#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:59:47 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180243 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/29/7112944.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7112944
loop_
_publ_author_name
'Zhang, Zhi-Hui'
'Chen, Sheng-Chun'
'Mi, Jin-Ling'
'He, Ming-Yang'
'Chen, Qun'
'Du, Miao'
_publ_section_title
;
 Unique Zn(II) coordination entanglement networks with a flexible
 fluorinated bis-pyridinecarboxamide tecton and benzenedicarboxylates.
;
_journal_issue                   44
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8427
_journal_page_last               8429
_journal_paper_doi               10.1039/c0cc03173a
_journal_volume                  46
_journal_year                    2010
_chemical_formula_sum            'C28 H19 F5 N4 O7 Zn'
_chemical_formula_weight         683.84
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.683(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.511(4)
_cell_length_b                   11.031(3)
_cell_length_c                   16.949(4)
_cell_measurement_reflns_used    9926
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      27.54
_cell_measurement_theta_min      2.26
_cell_volume                     2848.2(12)
_computing_cell_refinement       'APEX2 and SAINT (Bruker, 2001)'
_computing_data_collection       'APEX2 (Bruker, 2003)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL and DIAMOND (Brandenburg, 2005)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL(Scheldrick, 2008)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0227
_diffrn_reflns_av_sigmaI/netI    0.0200
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            20033
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.26
_exptl_absorpt_coefficient_mu    0.949
_exptl_absorpt_correction_T_max  0.8184
_exptl_absorpt_correction_T_min  0.7770
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2003)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.595
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.300
_refine_diff_density_min         -0.252
_refine_diff_density_rms         0.044
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         5005
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0318
_refine_ls_R_factor_gt           0.0266
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0374P)²+1.2113P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0698
_refine_ls_wR_factor_ref         0.0737
_reflns_number_gt                4421
_reflns_number_total             5005
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0cc03173a.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        2848.4(12)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7112944
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.672471(14) 0.420511(18) 0.776518(13) 0.03516(8) Uani 1 1 d .
C1 C 0.74961(15) 0.59513(18) 0.69140(13) 0.0464(5) Uani 1 1 d .
H1 H 0.7239 0.5442 0.6446 0.056 Uiso 1 1 calc R
C2 C 0.79301(15) 0.69748(19) 0.68189(13) 0.0497(5) Uani 1 1 d .
H2 H 0.7951 0.7159 0.6292 0.060 Uiso 1 1 calc R
C3 C 0.83340(13) 0.77241(17) 0.75155(13) 0.0440(4) Uani 1 1 d .
C4 C 0.82618(15) 0.74321(19) 0.82759(14) 0.0521(5) Uani 1 1 d .
H4 H 0.8516 0.7924 0.8754 0.062 Uiso 1 1 calc R
C5 C 0.78086(14) 0.64024(19) 0.83206(13) 0.0487(5) Uani 1 1 d .
H5 H 0.7764 0.6214 0.8837 0.058 Uiso 1 1 calc R
C6 C 0.88563(15) 0.88430(18) 0.74951(14) 0.0490(5) Uani 1 1 d .
C7 C 0.97806(13) 0.98043(18) 0.68651(14) 0.0483(5) Uani 1 1 d .
H7A H 1.0246 0.9432 0.6733 0.058 Uiso 1 1 calc R
H7B H 1.0045 1.0157 0.7432 0.058 Uiso 1 1 calc R
C8 C 0.93689(12) 1.08051(16) 0.62270(13) 0.0416(4) Uani 1 1 d .
C9 C 0.91689(13) 1.06325(17) 0.53659(13) 0.0432(4) Uani 1 1 d .
C10 C 0.89035(13) 1.15674(18) 0.47877(12) 0.0425(4) Uani 1 1 d .
C11 C 0.88244(12) 1.27395(17) 0.50344(12) 0.0397(4) Uani 1 1 d .
C12 C 0.89741(13) 1.28980(17) 0.58885(13) 0.0445(5) Uani 1 1 d .
C13 C 0.92287(13) 1.19615(18) 0.64656(12) 0.0449(5) Uani 1 1 d .
C14 C 0.85850(13) 1.37777(18) 0.44042(13) 0.0451(5) Uani 1 1 d .
H14A H 0.8919 1.4491 0.4679 0.054 Uiso 1 1 calc R
H14B H 0.8742 1.3569 0.3925 0.054 Uiso 1 1 calc R
C15 C 0.73318(13) 1.50219(17) 0.43391(12) 0.0426(4) Uani 1 1 d .
C16 C 0.63532(13) 1.51574(17) 0.39157(11) 0.0397(4) Uani 1 1 d .
C17 C 0.57798(14) 1.41789(17) 0.36790(13) 0.0445(5) Uani 1 1 d .
H17 H 0.5988 1.3391 0.3813 0.053 Uiso 1 1 calc R
C18 C 0.48965(14) 1.43982(17) 0.32418(13) 0.0446(5) Uani 1 1 d .
H18 H 0.4514 1.3741 0.3084 0.054 Uiso 1 1 calc R
C19 C 0.51220(13) 1.64555(17) 0.32835(13) 0.0457(5) Uani 1 1 d .
H19 H 0.4897 1.7236 0.3153 0.055 Uiso 1 1 calc R
C20 C 0.60092(14) 1.63142(18) 0.37225(14) 0.0473(5) Uani 1 1 d .
H20 H 0.6375 1.6988 0.3888 0.057 Uiso 1 1 calc R
C21 C 0.64376(13) 0.49627(16) 0.91655(12) 0.0397(4) Uani 1 1 d .
C22 C 0.64140(13) 0.48844(16) 1.00444(12) 0.0393(4) Uani 1 1 d .
C23 C 0.66912(13) 0.38466(17) 1.05373(12) 0.0389(4) Uani 1 1 d .
H23 H 0.6916 0.3199 1.0334 0.047 Uiso 1 1 calc R
C24 C 0.66355(13) 0.37684(17) 1.13336(12) 0.0413(4) Uani 1 1 d .
C25 C 0.63116(17) 0.47351(19) 1.16386(13) 0.0546(6) Uani 1 1 d .
H25 H 0.6276 0.4699 1.2173 0.066 Uiso 1 1 calc R
C26 C 0.6043(2) 0.57513(19) 1.11382(15) 0.0630(7) Uani 1 1 d .
C27 C 0.60805(17) 0.58537(18) 1.03473(14) 0.0546(6) Uani 1 1 d .
H27 H 0.5888 0.6553 1.0022 0.065 Uiso 1 1 calc R
C28 C 0.68582(14) 0.25904(18) 1.18117(13) 0.0458(5) Uani 1 1 d .
F1 F 0.92510(9) 0.95075(11) 0.50908(8) 0.0604(3) Uani 1 1 d .
F2 F 0.87368(9) 1.13307(12) 0.39587(8) 0.0591(3) Uani 1 1 d .
F3 F 0.93657(10) 1.21913(12) 0.72883(8) 0.0672(4) Uani 1 1 d .
F4 F 0.88773(10) 1.40139(11) 0.61713(8) 0.0642(4) Uani 1 1 d .
F5 F 0.57146(16) 0.66977(14) 1.14381(11) 0.1121(8) Uani 1 1 d .
N1 N 0.74307(10) 0.56629(13) 0.76537(10) 0.0392(4) Uani 1 1 d .
N2 N 0.91645(11) 0.88695(15) 0.68754(11) 0.0466(4) Uani 1 1 d .
H2A H 0.9133 0.8234 0.6571 0.070 Uiso 1 1 d R
N3 N 0.76546(11) 1.40554(14) 0.40907(10) 0.0441(4) Uani 1 1 d .
H3A H 0.7336 1.3571 0.3696 0.066 Uiso 1 1 d R
N4 N 0.45643(10) 1.55158(14) 0.30336(10) 0.0394(4) Uani 1 1 d .
O1 O 0.89971(14) 0.96356(16) 0.80340(13) 0.0805(6) Uani 1 1 d .
O2 O 0.77727(10) 1.57901(13) 0.48460(11) 0.0596(4) Uani 1 1 d .
O3 O 0.68078(10) 0.40714(12) 0.89470(8) 0.0459(3) Uani 1 1 d .
O4 O 0.61189(11) 0.58472(12) 0.87111(9) 0.0546(4) Uani 1 1 d .
O5 O 0.69958(15) 0.16836(14) 1.14658(12) 0.0780(6) Uani 1 1 d .
O6 O 0.68310(9) 0.25537(12) 1.25580(8) 0.0460(3) Uani 1 1 d .
O7 O 0.05604(12) 0.17058(16) 0.90995(11) 0.0714(5) Uani 1 1 d .
H7AA H 0.1057 0.1492 0.9412 0.107 Uiso 1 1 d R
H7AB H 0.0184 0.1210 0.8834 0.107 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Zn1 O6 97.51(6) . 4_565
O3 Zn1 N1 109.70(6) . .
O6 Zn1 N1 131.32(6) 4_565 .
O3 Zn1 N4 109.31(6) . 3_676
O6 Zn1 N4 99.72(6) 4_565 3_676
N1 Zn1 N4 107.73(6) . 3_676
N1 C1 C2 122.52(19) . .
N1 C1 H1 118.7 . .
C2 C1 H1 118.7 . .
C1 C2 C3 119.36(19) . .
C1 C2 H2 120.3 . .
C3 C2 H2 120.3 . .
C4 C3 C2 118.13(18) . .
C4 C3 C6 117.88(18) . .
C2 C3 C6 123.99(18) . .
C3 C4 C5 119.27(19) . .
C3 C4 H4 120.4 . .
C5 C4 H4 120.4 . .
N1 C5 C4 122.84(18) . .
N1 C5 H5 118.6 . .
C4 C5 H5 118.6 . .
O1 C6 N2 123.6(2) . .
O1 C6 C3 120.86(19) . .
N2 C6 C3 115.47(17) . .
N2 C7 C8 113.78(17) . .
N2 C7 H7A 108.8 . .
C8 C7 H7A 108.8 . .
N2 C7 H7B 108.8 . .
C8 C7 H7B 108.8 . .
H7A C7 H7B 107.7 . .
C9 C8 C13 115.94(17) . .
C9 C8 C7 120.96(18) . .
C13 C8 C7 122.94(19) . .
F1 C9 C10 119.38(18) . .
F1 C9 C8 118.49(17) . .
C10 C9 C8 122.12(18) . .
F2 C10 C9 118.61(18) . .
F2 C10 C11 119.45(17) . .
C9 C10 C11 121.92(18) . .
C10 C11 C12 115.85(17) . .
C10 C11 C14 121.69(18) . .
C12 C11 C14 122.46(18) . .
F4 C12 C13 118.56(18) . .
F4 C12 C11 119.23(17) . .
C13 C12 C11 122.20(18) . .
F3 C13 C12 118.60(18) . .
F3 C13 C8 119.69(18) . .
C12 C13 C8 121.68(19) . .
N3 C14 C11 111.72(16) . .
N3 C14 H14A 109.3 . .
C11 C14 H14A 109.3 . .
N3 C14 H14B 109.3 . .
C11 C14 H14B 109.3 . .
H14A C14 H14B 107.9 . .
O2 C15 N3 124.98(19) . .
O2 C15 C16 120.32(18) . .
N3 C15 C16 114.65(16) . .
C20 C16 C17 118.46(18) . .
C20 C16 C15 118.21(17) . .
C17 C16 C15 123.28(17) . .
C18 C17 C16 118.73(17) . .
C18 C17 H17 120.6 . .
C16 C17 H17 120.6 . .
N4 C18 C17 122.92(18) . .
N4 C18 H18 118.5 . .
C17 C18 H18 118.5 . .
N4 C19 C20 122.85(18) . .
N4 C19 H19 118.6 . .
C20 C19 H19 118.6 . .
C19 C20 C16 119.21(18) . .
C19 C20 H20 120.4 . .
C16 C20 H20 120.4 . .
O4 C21 O3 124.27(17) . .
O4 C21 C22 119.79(17) . .
O3 C21 C22 115.93(16) . .
C23 C22 C27 119.91(17) . .
C23 C22 C21 120.95(16) . .
C27 C22 C21 119.10(17) . .
C22 C23 C24 120.40(17) . .
C22 C23 H23 119.8 . .
C24 C23 H23 119.8 . .
C25 C24 C23 119.73(18) . .
C25 C24 C28 121.11(17) . .
C23 C24 C28 118.94(17) . .
C26 C25 C24 118.66(18) . .
C26 C25 H25 120.7 . .
C24 C25 H25 120.7 . .
F5 C26 C27 118.47(19) . .
F5 C26 C25 118.44(19) . .
C27 C26 C25 123.09(19) . .
C26 C27 C22 118.19(19) . .
C26 C27 H27 120.9 . .
C22 C27 H27 120.9 . .
O5 C28 O6 121.98(18) . .
O5 C28 C24 120.08(18) . .
O6 C28 C24 117.73(18) . .
C5 N1 C1 117.85(17) . .
C5 N1 Zn1 120.01(13) . .
C1 N1 Zn1 122.05(13) . .
C6 N2 C7 120.45(18) . .
C6 N2 H2A 120.1 . .
C7 N2 H2A 116.9 . .
C15 N3 C14 123.35(17) . .
C15 N3 H3A 123.0 . .
C14 N3 H3A 113.4 . .
C18 N4 C19 117.79(17) . .
C18 N4 Zn1 121.68(13) . 3_676
C19 N4 Zn1 120.11(13) . 3_676
C21 O3 Zn1 112.54(12) . .
C28 O6 Zn1 104.09(12) . 4_566
H7AA O7 H7AB 121.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O3 1.9598(14) .
Zn1 O6 1.9916(14) 4_565
Zn1 N1 2.0373(16) .
Zn1 N4 2.0579(16) 3_676
C1 N1 1.338(3) .
C1 C2 1.380(3) .
C1 H1 0.9300 .
C2 C3 1.384(3) .
C2 H2 0.9300 .
C3 C4 1.378(3) .
C3 C6 1.514(3) .
C4 C5 1.378(3) .
C4 H4 0.9300 .
C5 N1 1.337(3) .
C5 H5 0.9300 .
C6 O1 1.220(3) .
C6 N2 1.333(3) .
C7 N2 1.453(2) .
C7 C8 1.511(3) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C9 1.380(3) .
C8 C13 1.384(3) .
C9 F1 1.351(2) .
C9 C10 1.373(3) .
C10 F2 1.349(2) .
C10 C11 1.381(3) .
C11 C12 1.383(3) .
C11 C14 1.511(3) .
C12 F4 1.353(2) .
C12 C13 1.373(3) .
C13 F3 1.348(2) .
C14 N3 1.451(3) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 O2 1.226(2) .
C15 N3 1.331(3) .
C15 C16 1.501(3) .
C16 C20 1.384(3) .
C16 C17 1.389(3) .
C17 C18 1.379(3) .
C17 H17 0.9300 .
C18 N4 1.340(2) .
C18 H18 0.9300 .
C19 N4 1.342(2) .
C19 C20 1.372(3) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 O4 1.229(2) .
C21 O3 1.285(2) .
C21 C22 1.508(2) .
C22 C23 1.387(3) .
C22 C27 1.389(3) .
C23 C24 1.390(3) .
C23 H23 0.9300 .
C24 C25 1.380(3) .
C24 C28 1.500(3) .
C25 C26 1.372(3) .
C25 H25 0.9300 .
C26 F5 1.362(2) .
C26 C27 1.371(3) .
C27 H27 0.9300 .
C28 O5 1.224(3) .
C28 O6 1.284(2) .
N2 H2A 0.8599 .
N3 H3A 0.8599 .
N4 Zn1 2.0579(16) 3_676
O6 Zn1 1.9916(14) 4_566
O7 H7AA 0.8201 .
O7 H7AB 0.8201 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 1.6(3) . .
C1 C2 C3 C4 -1.9(3) . .
C1 C2 C3 C6 177.6(2) . .
C2 C3 C4 C5 1.2(3) . .
C6 C3 C4 C5 -178.4(2) . .
C3 C4 C5 N1 0.0(3) . .
C4 C3 C6 O1 -20.1(3) . .
C2 C3 C6 O1 160.3(2) . .
C4 C3 C6 N2 157.8(2) . .
C2 C3 C6 N2 -21.8(3) . .
N2 C7 C8 C9 -77.1(3) . .
N2 C7 C8 C13 107.8(2) . .
C13 C8 C9 F1 -176.74(18) . .
C7 C8 C9 F1 7.8(3) . .
C13 C8 C9 C10 4.2(3) . .
C7 C8 C9 C10 -171.25(18) . .
F1 C9 C10 F2 -0.3(3) . .
C8 C9 C10 F2 178.68(18) . .
F1 C9 C10 C11 -178.73(18) . .
C8 C9 C10 C11 0.3(3) . .
F2 C10 C11 C12 177.63(17) . .
C9 C10 C11 C12 -4.0(3) . .
F2 C10 C11 C14 -2.1(3) . .
C9 C10 C11 C14 176.26(18) . .
C10 C11 C12 F4 -177.62(18) . .
C14 C11 C12 F4 2.1(3) . .
C10 C11 C12 C13 3.2(3) . .
C14 C11 C12 C13 -177.09(19) . .
F4 C12 C13 F3 0.4(3) . .
C11 C12 C13 F3 179.68(18) . .
F4 C12 C13 C8 -177.82(18) . .
C11 C12 C13 C8 1.4(3) . .
C9 C8 C13 F3 176.69(18) . .
C7 C8 C13 F3 -7.9(3) . .
C9 C8 C13 C12 -5.1(3) . .
C7 C8 C13 C12 170.34(19) . .
C10 C11 C14 N3 97.5(2) . .
C12 C11 C14 N3 -82.3(2) . .
O2 C15 C16 C20 33.9(3) . .
N3 C15 C16 C20 -143.61(19) . .
O2 C15 C16 C17 -148.7(2) . .
N3 C15 C16 C17 33.8(3) . .
C20 C16 C17 C18 1.7(3) . .
C15 C16 C17 C18 -175.67(19) . .
C16 C17 C18 N4 0.0(3) . .
N4 C19 C20 C16 0.4(3) . .
C17 C16 C20 C19 -1.9(3) . .
C15 C16 C20 C19 175.59(19) . .
O4 C21 C22 C23 173.70(19) . .
O3 C21 C22 C23 -6.8(3) . .
O4 C21 C22 C27 -4.1(3) . .
O3 C21 C22 C27 175.5(2) . .
C27 C22 C23 C24 0.2(3) . .
C21 C22 C23 C24 -177.58(18) . .
C22 C23 C24 C25 -0.7(3) . .
C22 C23 C24 C28 174.09(19) . .
C23 C24 C25 C26 0.7(4) . .
C28 C24 C25 C26 -174.0(2) . .
C24 C25 C26 F5 179.3(2) . .
C24 C25 C26 C27 0.0(4) . .
F5 C26 C27 C22 -179.9(2) . .
C25 C26 C27 C22 -0.5(4) . .
C23 C22 C27 C26 0.5(4) . .
C21 C22 C27 C26 178.3(2) . .
C25 C24 C28 O5 167.2(2) . .
C23 C24 C28 O5 -7.6(3) . .
C25 C24 C28 O6 -7.6(3) . .
C23 C24 C28 O6 177.64(18) . .
C4 C5 N1 C1 -0.5(3) . .
C4 C5 N1 Zn1 -177.08(17) . .
C2 C1 N1 C5 -0.4(3) . .
C2 C1 N1 Zn1 176.19(17) . .
O3 Zn1 N1 C5 -4.58(17) . .
O6 Zn1 N1 C5 -124.56(15) 4_565 .
N4 Zn1 N1 C5 114.31(16) 3_676 .
O3 Zn1 N1 C1 178.93(15) . .
O6 Zn1 N1 C1 58.96(18) 4_565 .
N4 Zn1 N1 C1 -62.17(17) 3_676 .
O1 C6 N2 C7 7.0(4) . .
C3 C6 N2 C7 -170.90(18) . .
C8 C7 N2 C6 -102.7(2) . .
O2 C15 N3 C14 0.9(3) . .
C16 C15 N3 C14 178.24(17) . .
C11 C14 N3 C15 105.5(2) . .
C17 C18 N4 C19 -1.6(3) . .
C17 C18 N4 Zn1 171.04(16) . 3_676
C20 C19 N4 C18 1.4(3) . .
C20 C19 N4 Zn1 -171.37(16) . 3_676
O4 C21 O3 Zn1 -4.8(3) . .
C22 C21 O3 Zn1 175.71(13) . .
O6 Zn1 O3 C21 -155.02(13) 4_565 .
N1 Zn1 O3 C21 66.00(14) . .
N4 Zn1 O3 C21 -51.92(14) 3_676 .
O5 C28 O6 Zn1 -14.8(3) . 4_566
C24 C28 O6 Zn1 159.84(15) . 4_566
