#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:40:09 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180272 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/58/7115896.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7115896
loop_
_publ_author_name
'Jun-Yan Cheng'
'Peng Wang'
'Jian-Ping Ma'
'Qi-Kui Liu'
'Yu-Bin Dong'
_publ_section_title
;
 A nanoporous Ag(I)-MOF showing unique selective adsorption of benzene
 among its organic analogues
;
_journal_name_full               Chem.Commun.
_journal_page_first              13672
_journal_paper_doi               10.1039/C4cc03204G
_journal_volume                  50
_journal_year                    2014
_chemical_formula_sum            'C45 H43 Ag3 Cl3 F18 N12 O5 Sb3'
_chemical_formula_weight         1969.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           179
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 65 2 (0 0 1)'
_symmetry_space_group_name_H-M   'P 65 2 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   15.9174(15)
_cell_length_b                   15.9174(15)
_cell_length_c                   44.260(6)
_cell_measurement_reflns_used    18626
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.355
_cell_measurement_theta_min      2.360
_cell_volume                     9711.5(18)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0437
_diffrn_reflns_av_sigmaI/netI    0.0252
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       52
_diffrn_reflns_limit_l_min       -52
_diffrn_reflns_number            40898
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.55
_exptl_absorpt_coefficient_mu    2.350
_exptl_absorpt_correction_T_max  0.6770
_exptl_absorpt_correction_T_min  0.5911
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.020
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5664
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         4.065
_refine_diff_density_min         -2.101
_refine_diff_density_rms         0.178
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.95(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     418
_refine_ls_number_reflns         5726
_refine_ls_number_restraints     11
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0694
_refine_ls_R_factor_gt           0.0646
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1057P)²+83.8192P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1792
_refine_ls_wR_factor_ref         0.1855
_reflns_number_gt                5315
_reflns_number_total             5726
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4cc03204g2.cif
_cod_data_source_block           110625c
_cod_original_sg_symbol_H-M      P6(5)22
_cod_database_code               7115896
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x-y, x, z+5/6'
'-y, x-y, z+2/3'
'-x, -y, z+1/2'
'-x+y, -x, z+1/3'
'y, -x+y, z+1/6'
'-y, -x, -z+1/6'
'x-y, -y, -z'
'x, x-y, -z+5/6'
'y, x, -z+2/3'
'-x+y, y, -z+1/2'
'-x, -x+y, -z+1/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.40692(4) 0.59308(4) 0.0833 0.0394(3) Uani 1 2 d S
Ag2 Ag 0.24521(4) 0.75479(4) 0.0833 0.0481(3) Uani 1 2 d S
Ag3 Ag 0.55216(17) 0.77608(9) -0.0833 0.0812(6) Uani 1 2 d S
C1 C 0.5812(8) 0.6651(9) 0.0362(2) 0.040(2) Uani 1 1 d .
C2 C 0.6263(11) 0.6457(12) 0.0601(3) 0.061(4) Uani 1 1 d .
H2 H 0.5939 0.6195 0.0781 0.074 Uiso 1 1 calc R
C3 C 0.7221(12) 0.6670(15) 0.0558(3) 0.076(5) Uani 1 1 d .
H3 H 0.7540 0.6561 0.0716 0.092 Uiso 1 1 calc R
C4 C 0.7685(11) 0.7021(15) 0.0302(4) 0.090(7) Uani 1 1 d .
H4 H 0.8313 0.7129 0.0282 0.108 Uiso 1 1 calc R
C5 C 0.7271(9) 0.7233(12) 0.0062(3) 0.067(4) Uani 1 1 d .
H5 H 0.7622 0.7515 -0.0114 0.080 Uiso 1 1 calc R
C6 C 0.6303(8) 0.7011(9) 0.0090(3) 0.042(3) Uani 1 1 d .
C7 C 0.4950(8) 0.6988(8) -0.0107(2) 0.037(2) Uani 1 1 d .
H7 H 0.4615 0.7069 -0.0266 0.044 Uiso 1 1 calc R
C8 C 0.4493(7) 0.6668(7) 0.01733(19) 0.0245(19) Uani 1 1 d .
C9 C 0.3491(7) 0.6534(7) 0.0216(2) 0.0298(19) Uani 1 1 d .
C10 C 0.3037(8) 0.6839(9) -0.0025(2) 0.040(2) Uani 1 1 d .
H10A H 0.3540 0.7401 -0.0130 0.048 Uiso 1 1 calc R
H10B H 0.2601 0.7023 0.0068 0.048 Uiso 1 1 calc R
C11 C 0.2474(11) 0.6021(11) -0.0252(3) 0.057(3) Uani 1 1 d .
H11A H 0.2917 0.5884 -0.0359 0.085 Uiso 1 1 calc R
H11B H 0.2146 0.6217 -0.0393 0.085 Uiso 1 1 calc R
H11C H 0.2007 0.5449 -0.0147 0.085 Uiso 1 1 calc R
C12 C 0.1272(13) 0.3785(12) 0.0770(4) 0.088(6) Uani 1 1 d .
H12A H 0.1874 0.3784 0.0782 0.132 Uiso 1 1 calc R
H12B H 0.0750 0.3134 0.0738 0.132 Uiso 1 1 calc R
H12C H 0.1166 0.4035 0.0954 0.132 Uiso 1 1 calc R
C13 C 0.1315(9) 0.4417(9) 0.0508(3) 0.052(3) Uani 1 1 d .
H13A H 0.1833 0.4506 0.0373 0.063 Uiso 1 1 calc R
H13B H 0.0711 0.4080 0.0396 0.063 Uiso 1 1 calc R
C14 C 0.1472(8) 0.5359(9) 0.0594(2) 0.042(3) Uani 1 1 d .
C15 C 0.0712(8) 0.5490(12) 0.0753(2) 0.054(4) Uani 1 1 d .
C16 C -0.0247(8) 0.4699(12) 0.0753(3) 0.062(4) Uani 1 1 d .
H16 H -0.0365 0.4134 0.0655 0.075 Uiso 1 1 calc R
C17 C -0.0779(10) 0.5569(15) 0.1015(3) 0.071(5) Uani 1 1 d .
C18 C -0.1514(16) 0.570(2) 0.1143(5) 0.123(11) Uani 1 1 d .
H18 H -0.2157 0.5200 0.1145 0.148 Uiso 1 1 calc R
C19 C -0.1229(16) 0.662(2) 0.1269(5) 0.129(8) Uani 1 1 d D
H19 H -0.1709 0.6715 0.1352 0.155 Uiso 1 1 calc R
C20 C -0.0275(15) 0.7389(19) 0.1277(5) 0.129(8) Uani 1 1 d D
H20 H -0.0126 0.7980 0.1363 0.155 Uiso 1 1 calc R
C21 C 0.0444(16) 0.725(2) 0.1151(4) 0.102(8) Uani 1 1 d D
H21 H 0.1085 0.7749 0.1156 0.122 Uiso 1 1 calc R
C22 C 0.0241(11) 0.6422(14) 0.1025(3) 0.066(4) Uani 1 1 d .
C23 C 0.9213(18) 0.0593(19) 0.0531(8) 0.141(19) Uani 0.50 1 d PDU
H23 H 0.9002 0.0883 0.0374 0.170 Uiso 0.50 1 calc PR
Cl1 Cl 0.8939(4) 0.1061(4) 0.0833 0.179(6) Uani 1 2 d SD
Cl2 Cl 1.0391(13) 0.1122(12) 0.0425(4) 0.162(7) Uani 0.50 1 d PD
Cl3 Cl 0.8635(12) -0.0550(14) 0.0394(6) 0.224(13) Uani 0.50 1 d PD
F1 F 0.4815(5) 0.4808(5) -0.00795(18) 0.065(2) Uani 1 1 d .
F4 F 0.2422(5) 0.2635(5) 0.00893(19) 0.060(2) Uani 1 1 d .
F2 F 0.4115(8) 0.3551(8) 0.03619(18) 0.091(3) Uani 1 1 d .
F3 F 0.4009(6) 0.2968(7) -0.0198(2) 0.072(2) Uani 1 1 d .
F5 F 0.3108(7) 0.3866(10) -0.0358(2) 0.104(4) Uani 1 1 d .
F8 F 0.0725(7) 0.4180(10) 0.2025(2) 0.103(4) Uani 1 1 d .
F7 F -0.0822(12) 0.4209(16) 0.1829(5) 0.188(9) Uani 1 1 d .
F6 F 0.3221(9) 0.4484(7) 0.0207(3) 0.118(5) Uani 1 1 d .
F9 F 0.0831(10) 0.3440(13) 0.1516(2) 0.125(5) Uani 1 1 d .
N1 N 0.5828(7) 0.7172(7) -0.01488(19) 0.037(2) Uani 1 1 d .
N2 N 0.4897(7) 0.6498(7) 0.03979(18) 0.0366(19) Uani 1 1 d .
N3 N 0.3094(6) 0.6166(6) 0.04683(19) 0.0313(18) Uani 1 1 d .
N4 N 0.2270(6) 0.6183(6) 0.05593(19) 0.0340(18) Uani 1 1 d .
N5 N 0.0957(7) 0.6311(9) 0.0886(2) 0.050(3) Uani 1 1 d .
N6 N -0.0953(8) 0.4709(10) 0.0878(2) 0.059(3) Uani 1 1 d .
O1 O -0.1828(7) 0.4082(13) 0.0882(3) 0.116(6) Uani 1 1 d .
O2 O 0.6271(7) 0.7457(8) -0.0412(2) 0.061(2) Uani 1 1 d .
O1W O 0.0115(15) 0.884(2) 0.0567(7) 0.103(9) Uani 0.50 1 d P
H1A H 0.0101 0.8945 0.0379 0.124 Uiso 0.50 1 d PR
H1B H -0.0064 0.8265 0.0625 0.124 Uiso 0.50 1 d PR
Sb2 Sb 0.36091(5) 0.37219(5) 0.000551(16) 0.0380(2) Uani 1 1 d .
Sb1 Sb 0.0000 0.38280(9) 0.1667 0.0590(4) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N2 161.6(5) . 7_665
N2 Ag1 N3 69.8(3) . .
N2 Ag1 N3 124.5(3) 7_665 .
N2 Ag1 N3 124.5(3) . 7_665
N2 Ag1 N3 69.8(3) 7_665 7_665
N3 Ag1 N3 91.8(4) . 7_665
N5 Ag2 N5 161.5(5) 7_665 .
N5 Ag2 N4 124.4(3) 7_665 .
N5 Ag2 N4 69.8(3) . .
N5 Ag2 N4 69.8(3) 7_665 7_665
N5 Ag2 N4 124.4(3) . 7_665
N4 Ag2 N4 93.3(4) . 7_665
O2 Ag3 O2 128.8(5) . 9_564
N2 C1 C2 119.7(11) . .
N2 C1 C6 120.3(10) . .
C2 C1 C6 120.0(11) . .
C1 C2 C3 117.7(14) . .
C1 C2 H2 121.2 . .
C3 C2 H2 121.2 . .
C4 C3 C2 122.0(14) . .
C4 C3 H3 119.0 . .
C2 C3 H3 119.0 . .
C3 C4 C5 122.2(13) . .
C3 C4 H4 118.9 . .
C5 C4 H4 118.9 . .
C4 C5 C6 118.0(14) . .
C4 C5 H5 121.0 . .
C6 C5 H5 121.0 . .
N1 C6 C1 119.1(10) . .
N1 C6 C5 121.0(12) . .
C1 C6 C5 119.9(12) . .
N1 C7 C8 121.1(10) . .
N1 C7 H7 119.5 . .
C8 C7 H7 119.5 . .
N2 C8 C7 122.6(9) . .
N2 C8 C9 118.6(8) . .
C7 C8 C9 118.8(8) . .
N3 C9 C10 124.4(9) . .
N3 C9 C8 114.8(8) . .
C10 C9 C8 120.8(8) . .
C9 C10 C11 111.4(9) . .
C9 C10 H10A 109.4 . .
C11 C10 H10A 109.4 . .
C9 C10 H10B 109.4 . .
C11 C10 H10B 109.4 . .
H10A C10 H10B 108.0 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C13 C12 H12A 109.5 . .
C13 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C13 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C14 C13 C12 114.5(12) . .
C14 C13 H13A 108.6 . .
C12 C13 H13A 108.6 . .
C14 C13 H13B 108.6 . .
C12 C13 H13B 108.6 . .
H13A C13 H13B 107.6 . .
N4 C14 C13 126.2(11) . .
N4 C14 C15 111.3(11) . .
C13 C14 C15 122.4(11) . .
N5 C15 C16 122.8(13) . .
N5 C15 C14 119.6(11) . .
C16 C15 C14 117.6(14) . .
N6 C16 C15 124.2(17) . .
N6 C16 H16 117.9 . .
C15 C16 H16 117.9 . .
N6 C17 C18 123.2(19) . .
N6 C17 C22 119.5(11) . .
C18 C17 C22 117(2) . .
C17 C18 C19 117(2) . .
C17 C18 H18 121.6 . .
C19 C18 H18 121.6 . .
C20 C19 C18 124.5(19) . .
C20 C19 H19 117.8 . .
C18 C19 H19 117.8 . .
C21 C20 C19 118(2) . .
C21 C20 H20 121.0 . .
C19 C20 H20 121.0 . .
C22 C21 C20 122(2) . .
C22 C21 H21 119.2 . .
C20 C21 H21 119.2 . .
C21 C22 N5 120.8(17) . .
C21 C22 C17 122.0(14) . .
N5 C22 C17 117.2(15) . .
Cl3 C23 Cl2 108.0(12) . .
Cl3 C23 Cl1 129.6(16) . .
Cl2 C23 Cl1 117.7(14) . .
Cl3 C23 H23 97.2 . .
Cl2 C23 H23 97.2 . .
Cl1 C23 H23 97.2 . .
C23 Cl1 C23 106(4) . 7_665
C7 N1 O2 122.5(10) . .
C7 N1 C6 118.4(9) . .
O2 N1 C6 119.0(9) . .
C8 N2 C1 118.5(9) . .
C8 N2 Ag1 119.5(7) . .
C1 N2 Ag1 122.0(7) . .
C9 N3 N4 120.2(8) . .
C9 N3 Ag1 117.0(6) . .
N4 N3 Ag1 120.0(6) . .
C14 N4 N3 118.2(9) . .
C14 N4 Ag2 118.2(7) . .
N3 N4 Ag2 118.8(6) . .
C15 N5 C22 118.6(13) . .
C15 N5 Ag2 119.5(7) . .
C22 N5 Ag2 121.4(11) . .
O1 N6 C16 130.1(17) . .
O1 N6 C17 112.1(13) . .
C16 N6 C17 117.6(14) . .
N1 O2 Ag3 121.5(7) . .
H1A O1W H1B 118.7 . .
F6 Sb2 F3 179.4(5) . .
F6 Sb2 F2 89.8(6) . .
F3 Sb2 F2 90.2(5) . .
F6 Sb2 F4 89.8(4) . .
F3 Sb2 F4 90.7(4) . .
F2 Sb2 F4 90.4(4) . .
F6 Sb2 F5 91.9(7) . .
F3 Sb2 F5 88.1(6) . .
F2 Sb2 F5 178.3(6) . .
F4 Sb2 F5 89.4(4) . .
F6 Sb2 F1 90.9(4) . .
F3 Sb2 F1 88.5(4) . .
F2 Sb2 F1 89.2(4) . .
F4 Sb2 F1 179.2(4) . .
F5 Sb2 F1 90.9(4) . .
F7 Sb1 F7 93.6(15) . 12
F7 Sb1 F9 87.2(9) . 12
F7 Sb1 F9 178.2(8) 12 12
F7 Sb1 F9 178.2(8) . .
F7 Sb1 F9 87.2(9) 12 .
F9 Sb1 F9 92.0(11) 12 .
F7 Sb1 F8 90.2(7) . .
F7 Sb1 F8 90.5(7) 12 .
F9 Sb1 F8 91.2(6) 12 .
F9 Sb1 F8 88.1(5) . .
F7 Sb1 F8 90.5(7) . 12
F7 Sb1 F8 90.2(7) 12 12
F9 Sb1 F8 88.1(5) 12 12
F9 Sb1 F8 91.2(6) . 12
F8 Sb1 F8 179.0(9) . 12
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.253(9) .
Ag1 N2 2.253(9) 7_665
Ag1 N3 2.395(8) .
Ag1 N3 2.395(8) 7_665
Ag2 N5 2.216(12) 7_665
Ag2 N5 2.216(12) .
Ag2 N4 2.376(9) .
Ag2 N4 2.376(9) 7_665
Ag3 O2 2.392(10) .
Ag3 O2 2.392(10) 9_564
C1 N2 1.360(14) .
C1 C2 1.395(17) .
C1 C6 1.395(17) .
C2 C3 1.40(2) .
C2 H2 0.9300 .
C3 C4 1.32(3) .
C3 H3 0.9300 .
C4 C5 1.38(2) .
C4 H4 0.9300 .
C5 C6 1.403(16) .
C5 H5 0.9300 .
C6 N1 1.394(15) .
C7 N1 1.291(14) .
C7 C8 1.400(13) .
C7 H7 0.9300 .
C8 N2 1.285(13) .
C8 C9 1.511(12) .
C9 N3 1.273(13) .
C9 C10 1.497(13) .
C10 C11 1.530(18) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 C13 1.51(2) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 C14 1.442(18) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 N4 1.300(15) .
C14 C15 1.500(17) .
C15 N5 1.303(19) .
C15 C16 1.412(18) .
C16 N6 1.260(17) .
C16 H16 0.9300 .
C17 N6 1.39(2) .
C17 C18 1.40(2) .
C17 C22 1.51(2) .
C18 C19 1.41(4) .
C18 H18 0.9300 .
C19 C20 1.396(10) .
C19 H19 0.9300 .
C20 C21 1.389(10) .
C20 H20 0.9300 .
C21 C22 1.31(3) .
C21 H21 0.9300 .
C22 N5 1.382(14) .
C23 Cl3 1.688(10) .
C23 Cl2 1.694(10) .
C23 Cl1 1.693(10) .
C23 H23 0.9800 .
Cl1 C23 1.693(10) 7_665
F1 Sb2 1.870(7) .
F4 Sb2 1.852(7) .
F2 Sb2 1.851(8) .
F3 Sb2 1.849(7) .
F5 Sb2 1.862(9) .
F8 Sb1 1.874(9) .
F7 Sb1 1.842(12) .
F6 Sb2 1.843(8) .
F9 Sb1 1.843(12) .
N1 O2 1.317(12) .
N3 N4 1.386(12) .
N6 O1 1.244(17) .
O1W H1A 0.8501 .
O1W H1B 0.8501 .
Sb1 F7 1.842(12) 12
Sb1 F9 1.843(12) 12
Sb1 F8 1.874(9) 12
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 C1 C2 C3 -177.0(13) . .
C6 C1 C2 C3 2(2) . .
C1 C2 C3 C4 -2(3) . .
C2 C3 C4 C5 2(3) . .
C3 C4 C5 C6 -4(2) . .
N2 C1 C6 N1 -2.7(17) . .
C2 C1 C6 N1 178.0(11) . .
N2 C1 C6 C5 175.4(11) . .
C2 C1 C6 C5 -3.8(19) . .
C4 C5 C6 N1 -177.5(12) . .
C4 C5 C6 C1 4.4(19) . .
N1 C7 C8 N2 -3.4(17) . .
N1 C7 C8 C9 175.6(10) . .
N2 C8 C9 N3 -6.5(13) . .
C7 C8 C9 N3 174.4(9) . .
N2 C8 C9 C10 172.4(10) . .
C7 C8 C9 C10 -6.6(14) . .
N3 C9 C10 C11 -92.6(13) . .
C8 C9 C10 C11 88.6(12) . .
C12 C13 C14 N4 106.8(14) . .
C12 C13 C14 C15 -70.4(15) . .
N4 C14 C15 N5 -13.3(14) . .
C13 C14 C15 N5 164.3(11) . .
N4 C14 C15 C16 167.6(10) . .
C13 C14 C15 C16 -14.8(16) . .
N5 C15 C16 N6 1(2) . .
C14 C15 C16 N6 179.7(11) . .
N6 C17 C18 C19 -178.9(16) . .
C22 C17 C18 C19 0(2) . .
C17 C18 C19 C20 -1(3) . .
C18 C19 C20 C21 0(4) . .
C19 C20 C21 C22 1(3) . .
C20 C21 C22 N5 176.3(16) . .
C20 C21 C22 C17 -1(3) . .
N6 C17 C22 C21 -179.9(13) . .
C18 C17 C22 C21 1(2) . .
N6 C17 C22 N5 2.2(17) . .
C18 C17 C22 N5 -177.0(12) . .
Cl3 C23 Cl1 C23 83(4) . 7_665
Cl2 C23 Cl1 C23 -69(3) . 7_665
C8 C7 N1 O2 178.7(10) . .
C8 C7 N1 C6 2.3(16) . .
C1 C6 N1 C7 0.6(16) . .
C5 C6 N1 C7 -177.5(11) . .
C1 C6 N1 O2 -176.0(10) . .
C5 C6 N1 O2 5.9(16) . .
C7 C8 N2 C1 1.2(15) . .
C9 C8 N2 C1 -177.8(9) . .
C7 C8 N2 Ag1 -177.7(8) . .
C9 C8 N2 Ag1 3.3(12) . .
C2 C1 N2 C8 -179.0(11) . .
C6 C1 N2 C8 1.8(16) . .
C2 C1 N2 Ag1 -0.2(16) . .
C6 C1 N2 Ag1 -179.4(8) . .
N2 Ag1 N2 C8 144.0(8) 7_665 .
N3 Ag1 N2 C8 -0.1(7) . .
N3 Ag1 N2 C8 -77.8(8) 7_665 .
N2 Ag1 N2 C1 -34.8(8) 7_665 .
N3 Ag1 N2 C1 -179.0(9) . .
N3 Ag1 N2 C1 103.4(9) 7_665 .
C10 C9 N3 N4 -11.7(15) . .
C8 C9 N3 N4 167.2(8) . .
C10 C9 N3 Ag1 -172.6(8) . .
C8 C9 N3 Ag1 6.3(11) . .
N2 Ag1 N3 C9 -3.6(7) . .
N2 Ag1 N3 C9 -170.7(7) 7_665 .
N3 Ag1 N3 C9 122.8(8) 7_665 .
N2 Ag1 N3 N4 -164.6(8) . .
N2 Ag1 N3 N4 28.4(8) 7_665 .
N3 Ag1 N3 N4 -38.2(6) 7_665 .
C13 C14 N4 N3 -9.3(16) . .
C15 C14 N4 N3 168.2(8) . .
C13 C14 N4 Ag2 -164.4(9) . .
C15 C14 N4 Ag2 13.1(11) . .
C9 N3 N4 C14 116.5(11) . .
Ag1 N3 N4 C14 -83.1(10) . .
C9 N3 N4 Ag2 -88.4(10) . .
Ag1 N3 N4 Ag2 71.9(7) . .
N5 Ag2 N4 C14 -174.7(7) 7_665 .
N5 Ag2 N4 C14 -8.0(8) . .
N4 Ag2 N4 C14 117.6(9) 7_665 .
N5 Ag2 N4 N3 30.3(8) 7_665 .
N5 Ag2 N4 N3 -163.0(8) . .
N4 Ag2 N4 N3 -37.4(5) 7_665 .
C16 C15 N5 C22 -2.3(17) . .
C14 C15 N5 C22 178.6(10) . .
C16 C15 N5 Ag2 -174.1(9) . .
C14 C15 N5 Ag2 6.8(14) . .
C21 C22 N5 C15 -177.1(13) . .
C17 C22 N5 C15 0.8(16) . .
C21 C22 N5 Ag2 -5.4(17) . .
C17 C22 N5 Ag2 172.5(8) . .
N5 Ag2 N5 C15 143.2(9) 7_665 .
N4 Ag2 N5 C15 0.1(8) . .
N4 Ag2 N5 C15 -79.8(9) 7_665 .
N5 Ag2 N5 C22 -28.3(8) 7_665 .
N4 Ag2 N5 C22 -171.5(9) . .
N4 Ag2 N5 C22 108.7(9) 7_665 .
C15 C16 N6 O1 176.3(13) . .
C15 C16 N6 C17 2.5(18) . .
C18 C17 N6 O1 0.4(19) . .
C22 C17 N6 O1 -178.7(11) . .
C18 C17 N6 C16 175.4(13) . .
C22 C17 N6 C16 -3.7(17) . .
C7 N1 O2 Ag3 3.9(14) . .
C6 N1 O2 Ag3 -179.6(8) . .
O2 Ag3 O2 N1 153.8(9) 9_564 .
