#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:54:05 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180280 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/66/7116627.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116627
loop_
_publ_author_name
'Surendar Karwasara'
'Dhirendra Yadav'
'Chandan Kumar Jha'
'Gopalan Rajaraman'
'Selvarajan Nagendran'
_publ_section_title
;
 Single-step conversion of silathiogermylene to germaacid anhydrides:
 unusual reactivity
;
_journal_name_full               Chem.Commun.
_journal_page_first              4310
_journal_paper_doi               10.1039/C5cc00169B
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C30 H46 Ge2 N4 S3'
_chemical_formula_sum            'C30 H46 Ge2 N4 S3'
_chemical_formula_weight         704.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-10-08 deposited with the CCDC.
2015-02-02 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 106.005(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.400(4)
_cell_length_b                   11.364(3)
_cell_length_c                   18.733(5)
_cell_measurement_reflns_used    3366
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.000
_cell_measurement_theta_min      2.58
_cell_volume                     3355.9(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0503
_diffrn_reflns_av_sigmaI/netI    0.0602
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            17191
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.29
_exptl_absorpt_coefficient_mu    2.003
_exptl_absorpt_correction_T_max  0.600
_exptl_absorpt_correction_T_min  0.447
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.394
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1464.0
_exptl_crystal_size_max          0.474
_exptl_crystal_size_mid          0.339
_exptl_crystal_size_min          0.255
_refine_diff_density_max         0.774
_refine_diff_density_min         -0.359
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     360
_refine_ls_number_reflns         5903
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0599
_refine_ls_R_factor_gt           0.0426
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0481P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0921
_refine_ls_wR_factor_ref         0.0981
_reflns_number_gt                4692
_reflns_number_total             5904
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc00169b2.cif
_cod_data_source_block           4
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7116627
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.35207(2) 0.28950(3) 0.43036(2) 0.01917(12) Uani 1 1 d .
Ge2 Ge 0.18557(2) 0.17880(3) 0.28259(2) 0.01919(12) Uani 1 1 d .
S3 S 0.32319(6) 0.22066(8) 0.31522(6) 0.0261(2) Uani 1 1 d .
S2 S 0.13786(6) 0.07887(8) 0.35481(6) 0.0276(2) Uani 1 1 d .
S1 S 0.27474(6) 0.40886(8) 0.46535(6) 0.0251(2) Uani 1 1 d .
N1 N 0.46605(18) 0.3382(2) 0.44486(17) 0.0207(7) Uani 1 1 d .
N2 N 0.40083(19) 0.1653(2) 0.49477(17) 0.0201(7) Uani 1 1 d .
N3 N 0.11972(18) 0.3096(2) 0.23745(17) 0.0206(7) Uani 1 1 d .
N4 N 0.17393(18) 0.1304(2) 0.18346(17) 0.0185(7) Uani 1 1 d .
C7 C 0.4846(2) 0.1768(3) 0.5268(2) 0.0204(8) Uani 1 1 d .
C17 C 0.0189(2) 0.3680(3) 0.1246(2) 0.0242(9) Uani 1 1 d .
H17 H -0.0053 0.4144 0.1543 0.029 Uiso 1 1 calc R
C22 C 0.1249(2) 0.2024(3) 0.1317(2) 0.0194(8) Uani 1 1 d .
C16 C 0.0872(2) 0.2987(3) 0.1636(2) 0.0198(8) Uani 1 1 d .
C9 C 0.3469(2) 0.0695(3) 0.5092(2) 0.0227(9) Uani 1 1 d .
H9A H 0.3831 0.0047 0.5322 0.027 Uiso 1 1 calc R
H9B H 0.3110 0.0418 0.4621 0.027 Uiso 1 1 calc R
C27 C 0.2155(3) 0.5382(3) 0.2714(2) 0.0327(10) Uani 1 1 d .
H27A H 0.2278 0.6163 0.2577 0.049 Uiso 1 1 calc R
H27B H 0.2308 0.4821 0.2390 0.049 Uiso 1 1 calc R
H27C H 0.2475 0.5228 0.3218 0.049 Uiso 1 1 calc R
C18 C -0.0182(2) 0.3787(3) 0.0498(2) 0.0291(10) Uani 1 1 d .
H18 H -0.0661 0.4265 0.0368 0.035 Uiso 1 1 calc R
C6 C 0.5286(2) 0.1027(3) 0.5849(2) 0.0269(9) Uani 1 1 d .
H6 H 0.4947 0.0469 0.5992 0.032 Uiso 1 1 calc R
C21 C 0.1171(2) 0.1883(3) 0.0559(2) 0.0250(9) Uani 1 1 d .
H21 H 0.1516 0.1299 0.0451 0.030 Uiso 1 1 calc R
C24 C 0.2183(2) 0.0284(3) 0.1622(2) 0.0256(9) Uani 1 1 d .
H24A H 0.2603 -0.0003 0.2059 0.031 Uiso 1 1 calc R
H24B H 0.2480 0.0543 0.1269 0.031 Uiso 1 1 calc R
C1 C 0.5231(2) 0.2749(3) 0.4951(2) 0.0190(8) Uani 1 1 d .
C10 C 0.4837(3) 0.4394(3) 0.3308(2) 0.0331(10) Uani 1 1 d .
H10 H 0.4274 0.4126 0.3020 0.040 Uiso 1 1 calc R
C23 C 0.0948(2) 0.4035(3) 0.2813(2) 0.0257(9) Uani 1 1 d .
H23A H 0.1196 0.3870 0.3336 0.031 Uiso 1 1 calc R
H23B H 0.0336 0.4017 0.2721 0.031 Uiso 1 1 calc R
C3 C 0.6784(2) 0.2531(3) 0.5663(2) 0.0322(10) Uani 1 1 d .
H3 H 0.7307 0.2862 0.5676 0.039 Uiso 1 1 calc R
C11 C 0.2908(2) 0.1024(3) 0.5585(2) 0.0269(9) Uani 1 1 d .
H11 H 0.2515 0.1636 0.5327 0.032 Uiso 1 1 calc R
C20 C 0.0671(2) 0.2458(3) -0.0057(2) 0.0292(9) Uani 1 1 d .
H20 H 0.0767 0.2256 -0.0508 0.035 Uiso 1 1 calc R
C8 C 0.4834(2) 0.4491(3) 0.4116(2) 0.0256(9) Uani 1 1 d .
H8A H 0.5381 0.4786 0.4403 0.031 Uiso 1 1 calc R
H8B H 0.4409 0.5064 0.4153 0.031 Uiso 1 1 calc R
C2 C 0.6100(2) 0.3003(3) 0.5140(2) 0.0292(9) Uani 1 1 d .
H2 H 0.6243 0.3604 0.4860 0.035 Uiso 1 1 calc R
C5 C 0.6128(3) 0.0983(3) 0.6244(2) 0.0327(10) Uani 1 1 d .
H5 H 0.6260 0.0422 0.6620 0.039 Uiso 1 1 calc R
C19 C 0.0046(3) 0.3294(3) -0.0094(2) 0.0336(10) Uani 1 1 d .
H19 H -0.0250 0.3550 -0.0566 0.040 Uiso 1 1 calc R
C26 C 0.1589(2) -0.0730(3) 0.1279(2) 0.0266(9) Uani 1 1 d .
H26 H 0.1095 -0.0397 0.0915 0.032 Uiso 1 1 calc R
C4 C 0.6811(3) 0.1641(3) 0.6169(2) 0.0333(10) Uani 1 1 d .
H4 H 0.7339 0.1465 0.6492 0.040 Uiso 1 1 calc R
C25 C 0.1212(3) 0.5278(3) 0.2647(2) 0.0298(10) Uani 1 1 d .
H25 H 0.0897 0.5481 0.2137 0.036 Uiso 1 1 calc R
C14 C 0.3390(3) 0.1513(4) 0.6336(2) 0.0412(12) Uani 1 1 d .
H14A H 0.3744 0.0908 0.6621 0.062 Uiso 1 1 calc R
H14B H 0.2995 0.1779 0.6596 0.062 Uiso 1 1 calc R
H14C H 0.3737 0.2160 0.6268 0.062 Uiso 1 1 calc R
C15 C 0.2381(3) -0.0044(4) 0.5668(2) 0.0398(11) Uani 1 1 d .
H15A H 0.2097 -0.0349 0.5185 0.060 Uiso 1 1 calc R
H15B H 0.1967 0.0183 0.5918 0.060 Uiso 1 1 calc R
H15C H 0.2745 -0.0639 0.5952 0.060 Uiso 1 1 calc R
C28 C 0.0941(3) 0.6123(3) 0.3172(3) 0.0406(12) Uani 1 1 d .
H28A H 0.1230 0.5924 0.3677 0.061 Uiso 1 1 calc R
H28B H 0.0340 0.6063 0.3099 0.061 Uiso 1 1 calc R
H28C H 0.1083 0.6914 0.3072 0.061 Uiso 1 1 calc R
C29 C 0.1279(3) -0.1369(4) 0.1856(3) 0.0437(12) Uani 1 1 d .
H29A H 0.0864 -0.1944 0.1619 0.066 Uiso 1 1 calc R
H29B H 0.1028 -0.0816 0.2120 0.066 Uiso 1 1 calc R
H29C H 0.1748 -0.1754 0.2198 0.066 Uiso 1 1 calc R
C13 C 0.4985(4) 0.5615(4) 0.3027(3) 0.0613(16) Uani 1 1 d .
H13A H 0.5515 0.5922 0.3327 0.092 Uiso 1 1 calc R
H13B H 0.4532 0.6130 0.3059 0.092 Uiso 1 1 calc R
H13C H 0.5002 0.5562 0.2520 0.092 Uiso 1 1 calc R
C30 C 0.2032(3) -0.1566(4) 0.0871(3) 0.0549(15) Uani 1 1 d .
H30A H 0.2531 -0.1880 0.1214 0.082 Uiso 1 1 calc R
H30B H 0.2189 -0.1146 0.0484 0.082 Uiso 1 1 calc R
H30C H 0.1655 -0.2197 0.0657 0.082 Uiso 1 1 calc R
C12 C 0.5484(3) 0.3521(4) 0.3188(3) 0.0527(13) Uani 1 1 d .
H12A H 0.6043 0.3782 0.3449 0.079 Uiso 1 1 calc R
H12B H 0.5438 0.3463 0.2667 0.079 Uiso 1 1 calc R
H12C H 0.5380 0.2763 0.3373 0.079 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N2 Ge1 N1 84.23(12)
N2 Ge1 S1 118.28(10)
N1 Ge1 S1 115.26(9)
N2 Ge1 S3 107.30(9)
N1 Ge1 S3 100.36(10)
S1 Ge1 S3 123.39(4)
N3 Ge2 N4 84.21(12)
N3 Ge2 S2 116.68(10)
N4 Ge2 S2 121.68(9)
N3 Ge2 S3 111.46(9)
N4 Ge2 S3 98.74(9)
S2 Ge2 S3 118.33(4)
Ge1 S3 Ge2 105.74(4)
C1 N1 C8 125.5(3)
C1 N1 Ge1 114.4(2)
C8 N1 Ge1 119.2(2)
C7 N2 C9 125.5(3)
C7 N2 Ge1 114.4(2)
C9 N2 Ge1 120.0(2)
C16 N3 C23 123.3(3)
C16 N3 Ge2 113.7(2)
C23 N3 Ge2 122.1(2)
C22 N4 C24 121.4(3)
C22 N4 Ge2 114.0(2)
C24 N4 Ge2 124.5(2)
N2 C7 C6 122.0(3)
N2 C7 C1 112.9(3)
C6 C7 C1 125.1(3)
C18 C17 C16 130.4(4)
C18 C17 H17 114.8
C16 C17 H17 114.8
N4 C22 C21 121.9(3)
N4 C22 C16 113.2(3)
C21 C22 C16 124.7(3)
N3 C16 C17 121.2(3)
N3 C16 C22 113.4(3)
C17 C16 C22 125.2(4)
N2 C9 C11 115.2(3)
N2 C9 H9A 108.5
C11 C9 H9A 108.5
N2 C9 H9B 108.5
C11 C9 H9B 108.5
H9A C9 H9B 107.5
C25 C27 H27A 109.5
C25 C27 H27B 109.5
H27A C27 H27B 109.5
C25 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
C17 C18 C19 130.0(4)
C17 C18 H18 115.0
C19 C18 H18 115.0
C5 C6 C7 131.5(4)
C5 C6 H6 114.3
C7 C6 H6 114.3
C20 C21 C22 131.3(4)
C20 C21 H21 114.3
C22 C21 H21 114.3
N4 C24 C26 113.6(3)
N4 C24 H24A 108.9
C26 C24 H24A 108.9
N4 C24 H24B 108.9
C26 C24 H24B 108.9
H24A C24 H24B 107.7
N1 C1 C2 122.1(3)
N1 C1 C7 113.2(3)
C2 C1 C7 124.7(3)
C12 C10 C8 113.0(3)
C12 C10 C13 111.1(4)
C8 C10 C13 108.7(3)
C12 C10 H10 108.0
C8 C10 H10 108.0
C13 C10 H10 108.0
N3 C23 C25 114.6(3)
N3 C23 H23A 108.6
C25 C23 H23A 108.6
N3 C23 H23B 108.6
C25 C23 H23B 108.6
H23A C23 H23B 107.6
C4 C3 C2 129.8(4)
C4 C3 H3 115.1
C2 C3 H3 115.1
C14 C11 C9 113.9(3)
C14 C11 C15 111.3(3)
C9 C11 C15 108.8(3)
C14 C11 H11 107.5
C9 C11 H11 107.5
C15 C11 H11 107.5
C21 C20 C19 128.9(4)
C21 C20 H20 115.6
C19 C20 H20 115.6
N1 C8 C10 114.5(3)
N1 C8 H8A 108.6
C10 C8 H8A 108.6
N1 C8 H8B 108.6
C10 C8 H8B 108.6
H8A C8 H8B 107.6
C3 C2 C1 132.2(4)
C3 C2 H2 113.9
C1 C2 H2 113.9
C6 C5 C4 130.2(4)
C6 C5 H5 114.9
C4 C5 H5 114.9
C18 C19 C20 126.7(4)
C18 C19 H19 116.7
C20 C19 H19 116.7
C29 C26 C30 111.3(3)
C29 C26 C24 111.3(3)
C30 C26 C24 110.1(3)
C29 C26 H26 108.0
C30 C26 H26 108.0
C24 C26 H26 108.0
C3 C4 C5 126.3(4)
C3 C4 H4 116.9
C5 C4 H4 116.9
C27 C25 C28 111.6(3)
C27 C25 C23 113.1(3)
C28 C25 C23 107.5(3)
C27 C25 H25 108.2
C28 C25 H25 108.2
C23 C25 H25 108.2
C11 C14 H14A 109.5
C11 C14 H14B 109.5
H14A C14 H14B 109.5
C11 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C11 C15 H15A 109.5
C11 C15 H15B 109.5
H15A C15 H15B 109.5
C11 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C25 C28 H28A 109.5
C25 C28 H28B 109.5
H28A C28 H28B 109.5
C25 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C26 C29 H29A 109.5
C26 C29 H29B 109.5
H29A C29 H29B 109.5
C26 C29 H29C 109.5
H29A C29 H29C 109.5
H29B C29 H29C 109.5
C10 C13 H13A 109.5
C10 C13 H13B 109.5
H13A C13 H13B 109.5
C10 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C26 C30 H30A 109.5
C26 C30 H30B 109.5
H30A C30 H30B 109.5
C26 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
C10 C12 H12A 109.5
C10 C12 H12B 109.5
H12A C12 H12B 109.5
C10 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Ge1 N2 1.886(3)
Ge1 N1 1.896(3)
Ge1 S1 2.0824(10)
Ge1 S3 2.2192(12)
Ge2 N3 1.894(3)
Ge2 N4 1.895(3)
Ge2 S2 2.0774(11)
Ge2 S3 2.2212(11)
N1 C1 1.339(4)
N1 C8 1.468(4)
N2 C7 1.345(4)
N2 C9 1.474(4)
N3 C16 1.345(5)
N3 C23 1.472(4)
N4 C22 1.351(4)
N4 C24 1.480(4)
C7 C6 1.407(5)
C7 C1 1.484(5)
C17 C18 1.371(5)
C17 C16 1.400(5)
C17 H17 0.9300
C22 C21 1.399(5)
C22 C16 1.462(5)
C9 C11 1.518(5)
C9 H9A 0.9700
C9 H9B 0.9700
C27 C25 1.522(5)
C27 H27A 0.9600
C27 H27B 0.9600
C27 H27C 0.9600
C18 C19 1.383(6)
C18 H18 0.9300
C6 C5 1.376(5)
C6 H6 0.9300
C21 C20 1.381(5)
C21 H21 0.9300
C24 C26 1.531(5)
C24 H24A 0.9700
C24 H24B 0.9700
C1 C2 1.401(5)
C10 C12 1.513(6)
C10 C8 1.520(5)
C10 C13 1.527(5)
C10 H10 0.9800
C23 C25 1.534(5)
C23 H23A 0.9700
C23 H23B 0.9700
C3 C4 1.378(6)
C3 C2 1.379(5)
C3 H3 0.9300
C11 C14 1.517(5)
C11 C15 1.523(5)
C11 H11 0.9800
C20 C19 1.385(5)
C20 H20 0.9300
C8 H8A 0.9700
C8 H8B 0.9700
C2 H2 0.9300
C5 C4 1.386(6)
C5 H5 0.9300
C19 H19 0.9300
C26 C29 1.502(6)
C26 C30 1.523(5)
C26 H26 0.9800
C4 H4 0.9300
C25 C28 1.526(5)
C25 H25 0.9800
C14 H14A 0.9600
C14 H14B 0.9600
C14 H14C 0.9600
C15 H15A 0.9600
C15 H15B 0.9600
C15 H15C 0.9600
C28 H28A 0.9600
C28 H28B 0.9600
C28 H28C 0.9600
C29 H29A 0.9600
C29 H29B 0.9600
C29 H29C 0.9600
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
C30 H30A 0.9600
C30 H30B 0.9600
C30 H30C 0.9600
C12 H12A 0.9600
C12 H12B 0.9600
C12 H12C 0.9600
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N2 Ge1 S3 Ge2 99.69(10)
N1 Ge1 S3 Ge2 -173.19(9)
S1 Ge1 S3 Ge2 -43.39(6)
N3 Ge2 S3 Ge1 90.04(11)
N4 Ge2 S3 Ge1 177.22(8)
S2 Ge2 S3 Ge1 -49.42(6)
N2 Ge1 N1 C1 -5.7(3)
S1 Ge1 N1 C1 112.9(2)
S3 Ge1 N1 C1 -112.3(2)
N2 Ge1 N1 C8 -175.7(3)
S1 Ge1 N1 C8 -57.1(3)
S3 Ge1 N1 C8 77.7(3)
N1 Ge1 N2 C7 8.5(3)
S1 Ge1 N2 C7 -107.1(2)
S3 Ge1 N2 C7 107.6(2)
N1 Ge1 N2 C9 -174.5(3)
S1 Ge1 N2 C9 69.9(3)
S3 Ge1 N2 C9 -75.4(3)
N4 Ge2 N3 C16 9.2(3)
S2 Ge2 N3 C16 -113.5(2)
S3 Ge2 N3 C16 106.3(2)
N4 Ge2 N3 C23 179.1(3)
S2 Ge2 N3 C23 56.4(3)
S3 Ge2 N3 C23 -83.8(3)
N3 Ge2 N4 C22 -2.9(2)
S2 Ge2 N4 C22 115.0(2)
S3 Ge2 N4 C22 -113.8(2)
N3 Ge2 N4 C24 172.9(3)
S2 Ge2 N4 C24 -69.2(3)
S3 Ge2 N4 C24 62.1(3)
C9 N2 C7 C6 -6.9(5)
Ge1 N2 C7 C6 169.8(3)
C9 N2 C7 C1 173.8(3)
Ge1 N2 C7 C1 -9.4(4)
C24 N4 C22 C21 -3.5(5)
Ge2 N4 C22 C21 172.5(3)
C24 N4 C22 C16 -179.4(3)
Ge2 N4 C22 C16 -3.4(4)
C23 N3 C16 C17 -8.3(5)
Ge2 N3 C16 C17 161.4(3)
C23 N3 C16 C22 177.0(3)
Ge2 N3 C16 C22 -13.2(4)
C18 C17 C16 N3 173.2(4)
C18 C17 C16 C22 -12.8(6)
N4 C22 C16 N3 10.9(4)
C21 C22 C16 N3 -164.9(3)
N4 C22 C16 C17 -163.5(3)
C21 C22 C16 C17 20.7(6)
C7 N2 C9 C11 103.6(4)
Ge1 N2 C9 C11 -73.0(4)
C16 C17 C18 C19 -4.6(7)
N2 C7 C6 C5 179.2(4)
C1 C7 C6 C5 -1.7(7)
N4 C22 C21 C20 175.2(4)
C16 C22 C21 C20 -9.4(6)
C22 N4 C24 C26 -72.4(4)
Ge2 N4 C24 C26 112.1(3)
C8 N1 C1 C2 -9.2(6)
Ge1 N1 C1 C2 -178.5(3)
C8 N1 C1 C7 171.3(3)
Ge1 N1 C1 C7 2.0(4)
N2 C7 C1 N1 4.8(4)
C6 C7 C1 N1 -174.4(3)
N2 C7 C1 C2 -174.6(3)
C6 C7 C1 C2 6.1(6)
C16 N3 C23 C25 -66.9(4)
Ge2 N3 C23 C25 124.2(3)
N2 C9 C11 C14 -56.4(4)
N2 C9 C11 C15 178.8(3)
C22 C21 C20 C19 -5.6(7)
C1 N1 C8 C10 107.8(4)
Ge1 N1 C8 C10 -83.3(4)
C12 C10 C8 N1 -58.6(5)
C13 C10 C8 N1 177.6(3)
C4 C3 C2 C1 -0.1(7)
N1 C1 C2 C3 175.4(4)
C7 C1 C2 C3 -5.2(7)
C7 C6 C5 C4 -2.4(7)
C17 C18 C19 C20 7.4(7)
C21 C20 C19 C18 3.9(7)
N4 C24 C26 C29 -73.0(4)
N4 C24 C26 C30 163.1(4)
C2 C3 C4 C5 2.3(7)
C6 C5 C4 C3 0.8(7)
N3 C23 C25 C27 -53.8(5)
N3 C23 C25 C28 -177.4(3)
