#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:19:44 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180257 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/43/7114342.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7114342
loop_
_publ_author_name
'Petrov, Viacheslav A.'
'Marshall, William J.'
'Grushin, Vladimir V.'
_publ_section_title
;
 The first perfluoroacetylacetonate metal complexes: as unexpectedly
 robust as tricky to makeElectronic supplementary information (ESI)
 available: details of the preparation of the complexes, analytical, NMR
 spectroscopical, and crystallographic data. See:
 http://www.rsc.org/suppdata/cc/b1/b111249j/
;
_journal_issue                   5
_journal_name_full               'Chemical Communications'
_journal_page_first              520
_journal_paper_doi               10.1039/b111249j
_journal_year                    2002
_chemical_formula_sum            'C38 H20 Eu2 F20 N4 O8'
_chemical_formula_weight         1344.50
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.000(10)
_cell_angle_beta                 90.000(10)
_cell_angle_gamma                90.000(10)
_cell_formula_units_Z            8
_cell_length_a                   22.2956(10)
_cell_length_b                   18.0122(8)
_cell_length_c                   21.9719(10)
_cell_measurement_temperature    173(2)
_cell_volume                     8823.8(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0842
_diffrn_reflns_av_sigmaI/netI    0.0838
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            55115
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         1.45
_exptl_absorpt_coefficient_mu    2.957
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.024
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelpiped
_exptl_crystal_F_000             5168
_exptl_crystal_size_max          .20
_exptl_crystal_size_mid          .04
_exptl_crystal_size_min          .04
_refine_diff_density_max         1.282
_refine_diff_density_min         -0.687
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.863
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     682
_refine_ls_number_reflns         10706
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.863
_refine_ls_R_factor_all          0.0795
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0285P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0658
_refine_ls_wR_factor_ref         0.0731
_reflns_number_gt                6749
_reflns_number_total             10706
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b111249j.txt
_cod_data_source_block           00063
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      Pbcn
_cod_database_code               7114342
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x, -y, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, -z'
'-x, y, -z-1/2'
'x-1/2, y-1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu -0.042522(9) 0.161498(13) 0.327466(9) 0.02293(6) Uani 1 1 d .
Eu2 Eu 0.059696(9) 0.011724(13) 0.313474(10) 0.02726(6) Uani 1 1 d .
F1 F 0.05001(9) 0.14027(13) 0.27983(9) 0.0238(5) Uani 1 1 d .
F2 F 0.01731(10) 0.08637(14) 0.38687(11) 0.0324(6) Uani 1 1 d .
F3 F -0.04136(9) 0.03261(13) 0.29179(10) 0.0244(5) Uani 1 1 d .
F7 F 0.031(2) 0.4191(6) 0.2978(9) 0.123(10) Uani 0.50 1 d P
F8 F 0.0508(5) 0.4254(7) 0.248(3) 0.142(9) Uani 0.50 1 d P
F9 F 0.0286(15) 0.4264(6) 0.2060(11) 0.078(4) Uani 0.50 1 d P
F11 F -0.17951(13) 0.32316(18) 0.43666(14) 0.0611(9) Uani 1 1 d .
F12 F -0.13088(14) 0.42126(18) 0.41303(14) 0.0641(9) Uani 1 1 d .
F13 F -0.12160(13) 0.37418(18) 0.50209(13) 0.0608(9) Uani 1 1 d .
F14 F -0.01175(12) 0.40518(16) 0.45277(13) 0.0497(8) Uani 1 1 d .
F15 F 0.09695(15) 0.4094(2) 0.39946(19) 0.0896(12) Uani 1 1 d .
F16 F 0.13835(13) 0.3056(2) 0.38883(17) 0.0809(12) Uani 1 1 d .
F17 F 0.10749(14) 0.3402(2) 0.47530(14) 0.0878(13) Uani 1 1 d .
F31 F 0.21935(14) -0.1398(2) 0.39375(17) 0.0830(12) Uani 1 1 d .
F32 F 0.16980(16) -0.2386(2) 0.37448(15) 0.0794(11) Uani 1 1 d .
F33 F 0.17806(15) -0.19985(19) 0.46638(14) 0.0727(10) Uani 1 1 d .
F34 F 0.06074(14) -0.23089(17) 0.44491(13) 0.0619(9) Uani 1 1 d .
F35 F -0.04747(16) -0.1765(3) 0.49398(16) 0.1061(15) Uani 1 1 d .
F36 F -0.10083(15) -0.1317(2) 0.42321(17) 0.0857(12) Uani 1 1 d .
F37 F -0.05919(17) -0.2347(2) 0.4109(2) 0.1000(14) Uani 1 1 d .
F41 F -0.024(3) -0.2454(9) 0.3017(10) 0.184(11) Uani 0.50 1 d P
F42 F 0.0277(13) -0.2540(6) 0.2927(11) 0.094(4) Uani 0.50 1 d P
F43 F 0.0555(8) -0.2522(8) 0.247(2) 0.139(6) Uani 0.50 1 d P
O1 O -0.08891(13) 0.24708(17) 0.39744(13) 0.0321(8) Uani 1 1 d .
O2 O 0.03494(12) 0.24187(18) 0.37699(13) 0.0319(8) Uani 1 1 d .
O6 O -0.04142(12) 0.28230(16) 0.27951(12) 0.0286(7) Uani 1 1 d .
O31 O 0.12029(14) -0.07003(19) 0.37419(14) 0.0408(9) Uani 1 1 d .
O32 O -0.00434(14) -0.06885(18) 0.38233(14) 0.0402(9) Uani 1 1 d .
O36 O 0.04693(15) -0.10926(19) 0.26998(15) 0.0438(9) Uani 1 1 d .
N11 N -0.12093(17) 0.0937(2) 0.39306(16) 0.0352(10) Uani 1 1 d .
N12 N -0.15231(15) 0.1772(2) 0.29549(16) 0.0324(10) Uani 1 1 d .
N41 N 0.15206(16) 0.0792(2) 0.35450(18) 0.0369(10) Uani 1 1 d .
N42 N 0.15846(17) -0.0101(2) 0.25533(18) 0.0423(11) Uani 1 1 d .
C1 C -0.1278(2) 0.3566(3) 0.4433(2) 0.0448(14) Uani 1 1 d .
C2 C -0.0755(2) 0.3083(3) 0.41949(18) 0.0328(11) Uani 1 1 d .
C3 C -0.0177(2) 0.3379(3) 0.42493(19) 0.0326(11) Uani 1 1 d .
C4 C 0.0341(2) 0.3026(3) 0.40464(19) 0.0304(11) Uani 1 1 d .
C5 C 0.0945(2) 0.3402(3) 0.4171(2) 0.0419(13) Uani 1 1 d .
C6 C 0.0000 0.3120(4) 0.2500 0.0275(15) Uani 1 2 d S
C7 C 0.0000 0.3966(4) 0.2500 0.045(2) Uani 1 2 d S
C12 C -0.1062(3) 0.0512(3) 0.4401(2) 0.0459(14) Uani 1 1 d .
H12A H -0.0658 0.0414 0.4469 0.055 Uiso 1 1 calc R
C13 C -0.1484(3) 0.0205(3) 0.4799(2) 0.0672(19) Uani 1 1 d .
H13A H -0.1364 -0.0092 0.5123 0.081 Uiso 1 1 calc R
C14 C -0.2074(3) 0.0355(4) 0.4699(3) 0.069(2) Uani 1 1 d .
H14A H -0.2361 0.0158 0.4961 0.083 Uiso 1 1 calc R
C15 C -0.2255(3) 0.0791(4) 0.4220(3) 0.0591(17) Uani 1 1 d .
C16 C -0.1804(2) 0.1075(3) 0.3837(2) 0.0417(13) Uani 1 1 d .
C17 C -0.2862(3) 0.0961(4) 0.4085(3) 0.079(2) Uani 1 1 d .
H17A H -0.3160 0.0778 0.4340 0.095 Uiso 1 1 calc R
C18 C -0.3023(3) 0.1367(4) 0.3612(3) 0.077(2) Uani 1 1 d .
H18A H -0.3428 0.1456 0.3541 0.092 Uiso 1 1 calc R
C19 C -0.2582(2) 0.1675(4) 0.3203(3) 0.0572(17) Uani 1 1 d .
C20 C -0.19735(19) 0.1517(3) 0.3320(2) 0.0386(13) Uani 1 1 d .
C21 C -0.2709(2) 0.2100(4) 0.2696(3) 0.066(2) Uani 1 1 d .
H21A H -0.3107 0.2208 0.2602 0.079 Uiso 1 1 calc R
C22 C -0.2263(2) 0.2367(3) 0.2329(2) 0.0562(17) Uani 1 1 d .
H22A H -0.2351 0.2663 0.1993 0.067 Uiso 1 1 calc R
C23 C -0.1674(2) 0.2183(3) 0.2472(2) 0.0392(13) Uani 1 1 d .
H23A H -0.1369 0.2355 0.2220 0.047 Uiso 1 1 calc R
C31 C 0.1712(3) -0.1770(4) 0.4092(3) 0.0573(16) Uani 1 1 d .
C32 C 0.1136(2) -0.1316(3) 0.3997(2) 0.0395(13) Uani 1 1 d .
C33 C 0.0601(2) -0.1623(3) 0.4175(2) 0.0429(13) Uani 1 1 d .
C34 C 0.0043(2) -0.1294(3) 0.4089(2) 0.0398(13) Uani 1 1 d .
C35 C -0.0512(3) -0.1682(3) 0.4350(3) 0.0515(15) Uani 1 1 d .
C36 C 0.0000 -0.1392(4) 0.2500 0.045(2) Uani 1 2 d S
C37 C 0.0000 -0.2237(5) 0.2500 0.067(3) Uani 1 2 d S
C42 C 0.1493(2) 0.1254(3) 0.4017(2) 0.0455(14) Uani 1 1 d .
H42A H 0.1116 0.1412 0.4144 0.055 Uiso 1 1 calc R
C43 C 0.1996(2) 0.1518(3) 0.4335(3) 0.0570(17) Uani 1 1 d .
H43A H 0.1953 0.1838 0.4664 0.068 Uiso 1 1 calc R
C44 C 0.2541(3) 0.1292(4) 0.4148(3) 0.0603(17) Uani 1 1 d .
H44A H 0.2879 0.1455 0.4357 0.072 Uiso 1 1 calc R
C45 C 0.2612(2) 0.0821(3) 0.3650(3) 0.0527(16) Uani 1 1 d .
C46 C 0.2072(2) 0.0574(3) 0.3355(2) 0.0440(14) Uani 1 1 d .
C47 C 0.3163(3) 0.0565(5) 0.3406(3) 0.084(2) Uani 1 1 d .
H47A H 0.3516 0.0703 0.3601 0.101 Uiso 1 1 calc R
C48 C 0.3203(2) 0.0141(4) 0.2916(3) 0.079(2) Uani 1 1 d .
H48A H 0.3579 -0.0001 0.2775 0.095 Uiso 1 1 calc R
C49 C 0.2674(3) -0.0102(4) 0.2600(3) 0.067(2) Uani 1 1 d .
C50 C 0.2108(2) 0.0117(3) 0.2832(2) 0.0443(14) Uani 1 1 d .
C51 C 0.2682(3) -0.0553(4) 0.2084(3) 0.081(2) Uani 1 1 d .
H51A H 0.3047 -0.0720 0.1930 0.097 Uiso 1 1 calc R
C52 C 0.2165(3) -0.0749(4) 0.1804(3) 0.072(2) Uani 1 1 d .
H52A H 0.2172 -0.1038 0.1454 0.086 Uiso 1 1 calc R
C53 C 0.1611(2) -0.0505(3) 0.2055(2) 0.0512(15) Uani 1 1 d .
H53A H 0.1255 -0.0636 0.1860 0.061 Uiso 1 1 calc R
O60 O 0.05712(16) 0.5900(2) 0.1932(2) 0.0507(10) Uani 1 1 d .
O61 O -0.04284(15) 0.5861(2) 0.18696(16) 0.0501(10) Uani 1 1 d .
C60 C 0.0077(3) 0.5866(3) 0.1633(3) 0.0459(14) Uani 1 1 d .
C61 C 0.0138(2) 0.5847(3) 0.0956(3) 0.0641(17) Uani 1 1 d .
H61A H -0.0253 0.5822 0.0774 0.096 Uiso 1 1 calc R
H61B H 0.0367 0.5418 0.0840 0.096 Uiso 1 1 calc R
H61C H 0.0340 0.6288 0.0820 0.096 Uiso 1 1 calc R
H60D H 0.051(3) 0.586(4) 0.230(3) 0.12(3) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
F2 Eu1 F1 69.38(8) . .
F2 Eu1 F1 120.27(8) . 7_556
F1 Eu1 F1 66.16(8) . 7_556
F2 Eu1 O1 105.22(9) . .
F1 Eu1 O1 140.04(9) . .
F1 Eu1 O1 134.45(9) 7_556 .
F2 Eu1 O6 140.28(9) . .
F1 Eu1 O6 86.75(9) . .
F1 Eu1 O6 73.46(8) 7_556 .
O1 Eu1 O6 72.95(10) . .
F2 Eu1 F3 67.60(8) . .
F1 Eu1 F3 72.15(7) . .
F1 Eu1 F3 62.26(7) 7_556 .
O1 Eu1 F3 144.54(9) . .
O6 Eu1 F3 135.49(8) . .
F2 Eu1 O2 72.18(9) . .
F1 Eu1 O2 71.41(9) . .
F1 Eu1 O2 124.66(8) 7_556 .
O1 Eu1 O2 69.44(10) . .
O6 Eu1 O2 70.24(10) . .
F3 Eu1 O2 132.83(8) . .
F2 Eu1 N12 140.61(11) . .
F1 Eu1 N12 137.40(9) . .
F1 Eu1 N12 71.40(9) 7_556 .
O1 Eu1 N12 72.21(11) . .
O6 Eu1 N12 77.93(11) . .
F3 Eu1 N12 91.54(10) . .
O2 Eu1 N12 135.62(11) . .
F2 Eu1 N11 78.32(11) . .
F1 Eu1 N11 140.38(11) . .
F1 Eu1 N11 115.36(10) 7_556 .
O1 Eu1 N11 69.80(11) . .
O6 Eu1 N11 132.67(11) . .
F3 Eu1 N11 74.75(10) . .
O2 Eu1 N11 119.98(10) . .
N12 Eu1 N11 63.70(12) . .
F2 Eu1 Eu2 39.68(6) . .
F1 Eu1 Eu2 43.24(6) . .
F1 Eu1 Eu2 80.67(5) 7_556 .
O1 Eu1 Eu2 144.87(7) . .
O6 Eu1 Eu2 129.84(7) . .
F3 Eu1 Eu2 40.93(5) . .
O2 Eu1 Eu2 91.96(7) . .
N12 Eu1 Eu2 132.41(8) . .
N11 Eu1 Eu2 97.14(9) . .
F2 Eu1 Eu1 102.30(6) . 7_556
F1 Eu1 Eu1 35.11(5) . 7_556
F1 Eu1 Eu1 34.27(5) 7_556 7_556
O1 Eu1 Eu1 140.00(7) . 7_556
O6 Eu1 Eu1 67.31(7) . 7_556
F3 Eu1 Eu1 73.47(5) . 7_556
O2 Eu1 Eu1 92.53(7) . 7_556
N12 Eu1 Eu1 103.02(8) . 7_556
N11 Eu1 Eu1 145.06(8) . 7_556
Eu2 Eu1 Eu1 67.134(10) . 7_556
F2 Eu1 Eu2 95.44(6) . 7_556
F1 Eu1 Eu2 68.89(5) . 7_556
F1 Eu1 Eu2 31.77(5) 7_556 7_556
O1 Eu1 Eu2 149.02(7) . 7_556
O6 Eu1 Eu2 105.21(7) . 7_556
F3 Eu1 Eu2 30.82(5) . 7_556
O2 Eu1 Eu2 140.25(7) . 7_556
N12 Eu1 Eu2 77.15(8) . 7_556
N11 Eu1 Eu2 92.71(8) . 7_556
Eu2 Eu1 Eu2 59.790(10) . 7_556
Eu1 Eu1 Eu2 52.357(8) 7_556 7_556
F2 Eu2 F3 69.67(8) . .
F2 Eu2 F3 121.21(8) . 7_556
F3 Eu2 F3 67.05(9) . 7_556
F2 Eu2 O36 139.60(10) . .
F3 Eu2 O36 87.16(10) . .
F3 Eu2 O36 74.67(9) 7_556 .
F2 Eu2 O31 101.53(10) . .
F3 Eu2 O31 139.03(9) . .
F3 Eu2 O31 137.17(9) 7_556 .
O36 Eu2 O31 74.39(11) . .
F2 Eu2 F1 67.77(8) . .
F3 Eu2 F1 72.53(7) . .
F3 Eu2 F1 62.62(7) 7_556 .
O36 Eu2 F1 137.02(9) . .
O31 Eu2 F1 143.08(10) . .
F2 Eu2 O32 71.66(10) . .
F3 Eu2 O32 70.76(9) . .
F3 Eu2 O32 125.01(9) 7_556 .
O36 Eu2 O32 69.56(11) . .
O31 Eu2 O32 68.57(10) . .
F1 Eu2 O32 132.36(9) . .
F2 Eu2 N41 78.82(11) . .
F3 Eu2 N41 140.67(11) . .
F3 Eu2 N41 113.97(10) 7_556 .
O36 Eu2 N41 131.97(12) . .
O31 Eu2 N41 69.05(12) . .
F1 Eu2 N41 74.15(10) . .
O32 Eu2 N41 121.02(11) . .
F2 Eu2 N42 141.95(12) . .
F3 Eu2 N42 138.48(10) . .
F3 Eu2 N42 71.87(10) 7_556 .
O36 Eu2 N42 76.39(13) . .
O31 Eu2 N42 72.60(11) . .
F1 Eu2 N42 94.04(10) . .
O32 Eu2 N42 133.59(12) . .
N41 Eu2 N42 63.82(14) . .
F2 Eu2 Eu1 39.73(6) . .
F3 Eu2 Eu1 43.47(6) . .
F3 Eu2 Eu1 81.57(5) 7_556 .
O36 Eu2 Eu1 130.56(8) . .
O31 Eu2 Eu1 141.23(8) . .
F1 Eu2 Eu1 41.17(5) . .
O32 Eu2 Eu1 91.25(7) . .
N41 Eu2 Eu1 97.22(9) . .
N42 Eu2 Eu1 135.15(9) . .
F2 Eu2 Eu2 102.90(6) . 7_556
F3 Eu2 Eu2 35.48(5) . 7_556
F3 Eu2 Eu2 34.70(5) 7_556 7_556
O36 Eu2 Eu2 68.26(8) . 7_556
O31 Eu2 Eu2 142.17(8) . 7_556
F1 Eu2 Eu2 73.72(5) . 7_556
O32 Eu2 Eu2 92.46(7) . 7_556
N41 Eu2 Eu2 144.25(8) . 7_556
N42 Eu2 Eu2 103.38(9) . 7_556
Eu1 Eu2 Eu2 67.597(10) . 7_556
F2 Eu2 Eu1 96.07(6) . 7_556
F3 Eu2 Eu1 69.61(5) . 7_556
F3 Eu2 Eu1 31.86(6) 7_556 7_556
O36 Eu2 Eu1 106.52(8) . 7_556
O31 Eu2 Eu1 150.44(8) . 7_556
F1 Eu2 Eu1 31.10(5) . 7_556
O32 Eu2 Eu1 140.33(7) . 7_556
N41 Eu2 Eu1 91.64(8) . 7_556
N42 Eu2 Eu1 78.88(9) . 7_556
Eu1 Eu2 Eu1 60.508(10) . 7_556
Eu2 Eu2 Eu1 52.609(9) 7_556 7_556
Eu1 F1 Eu1 110.62(8) . 7_556
Eu1 F1 Eu2 95.59(8) . .
Eu1 F1 Eu2 117.13(9) 7_556 .
Eu2 F2 Eu1 100.59(9) . .
Eu2 F3 Eu2 109.81(8) . 7_556
Eu2 F3 Eu1 95.60(8) . .
Eu2 F3 Eu1 117.32(9) 7_556 .
F8 F7 C7 59.2(10) . .
F8 F7 F9 107.4(16) . 7_556
C7 F7 F9 57.3(7) . 7_556
F9 F8 F7 129.8(18) . .
F9 F8 C7 67.2(11) . .
F7 F8 C7 65.7(10) . .
F8 F9 C7 64.1(11) . .
F8 F9 F7 121.7(14) . 7_556
C7 F9 F7 60.7(6) . 7_556
F42 F41 F43 113(3) . 7_556
F42 F41 C37 59.9(13) . .
F43 F41 C37 62.2(12) 7_556 .
F41 F42 F43 130.6(19) . .
F41 F42 C37 65.5(12) . .
F43 F42 C37 66.9(9) . .
F42 F43 F41 115(3) . 7_556
F42 F43 C37 58.9(12) . .
F41 F43 C37 60.0(14) 7_556 .
C2 O1 Eu1 135.5(3) . .
C4 O2 Eu1 135.0(3) . .
C6 O6 Eu1 128.2(3) . .
C32 O31 Eu2 136.4(3) . .
C34 O32 Eu2 133.6(3) . .
C36 O36 Eu2 129.0(4) . .
C12 N11 C16 117.6(4) . .
C12 N11 Eu1 122.8(3) . .
C16 N11 Eu1 119.3(3) . .
C23 N12 C20 117.9(4) . .
C23 N12 Eu1 121.3(3) . .
C20 N12 Eu1 120.3(3) . .
C42 N41 C46 117.5(4) . .
C42 N41 Eu2 122.3(3) . .
C46 N41 Eu2 119.0(4) . .
C53 N42 C50 119.4(4) . .
C53 N42 Eu2 122.3(4) . .
C50 N42 Eu2 117.5(3) . .
F11 C1 F13 107.8(4) . .
F11 C1 F12 107.4(4) . .
F13 C1 F12 106.1(4) . .
F11 C1 C2 111.7(4) . .
F13 C1 C2 112.5(4) . .
F12 C1 C2 111.1(4) . .
O1 C2 C3 126.4(4) . .
O1 C2 C1 116.7(4) . .
C3 C2 C1 116.9(4) . .
F14 C3 C4 117.9(4) . .
F14 C3 C2 117.7(4) . .
C4 C3 C2 124.3(4) . .
O2 C4 C3 124.5(4) . .
O2 C4 C5 117.4(4) . .
C3 C4 C5 118.1(4) . .
F15 C5 F17 106.2(5) . .
F15 C5 F16 106.3(4) . .
F17 C5 F16 107.3(5) . .
F15 C5 C4 113.9(5) . .
F17 C5 C4 111.6(4) . .
F16 C5 C4 111.1(4) . .
O6 C6 O6 129.3(6) . 7_556
O6 C6 C7 115.3(3) . .
O6 C6 C7 115.3(3) 7_556 .
F8 C7 F8 130.9(14) 7_556 .
F8 C7 F9 48.7(12) 7_556 7_556
F8 C7 F9 108.1(10) . 7_556
F8 C7 F9 108.1(10) 7_556 .
F8 C7 F9 48.7(12) . .
F9 C7 F9 130.3(12) 7_556 .
F8 C7 F7 108.4(10) 7_556 .
F8 C7 F7 55.1(11) . .
F9 C7 F7 62.1(7) 7_556 .
F9 C7 F7 102.1(7) . .
F8 C7 F7 55.1(11) 7_556 7_556
F8 C7 F7 108.4(10) . 7_556
F9 C7 F7 102.1(7) 7_556 7_556
F9 C7 F7 62.1(7) . 7_556
F7 C7 F7 144.2(12) . 7_556
F8 C7 C6 114.6(7) 7_556 .
F8 C7 C6 114.6(7) . .
F9 C7 C6 114.9(6) 7_556 .
F9 C7 C6 114.8(6) . .
F7 C7 C6 107.9(6) . .
F7 C7 C6 107.9(6) 7_556 .
N11 C12 C13 123.3(5) . .
C14 C13 C12 118.1(6) . .
C13 C14 C15 121.4(5) . .
C14 C15 C16 117.2(6) . .
C14 C15 C17 124.3(6) . .
C16 C15 C17 118.5(6) . .
N11 C16 C15 122.5(5) . .
N11 C16 C20 118.4(4) . .
C15 C16 C20 119.1(5) . .
C18 C17 C15 122.9(6) . .
C17 C18 C19 121.3(6) . .
C21 C19 C20 117.2(5) . .
C21 C19 C18 125.2(5) . .
C20 C19 C18 117.6(6) . .
N12 C20 C19 122.2(5) . .
N12 C20 C16 117.2(4) . .
C19 C20 C16 120.6(5) . .
C22 C21 C19 121.4(5) . .
C21 C22 C23 118.0(5) . .
N12 C23 C22 123.3(5) . .
F31 C31 F33 108.0(5) . .
F31 C31 F32 107.0(5) . .
F33 C31 F32 106.4(5) . .
F31 C31 C32 112.2(5) . .
F33 C31 C32 112.9(5) . .
F32 C31 C32 110.0(5) . .
O31 C32 C33 126.0(5) . .
O31 C32 C31 115.6(5) . .
C33 C32 C31 118.3(5) . .
C32 C33 F34 118.5(4) . .
C32 C33 C34 124.6(5) . .
F34 C33 C34 116.8(5) . .
O32 C34 C33 124.9(5) . .
O32 C34 C35 116.5(5) . .
C33 C34 C35 118.6(5) . .
F35 C35 F36 107.9(5) . .
F35 C35 F37 107.6(5) . .
F36 C35 F37 105.1(5) . .
F35 C35 C34 111.8(5) . .
F36 C35 C34 112.3(5) . .
F37 C35 C34 111.8(5) . .
O36 C36 O36 129.1(7) . 7_556
O36 C36 C37 115.4(4) . .
O36 C36 C37 115.4(4) 7_556 .
F42 C37 F42 128.1(14) . 7_556
F42 C37 F41 54.6(14) . .
F42 C37 F41 108.6(10) 7_556 .
F42 C37 F41 108.6(10) . 7_556
F42 C37 F41 54.6(14) 7_556 7_556
F41 C37 F41 145.4(19) . 7_556
F42 C37 F43 104.4(8) . 7_556
F42 C37 F43 54.2(10) 7_556 7_556
F41 C37 F43 57.8(10) . 7_556
F41 C37 F43 107.7(11) 7_556 7_556
F42 C37 F43 54.2(10) . .
F42 C37 F43 104.4(8) 7_556 .
F41 C37 F43 107.7(11) . .
F41 C37 F43 57.8(10) 7_556 .
F43 C37 F43 134.9(18) 7_556 .
F42 C37 C36 116.0(7) . .
F42 C37 C36 116.0(7) 7_556 .
F41 C37 C36 107.3(10) . .
F41 C37 C36 107.3(10) 7_556 .
F43 C37 C36 112.5(9) 7_556 .
F43 C37 C36 112.5(9) . .
N41 C42 C43 124.2(5) . .
C44 C43 C42 117.8(6) . .
C43 C44 C45 121.8(5) . .
C44 C45 C47 126.4(6) . .
C44 C45 C46 116.5(5) . .
C47 C45 C46 117.0(6) . .
N41 C46 C50 118.0(4) . .
N41 C46 C45 122.1(5) . .
C50 C46 C45 119.9(5) . .
C48 C47 C45 123.7(6) . .
C47 C48 C49 120.8(6) . .
C51 C49 C50 117.8(6) . .
C51 C49 C48 123.9(6) . .
C50 C49 C48 118.2(6) . .
N42 C50 C49 121.1(6) . .
N42 C50 C46 118.6(4) . .
C49 C50 C46 120.3(5) . .
C52 C51 C49 120.5(6) . .
C51 C52 C53 119.1(6) . .
N42 C53 C52 122.0(6) . .
O61 C60 O60 124.5(5) . .
O61 C60 C61 120.0(5) . .
O60 C60 C61 115.5(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 F2 2.305(2) .
Eu1 F1 2.345(2) .
Eu1 F1 2.394(2) 7_556
Eu1 O1 2.410(3) .
Eu1 O6 2.418(3) .
Eu1 F3 2.450(2) .
Eu1 O2 2.503(3) .
Eu1 N12 2.562(3) .
Eu1 N11 2.574(4) .
Eu1 Eu2 3.5449(5) .
Eu1 Eu1 3.8967(5) 7_556
Eu1 Eu2 4.1248(5) 7_556
Eu2 F2 2.302(2) .
Eu2 F3 2.333(2) .
Eu2 F3 2.379(2) 7_556
Eu2 O36 2.396(3) .
Eu2 O31 2.403(3) .
Eu2 F1 2.440(2) .
Eu2 O32 2.536(3) .
Eu2 N41 2.555(4) .
Eu2 N42 2.576(4) .
Eu2 Eu2 3.8556(6) 7_556
Eu2 Eu1 4.1249(5) 7_556
F1 Eu1 2.394(2) 7_556
F3 Eu2 2.379(2) 7_556
F7 F8 1.19(3) .
F7 C7 1.322(13) .
F7 F9 1.340(19) 7_556
F8 F9 1.04(2) .
F8 C7 1.246(11) .
F9 C7 1.276(10) .
F9 F7 1.340(19) 7_556
F11 C1 1.309(6) .
F12 C1 1.343(6) .
F13 C1 1.338(5) .
F14 C3 1.365(5) .
F15 C5 1.308(6) .
F16 C5 1.315(6) .
F17 C5 1.311(5) .
F31 C31 1.310(7) .
F32 C31 1.347(6) .
F33 C31 1.331(6) .
F34 C33 1.375(5) .
F35 C35 1.308(6) .
F36 C35 1.312(6) .
F37 C35 1.322(6) .
F41 F42 1.18(3) .
F41 F43 1.28(2) 7_556
F41 C37 1.313(17) .
F42 F43 1.18(2) .
F42 C37 1.249(13) .
F43 F41 1.28(2) 7_556
F43 C37 1.341(17) .
O1 C2 1.242(5) .
O2 C4 1.252(5) .
O6 C6 1.248(4) .
O31 C32 1.251(5) .
O32 C34 1.253(5) .
O36 C36 1.257(4) .
N11 C12 1.327(6) .
N11 C16 1.365(6) .
N12 C23 1.336(6) .
N12 C20 1.365(5) .
N41 C42 1.330(6) .
N41 C46 1.356(6) .
N42 C53 1.317(6) .
N42 C50 1.375(6) .
C1 C2 1.545(6) .
C2 C3 1.399(6) .
C3 C4 1.392(6) .
C4 C5 1.531(6) .
C6 O6 1.248(4) 7_556
C6 C7 1.525(9) .
C7 F8 1.246(11) 7_556
C7 F9 1.276(10) 7_556
C7 F7 1.322(13) 7_556
C12 C13 1.399(7) .
C13 C14 1.361(8) .
C14 C15 1.374(8) .
C15 C16 1.408(7) .
C15 C17 1.419(8) .
C16 C20 1.437(7) .
C17 C18 1.320(9) .
C18 C19 1.442(8) .
C19 C21 1.381(8) .
C19 C20 1.411(6) .
C21 C22 1.368(7) .
C22 C23 1.391(6) .
C31 C32 1.536(7) .
C32 C33 1.372(7) .
C33 C34 1.389(6) .
C34 C35 1.533(7) .
C36 O36 1.257(4) 7_556
C36 C37 1.521(11) .
C37 F42 1.249(13) 7_556
C37 F41 1.313(17) 7_556
C37 F43 1.341(17) 7_556
C42 C43 1.405(6) .
C43 C44 1.346(7) .
C44 C45 1.393(8) .
C45 C47 1.417(8) .
C45 C46 1.437(7) .
C46 C50 1.417(7) .
C47 C48 1.322(9) .
C48 C49 1.438(9) .
C49 C51 1.396(9) .
C49 C50 1.415(7) .
C51 C52 1.353(9) .
C52 C53 1.422(7) .
O60 C60 1.285(6) .
O61 C60 1.240(6) .
C60 C61 1.494(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
F1 Eu1 Eu2 F2 118.47(12) . .
F1 Eu1 Eu2 F2 -176.57(10) 7_556 .
O1 Eu1 Eu2 F2 2.81(15) . .
O6 Eu1 Eu2 F2 124.28(12) . .
F3 Eu1 Eu2 F2 -118.62(12) . .
O2 Eu1 Eu2 F2 58.61(11) . .
N12 Eu1 Eu2 F2 -122.57(14) . .
N11 Eu1 Eu2 F2 -61.93(12) . .
Eu1 Eu1 Eu2 F2 150.53(9) 7_556 .
Eu2 Eu1 Eu2 F2 -150.90(9) 7_556 .
F2 Eu1 Eu2 F3 118.62(12) . .
F1 Eu1 Eu2 F3 -122.91(11) . .
F1 Eu1 Eu2 F3 -57.95(9) 7_556 .
O1 Eu1 Eu2 F3 121.43(15) . .
O6 Eu1 Eu2 F3 -117.10(11) . .
O2 Eu1 Eu2 F3 177.23(10) . .
N12 Eu1 Eu2 F3 -3.95(13) . .
N11 Eu1 Eu2 F3 56.69(11) . .
Eu1 Eu1 Eu2 F3 -90.85(8) 7_556 .
Eu2 Eu1 Eu2 F3 -32.28(8) 7_556 .
F2 Eu1 Eu2 F3 -176.01(10) . 7_556
F1 Eu1 Eu2 F3 -57.54(9) . 7_556
F1 Eu1 Eu2 F3 7.42(7) 7_556 7_556
O1 Eu1 Eu2 F3 -173.20(14) . 7_556
O6 Eu1 Eu2 F3 -51.73(10) . 7_556
F3 Eu1 Eu2 F3 65.37(9) . 7_556
O2 Eu1 Eu2 F3 -117.40(9) . 7_556
N12 Eu1 Eu2 F3 61.42(12) . 7_556
N11 Eu1 Eu2 F3 122.06(10) . 7_556
Eu1 Eu1 Eu2 F3 -25.48(5) 7_556 7_556
Eu2 Eu1 Eu2 F3 33.09(5) 7_556 7_556
F2 Eu1 Eu2 O36 122.58(14) . .
F1 Eu1 Eu2 O36 -118.95(13) . .
F1 Eu1 Eu2 O36 -53.99(11) 7_556 .
O1 Eu1 Eu2 O36 125.39(16) . .
O6 Eu1 Eu2 O36 -113.14(13) . .
F3 Eu1 Eu2 O36 3.96(13) . .
O2 Eu1 Eu2 O36 -178.81(12) . .
N12 Eu1 Eu2 O36 0.01(15) . .
N11 Eu1 Eu2 O36 60.65(13) . .
Eu1 Eu1 Eu2 O36 -86.90(10) 7_556 .
Eu2 Eu1 Eu2 O36 -28.32(10) 7_556 .
F2 Eu1 Eu2 O31 2.57(15) . .
F1 Eu1 Eu2 O31 121.04(15) . .
F1 Eu1 Eu2 O31 -174.00(14) 7_556 .
O1 Eu1 Eu2 O31 5.37(18) . .
O6 Eu1 Eu2 O31 126.85(15) . .
F3 Eu1 Eu2 O31 -116.05(15) . .
O2 Eu1 Eu2 O31 61.18(14) . .
N12 Eu1 Eu2 O31 -120.00(17) . .
N11 Eu1 Eu2 O31 -59.36(15) . .
Eu1 Eu1 Eu2 O31 153.09(13) 7_556 .
Eu2 Eu1 Eu2 O31 -148.34(13) 7_556 .
F2 Eu1 Eu2 F1 -118.47(12) . .
F1 Eu1 Eu2 F1 64.96(9) 7_556 .
O1 Eu1 Eu2 F1 -115.67(14) . .
O6 Eu1 Eu2 F1 5.81(11) . .
F3 Eu1 Eu2 F1 122.91(11) . .
O2 Eu1 Eu2 F1 -59.86(10) . .
N12 Eu1 Eu2 F1 118.95(14) . .
N11 Eu1 Eu2 F1 179.60(11) . .
Eu1 Eu1 Eu2 F1 32.05(7) 7_556 .
Eu2 Eu1 Eu2 F1 90.62(7) 7_556 .
F2 Eu1 Eu2 O32 58.76(12) . .
F1 Eu1 Eu2 O32 177.23(10) . .
F1 Eu1 Eu2 O32 -117.81(9) 7_556 .
O1 Eu1 Eu2 O32 61.56(15) . .
O6 Eu1 Eu2 O32 -176.96(11) . .
F3 Eu1 Eu2 O32 -59.86(10) . .
O2 Eu1 Eu2 O32 117.37(10) . .
N12 Eu1 Eu2 O32 -63.81(13) . .
N11 Eu1 Eu2 O32 -3.17(11) . .
Eu1 Eu1 Eu2 O32 -150.72(7) 7_556 .
Eu2 Eu1 Eu2 O32 -92.15(7) 7_556 .
F2 Eu1 Eu2 N41 -62.73(12) . .
F1 Eu1 Eu2 N41 55.75(11) . .
F1 Eu1 Eu2 N41 120.70(10) 7_556 .
O1 Eu1 Eu2 N41 -59.92(15) . .
O6 Eu1 Eu2 N41 61.56(12) . .
F3 Eu1 Eu2 N41 178.65(11) . .
O2 Eu1 Eu2 N41 -4.12(11) . .
N12 Eu1 Eu2 N41 174.70(14) . .
N11 Eu1 Eu2 N41 -124.66(12) . .
Eu1 Eu1 Eu2 N41 87.80(9) 7_556 .
Eu2 Eu1 Eu2 N41 146.37(9) 7_556 .
F2 Eu1 Eu2 N42 -122.51(17) . .
F1 Eu1 Eu2 N42 -4.04(16) . .
F1 Eu1 Eu2 N42 60.92(15) 7_556 .
O1 Eu1 Eu2 N42 -119.70(19) . .
O6 Eu1 Eu2 N42 1.77(16) . .
F3 Eu1 Eu2 N42 118.87(16) . .
O2 Eu1 Eu2 N42 -63.90(16) . .
N12 Eu1 Eu2 N42 114.92(18) . .
N11 Eu1 Eu2 N42 175.56(16) . .
Eu1 Eu1 Eu2 N42 28.02(14) 7_556 .
Eu2 Eu1 Eu2 N42 86.59(14) 7_556 .
F2 Eu1 Eu2 Eu2 150.90(9) . 7_556
F1 Eu1 Eu2 Eu2 -90.62(7) . 7_556
F1 Eu1 Eu2 Eu2 -25.67(5) 7_556 7_556
O1 Eu1 Eu2 Eu2 153.71(13) . 7_556
O6 Eu1 Eu2 Eu2 -84.81(9) . 7_556
F3 Eu1 Eu2 Eu2 32.28(8) . 7_556
O2 Eu1 Eu2 Eu2 -150.48(7) . 7_556
N12 Eu1 Eu2 Eu2 28.33(11) . 7_556
N11 Eu1 Eu2 Eu2 88.98(8) . 7_556
Eu1 Eu1 Eu2 Eu2 -58.571(8) 7_556 7_556
F2 Eu1 Eu2 Eu1 -150.53(9) . 7_556
F1 Eu1 Eu2 Eu1 -32.05(7) . 7_556
F1 Eu1 Eu2 Eu1 32.91(5) 7_556 7_556
O1 Eu1 Eu2 Eu1 -147.72(13) . 7_556
O6 Eu1 Eu2 Eu1 -26.24(9) . 7_556
F3 Eu1 Eu2 Eu1 90.85(8) . 7_556
O2 Eu1 Eu2 Eu1 -91.91(7) . 7_556
N12 Eu1 Eu2 Eu1 86.90(11) . 7_556
N11 Eu1 Eu2 Eu1 147.55(8) . 7_556
Eu2 Eu1 Eu2 Eu1 58.571(8) 7_556 7_556
F2 Eu1 F1 Eu1 158.60(12) . 7_556
F1 Eu1 F1 Eu1 19.56(11) 7_556 7_556
O1 Eu1 F1 Eu1 -112.10(13) . 7_556
O6 Eu1 F1 Eu1 -53.77(10) . 7_556
F3 Eu1 F1 Eu1 86.46(9) . 7_556
O2 Eu1 F1 Eu1 -124.01(12) . 7_556
N12 Eu1 F1 Eu1 14.43(19) . 7_556
N11 Eu1 F1 Eu1 121.13(15) . 7_556
Eu2 Eu1 F1 Eu1 121.76(12) . 7_556
Eu2 Eu1 F1 Eu1 53.90(7) 7_556 7_556
F2 Eu1 F1 Eu2 36.84(7) . .
F1 Eu1 F1 Eu2 -102.20(5) 7_556 .
O1 Eu1 F1 Eu2 126.14(13) . .
O6 Eu1 F1 Eu2 -175.53(8) . .
F3 Eu1 F1 Eu2 -35.30(7) . .
O2 Eu1 F1 Eu2 114.23(10) . .
N12 Eu1 F1 Eu2 -107.33(15) . .
N11 Eu1 F1 Eu2 -0.63(17) . .
Eu1 Eu1 F1 Eu2 -121.76(12) 7_556 .
Eu2 Eu1 F1 Eu2 -67.86(5) 7_556 .
F2 Eu2 F1 Eu1 -37.37(7) . .
F3 Eu2 F1 Eu1 37.27(7) . .
F3 Eu2 F1 Eu1 109.97(9) 7_556 .
O36 Eu2 F1 Eu1 102.82(13) . .
O31 Eu2 F1 Eu1 -116.74(14) . .
O32 Eu2 F1 Eu1 -3.75(14) . .
N41 Eu2 F1 Eu1 -121.53(12) . .
N42 Eu2 F1 Eu1 177.15(11) . .
Eu2 Eu2 F1 Eu1 74.38(5) 7_556 .
Eu1 Eu2 F1 Eu1 116.59(11) 7_556 .
F2 Eu2 F1 Eu1 -153.97(11) . 7_556
F3 Eu2 F1 Eu1 -79.33(9) . 7_556
F3 Eu2 F1 Eu1 -6.63(8) 7_556 7_556
O36 Eu2 F1 Eu1 -13.77(17) . 7_556
O31 Eu2 F1 Eu1 126.67(14) . 7_556
O32 Eu2 F1 Eu1 -120.34(12) . 7_556
N41 Eu2 F1 Eu1 121.88(13) . 7_556
N42 Eu2 F1 Eu1 60.55(13) . 7_556
Eu1 Eu2 F1 Eu1 -116.59(11) . 7_556
Eu2 Eu2 F1 Eu1 -42.21(7) 7_556 7_556
F3 Eu2 F2 Eu1 -40.09(8) . .
F3 Eu2 F2 Eu1 4.61(12) 7_556 .
O36 Eu2 F2 Eu1 -98.97(16) . .
O31 Eu2 F2 Eu1 -178.36(10) . .
F1 Eu2 F2 Eu1 38.69(8) . .
O32 Eu2 F2 Eu1 -115.78(11) . .
N41 Eu2 F2 Eu1 115.99(11) . .
N42 Eu2 F2 Eu1 105.21(16) . .
Eu2 Eu2 F2 Eu1 -27.47(8) 7_556 .
Eu1 Eu2 F2 Eu1 25.51(7) 7_556 .
F1 Eu1 F2 Eu2 -40.05(8) . .
F1 Eu1 F2 Eu2 3.92(12) 7_556 .
O1 Eu1 F2 Eu2 -178.33(9) . .
O6 Eu1 F2 Eu2 -96.84(14) . .
F3 Eu1 F2 Eu2 38.46(8) . .
O2 Eu1 F2 Eu2 -116.34(10) . .
N12 Eu1 F2 Eu2 101.32(15) . .
N11 Eu1 F2 Eu2 116.62(11) . .
Eu1 Eu1 F2 Eu2 -27.65(8) 7_556 .
Eu2 Eu1 F2 Eu2 24.97(7) 7_556 .
F2 Eu2 F3 Eu2 158.46(12) . 7_556
F3 Eu2 F3 Eu2 19.26(11) 7_556 7_556
O36 Eu2 F3 Eu2 -55.28(11) . 7_556
O31 Eu2 F3 Eu2 -117.38(14) . 7_556
F1 Eu2 F3 Eu2 86.30(9) . 7_556
O32 Eu2 F3 Eu2 -124.61(12) . 7_556
N41 Eu2 F3 Eu2 119.60(15) . 7_556
N42 Eu2 F3 Eu2 10.4(2) . 7_556
Eu1 Eu2 F3 Eu2 121.71(12) . 7_556
Eu1 Eu2 F3 Eu2 53.51(7) 7_556 7_556
F2 Eu2 F3 Eu1 36.75(8) . .
F3 Eu2 F3 Eu1 -102.44(5) 7_556 .
O36 Eu2 F3 Eu1 -176.99(10) . .
O31 Eu2 F3 Eu1 120.91(14) . .
F1 Eu2 F3 Eu1 -35.41(7) . .
O32 Eu2 F3 Eu1 113.69(10) . .
N41 Eu2 F3 Eu1 -2.11(18) . .
N42 Eu2 F3 Eu1 -111.28(16) . .
Eu2 Eu2 F3 Eu1 -121.71(12) 7_556 .
Eu1 Eu2 F3 Eu1 -68.20(5) 7_556 .
F2 Eu1 F3 Eu2 -37.32(8) . .
F1 Eu1 F3 Eu2 37.18(7) . .
F1 Eu1 F3 Eu2 109.09(9) 7_556 .
O1 Eu1 F3 Eu2 -122.20(14) . .
O6 Eu1 F3 Eu2 102.81(12) . .
O2 Eu1 F3 Eu2 -3.77(14) . .
N12 Eu1 F3 Eu2 177.08(10) . .
N11 Eu1 F3 Eu2 -120.74(11) . .
Eu1 Eu1 F3 Eu2 73.96(6) 7_556 .
Eu2 Eu1 F3 Eu2 115.72(12) 7_556 .
F2 Eu1 F3 Eu2 -153.04(12) . 7_556
F1 Eu1 F3 Eu2 -78.55(9) . 7_556
F1 Eu1 F3 Eu2 -6.63(8) 7_556 7_556
O1 Eu1 F3 Eu2 122.08(14) . 7_556
O6 Eu1 F3 Eu2 -12.91(16) . 7_556
O2 Eu1 F3 Eu2 -119.49(12) . 7_556
N12 Eu1 F3 Eu2 61.36(12) . 7_556
N11 Eu1 F3 Eu2 123.54(13) . 7_556
Eu2 Eu1 F3 Eu2 -115.72(12) . 7_556
Eu1 Eu1 F3 Eu2 -41.77(7) 7_556 7_556
C7 F7 F8 F9 21.3(18) . .
F9 F7 F8 F9 -11(2) 7_556 .
F9 F7 F8 C7 -32.1(9) 7_556 .
F7 F8 F9 C7 -21.1(18) . .
F7 F8 F9 F7 -1(3) . 7_556
C7 F8 F9 F7 20.1(14) . 7_556
F43 F41 F42 F43 18(3) 7_556 .
C37 F41 F42 F43 -16.4(18) . .
F43 F41 F42 C37 34.4(14) 7_556 .
F41 F42 F43 F41 -6(3) . 7_556
C37 F42 F43 F41 -22.3(16) . 7_556
F41 F42 F43 C37 16.2(17) . .
F2 Eu1 O1 C2 87.8(4) . .
F1 Eu1 O1 C2 11.9(5) . .
F1 Eu1 O1 C2 -94.9(4) 7_556 .
O6 Eu1 O1 C2 -50.9(4) . .
F3 Eu1 O1 C2 160.4(4) . .
O2 Eu1 O1 C2 23.9(4) . .
N12 Eu1 O1 C2 -133.3(4) . .
N11 Eu1 O1 C2 158.9(4) . .
Eu2 Eu1 O1 C2 85.9(4) . .
Eu1 Eu1 O1 C2 -44.1(5) 7_556 .
Eu2 Eu1 O1 C2 -142.1(4) 7_556 .
F2 Eu1 O2 C4 -133.4(4) . .
F1 Eu1 O2 C4 152.9(4) . .
F1 Eu1 O2 C4 111.6(4) 7_556 .
O1 Eu1 O2 C4 -18.9(4) . .
O6 Eu1 O2 C4 59.7(4) . .
F3 Eu1 O2 C4 -165.9(4) . .
N12 Eu1 O2 C4 12.9(5) . .
N11 Eu1 O2 C4 -69.0(4) . .
Eu2 Eu1 O2 C4 -168.4(4) . .
Eu1 Eu1 O2 C4 124.4(4) 7_556 .
Eu2 Eu1 O2 C4 149.9(3) 7_556 .
F2 Eu1 O6 C6 44.4(3) . .
F1 Eu1 O6 C6 -7.3(3) . .
F1 Eu1 O6 C6 -73.4(3) 7_556 .
O1 Eu1 O6 C6 137.8(3) . .
F3 Eu1 O6 C6 -67.6(3) . .
O2 Eu1 O6 C6 64.1(3) . .
N12 Eu1 O6 C6 -147.3(3) . .
N11 Eu1 O6 C6 177.1(2) . .
Eu2 Eu1 O6 C6 -11.3(3) . .
Eu1 Eu1 O6 C6 -37.5(3) 7_556 .
Eu2 Eu1 O6 C6 -74.4(3) 7_556 .
F2 Eu2 O31 C32 90.9(5) . .
F3 Eu2 O31 C32 18.7(5) . .
F3 Eu2 O31 C32 -92.9(5) 7_556 .
O36 Eu2 O31 C32 -47.7(5) . .
F1 Eu2 O31 C32 159.1(4) . .
O32 Eu2 O31 C32 26.0(4) . .
N41 Eu2 O31 C32 164.0(5) . .
N42 Eu2 O31 C32 -128.0(5) . .
Eu1 Eu2 O31 C32 89.2(5) . .
Eu2 Eu2 O31 C32 -38.5(5) 7_556 .
Eu1 Eu2 O31 C32 -143.8(4) 7_556 .
F2 Eu2 O32 C34 -132.3(5) . .
F3 Eu2 O32 C34 153.5(5) . .
F3 Eu2 O32 C34 112.0(4) 7_556 .
O36 Eu2 O32 C34 59.3(4) . .
O31 Eu2 O32 C34 -21.4(4) . .
F1 Eu2 O32 C34 -165.0(4) . .
N41 Eu2 O32 C34 -68.2(5) . .
N42 Eu2 O32 C34 13.8(5) . .
Eu1 Eu2 O32 C34 -167.4(4) . .
Eu2 Eu2 O32 C34 124.9(4) 7_556 .
Eu1 Eu2 O32 C34 150.7(4) 7_556 .
F2 Eu2 O36 C36 49.8(4) . .
F3 Eu2 O36 C36 -3.7(3) . .
F3 Eu2 O36 C36 -70.6(3) 7_556 .
O31 Eu2 O36 C36 139.3(3) . .
F1 Eu2 O36 C36 -64.1(3) . .
O32 Eu2 O36 C36 66.8(3) . .
N41 Eu2 O36 C36 -179.3(3) . .
N42 Eu2 O36 C36 -145.2(3) . .
Eu1 Eu2 O36 C36 -6.4(4) . .
Eu2 Eu2 O36 C36 -34.6(3) 7_556 .
Eu1 Eu2 O36 C36 -71.4(3) 7_556 .
F2 Eu1 N11 C12 9.1(4) . .
F1 Eu1 N11 C12 44.6(4) . .
F1 Eu1 N11 C12 127.2(3) 7_556 .
O1 Eu1 N11 C12 -102.1(4) . .
O6 Eu1 N11 C12 -142.3(3) . .
F3 Eu1 N11 C12 78.8(4) . .
O2 Eu1 N11 C12 -52.2(4) . .
N12 Eu1 N11 C12 178.3(4) . .
Eu2 Eu1 N11 C12 44.2(4) . .
Eu1 Eu1 N11 C12 103.9(4) 7_556 .
Eu2 Eu1 N11 C12 104.1(4) 7_556 .
F2 Eu1 N11 C16 -177.9(3) . .
F1 Eu1 N11 C16 -142.3(3) . .
F1 Eu1 N11 C16 -59.7(3) 7_556 .
O1 Eu1 N11 C16 70.9(3) . .
O6 Eu1 N11 C16 30.7(4) . .
F3 Eu1 N11 C16 -108.2(3) . .
O2 Eu1 N11 C16 120.8(3) . .
N12 Eu1 N11 C16 -8.6(3) . .
Eu2 Eu1 N11 C16 -142.8(3) . .
Eu1 Eu1 N11 C16 -83.1(4) 7_556 .
Eu2 Eu1 N11 C16 -82.9(3) 7_556 .
F2 Eu1 N12 C23 -163.1(3) . .
F1 Eu1 N12 C23 -42.8(4) . .
F1 Eu1 N12 C23 -47.7(3) 7_556 .
O1 Eu1 N12 C23 104.4(4) . .
O6 Eu1 N12 C23 28.7(3) . .
F3 Eu1 N12 C23 -107.7(3) . .
O2 Eu1 N12 C23 73.2(4) . .
N11 Eu1 N12 C23 -179.8(4) . .
Eu2 Eu1 N12 C23 -105.1(3) . .
Eu1 Eu1 N12 C23 -34.3(4) 7_556 .
Eu2 Eu1 N12 C23 -80.2(3) 7_556 .
F2 Eu1 N12 C20 25.5(4) . .
F1 Eu1 N12 C20 145.9(3) . .
F1 Eu1 N12 C20 140.9(4) 7_556 .
O1 Eu1 N12 C20 -67.0(3) . .
O6 Eu1 N12 C20 -142.7(4) . .
F3 Eu1 N12 C20 80.9(3) . .
O2 Eu1 N12 C20 -98.2(4) . .
N11 Eu1 N12 C20 8.8(3) . .
Eu2 Eu1 N12 C20 83.5(3) . .
Eu1 Eu1 N12 C20 154.3(3) 7_556 .
Eu2 Eu1 N12 C20 108.4(3) 7_556 .
F2 Eu2 N41 C42 4.8(3) . .
F3 Eu2 N41 C42 41.6(4) . .
F3 Eu2 N41 C42 124.1(3) 7_556 .
O36 Eu2 N41 C42 -145.3(3) . .
O31 Eu2 N41 C42 -102.3(4) . .
F1 Eu2 N41 C42 74.6(4) . .
O32 Eu2 N41 C42 -55.7(4) . .
N42 Eu2 N41 C42 177.4(4) . .
Eu1 Eu2 N41 C42 40.2(4) . .
Eu2 Eu2 N41 C42 101.4(4) 7_556 .
Eu1 Eu2 N41 C42 100.6(4) 7_556 .
F2 Eu2 N41 C46 172.2(3) . .
F3 Eu2 N41 C46 -150.9(3) . .
F3 Eu2 N41 C46 -68.4(3) 7_556 .
O36 Eu2 N41 C46 22.2(4) . .
O31 Eu2 N41 C46 65.2(3) . .
F1 Eu2 N41 C46 -117.9(3) . .
O32 Eu2 N41 C46 111.8(3) . .
N42 Eu2 N41 C46 -15.1(3) . .
Eu1 Eu2 N41 C46 -152.4(3) . .
Eu2 Eu2 N41 C46 -91.2(3) 7_556 .
Eu1 Eu2 N41 C46 -91.9(3) 7_556 .
F2 Eu2 N42 C53 -164.8(3) . .
F3 Eu2 N42 C53 -38.4(5) . .
F3 Eu2 N42 C53 -47.0(4) 7_556 .
O36 Eu2 N42 C53 31.1(4) . .
O31 Eu2 N42 C53 108.7(4) . .
F1 Eu2 N42 C53 -106.4(4) . .
O32 Eu2 N42 C53 74.5(4) . .
N41 Eu2 N42 C53 -176.6(4) . .
Eu1 Eu2 N42 C53 -103.8(4) . .
Eu2 Eu2 N42 C53 -32.2(4) 7_556 .
Eu1 Eu2 N42 C53 -79.1(4) 7_556 .
F2 Eu2 N42 C50 25.5(4) . .
F3 Eu2 N42 C50 151.9(3) . .
F3 Eu2 N42 C50 143.3(4) 7_556 .
O36 Eu2 N42 C50 -138.6(4) . .
O31 Eu2 N42 C50 -61.0(3) . .
F1 Eu2 N42 C50 83.9(3) . .
O32 Eu2 N42 C50 -95.2(4) . .
N41 Eu2 N42 C50 13.7(3) . .
Eu1 Eu2 N42 C50 86.5(3) . .
Eu2 Eu2 N42 C50 158.1(3) 7_556 .
Eu1 Eu2 N42 C50 111.2(3) 7_556 .
Eu1 O1 C2 C3 -22.5(7) . .
Eu1 O1 C2 C1 157.5(3) . .
F11 C1 C2 O1 0.9(6) . .
F13 C1 C2 O1 122.3(5) . .
F12 C1 C2 O1 -119.0(5) . .
F11 C1 C2 C3 -179.1(4) . .
F13 C1 C2 C3 -57.7(6) . .
F12 C1 C2 C3 61.1(6) . .
O1 C2 C3 F14 -177.4(4) . .
C1 C2 C3 F14 2.5(6) . .
O1 C2 C3 C4 1.6(7) . .
C1 C2 C3 C4 -178.5(4) . .
Eu1 O2 C4 C3 12.2(7) . .
Eu1 O2 C4 C5 -168.2(3) . .
F14 C3 C4 O2 -178.0(4) . .
C2 C3 C4 O2 3.0(7) . .
F14 C3 C4 C5 2.4(6) . .
C2 C3 C4 C5 -176.6(4) . .
O2 C4 C5 F15 128.3(5) . .
C3 C4 C5 F15 -52.0(6) . .
O2 C4 C5 F17 -111.4(5) . .
C3 C4 C5 F17 68.3(6) . .
O2 C4 C5 F16 8.3(6) . .
C3 C4 C5 F16 -172.0(4) . .
Eu1 O6 C6 O6 26.54(17) . 7_556
Eu1 O6 C6 C7 -153.47(17) . .
F9 F8 C7 F8 -77.7(11) . 7_556
F7 F8 C7 F8 84.7(8) . 7_556
F9 F8 C7 F9 -128.2(14) . 7_556
F7 F8 C7 F9 34.1(13) . 7_556
F7 F8 C7 F9 162.3(16) . .
F9 F8 C7 F7 -162.3(16) . .
F9 F8 C7 F7 -18.2(13) . 7_556
F7 F8 C7 F7 144.1(13) . 7_556
F9 F8 C7 C6 102.3(11) . .
F7 F8 C7 C6 -95.3(8) . .
F8 F9 C7 F8 129.0(17) . 7_556
F7 F9 C7 F8 -31.4(13) 7_556 7_556
F7 F9 C7 F8 -160.4(14) 7_556 .
F8 F9 C7 F9 78.3(10) . 7_556
F7 F9 C7 F9 -82.1(7) 7_556 7_556
F8 F9 C7 F7 14.7(13) . .
F7 F9 C7 F7 -145.6(12) 7_556 .
F8 F9 C7 F7 160.4(14) . 7_556
F8 F9 C7 C6 -101.7(10) . .
F7 F9 C7 C6 97.9(7) 7_556 .
F8 F7 C7 F8 -127.5(15) . 7_556
F9 F7 C7 F8 15.4(11) 7_556 7_556
F9 F7 C7 F8 142.9(13) 7_556 .
F8 F7 C7 F9 -142.9(13) . 7_556
F8 F7 C7 F9 -13.5(13) . .
F9 F7 C7 F9 129.4(12) 7_556 .
F8 F7 C7 F7 -72.1(10) . 7_556
F9 F7 C7 F7 70.8(7) 7_556 7_556
F8 F7 C7 C6 107.9(10) . .
F9 F7 C7 C6 -109.2(7) 7_556 .
O6 C6 C7 F8 -32(3) . 7_556
O6 C6 C7 F8 148(3) 7_556 7_556
O6 C6 C7 F8 148(3) . .
O6 C6 C7 F8 -32(3) 7_556 .
O6 C6 C7 F9 22(2) . 7_556
O6 C6 C7 F9 -159(2) 7_556 7_556
O6 C6 C7 F9 -158(2) . .
O6 C6 C7 F9 22(2) 7_556 .
O6 C6 C7 F7 88(2) . .
O6 C6 C7 F7 -92(2) 7_556 .
O6 C6 C7 F7 -92(2) . 7_556
O6 C6 C7 F7 88(2) 7_556 7_556
C16 N11 C12 C13 -0.2(7) . .
Eu1 N11 C12 C13 173.0(4) . .
N11 C12 C13 C14 -0.3(9) . .
C12 C13 C14 C15 0.3(10) . .
C13 C14 C15 C16 0.1(9) . .
C13 C14 C15 C17 179.1(6) . .
C12 N11 C16 C15 0.6(7) . .
Eu1 N11 C16 C15 -172.7(4) . .
C12 N11 C16 C20 -178.3(4) . .
Eu1 N11 C16 C20 8.3(6) . .
C14 C15 C16 N11 -0.6(8) . .
C17 C15 C16 N11 -179.7(5) . .
C14 C15 C16 C20 178.4(5) . .
C17 C15 C16 C20 -0.7(8) . .
C14 C15 C17 C18 -178.3(7) . .
C16 C15 C17 C18 0.7(10) . .
C15 C17 C18 C19 -0.8(12) . .
C17 C18 C19 C21 179.5(7) . .
C17 C18 C19 C20 1.0(10) . .
C23 N12 C20 C19 0.0(7) . .
Eu1 N12 C20 C19 171.6(4) . .
C23 N12 C20 C16 179.9(4) . .
Eu1 N12 C20 C16 -8.5(6) . .
C21 C19 C20 N12 0.2(8) . .
C18 C19 C20 N12 178.9(5) . .
C21 C19 C20 C16 -179.7(5) . .
C18 C19 C20 C16 -1.0(8) . .
N11 C16 C20 N12 0.0(7) . .
C15 C16 C20 N12 -179.0(4) . .
N11 C16 C20 C19 179.9(5) . .
C15 C16 C20 C19 0.9(8) . .
C20 C19 C21 C22 -1.0(9) . .
C18 C19 C21 C22 -179.5(6) . .
C19 C21 C22 C23 1.4(9) . .
C20 N12 C23 C22 0.5(7) . .
Eu1 N12 C23 C22 -171.0(4) . .
C21 C22 C23 N12 -1.2(8) . .
Eu2 O31 C32 C33 -23.7(8) . .
Eu2 O31 C32 C31 153.9(4) . .
F31 C31 C32 O31 6.0(7) . .
F33 C31 C32 O31 128.3(5) . .
F32 C31 C32 O31 -113.0(6) . .
F31 C31 C32 C33 -176.2(5) . .
F33 C31 C32 C33 -53.8(7) . .
F32 C31 C32 C33 64.8(6) . .
O31 C32 C33 F34 179.8(4) . .
C31 C32 C33 F34 2.2(7) . .
O31 C32 C33 C34 1.0(9) . .
C31 C32 C33 C34 -176.5(5) . .
Eu2 O32 C34 C33 15.0(8) . .
Eu2 O32 C34 C35 -166.7(3) . .
C32 C33 C34 O32 2.2(8) . .
F34 C33 C34 O32 -176.6(4) . .
C32 C33 C34 C35 -176.1(5) . .
F34 C33 C34 C35 5.1(7) . .
O32 C34 C35 F35 -119.3(5) . .
C33 C34 C35 F35 59.1(7) . .
O32 C34 C35 F36 2.1(7) . .
C33 C34 C35 F36 -179.5(5) . .
O32 C34 C35 F37 120.0(5) . .
C33 C34 C35 F37 -61.5(7) . .
Eu2 O36 C36 O36 24.45(19) . 7_556
Eu2 O36 C36 C37 -155.55(19) . .
F41 F42 C37 F42 -86.6(12) . 7_556
F43 F42 C37 F42 80.0(10) . 7_556
F43 F42 C37 F41 166.5(16) . .
F41 F42 C37 F41 -146(2) . 7_556
F43 F42 C37 F41 21(2) . 7_556
F41 F42 C37 F43 -31.0(17) . 7_556
F43 F42 C37 F43 135.5(19) . 7_556
F41 F42 C37 F43 -166.5(16) . .
F41 F42 C37 C36 93.4(12) . .
F43 F42 C37 C36 -100.0(10) . .
F43 F41 C37 F42 -144(2) 7_556 .
F42 F41 C37 F42 124.0(18) . 7_556
F43 F41 C37 F42 -20(2) 7_556 7_556
F42 F41 C37 F41 70.1(11) . 7_556
F43 F41 C37 F41 -73.9(13) 7_556 7_556
F42 F41 C37 F43 144(2) . 7_556
F42 F41 C37 F43 11.5(13) . .
F43 F41 C37 F43 -132(2) 7_556 .
F42 F41 C37 C36 -109.9(11) . .
F43 F41 C37 C36 106.2(13) 7_556 .
F41 F43 C37 F42 157(2) 7_556 .
F42 F43 C37 F42 -126.8(14) . 7_556
F41 F43 C37 F42 30(2) 7_556 7_556
F42 F43 C37 F41 -11.5(15) . .
F41 F43 C37 F41 145(2) 7_556 .
F42 F43 C37 F41 -157(2) . 7_556
F42 F43 C37 F43 -73.4(11) . 7_556
F41 F43 C37 F43 83.1(15) 7_556 7_556
F42 F43 C37 C36 106.6(11) . .
F41 F43 C37 C36 -96.9(15) 7_556 .
O36 C36 C37 F42 33.9(18) . .
O36 C36 C37 F42 -146.1(18) 7_556 .
O36 C36 C37 F42 -146.1(18) . 7_556
O36 C36 C37 F42 33.9(18) 7_556 7_556
O36 C36 C37 F41 92(3) . .
O36 C36 C37 F41 -88(3) 7_556 .
O36 C36 C37 F41 -88(3) . 7_556
O36 C36 C37 F41 92(3) 7_556 7_556
O36 C36 C37 F43 154(2) . 7_556
O36 C36 C37 F43 -26(2) 7_556 7_556
O36 C36 C37 F43 -26(2) . .
O36 C36 C37 F43 154(2) 7_556 .
C46 N41 C42 C43 -1.2(7) . .
Eu2 N41 C42 C43 166.5(4) . .
N41 C42 C43 C44 0.4(8) . .
C42 C43 C44 C45 1.0(8) . .
C43 C44 C45 C47 178.3(6) . .
C43 C44 C45 C46 -1.4(8) . .
C42 N41 C46 C50 -176.4(4) . .
Eu2 N41 C46 C50 15.6(6) . .
C42 N41 C46 C45 0.6(7) . .
Eu2 N41 C46 C45 -167.5(4) . .
C44 C45 C46 N41 0.7(7) . .
C47 C45 C46 N41 -179.1(5) . .
C44 C45 C46 C50 177.5(5) . .
C47 C45 C46 C50 -2.2(7) . .
C44 C45 C47 C48 -177.1(7) . .
C46 C45 C47 C48 2.6(10) . .
C45 C47 C48 C49 -1.1(11) . .
C47 C48 C49 C51 -179.6(7) . .
C47 C48 C49 C50 -0.7(10) . .
C53 N42 C50 C49 -1.8(7) . .
Eu2 N42 C50 C49 168.2(4) . .
C53 N42 C50 C46 177.8(5) . .
Eu2 N42 C50 C46 -12.2(6) . .
C51 C49 C50 N42 -0.6(8) . .
C48 C49 C50 N42 -179.5(5) . .
C51 C49 C50 C46 179.9(5) . .
C48 C49 C50 C46 1.0(8) . .
N41 C46 C50 N42 -2.0(7) . .
C45 C46 C50 N42 -179.0(4) . .
N41 C46 C50 C49 177.5(5) . .
C45 C46 C50 C49 0.5(8) . .
C50 C49 C51 C52 2.3(10) . .
C48 C49 C51 C52 -178.9(6) . .
C49 C51 C52 C53 -1.7(10) . .
C50 N42 C53 C52 2.4(8) . .
Eu2 N42 C53 C52 -167.1(4) . .
C51 C52 C53 N42 -0.7(9) . .
