#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:59:58 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180283 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/69/7116926.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116926
loop_
_publ_author_name
'Yin-Ling Hou'
'Hang Xu'
'Rui-Rui Cheng'
'Bin Zhao'
_publ_section_title
;
 Controlled lanthanide-organic framework nanospheres as reversible and
 sensitive luminescent sensors for practical applications
;
_journal_name_full               Chem.Commun.
_journal_page_first              6769
_journal_paper_doi               10.1039/C5cc01181G
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C36 H52 Eu2 N8 O22'
_chemical_formula_weight         1252.78
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-12-04 deposited with the CCDC.
2015-03-06 downloaded from the CCDC.
;
_cell_angle_alpha                99.680(5)
_cell_angle_beta                 91.009(4)
_cell_angle_gamma                117.103(5)
_cell_formula_units_Z            2
_cell_length_a                   13.2205(6)
_cell_length_b                   13.9973(8)
_cell_length_c                   14.9000(8)
_cell_measurement_reflns_used    9167
_cell_measurement_temperature    122.5(8)
_cell_measurement_theta_max      29.1192
_cell_measurement_theta_min      2.3715
_cell_volume                     2405.6(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      122.5(8)
_diffrn_detector_area_resol_mean 16.2116
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'SuperNova, Single source at offset), Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            14209
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.38
_exptl_absorpt_coefficient_mu    2.670
_exptl_absorpt_correction_T_max  0.6450
_exptl_absorpt_correction_T_min  0.5911
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1252
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         2.646
_refine_diff_density_min         -1.416
_refine_diff_density_rms         0.145
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    Constrained
_refine_ls_matrix_type           full
_refine_ls_number_parameters     638
_refine_ls_number_reflns         8406
_refine_ls_number_restraints     83
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0477
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0198P)²+11.7029P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0780
_refine_ls_wR_factor_ref         0.0842
_reflns_number_gt                7034
_reflns_number_total             8406
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc01181g2.cif
_cod_data_source_block           added_by_encifer
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3105 2015-03-04 15:46:00Z robertas 
;
_cod_original_cell_volume        2405.5(2)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7116926
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.48974(2) -0.14677(2) 0.459634(18) 0.00778(8) Uani 1 1 d . . .
Eu2 Eu 1.15523(2) 0.14805(2) 0.038690(18) 0.00862(8) Uani 1 1 d . . .
C1 C 0.6678(6) -0.2634(6) 0.4083(5) 0.0284(16) Uani 1 1 d . A .
H1 H 0.709(6) -0.246(6) 0.474(5) 0.034 Uiso 1 1 d . . .
C2A C 0.678(2) -0.331(2) 0.2511(7) 0.055(3) Uani 0.48(2) 1 d PDU A 1
H2AA H 0.5995 -0.3785 0.2290 0.083 Uiso 0.48(2) 1 calc PR A 1
H2AB H 0.7253 -0.3584 0.2199 0.083 Uiso 0.48(2) 1 calc PR A 1
H2AC H 0.6990 -0.2588 0.2396 0.083 Uiso 0.48(2) 1 calc PR A 1
C2B C 0.6228(18) -0.3771(18) 0.2586(10) 0.055(3) Uani 0.52(2) 1 d PDU A 2
H2BA H 0.5475 -0.3852 0.2659 0.083 Uiso 0.52(2) 1 calc PR A 2
H2BB H 0.6183 -0.4478 0.2380 0.083 Uiso 0.52(2) 1 calc PR A 2
H2BC H 0.6559 -0.3321 0.2144 0.083 Uiso 0.52(2) 1 calc PR A 2
C3A C 0.7884(9) -0.3467(12) 0.3796(11) 0.037(3) Uani 0.68(2) 1 d PDU A 1
H3AA H 0.8512 -0.3174 0.3437 0.056 Uiso 0.68(2) 1 calc PR A 1
H3AB H 0.7605 -0.4242 0.3726 0.056 Uiso 0.68(2) 1 calc PR A 1
H3AC H 0.8136 -0.3125 0.4429 0.056 Uiso 0.68(2) 1 calc PR A 1
C3B C 0.761(2) -0.384(2) 0.340(2) 0.037(3) Uani 0.32(2) 1 d PDU A 2
H3BA H 0.8216 -0.3518 0.3895 0.056 Uiso 0.32(2) 1 calc PR A 2
H3BB H 0.7939 -0.3795 0.2827 0.056 Uiso 0.32(2) 1 calc PR A 2
H3BC H 0.7127 -0.4590 0.3425 0.056 Uiso 0.32(2) 1 calc PR A 2
C4 C 0.4541(5) -0.2242(5) 0.2338(4) 0.0179(13) Uani 1 1 d . A .
H4 H 0.5327 -0.1797 0.2396 0.022 Uiso 1 1 calc R . .
C5 C 0.4660(6) -0.2700(6) 0.0715(4) 0.0318(17) Uani 1 1 d . . .
H5A H 0.4385 -0.2401 0.0293 0.048 Uiso 1 1 calc R . .
H5B H 0.4557 -0.3408 0.0422 0.048 Uiso 1 1 calc R . .
H5C H 0.5457 -0.2222 0.0905 0.048 Uiso 1 1 calc R . .
C6 C 0.2788(5) -0.3534(6) 0.1369(4) 0.0291(16) Uani 1 1 d . . .
H6A H 0.2475 -0.3559 0.1947 0.044 Uiso 1 1 calc R . .
H6B H 0.2649 -0.4257 0.1082 0.044 Uiso 1 1 calc R . .
H6C H 0.2430 -0.3267 0.0981 0.044 Uiso 1 1 calc R . .
C7 C 0.6428(5) 0.0765(4) 0.3667(3) 0.0107(12) Uani 1 1 d . A .
C8 C 0.7410(4) 0.1293(4) 0.3120(4) 0.0103(11) Uani 1 1 d . . .
C9 C 0.8113(5) 0.2437(4) 0.3345(4) 0.0133(12) Uani 1 1 d . . .
H9 H 0.7941 0.2865 0.3801 0.016 Uiso 1 1 calc R . .
C10 C 0.9049(5) 0.2911(4) 0.2888(4) 0.0116(12) Uani 1 1 d . . .
C11 C 0.9311(4) 0.2280(4) 0.2190(4) 0.0125(12) Uani 1 1 d . . .
H11 H 0.9964 0.2604 0.1898 0.015 Uiso 1 1 calc R . .
C12 C 0.8584(5) 0.1171(4) 0.1943(4) 0.0119(12) Uani 1 1 d . . .
C13 C 0.7631(5) 0.0672(4) 0.2414(3) 0.0103(11) Uani 1 1 d . . .
H13 H 0.7150 -0.0078 0.2249 0.012 Uiso 1 1 calc R . .
C14 C 0.8781(5) 0.0479(5) 0.1147(4) 0.0140(12) Uani 1 1 d U . .
C15 C 1.3717(5) 0.1017(6) 0.0872(4) 0.0261(15) Uani 1 1 d . . .
H15 H 1.3301 0.0366 0.0452 0.031 Uiso 1 1 calc R . .
C16 C 1.4767(8) 0.0146(7) 0.1393(6) 0.059(3) Uani 1 1 d . . .
H16A H 1.4184 -0.0476 0.0981 0.070 Uiso 1 1 calc R . .
H16B H 1.4757 -0.0017 0.1994 0.070 Uiso 1 1 calc R . .
H16C H 1.5500 0.0314 0.1183 0.070 Uiso 1 1 calc R . .
C17 C 1.5226(6) 0.2051(6) 0.2119(5) 0.043(2) Uani 1 1 d . . .
H17A H 1.5065 0.2635 0.2032 0.064 Uiso 1 1 calc R . .
H17B H 1.6022 0.2272 0.2075 0.064 Uiso 1 1 calc R . .
H17C H 1.5040 0.1885 0.2712 0.064 Uiso 1 1 calc R . .
C18 C 1.2752(5) 0.2842(5) 0.2585(4) 0.0237(15) Uani 1 1 d . . .
H18 H 1.3075 0.2409 0.2720 0.028 Uiso 1 1 calc R . .
C19 C 1.3972(6) 0.4196(6) 0.3890(5) 0.042(2) Uani 1 1 d . . .
H19A H 1.3633 0.4317 0.4433 0.063 Uiso 1 1 calc R . .
H19B H 1.4622 0.4867 0.3833 0.063 Uiso 1 1 calc R . .
H19C H 1.4210 0.3649 0.3928 0.063 Uiso 1 1 calc R . .
C20 C 1.2660(6) 0.4528(6) 0.2935(5) 0.0345(12) Uani 1 1 d U . .
H20A H 1.2374 0.4355 0.2301 0.052 Uiso 1 1 calc R . .
H20B H 1.3239 0.5278 0.3091 0.052 Uiso 1 1 calc R . .
H20C H 1.2045 0.4420 0.3307 0.052 Uiso 1 1 calc R . .
C21 C 0.9478(5) 0.4708(5) 0.3677(4) 0.0179(13) Uani 1 1 d . . .
H21A H 0.9469 0.4533 0.4281 0.021 Uiso 1 1 calc R . .
H21B H 0.8722 0.4595 0.3481 0.021 Uiso 1 1 calc R . .
C22 C 1.0344(5) 0.5874(4) 0.3707(4) 0.0154(12) Uani 1 1 d . . .
H22A H 1.0289 0.6346 0.4239 0.018 Uiso 1 1 calc R . .
H22B H 1.1109 0.5945 0.3744 0.018 Uiso 1 1 calc R . .
C23 C 1.0756(4) 0.7262(4) 0.2821(4) 0.0099(11) Uani 1 1 d . . .
C24 C 1.0391(5) 0.7620(5) 0.2123(4) 0.0127(12) Uani 1 1 d . . .
H24 H 0.9743 0.7130 0.1725 0.015 Uiso 1 1 calc R . .
C25 C 1.0981(4) 0.8697(4) 0.2012(4) 0.0101(11) Uani 1 1 d . . .
C26 C 1.1944(5) 0.9447(4) 0.2631(4) 0.0135(12) Uani 1 1 d . . .
H26 H 1.2334 1.0177 0.2577 0.016 Uiso 1 1 calc R . .
C27 C 1.2300(5) 0.9081(4) 0.3319(3) 0.0102(11) Uani 1 1 d . . .
C28 C 1.1730(5) 0.7992(4) 0.3418(4) 0.0117(12) Uani 1 1 d . . .
H28 H 1.1995 0.7757 0.3874 0.014 Uiso 1 1 calc R . .
C29 C 1.3302(4) 0.9882(4) 0.3999(4) 0.0104(11) Uani 1 1 d U . .
C30 C 1.0585(5) 0.9103(5) 0.1270(4) 0.0138(12) Uani 1 1 d . . .
C31 C 1.0572(9) 0.1196(9) 0.3646(6) 0.063(3) Uani 1 1 d . . .
H31 H 1.0817 0.1016 0.3091 0.075 Uiso 1 1 calc R . .
C32 C 0.9093(7) 0.0606(9) 0.4686(6) 0.058(3) Uani 1 1 d . . .
H32A H 0.9132 0.0129 0.5063 0.069 Uiso 1 1 calc R . .
H32B H 0.8308 0.0424 0.4537 0.069 Uiso 1 1 calc R . .
H32C H 0.9501 0.1352 0.5010 0.069 Uiso 1 1 calc R . .
C33 C 0.8979(9) -0.0585(8) 0.3260(6) 0.065(3) Uani 1 1 d . . .
H33A H 0.9279 -0.0539 0.2677 0.079 Uiso 1 1 calc R . .
H33B H 0.8179 -0.0791 0.3180 0.079 Uiso 1 1 calc R . .
H33C H 0.9082 -0.1123 0.3516 0.079 Uiso 1 1 calc R . .
C34 C 0.8433(10) 0.2580(10) 0.0295(6) 0.069(3) Uani 1 1 d U . .
H34 H 0.8950 0.2366 0.0033 0.082 Uiso 1 1 calc R . .
C35 C 0.8086(7) 0.3968(7) 0.1143(5) 0.046(2) Uani 1 1 d . . .
H35A H 0.7308 0.3402 0.1022 0.070 Uiso 1 1 calc R . .
H35B H 0.8159 0.4588 0.0901 0.070 Uiso 1 1 calc R . .
H35C H 0.8302 0.4184 0.1792 0.070 Uiso 1 1 calc R . .
C36 C 1.0066(8) 0.4369(8) 0.0905(7) 0.068(3) Uani 1 1 d U . .
H36A H 1.0326 0.4445 0.1531 0.082 Uiso 1 1 calc R . .
H36B H 1.0187 0.5067 0.0794 0.082 Uiso 1 1 calc R . .
H36C H 1.0486 0.4103 0.0507 0.082 Uiso 1 1 calc R . .
N1 N 0.6952(6) -0.3246(6) 0.3479(4) 0.0501(19) Uani 1 1 d DU . .
N2 N 0.4020(4) -0.2803(4) 0.1518(3) 0.0197(12) Uani 1 1 d . . .
N3 N 0.3408(5) -0.3604(4) 0.5058(4) 0.0233(12) Uani 1 1 d . A .
N4 N 1.4550(5) 0.1095(5) 0.1425(4) 0.0310(14) Uani 1 1 d . . .
N5 N 1.3141(5) 0.3824(5) 0.3096(4) 0.0310(11) Uani 1 1 d U . .
N6 N 1.2623(5) 0.3624(4) -0.0163(4) 0.0292(13) Uani 1 1 d . . .
N7 N 0.9583(5) 0.0481(6) 0.3879(4) 0.0375(16) Uani 1 1 d . . .
N8 N 0.8811(6) 0.3569(6) 0.0719(4) 0.0459(17) Uani 1 1 d . . .
O1 O 0.5983(4) -0.2311(4) 0.3905(3) 0.0284(11) Uani 1 1 d . . .
O2 O 0.4038(3) -0.2276(3) 0.3038(3) 0.0195(9) Uani 1 1 d . . .
O3 O 0.4471(4) -0.3129(3) 0.5285(3) 0.0268(10) Uani 1 1 d . . .
O4 O 0.3051(3) -0.3184(3) 0.4522(3) 0.0236(10) Uani 1 1 d . . .
O5 O 0.2756(4) -0.4424(4) 0.5337(4) 0.0416(13) Uani 1 1 d . . .
O6 O 0.6090(3) -0.0238(3) 0.3689(3) 0.0154(9) Uani 1 1 d . . .
O7 O 0.6015(3) 0.1354(3) 0.4064(2) 0.0136(8) Uani 1 1 d . . .
O8 O 0.7997(3) -0.0472(3) 0.0842(3) 0.0182(9) Uani 1 1 d . . .
O9 O 0.9732(3) 0.0893(4) 0.0823(3) 0.0217(10) Uani 1 1 d . . .
O10 O 1.1985(4) 0.2446(4) 0.1936(3) 0.0244(10) Uani 1 1 d . . .
O11 O 1.3450(3) 0.1773(3) 0.0880(3) 0.0192(9) Uani 1 1 d . . .
O12 O 1.2899(4) 0.2893(4) -0.0453(3) 0.0291(11) Uani 1 1 d . . .
O13 O 1.1948(4) 0.3441(4) 0.0440(3) 0.0358(12) Uani 1 1 d . . .
O14 O 1.2996(6) 0.4485(4) -0.0453(4) 0.0550(16) Uani 1 1 d . . .
O15 O 0.9787(3) 0.4025(3) 0.3047(3) 0.0182(9) Uani 1 1 d . . .
O16 O 1.0113(3) 0.6184(3) 0.2878(3) 0.0149(9) Uani 1 1 d . . .
O17 O 0.9588(3) 0.8504(3) 0.0882(3) 0.0193(9) Uani 1 1 d . . .
O18 O 1.1279(3) 1.0023(3) 0.1116(3) 0.0188(9) Uani 1 1 d . . .
O19 O 1.3883(3) 0.9535(3) 0.4412(2) 0.0119(8) Uani 1 1 d . . .
O20 O 1.3532(3) 1.0877(3) 0.4188(3) 0.0163(9) Uani 1 1 d . . .
O21 O 1.1154(7) 0.2067(7) 0.4137(5) 0.088(2) Uani 1 1 d U . .
O22 O 0.7412(6) 0.1889(6) 0.0214(5) 0.076(2) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O6 136.96(13) 2_656 .
O7 Eu1 O19 72.07(13) 2_656 1_445
O6 Eu1 O19 78.91(13) . 1_445
O7 Eu1 O1 140.66(14) 2_656 .
O6 Eu1 O1 75.32(15) . .
O19 Eu1 O1 146.91(14) 1_445 .
O7 Eu1 O2 128.39(13) 2_656 .
O6 Eu1 O2 74.26(13) . .
O19 Eu1 O2 79.51(13) 1_445 .
O1 Eu1 O2 73.81(14) . .
O7 Eu1 O20 78.29(13) 2_656 2_766
O6 Eu1 O20 93.05(13) . 2_766
O19 Eu1 O20 123.98(12) 1_445 2_766
O1 Eu1 O20 78.14(14) . 2_766
O2 Eu1 O20 151.31(13) . 2_766
O7 Eu1 O4 69.42(13) 2_656 .
O6 Eu1 O4 142.88(13) . .
O19 Eu1 O4 90.69(13) 1_445 .
O1 Eu1 O4 97.44(15) . .
O2 Eu1 O4 68.81(14) . .
O20 Eu1 O4 121.53(14) 2_766 .
O7 Eu1 O3 71.39(14) 2_656 .
O6 Eu1 O3 146.68(13) . .
O19 Eu1 O3 133.88(13) 1_445 .
O1 Eu1 O3 72.05(15) . .
O2 Eu1 O3 102.49(14) . .
O20 Eu1 O3 73.95(13) 2_766 .
O4 Eu1 O3 50.30(14) . .
O7 Eu1 O19 72.62(12) 2_656 2_766
O6 Eu1 O19 69.31(12) . 2_766
O19 Eu1 O19 74.28(13) 1_445 2_766
O1 Eu1 O19 114.38(14) . 2_766
O2 Eu1 O19 138.30(13) . 2_766
O20 Eu1 O19 51.65(12) 2_766 2_766
O4 Eu1 O19 141.88(13) . 2_766
O3 Eu1 O19 119.09(13) . 2_766
O7 Eu1 C29 74.26(14) 2_656 2_766
O6 Eu1 C29 80.18(14) . 2_766
O19 Eu1 C29 99.58(14) 1_445 2_766
O1 Eu1 C29 96.13(15) . 2_766
O2 Eu1 C29 154.13(15) . 2_766
O20 Eu1 C29 25.55(14) 2_766 2_766
O4 Eu1 C29 136.92(14) . 2_766
O3 Eu1 C29 96.64(15) . 2_766
O19 Eu1 C29 26.11(13) 2_766 2_766
O7 Eu1 N3 65.97(13) 2_656 .
O6 Eu1 N3 156.71(13) . .
O19 Eu1 N3 111.84(14) 1_445 .
O1 Eu1 N3 86.26(15) . .
O2 Eu1 N3 87.12(15) . .
O20 Eu1 N3 97.03(15) 2_766 .
O4 Eu1 N3 25.32(14) . .
O3 Eu1 N3 25.18(14) . .
O19 Eu1 N3 132.64(13) 2_766 .
C29 Eu1 N3 116.47(15) 2_766 .
O7 Eu1 Eu1 67.66(9) 2_656 2_656
O6 Eu1 Eu1 69.74(9) . 2_656
O19 Eu1 Eu1 38.94(8) 1_445 2_656
O1 Eu1 Eu1 140.62(12) . 2_656
O2 Eu1 Eu1 112.22(10) . 2_656
O20 Eu1 Eu1 86.02(8) 2_766 2_656
O4 Eu1 Eu1 121.40(10) . 2_656
O3 Eu1 Eu1 137.22(10) . 2_656
O19 Eu1 Eu1 35.34(8) 2_766 2_656
C29 Eu1 Eu1 60.90(11) 2_766 2_656
N3 Eu1 Eu1 131.75(9) . 2_656
O9 Eu2 O18 76.11(15) . 1_545
O9 Eu2 O8 122.85(14) . 2_755
O18 Eu2 O8 83.84(14) 1_545 2_755
O9 Eu2 O10 79.84(14) . .
O18 Eu2 O10 81.33(15) 1_545 .
O8 Eu2 O10 148.69(14) 2_755 .
O9 Eu2 O17 74.18(14) . 2_765
O18 Eu2 O17 129.21(13) 1_545 2_765
O8 Eu2 O17 79.02(14) 2_755 2_765
O10 Eu2 O17 131.13(14) . 2_765
O9 Eu2 O11 142.57(14) . .
O18 Eu2 O11 73.89(14) 1_545 .
O8 Eu2 O11 75.45(13) 2_755 .
O10 Eu2 O11 73.99(14) . .
O17 Eu2 O11 143.11(14) 2_765 .
O9 Eu2 O12 138.47(14) . .
O18 Eu2 O12 145.39(14) 1_545 .
O8 Eu2 O12 74.98(14) 2_755 .
O10 Eu2 O12 102.99(15) . .
O17 Eu2 O12 73.48(14) 2_765 .
O11 Eu2 O12 74.46(14) . .
O9 Eu2 O13 95.41(16) . .
O18 Eu2 O13 151.35(14) 1_545 .
O8 Eu2 O13 122.51(15) 2_755 .
O10 Eu2 O13 70.18(15) . .
O17 Eu2 O13 71.93(15) 2_765 .
O11 Eu2 O13 100.25(15) . .
O12 Eu2 O13 49.81(14) . .
O9 Eu2 N6 116.96(16) . .
O18 Eu2 N6 161.18(14) 1_545 .
O8 Eu2 N6 98.31(15) 2_755 .
O10 Eu2 N6 87.60(15) . .
O17 Eu2 N6 69.28(14) 2_765 .
O11 Eu2 N6 88.48(15) . .
O12 Eu2 N6 24.90(14) . .
O13 Eu2 N6 25.00(14) . .
O9 Eu2 C14 101.63(15) . 2_755
O18 Eu2 C14 73.23(14) 1_545 2_755
O8 Eu2 C14 21.50(15) 2_755 2_755
O10 Eu2 C14 153.19(15) . 2_755
O17 Eu2 C14 73.66(14) 2_765 2_755
O11 Eu2 C14 90.66(13) . 2_755
O12 Eu2 C14 93.53(15) . 2_755
O13 Eu2 C14 135.39(15) . 2_755
N6 Eu2 C14 114.36(15) . 2_755
O9 Eu2 O9 78.69(13) . 2_755
O18 Eu2 O9 63.48(12) 1_545 2_755
O8 Eu2 O9 44.80(12) 2_755 2_755
O10 Eu2 O9 142.17(13) . 2_755
O17 Eu2 O9 70.91(12) 2_765 2_755
O11 Eu2 O9 106.66(12) . 2_755
O12 Eu2 O9 113.74(13) . 2_755
O13 Eu2 O9 142.57(13) . 2_755
N6 Eu2 O9 129.99(13) . 2_755
C14 Eu2 O9 23.30(12) 2_755 2_755
O9 Eu2 Eu2 46.54(10) . 2_755
O18 Eu2 Eu2 62.56(9) 1_545 2_755
O8 Eu2 Eu2 76.65(10) 2_755 2_755
O10 Eu2 Eu2 119.27(11) . 2_755
O17 Eu2 Eu2 67.04(10) 2_765 2_755
O11 Eu2 Eu2 130.03(10) . 2_755
O12 Eu2 Eu2 134.77(11) . 2_755
O13 Eu2 Eu2 129.72(12) . 2_755
N6 Eu2 Eu2 136.20(11) . 2_755
C14 Eu2 Eu2 55.22(11) 2_755 2_755
O9 Eu2 Eu2 32.15(7) 2_755 2_755
O1 C1 N1 123.7(7) . .
O2 C4 N2 123.5(6) . .
O7 C7 O6 125.8(5) . .
O7 C7 C8 117.2(5) . .
O6 C7 C8 117.0(5) . .
C13 C8 C9 120.1(5) . .
C13 C8 C7 120.6(5) . .
C9 C8 C7 119.3(5) . .
C10 C9 C8 119.5(5) . .
C9 C10 O15 124.3(5) . .
C9 C10 C11 120.9(5) . .
O15 C10 C11 114.8(5) . .
C12 C11 C10 119.0(5) . .
C11 C12 C13 120.6(5) . .
C11 C12 C14 120.7(5) . .
C13 C12 C14 118.7(5) . .
C8 C13 C12 119.7(5) . .
O8 C14 O9 123.7(5) . .
O8 C14 C12 118.4(5) . .
O9 C14 C12 117.9(5) . .
O8 C14 Eu2 43.9(3) . 2_755
O9 C14 Eu2 79.8(3) . 2_755
C12 C14 Eu2 162.3(4) . 2_755
O11 C15 N4 123.7(6) . .
O10 C18 N5 125.1(6) . .
O15 C21 C22 107.9(5) . .
O16 C22 C21 107.9(4) . .
O16 C23 C24 116.6(5) . .
O16 C23 C28 123.5(5) . .
C24 C23 C28 119.8(5) . .
C25 C24 C23 120.9(5) . .
C24 C25 C26 119.5(5) . .
C24 C25 C30 121.6(5) . .
C26 C25 C30 118.8(5) . .
C27 C26 C25 119.0(5) . .
C26 C27 C28 121.8(5) . .
C26 C27 C29 119.3(5) . .
C28 C27 C29 118.9(5) . .
C27 C28 C23 118.9(5) . .
O20 C29 O19 120.5(5) . .
O20 C29 C27 120.2(5) . .
O19 C29 C27 119.2(5) . .
O20 C29 Eu1 57.4(3) . 2_766
O19 C29 Eu1 63.1(3) . 2_766
C27 C29 Eu1 175.2(4) . 2_766
O17 C30 O18 126.3(5) . .
O17 C30 C25 117.0(5) . .
O18 C30 C25 116.6(5) . .
O21 C31 N7 121.3(9) . .
O22 C34 N8 123.4(10) . .
C1 N1 C2A 122.1(10) . .
C1 N1 C3B 141.6(14) . .
C2A N1 C3B 95.1(16) . .
C1 N1 C3A 116.2(8) . .
C2A N1 C3A 116.3(11) . .
C3B N1 C3A 26.9(10) . .
C1 N1 C2B 118.1(9) . .
C2A N1 C2B 29.8(10) . .
C3B N1 C2B 98.6(16) . .
C3A N1 C2B 125.3(11) . .
C4 N2 C6 121.8(5) . .
C4 N2 C5 120.8(5) . .
C6 N2 C5 117.5(5) . .
O5 N3 O3 122.3(6) . .
O5 N3 O4 121.8(6) . .
O3 N3 O4 115.9(5) . .
O5 N3 Eu1 172.2(4) . .
O3 N3 Eu1 58.7(3) . .
O4 N3 Eu1 57.8(3) . .
C15 N4 C17 122.9(6) . .
C15 N4 C16 119.8(6) . .
C17 N4 C16 117.2(5) . .
C18 N5 C20 120.2(6) . .
C18 N5 C19 121.9(6) . .
C20 N5 C19 117.6(6) . .
O14 N6 O12 122.0(6) . .
O14 N6 O13 121.4(6) . .
O12 N6 O13 116.6(5) . .
O14 N6 Eu2 174.4(5) . .
O12 N6 Eu2 58.1(3) . .
O13 N6 Eu2 58.8(3) . .
C31 N7 C32 127.1(8) . .
C31 N7 C33 116.8(7) . .
C32 N7 C33 115.9(7) . .
C34 N8 C35 122.3(9) . .
C34 N8 C36 123.0(8) . .
C35 N8 C36 114.3(7) . .
C1 O1 Eu1 142.8(4) . .
C4 O2 Eu1 127.0(4) . .
N3 O3 Eu1 96.1(3) . .
N3 O4 Eu1 96.9(3) . .
C7 O6 Eu1 135.2(3) . .
C7 O7 Eu1 137.6(4) . 2_656
C14 O8 Eu2 114.6(4) . 2_755
C14 O9 Eu2 170.0(4) . .
C14 O9 Eu2 76.9(3) . 2_755
Eu2 O9 Eu2 101.31(13) . 2_755
C18 O10 Eu2 141.2(4) . .
C15 O11 Eu2 124.1(4) . .
N6 O12 Eu2 97.0(4) . .
N6 O13 Eu2 96.2(3) . .
C10 O15 C21 116.4(4) . .
C23 O16 C22 116.3(4) . .
C30 O17 Eu2 136.0(4) . 2_765
C30 O18 Eu2 146.6(4) . 1_565
C29 O19 Eu1 158.0(3) . 1_665
C29 O19 Eu1 90.8(3) . 2_766
Eu1 O19 Eu1 105.72(13) 1_665 2_766
C29 O20 Eu1 97.0(3) . 2_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.370(4) 2_656
Eu1 O6 2.379(4) .
Eu1 O19 2.382(4) 1_445
Eu1 O1 2.389(4) .
Eu1 O2 2.412(4) .
Eu1 O20 2.465(4) 2_766
Eu1 O4 2.510(4) .
Eu1 O3 2.531(4) .
Eu1 O19 2.588(4) 2_766
Eu1 C29 2.902(5) 2_766
Eu1 N3 2.944(5) .
Eu1 Eu1 3.9640(6) 2_656
Eu2 O9 2.307(4) .
Eu2 O18 2.358(4) 1_545
Eu2 O8 2.374(4) 2_755
Eu2 O10 2.383(4) .
Eu2 O17 2.406(4) 2_765
Eu2 O11 2.429(4) .
Eu2 O12 2.519(5) .
Eu2 O13 2.535(5) .
Eu2 N6 2.945(6) .
Eu2 C14 3.114(6) 2_755
Eu2 O9 3.147(4) 2_755
Eu2 Eu2 4.2520(6) 2_755
C1 O1 1.235(8) .
C1 N1 1.308(8) .
C2A N1 1.439(9) .
C2B N1 1.487(9) .
C3A N1 1.486(8) .
C3B N1 1.447(10) .
C4 O2 1.242(7) .
C4 N2 1.318(7) .
C5 N2 1.466(8) .
C6 N2 1.464(8) .
C7 O7 1.259(6) .
C7 O6 1.271(6) .
C7 C8 1.505(8) .
C8 C13 1.372(7) .
C8 C9 1.411(7) .
C9 C10 1.366(8) .
C10 O15 1.385(6) .
C10 C11 1.402(7) .
C11 C12 1.380(8) .
C12 C13 1.401(8) .
C12 C14 1.506(7) .
C14 O8 1.256(7) .
C14 O9 1.265(7) .
C14 Eu2 3.114(6) 2_755
C15 O11 1.256(8) .
C15 N4 1.317(8) .
C16 N4 1.475(9) .
C17 N4 1.439(8) .
C18 O10 1.242(7) .
C18 N5 1.313(8) .
C19 N5 1.450(8) .
C20 N5 1.442(8) .
C21 O15 1.425(7) .
C21 C22 1.500(8) .
C22 O16 1.446(6) .
C23 O16 1.372(6) .
C23 C24 1.396(8) .
C23 C28 1.396(7) .
C24 C25 1.387(8) .
C25 C26 1.410(7) .
C25 C30 1.511(8) .
C26 C27 1.384(8) .
C27 C28 1.394(8) .
C27 C29 1.501(7) .
C29 O20 1.261(6) .
C29 O19 1.277(6) .
C29 Eu1 2.902(5) 2_766
C30 O17 1.256(7) .
C30 O18 1.258(7) .
C31 O21 1.199(11) .
C31 N7 1.332(11) .
C32 N7 1.399(9) .
C33 N7 1.463(11) .
C34 O22 1.240(12) .
C34 N8 1.277(12) .
C35 N8 1.422(9) .
C36 N8 1.507(11) .
N3 O5 1.226(7) .
N3 O3 1.260(6) .
N3 O4 1.268(7) .
N6 O14 1.234(7) .
N6 O12 1.250(7) .
N6 O13 1.252(7) .
O7 Eu1 2.370(4) 2_656
O8 Eu2 2.374(4) 2_755
O9 Eu2 3.147(4) 2_755
O17 Eu2 2.406(4) 2_765
O18 Eu2 2.358(4) 1_565
O19 Eu1 2.382(4) 1_665
O19 Eu1 2.588(4) 2_766
O20 Eu1 2.465(4) 2_766
