#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:48:51 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180277 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/63/7116366.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116366
loop_
_publ_author_name
'Zhao Chen'
'Jing Zhang'
'Min Song'
'Jun Yin'
Guang-AoYu
'Sheng Hua Liu'
_publ_section_title
;
 A novel fluorene-based aggregation-induced emission (AIE)-active gold(I)
 complex with crystallization-induced emission enhancement (CIEE) and
 reversible mechanochromism characteristics
;
_journal_name_full               Chem.Commun.
_journal_page_first              326
_journal_paper_doi               10.1039/C4cc08087D
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C39 H32 Au2 F10 N2'
_chemical_formula_weight         1112.60
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.282(2)
_cell_angle_beta                 107.229(2)
_cell_angle_gamma                100.920(2)
_cell_formula_units_Z            2
_cell_length_a                   12.3529(19)
_cell_length_b                   12.613(2)
_cell_length_c                   12.950(2)
_cell_measurement_reflns_used    9202
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      31.48
_cell_measurement_theta_min      2.66
_cell_volume                     1840.7(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0468
_diffrn_reflns_av_sigmaI/netI    0.0705
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            11843
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.00
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.043
_exptl_absorpt_correction_T_max  0.5001
_exptl_absorpt_correction_T_min  0.4453
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    2.007
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1056
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.642
_refine_diff_density_min         -4.113
_refine_diff_density_rms         0.354
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     480
_refine_ls_number_reflns         6339
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0839
_refine_ls_R_factor_gt           0.0733
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1841P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2189
_refine_ls_wR_factor_ref         0.2359
_reflns_number_gt                5182
_reflns_number_total             6339
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4cc08087d2.cif
_cod_data_source_block           e:\140221d\work\mo_140221d_0m
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7116366
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.60036(4) 0.86916(3) 1.17477(4) 0.0404(2) Uani 1 1 d .
Au2 Au 0.86299(4) 0.99068(4) 1.37410(4) 0.0471(2) Uani 1 1 d .
C1 C 0.6576(8) 0.5492(9) 1.0118(9) 0.034(2) Uani 1 1 d .
C2 C 0.6607(9) 0.4605(10) 1.0587(9) 0.039(3) Uani 1 1 d .
H2 H 0.6497 0.4626 1.1270 0.047 Uiso 1 1 calc R
C3 C 0.6808(9) 0.3655(9) 1.0021(9) 0.033(2) Uani 1 1 d .
H3 H 0.6831 0.3036 1.0324 0.039 Uiso 1 1 calc R
C4 C 0.6971(8) 0.3648(8) 0.9013(8) 0.026(2) Uani 1 1 d .
C5 C 0.6894(8) 0.4574(9) 0.8520(9) 0.030(2) Uani 1 1 d .
C6 C 0.6687(9) 0.5503(9) 0.9074(9) 0.033(2) Uani 1 1 d .
H6 H 0.6622 0.6114 0.8765 0.040 Uiso 1 1 calc R
C7 C 0.7002(9) 0.4338(8) 0.7382(8) 0.027(2) Uani 1 1 d .
C8 C 0.7237(8) 0.3181(8) 0.7327(9) 0.032(2) Uani 1 1 d .
C9 C 0.7194(8) 0.2799(9) 0.8263(9) 0.034(2) Uani 1 1 d .
C10 C 0.7415(10) 0.1763(9) 0.8372(10) 0.037(2) Uani 1 1 d .
H10 H 0.7382 0.1493 0.8992 0.045 Uiso 1 1 calc R
C11 C 0.7680(10) 0.1157(9) 0.7539(10) 0.042(3) Uani 1 1 d .
H11 H 0.7847 0.0477 0.7604 0.051 Uiso 1 1 calc R
C12 C 0.7701(10) 0.1552(10) 0.6599(10) 0.041(3) Uani 1 1 d .
C13 C 0.7478(10) 0.2553(9) 0.6485(9) 0.035(2) Uani 1 1 d .
H13 H 0.7488 0.2808 0.5852 0.042 Uiso 1 1 calc R
C14 C 0.6276(9) 0.7274(10) 1.1132(10) 0.040(3) Uani 1 1 d .
C15 C 0.8249(10) 0.0527(10) 0.5036(12) 0.047(3) Uani 1 1 d .
C16 C 0.8030(9) 0.5189(9) 0.7295(9) 0.036(2) Uani 1 1 d .
H16A H 0.7869 0.5915 0.7388 0.044 Uiso 1 1 calc R
H16B H 0.8073 0.4991 0.6555 0.044 Uiso 1 1 calc R
C17 C 0.9241(10) 0.5263(11) 0.8166(10) 0.046(3) Uani 1 1 d .
H17A H 0.9201 0.5470 0.8906 0.055 Uiso 1 1 calc R
H17B H 0.9400 0.4536 0.8078 0.055 Uiso 1 1 calc R
C18 C 1.0264(11) 0.6108(11) 0.8064(12) 0.054(3) Uani 1 1 d .
H18A H 1.0047 0.6802 0.8015 0.065 Uiso 1 1 calc R
H18B H 1.0942 0.6250 0.8729 0.065 Uiso 1 1 calc R
C19 C 1.0592(12) 0.5710(13) 0.7065(13) 0.062(4) Uani 1 1 d .
H19A H 0.9907 0.5516 0.6399 0.074 Uiso 1 1 calc R
H19B H 1.0880 0.5052 0.7139 0.074 Uiso 1 1 calc R
C20 C 1.1556(13) 0.6640(16) 0.6966(15) 0.080(5) Uani 1 1 d .
H20A H 1.1253 0.7288 0.6880 0.096 Uiso 1 1 calc R
H20B H 1.2222 0.6848 0.7649 0.096 Uiso 1 1 calc R
C21 C 1.195(2) 0.630(3) 0.6026(19) 0.167(15) Uani 1 1 d .
H21A H 1.2099 0.5584 0.6019 0.250 Uiso 1 1 calc R
H21B H 1.2656 0.6833 0.6101 0.250 Uiso 1 1 calc R
H21C H 1.1353 0.6279 0.5343 0.250 Uiso 1 1 calc R
C22 C 0.5862(9) 0.4322(9) 0.6482(9) 0.031(2) Uani 1 1 d .
H22A H 0.5780 0.5077 0.6529 0.038 Uiso 1 1 calc R
H22B H 0.5920 0.4056 0.5759 0.038 Uiso 1 1 calc R
C23 C 0.4763(10) 0.3603(11) 0.6562(11) 0.048(3) Uani 1 1 d .
H23A H 0.4668 0.3896 0.7262 0.058 Uiso 1 1 calc R
H23B H 0.4856 0.2855 0.6558 0.058 Uiso 1 1 calc R
C24 C 0.3653(9) 0.3559(11) 0.5595(11) 0.045(3) Uani 1 1 d .
H24A H 0.3534 0.4300 0.5620 0.054 Uiso 1 1 calc R
H24B H 0.3758 0.3298 0.4894 0.054 Uiso 1 1 calc R
C25 C 0.2581(12) 0.2794(17) 0.5663(15) 0.085(6) Uani 1 1 d .
H25A H 0.2763 0.2096 0.5770 0.102 Uiso 1 1 calc R
H25B H 0.2418 0.3124 0.6313 0.102 Uiso 1 1 calc R
C26 C 0.1485(13) 0.2552(18) 0.4658(17) 0.088(6) Uani 1 1 d .
H26A H 0.0836 0.2148 0.4830 0.105 Uiso 1 1 calc R
H26B H 0.1323 0.3254 0.4537 0.105 Uiso 1 1 calc R
C27 C 0.1511(17) 0.1945(17) 0.3658(18) 0.098(7) Uani 1 1 d .
H27A H 0.2208 0.2278 0.3524 0.147 Uiso 1 1 calc R
H27B H 0.0835 0.1947 0.3055 0.147 Uiso 1 1 calc R
H27C H 0.1509 0.1194 0.3711 0.147 Uiso 1 1 calc R
C28 C 0.5590(9) 1.0132(9) 1.2245(10) 0.038(3) Uani 1 1 d .
C29 C 0.5590(9) 1.0948(10) 1.1669(10) 0.039(3) Uani 1 1 d .
C30 C 0.5202(11) 1.1879(10) 1.1964(11) 0.047(3) Uani 1 1 d .
C31 C 0.4834(13) 1.2016(11) 1.2863(12) 0.055(3) Uani 1 1 d .
C32 C 0.5241(10) 1.0317(10) 1.3168(10) 0.039(3) Uani 1 1 d .
C33 C 0.4863(12) 1.1228(11) 1.3468(11) 0.051(3) Uani 1 1 d .
C34 C 0.8936(9) 0.9300(10) 1.2333(10) 0.041(3) Uani 1 1 d .
C35 C 0.8746(10) 0.9804(10) 1.1461(11) 0.049(3) Uani 1 1 d .
C36 C 0.8770(14) 0.9342(13) 1.0403(12) 0.061(4) Uani 1 1 d .
C37 C 0.9054(12) 0.8361(11) 1.0250(11) 0.055(3) Uani 1 1 d .
C38 C 0.9278(10) 0.7818(10) 1.1095(11) 0.047(3) Uani 1 1 d .
C39 C 0.9219(10) 0.8302(11) 1.2102(11) 0.044(3) Uani 1 1 d .
F1 F 0.5945(7) 1.0899(7) 1.0781(6) 0.059(2) Uani 1 1 d .
F2 F 0.5173(8) 1.2660(7) 1.1364(8) 0.071(2) Uani 1 1 d .
F3 F 0.4454(12) 1.2922(8) 1.3138(10) 0.104(4) Uani 1 1 d .
F4 F 0.4484(12) 1.1362(9) 1.4358(9) 0.092(4) Uani 1 1 d .
F5 F 0.5230(8) 0.9570(7) 1.3793(8) 0.063(2) Uani 1 1 d .
F6 F 0.8474(8) 1.0808(7) 1.1577(9) 0.073(3) Uani 1 1 d .
F7 F 0.8538(11) 0.9875(10) 0.9613(9) 0.096(3) Uani 1 1 d .
F8 F 0.9095(11) 0.7886(9) 0.9271(8) 0.095(3) Uani 1 1 d .
F9 F 0.9545(9) 0.6835(7) 1.0937(8) 0.072(3) Uani 1 1 d .
F10 F 0.9412(7) 0.7715(7) 1.2901(7) 0.064(2) Uani 1 1 d .
N1 N 0.6412(8) 0.6466(8) 1.0707(8) 0.037(2) Uani 1 1 d .
N2 N 0.7988(9) 0.0945(9) 0.5762(9) 0.043(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C14 Au1 C28 174.5(5) . .
C14 Au1 Au2 100.9(3) . .
C28 Au1 Au2 84.3(3) . .
C15 Au2 C34 176.1(5) 1_566 .
C15 Au2 Au1 104.6(3) 1_566 .
C34 Au2 Au1 72.5(3) . .
C2 C1 C6 123.8(10) . .
C2 C1 N1 118.7(10) . .
C6 C1 N1 117.5(10) . .
C1 C2 C3 118.7(10) . .
C1 C2 H2 120.7 . .
C3 C2 H2 120.7 . .
C4 C3 C2 119.5(10) . .
C4 C3 H3 120.3 . .
C2 C3 H3 120.3 . .
C3 C4 C5 120.8(10) . .
C3 C4 C9 131.1(10) . .
C5 C4 C9 108.0(9) . .
C6 C5 C4 119.6(10) . .
C6 C5 C7 129.1(9) . .
C4 C5 C7 111.2(9) . .
C5 C6 C1 117.6(10) . .
C5 C6 H6 121.2 . .
C1 C6 H6 121.2 . .
C5 C7 C22 111.0(8) . .
C5 C7 C8 100.3(8) . .
C22 C7 C8 112.1(8) . .
C5 C7 C16 112.0(9) . .
C22 C7 C16 109.6(8) . .
C8 C7 C16 111.7(8) . .
C13 C8 C9 121.2(10) . .
C13 C8 C7 127.2(10) . .
C9 C8 C7 111.6(9) . .
C8 C9 C10 119.8(10) . .
C8 C9 C4 108.7(9) . .
C10 C9 C4 131.4(11) . .
C11 C10 C9 118.4(11) . .
C11 C10 H10 120.8 . .
C9 C10 H10 120.8 . .
C10 C11 C12 120.6(11) . .
C10 C11 H11 119.7 . .
C12 C11 H11 119.7 . .
C13 C12 C11 121.2(11) . .
C13 C12 N2 118.1(12) . .
C11 C12 N2 120.6(11) . .
C12 C13 C8 118.7(11) . .
C12 C13 H13 120.6 . .
C8 C13 H13 120.6 . .
N1 C14 Au1 175.5(11) . .
N2 C15 Au2 175.1(12) . 1_544
C7 C16 C17 113.9(9) . .
C7 C16 H16A 108.8 . .
C17 C16 H16A 108.8 . .
C7 C16 H16B 108.8 . .
C17 C16 H16B 108.8 . .
H16A C16 H16B 107.7 . .
C18 C17 C16 113.5(10) . .
C18 C17 H17A 108.9 . .
C16 C17 H17A 108.9 . .
C18 C17 H17B 108.9 . .
C16 C17 H17B 108.9 . .
H17A C17 H17B 107.7 . .
C19 C18 C17 112.7(11) . .
C19 C18 H18A 109.0 . .
C17 C18 H18A 109.0 . .
C19 C18 H18B 109.0 . .
C17 C18 H18B 109.0 . .
H18A C18 H18B 107.8 . .
C18 C19 C20 109.7(13) . .
C18 C19 H19A 109.7 . .
C20 C19 H19A 109.7 . .
C18 C19 H19B 109.7 . .
C20 C19 H19B 109.7 . .
H19A C19 H19B 108.2 . .
C21 C20 C19 113.1(17) . .
C21 C20 H20A 109.0 . .
C19 C20 H20A 109.0 . .
C21 C20 H20B 109.0 . .
C19 C20 H20B 109.0 . .
H20A C20 H20B 107.8 . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C23 C22 C7 114.4(9) . .
C23 C22 H22A 108.7 . .
C7 C22 H22A 108.7 . .
C23 C22 H22B 108.7 . .
C7 C22 H22B 108.7 . .
H22A C22 H22B 107.6 . .
C22 C23 C24 112.2(10) . .
C22 C23 H23A 109.2 . .
C24 C23 H23A 109.2 . .
C22 C23 H23B 109.2 . .
C24 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
C25 C24 C23 111.2(11) . .
C25 C24 H24A 109.4 . .
C23 C24 H24A 109.4 . .
C25 C24 H24B 109.4 . .
C23 C24 H24B 109.4 . .
H24A C24 H24B 108.0 . .
C26 C25 C24 115.1(14) . .
C26 C25 H25A 108.5 . .
C24 C25 H25A 108.5 . .
C26 C25 H25B 108.5 . .
C24 C25 H25B 108.5 . .
H25A C25 H25B 107.5 . .
C27 C26 C25 116.4(17) . .
C27 C26 H26A 108.2 . .
C25 C26 H26A 108.2 . .
C27 C26 H26B 108.2 . .
C25 C26 H26B 108.2 . .
H26A C26 H26B 107.3 . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C29 C28 C32 116.1(11) . .
C29 C28 Au1 122.4(9) . .
C32 C28 Au1 121.5(9) . .
F1 C29 C28 122.6(11) . .
F1 C29 C30 115.9(11) . .
C28 C29 C30 121.5(11) . .
F2 C30 C31 118.8(11) . .
F2 C30 C29 120.7(12) . .
C31 C30 C29 120.6(11) . .
F3 C31 C33 121.2(12) . .
F3 C31 C30 120.0(12) . .
C33 C31 C30 118.8(11) . .
F5 C32 C33 116.7(11) . .
F5 C32 C28 120.4(11) . .
C33 C32 C28 122.9(11) . .
C31 C33 C32 120.0(12) . .
C31 C33 F4 118.6(11) . .
C32 C33 F4 121.3(12) . .
C35 C34 C39 113.3(11) . .
C35 C34 Au2 121.5(9) . .
C39 C34 Au2 124.8(10) . .
C34 C35 F6 119.7(11) . .
C34 C35 C36 124.4(12) . .
F6 C35 C36 115.9(13) . .
F7 C36 C37 122.0(13) . .
F7 C36 C35 119.7(14) . .
C37 C36 C35 118.2(14) . .
F8 C37 C36 121.0(14) . .
F8 C37 C38 118.5(12) . .
C36 C37 C38 120.4(12) . .
F9 C38 C37 120.4(11) . .
F9 C38 C39 121.1(13) . .
C37 C38 C39 118.5(12) . .
F10 C39 C38 116.2(11) . .
F10 C39 C34 118.7(11) . .
C38 C39 C34 125.0(13) . .
C14 N1 C1 176.3(12) . .
C15 N2 C12 173.9(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C14 1.968(12) .
Au1 C28 2.036(11) .
Au1 Au2 3.3788(8) .
Au2 C15 1.957(15) 1_566
Au2 C34 2.030(12) .
C1 C2 1.358(16) .
C1 C6 1.401(15) .
C1 N1 1.419(14) .
C2 C3 1.405(15) .
C2 H2 0.9300 .
C3 C4 1.377(15) .
C3 H3 0.9300 .
C4 C5 1.424(14) .
C4 C9 1.449(15) .
C5 C6 1.380(16) .
C5 C7 1.506(14) .
C6 H6 0.9300 .
C7 C22 1.534(14) .
C7 C8 1.536(13) .
C7 C16 1.544(13) .
C8 C13 1.381(15) .
C8 C9 1.386(16) .
C9 C10 1.405(16) .
C10 C11 1.376(16) .
C10 H10 0.9300 .
C11 C12 1.393(17) .
C11 H11 0.9300 .
C12 C13 1.364(17) .
C12 N2 1.396(15) .
C13 H13 0.9300 .
C14 N1 1.145(15) .
C15 N2 1.162(17) .
C15 Au2 1.957(15) 1_544
C16 C17 1.560(16) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C18 1.544(16) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.51(2) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.56(2) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C21 1.47(3) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 C23 1.525(15) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 C24 1.544(17) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C25 1.517(17) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C26 1.51(2) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.41(3) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 C29 1.365(16) .
C28 C32 1.386(17) .
C29 F1 1.345(14) .
C29 C30 1.389(17) .
C30 F2 1.349(14) .
C30 C31 1.368(19) .
C31 F3 1.351(14) .
C31 C33 1.361(18) .
C32 F5 1.338(15) .
C32 C33 1.363(17) .
C33 F4 1.365(15) .
C34 C35 1.366(18) .
C34 C39 1.379(18) .
C35 F6 1.367(14) .
C35 C36 1.411(19) .
C36 F7 1.304(18) .
C36 C37 1.35(2) .
C37 F8 1.332(15) .
C37 C38 1.37(2) .
C38 F9 1.343(15) .
C38 C39 1.376(18) .
C39 F10 1.358(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C14 Au1 Au2 C15 -135.6(6) . 1_566
C28 Au1 Au2 C15 46.3(5) . 1_566
C14 Au1 Au2 C34 47.1(5) . .
C28 Au1 Au2 C34 -131.0(5) . .
C6 C1 C2 C3 2.7(16) . .
N1 C1 C2 C3 -177.9(9) . .
C1 C2 C3 C4 0.2(15) . .
C2 C3 C4 C5 -2.4(14) . .
C2 C3 C4 C9 179.8(10) . .
C3 C4 C5 C6 1.9(14) . .
C9 C4 C5 C6 -179.9(9) . .
C3 C4 C5 C7 -175.2(8) . .
C9 C4 C5 C7 3.0(11) . .
C4 C5 C6 C1 0.8(14) . .
C7 C5 C6 C1 177.4(10) . .
C2 C1 C6 C5 -3.2(15) . .
N1 C1 C6 C5 177.4(9) . .
C6 C5 C7 C22 -61.8(13) . .
C4 C5 C7 C22 115.0(9) . .
C6 C5 C7 C8 179.5(10) . .
C4 C5 C7 C8 -3.7(10) . .
C6 C5 C7 C16 61.0(14) . .
C4 C5 C7 C16 -122.3(9) . .
C5 C7 C8 C13 -176.1(10) . .
C22 C7 C8 C13 66.0(13) . .
C16 C7 C8 C13 -57.4(14) . .
C5 C7 C8 C9 3.2(10) . .
C22 C7 C8 C9 -114.6(9) . .
C16 C7 C8 C9 122.0(9) . .
C13 C8 C9 C10 0.9(15) . .
C7 C8 C9 C10 -178.5(9) . .
C13 C8 C9 C4 177.8(9) . .
C7 C8 C9 C4 -1.7(11) . .
C3 C4 C9 C8 177.2(10) . .
C5 C4 C9 C8 -0.8(11) . .
C3 C4 C9 C10 -6.4(18) . .
C5 C4 C9 C10 175.6(11) . .
C8 C9 C10 C11 0.6(16) . .
C4 C9 C10 C11 -175.5(10) . .
C9 C10 C11 C12 -1.5(17) . .
C10 C11 C12 C13 1.0(17) . .
C10 C11 C12 N2 179.0(11) . .
C11 C12 C13 C8 0.4(16) . .
N2 C12 C13 C8 -177.6(10) . .
C9 C8 C13 C12 -1.4(16) . .
C7 C8 C13 C12 177.9(10) . .
C28 Au1 C14 N1 35(15) . .
Au2 Au1 C14 N1 -125(12) . .
C5 C7 C16 C17 57.2(13) . .
C22 C7 C16 C17 -179.3(9) . .
C8 C7 C16 C17 -54.4(13) . .
C7 C16 C17 C18 179.4(10) . .
C16 C17 C18 C19 -73.0(15) . .
C17 C18 C19 C20 175.4(13) . .
C18 C19 C20 C21 178.3(19) . .
C5 C7 C22 C23 -49.6(12) . .
C8 C7 C22 C23 61.6(12) . .
C16 C7 C22 C23 -173.8(10) . .
C7 C22 C23 C24 -176.4(10) . .
C22 C23 C24 C25 177.2(13) . .
C23 C24 C25 C26 -170.8(16) . .
C24 C25 C26 C27 66(3) . .
C14 Au1 C28 C29 -59(5) . .
Au2 Au1 C28 C29 101.2(9) . .
C14 Au1 C28 C32 118(5) . .
Au2 Au1 C28 C32 -81.7(9) . .
C32 C28 C29 F1 177.7(10) . .
Au1 C28 C29 F1 -5.1(15) . .
C32 C28 C29 C30 -3.2(16) . .
Au1 C28 C29 C30 174.0(9) . .
F1 C29 C30 F2 1.3(17) . .
C28 C29 C30 F2 -177.9(11) . .
F1 C29 C30 C31 -179.3(12) . .
C28 C29 C30 C31 1.6(19) . .
F2 C30 C31 F3 0(2) . .
C29 C30 C31 F3 -179.7(13) . .
F2 C30 C31 C33 180.0(13) . .
C29 C30 C31 C33 1(2) . .
C29 C28 C32 F5 -179.0(11) . .
Au1 C28 C32 F5 3.7(15) . .
C29 C28 C32 C33 3.0(17) . .
Au1 C28 C32 C33 -174.2(10) . .
F3 C31 C33 C32 179.4(14) . .
C30 C31 C33 C32 -1(2) . .
F3 C31 C33 F4 1(2) . .
C30 C31 C33 F4 -179.3(14) . .
F5 C32 C33 C31 -179.1(13) . .
C28 C32 C33 C31 -1(2) . .
F5 C32 C33 F4 -1(2) . .
C28 C32 C33 F4 177.5(12) . .
C15 Au2 C34 C35 32(7) 1_566 .
Au1 Au2 C34 C35 74.2(9) . .
C15 Au2 C34 C39 -140(7) 1_566 .
Au1 Au2 C34 C39 -98.2(10) . .
C39 C34 C35 F6 -179.1(10) . .
Au2 C34 C35 F6 7.6(15) . .
C39 C34 C35 C36 3.2(18) . .
Au2 C34 C35 C36 -170.0(11) . .
C34 C35 C36 F7 177.7(13) . .
F6 C35 C36 F7 0(2) . .
C34 C35 C36 C37 -3(2) . .
F6 C35 C36 C37 178.9(12) . .
F7 C36 C37 F8 -1(2) . .
C35 C36 C37 F8 -179.7(13) . .
F7 C36 C37 C38 -179.2(14) . .
C35 C36 C37 C38 2(2) . .
F8 C37 C38 F9 1(2) . .
C36 C37 C38 F9 179.1(13) . .
F8 C37 C38 C39 -179.1(12) . .
C36 C37 C38 C39 -1(2) . .
F9 C38 C39 F10 -1.9(17) . .
C37 C38 C39 F10 178.0(11) . .
F9 C38 C39 C34 -179.1(11) . .
C37 C38 C39 C34 0.8(19) . .
C35 C34 C39 F10 -179.1(10) . .
Au2 C34 C39 F10 -6.1(15) . .
C35 C34 C39 C38 -1.9(17) . .
Au2 C34 C39 C38 171.1(9) . .
Au1 C14 N1 C1 13(27) . .
C2 C1 N1 C14 -173(16) . .
C6 C1 N1 C14 6(17) . .
Au2 C15 N2 C12 -36(22) 1_544 .
C13 C12 N2 C15 18(12) . .
C11 C12 N2 C15 -160(11) . .
