 2
H1'A H 0.4628 1.0590 0.0608 0.134 Uiso 0.33 1 calc PR B 2
H1'B H 0.3729 1.0224 0.0708 0.134 Uiso 0.33 1 calc PR B 2
C2' C 0.387(2) 1.106(2) 0.0501(5) 0.091(10) Uiso 0.33 1 d PD B 2
H2'A H 0.4381 1.1624 0.0517 0.137 Uiso 0.33 1 calc PR B 2
H2'B H 0.3375 1.1060 0.0554 0.137 Uiso 0.33 1 calc PR B 2
H2'C H 0.3769 1.0939 0.0374 0.137 Uiso 0.33 1 calc PR B 2
C3 C 0.4392(9) 0.8724(9) 0.01828(14) 0.110(4) Uani 1 1 d . B .
H3A H 0.4093 0.9010 0.0133 0.131 Uiso 1 1 calc R . .
H3B H 0.4006 0.8098 0.0173 0.131 Uiso 1 1 calc R . .
C4 C 0.5194(11) 0.8980(13) 0.0080(2) 0.165(7) Uani 1 1 d . . .
H4A H 0.5050 0.8823 -0.0045 0.248 Uiso 1 1 calc R B .
H4B H 0.5481 0.8685 0.0128 0.248 Uiso 1 1 calc R . .
H4C H 0.5575 0.9599 0.0090 0.248 Uiso 1 1 calc R . .
C5 C 0.4027(14) 0.3892(16) 0.1188(4) 0.112(4) Uiso 0.50 1 d PD A 1
H5A H 0.4251 0.4343 0.1280 0.134 Uiso 0.50 1 calc PR A 1
H5B H 0.4363 0.4161 0.1080 0.134 Uiso 0.50 1 calc PR A 1
C6 C 0.4296(19) 0.3245(17) 0.1247(4) 0.131(10) Uiso 0.50 1 d PD A 1
H6A H 0.4877 0.3553 0.1296 0.197 Uiso 0.50 1 calc PR A 1
H6B H 0.4280 0.2901 0.1146 0.197 Uiso 0.50 1 calc PR A 1
H6C H 0.3901 0.2870 0.1339 0.197 Uiso 0.50 1 calc PR A 1
C5' C 0.3590(15) 0.3460(18) 0.1126(3) 0.112(4) Uiso 0.50 1 d PD A 2
H5'A H 0.3542 0.3768 0.1022 0.134 Uiso 0.50 1 calc PR A 2
H5'B H 0.3128 0.2858 0.1113 0.134 Uiso 0.50 1 calc PR A 2
C6' C 0.4434(14) 0.3447(17) 0.1098(4) 0.108(7) Uiso 0.50 1 d PD A 2
H6'A H 0.4415 0.3179 0.0984 0.163 Uiso 0.50 1 calc PR A 2
H6'B H 0.4504 0.3119 0.1194 0.163 Uiso 0.50 1 calc PR A 2
H6'C H 0.4918 0.4034 0.1100 0.163 Uiso 0.50 1 calc PR A 2
C7 C 0.1737(12) 0.4064(13) 0.1483(2) 0.186(8) Uani 1 1 d D . .
H7A H 0.1329 0.3968 0.1386 0.223 Uiso 1 1 calc R A .
H7B H 0.1965 0.4654 0.1528 0.223 Uiso 1 1 calc R . .
C8 C 0.1278(12) 0.3422(9) 0.16327(19) 0.174(8) Uani 1 1 d D A .
H8A H 0.0796 0.3478 0.1675 0.261 Uiso 1 1 calc R . .
H8B H 0.1678 0.3536 0.1731 0.261 Uiso 1 1 calc R . .
H8C H 0.1067 0.2840 0.1588 0.261 Uiso 1 1 calc R . .
O5 O 0.582(3) 0.284(2) 0.0838(6) 0.092(12) Uiso 0.17 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
S4 Ag1 S4 119.560(18) . 3_565
S4 Ag1 S4 119.560(18) . 2_665
S4 Ag1 S4 119.560(19) 3_565 2_665
S4 Ag1 Cl1 93.82(8) . .
S4 Ag1 Cl1 93.82(8) 3_565 .
S4 Ag1 Cl1 93.82(8) 2_665 .
S4 Ag1 Ag2 91.33(8) . 3_565
S4 Ag1 Ag2 50.03(7) 3_565 3_565
S4 Ag1 Ag2 137.67(8) 2_665 3_565
Cl1 Ag1 Ag2 53.10(3) . 3_565
S4 Ag1 Ag2 50.03(7) . .
S4 Ag1 Ag2 137.67(8) 3_565 .
S4 Ag1 Ag2 91.33(8) 2_665 .
Cl1 Ag1 Ag2 53.10(3) . .
Ag2 Ag1 Ag2 87.67(4) 3_565 .
S4 Ag1 Ag2 137.67(8) . 2_665
S4 Ag1 Ag2 91.33(8) 3_565 2_665
S4 Ag1 Ag2 50.03(7) 2_665 2_665
Cl1 Ag1 Ag2 53.10(3) . 2_665
Ag2 Ag1 Ag2 87.67(4) 3_565 2_665
Ag2 Ag1 Ag2 87.67(4) . 2_665
S2 Ag2 S3 124.18(10) . .
S2 Ag2 S4 115.20(11) . .
S3 Ag2 S4 116.56(11) . .
S2 Ag2 Cl1 94.49(9) . .
S3 Ag2 Cl1 99.70(7) . .
S4 Ag2 Cl1 95.81(9) . .
S2 Ag2 Ag3 95.14(6) . .
S3 Ag2 Ag3 50.39(6) . .
S4 Ag2 Ag3 143.42(9) . .
Cl1 Ag2 Ag3 60.16(4) . .
S2 Ag2 Ag1 137.51(7) . .
S3 Ag2 Ag1 93.25(7) . .
S4 Ag2 Ag1 49.04(8) . .
Cl1 Ag2 Ag1 56.38(7) . .
Ag3 Ag2 Ag1 94.85(3) . .
S3 Ag3 S1 124.67(10) . 2_665
S3 Ag3 S2 118.88(10) . 2_665
S1 Ag3 S2 116.36(8) 2_665 2_665
S3 Ag3 Ag2 50.83(7) . .
S1 Ag3 Ag2 91.82(6) 2_665 .
S2 Ag3 Ag2 133.46(7) 2_665 .
S1 Ag4 S1 119.515(15) . 2_665
S1 Ag4 S1 119.515(15) . 3_565
S1 Ag4 S1 119.515(15) 2_665 3_565
S1 Ag4 Cl1 94.01(6) . .
S1 Ag4 Cl1 94.01(6) 2_665 .
S1 Ag4 Cl1 94.01(6) 3_565 .
Ag2 Cl1 Ag2 109.46(7) 3_565 .
Ag2 Cl1 Ag2 109.46(7) 3_565 2_665
Ag2 Cl1 Ag2 109.46(7) . 2_665
Ag2 Cl1 Ag4 109.48(7) 3_565 .
Ag2 Cl1 Ag4 109.48(7) . .
Ag2 Cl1 Ag4 109.48(7) 2_665 .
Ag2 Cl1 Ag1 70.52(7) 3_565 .
Ag2 Cl1 Ag1 70.52(7) . .
Ag2 Cl1 Ag1 70.52(7) 2_665 .
Ag4 Cl1 Ag1 180.0 . .
P1 S1 Ag3 113.49(13) . 3_565
P1 S1 Ag4 100.65(11) . .
Ag3 S1 Ag4 87.01(8) 3_565 .
P1 S2 Ag2 111.16(13) 2_665 .
P1 S2 Ag3 104.61(13) 2_665 3_565
Ag2 S2 Ag3 85.85(8) . 3_565
P2 S3 Ag3 108.53(15) . .
P2 S3 Ag2 109.70(15) . .
Ag3 S3 Ag2 78.78(8) . .
P2 S4 Ag1 110.63(16) 3_565 .
P2 S4 Ag2 110.79(16) 3_565 .
Ag1 S4 Ag2 80.93(9) . .
O1 P1 O2 108.6(4) . .
O1 P1 S1 103.1(3) . .
O2 P1 S1 109.3(3) . .
O1 P1 S2 109.7(3) . 3_565
O2 P1 S2 102.9(3) . 3_565
S1 P1 S2 122.75(15) . 3_565
O4 P2 O3' 78.4(8) . .
O4 P2 O3 103.8(10) . .
O3' P2 O3 37.9(9) . .
O4 P2 S4 110.2(5) . 2_665
O3' P2 S4 106.3(8) . 2_665
O3 P2 S4 121.6(8) . 2_665
O4 P2 S3 109.6(4) . .
O3' P2 S3 120.5(7) . .
O3 P2 S3 85.4(8) . .
S4 P2 S3 122.91(18) 2_665 .
F2 P3 F2 96.7(12) . 2_665
F2 P3 F2 96.7(12) . 3_565
F2 P3 F2 96.7(12) 2_665 3_565
F2 P3 F1 88.8(12) . 2_665
F2 P3 F1 84.7(12) 2_665 2_665
F2 P3 F1 174.2(14) 3_565 2_665
F2 P3 F1 84.7(12) . .
F2 P3 F1 174.2(14) 2_665 .
F2 P3 F1 88.8(12) 3_565 .
F1 P3 F1 89.8(14) 2_665 .
F2 P3 F1 174.2(14) . 3_565
F2 P3 F1 88.8(12) 2_665 3_565
F2 P3 F1 84.7(12) 3_565 3_565
F1 P3 F1 89.8(14) 2_665 3_565
F1 P3 F1 89.8(14) . 3_565
C1 O1 C1' 39.3(15) . .
C1 O1 P1 121.3(8) . .
C1' O1 P1 119.6(12) . .
C3 O2 P1 123.8(7) . .
C5 O3 P2 112.4(15) . .
C5' O3' P2 116.6(14) . .
C7 O4 P2 121.6(9) . .
O1 C1 C2 107.4(16) . .
O1 C1 H1A 110.2 . .
C2 C1 H1A 110.2 . .
O1 C1 H1B 110.2 . .
C2 C1 H1B 110.2 . .
H1A C1 H1B 108.5 . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
O1 C1' C2' 110(2) . .
O1 C1' H1'A 109.6 . .
C2' C1' H1'A 109.6 . .
O1 C1' H1'B 109.6 . .
C2' C1' H1'B 109.6 . .
H1'A C1' H1'B 108.1 . .
C1' C2' H2'A 109.5 . .
C1' C2' H2'B 109.5 . .
H2'A C2' H2'B 109.5 . .
C1' C2' H2'C 109.5 . .
H2'A C2' H2'C 109.5 . .
H2'B C2' H2'C 109.5 . .
O2 C3 C4 110.2(12) . .
O2 C3 H3A 109.6 . .
C4 C3 H3A 109.6 . .
O2 C3 H3B 109.6 . .
C4 C3 H3B 109.6 . .
H3A C3 H3B 108.1 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
O3 C5 C6 127(2) . .
O3 C5 H5A 105.4 . .
C6 C5 H5A 105.4 . .
O3 C5 H5B 105.4 . .
C6 C5 H5B 105.4 . .
H5A C5 H5B 106.0 . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
O3' C5' C6' 128(2) . .
O3' C5' H5'A 105.2 . .
C6' C5' H5'A 105.2 . .
O3' C5' H5'B 105.2 . .
C6' C5' H5'B 105.2 . .
H5'A C5' H5'B 105.9 . .
C5' C6' H6'A 109.5 . .
C5' C6' H6'B 109.5 . .
H6'A C6' H6'B 109.5 . .
C5' C6' H6'C 109.5 . .
H6'A C6' H6'C 109.5 . .
H6'B C6' H6'C 109.5 . .
O4 C7 C8 109.2(12) . .
O4 C7 H7A 109.8 . .
C8 C7 H7A 109.8 . .
O4 C7 H7B 109.8 . .
C8 C7 H7B 109.8 . .
H7A C7 H7B 108.3 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
O5 O5 O5 119.7(8) 16_544 17_554
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 S4 2.509(3) .
Ag1 S4 2.509(3) 3_565
Ag1 S4 2.509(3) 2_665
Ag1 Cl1 2.898(4) .
Ag1 Ag2 3.2813(13) 3_565
Ag1 Ag2 3.2813(13) .
Ag1 Ag2 3.2813(13) 2_665
Ag2 S2 2.515(3) .
Ag2 S3 2.527(3) .
Ag2 S4 2.546(3) .
Ag2 Cl1 2.7834(14) .
Ag2 Ag3 3.1972(12) .
Ag3 S3 2.511(3) .
Ag3 S1 2.517(3) 2_665
Ag3 S2 2.524(3) 2_665
Ag4 S1 2.517(2) .
Ag4 S1 2.517(2) 2_665
Ag4 S1 2.517(2) 3_565
Ag4 Cl1 2.835(4) .
Cl1 Ag2 2.7834(14) 3_565
Cl1 Ag2 2.7834(14) 2_665
S1 P1 1.989(3) .
S1 Ag3 2.517(3) 3_565
S2 P1 2.006(3) 2_665
S2 Ag3 2.524(3) 3_565
S3 P2 1.999(5) .
S4 P2 1.977(5) 3_565
P1 O1 1.569(7) .
P1 O2 1.569(7) .
P1 S2 2.006(3) 3_565
P2 O4 1.564(5) .
P2 O3' 1.577(5) .
P2 O3 1.582(5) .
P2 S4 1.977(5) 2_665
P3 F2 1.423(12) .
P3 F2 1.423(12) 2_665
P3 F2 1.423(12) 3_565
P3 F1 1.482(14) 2_665
P3 F1 1.482(14) .
P3 F1 1.482(14) 3_565
O1 C1 1.46(2) .
O1 C1' 1.494(10) .
O2 C3 1.418(12) .
O3 C5 1.459(10) .
O3' C5' 1.471(10) .
O4 C7 1.450(9) .
C1 C2 1.527(10) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C1' C2' 1.519(10) .
C1' H1'A 0.9700 .
C1' H1'B 0.9700 .
C2' H2'A 0.9600 .
C2' H2'B 0.9600 .
C2' H2'C 0.9600 .
C3 C4 1.466(18) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 C6 1.507(10) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C5' C6' 1.521(10) .
C5' H5'A 0.9700 .
C5' H5'B 0.9700 .
C6' H6'A 0.9600 .
C6' H6'B 0.9600 .
C6' H6'C 0.9600 .
C7 C8 1.499(9) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
O5 O5 1.08(7) 16_544
O5 O5 1.51(8) 17_554
