#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:41:37 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180273 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/59/7115990.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7115990
loop_
_publ_author_name
'Marc Devillard'
'Emmanuel Nicolas'
'Christian Appelt'
'Jana Backs'
'Sonia Mallet-Ladeira'
Ghenwa
Bouhadir'
'J. Chris Slootweg'
'Werner Uhl'
'Didier Bourissou'
_publ_section_title
;
 Novel zwitterionic complexes arising from the coordination of an
 ambiphilic phosphorus-aluminum ligand to gold
;
_journal_name_full               Chem.Commun.
_journal_page_first              14805
_journal_paper_doi               10.1039/C4cc06992G
_journal_volume                  50
_journal_year                    2014
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C37 H55 Al Au Cl P2, 0.5(C6 H6)'
_chemical_formula_sum            'C40 H58 Al Au Cl P2'
_chemical_formula_weight         860.2
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90
_cell_angle_beta                 97.902(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.6291(5)
_cell_length_b                   23.6665(12)
_cell_length_c                   17.7492(9)
_cell_measurement_reflns_used    9910
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      29.11
_cell_measurement_theta_min      2.3
_cell_measurement_wavelength     0.71073
_cell_volume                     4006.4(4)
_computing_cell_refinement       'APEX2 and SAINT (Bruker, 2008)'
_computing_data_collection       'APEX2 (Bruker, 2008)'
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Kappa APEX II Quazar'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'multilayer optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_unetI/netI     0.0475
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            64611
_diffrn_reflns_theta_full        29.21
_diffrn_reflns_theta_max         29.21
_diffrn_reflns_theta_min         2.89
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.866
_exptl_absorpt_correction_T_max  0.9267
_exptl_absorpt_correction_T_min  0.8310
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.426
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1748
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.658
_refine_diff_density_min         -0.608
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.998
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     421
_refine_ls_number_reflns         10792
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.998
_refine_ls_R_factor_all          0.0509
_refine_ls_R_factor_gt           0.0289
_refine_ls_shift/su_max          0.024
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0196P)²+1.1808P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0495
_refine_ls_wR_factor_ref         0.055
_reflns_number_gt                8252
_reflns_number_total             10792
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4cc06992g2.cif
_cod_data_source_block           3PMe
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7115990
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.4116(3) 0.24843(13) 0.45832(19) 0.0460(8) Uani 1 1 d .
H1A H 0.3816 0.228 0.4109 0.069 Uiso 1 1 calc R
H1B H 0.3313 0.2535 0.4861 0.069 Uiso 1 1 calc R
H1C H 0.4846 0.2267 0.4897 0.069 Uiso 1 1 calc R
C2 C 0.6347(4) 0.30197(16) 0.3943(2) 0.0599(10) Uani 1 1 d .
H2A H 0.6968 0.277 0.4276 0.09 Uiso 1 1 calc R
H2B H 0.6835 0.3375 0.387 0.09 Uiso 1 1 calc R
H2C H 0.6083 0.2836 0.3449 0.09 Uiso 1 1 calc R
C3 C 0.5439(4) 0.34646(14) 0.52884(18) 0.0565(10) Uani 1 1 d .
H3A H 0.6138 0.3211 0.5563 0.085 Uiso 1 1 calc R
H3B H 0.4656 0.3513 0.5582 0.085 Uiso 1 1 calc R
H3C H 0.587 0.3833 0.5219 0.085 Uiso 1 1 calc R
C4 C 0.0993(3) 0.38838(10) 0.19977(13) 0.0187(5) Uani 1 1 d .
C5 C 0.1022(3) 0.41691(10) 0.13430(13) 0.0202(5) Uani 1 1 d .
H5 H 0.1365 0.4546 0.1392 0.024 Uiso 1 1 calc R
C6 C 0.0585(3) 0.39662(10) 0.05576(13) 0.0214(5) Uani 1 1 d .
C7 C -0.0365(3) 0.42835(11) 0.00723(14) 0.0264(6) Uani 1 1 d .
H7 H -0.069 0.4632 0.0248 0.032 Uiso 1 1 calc R
C8 C -0.0852(3) 0.41084(12) -0.06580(15) 0.0328(7) Uani 1 1 d .
H8 H -0.1524 0.4328 -0.0974 0.039 Uiso 1 1 calc R
C9 C -0.0353(3) 0.36109(13) -0.09248(16) 0.0389(8) Uani 1 1 d .
H9 H -0.0686 0.3484 -0.1425 0.047 Uiso 1 1 calc R
C10 C 0.0628(3) 0.33001(14) -0.04662(16) 0.0436(8) Uani 1 1 d .
H10 H 0.0988 0.2962 -0.0654 0.052 Uiso 1 1 calc R
C11 C 0.1097(3) 0.34763(12) 0.02707(15) 0.0321(7) Uani 1 1 d .
H11 H 0.1778 0.3258 0.0582 0.039 Uiso 1 1 calc R
C12 C -0.1726(3) 0.29717(11) 0.16536(15) 0.0275(6) Uani 1 1 d .
C13 C -0.2584(3) 0.34555(12) 0.1935(2) 0.0423(8) Uani 1 1 d .
H13A H -0.2338 0.3811 0.1703 0.063 Uiso 1 1 calc R
H13B H -0.2374 0.3484 0.2489 0.063 Uiso 1 1 calc R
H13C H -0.3586 0.338 0.1791 0.063 Uiso 1 1 calc R
C14 C -0.2049(3) 0.29521(13) 0.07871(16) 0.0409(8) Uani 1 1 d .
H14A H -0.3055 0.2889 0.0638 0.061 Uiso 1 1 calc R
H14B H -0.1519 0.2644 0.0593 0.061 Uiso 1 1 calc R
H14C H -0.1779 0.3312 0.0575 0.061 Uiso 1 1 calc R
C15 C -0.2269(3) 0.24181(11) 0.19598(17) 0.0363(7) Uani 1 1 d .
H15A H -0.3283 0.2389 0.1802 0.054 Uiso 1 1 calc R
H15B H -0.2073 0.2416 0.2516 0.054 Uiso 1 1 calc R
H15C H -0.1797 0.2097 0.1756 0.054 Uiso 1 1 calc R
C16 C 0.1631(3) 0.24226(11) 0.18826(15) 0.0285(6) Uani 1 1 d .
C17 C 0.1233(3) 0.21254(12) 0.11107(17) 0.0384(7) Uani 1 1 d .
H17A H 0.1225 0.2402 0.0699 0.058 Uiso 1 1 calc R
H17B H 0.03 0.1956 0.1091 0.058 Uiso 1 1 calc R
H17C H 0.192 0.1829 0.1051 0.058 Uiso 1 1 calc R
C18 C 0.1599(3) 0.19539(12) 0.24864(18) 0.0429(8) Uani 1 1 d .
H18A H 0.2201 0.164 0.2373 0.064 Uiso 1 1 calc R
H18B H 0.0635 0.1818 0.2477 0.064 Uiso 1 1 calc R
H18C H 0.194 0.2107 0.2991 0.064 Uiso 1 1 calc R
C19 C 0.3153(3) 0.26274(12) 0.19354(18) 0.0395(7) Uani 1 1 d .
H19A H 0.3761 0.2308 0.1851 0.059 Uiso 1 1 calc R
H19B H 0.3449 0.2788 0.2441 0.059 Uiso 1 1 calc R
H19C H 0.322 0.2917 0.1548 0.059 Uiso 1 1 calc R
C20 C 0.2575(3) 0.49166(9) 0.26429(13) 0.0190(5) Uani 1 1 d .
C21 C 0.3664(3) 0.48323(10) 0.21932(14) 0.0211(5) Uani 1 1 d .
C22 C 0.4308(3) 0.52992(11) 0.19147(14) 0.0255(6) Uani 1 1 d .
H22 H 0.5002 0.5238 0.1591 0.031 Uiso 1 1 calc R
C23 C 0.3980(3) 0.58491(11) 0.20889(15) 0.0280(6) Uani 1 1 d .
C24 C 0.3047(3) 0.59183(11) 0.26103(15) 0.0295(6) Uani 1 1 d .
H24 H 0.2884 0.6289 0.2782 0.035 Uiso 1 1 calc R
C25 C 0.2341(3) 0.54736(11) 0.28938(14) 0.0241(6) Uani 1 1 d .
C26 C 0.4244(3) 0.42627(11) 0.20177(16) 0.0306(6) Uani 1 1 d .
H26A H 0.3724 0.4116 0.1545 0.046 Uiso 1 1 calc R
H26B H 0.4148 0.4001 0.2435 0.046 Uiso 1 1 calc R
H26C H 0.5237 0.4301 0.1959 0.046 Uiso 1 1 calc R
C27 C 0.4618(4) 0.63472(12) 0.17366(19) 0.0457(8) Uani 1 1 d .
H27A H 0.5559 0.6248 0.163 0.068 Uiso 1 1 calc R
H27B H 0.4679 0.6668 0.2089 0.068 Uiso 1 1 calc R
H27C H 0.403 0.6451 0.1261 0.068 Uiso 1 1 calc R
C28 C 0.1416(3) 0.56236(12) 0.34890(16) 0.0369(7) Uani 1 1 d .
H28A H 0.1712 0.5988 0.372 0.055 Uiso 1 1 calc R
H28B H 0.1499 0.533 0.3883 0.055 Uiso 1 1 calc R
H28C H 0.0439 0.565 0.3249 0.055 Uiso 1 1 calc R
C29 C -0.0020(3) 0.44967(10) 0.32598(13) 0.0201(5) Uani 1 1 d .
C30 C -0.1099(3) 0.47896(10) 0.27971(14) 0.0234(6) Uani 1 1 d .
C31 C -0.2334(3) 0.49187(11) 0.30878(16) 0.0306(6) Uani 1 1 d .
H31 H -0.3054 0.5113 0.277 0.037 Uiso 1 1 calc R
C32 C -0.2562(3) 0.47781(12) 0.38129(16) 0.0311(6) Uani 1 1 d .
C33 C -0.1469(3) 0.45102(11) 0.42681(15) 0.0294(6) Uani 1 1 d .
H33 H -0.1593 0.4416 0.4775 0.035 Uiso 1 1 calc R
C34 C -0.0207(3) 0.43735(10) 0.40219(14) 0.0235(6) Uani 1 1 d .
C35 C -0.0993(3) 0.50153(12) 0.20111(14) 0.0306(6) Uani 1 1 d .
H35A H -0.1241 0.4716 0.1635 0.046 Uiso 1 1 calc R
H35B H -0.0032 0.5142 0.1986 0.046 Uiso 1 1 calc R
H35C H -0.1639 0.5334 0.1902 0.046 Uiso 1 1 calc R
C36 C -0.3925(3) 0.49250(14) 0.41015(18) 0.0459(8) Uani 1 1 d .
H36A H -0.4274 0.5287 0.3883 0.069 Uiso 1 1 calc R
H36B H -0.3764 0.4955 0.4657 0.069 Uiso 1 1 calc R
H36C H -0.4618 0.4629 0.3951 0.069 Uiso 1 1 calc R
C37 C 0.0896(3) 0.41284(12) 0.46162(14) 0.0338(7) Uani 1 1 d .
H37A H 0.0592 0.4165 0.5119 0.051 Uiso 1 1 calc R
H37B H 0.178 0.4332 0.4611 0.051 Uiso 1 1 calc R
H37C H 0.1033 0.3728 0.4506 0.051 Uiso 1 1 calc R
C38 C 0.3620(4) 0.48356(17) -0.01463(18) 0.0507(9) Uani 1 1 d .
H38 H 0.2666 0.4722 -0.0248 0.061 Uiso 1 1 calc R
C39 C 0.4646(4) 0.44391(16) 0.00557(18) 0.0501(9) Uani 1 1 d .
H39 H 0.4402 0.4052 0.0095 0.06 Uiso 1 1 calc R
C40 C 0.6031(4) 0.46047(16) 0.02015(18) 0.0536(10) Uani 1 1 d .
H40 H 0.6743 0.4331 0.034 0.064 Uiso 1 1 calc R
P1 P 0.15920(7) 0.42802(3) 0.28734(3) 0.01845(13) Uani 1 1 d .
P2 P 0.48000(8) 0.31642(3) 0.43694(4) 0.02948(17) Uani 1 1 d .
Cl1 Cl 0.02324(8) 0.30009(3) 0.33479(4) 0.03474(17) Uani 1 1 d .
Au1 Au 0.315828(11) 0.370771(4) 0.365181(6) 0.02529(4) Uani 1 1 d .
Al1 Al 0.03064(8) 0.30628(3) 0.20941(4) 0.02080(16) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
P2 C1 H1A 109.5 .
P2 C1 H1B 109.5 .
H1A C1 H1B 109.5 .
P2 C1 H1C 109.5 .
H1A C1 H1C 109.5 .
H1B C1 H1C 109.5 .
P2 C2 H2A 109.5 .
P2 C2 H2B 109.5 .
H2A C2 H2B 109.5 .
P2 C2 H2C 109.5 .
H2A C2 H2C 109.5 .
H2B C2 H2C 109.5 .
P2 C3 H3A 109.5 .
P2 C3 H3B 109.5 .
H3A C3 H3B 109.5 .
P2 C3 H3C 109.5 .
H3A C3 H3C 109.5 .
H3B C3 H3C 109.5 .
C5 C4 P1 115.58(18) .
C5 C4 Al1 125.96(18) .
P1 C4 Al1 118.44(12) .
C4 C5 C6 127.8(2) .
C4 C5 H5 116.1 .
C6 C5 H5 116.1 .
C11 C6 C7 117.6(2) .
C11 C6 C5 123.3(2) .
C7 C6 C5 119.2(2) .
C8 C7 C6 122.0(2) .
C8 C7 H7 119 .
C6 C7 H7 119 .
C7 C8 C9 119.3(3) .
C7 C8 H8 120.4 .
C9 C8 H8 120.4 .
C10 C9 C8 119.8(3) .
C10 C9 H9 120.1 .
C8 C9 H9 120.1 .
C9 C10 C11 120.4(3) .
C9 C10 H10 119.8 .
C11 C10 H10 119.8 .
C6 C11 C10 120.8(3) .
C6 C11 H11 119.6 .
C10 C11 H11 119.6 .
C14 C12 C13 107.8(2) .
C14 C12 C15 107.3(2) .
C13 C12 C15 107.3(2) .
C14 C12 Al1 116.46(19) .
C13 C12 Al1 109.33(19) .
C15 C12 Al1 108.24(18) .
C12 C13 H13A 109.5 .
C12 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
C12 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
C12 C14 H14A 109.5 .
C12 C14 H14B 109.5 .
H14A C14 H14B 109.5 .
C12 C14 H14C 109.5 .
H14A C14 H14C 109.5 .
H14B C14 H14C 109.5 .
C12 C15 H15A 109.5 .
C12 C15 H15B 109.5 .
H15A C15 H15B 109.5 .
C12 C15 H15C 109.5 .
H15A C15 H15C 109.5 .
H15B C15 H15C 109.5 .
C19 C16 C17 108.5(2) .
C19 C16 C18 107.1(2) .
C17 C16 C18 105.2(2) .
C19 C16 Al1 111.63(18) .
C17 C16 Al1 114.56(19) .
C18 C16 Al1 109.37(19) .
C16 C17 H17A 109.5 .
C16 C17 H17B 109.5 .
H17A C17 H17B 109.5 .
C16 C17 H17C 109.5 .
H17A C17 H17C 109.5 .
H17B C17 H17C 109.5 .
C16 C18 H18A 109.5 .
C16 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C16 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
C16 C19 H19A 109.5 .
C16 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C16 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
C21 C20 C25 118.0(2) .
C21 C20 P1 116.73(17) .
C25 C20 P1 125.27(19) .
C22 C21 C20 119.3(2) .
C22 C21 C26 116.1(2) .
C20 C21 C26 124.5(2) .
C23 C22 C21 122.7(3) .
C23 C22 H22 118.6 .
C21 C22 H22 118.6 .
C22 C23 C24 116.7(2) .
C22 C23 C27 121.7(3) .
C24 C23 C27 121.6(3) .
C25 C24 C23 123.3(2) .
C25 C24 H24 118.3 .
C23 C24 H24 118.3 .
C24 C25 C20 119.0(2) .
C24 C25 C28 116.1(2) .
C20 C25 C28 124.8(2) .
C21 C26 H26A 109.5 .
C21 C26 H26B 109.5 .
H26A C26 H26B 109.5 .
C21 C26 H26C 109.5 .
H26A C26 H26C 109.5 .
H26B C26 H26C 109.5 .
C23 C27 H27A 109.5 .
C23 C27 H27B 109.5 .
H27A C27 H27B 109.5 .
C23 C27 H27C 109.5 .
H27A C27 H27C 109.5 .
H27B C27 H27C 109.5 .
C25 C28 H28A 109.5 .
C25 C28 H28B 109.5 .
H28A C28 H28B 109.5 .
C25 C28 H28C 109.5 .
H28A C28 H28C 109.5 .
H28B C28 H28C 109.5 .
C30 C29 C34 118.3(2) .
C30 C29 P1 120.42(18) .
C34 C29 P1 121.24(19) .
C31 C30 C29 119.2(2) .
C31 C30 C35 115.7(2) .
C29 C30 C35 124.9(2) .
C32 C31 C30 123.2(3) .
C32 C31 H31 118.4 .
C30 C31 H31 118.4 .
C31 C32 C33 116.7(3) .
C31 C32 C36 121.2(3) .
C33 C32 C36 122.1(3) .
C34 C33 C32 123.4(2) .
C34 C33 H33 118.3 .
C32 C33 H33 118.3 .
C33 C34 C29 119.0(2) .
C33 C34 C37 115.7(2) .
C29 C34 C37 125.2(2) .
C30 C35 H35A 109.5 .
C30 C35 H35B 109.5 .
H35A C35 H35B 109.5 .
C30 C35 H35C 109.5 .
H35A C35 H35C 109.5 .
H35B C35 H35C 109.5 .
C32 C36 H36A 109.5 .
C32 C36 H36B 109.5 .
H36A C36 H36B 109.5 .
C32 C36 H36C 109.5 .
H36A C36 H36C 109.5 .
H36B C36 H36C 109.5 .
C34 C37 H37A 109.5 .
C34 C37 H37B 109.5 .
H37A C37 H37B 109.5 .
C34 C37 H37C 109.5 .
H37A C37 H37C 109.5 .
H37B C37 H37C 109.5 .
C40 C38 C39 120.2(3) 3_665
C40 C38 H38 119.9 3_665
C39 C38 H38 119.9 .
C38 C39 C40 119.8(3) .
C38 C39 H39 120.1 .
C40 C39 H39 120.1 .
C38 C40 C39 120.0(3) 3_665
C38 C40 H40 120 3_665
C39 C40 H40 120 .
C4 P1 C29 105.82(11) .
C4 P1 C20 109.76(11) .
C29 P1 C20 109.63(11) .
C4 P1 Au1 107.82(8) .
C29 P1 Au1 116.57(8) .
C20 P1 Au1 107.12(8) .
C2 P2 C1 105.54(17) .
C2 P2 C3 104.84(19) .
C1 P2 C3 104.51(16) .
C2 P2 Au1 115.03(12) .
C1 P2 Au1 112.07(10) .
C3 P2 Au1 113.90(11) .
P2 Au1 P1 176.37(3) .
C12 Al1 C16 116.45(11) .
C12 Al1 C4 111.89(10) .
C16 Al1 C4 117.76(11) .
C12 Al1 Cl1 102.49(9) .
C16 Al1 Cl1 103.84(8) .
C4 Al1 Cl1 101.41(7) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 P2 1.799(3) .
C1 H1A 0.98 .
C1 H1B 0.98 .
C1 H1C 0.98 .
C2 P2 1.794(3) .
C2 H2A 0.98 .
C2 H2B 0.98 .
C2 H2C 0.98 .
C3 P2 1.808(3) .
C3 H3A 0.98 .
C3 H3B 0.98 .
C3 H3C 0.98 .
C4 C5 1.348(3) .
C4 P1 1.839(2) .
C4 Al1 2.067(2) .
C5 C6 1.480(3) .
C5 H5 0.95 .
C6 C11 1.384(4) .
C6 C7 1.388(3) .
C7 C8 1.380(3) .
C7 H7 0.95 .
C8 C9 1.380(4) .
C8 H8 0.95 .
C9 C10 1.372(4) .
C9 H9 0.95 .
C10 C11 1.388(4) .
C10 H10 0.95 .
C11 H11 0.95 .
C12 C14 1.527(4) .
C12 C13 1.534(4) .
C12 C15 1.537(4) .
C12 Al1 2.017(3) .
C13 H13A 0.98 .
C13 H13B 0.98 .
C13 H13C 0.98 .
C14 H14A 0.98 .
C14 H14B 0.98 .
C14 H14C 0.98 .
C15 H15A 0.98 .
C15 H15B 0.98 .
C15 H15C 0.98 .
C16 C19 1.534(4) .
C16 C17 1.541(4) .
C16 C18 1.546(4) .
C16 Al1 2.048(3) .
C17 H17A 0.98 .
C17 H17B 0.98 .
C17 H17C 0.98 .
C18 H18A 0.98 .
C18 H18B 0.98 .
C18 H18C 0.98 .
C19 H19A 0.98 .
C19 H19B 0.98 .
C19 H19C 0.98 .
C20 C21 1.417(3) .
C20 C25 1.419(3) .
C20 P1 1.854(2) .
C21 C22 1.391(3) .
C21 C26 1.508(3) .
C22 C23 1.384(4) .
C22 H22 0.95 .
C23 C24 1.385(4) .
C23 C27 1.504(4) .
C24 C25 1.385(4) .
C24 H24 0.95 .
C25 C28 1.514(4) .
C26 H26A 0.98 .
C26 H26B 0.98 .
C26 H26C 0.98 .
C27 H27A 0.98 .
C27 H27B 0.98 .
C27 H27C 0.98 .
C28 H28A 0.98 .
C28 H28B 0.98 .
C28 H28C 0.98 .
C29 C30 1.414(3) .
C29 C34 1.419(3) .
C29 P1 1.853(3) .
C30 C31 1.394(4) .
C30 C35 1.510(3) .
C31 C32 1.376(4) .
C31 H31 0.95 .
C32 C33 1.389(4) .
C32 C36 1.513(4) .
C33 C34 1.385(4) .
C33 H33 0.95 .
C34 C37 1.506(4) .
C35 H35A 0.98 .
C35 H35B 0.98 .
C35 H35C 0.98 .
C36 H36A 0.98 .
C36 H36B 0.98 .
C36 H36C 0.98 .
C37 H37A 0.98 .
C37 H37B 0.98 .
C37 H37C 0.98 .
C38 C40 1.374(5) 3_665
C38 C39 1.374(5) .
C38 H38 0.95 .
C39 C40 1.380(5) .
C39 H39 0.95 .
C40 C38 1.374(5) 3_665
C40 H40 0.95 .
P1 Au1 2.3337(6) .
P2 Au1 2.2852(7) .
Cl1 Al1 2.2411(10) .
