#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:59:58 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180283 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/69/7116930.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116930
loop_
_publ_author_name
'Terrance J. Hadlington'
'Benedikt Schwarze'
'Ekaterina I. Izgorodina'
'Cameron Jones'
_publ_section_title
;
 Two-coordinate hydrido-germylenes
;
_journal_name_full               Chem.Commun.
_journal_page_first              6854
_journal_paper_doi               10.1039/C5cc01314C
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C50 H66 Ge N O3 Si'
_chemical_formula_weight         829.72
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-02-11 deposited with the CCDC.
2015-03-17 downloaded from the CCDC.
;
_cell_angle_alpha                109.23(3)
_cell_angle_beta                 96.79(3)
_cell_angle_gamma                97.99(3)
_cell_formula_units_Z            2
_cell_length_a                   10.074(2)
_cell_length_b                   14.516(3)
_cell_length_c                   18.777(4)
_cell_measurement_temperature    100(2)
_cell_volume                     2527.7(11)
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_collection       'Blu-Ice (McPhillips, 2002)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_molecular_graphics    X-Seed
_computing_publication_material  CifTAB
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'ADSC Quantum 210r'
_diffrn_radiation_source         'Australian Synchrotron'
_diffrn_radiation_type           Synchrotron
_diffrn_radiation_wavelength     0.71090
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0318
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            9771
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    0.666
_exptl_absorpt_correction_T_max  0.967
_exptl_absorpt_correction_T_min  0.877
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   XDS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.090
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             886
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.567
_refine_diff_density_min         -1.222
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     516
_refine_ls_number_reflns         9771
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0747
_refine_ls_R_factor_gt           0.0716
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1058P)²+6.3706P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2077
_refine_ls_wR_factor_ref         0.2099
_reflns_number_gt                9048
_reflns_number_total             9771
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc01314c2.cif
_cod_data_source_block           compound4
_cod_original_cell_volume        2527.7(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7116930
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.39713(4) 0.18068(3) 0.31775(3) 0.03964(17) Uani 1 1 d . . .
Si2 Si 0.71406(9) 0.26635(6) 0.37439(5) 0.0225(2) Uani 1 1 d . . .
N1 N 0.5816(3) 0.1800(2) 0.30875(16) 0.0229(5) Uani 1 1 d . . .
O2 O 0.7433(3) 0.23543(18) 0.44974(14) 0.0286(5) Uani 1 1 d . . .
O1 O 0.8435(2) 0.26712(18) 0.33198(14) 0.0281(5) Uani 1 1 d . . .
O3 O 0.6746(3) 0.37466(18) 0.40492(14) 0.0303(5) Uani 1 1 d . . .
C1 C 0.6145(3) 0.0965(2) 0.25114(18) 0.0217(6) Uani 1 1 d . . .
C4 C 0.6952(3) -0.0629(2) 0.14245(19) 0.0245(6) Uani 1 1 d . . .
C2 C 0.6332(3) 0.0108(2) 0.26776(18) 0.0227(6) Uani 1 1 d . . .
C11 C 0.6685(3) -0.0742(2) 0.36492(18) 0.0237(6) Uani 1 1 d . . .
C6 C 0.6277(3) 0.0994(2) 0.17837(19) 0.0228(6) Uani 1 1 d . . .
C10 C 0.5974(3) 0.0009(2) 0.34196(19) 0.0246(6) Uani 1 1 d . . .
H10 H 0.6319 0.0671 0.3834 0.029 Uiso 1 1 calc R . .
C3 C 0.6736(3) -0.0668(2) 0.21309(19) 0.0242(6) Uani 1 1 d . . .
H3 H 0.6867 -0.1242 0.2247 0.029 Uiso 1 1 calc R . .
C24 C 0.6642(3) 0.2087(3) 0.0976(2) 0.0269(7) Uani 1 1 d . . .
C23 C 0.5883(3) 0.1862(2) 0.15711(19) 0.0248(7) Uani 1 1 d . . .
H23 H 0.6152 0.2464 0.2048 0.030 Uiso 1 1 calc R . .
C17 C 0.4430(4) -0.0207(3) 0.3356(2) 0.0293(7) Uani 1 1 d . . .
C5 C 0.6691(3) 0.0212(2) 0.12567(18) 0.0248(6) Uani 1 1 d . . .
H5 H 0.6800 0.0245 0.0770 0.030 Uiso 1 1 calc R . .
C30 C 0.4334(3) 0.1706(3) 0.13436(19) 0.0278(7) Uani 1 1 d . . .
C16 C 0.8051(4) -0.0440(3) 0.3997(2) 0.0309(7) Uani 1 1 d . . .
H16 H 0.8492 0.0226 0.4110 0.037 Uiso 1 1 calc R . .
C14 C 0.8152(4) -0.2072(3) 0.4023(2) 0.0361(8) Uani 1 1 d . . .
H14 H 0.8649 -0.2527 0.4145 0.043 Uiso 1 1 calc R . .
C39 C 0.9741(4) 0.1504(3) 0.2663(2) 0.0368(8) Uani 1 1 d . . .
H39A H 0.9197 0.0944 0.2744 0.055 Uiso 1 1 calc R . .
H39B H 1.0667 0.1381 0.2623 0.055 Uiso 1 1 calc R . .
H39C H 0.9325 0.1573 0.2190 0.055 Uiso 1 1 calc R . .
C40 C 0.7428(4) 0.2823(3) 0.5308(2) 0.0328(8) Uani 1 1 d . . .
C38 C 1.0350(4) 0.2333(3) 0.4078(2) 0.0384(9) Uani 1 1 d . . .
H38A H 1.0342 0.2940 0.4506 0.058 Uiso 1 1 calc R . .
H38B H 1.1285 0.2218 0.4073 0.058 Uiso 1 1 calc R . .
H38C H 0.9780 0.1767 0.4138 0.058 Uiso 1 1 calc R . .
C12 C 0.6063(4) -0.1713(3) 0.3501(3) 0.0384(9) Uani 1 1 d . . .
H12 H 0.5128 -0.1930 0.3272 0.046 Uiso 1 1 calc R . .
C7 C 0.7508(4) -0.1425(3) 0.0862(2) 0.0309(7) Uani 1 1 d . . .
H7 H 0.7281 -0.1368 0.0347 0.037 Uiso 1 1 calc R . .
C25 C 0.7952(4) 0.2672(3) 0.1219(3) 0.0399(9) Uani 1 1 d . . .
H25 H 0.8348 0.2914 0.1747 0.048 Uiso 1 1 calc R . .
C37 C 1.0682(4) 0.3329(3) 0.3235(3) 0.0406(9) Uani 1 1 d . . .
H37A H 1.0313 0.3407 0.2756 0.061 Uiso 1 1 calc R . .
H37B H 1.1615 0.3210 0.3222 0.061 Uiso 1 1 calc R . .
H37C H 1.0686 0.3934 0.3667 0.061 Uiso 1 1 calc R . .
C22 C 0.3595(4) -0.0892(3) 0.2697(2) 0.0372(8) Uani 1 1 d . . .
H22 H 0.3997 -0.1265 0.2290 0.045 Uiso 1 1 calc R . .
C15 C 0.8776(4) -0.1103(3) 0.4182(2) 0.0354(8) Uani 1 1 d . . .
H15 H 0.9706 -0.0886 0.4419 0.042 Uiso 1 1 calc R . .
C36 C 0.9796(3) 0.2445(3) 0.3330(2) 0.0276(7) Uani 1 1 d . . .
C27 C 0.8112(5) 0.2555(4) -0.0074(3) 0.0510(12) Uani 1 1 d . . .
H27 H 0.8611 0.2714 -0.0431 0.061 Uiso 1 1 calc R . .
C18 C 0.3813(4) 0.0297(3) 0.3954(2) 0.0362(8) Uani 1 1 d . . .
H18 H 0.4359 0.0744 0.4420 0.043 Uiso 1 1 calc R . .
C41 C 0.6062(5) 0.3102(4) 0.5439(3) 0.0469(10) Uani 1 1 d . . .
H41A H 0.5912 0.3618 0.5226 0.070 Uiso 1 1 calc R . .
H41B H 0.6048 0.3353 0.5990 0.070 Uiso 1 1 calc R . .
H41C H 0.5339 0.2514 0.5187 0.070 Uiso 1 1 calc R . .
C43 C 0.7695(5) 0.2036(3) 0.5652(2) 0.0427(10) Uani 1 1 d . . .
H43A H 0.6938 0.1466 0.5444 0.064 Uiso 1 1 calc R . .
H43B H 0.7776 0.2317 0.6210 0.064 Uiso 1 1 calc R . .
H43C H 0.8542 0.1819 0.5522 0.064 Uiso 1 1 calc R . .
C29 C 0.6089(4) 0.1749(3) 0.0203(2) 0.0361(8) Uani 1 1 d . . .
H29 H 0.5197 0.1358 0.0029 0.043 Uiso 1 1 calc R . .
C19 C 0.2388(5) 0.0149(4) 0.3873(3) 0.0471(11) Uani 1 1 d . . .
H19 H 0.1977 0.0506 0.4282 0.057 Uiso 1 1 calc R . .
C20 C 0.1582(4) -0.0507(4) 0.3208(3) 0.0503(12) Uani 1 1 d . . .
H20 H 0.0618 -0.0591 0.3153 0.060 Uiso 1 1 calc R . .
C46 C 0.5159(5) 0.4471(4) 0.3453(3) 0.0504(11) Uani 1 1 d . . .
H46A H 0.4909 0.3844 0.3016 0.076 Uiso 1 1 calc R . .
H46B H 0.5062 0.5025 0.3275 0.076 Uiso 1 1 calc R . .
H46C H 0.4560 0.4463 0.3827 0.076 Uiso 1 1 calc R . .
C42 C 0.8569(5) 0.3733(3) 0.5645(2) 0.0461(10) Uani 1 1 d . . .
H42A H 0.9444 0.3531 0.5561 0.069 Uiso 1 1 calc R . .
H42B H 0.8582 0.4038 0.6196 0.069 Uiso 1 1 calc R . .
H42C H 0.8417 0.4214 0.5395 0.069 Uiso 1 1 calc R . .
C45 C 0.7567(6) 0.4689(4) 0.3278(4) 0.0617(14) Uani 1 1 d . . .
H45A H 0.8513 0.4825 0.3539 0.093 Uiso 1 1 calc R . .
H45B H 0.7406 0.5235 0.3102 0.093 Uiso 1 1 calc R . .
H45C H 0.7396 0.4067 0.2837 0.093 Uiso 1 1 calc R . .
C44 C 0.6622(4) 0.4596(3) 0.3826(2) 0.0323(8) Uani 1 1 d . . .
C13 C 0.6797(4) -0.2376(3) 0.3684(3) 0.0455(10) Uani 1 1 d . . .
H13 H 0.6359 -0.3043 0.3575 0.055 Uiso 1 1 calc R . .
C21 C 0.2183(4) -0.1042(4) 0.2621(3) 0.0477(11) Uani 1 1 d . . .
H21 H 0.1633 -0.1512 0.2166 0.057 Uiso 1 1 calc R . .
C47 C 0.6943(6) 0.5472(3) 0.4562(3) 0.0499(11) Uani 1 1 d . . .
H47A H 0.6340 0.5360 0.4911 0.075 Uiso 1 1 calc R . .
H47B H 0.6806 0.6073 0.4456 0.075 Uiso 1 1 calc R . .
H47C H 0.7892 0.5555 0.4800 0.075 Uiso 1 1 calc R . .
C9 C 0.6890(6) -0.2478(3) 0.0793(3) 0.0515(12) Uani 1 1 d . . .
H9A H 0.7247 -0.2957 0.0395 0.077 Uiso 1 1 calc R . .
H9B H 0.5898 -0.2586 0.0654 0.077 Uiso 1 1 calc R . .
H9C H 0.7129 -0.2567 0.1284 0.077 Uiso 1 1 calc R . .
C28 C 0.6826(5) 0.1978(4) -0.0322(3) 0.0464(10) Uani 1 1 d . . .
H28 H 0.6439 0.1735 -0.0851 0.056 Uiso 1 1 calc R . .
C26 C 0.8675(4) 0.2902(4) 0.0699(3) 0.0515(12) Uani 1 1 d . . .
H26 H 0.9563 0.3300 0.0872 0.062 Uiso 1 1 calc R . .
C8 C 0.9057(5) -0.1216(4) 0.1077(3) 0.0571(13) Uani 1 1 d . . .
H8A H 0.9424 -0.0552 0.1084 0.086 Uiso 1 1 calc R . .
H8B H 0.9428 -0.1712 0.0700 0.086 Uiso 1 1 calc R . .
H8C H 0.9314 -0.1252 0.1586 0.086 Uiso 1 1 calc R . .
C35 C 0.3521(4) 0.0768(3) 0.1042(2) 0.0360(8) Uani 1 1 d . . .
H35 H 0.3932 0.0201 0.0965 0.043 Uiso 1 1 calc R . .
C31 C 0.3713(4) 0.2525(3) 0.1441(2) 0.0391(9) Uani 1 1 d . . .
H31 H 0.4254 0.3175 0.1630 0.047 Uiso 1 1 calc R . .
C33 C 0.1501(4) 0.1464(4) 0.0969(2) 0.0490(11) Uani 1 1 d . . .
H33 H 0.0539 0.1384 0.0851 0.059 Uiso 1 1 calc R . .
C34 C 0.2103(4) 0.0639(4) 0.0847(3) 0.0447(10) Uani 1 1 d . . .
H34 H 0.1562 -0.0010 0.0633 0.054 Uiso 1 1 calc R . .
C32 C 0.2297(4) 0.2403(4) 0.1262(2) 0.0498(11) Uani 1 1 d . . .
H32 H 0.1882 0.2969 0.1342 0.060 Uiso 1 1 calc R . .
C51 C 0.3801(4) 0.5477(4) 0.1664(2) 0.110(5) Uiso 0.50 1 d PRD . .
H51A H 0.4370 0.6066 0.2075 0.132 Uiso 0.50 1 calc PR . .
H51B H 0.3652 0.4932 0.1870 0.132 Uiso 0.50 1 calc PR . .
C52 C 0.4537(15) 0.517(2) 0.0992(6) 0.156(9) Uiso 0.50 1 d PD . .
H52A H 0.3981 0.4562 0.0590 0.187 Uiso 0.50 1 calc PR . .
H52B H 0.4649 0.5700 0.0773 0.187 Uiso 0.50 1 calc PR . .
C50 C 0.2438(11) 0.5723(17) 0.1427(7) 0.127(7) Uiso 0.50 1 d PD . .
H50A H 0.2594 0.6357 0.1330 0.153 Uiso 0.50 1 calc PR . .
H50B H 0.1955 0.5196 0.0944 0.153 Uiso 0.50 1 calc PR . .
C49 C 0.1560(13) 0.581(2) 0.2036(10) 0.149(8) Uiso 0.50 1 d PD . .
H49A H 0.2050 0.6334 0.2521 0.179 Uiso 0.50 1 calc PR . .
H49B H 0.1392 0.5177 0.2127 0.179 Uiso 0.50 1 calc PR . .
C48 C 0.0211(13) 0.608(2) 0.1806(13) 0.159(9) Uiso 0.50 1 d PD . .
H48A H 0.0360 0.6585 0.1572 0.238 Uiso 0.50 1 calc PR . .
H48B H -0.0204 0.6332 0.2261 0.238 Uiso 0.50 1 calc PR . .
H48C H -0.0398 0.5481 0.1437 0.238 Uiso 0.50 1 calc PR . .
H1 H 0.408(5) 0.257(3) 0.393(3) 0.043(12) Uiso 1 1 d . . .
C53 C 0.5921(13) 0.4956(18) 0.1223(10) 0.138(8) Uiso 0.50 1 d PD . .
H53A H 0.6284 0.5370 0.1759 0.207 Uiso 0.50 1 calc PR . .
H53B H 0.6540 0.5109 0.0895 0.207 Uiso 0.50 1 calc PR . .
H53C H 0.5834 0.4253 0.1165 0.207 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Si2 O3 111.72(14) . .
O1 Si2 O2 112.02(13) . .
O3 Si2 O2 105.54(13) . .
O1 Si2 N1 106.78(14) . .
O3 Si2 N1 111.39(14) . .
O2 Si2 N1 109.44(14) . .
C1 N1 Si2 118.2(2) . .
C1 N1 Ge1 118.5(2) . .
Si2 N1 Ge1 122.73(16) . .
C40 O2 Si2 135.2(2) . .
C36 O1 Si2 143.1(2) . .
C44 O3 Si2 141.4(2) . .
C6 C1 C2 119.4(3) . .
C6 C1 N1 120.7(3) . .
C2 C1 N1 119.9(3) . .
C3 C4 C5 117.5(3) . .
C3 C4 C7 122.3(3) . .
C5 C4 C7 120.2(3) . .
C3 C2 C1 119.2(3) . .
C3 C2 C10 121.3(3) . .
C1 C2 C10 119.4(3) . .
C12 C11 C16 118.4(3) . .
C12 C11 C10 123.5(3) . .
C16 C11 C10 118.1(3) . .
C5 C6 C1 119.7(3) . .
C5 C6 C23 121.3(3) . .
C1 C6 C23 119.0(3) . .
C17 C10 C2 109.6(3) . .
C17 C10 C11 113.7(3) . .
C2 C10 C11 112.1(3) . .
C4 C3 C2 122.3(3) . .
C29 C24 C25 118.4(3) . .
C29 C24 C23 122.9(3) . .
C25 C24 C23 118.7(3) . .
C24 C23 C6 113.5(3) . .
C24 C23 C30 112.7(3) . .
C6 C23 C30 110.4(3) . .
C18 C17 C22 117.9(3) . .
C18 C17 C10 120.5(4) . .
C22 C17 C10 121.5(3) . .
C6 C5 C4 121.8(3) . .
C35 C30 C31 118.3(3) . .
C35 C30 C23 122.2(3) . .
C31 C30 C23 119.5(3) . .
C15 C16 C11 120.9(3) . .
C15 C14 C13 119.3(3) . .
O2 C40 C41 110.8(3) . .
O2 C40 C42 109.5(3) . .
C41 C40 C42 111.0(4) . .
O2 C40 C43 104.6(3) . .
C41 C40 C43 110.3(3) . .
C42 C40 C43 110.3(3) . .
C11 C12 C13 120.5(4) . .
C4 C7 C9 113.6(3) . .
C4 C7 C8 109.0(3) . .
C9 C7 C8 111.6(4) . .
C26 C25 C24 120.7(4) . .
C21 C22 C17 121.4(4) . .
C14 C15 C16 120.3(3) . .
O1 C36 C39 108.2(3) . .
O1 C36 C38 112.0(3) . .
C39 C36 C38 110.6(3) . .
O1 C36 C37 105.5(3) . .
C39 C36 C37 110.8(3) . .
C38 C36 C37 109.6(3) . .
C28 C27 C26 119.6(4) . .
C17 C18 C19 120.4(4) . .
C24 C29 C28 120.8(4) . .
C20 C19 C18 120.6(4) . .
C19 C20 C21 119.5(4) . .
O3 C44 C47 105.1(3) . .
O3 C44 C45 111.2(3) . .
C47 C44 C45 112.4(4) . .
O3 C44 C46 108.1(3) . .
C47 C44 C46 109.6(4) . .
C45 C44 C46 110.2(4) . .
C14 C13 C12 120.6(4) . .
C20 C21 C22 120.0(5) . .
C27 C28 C29 120.1(4) . .
C25 C26 C27 120.4(4) . .
C30 C35 C34 121.4(4) . .
C30 C31 C32 120.6(4) . .
C32 C33 C34 120.0(4) . .
C33 C34 C35 119.4(4) . .
C33 C32 C31 120.3(4) . .
C52 C51 C50 111.0(5) . .
C53 C52 C51 111.8(5) . .
C49 C50 C51 111.6(5) . .
C50 C49 C48 111.7(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 N1 1.886(3) .
Si2 O1 1.607(2) .
Si2 O3 1.610(2) .
Si2 O2 1.627(2) .
Si2 N1 1.732(3) .
N1 C1 1.443(4) .
O2 C40 1.449(4) .
O1 C36 1.452(4) .
O3 C44 1.443(4) .
C1 C6 1.402(4) .
C1 C2 1.411(4) .
C4 C3 1.387(5) .
C4 C5 1.407(4) .
C4 C7 1.510(5) .
C2 C3 1.397(5) .
C2 C10 1.526(4) .
C11 C12 1.383(5) .
C11 C16 1.393(5) .
C11 C10 1.530(4) .
C6 C5 1.390(5) .
C6 C23 1.529(4) .
C10 C17 1.525(5) .
C24 C29 1.386(5) .
C24 C25 1.401(5) .
C24 C23 1.521(5) .
C23 C30 1.532(5) .
C17 C18 1.391(5) .
C17 C22 1.393(6) .
C30 C35 1.384(6) .
C30 C31 1.390(5) .
C16 C15 1.390(5) .
C14 C15 1.378(6) .
C14 C13 1.381(6) .
C39 C36 1.508(5) .
C40 C41 1.512(6) .
C40 C42 1.524(6) .
C40 C43 1.526(5) .
C38 C36 1.517(5) .
C12 C13 1.396(5) .
C7 C9 1.525(6) .
C7 C8 1.526(6) .
C25 C26 1.382(6) .
C37 C36 1.531(5) .
C22 C21 1.391(5) .
C27 C28 1.376(7) .
C27 C26 1.389(8) .
C18 C19 1.404(6) .
C29 C28 1.399(5) .
C19 C20 1.373(8) .
C20 C21 1.383(7) .
C46 C44 1.514(6) .
C45 C44 1.507(6) .
C44 C47 1.502(6) .
C35 C34 1.402(5) .
C31 C32 1.398(6) .
C33 C32 1.379(7) .
C33 C34 1.381(7) .
C51 C52 1.513(5) .
C51 C50 1.519(5) .
C52 C53 1.511(5) .
C50 C49 1.510(5) .
C49 C48 1.515(5) .
