#------------------------------------------------------------------------------
#$Date: 2018-09-27 07:13:35 +0300 (Thu, 27 Sep 2018) $
#$Revision: 211196 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/72/7117291.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7117291
loop_
_publ_author_name
'Norio Nakata'
'Noriko Sekizawa'
'Akihiko Ishii'
_publ_section_title
;
 Cationic dinuclear platinum and palladium complexes with bridging
 hydrogermylene and hydrido ligands
;
_journal_name_full               Chem.Commun.
_journal_page_first              10111
_journal_paper_doi               10.1039/C5cc03062E
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C72 H110 Cl Ge P4 Pt2, C18 H B F15'
_chemical_formula_sum            'C90 H111 B Cl F15 Ge P4 Pt2'
_chemical_formula_weight         2110.70
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-23 deposited with the CCDC.
2015-05-12 downloaded from the CCDC.
;
_cell_angle_alpha                92.6870(10)
_cell_angle_beta                 105.9720(10)
_cell_angle_gamma                96.8460(10)
_cell_formula_units_Z            2
_cell_length_a                   13.4568(16)
_cell_length_b                   18.179(2)
_cell_length_c                   18.421(2)
_cell_measurement_temperature    100(2)
_cell_volume                     4286.5(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX-II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Bruker Helios multilayered confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0716
_diffrn_reflns_av_sigmaI/netI    0.0591
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            22264
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    3.788
_exptl_absorpt_correction_T_max  0.7515
_exptl_absorpt_correction_T_min  0.7268
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.635
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2112
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_refine_diff_density_max         3.424
_refine_diff_density_min         -1.977
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1035
_refine_ls_number_reflns         16406
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0441
_refine_ls_R_factor_gt           0.0383
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0608P)²+0.0150P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1019
_reflns_number_gt                14001
_reflns_number_total             16406
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc03062e2.cif
_cod_data_source_block           naka095
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3392 2015-05-12 13:50:21Z andrius 
;
_cod_original_cell_volume        4286.5(9)
_cod_database_code               7117291
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt2 Pt 0.194441(13) 0.326085(9) 0.243934(10) 0.01229(6) Uani 1 1 d D . .
Pt1 Pt 0.222687(13) 0.171404(9) 0.273949(10) 0.01228(6) Uani 1 1 d D . .
Ge1 Ge 0.32601(4) 0.25749(3) 0.21638(3) 0.01307(11) Uani 1 1 d . . .
Cl1 Cl 0.48273(11) 0.29936(8) 0.29188(8) 0.0329(3) Uani 1 1 d . . .
P2 P 0.12781(10) 0.11135(6) 0.34785(7) 0.0149(2) Uani 1 1 d . . .
P4 P 0.05227(9) 0.37319(6) 0.26637(7) 0.0144(2) Uani 1 1 d . . .
P1 P 0.28508(9) 0.06305(6) 0.26063(7) 0.0141(2) Uani 1 1 d . . .
P3 P 0.23655(9) 0.43633(6) 0.20038(7) 0.0156(3) Uani 1 1 d . . .
F3 F -0.2912(3) 0.3350(3) 0.3666(2) 0.0612(12) Uani 1 1 d . . .
F5 F -0.2857(3) 0.34441(17) 0.62111(18) 0.0332(8) Uani 1 1 d . . .
F4 F -0.3551(3) 0.3892(2) 0.4842(2) 0.0486(10) Uani 1 1 d . . .
C75 C -0.1991(5) 0.2528(4) 0.4463(3) 0.0376(15) Uani 1 1 d . . .
F9 F 0.1425(3) 0.44140(17) 0.72833(19) 0.0332(8) Uani 1 1 d . . .
C14 C 0.4034(4) 0.3013(3) 0.0785(3) 0.0185(10) Uani 1 1 d . . .
F10 F -0.0583(2) 0.38281(16) 0.67519(19) 0.0331(8) Uani 1 1 d . . .
C85 C -0.2157(4) 0.2355(3) 0.7209(3) 0.0257(12) Uani 1 1 d . . .
C69 C 0.0480(4) 0.3560(3) 0.4912(3) 0.0272(12) Uani 1 1 d . . .
H102 H 0.0526 0.3120 0.5211 0.033 Uiso 1 1 calc R . .
H103 H -0.0204 0.3729 0.4873 0.033 Uiso 1 1 calc R . .
F6 F 0.0354(3) 0.14341(17) 0.7263(2) 0.0353(8) Uani 1 1 d . . .
C61 C -0.0779(4) 0.3176(3) 0.2244(3) 0.0187(10) Uani 1 1 d . . .
H88 H -0.0800 0.2724 0.2532 0.022 Uiso 1 1 calc R . .
C34 C 0.4637(4) 0.1234(3) 0.3793(3) 0.0227(11) Uani 1 1 d . . .
H38 H 0.4270 0.1167 0.4188 0.027 Uiso 1 1 calc R . .
H39 H 0.4500 0.1713 0.3577 0.027 Uiso 1 1 calc R . .
F8 F 0.2910(2) 0.3524(2) 0.78058(19) 0.0391(8) Uani 1 1 d . . .
F2 F -0.1711(3) 0.2233(2) 0.3867(2) 0.0526(11) Uani 1 1 d . . .
F1 F -0.1044(3) 0.17421(19) 0.5231(2) 0.0412(9) Uani 1 1 d . . .
C35 C -0.0160(4) 0.0927(3) 0.3070(3) 0.0185(10) Uani 1 1 d . . .
H40 H -0.0403 0.1422 0.2977 0.022 Uiso 1 1 calc R . .
C50 C 0.2572(5) 0.4954(4) 0.0617(4) 0.0428(16) Uani 1 1 d . . .
H67 H 0.3323 0.5105 0.0876 0.051 Uiso 1 1 calc R . .
H68 H 0.2198 0.5377 0.0689 0.051 Uiso 1 1 calc R . .
C32 C 0.6068(4) 0.0521(3) 0.4458(3) 0.0296(13) Uani 1 1 d . . .
H34 H 0.6835 0.0535 0.4626 0.036 Uiso 1 1 calc R . .
H35 H 0.5805 0.0453 0.4905 0.036 Uiso 1 1 calc R . .
F7 F 0.2352(3) 0.2032(2) 0.7774(2) 0.0382(8) Uani 1 1 d . . .
C49 C 0.2177(4) 0.4304(3) 0.0968(3) 0.0236(11) Uani 1 1 d . . .
H66 H 0.2585 0.3903 0.0872 0.028 Uiso 1 1 calc R . .
C67 C 0.0543(4) 0.4005(3) 0.3649(3) 0.0170(10) Uani 1 1 d . . .
H99 H -0.0110 0.4224 0.3629 0.020 Uiso 1 1 calc R . .
C27 C 0.3177(4) -0.0687(3) 0.0763(3) 0.0274(12) Uani 1 1 d . . .
H25 H 0.3620 -0.0310 0.0576 0.033 Uiso 1 1 calc R . .
H26 H 0.3452 -0.1167 0.0741 0.033 Uiso 1 1 calc R . .
C28 C 0.3234(4) -0.0454(3) 0.1585(3) 0.0231(11) Uani 1 1 d . . .
H27 H 0.3972 -0.0372 0.1895 0.028 Uiso 1 1 calc R . .
H28 H 0.2860 -0.0857 0.1791 0.028 Uiso 1 1 calc R . .
C18 C 0.4527(4) 0.3325(3) -0.0350(3) 0.0252(12) Uani 1 1 d . . .
H12 H 0.4516 0.3199 -0.0859 0.030 Uiso 1 1 calc R . .
C9 C 0.4917(4) 0.1524(2) 0.1701(3) 0.0168(10) Uani 1 1 d . . .
H5 H 0.4944 0.1680 0.2206 0.020 Uiso 1 1 calc R . .
C11 C 0.5559(4) 0.0803(3) 0.0832(3) 0.0241(11) Uani 1 1 d . . .
H7 H 0.6000 0.0460 0.0743 0.029 Uiso 1 1 calc R . .
C26 C 0.2068(4) -0.0767(3) 0.0257(3) 0.0270(12) Uani 1 1 d . . .
H23 H 0.1644 -0.1184 0.0407 0.032 Uiso 1 1 calc R . .
H24 H 0.2063 -0.0886 -0.0274 0.032 Uiso 1 1 calc R . .
C16 C 0.5071(4) 0.4181(3) 0.0764(3) 0.0269(12) Uani 1 1 d . . .
H10 H 0.5440 0.4643 0.1014 0.032 Uiso 1 1 calc R . .
C8 C 0.4218(4) 0.1790(3) 0.1092(3) 0.0163(10) Uani 1 1 d . . .
C21 C 0.2031(4) -0.0093(3) 0.2929(3) 0.0180(10) Uani 1 1 d . . .
H14 H 0.1387 -0.0263 0.2515 0.022 Uiso 1 1 calc R . .
H15 H 0.2412 -0.0524 0.3056 0.022 Uiso 1 1 calc R . .
C80 C 0.0573(4) 0.2178(3) 0.7247(3) 0.0255(12) Uani 1 1 d . . .
C19 C 0.4039(4) 0.2823(3) 0.0037(3) 0.0196(10) Uani 1 1 d . . .
C29 C 0.4219(4) 0.0602(3) 0.3170(3) 0.0169(10) Uani 1 1 d . . .
H29 H 0.4652 0.0674 0.2811 0.020 Uiso 1 1 calc R . .
C13 C 0.4243(4) 0.1578(3) 0.0351(3) 0.0182(10) Uani 1 1 d . . .
C36 C -0.0429(4) 0.0491(3) 0.2288(3) 0.0264(12) Uani 1 1 d . . .
H41 H -0.0087 0.0775 0.1957 0.032 Uiso 1 1 calc R . .
H42 H -0.0154 0.0009 0.2347 0.032 Uiso 1 1 calc R . .
C43 C 0.1640(4) 0.1485(3) 0.5833(3) 0.0294(12) Uani 1 1 d . . .
H54 H 0.1132 0.1843 0.5793 0.035 Uiso 1 1 calc R . .
H55 H 0.1552 0.1148 0.6224 0.035 Uiso 1 1 calc R . .
C74 C -0.1661(4) 0.2283(3) 0.5171(3) 0.0302(13) Uani 1 1 d . . .
C52 C 0.1261(5) 0.4501(3) -0.0649(3) 0.0339(14) Uani 1 1 d . . .
H71 H 0.0830 0.4898 -0.0613 0.041 Uiso 1 1 calc R . .
H72 H 0.1186 0.4372 -0.1192 0.041 Uiso 1 1 calc R . .
C12 C 0.4885(4) 0.1087(3) 0.0224(3) 0.0234(11) Uani 1 1 d . . .
H8 H 0.4872 0.0938 -0.0280 0.028 Uiso 1 1 calc R . .
C23 C 0.2746(4) 0.0263(2) 0.1636(3) 0.0163(10) Uani 1 1 d . . .
H18 H 0.3152 0.0650 0.1423 0.020 Uiso 1 1 calc R . .
C10 C 0.5580(4) 0.1026(3) 0.1564(3) 0.0227(11) Uani 1 1 d . . .
H6 H 0.6047 0.0841 0.1978 0.027 Uiso 1 1 calc R . .
C70 C 0.1357(5) 0.4182(3) 0.5322(3) 0.0296(13) Uani 1 1 d . . .
H104 H 0.1243 0.4352 0.5807 0.036 Uiso 1 1 calc R . .
H105 H 0.2035 0.3986 0.5438 0.036 Uiso 1 1 calc R . .
C33 C 0.5811(4) 0.1254(3) 0.4150(3) 0.0260(12) Uani 1 1 d . . .
H36 H 0.6182 0.1368 0.3765 0.031 Uiso 1 1 calc R . .
H37 H 0.6058 0.1655 0.4566 0.031 Uiso 1 1 calc R . .
C17 C 0.5026(4) 0.4002(3) 0.0013(3) 0.0282(12) Uani 1 1 d . . .
H11 H 0.5342 0.4351 -0.0253 0.034 Uiso 1 1 calc R . .
C72 C 0.1480(4) 0.4601(3) 0.4052(3) 0.0232(11) Uani 1 1 d . . .
H108 H 0.2142 0.4397 0.4100 0.028 Uiso 1 1 calc R . .
H109 H 0.1478 0.5038 0.3751 0.028 Uiso 1 1 calc R . .
C71 C 0.1392(5) 0.4835(3) 0.4838(3) 0.0299(13) Uani 1 1 d . . .
H106 H 0.1996 0.5210 0.5100 0.036 Uiso 1 1 calc R . .
H107 H 0.0751 0.5070 0.4782 0.036 Uiso 1 1 calc R . .
C24 C 0.1618(4) 0.0171(3) 0.1119(3) 0.0245(11) Uani 1 1 d . . .
H19 H 0.1179 -0.0210 0.1304 0.029 Uiso 1 1 calc R . .
H20 H 0.1333 0.0647 0.1135 0.029 Uiso 1 1 calc R . .
C37 C -0.1603(4) 0.0349(3) 0.1914(3) 0.0292(12) Uani 1 1 d . . .
H43 H -0.1869 0.0829 0.1806 0.035 Uiso 1 1 calc R . .
H44 H -0.1747 0.0047 0.1426 0.035 Uiso 1 1 calc R . .
C41 C 0.1545(4) 0.1551(3) 0.4455(3) 0.0176(10) Uani 1 1 d . . .
H51 H 0.1049 0.1923 0.4437 0.021 Uiso 1 1 calc R . .
C76 C -0.2614(5) 0.3085(4) 0.4346(3) 0.0378(15) Uani 1 1 d . . .
C1 C 0.3499(4) 0.2374(3) 0.1139(3) 0.0161(10) Uani 1 1 d . . .
C78 C -0.2560(4) 0.3104(3) 0.5647(3) 0.0281(12) Uani 1 1 d . . .
C45 C 0.2925(4) 0.2409(3) 0.5474(3) 0.0309(13) Uani 1 1 d . . .
H58 H 0.3665 0.2638 0.5622 0.037 Uiso 1 1 calc R . .
H59 H 0.2488 0.2814 0.5447 0.037 Uiso 1 1 calc R . .
C46 C 0.2662(4) 0.1985(3) 0.4696(3) 0.0254(12) Uani 1 1 d . . .
H60 H 0.3170 0.1632 0.4704 0.031 Uiso 1 1 calc R . .
H61 H 0.2729 0.2341 0.4316 0.031 Uiso 1 1 calc R . .
C55 C 0.3672(4) 0.4857(3) 0.2489(3) 0.0222(11) Uani 1 1 d . . .
H77 H 0.4177 0.4629 0.2270 0.027 Uiso 1 1 calc R . .
C22 C 0.1739(4) 0.0200(2) 0.3627(3) 0.0170(10) Uani 1 1 d . . .
H16 H 0.2355 0.0248 0.4077 0.020 Uiso 1 1 calc R . .
H17 H 0.1182 -0.0158 0.3722 0.020 Uiso 1 1 calc R . .
C54 C 0.1031(5) 0.3999(4) 0.0550(3) 0.0372(14) Uani 1 1 d . . .
H75 H 0.0818 0.3543 0.0775 0.045 Uiso 1 1 calc R . .
H76 H 0.0576 0.4372 0.0615 0.045 Uiso 1 1 calc R . .
C44 C 0.2745(4) 0.1906(3) 0.6072(3) 0.0297(13) Uani 1 1 d . . .
H56 H 0.2858 0.2208 0.6556 0.036 Uiso 1 1 calc R . .
H57 H 0.3254 0.1546 0.6154 0.036 Uiso 1 1 calc R . .
C56 C 0.3972(5) 0.4731(3) 0.3348(4) 0.0387(15) Uani 1 1 d . . .
H78 H 0.3516 0.4978 0.3593 0.046 Uiso 1 1 calc R . .
H79 H 0.3860 0.4192 0.3410 0.046 Uiso 1 1 calc R . .
C77 C -0.2922(5) 0.3363(3) 0.4939(3) 0.0336(13) Uani 1 1 d . . .
C82 C 0.1905(4) 0.3225(3) 0.7537(3) 0.0291(13) Uani 1 1 d . . .
C73 C -0.1916(4) 0.2563(3) 0.5799(3) 0.0247(11) Uani 1 1 d . . .
C68 C 0.0553(4) 0.3340(3) 0.4117(3) 0.0246(11) Uani 1 1 d . . .
H100 H 0.1204 0.3121 0.4159 0.030 Uiso 1 1 calc R . .
H101 H -0.0043 0.2957 0.3858 0.030 Uiso 1 1 calc R . .
C38 C -0.2167(4) -0.0054(3) 0.2420(3) 0.0295(13) Uani 1 1 d . . .
H45 H -0.2928 -0.0132 0.2171 0.035 Uiso 1 1 calc R . .
H46 H -0.1933 -0.0547 0.2505 0.035 Uiso 1 1 calc R . .
C81 C 0.1605(4) 0.2476(3) 0.7513(3) 0.0289(12) Uani 1 1 d . . .
C51 C 0.2426(6) 0.4782(4) -0.0228(4) 0.0465(17) Uani 1 1 d . . .
H69 H 0.2861 0.4398 -0.0299 0.056 Uiso 1 1 calc R . .
H70 H 0.2658 0.5237 -0.0446 0.056 Uiso 1 1 calc R . .
C79 C -0.0221(4) 0.2596(3) 0.6963(3) 0.0236(11) Uani 1 1 d . . .
C25 C 0.1584(4) -0.0061(3) 0.0307(3) 0.0297(13) Uani 1 1 d . . .
H21 H 0.0849 -0.0142 -0.0011 0.036 Uiso 1 1 calc R . .
H22 H 0.1963 0.0344 0.0107 0.036 Uiso 1 1 calc R . .
C39 C -0.1941(4) 0.0398(3) 0.3172(3) 0.0301(13) Uani 1 1 d . . .
H47 H -0.2290 0.0122 0.3505 0.036 Uiso 1 1 calc R . .
H48 H -0.2231 0.0872 0.3088 0.036 Uiso 1 1 calc R . .
C15 C 0.4581(4) 0.3690(3) 0.1151(3) 0.0208(11) Uani 1 1 d . . .
H9 H 0.4618 0.3815 0.1665 0.025 Uiso 1 1 calc R . .
C53 C 0.0887(6) 0.3819(4) -0.0297(4) 0.0491(17) Uani 1 1 d . . .
H73 H 0.1287 0.3411 -0.0366 0.059 Uiso 1 1 calc R . .
H74 H 0.0141 0.3650 -0.0557 0.059 Uiso 1 1 calc R . .
C42 C 0.1422(5) 0.1033(3) 0.5071(3) 0.0287(12) Uani 1 1 d . . .
H52 H 0.0704 0.0762 0.4928 0.034 Uiso 1 1 calc R . .
H53 H 0.1915 0.0663 0.5114 0.034 Uiso 1 1 calc R . .
C31 C 0.5600(4) -0.0133(3) 0.3880(4) 0.0352(14) Uani 1 1 d . . .
H32 H 0.5708 -0.0599 0.4130 0.042 Uiso 1 1 calc R . .
H33 H 0.5969 -0.0119 0.3483 0.042 Uiso 1 1 calc R . .
C84 C 0.0130(4) 0.3352(3) 0.6992(3) 0.0234(11) Uani 1 1 d . . .
C40 C -0.0763(4) 0.0564(3) 0.3569(3) 0.0263(12) Uani 1 1 d . . .
H49 H -0.0647 0.0896 0.4035 0.032 Uiso 1 1 calc R . .
H50 H -0.0494 0.0094 0.3721 0.032 Uiso 1 1 calc R . .
C30 C 0.4427(4) -0.0141(3) 0.3504(3) 0.0218(11) Uani 1 1 d . . .
H30 H 0.4175 -0.0550 0.3097 0.026 Uiso 1 1 calc R . .
H31 H 0.4039 -0.0230 0.3884 0.026 Uiso 1 1 calc R . .
C83 C 0.1150(4) 0.3675(3) 0.7263(3) 0.0251(12) Uani 1 1 d . . .
C48 C 0.0416(4) 0.4604(2) 0.2191(3) 0.0168(10) Uani 1 1 d . . .
H64 H -0.0031 0.4491 0.1663 0.020 Uiso 1 1 calc R . .
H65 H 0.0073 0.4938 0.2456 0.020 Uiso 1 1 calc R . .
C58 C 0.5330(5) 0.5862(4) 0.3601(5) 0.068(3) Uani 1 1 d . . .
H82 H 0.4963 0.6158 0.3882 0.081 Uiso 1 1 calc R . .
H83 H 0.6088 0.6029 0.3809 0.081 Uiso 1 1 calc R . .
C47 C 0.1480(4) 0.5005(3) 0.2185(3) 0.0196(10) Uani 1 1 d . . .
H62 H 0.1812 0.5293 0.2680 0.024 Uiso 1 1 calc R . .
H63 H 0.1376 0.5361 0.1789 0.024 Uiso 1 1 calc R . .
B1 B -0.1452(5) 0.2238(3) 0.6620(4) 0.0234(13) Uani 1 1 d . . .
H110 H -0.142(4) 0.164(3) 0.649(3) 0.011(12) Uiso 1 1 d . . .
C57 C 0.5104(5) 0.5040(4) 0.3734(5) 0.061(2) Uani 1 1 d . . .
H80 H 0.5563 0.4751 0.3533 0.073 Uiso 1 1 calc R . .
H81 H 0.5260 0.4987 0.4285 0.073 Uiso 1 1 calc R . .
C60 C 0.3845(4) 0.5697(3) 0.2413(3) 0.0295(13) Uani 1 1 d . . .
H86 H 0.3400 0.5950 0.2662 0.035 Uiso 1 1 calc R . .
H87 H 0.3645 0.5792 0.1870 0.035 Uiso 1 1 calc R . .
C59 C 0.4998(5) 0.6011(3) 0.2780(5) 0.052(2) Uani 1 1 d . . .
H84 H 0.5439 0.5779 0.2509 0.062 Uiso 1 1 calc R . .
H85 H 0.5100 0.6554 0.2736 0.062 Uiso 1 1 calc R . .
F15 F -0.3685(3) 0.18106(18) 0.62634(19) 0.0375(8) Uani 1 1 d . . .
C2 C 0.2439(4) 0.2111(3) 0.0557(3) 0.0186(10) Uani 1 1 d . . .
C20 C 0.3601(4) 0.2018(3) -0.0240(3) 0.0209(11) Uani 1 1 d . . .
H13 H 0.3635 0.1883 -0.0765 0.025 Uiso 1 1 calc R . .
C7 C 0.2494(4) 0.1912(3) -0.0169(3) 0.0202(10) Uani 1 1 d . . .
C63 C -0.1978(4) 0.2435(3) 0.1061(3) 0.0286(12) Uani 1 1 d . . .
H91 H -0.2057 0.2314 0.0517 0.034 Uiso 1 1 calc R . .
H92 H -0.2006 0.1962 0.1305 0.034 Uiso 1 1 calc R . .
C3 C 0.1464(4) 0.2070(3) 0.0686(3) 0.0246(11) Uani 1 1 d . . .
H1 H 0.1411 0.2201 0.1178 0.030 Uiso 1 1 calc R . .
C90 C -0.3223(4) 0.2107(3) 0.6990(3) 0.0288(13) Uani 1 1 d . . .
C5 C 0.0626(4) 0.1635(3) -0.0621(3) 0.0296(13) Uani 1 1 d . . .
H3 H 0.0006 0.1475 -0.1018 0.036 Uiso 1 1 calc R . .
C4 C 0.0566(4) 0.1835(3) 0.0095(3) 0.0309(13) Uani 1 1 d . . .
H2 H -0.0098 0.1813 0.0186 0.037 Uiso 1 1 calc R . .
C66 C -0.1695(4) 0.3578(3) 0.2314(3) 0.0253(12) Uani 1 1 d . . .
H97 H -0.1617 0.3713 0.2856 0.030 Uiso 1 1 calc R . .
H98 H -0.1681 0.4043 0.2055 0.030 Uiso 1 1 calc R . .
C6 C 0.1590(4) 0.1666(3) -0.0765(3) 0.0255(12) Uani 1 1 d . . .
H4 H 0.1638 0.1524 -0.1256 0.031 Uiso 1 1 calc R . .
C65 C -0.2741(4) 0.3089(3) 0.1964(3) 0.0320(13) Uani 1 1 d . . .
H95 H -0.2783 0.2649 0.2256 0.038 Uiso 1 1 calc R . .
H96 H -0.3315 0.3372 0.1995 0.038 Uiso 1 1 calc R . .
C64 C -0.2877(4) 0.2834(3) 0.1141(3) 0.0276(12) Uani 1 1 d . . .
H93 H -0.2913 0.3271 0.0837 0.033 Uiso 1 1 calc R . .
H94 H -0.3542 0.2496 0.0941 0.033 Uiso 1 1 calc R . .
C62 C -0.0919(4) 0.2903(3) 0.1422(3) 0.0245(11) Uani 1 1 d . . .
H89 H -0.0359 0.2603 0.1400 0.029 Uiso 1 1 calc R . .
H90 H -0.0848 0.3338 0.1126 0.029 Uiso 1 1 calc R . .
F11 F -0.0768(3) 0.2925(2) 0.8262(2) 0.0485(10) Uani 1 1 d . . .
F14 F -0.4899(3) 0.1900(2) 0.7183(2) 0.0503(10) Uani 1 1 d . . .
F13 F -0.4075(3) 0.2490(2) 0.8643(2) 0.0519(10) Uani 1 1 d . . .
F12 F -0.1995(3) 0.3003(2) 0.9157(2) 0.0566(11) Uani 1 1 d . . .
C86 C -0.1797(4) 0.2651(3) 0.7951(3) 0.0313(13) Uani 1 1 d . . .
C88 C -0.3466(5) 0.2447(3) 0.8179(4) 0.0380(15) Uani 1 1 d . . .
C89 C -0.3864(5) 0.2155(3) 0.7445(4) 0.0326(13) Uani 1 1 d . . .
C87 C -0.2413(5) 0.2704(3) 0.8434(3) 0.0373(15) Uani 1 1 d . . .
H111 H 0.171(6) 0.2527(16) 0.306(3) 0.11(3) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P3 Pt2 P4 87.74(4) . .
P3 Pt2 Ge1 100.02(3) . .
P4 Pt2 Ge1 170.82(3) . .
P3 Pt2 Pt1 153.05(3) . .
P4 Pt2 Pt1 119.07(3) . .
Ge1 Pt2 Pt1 53.026(12) . .
P3 Pt2 H111 163.4(18) . .
P4 Pt2 H111 86.1(13) . .
Ge1 Pt2 H111 87.7(10) . .
Pt1 Pt2 H111 37.3(3) . .
P1 Pt1 P2 87.10(4) . .
P1 Pt1 Ge1 102.84(3) . .
P2 Pt1 Ge1 167.48(3) . .
P1 Pt1 Pt2 154.76(3) . .
P2 Pt1 Pt2 118.00(3) . .
Ge1 Pt1 Pt2 52.732(13) . .
P1 Pt1 H111 167.0(9) . .
P2 Pt1 H111 81.7(7) . .
Ge1 Pt1 H111 87.5(10) . .
Pt2 Pt1 H111 37.4(3) . .
C1 Ge1 Cl1 104.24(14) . .
C1 Ge1 Pt2 126.90(13) . .
Cl1 Ge1 Pt2 111.30(4) . .
C1 Ge1 Pt1 124.72(13) . .
Cl1 Ge1 Pt1 113.52(4) . .
Pt2 Ge1 Pt1 74.242(16) . .
C22 P2 C35 106.6(2) . .
C22 P2 C41 103.5(2) . .
C35 P2 C41 107.4(2) . .
C22 P2 Pt1 106.26(15) . .
C35 P2 Pt1 116.87(16) . .
C41 P2 Pt1 115.03(16) . .
C48 P4 C67 104.0(2) . .
C48 P4 C61 103.5(2) . .
C67 P4 C61 104.5(2) . .
C48 P4 Pt2 106.49(16) . .
C67 P4 Pt2 119.40(16) . .
C61 P4 Pt2 117.09(16) . .
C23 P1 C21 102.8(2) . .
C23 P1 C29 106.4(2) . .
C21 P1 C29 106.7(2) . .
C23 P1 Pt1 117.17(15) . .
C21 P1 Pt1 107.02(15) . .
C29 P1 Pt1 115.58(15) . .
C55 P3 C47 103.6(2) . .
C55 P3 C49 109.3(2) . .
C47 P3 C49 105.9(2) . .
C55 P3 Pt2 115.60(17) . .
C47 P3 Pt2 108.15(15) . .
C49 P3 Pt2 113.34(17) . .
F2 C75 C74 121.3(6) . .
F2 C75 C76 118.8(6) . .
C74 C75 C76 119.9(6) . .
C15 C14 C19 119.0(5) . .
C15 C14 C1 127.3(5) . .
C19 C14 C1 113.4(4) . .
C86 C85 C90 112.7(5) . .
C86 C85 B1 126.7(5) . .
C90 C85 B1 120.5(5) . .
C68 C69 C70 111.3(5) . .
C68 C69 H102 109.4 . .
C70 C69 H102 109.4 . .
C68 C69 H103 109.4 . .
C70 C69 H103 109.4 . .
H102 C69 H103 108.0 . .
C62 C61 C66 110.8(4) . .
C62 C61 P4 111.0(3) . .
C66 C61 P4 113.9(3) . .
C62 C61 H88 106.9 . .
C66 C61 H88 106.9 . .
P4 C61 H88 106.9 . .
C29 C34 C33 110.9(4) . .
C29 C34 H38 109.5 . .
C33 C34 H38 109.5 . .
C29 C34 H39 109.5 . .
C33 C34 H39 109.5 . .
H38 C34 H39 108.1 . .
C40 C35 C36 111.5(4) . .
C40 C35 P2 116.0(4) . .
C36 C35 P2 109.7(3) . .
C40 C35 H40 106.3 . .
C36 C35 H40 106.3 . .
P2 C35 H40 106.3 . .
C49 C50 C51 112.0(5) . .
C49 C50 H67 109.2 . .
C51 C50 H67 109.2 . .
C49 C50 H68 109.2 . .
C51 C50 H68 109.2 . .
H67 C50 H68 107.9 . .
C31 C32 C33 112.6(5) . .
C31 C32 H34 109.1 . .
C33 C32 H34 109.1 . .
C31 C32 H35 109.1 . .
C33 C32 H35 109.1 . .
H34 C32 H35 107.8 . .
C50 C49 C54 112.1(5) . .
C50 C49 P3 119.5(4) . .
C54 C49 P3 109.8(4) . .
C50 C49 H66 104.7 . .
C54 C49 H66 104.7 . .
P3 C49 H66 104.7 . .
C68 C67 C72 109.3(4) . .
C68 C67 P4 111.7(3) . .
C72 C67 P4 112.5(3) . .
C68 C67 H99 107.7 . .
C72 C67 H99 107.7 . .
P4 C67 H99 107.7 . .
C26 C27 C28 111.2(4) . .
C26 C27 H25 109.4 . .
C28 C27 H25 109.4 . .
C26 C27 H26 109.4 . .
C28 C27 H26 109.4 . .
H25 C27 H26 108.0 . .
C27 C28 C23 111.0(4) . .
C27 C28 H27 109.4 . .
C23 C28 H27 109.4 . .
C27 C28 H28 109.4 . .
C23 C28 H28 109.4 . .
H27 C28 H28 108.0 . .
C17 C18 C19 119.4(5) . .
C17 C18 H12 120.3 . .
C19 C18 H12 120.3 . .
C8 C9 C10 119.9(5) . .
C8 C9 H5 120.1 . .
C10 C9 H5 120.1 . .
C10 C11 C12 119.5(5) . .
C10 C11 H7 120.2 . .
C12 C11 H7 120.2 . .
C27 C26 C25 111.6(4) . .
C27 C26 H23 109.3 . .
C25 C26 H23 109.3 . .
C27 C26 H24 109.3 . .
C25 C26 H24 109.3 . .
H23 C26 H24 108.0 . .
C15 C16 C17 120.4(5) . .
C15 C16 H10 119.8 . .
C17 C16 H10 119.8 . .
C9 C8 C13 118.3(4) . .
C9 C8 C1 126.6(4) . .
C13 C8 C1 114.7(4) . .
C22 C21 P1 111.3(3) . .
C22 C21 H14 109.4 . .
P1 C21 H14 109.4 . .
C22 C21 H15 109.4 . .
P1 C21 H15 109.4 . .
H14 C21 H15 108.0 . .
F6 C80 C81 116.4(5) . .
F6 C80 C79 120.2(5) . .
C81 C80 C79 123.4(5) . .
C18 C19 C14 120.5(5) . .
C18 C19 C20 125.4(5) . .
C14 C19 C20 113.6(4) . .
C34 C29 C30 109.5(4) . .
C34 C29 P1 113.4(3) . .
C30 C29 P1 114.9(3) . .
C34 C29 H29 106.1 . .
C30 C29 H29 106.1 . .
P1 C29 H29 106.1 . .
C12 C13 C8 121.2(5) . .
C12 C13 C20 125.8(5) . .
C8 C13 C20 112.7(4) . .
C37 C36 C35 111.8(4) . .
C37 C36 H41 109.2 . .
C35 C36 H41 109.2 . .
C37 C36 H42 109.2 . .
C35 C36 H42 109.2 . .
H41 C36 H42 107.9 . .
C44 C43 C42 110.9(5) . .
C44 C43 H54 109.5 . .
C42 C43 H54 109.5 . .
C44 C43 H55 109.5 . .
C42 C43 H55 109.5 . .
H54 C43 H55 108.0 . .
F1 C74 C75 115.6(5) . .
F1 C74 C73 120.5(5) . .
C75 C74 C73 123.9(6) . .
C53 C52 C51 109.7(5) . .
C53 C52 H71 109.7 . .
C51 C52 H71 109.7 . .
C53 C52 H72 109.7 . .
C51 C52 H72 109.7 . .
H71 C52 H72 108.2 . .
C13 C12 C11 120.3(5) . .
C13 C12 H8 119.8 . .
C11 C12 H8 119.8 . .
C28 C23 C24 110.7(4) . .
C28 C23 P1 114.7(3) . .
C24 C23 P1 112.4(3) . .
C28 C23 H18 106.1 . .
C24 C23 H18 106.1 . .
P1 C23 H18 106.1 . .
C11 C10 C9 120.7(5) . .
C11 C10 H6 119.7 . .
C9 C10 H6 119.7 . .
C71 C70 C69 111.0(4) . .
C71 C70 H104 109.4 . .
C69 C70 H104 109.4 . .
C71 C70 H105 109.4 . .
C69 C70 H105 109.4 . .
H104 C70 H105 108.0 . .
C32 C33 C34 111.6(4) . .
C32 C33 H36 109.3 . .
C34 C33 H36 109.3 . .
C32 C33 H37 109.3 . .
C34 C33 H37 109.3 . .
H36 C33 H37 108.0 . .
C18 C17 C16 120.6(5) . .
C18 C17 H11 119.7 . .
C16 C17 H11 119.7 . .
C71 C72 C67 109.0(4) . .
C71 C72 H108 109.9 . .
C67 C72 H108 109.9 . .
C71 C72 H109 109.9 . .
C67 C72 H109 109.9 . .
H108 C72 H109 108.3 . .
C70 C71 C72 112.4(4) . .
C70 C71 H106 109.1 . .
C72 C71 H106 109.1 . .
C70 C71 H107 109.1 . .
C72 C71 H107 109.1 . .
H106 C71 H107 107.8 . .
C25 C24 C23 110.6(4) . .
C25 C24 H19 109.5 . .
C23 C24 H19 109.5 . .
C25 C24 H20 109.5 . .
C23 C24 H20 109.5 . .
H19 C24 H20 108.1 . .
C38 C37 C36 111.0(4) . .
C38 C37 H43 109.4 . .
C36 C37 H43 109.4 . .
C38 C37 H44 109.4 . .
C36 C37 H44 109.4 . .
H43 C37 H44 108.0 . .
C42 C41 C46 109.0(4) . .
C42 C41 P2 117.0(3) . .
C46 C41 P2 108.6(3) . .
C42 C41 H51 107.3 . .
C46 C41 H51 107.3 . .
P2 C41 H51 107.3 . .
F3 C76 C77 120.5(6) . .
F3 C76 C75 120.8(6) . .
C77 C76 C75 118.7(6) . .
C8 C1 C2 107.5(4) . .
C8 C1 C14 98.7(4) . .
C2 C1 C14 105.7(4) . .
C8 C1 Ge1 116.0(3) . .
C2 C1 Ge1 108.5(3) . .
C14 C1 Ge1 119.4(3) . .
F5 C78 C73 120.6(5) . .
F5 C78 C77 115.1(5) . .
C73 C78 C77 124.3(5) . .
C44 C45 C46 111.8(5) . .
C44 C45 H58 109.3 . .
C46 C45 H58 109.3 . .
C44 C45 H59 109.3 . .
C46 C45 H59 109.3 . .
H58 C45 H59 107.9 . .
C45 C46 C41 112.4(4) . .
C45 C46 H60 109.1 . .
C41 C46 H60 109.1 . .
C45 C46 H61 109.1 . .
C41 C46 H61 109.1 . .
H60 C46 H61 107.9 . .
C60 C55 C56 108.1(4) . .
C60 C55 P3 116.6(4) . .
C56 C55 P3 110.5(4) . .
C60 C55 H77 107.0 . .
C56 C55 H77 107.0 . .
P3 C55 H77 107.0 . .
C21 C22 P2 110.4(3) . .
C21 C22 H16 109.6 . .
P2 C22 H16 109.6 . .
C21 C22 H17 109.6 . .
P2 C22 H17 109.6 . .
H16 C22 H17 108.1 . .
C53 C54 C49 111.1(5) . .
C53 C54 H75 109.4 . .
C49 C54 H75 109.4 . .
C53 C54 H76 109.4 . .
C49 C54 H76 109.4 . .
H75 C54 H76 108.0 . .
C45 C44 C43 111.1(4) . .
C45 C44 H56 109.4 . .
C43 C44 H56 109.4 . .
C45 C44 H57 109.4 . .
C43 C44 H57 109.4 . .
H56 C44 H57 108.0 . .
C57 C56 C55 111.1(6) . .
C57 C56 H78 109.4 . .
C55 C56 H78 109.4 . .
C57 C56 H79 109.4 . .
C55 C56 H79 109.4 . .
H78 C56 H79 108.0 . .
F4 C77 C76 120.5(5) . .
F4 C77 C78 120.2(5) . .
C76 C77 C78 119.3(6) . .
F8 C82 C81 121.4(5) . .
F8 C82 C83 120.0(5) . .
C81 C82 C83 118.6(5) . .
C78 C73 C74 113.8(5) . .
C78 C73 B1 126.8(5) . .
C74 C73 B1 119.4(5) . .
C67 C68 C69 111.4(4) . .
C67 C68 H100 109.3 . .
C69 C68 H100 109.3 . .
C67 C68 H101 109.3 . .
C69 C68 H101 109.3 . .
H100 C68 H101 108.0 . .
C39 C38 C37 109.9(5) . .
C39 C38 H45 109.7 . .
C37 C38 H45 109.7 . .
C39 C38 H46 109.7 . .
C37 C38 H46 109.7 . .
H45 C38 H46 108.2 . .
F7 C81 C82 118.6(5) . .
F7 C81 C80 120.5(5) . .
C82 C81 C80 120.9(5) . .
C50 C51 C52 110.9(5) . .
C50 C51 H69 109.5 . .
C52 C51 H69 109.5 . .
C50 C51 H70 109.5 . .
C52 C51 H70 109.5 . .
H69 C51 H70 108.1 . .
C80 C79 C84 113.2(5) . .
C80 C79 B1 123.6(5) . .
C84 C79 B1 123.3(5) . .
C26 C25 C24 111.7(5) . .
C26 C25 H21 109.3 . .
C24 C25 H21 109.3 . .
C26 C25 H22 109.3 . .
C24 C25 H22 109.3 . .
H21 C25 H22 108.0 . .
C38 C39 C40 111.8(4) . .
C38 C39 H47 109.3 . .
C40 C39 H47 109.3 . .
C38 C39 H48 109.3 . .
C40 C39 H48 109.3 . .
H47 C39 H48 107.9 . .
C16 C15 C14 120.0(5) . .
C16 C15 H9 120.0 . .
C14 C15 H9 120.0 . .
C52 C53 C54 110.6(5) . .
C52 C53 H73 109.5 . .
C54 C53 H73 109.5 . .
C52 C53 H74 109.5 . .
C54 C53 H74 109.5 . .
H73 C53 H74 108.1 . .
C43 C42 C41 110.1(4) . .
C43 C42 H52 109.6 . .
C41 C42 H52 109.6 . .
C43 C42 H53 109.6 . .
C41 C42 H53 109.6 . .
H52 C42 H53 108.1 . .
C32 C31 C30 112.9(5) . .
C32 C31 H32 109.0 . .
C30 C31 H32 109.0 . .
C32 C31 H33 109.0 . .
C30 C31 H33 109.0 . .
H32 C31 H33 107.8 . .
F10 C84 C83 115.7(4) . .
F10 C84 C79 118.9(5) . .
C83 C84 C79 125.4(5) . .
C35 C40 C39 112.5(4) . .
C35 C40 H49 109.1 . .
C39 C40 H49 109.1 . .
C35 C40 H50 109.1 . .
C39 C40 H50 109.1 . .
H49 C40 H50 107.8 . .
C29 C30 C31 110.5(4) . .
C29 C30 H30 109.6 . .
C31 C30 H30 109.6 . .
C29 C30 H31 109.6 . .
C31 C30 H31 109.6 . .
H30 C30 H31 108.1 . .
F9 C83 C84 121.8(5) . .
F9 C83 C82 119.7(5) . .
C84 C83 C82 118.5(5) . .
C47 C48 P4 112.4(3) . .
C47 C48 H64 109.1 . .
P4 C48 H64 109.1 . .
C47 C48 H65 109.1 . .
P4 C48 H65 109.1 . .
H64 C48 H65 107.9 . .
C59 C58 C57 113.4(6) . .
C59 C58 H82 108.9 . .
C57 C58 H82 108.9 . .
C59 C58 H83 108.9 . .
C57 C58 H83 108.9 . .
H82 C58 H83 107.7 . .
C48 C47 P3 112.9(3) . .
C48 C47 H62 109.0 . .
P3 C47 H62 109.0 . .
C48 C47 H63 109.0 . .
P3 C47 H63 109.0 . .
H62 C47 H63 107.8 . .
C73 B1 C79 108.4(4) . .
C73 B1 C85 113.2(4) . .
C79 B1 C85 113.7(4) . .
C73 B1 H110 105(2) . .
C79 B1 H110 104(2) . .
C85 B1 H110 112(2) . .
C56 C57 C58 111.0(5) . .
C56 C57 H80 109.4 . .
C58 C57 H80 109.4 . .
C56 C57 H81 109.4 . .
C58 C57 H81 109.4 . .
H80 C57 H81 108.0 . .
C55 C60 C59 110.1(5) . .
C55 C60 H86 109.6 . .
C59 C60 H86 109.6 . .
C55 C60 H87 109.6 . .
C59 C60 H87 109.6 . .
H86 C60 H87 108.2 . .
C58 C59 C60 110.8(6) . .
C58 C59 H84 109.5 . .
C60 C59 H84 109.5 . .
C58 C59 H85 109.5 . .
C60 C59 H85 109.5 . .
H84 C59 H85 108.1 . .
C3 C2 C7 118.8(4) . .
C3 C2 C1 126.6(4) . .
C7 C2 C1 114.6(4) . .
C13 C20 C19 103.8(4) . .
C13 C20 C7 107.2(4) . .
C19 C20 C7 106.0(4) . .
C13 C20 H13 113.0 . .
C19 C20 H13 113.0 . .
C7 C20 H13 113.0 . .
C2 C7 C6 121.4(5) . .
C2 C7 C20 113.3(4) . .
C6 C7 C20 125.2(5) . .
C64 C63 C62 112.2(4) . .
C64 C63 H91 109.2 . .
C62 C63 H91 109.2 . .
C64 C63 H92 109.2 . .
C62 C63 H92 109.2 . .
H91 C63 H92 107.9 . .
C2 C3 C4 120.0(5) . .
C2 C3 H1 120.0 . .
C4 C3 H1 120.0 . .
F15 C90 C89 116.5(5) . .
F15 C90 C85 118.8(5) . .
C89 C90 C85 124.7(6) . .
C4 C5 C6 120.3(5) . .
C4 C5 H3 119.8 . .
C6 C5 H3 119.8 . .
C5 C4 C3 120.9(5) . .
C5 C4 H2 119.6 . .
C3 C4 H2 119.6 . .
C65 C66 C61 111.3(4) . .
C65 C66 H97 109.4 . .
C61 C66 H97 109.4 . .
C65 C66 H98 109.4 . .
C61 C66 H98 109.4 . .
H97 C66 H98 108.0 . .
C5 C6 C7 118.6(5) . .
C5 C6 H4 120.7 . .
C7 C6 H4 120.7 . .
C64 C65 C66 111.6(5) . .
C64 C65 H95 109.3 . .
C66 C65 H95 109.3 . .
C64 C65 H96 109.3 . .
C66 C65 H96 109.3 . .
H95 C65 H96 108.0 . .
C65 C64 C63 111.0(4) . .
C65 C64 H93 109.4 . .
C63 C64 H93 109.4 . .
C65 C64 H94 109.4 . .
C63 C64 H94 109.4 . .
H93 C64 H94 108.0 . .
C61 C62 C63 112.4(4) . .
C61 C62 H89 109.1 . .
C63 C62 H89 109.1 . .
C61 C62 H90 109.1 . .
C63 C62 H90 109.1 . .
H89 C62 H90 107.9 . .
F11 C86 C85 120.7(5) . .
F11 C86 C87 114.8(5) . .
C85 C86 C87 124.5(6) . .
F13 C88 C89 121.5(6) . .
F13 C88 C87 120.5(6) . .
C89 C88 C87 118.0(6) . .
F14 C89 C88 119.0(6) . .
F14 C89 C90 120.8(6) . .
C88 C89 C90 120.2(6) . .
F12 C87 C88 119.5(6) . .
F12 C87 C86 120.7(6) . .
C88 C87 C86 119.8(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt2 P3 2.2608(12) .
Pt2 P4 2.3145(12) .
Pt2 Ge1 2.4308(5) .
Pt2 Pt1 2.9397(4) .
Pt2 H111 1.851(10) .
Pt1 P1 2.2599(12) .
Pt1 P2 2.3321(12) .
Pt1 Ge1 2.4403(5) .
Pt1 H111 1.847(10) .
Ge1 C1 2.025(5) .
Ge1 Cl1 2.2057(15) .
P2 C22 1.847(5) .
P2 C35 1.856(5) .
P2 C41 1.855(5) .
P4 C48 1.845(5) .
P4 C67 1.851(5) .
P4 C61 1.857(5) .
P1 C23 1.840(5) .
P1 C21 1.841(5) .
P1 C29 1.857(5) .
P3 C55 1.838(5) .
P3 C47 1.845(5) .
P3 C49 1.850(5) .
F3 C76 1.339(7) .
F5 C78 1.359(6) .
F4 C77 1.342(7) .
C75 F2 1.363(7) .
C75 C74 1.370(8) .
C75 C76 1.377(9) .
F9 C83 1.346(6) .
C14 C15 1.395(7) .
C14 C19 1.407(7) .
C14 C1 1.556(7) .
F10 C84 1.365(6) .
C85 C86 1.378(8) .
C85 C90 1.390(8) .
C85 B1 1.647(8) .
C69 C68 1.532(7) .
C69 C70 1.533(7) .
C69 H102 0.9900 .
C69 H103 0.9900 .
F6 C80 1.353(6) .
C61 C62 1.525(7) .
C61 C66 1.537(7) .
C61 H88 1.0000 .
C34 C29 1.523(7) .
C34 C33 1.530(7) .
C34 H38 0.9900 .
C34 H39 0.9900 .
F8 C82 1.342(6) .
F1 C74 1.350(7) .
C35 C40 1.509(7) .
C35 C36 1.540(7) .
C35 H40 1.0000 .
C50 C49 1.485(8) .
C50 C51 1.526(9) .
C50 H67 0.9900 .
C50 H68 0.9900 .
C32 C31 1.508(8) .
C32 C33 1.513(7) .
C32 H34 0.9900 .
C32 H35 0.9900 .
F7 C81 1.362(6) .
C49 C54 1.544(8) .
C49 H66 1.0000 .
C67 C68 1.517(7) .
C67 C72 1.549(7) .
C67 H99 1.0000 .
C27 C26 1.512(7) .
C27 C28 1.532(7) .
C27 H25 0.9900 .
C27 H26 0.9900 .
C28 C23 1.538(6) .
C28 H27 0.9900 .
C28 H28 0.9900 .
C18 C17 1.376(8) .
C18 C19 1.396(7) .
C18 H12 0.9500 .
C9 C8 1.399(7) .
C9 C10 1.404(7) .
C9 H5 0.9500 .
C11 C10 1.381(7) .
C11 C12 1.395(7) .
C11 H7 0.9500 .
C26 C25 1.517(7) .
C26 H23 0.9900 .
C26 H24 0.9900 .
C16 C15 1.384(7) .
C16 C17 1.390(8) .
C16 H10 0.9500 .
C8 C13 1.411(7) .
C8 C1 1.532(6) .
C21 C22 1.534(6) .
C21 H14 0.9900 .
C21 H15 0.9900 .
C80 C81 1.373(8) .
C80 C79 1.385(7) .
C19 C20 1.519(7) .
C29 C30 1.533(6) .
C29 H29 1.0000 .
C13 C12 1.370(7) .
C13 C20 1.517(7) .
C36 C37 1.524(7) .
C36 H41 0.9900 .
C36 H42 0.9900 .
C43 C44 1.524(8) .
C43 C42 1.530(7) .
C43 H54 0.9900 .
C43 H55 0.9900 .
C74 C73 1.387(8) .
C52 C53 1.522(9) .
C52 C51 1.557(9) .
C52 H71 0.9900 .
C52 H72 0.9900 .
C12 H8 0.9500 .
C23 C24 1.538(7) .
C23 H18 1.0000 .
C10 H6 0.9500 .
C70 C71 1.522(8) .
C70 H104 0.9900 .
C70 H105 0.9900 .
C33 H36 0.9900 .
C33 H37 0.9900 .
C17 H11 0.9500 .
C72 C71 1.530(7) .
C72 H108 0.9900 .
C72 H109 0.9900 .
C71 H106 0.9900 .
C71 H107 0.9900 .
C24 C25 1.520(7) .
C24 H19 0.9900 .
C24 H20 0.9900 .
C37 C38 1.519(8) .
C37 H43 0.9900 .
C37 H44 0.9900 .
C41 C42 1.538(7) .
C41 C46 1.548(7) .
C41 H51 1.0000 .
C76 C77 1.367(9) .
C1 C2 1.536(6) .
C78 C73 1.376(8) .
C78 C77 1.387(8) .
C45 C44 1.515(8) .
C45 C46 1.525(7) .
C45 H58 0.9900 .
C45 H59 0.9900 .
C46 H60 0.9900 .
C46 H61 0.9900 .
C55 C60 1.536(7) .
C55 C56 1.557(8) .
C55 H77 1.0000 .
C22 H16 0.9900 .
C22 H17 0.9900 .
C54 C53 1.534(8) .
C54 H75 0.9900 .
C54 H76 0.9900 .
C44 H56 0.9900 .
C44 H57 0.9900 .
C56 C57 1.517(8) .
C56 H78 0.9900 .
C56 H79 0.9900 .
C82 C81 1.368(8) .
C82 C83 1.382(8) .
C73 B1 1.635(8) .
C68 H100 0.9900 .
C68 H101 0.9900 .
C38 C39 1.513(8) .
C38 H45 0.9900 .
C38 H46 0.9900 .
C51 H69 0.9900 .
C51 H70 0.9900 .
C79 C84 1.393(7) .
C79 B1 1.642(8) .
C25 H21 0.9900 .
C25 H22 0.9900 .
C39 C40 1.538(7) .
C39 H47 0.9900 .
C39 H48 0.9900 .
C15 H9 0.9500 .
C53 H73 0.9900 .
C53 H74 0.9900 .
C42 H52 0.9900 .
C42 H53 0.9900 .
C31 C30 1.537(7) .
C31 H32 0.9900 .
C31 H33 0.9900 .
C84 C83 1.372(8) .
C40 H49 0.9900 .
C40 H50 0.9900 .
C30 H30 0.9900 .
C30 H31 0.9900 .
C48 C47 1.532(7) .
C48 H64 0.9900 .
C48 H65 0.9900 .
C58 C59 1.502(11) .
C58 C57 1.534(10) .
C58 H82 0.9900 .
C58 H83 0.9900 .
C47 H62 0.9900 .
C47 H63 0.9900 .
B1 H110 1.11(5) .
C57 H80 0.9900 .
C57 H81 0.9900 .
C60 C59 1.538(8) .
C60 H86 0.9900 .
C60 H87 0.9900 .
C59 H84 0.9900 .
C59 H85 0.9900 .
F15 C90 1.364(7) .
C2 C3 1.391(7) .
C2 C7 1.393(7) .
C20 C7 1.521(7) .
C20 H13 1.0000 .
C7 C6 1.405(7) .
C63 C64 1.519(8) .
C63 C62 1.528(7) .
C63 H91 0.9900 .
C63 H92 0.9900 .
C3 C4 1.393(7) .
C3 H1 0.9500 .
C90 C89 1.366(8) .
C5 C4 1.379(8) .
C5 C6 1.389(8) .
C5 H3 0.9500 .
C4 H2 0.9500 .
C66 C65 1.529(7) .
C66 H97 0.9900 .
C66 H98 0.9900 .
C6 H4 0.9500 .
C65 C64 1.519(8) .
C65 H95 0.9900 .
C65 H96 0.9900 .
C64 H93 0.9900 .
C64 H94 0.9900 .
C62 H89 0.9900 .
C62 H90 0.9900 .
F11 C86 1.365(7) .
F14 C89 1.358(7) .
F13 C88 1.342(7) .
F12 C87 1.354(7) .
C86 C87 1.380(9) .
C88 C89 1.365(9) .
C88 C87 1.378(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
P3 Pt2 Pt1 P1 -15.82(10) . . . .
P4 Pt2 Pt1 P1 157.97(8) . . . .
Ge1 Pt2 Pt1 P1 -16.44(7) . . . .
P3 Pt2 Pt1 P2 170.60(8) . . . .
P4 Pt2 Pt1 P2 -15.62(5) . . . .
Ge1 Pt2 Pt1 P2 169.98(4) . . . .
P3 Pt2 Pt1 Ge1 0.62(7) . . . .
P4 Pt2 Pt1 Ge1 174.40(4) . . . .
P3 Pt2 Ge1 C1 -57.83(17) . . . .
P4 Pt2 Ge1 C1 89.6(3) . . . .
Pt1 Pt2 Ge1 C1 121.89(17) . . . .
P3 Pt2 Ge1 Cl1 70.70(6) . . . .
P4 Pt2 Ge1 Cl1 -141.9(2) . . . .
Pt1 Pt2 Ge1 Cl1 -109.58(5) . . . .
P3 Pt2 Ge1 Pt1 -179.72(3) . . . .
P4 Pt2 Ge1 Pt1 -32.3(2) . . . .
P1 Pt1 Ge1 C1 48.59(16) . . . .
P2 Pt1 Ge1 C1 -169.4(2) . . . .
Pt2 Pt1 Ge1 C1 -124.30(16) . . . .
P1 Pt1 Ge1 Cl1 -80.32(6) . . . .
P2 Pt1 Ge1 Cl1 61.65(16) . . . .
Pt2 Pt1 Ge1 Cl1 106.79(5) . . . .
P1 Pt1 Ge1 Pt2 172.89(3) . . . .
P2 Pt1 Ge1 Pt2 -45.14(15) . . . .
P1 Pt1 P2 C22 8.14(17) . . . .
Ge1 Pt1 P2 C22 -134.9(2) . . . .
Pt2 Pt1 P2 C22 -174.60(16) . . . .
P1 Pt1 P2 C35 -110.68(17) . . . .
Ge1 Pt1 P2 C35 106.3(2) . . . .
Pt2 Pt1 P2 C35 66.59(18) . . . .
P1 Pt1 P2 C41 121.97(18) . . . .
Ge1 Pt1 P2 C41 -21.1(3) . . . .
Pt2 Pt1 P2 C41 -60.77(18) . . . .
P3 Pt2 P4 C48 11.35(16) . . . .
Ge1 Pt2 P4 C48 -136.6(2) . . . .
Pt1 Pt2 P4 C48 -165.83(16) . . . .
P3 Pt2 P4 C67 -105.85(18) . . . .
Ge1 Pt2 P4 C67 106.2(3) . . . .
Pt1 Pt2 P4 C67 76.97(18) . . . .
P3 Pt2 P4 C61 126.46(18) . . . .
Ge1 Pt2 P4 C61 -21.5(3) . . . .
Pt1 Pt2 P4 C61 -50.73(19) . . . .
P2 Pt1 P1 C23 128.36(17) . . . .
Ge1 Pt1 P1 C23 -59.32(17) . . . .
Pt2 Pt1 P1 C23 -46.0(2) . . . .
P2 Pt1 P1 C21 13.68(17) . . . .
Ge1 Pt1 P1 C21 -174.01(17) . . . .
Pt2 Pt1 P1 C21 -160.65(17) . . . .
P2 Pt1 P1 C29 -104.99(18) . . . .
Ge1 Pt1 P1 C29 67.33(18) . . . .
Pt2 Pt1 P1 C29 80.68(19) . . . .
P4 Pt2 P3 C55 122.42(19) . . . .
Ge1 Pt2 P3 C55 -62.52(19) . . . .
Pt1 Pt2 P3 C55 -63.0(2) . . . .
P4 Pt2 P3 C47 6.88(18) . . . .
Ge1 Pt2 P3 C47 -178.05(18) . . . .
Pt1 Pt2 P3 C47 -178.55(17) . . . .
P4 Pt2 P3 C49 -110.22(18) . . . .
Ge1 Pt2 P3 C49 64.85(18) . . . .
Pt1 Pt2 P3 C49 64.3(2) . . . .
C48 P4 C61 C62 71.5(4) . . . .
C67 P4 C61 C62 -179.8(3) . . . .
Pt2 P4 C61 C62 -45.2(4) . . . .
C48 P4 C61 C66 -54.4(4) . . . .
C67 P4 C61 C66 54.2(4) . . . .
Pt2 P4 C61 C66 -171.2(3) . . . .
C22 P2 C35 C40 63.6(4) . . . .
C41 P2 C35 C40 -46.8(4) . . . .
Pt1 P2 C35 C40 -177.8(3) . . . .
C22 P2 C35 C36 -63.9(4) . . . .
C41 P2 C35 C36 -174.3(3) . . . .
Pt1 P2 C35 C36 54.7(4) . . . .
C51 C50 C49 C54 -54.2(7) . . . .
C51 C50 C49 P3 175.4(4) . . . .
C55 P3 C49 C50 -40.1(5) . . . .
C47 P3 C49 C50 70.9(5) . . . .
Pt2 P3 C49 C50 -170.7(4) . . . .
C55 P3 C49 C54 -171.5(4) . . . .
C47 P3 C49 C54 -60.5(4) . . . .
Pt2 P3 C49 C54 57.9(4) . . . .
C48 P4 C67 C68 176.0(4) . . . .
C61 P4 C67 C68 67.7(4) . . . .
Pt2 P4 C67 C68 -65.6(4) . . . .
C48 P4 C67 C72 -60.6(4) . . . .
C61 P4 C67 C72 -168.8(3) . . . .
Pt2 P4 C67 C72 57.9(4) . . . .
C26 C27 C28 C23 -55.2(6) . . . .
C28 C27 C26 C25 55.4(6) . . . .
C10 C9 C8 C13 -3.5(7) . . . .
C10 C9 C8 C1 -175.4(4) . . . .
C23 P1 C21 C22 -162.8(3) . . . .
C29 P1 C21 C22 85.5(4) . . . .
Pt1 P1 C21 C22 -38.8(4) . . . .
C17 C18 C19 C14 1.4(7) . . . .
C17 C18 C19 C20 -170.4(5) . . . .
C15 C14 C19 C18 -4.0(7) . . . .
C1 C14 C19 C18 -177.4(4) . . . .
C15 C14 C19 C20 168.7(4) . . . .
C1 C14 C19 C20 -4.7(6) . . . .
C33 C34 C29 C30 59.4(5) . . . .
C33 C34 C29 P1 -170.8(3) . . . .
C23 P1 C29 C34 146.8(4) . . . .
C21 P1 C29 C34 -104.0(4) . . . .
Pt1 P1 C29 C34 14.8(4) . . . .
C23 P1 C29 C30 -86.1(4) . . . .
C21 P1 C29 C30 23.1(4) . . . .
Pt1 P1 C29 C30 141.9(3) . . . .
C9 C8 C13 C12 4.2(7) . . . .
C1 C8 C13 C12 177.1(4) . . . .
C9 C8 C13 C20 -168.9(4) . . . .
C1 C8 C13 C20 3.9(6) . . . .
C40 C35 C36 C37 52.2(6) . . . .
P2 C35 C36 C37 -177.8(4) . . . .
F2 C75 C74 F1 0.5(8) . . . .
C76 C75 C74 F1 -179.2(5) . . . .
F2 C75 C74 C73 179.7(5) . . . .
C76 C75 C74 C73 0.0(9) . . . .
C8 C13 C12 C11 -2.3(7) . . . .
C20 C13 C12 C11 170.0(5) . . . .
C10 C11 C12 C13 -0.5(7) . . . .
C27 C28 C23 C24 55.4(5) . . . .
C27 C28 C23 P1 -176.1(3) . . . .
C21 P1 C23 C28 -66.0(4) . . . .
C29 P1 C23 C28 46.0(4) . . . .
Pt1 P1 C23 C28 177.0(3) . . . .
C21 P1 C23 C24 61.7(4) . . . .
C29 P1 C23 C24 173.6(3) . . . .
Pt1 P1 C23 C24 -55.3(4) . . . .
C12 C11 C10 C9 1.1(7) . . . .
C8 C9 C10 C11 0.9(7) . . . .
C68 C69 C70 C71 52.5(6) . . . .
C31 C32 C33 C34 51.9(6) . . . .
C29 C34 C33 C32 -56.6(6) . . . .
C19 C18 C17 C16 1.8(8) . . . .
C15 C16 C17 C18 -2.4(8) . . . .
C68 C67 C72 C71 -59.4(5) . . . .
P4 C67 C72 C71 175.9(3) . . . .
C69 C70 C71 C72 -54.6(7) . . . .
C67 C72 C71 C70 57.8(6) . . . .
C28 C23 C24 C25 -55.7(6) . . . .
P1 C23 C24 C25 174.5(4) . . . .
C35 C36 C37 C38 -56.2(6) . . . .
C22 P2 C41 C42 -34.5(4) . . . .
C35 P2 C41 C42 78.0(4) . . . .
Pt1 P2 C41 C42 -150.0(3) . . . .
C22 P2 C41 C46 89.3(4) . . . .
C35 P2 C41 C46 -158.1(3) . . . .
Pt1 P2 C41 C46 -26.1(4) . . . .
F2 C75 C76 F3 -2.1(8) . . . .
C74 C75 C76 F3 177.5(5) . . . .
F2 C75 C76 C77 177.9(5) . . . .
C74 C75 C76 C77 -2.4(9) . . . .
C9 C8 C1 C2 -138.8(5) . . . .
C13 C8 C1 C2 49.1(5) . . . .
C9 C8 C1 C14 111.6(5) . . . .
C13 C8 C1 C14 -60.5(5) . . . .
C9 C8 C1 Ge1 -17.2(6) . . . .
C13 C8 C1 Ge1 170.7(3) . . . .
C15 C14 C1 C8 -112.0(5) . . . .
C19 C14 C1 C8 60.7(5) . . . .
C15 C14 C1 C2 137.0(5) . . . .
C19 C14 C1 C2 -50.3(5) . . . .
C15 C14 C1 Ge1 14.5(6) . . . .
C19 C14 C1 Ge1 -172.8(3) . . . .
Cl1 Ge1 C1 C8 61.5(3) . . . .
Pt2 Ge1 C1 C8 -167.3(2) . . . .
Pt1 Ge1 C1 C8 -71.1(4) . . . .
Cl1 Ge1 C1 C2 -177.4(3) . . . .
Pt2 Ge1 C1 C2 -46.2(4) . . . .
Pt1 Ge1 C1 C2 50.0(3) . . . .
Cl1 Ge1 C1 C14 -56.4(4) . . . .
Pt2 Ge1 C1 C14 74.8(4) . . . .
Pt1 Ge1 C1 C14 171.0(3) . . . .
C44 C45 C46 C41 53.8(6) . . . .
C42 C41 C46 C45 -55.4(6) . . . .
P2 C41 C46 C45 176.1(4) . . . .
C47 P3 C55 C60 -41.2(5) . . . .
C49 P3 C55 C60 71.4(5) . . . .
Pt2 P3 C55 C60 -159.3(4) . . . .
C47 P3 C55 C56 82.8(4) . . . .
C49 P3 C55 C56 -164.6(4) . . . .
Pt2 P3 C55 C56 -35.3(4) . . . .
P1 C21 C22 P2 47.2(4) . . . .
C35 P2 C22 C21 91.7(4) . . . .
C41 P2 C22 C21 -155.1(3) . . . .
Pt1 P2 C22 C21 -33.6(3) . . . .
C50 C49 C54 C53 54.4(7) . . . .
P3 C49 C54 C53 -170.4(4) . . . .
C46 C45 C44 C43 -53.7(6) . . . .
C42 C43 C44 C45 57.0(6) . . . .
C60 C55 C56 C57 -59.6(6) . . . .
P3 C55 C56 C57 171.7(4) . . . .
F3 C76 C77 F4 1.8(9) . . . .
C75 C76 C77 F4 -178.2(5) . . . .
F3 C76 C77 C78 -176.8(5) . . . .
C75 C76 C77 C78 3.2(9) . . . .
F5 C78 C77 F4 -2.4(8) . . . .
C73 C78 C77 F4 179.8(5) . . . .
F5 C78 C77 C76 176.2(5) . . . .
C73 C78 C77 C76 -1.6(9) . . . .
F5 C78 C73 C74 -178.4(5) . . . .
C77 C78 C73 C74 -0.7(8) . . . .
F5 C78 C73 B1 1.7(8) . . . .
C77 C78 C73 B1 179.3(5) . . . .
F1 C74 C73 C78 -179.3(5) . . . .
C75 C74 C73 C78 1.5(8) . . . .
F1 C74 C73 B1 0.6(7) . . . .
C75 C74 C73 B1 -178.6(5) . . . .
C72 C67 C68 C69 59.4(6) . . . .
P4 C67 C68 C69 -175.4(4) . . . .
C70 C69 C68 C67 -56.1(6) . . . .
C36 C37 C38 C39 58.3(6) . . . .
F8 C82 C81 F7 0.4(8) . . . .
C83 C82 C81 F7 179.1(5) . . . .
F8 C82 C81 C80 179.1(5) . . . .
C83 C82 C81 C80 -2.2(8) . . . .
F6 C80 C81 F7 0.2(8) . . . .
C79 C80 C81 F7 -178.8(5) . . . .
F6 C80 C81 C82 -178.5(5) . . . .
C79 C80 C81 C82 2.5(9) . . . .
C49 C50 C51 C52 55.7(7) . . . .
C53 C52 C51 C50 -57.1(7) . . . .
F6 C80 C79 C84 179.5(5) . . . .
C81 C80 C79 C84 -1.5(8) . . . .
F6 C80 C79 B1 -0.9(8) . . . .
C81 C80 C79 B1 178.1(5) . . . .
C27 C26 C25 C24 -56.2(6) . . . .
C23 C24 C25 C26 56.1(6) . . . .
C37 C38 C39 C40 -56.9(6) . . . .
C17 C16 C15 C14 -0.3(8) . . . .
C19 C14 C15 C16 3.4(7) . . . .
C1 C14 C15 C16 175.8(5) . . . .
C51 C52 C53 C54 57.5(7) . . . .
C49 C54 C53 C52 -56.2(7) . . . .
C44 C43 C42 C41 -59.7(6) . . . .
C46 C41 C42 C43 57.9(6) . . . .
P2 C41 C42 C43 -178.4(4) . . . .
C33 C32 C31 C30 -51.0(7) . . . .
C80 C79 C84 F10 -177.8(5) . . . .
B1 C79 C84 F10 2.6(8) . . . .
C80 C79 C84 C83 0.5(8) . . . .
B1 C79 C84 C83 -179.1(5) . . . .
C36 C35 C40 C39 -50.7(6) . . . .
P2 C35 C40 C39 -177.3(4) . . . .
C38 C39 C40 C35 54.0(6) . . . .
C34 C29 C30 C31 -57.4(6) . . . .
P1 C29 C30 C31 173.5(4) . . . .
C32 C31 C30 C29 53.7(6) . . . .
F10 C84 C83 F9 -0.6(8) . . . .
C79 C84 C83 F9 -178.9(5) . . . .
F10 C84 C83 C82 178.0(5) . . . .
C79 C84 C83 C82 -0.4(9) . . . .
F8 C82 C83 F9 -1.5(8) . . . .
C81 C82 C83 F9 179.8(5) . . . .
F8 C82 C83 C84 179.9(5) . . . .
C81 C82 C83 C84 1.2(8) . . . .
C67 P4 C48 C47 95.0(4) . . . .
C61 P4 C48 C47 -156.0(3) . . . .
Pt2 P4 C48 C47 -32.0(4) . . . .
P4 C48 C47 P3 39.7(4) . . . .
C55 P3 C47 C48 -151.8(4) . . . .
C49 P3 C47 C48 93.1(4) . . . .
Pt2 P3 C47 C48 -28.7(4) . . . .
C78 C73 B1 C79 -104.0(6) . . . .
C74 C73 B1 C79 76.1(6) . . . .
C78 C73 B1 C85 23.2(8) . . . .
C74 C73 B1 C85 -156.8(5) . . . .
C80 C79 B1 C73 -131.1(5) . . . .
C84 C79 B1 C73 48.5(7) . . . .
C80 C79 B1 C85 102.0(6) . . . .
C84 C79 B1 C85 -78.4(6) . . . .
C86 C85 B1 C73 -130.5(6) . . . .
C90 C85 B1 C73 53.3(6) . . . .
C86 C85 B1 C79 -6.2(8) . . . .
C90 C85 B1 C79 177.6(5) . . . .
C55 C56 C57 C58 54.9(8) . . . .
C59 C58 C57 C56 -52.3(10) . . . .
C56 C55 C60 C59 60.4(6) . . . .
P3 C55 C60 C59 -174.3(4) . . . .
C57 C58 C59 C60 53.6(8) . . . .
C55 C60 C59 C58 -58.2(7) . . . .
C8 C1 C2 C3 130.9(5) . . . .
C14 C1 C2 C3 -124.5(5) . . . .
Ge1 C1 C2 C3 4.7(6) . . . .
C8 C1 C2 C7 -50.4(5) . . . .
C14 C1 C2 C7 54.2(5) . . . .
Ge1 C1 C2 C7 -176.6(3) . . . .
C12 C13 C20 C19 -117.7(5) . . . .
C8 C13 C20 C19 55.2(5) . . . .
C12 C13 C20 C7 130.4(5) . . . .
C8 C13 C20 C7 -56.8(5) . . . .
C18 C19 C20 C13 117.6(5) . . . .
C14 C19 C20 C13 -54.7(5) . . . .
C18 C19 C20 C7 -129.6(5) . . . .
C14 C19 C20 C7 58.1(5) . . . .
C3 C2 C7 C6 -0.6(7) . . . .
C1 C2 C7 C6 -179.5(4) . . . .
C3 C2 C7 C20 177.2(5) . . . .
C1 C2 C7 C20 -1.6(6) . . . .
C13 C20 C7 C2 55.8(5) . . . .
C19 C20 C7 C2 -54.7(5) . . . .
C13 C20 C7 C6 -126.5(5) . . . .
C19 C20 C7 C6 123.1(5) . . . .
C7 C2 C3 C4 -0.2(8) . . . .
C1 C2 C3 C4 178.5(5) . . . .
C86 C85 C90 F15 179.0(5) . . . .
B1 C85 C90 F15 -4.3(7) . . . .
C86 C85 C90 C89 0.9(8) . . . .
B1 C85 C90 C89 177.7(5) . . . .
C6 C5 C4 C3 -0.2(9) . . . .
C2 C3 C4 C5 0.6(9) . . . .
C62 C61 C66 C65 54.4(6) . . . .
P4 C61 C66 C65 -179.6(4) . . . .
C4 C5 C6 C7 -0.6(8) . . . .
C2 C7 C6 C5 1.1(8) . . . .
C20 C7 C6 C5 -176.5(5) . . . .
C61 C66 C65 C64 -56.3(6) . . . .
C66 C65 C64 C63 55.8(6) . . . .
C62 C63 C64 C65 -54.1(6) . . . .
C66 C61 C62 C63 -53.1(6) . . . .
P4 C61 C62 C63 179.3(4) . . . .
C64 C63 C62 C61 53.4(6) . . . .
C90 C85 C86 F11 -179.7(5) . . . .
B1 C85 C86 F11 3.8(9) . . . .
C90 C85 C86 C87 -0.1(8) . . . .
B1 C85 C86 C87 -176.6(5) . . . .
F13 C88 C89 F14 -0.3(8) . . . .
C87 C88 C89 F14 -179.9(5) . . . .
F13 C88 C89 C90 -178.9(5) . . . .
C87 C88 C89 C90 1.5(9) . . . .
F15 C90 C89 F14 1.7(7) . . . .
C85 C90 C89 F14 179.8(5) . . . .
F15 C90 C89 C88 -179.8(5) . . . .
C85 C90 C89 C88 -1.7(9) . . . .
F13 C88 C87 F12 -0.3(9) . . . .
C89 C88 C87 F12 179.3(5) . . . .
F13 C88 C87 C86 179.6(5) . . . .
C89 C88 C87 C86 -0.8(9) . . . .
F11 C86 C87 F12 -0.4(8) . . . .
C85 C86 C87 F12 180.0(5) . . . .
F11 C86 C87 C88 179.7(5) . . . .
C85 C86 C87 C88 0.1(10) . . . .
