#------------------------------------------------------------------------------
#$Date: 2018-09-27 07:13:35 +0300 (Thu, 27 Sep 2018) $
#$Revision: 211196 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/72/7117292.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7117292
loop_
_publ_author_name
'Norio Nakata'
'Noriko Sekizawa'
'Akihiko Ishii'
_publ_section_title
;
 Cationic dinuclear platinum and palladium complexes with bridging
 hydrogermylene and hydrido ligands
;
_journal_name_full               Chem.Commun.
_journal_page_first              10111
_journal_paper_doi               10.1039/C5cc03062E
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C72 H111 Ge P4 Pt2, C18 H B F15'
_chemical_formula_sum            'C90 H112 B F15 Ge P4 Pt2'
_chemical_formula_weight         2076.26
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-23 deposited with the CCDC.
2015-05-12 downloaded from the CCDC.
;
_cell_angle_alpha                92.5760(10)
_cell_angle_beta                 106.1520(10)
_cell_angle_gamma                97.3110(10)
_cell_formula_units_Z            2
_cell_length_a                   13.4434(13)
_cell_length_b                   18.1970(17)
_cell_length_c                   18.3865(17)
_cell_measurement_temperature    100(2)
_cell_volume                     4269.9(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX-II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Bruker Helios multilayered confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0510
_diffrn_reflns_av_sigmaI/netI    0.0660
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            21360
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    3.771
_exptl_absorpt_correction_T_max  0.8953
_exptl_absorpt_correction_T_min  0.7782
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.615
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2080
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.185
_refine_diff_density_min         -1.678
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1026
_refine_ls_number_reflns         15558
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0508
_refine_ls_R_factor_gt           0.0376
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0384P)²+0.0010P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0862
_refine_ls_wR_factor_ref         0.0896
_reflns_number_gt                11975
_reflns_number_total             15558
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc03062e2.cif
_cod_data_source_block           naka114
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3392 2015-05-12 13:50:21Z andrius 
;
_cod_database_code               7117292
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.198650(16) 0.326287(11) 0.243300(12) 0.02225(6) Uani 1 1 d D . .
Pt2 Pt 0.221998(15) 0.171758(11) 0.272985(12) 0.02170(6) Uani 1 1 d D . .
Ge1 Ge 0.33209(4) 0.25727(3) 0.21811(3) 0.02466(14) Uani 1 1 d . . .
H1 H 0.4382 0.2835 0.2763 0.030 Uiso 1 1 calc R . .
P2 P 0.12643(11) 0.11117(8) 0.34632(8) 0.0246(3) Uani 1 1 d . . .
P3 P 0.23940(11) 0.43582(8) 0.19751(9) 0.0257(3) Uani 1 1 d . . .
P1 P 0.28348(11) 0.06392(7) 0.25927(8) 0.0244(3) Uani 1 1 d . . .
P4 P 0.05644(11) 0.37262(7) 0.26553(8) 0.0239(3) Uani 1 1 d . . .
C67 C -0.0742(4) 0.3165(3) 0.2253(3) 0.0283(13) Uani 1 1 d . . .
H101 H -0.0755 0.2714 0.2543 0.034 Uiso 1 1 calc R . .
C75 C 0.6125(5) 0.2107(3) 0.7413(4) 0.0444(17) Uani 1 1 d . . .
F8 F 0.6764(4) 0.3323(3) 0.3572(2) 0.0733(13) Uani 1 1 d . . .
F14 F 1.1398(3) 0.4456(2) 0.7240(2) 0.0531(10) Uani 1 1 d . . .
C88 C 1.1866(5) 0.3264(4) 0.7502(4) 0.0442(17) Uani 1 1 d . . .
F15 F 0.9394(3) 0.38691(19) 0.6670(2) 0.0526(10) Uani 1 1 d . . .
F3 F 0.5949(3) 0.2431(2) 0.8625(3) 0.0652(12) Uani 1 1 d . . .
F9 F 0.6195(4) 0.3838(2) 0.4790(2) 0.0696(13) Uani 1 1 d . . .
C2 C 0.2453(4) 0.2116(3) 0.0549(3) 0.0306(13) Uani 1 1 d . . .
F6 F 0.8951(3) 0.1870(2) 0.5142(2) 0.0515(10) Uani 1 1 d . . .
F11 F 1.0302(3) 0.1473(2) 0.7203(2) 0.0535(10) Uani 1 1 d . . .
F12 F 1.2310(3) 0.2082(2) 0.7748(2) 0.0648(12) Uani 1 1 d . . .
C24 C 0.1604(4) 0.0177(3) 0.1107(3) 0.0358(14) Uani 1 1 d . . .
H21 H 0.1318 0.0649 0.1132 0.043 Uiso 1 1 calc R . .
H22 H 0.1165 -0.0212 0.1285 0.043 Uiso 1 1 calc R . .
F10 F 0.7027(3) 0.3438(2) 0.6161(2) 0.0550(10) Uani 1 1 d . . .
F5 F 0.9198(3) 0.2981(3) 0.8186(2) 0.0655(12) Uani 1 1 d . . .
F13 F 1.2873(3) 0.3572(3) 0.7797(2) 0.0665(12) Uani 1 1 d . . .
C39 C -0.1960(5) 0.0410(4) 0.3182(4) 0.0483(18) Uani 1 1 d . . .
H49 H -0.2241 0.0885 0.3094 0.058 Uiso 1 1 calc R . .
H50 H -0.2309 0.0140 0.3521 0.058 Uiso 1 1 calc R . .
C77 C 0.7585(5) 0.2694(4) 0.8390(4) 0.0458(17) Uani 1 1 d . . .
C55 C 0.3717(4) 0.4877(3) 0.2399(4) 0.0356(15) Uani 1 1 d . . .
H79 H 0.4169 0.4705 0.2095 0.043 Uiso 1 1 calc R . .
F1 F 0.6292(3) 0.1796(2) 0.6225(2) 0.0524(10) Uani 1 1 d . . .
C49 C 0.2183(4) 0.4281(3) 0.0933(3) 0.0307(13) Uani 1 1 d . . .
H68 H 0.2602 0.3892 0.0831 0.037 Uiso 1 1 calc R . .
C34 C 0.4661(4) 0.1250(3) 0.3758(4) 0.0363(15) Uani 1 1 d . . .
H40 H 0.4285 0.1213 0.4151 0.044 Uiso 1 1 calc R . .
H41 H 0.4551 0.1723 0.3523 0.044 Uiso 1 1 calc R . .
C74 C 0.6753(5) 0.2095(3) 0.6941(4) 0.0397(16) Uani 1 1 d . . .
C50 C 0.1028(5) 0.3968(4) 0.0529(4) 0.0464(17) Uani 1 1 d . . .
H69 H 0.0820 0.3512 0.0757 0.056 Uiso 1 1 calc R . .
H70 H 0.0573 0.4338 0.0593 0.056 Uiso 1 1 calc R . .
C61 C 0.0597(4) 0.4015(3) 0.3641(3) 0.0255(12) Uani 1 1 d . . .
H90 H -0.0044 0.4249 0.3617 0.031 Uiso 1 1 calc R . .
C63 C 0.1497(5) 0.4846(3) 0.4830(4) 0.0428(16) Uani 1 1 d . . .
H93 H 0.2120 0.5214 0.5083 0.051 Uiso 1 1 calc R . .
H94 H 0.0868 0.5092 0.4780 0.051 Uiso 1 1 calc R . .
C23 C 0.2725(4) 0.0268(3) 0.1618(3) 0.0255(12) Uani 1 1 d . . .
H20 H 0.3137 0.0652 0.1403 0.031 Uiso 1 1 calc R . .
C73 C 0.7823(5) 0.2378(3) 0.7155(3) 0.0377(15) Uani 1 1 d . . .
C28 C 0.3198(5) -0.0446(3) 0.1573(4) 0.0346(14) Uani 1 1 d . . .
H29 H 0.2807 -0.0850 0.1770 0.042 Uiso 1 1 calc R . .
H30 H 0.3935 -0.0370 0.1892 0.042 Uiso 1 1 calc R . .
C26 C 0.2046(5) -0.0749(3) 0.0245(4) 0.0430(16) Uani 1 1 d . . .
H25 H 0.1617 -0.1163 0.0399 0.052 Uiso 1 1 calc R . .
H26 H 0.2038 -0.0874 -0.0286 0.052 Uiso 1 1 calc R . .
C90 C 1.0096(5) 0.3390(4) 0.6921(3) 0.0393(15) Uani 1 1 d . . .
C66 C 0.0577(5) 0.3357(3) 0.4119(3) 0.0317(14) Uani 1 1 d . . .
H99 H 0.1212 0.3121 0.4159 0.038 Uiso 1 1 calc R . .
H100 H -0.0041 0.2984 0.3865 0.038 Uiso 1 1 calc R . .
C89 C 1.1124(5) 0.3716(4) 0.7219(4) 0.0433(16) Uani 1 1 d . . .
C76 C 0.6543(6) 0.2404(4) 0.8144(4) 0.0488(18) Uani 1 1 d . . .
C10 C 0.5575(4) 0.1035(3) 0.1545(4) 0.0364(15) Uani 1 1 d . . .
H8 H 0.6038 0.0845 0.1960 0.044 Uiso 1 1 calc R . .
F7 F 0.8149(3) 0.2328(2) 0.3772(2) 0.0603(11) Uani 1 1 d . . .
C81 C 0.7875(5) 0.2606(4) 0.4374(4) 0.0439(17) Uani 1 1 d . . .
C86 C 1.0530(5) 0.2220(4) 0.7189(4) 0.0410(16) Uani 1 1 d . . .
C9 C 0.4932(4) 0.1529(3) 0.1683(3) 0.0320(14) Uani 1 1 d . . .
H7 H 0.4974 0.1690 0.2191 0.038 Uiso 1 1 calc R . .
C8 C 0.4222(4) 0.1794(3) 0.1077(3) 0.0255(12) Uani 1 1 d . . .
C47 C 0.1515(4) 0.4991(3) 0.2159(3) 0.0285(13) Uani 1 1 d . . .
H64 H 0.1858 0.5283 0.2652 0.034 Uiso 1 1 calc R . .
H65 H 0.1405 0.5345 0.1760 0.034 Uiso 1 1 calc R . .
C62 C 0.1550(5) 0.4591(3) 0.4035(3) 0.0346(14) Uani 1 1 d . . .
H91 H 0.1566 0.5023 0.3729 0.042 Uiso 1 1 calc R . .
H92 H 0.2199 0.4370 0.4079 0.042 Uiso 1 1 calc R . .
C84 C 0.7330(5) 0.3127(3) 0.5583(4) 0.0415(16) Uani 1 1 d . . .
C65 C 0.0532(5) 0.3596(3) 0.4918(3) 0.0418(16) Uani 1 1 d . . .
H97 H -0.0136 0.3787 0.4883 0.050 Uiso 1 1 calc R . .
H98 H 0.0556 0.3160 0.5223 0.050 Uiso 1 1 calc R . .
C56 C 0.3807(5) 0.5730(3) 0.2375(4) 0.0413(16) Uani 1 1 d . . .
H80 H 0.3476 0.5852 0.1851 0.050 Uiso 1 1 calc R . .
H81 H 0.3431 0.5934 0.2713 0.050 Uiso 1 1 calc R . .
C37 C -0.1658(5) 0.0320(4) 0.1911(4) 0.0467(17) Uani 1 1 d . . .
H45 H -0.1923 0.0797 0.1789 0.056 Uiso 1 1 calc R . .
H46 H -0.1810 0.0003 0.1430 0.056 Uiso 1 1 calc R . .
C78 C 0.8183(5) 0.2673(4) 0.7894(4) 0.0402(16) Uani 1 1 d . . .
C1 C 0.3505(4) 0.2372(3) 0.1133(3) 0.0271(12) Uani 1 1 d . . .
C87 C 1.1554(5) 0.2517(4) 0.7476(4) 0.0454(17) Uani 1 1 d . . .
C80 C 0.8274(5) 0.2374(3) 0.5091(4) 0.0376(15) Uani 1 1 d . . .
C32 C 0.6035(5) 0.0526(4) 0.4468(4) 0.0440(17) Uani 1 1 d . . .
H36 H 0.6800 0.0527 0.4659 0.053 Uiso 1 1 calc R . .
H37 H 0.5742 0.0478 0.4905 0.053 Uiso 1 1 calc R . .
C41 C 0.1547(4) 0.1549(3) 0.4448(3) 0.0285(13) Uani 1 1 d . . .
H53 H 0.1062 0.1926 0.4430 0.034 Uiso 1 1 calc R . .
C60 C 0.4193(6) 0.4705(4) 0.3207(4) 0.067(3) Uani 1 1 d . . .
H88 H 0.4135 0.4160 0.3236 0.080 Uiso 1 1 calc R . .
H89 H 0.3813 0.4908 0.3542 0.080 Uiso 1 1 calc R . .
C85 C 0.9742(5) 0.2637(3) 0.6890(3) 0.0381(15) Uani 1 1 d . . .
C21 C 0.2015(4) -0.0095(3) 0.2917(3) 0.0280(13) Uani 1 1 d . . .
H16 H 0.1372 -0.0275 0.2499 0.034 Uiso 1 1 calc R . .
H17 H 0.2403 -0.0520 0.3051 0.034 Uiso 1 1 calc R . .
F4 F 0.8009(3) 0.3005(3) 0.9106(2) 0.0672(12) Uani 1 1 d . . .
C58 C 0.5459(6) 0.5892(4) 0.3420(5) 0.075(3) Uani 1 1 d . . .
H84 H 0.5131 0.6116 0.3778 0.090 Uiso 1 1 calc R . .
H85 H 0.6209 0.6106 0.3570 0.090 Uiso 1 1 calc R . .
C19 C 0.4077(4) 0.2838(3) 0.0046(3) 0.0318(14) Uani 1 1 d . . .
C82 C 0.7173(6) 0.3101(4) 0.4272(4) 0.0515(19) Uani 1 1 d . . .
C45 C 0.1639(5) 0.1473(4) 0.5829(3) 0.0435(16) Uani 1 1 d . . .
H60 H 0.1140 0.1835 0.5798 0.052 Uiso 1 1 calc R . .
H61 H 0.1547 0.1130 0.6215 0.052 Uiso 1 1 calc R . .
C42 C 0.2658(5) 0.1971(3) 0.4687(3) 0.0393(15) Uani 1 1 d . . .
H54 H 0.2732 0.2329 0.4309 0.047 Uiso 1 1 calc R . .
H55 H 0.3159 0.1615 0.4694 0.047 Uiso 1 1 calc R . .
C51 C 0.0891(6) 0.3788(4) -0.0316(4) 0.0549(19) Uani 1 1 d . . .
H71 H 0.1307 0.3390 -0.0379 0.066 Uiso 1 1 calc R . .
H72 H 0.0146 0.3602 -0.0577 0.066 Uiso 1 1 calc R . .
C29 C 0.4212(4) 0.0611(3) 0.3159(3) 0.0264(12) Uani 1 1 d . . .
H31 H 0.4639 0.0661 0.2792 0.032 Uiso 1 1 calc R . .
C22 C 0.1713(4) 0.0200(3) 0.3612(3) 0.0289(13) Uani 1 1 d . . .
H18 H 0.2326 0.0248 0.4068 0.035 Uiso 1 1 calc R . .
H19 H 0.1149 -0.0158 0.3702 0.035 Uiso 1 1 calc R . .
C52 C 0.1237(5) 0.4463(4) -0.0674(4) 0.0486(18) Uani 1 1 d . . .
H73 H 0.0793 0.4850 -0.0640 0.058 Uiso 1 1 calc R . .
H74 H 0.1152 0.4330 -0.1218 0.058 Uiso 1 1 calc R . .
C25 C 0.1571(5) -0.0040(4) 0.0288(4) 0.0453(17) Uani 1 1 d . . .
H23 H 0.0837 -0.0117 -0.0037 0.054 Uiso 1 1 calc R . .
H24 H 0.1966 0.0366 0.0097 0.054 Uiso 1 1 calc R . .
C14 C 0.4060(4) 0.3012(3) 0.0799(3) 0.0294(13) Uani 1 1 d . . .
C64 C 0.1451(6) 0.4200(4) 0.5312(4) 0.0488(18) Uani 1 1 d . . .
H95 H 0.1375 0.4378 0.5807 0.059 Uiso 1 1 calc R . .
H96 H 0.2114 0.3987 0.5409 0.059 Uiso 1 1 calc R . .
C33 C 0.5826(4) 0.1259(3) 0.4132(4) 0.0385(15) Uani 1 1 d . . .
H38 H 0.6212 0.1348 0.3751 0.046 Uiso 1 1 calc R . .
H39 H 0.6083 0.1670 0.4539 0.046 Uiso 1 1 calc R . .
C46 C 0.1397(5) 0.1030(3) 0.5054(3) 0.0414(16) Uani 1 1 d . . .
H62 H 0.1868 0.0648 0.5091 0.050 Uiso 1 1 calc R . .
H63 H 0.0667 0.0774 0.4906 0.050 Uiso 1 1 calc R . .
C27 C 0.3147(5) -0.0666(3) 0.0749(4) 0.0406(16) Uani 1 1 d . . .
H27 H 0.3591 -0.0281 0.0569 0.049 Uiso 1 1 calc R . .
H28 H 0.3426 -0.1141 0.0723 0.049 Uiso 1 1 calc R . .
C13 C 0.4239(4) 0.1598(3) 0.0333(3) 0.0326(14) Uani 1 1 d . . .
C38 C -0.2200(5) -0.0055(4) 0.2425(4) 0.0453(17) Uani 1 1 d . . .
H47 H -0.1972 -0.0548 0.2517 0.054 Uiso 1 1 calc R . .
H48 H -0.2965 -0.0135 0.2179 0.054 Uiso 1 1 calc R . .
C15 C 0.4612(4) 0.3675(3) 0.1184(4) 0.0367(15) Uani 1 1 d . . .
H11 H 0.4642 0.3788 0.1700 0.044 Uiso 1 1 calc R . .
C36 C -0.0467(4) 0.0471(4) 0.2286(3) 0.0390(15) Uani 1 1 d . . .
H43 H -0.0129 0.0747 0.1945 0.047 Uiso 1 1 calc R . .
H44 H -0.0194 -0.0009 0.2353 0.047 Uiso 1 1 calc R . .
C17 C 0.5080(5) 0.4022(4) 0.0057(4) 0.0427(17) Uani 1 1 d . . .
H13 H 0.5407 0.4378 -0.0199 0.051 Uiso 1 1 calc R . .
C30 C 0.4393(4) -0.0130(3) 0.3511(3) 0.0339(14) Uani 1 1 d . . .
H32 H 0.4003 -0.0201 0.3893 0.041 Uiso 1 1 calc R . .
H33 H 0.4124 -0.0546 0.3110 0.041 Uiso 1 1 calc R . .
C54 C 0.2531(6) 0.4960(4) 0.0574(4) 0.0521(19) Uani 1 1 d . . .
H77 H 0.3281 0.5140 0.0825 0.063 Uiso 1 1 calc R . .
H78 H 0.2125 0.5361 0.0643 0.063 Uiso 1 1 calc R . .
C79 C 0.8015(5) 0.2615(3) 0.5731(4) 0.0370(15) Uani 1 1 d . . .
C18 C 0.4567(5) 0.3359(4) -0.0322(4) 0.0418(16) Uani 1 1 d . . .
H14 H 0.4544 0.3253 -0.0837 0.050 Uiso 1 1 calc R . .
C12 C 0.4886(5) 0.1101(3) 0.0203(4) 0.0376(15) Uani 1 1 d . . .
H10 H 0.4874 0.0958 -0.0303 0.045 Uiso 1 1 calc R . .
C44 C 0.2733(5) 0.1879(4) 0.6067(4) 0.0486(18) Uani 1 1 d . . .
H58 H 0.3233 0.1515 0.6144 0.058 Uiso 1 1 calc R . .
H59 H 0.2856 0.2176 0.6556 0.058 Uiso 1 1 calc R . .
C59 C 0.5361(6) 0.5058(4) 0.3472(6) 0.101(4) Uani 1 1 d . . .
H86 H 0.5677 0.4952 0.4004 0.121 Uiso 1 1 calc R . .
H87 H 0.5745 0.4837 0.3150 0.121 Uiso 1 1 calc R . .
C53 C 0.2363(6) 0.4766(4) -0.0282(4) 0.056(2) Uani 1 1 d . . .
H75 H 0.2570 0.5217 -0.0517 0.067 Uiso 1 1 calc R . .
H76 H 0.2812 0.4392 -0.0348 0.067 Uiso 1 1 calc R . .
C83 C 0.6893(5) 0.3359(4) 0.4877(4) 0.0452(17) Uani 1 1 d . . .
C11 C 0.5548(5) 0.0812(3) 0.0806(4) 0.0385(15) Uani 1 1 d . . .
H9 H 0.5981 0.0466 0.0715 0.046 Uiso 1 1 calc R . .
C57 C 0.4943(5) 0.6081(4) 0.2627(5) 0.056(2) Uani 1 1 d . . .
H82 H 0.5311 0.5897 0.2273 0.067 Uiso 1 1 calc R . .
H83 H 0.4990 0.6628 0.2615 0.067 Uiso 1 1 calc R . .
C40 C -0.0784(5) 0.0570(4) 0.3567(4) 0.0447(16) Uani 1 1 d . . .
H51 H -0.0654 0.0902 0.4035 0.054 Uiso 1 1 calc R . .
H52 H -0.0525 0.0097 0.3718 0.054 Uiso 1 1 calc R . .
C48 C 0.0441(4) 0.4592(3) 0.2177(3) 0.0273(13) Uani 1 1 d . . .
H66 H -0.0019 0.4476 0.1650 0.033 Uiso 1 1 calc R . .
H67 H 0.0110 0.4928 0.2446 0.033 Uiso 1 1 calc R . .
C31 C 0.5555(5) -0.0136(4) 0.3889(4) 0.0455(17) Uani 1 1 d . . .
H34 H 0.5647 -0.0601 0.4145 0.055 Uiso 1 1 calc R . .
H35 H 0.5929 -0.0131 0.3495 0.055 Uiso 1 1 calc R . .
C16 C 0.5128(5) 0.4178(3) 0.0808(4) 0.0391(15) Uani 1 1 d . . .
H12 H 0.5515 0.4632 0.1073 0.047 Uiso 1 1 calc R . .
C43 C 0.2927(5) 0.2391(4) 0.5474(4) 0.0462(17) Uani 1 1 d . . .
H56 H 0.3671 0.2618 0.5628 0.055 Uiso 1 1 calc R . .
H57 H 0.2495 0.2796 0.5449 0.055 Uiso 1 1 calc R . .
C35 C -0.0171(4) 0.0926(3) 0.3070(3) 0.0294(13) Uani 1 1 d . . .
H42 H -0.0410 0.1420 0.2969 0.035 Uiso 1 1 calc R . .
B1 B 0.8515(6) 0.2279(4) 0.6545(4) 0.0389(18) Uani 1 1 d . . .
H112 H 0.855(3) 0.167(2) 0.642(2) 0.007(11) Uiso 1 1 d . . .
F2 F 0.5109(3) 0.1832(2) 0.7170(3) 0.0651(12) Uani 1 1 d . . .
C68 C -0.0894(4) 0.2890(3) 0.1416(3) 0.0343(14) Uani 1 1 d . . .
H102 H -0.0821 0.3324 0.1120 0.041 Uiso 1 1 calc R . .
H103 H -0.0340 0.2588 0.1391 0.041 Uiso 1 1 calc R . .
C72 C -0.1660(4) 0.3548(3) 0.2315(4) 0.0359(14) Uani 1 1 d . . .
H110 H -0.1643 0.4015 0.2059 0.043 Uiso 1 1 calc R . .
H111 H -0.1581 0.3682 0.2858 0.043 Uiso 1 1 calc R . .
C7 C 0.2506(5) 0.1928(3) -0.0181(3) 0.0353(14) Uani 1 1 d . . .
C3 C 0.1476(4) 0.2067(3) 0.0668(4) 0.0362(15) Uani 1 1 d . . .
H3 H 0.1421 0.2186 0.1163 0.043 Uiso 1 1 calc R . .
C69 C -0.1970(5) 0.2422(3) 0.1058(4) 0.0410(16) Uani 1 1 d . . .
H104 H -0.2059 0.2295 0.0513 0.049 Uiso 1 1 calc R . .
H105 H -0.2007 0.1952 0.1307 0.049 Uiso 1 1 calc R . .
C4 C 0.0576(5) 0.1847(4) 0.0074(4) 0.0449(17) Uani 1 1 d . . .
H4 H -0.0088 0.1827 0.0166 0.054 Uiso 1 1 calc R . .
C70 C -0.2843(5) 0.2834(3) 0.1140(3) 0.0389(15) Uani 1 1 d . . .
H106 H -0.3523 0.2510 0.0923 0.047 Uiso 1 1 calc R . .
H107 H -0.2847 0.3280 0.0850 0.047 Uiso 1 1 calc R . .
C6 C 0.1594(5) 0.1696(3) -0.0779(3) 0.0411(16) Uani 1 1 d . . .
H6 H 0.1638 0.1565 -0.1274 0.049 Uiso 1 1 calc R . .
C20 C 0.3610(5) 0.2039(3) -0.0247(3) 0.0376(15) Uani 1 1 d . . .
H15 H 0.3643 0.1910 -0.0773 0.045 Uiso 1 1 calc R . .
C5 C 0.0625(5) 0.1659(4) -0.0640(4) 0.0446(17) Uani 1 1 d . . .
H5 H 0.0001 0.1504 -0.1040 0.054 Uiso 1 1 calc R . .
C71 C -0.2716(5) 0.3070(4) 0.1965(4) 0.0455(17) Uani 1 1 d . . .
H108 H -0.2768 0.2624 0.2249 0.055 Uiso 1 1 calc R . .
H109 H -0.3284 0.3354 0.2001 0.055 Uiso 1 1 calc R . .
H2 H 0.147(3) 0.2437(11) 0.273(3) 0.06(2) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P3 Pt1 P4 87.80(5) . .
P3 Pt1 Ge1 100.55(4) . .
P4 Pt1 Ge1 170.64(4) . .
P3 Pt1 Pt2 153.84(4) . .
P4 Pt1 Pt2 118.02(3) . .
Ge1 Pt1 Pt2 53.389(14) . .
P3 Pt1 H2 171.0(12) . .
P4 Pt1 H2 84.7(4) . .
Ge1 Pt1 H2 86.6(4) . .
Pt2 Pt1 H2 33.3(4) . .
P1 Pt2 P2 87.13(5) . .
P1 Pt2 Ge1 101.53(4) . .
P2 Pt2 Ge1 167.51(4) . .
P1 Pt2 Pt1 153.90(4) . .
P2 Pt2 Pt1 118.88(4) . .
Ge1 Pt2 Pt1 53.247(15) . .
P1 Pt2 H2 167.0(15) . .
P2 Pt2 H2 86.8(7) . .
Ge1 Pt2 H2 86.4(4) . .
Pt1 Pt2 H2 33.2(4) . .
C1 Ge1 Pt1 124.15(15) . .
C1 Ge1 Pt2 123.38(15) . .
Pt1 Ge1 Pt2 73.364(19) . .
C1 Ge1 H1 110.4 . .
Pt1 Ge1 H1 110.4 . .
Pt2 Ge1 H1 110.4 . .
C22 P2 C35 106.5(3) . .
C22 P2 C41 103.2(3) . .
C35 P2 C41 106.9(3) . .
C22 P2 Pt2 106.55(18) . .
C35 P2 Pt2 117.78(18) . .
C41 P2 Pt2 114.61(17) . .
C47 P3 C55 104.3(3) . .
C47 P3 C49 106.3(3) . .
C55 P3 C49 106.5(3) . .
C47 P3 Pt1 107.79(18) . .
C55 P3 Pt1 117.86(18) . .
C49 P3 Pt1 113.19(18) . .
C23 P1 C21 102.5(3) . .
C23 P1 C29 106.1(3) . .
C21 P1 C29 106.3(2) . .
C23 P1 Pt2 117.58(17) . .
C21 P1 Pt2 107.43(18) . .
C29 P1 Pt2 115.64(18) . .
C48 P4 C61 103.3(3) . .
C48 P4 C67 103.4(2) . .
C61 P4 C67 104.1(3) . .
C48 P4 Pt1 106.95(19) . .
C61 P4 Pt1 119.46(17) . .
C67 P4 Pt1 117.64(19) . .
C72 C67 C68 110.0(5) . .
C72 C67 P4 115.1(4) . .
C68 C67 P4 110.2(4) . .
C72 C67 H101 107.0 . .
C68 C67 H101 107.0 . .
P4 C67 H101 107.0 . .
F2 C75 C76 119.2(7) . .
F2 C75 C74 121.3(6) . .
C76 C75 C74 119.5(6) . .
F13 C88 C87 122.1(6) . .
F13 C88 C89 119.2(7) . .
C87 C88 C89 118.8(6) . .
C3 C2 C7 118.2(5) . .
C3 C2 C1 127.0(5) . .
C7 C2 C1 114.8(5) . .
C23 C24 C25 110.1(5) . .
C23 C24 H21 109.6 . .
C25 C24 H21 109.6 . .
C23 C24 H22 109.6 . .
C25 C24 H22 109.6 . .
H21 C24 H22 108.1 . .
C40 C39 C38 111.1(5) . .
C40 C39 H49 109.4 . .
C38 C39 H49 109.4 . .
C40 C39 H50 109.4 . .
C38 C39 H50 109.4 . .
H49 C39 H50 108.0 . .
F4 C77 C76 120.0(7) . .
F4 C77 C78 120.7(6) . .
C76 C77 C78 119.3(7) . .
C60 C55 C56 108.6(5) . .
C60 C55 P3 112.6(4) . .
C56 C55 P3 115.4(4) . .
C60 C55 H79 106.6 . .
C56 C55 H79 106.6 . .
P3 C55 H79 106.6 . .
C54 C49 C50 110.7(5) . .
C54 C49 P3 117.9(4) . .
C50 C49 P3 109.6(4) . .
C54 C49 H68 105.9 . .
C50 C49 H68 105.9 . .
P3 C49 H68 105.9 . .
C29 C34 C33 111.9(5) . .
C29 C34 H40 109.2 . .
C33 C34 H40 109.2 . .
C29 C34 H41 109.2 . .
C33 C34 H41 109.2 . .
H40 C34 H41 107.9 . .
F1 C74 C75 116.6(6) . .
F1 C74 C73 119.0(6) . .
C75 C74 C73 124.4(6) . .
C51 C50 C49 109.6(5) . .
C51 C50 H69 109.8 . .
C49 C50 H69 109.8 . .
C51 C50 H70 109.8 . .
C49 C50 H70 109.8 . .
H69 C50 H70 108.2 . .
C66 C61 C62 109.2(4) . .
C66 C61 P4 111.9(4) . .
C62 C61 P4 112.2(4) . .
C66 C61 H90 107.8 . .
C62 C61 H90 107.8 . .
P4 C61 H90 107.8 . .
C64 C63 C62 111.4(5) . .
C64 C63 H93 109.3 . .
C62 C63 H93 109.3 . .
C64 C63 H94 109.3 . .
C62 C63 H94 109.3 . .
H93 C63 H94 108.0 . .
C24 C23 C28 110.8(5) . .
C24 C23 P1 112.0(4) . .
C28 C23 P1 114.5(4) . .
C24 C23 H20 106.3 . .
C28 C23 H20 106.3 . .
P1 C23 H20 106.3 . .
C78 C73 C74 112.7(6) . .
C78 C73 B1 127.5(6) . .
C74 C73 B1 119.6(6) . .
C23 C28 C27 110.0(5) . .
C23 C28 H29 109.7 . .
C27 C28 H29 109.7 . .
C23 C28 H30 109.7 . .
C27 C28 H30 109.7 . .
H29 C28 H30 108.2 . .
C27 C26 C25 111.4(5) . .
C27 C26 H25 109.3 . .
C25 C26 H25 109.3 . .
C27 C26 H26 109.3 . .
C25 C26 H26 109.3 . .
H25 C26 H26 108.0 . .
F15 C90 C89 115.5(6) . .
F15 C90 C85 119.5(6) . .
C89 C90 C85 124.9(6) . .
C61 C66 C65 111.5(5) . .
C61 C66 H99 109.3 . .
C65 C66 H99 109.3 . .
C61 C66 H100 109.3 . .
C65 C66 H100 109.3 . .
H99 C66 H100 108.0 . .
F14 C89 C88 120.7(6) . .
F14 C89 C90 121.0(6) . .
C88 C89 C90 118.3(6) . .
F3 C76 C75 121.3(7) . .
F3 C76 C77 119.6(7) . .
C75 C76 C77 119.1(7) . .
C9 C10 C11 120.6(6) . .
C9 C10 H8 119.7 . .
C11 C10 H8 119.7 . .
F7 C81 C82 120.2(6) . .
F7 C81 C80 120.5(6) . .
C82 C81 C80 119.3(7) . .
F11 C86 C87 116.3(6) . .
F11 C86 C85 120.3(6) . .
C87 C86 C85 123.4(6) . .
C10 C9 C8 120.3(6) . .
C10 C9 H7 119.9 . .
C8 C9 H7 119.9 . .
C9 C8 C13 118.6(5) . .
C9 C8 C1 126.6(5) . .
C13 C8 C1 114.2(5) . .
C48 C47 P3 113.7(4) . .
C48 C47 H64 108.8 . .
P3 C47 H64 108.8 . .
C48 C47 H65 108.8 . .
P3 C47 H65 108.8 . .
H64 C47 H65 107.7 . .
C61 C62 C63 109.8(5) . .
C61 C62 H91 109.7 . .
C63 C62 H91 109.7 . .
C61 C62 H92 109.7 . .
C63 C62 H92 109.7 . .
H91 C62 H92 108.2 . .
F10 C84 C79 119.7(6) . .
F10 C84 C83 115.2(6) . .
C79 C84 C83 125.1(6) . .
C64 C65 C66 110.6(5) . .
C64 C65 H97 109.5 . .
C66 C65 H97 109.5 . .
C64 C65 H98 109.5 . .
C66 C65 H98 109.5 . .
H97 C65 H98 108.1 . .
C57 C56 C55 110.4(5) . .
C57 C56 H80 109.6 . .
C55 C56 H80 109.6 . .
C57 C56 H81 109.6 . .
C55 C56 H81 109.6 . .
H80 C56 H81 108.1 . .
C38 C37 C36 110.8(5) . .
C38 C37 H45 109.5 . .
C36 C37 H45 109.5 . .
C38 C37 H46 109.5 . .
C36 C37 H46 109.5 . .
H45 C37 H46 108.1 . .
F5 C78 C73 120.1(6) . .
F5 C78 C77 115.0(6) . .
C73 C78 C77 125.0(6) . .
C2 C1 C8 107.5(4) . .
C2 C1 C14 106.3(4) . .
C8 C1 C14 97.8(4) . .
C2 C1 Ge1 110.8(4) . .
C8 C1 Ge1 115.2(4) . .
C14 C1 Ge1 118.0(4) . .
C86 C87 C88 121.1(6) . .
C86 C87 F12 121.5(6) . .
C88 C87 F12 117.4(6) . .
F6 C80 C81 115.8(6) . .
F6 C80 C79 120.0(6) . .
C81 C80 C79 124.2(6) . .
C31 C32 C33 112.0(5) . .
C31 C32 H36 109.2 . .
C33 C32 H36 109.2 . .
C31 C32 H37 109.2 . .
C33 C32 H37 109.2 . .
H36 C32 H37 107.9 . .
C42 C41 C46 109.9(5) . .
C42 C41 P2 108.6(4) . .
C46 C41 P2 116.6(4) . .
C42 C41 H53 107.1 . .
C46 C41 H53 107.1 . .
P2 C41 H53 107.1 . .
C55 C60 C59 109.1(7) . .
C55 C60 H88 109.9 . .
C59 C60 H88 109.9 . .
C55 C60 H89 109.9 . .
C59 C60 H89 109.9 . .
H88 C60 H89 108.3 . .
C86 C85 C90 113.5(6) . .
C86 C85 B1 123.3(6) . .
C90 C85 B1 123.2(5) . .
C22 C21 P1 111.0(4) . .
C22 C21 H16 109.4 . .
P1 C21 H16 109.4 . .
C22 C21 H17 109.4 . .
P1 C21 H17 109.4 . .
H16 C21 H17 108.0 . .
C57 C58 C59 111.4(7) . .
C57 C58 H84 109.3 . .
C59 C58 H84 109.3 . .
C57 C58 H85 109.3 . .
C59 C58 H85 109.3 . .
H84 C58 H85 108.0 . .
C18 C19 C14 120.0(6) . .
C18 C19 C20 127.0(6) . .
C14 C19 C20 112.9(5) . .
C83 C82 F8 120.9(7) . .
C83 C82 C81 119.2(6) . .
F8 C82 C81 119.9(7) . .
C44 C45 C46 111.2(5) . .
C44 C45 H60 109.4 . .
C46 C45 H60 109.4 . .
C44 C45 H61 109.4 . .
C46 C45 H61 109.4 . .
H60 C45 H61 108.0 . .
C41 C42 C43 111.8(5) . .
C41 C42 H54 109.2 . .
C43 C42 H54 109.2 . .
C41 C42 H55 109.2 . .
C43 C42 H55 109.2 . .
H54 C42 H55 107.9 . .
C52 C51 C50 111.1(6) . .
C52 C51 H71 109.4 . .
C50 C51 H71 109.4 . .
C52 C51 H72 109.4 . .
C50 C51 H72 109.4 . .
H71 C51 H72 108.0 . .
C34 C29 C30 110.0(5) . .
C34 C29 P1 114.0(4) . .
C30 C29 P1 114.1(4) . .
C34 C29 H31 106.0 . .
C30 C29 H31 106.0 . .
P1 C29 H31 106.0 . .
C21 C22 P2 110.8(4) . .
C21 C22 H18 109.5 . .
P2 C22 H18 109.5 . .
C21 C22 H19 109.5 . .
P2 C22 H19 109.5 . .
H18 C22 H19 108.1 . .
C51 C52 C53 110.7(5) . .
C51 C52 H73 109.5 . .
C53 C52 H73 109.5 . .
C51 C52 H74 109.5 . .
C53 C52 H74 109.5 . .
H73 C52 H74 108.1 . .
C26 C25 C24 110.3(5) . .
C26 C25 H23 109.6 . .
C24 C25 H23 109.6 . .
C26 C25 H24 109.6 . .
C24 C25 H24 109.6 . .
H23 C25 H24 108.1 . .
C15 C14 C19 119.2(5) . .
C15 C14 C1 126.6(5) . .
C19 C14 C1 113.7(5) . .
C63 C64 C65 111.1(5) . .
C63 C64 H95 109.4 . .
C65 C64 H95 109.4 . .
C63 C64 H96 109.4 . .
C65 C64 H96 109.4 . .
H95 C64 H96 108.0 . .
C32 C33 C34 110.9(5) . .
C32 C33 H38 109.5 . .
C34 C33 H38 109.5 . .
C32 C33 H39 109.5 . .
C34 C33 H39 109.5 . .
H38 C33 H39 108.0 . .
C41 C46 C45 110.4(5) . .
C41 C46 H62 109.6 . .
C45 C46 H62 109.6 . .
C41 C46 H63 109.6 . .
C45 C46 H63 109.6 . .
H62 C46 H63 108.1 . .
C26 C27 C28 111.0(5) . .
C26 C27 H27 109.4 . .
C28 C27 H27 109.4 . .
C26 C27 H28 109.4 . .
C28 C27 H28 109.4 . .
H27 C27 H28 108.0 . .
C12 C13 C8 120.3(5) . .
C12 C13 C20 126.0(6) . .
C8 C13 C20 113.3(5) . .
C37 C38 C39 111.0(5) . .
C37 C38 H47 109.4 . .
C39 C38 H47 109.4 . .
C37 C38 H48 109.4 . .
C39 C38 H48 109.4 . .
H47 C38 H48 108.0 . .
C14 C15 C16 119.4(6) . .
C14 C15 H11 120.3 . .
C16 C15 H11 120.3 . .
C37 C36 C35 112.5(5) . .
C37 C36 H43 109.1 . .
C35 C36 H43 109.1 . .
C37 C36 H44 109.1 . .
C35 C36 H44 109.1 . .
H43 C36 H44 107.8 . .
C18 C17 C16 120.4(6) . .
C18 C17 H13 119.8 . .
C16 C17 H13 119.8 . .
C31 C30 C29 110.7(5) . .
C31 C30 H32 109.5 . .
C29 C30 H32 109.5 . .
C31 C30 H33 109.5 . .
C29 C30 H33 109.5 . .
H32 C30 H33 108.1 . .
C49 C54 C53 109.9(6) . .
C49 C54 H77 109.7 . .
C53 C54 H77 109.7 . .
C49 C54 H78 109.7 . .
C53 C54 H78 109.7 . .
H77 C54 H78 108.2 . .
C84 C79 C80 112.6(6) . .
C84 C79 B1 127.9(6) . .
C80 C79 B1 119.6(6) . .
C17 C18 C19 120.1(6) . .
C17 C18 H14 119.9 . .
C19 C18 H14 119.9 . .
C11 C12 C13 120.4(6) . .
C11 C12 H10 119.8 . .
C13 C12 H10 119.8 . .
C45 C44 C43 111.3(5) . .
C45 C44 H58 109.4 . .
C43 C44 H58 109.4 . .
C45 C44 H59 109.4 . .
C43 C44 H59 109.4 . .
H58 C44 H59 108.0 . .
C58 C59 C60 110.3(6) . .
C58 C59 H86 109.6 . .
C60 C59 H86 109.6 . .
C58 C59 H87 109.6 . .
C60 C59 H87 109.6 . .
H86 C59 H87 108.1 . .
C52 C53 C54 111.0(6) . .
C52 C53 H75 109.4 . .
C54 C53 H75 109.4 . .
C52 C53 H76 109.4 . .
C54 C53 H76 109.4 . .
H75 C53 H76 108.0 . .
F9 C83 C82 120.3(6) . .
F9 C83 C84 120.2(6) . .
C82 C83 C84 119.5(7) . .
C12 C11 C10 119.5(6) . .
C12 C11 H9 120.3 . .
C10 C11 H9 120.3 . .
C58 C57 C56 110.1(6) . .
C58 C57 H82 109.6 . .
C56 C57 H82 109.6 . .
C58 C57 H83 109.6 . .
C56 C57 H83 109.6 . .
H82 C57 H83 108.2 . .
C35 C40 C39 113.4(5) . .
C35 C40 H51 108.9 . .
C39 C40 H51 108.9 . .
C35 C40 H52 108.9 . .
C39 C40 H52 108.9 . .
H51 C40 H52 107.7 . .
C47 C48 P4 111.5(3) . .
C47 C48 H66 109.3 . .
P4 C48 H66 109.3 . .
C47 C48 H67 109.3 . .
P4 C48 H67 109.3 . .
H66 C48 H67 108.0 . .
C32 C31 C30 112.0(5) . .
C32 C31 H34 109.2 . .
C30 C31 H34 109.2 . .
C32 C31 H35 109.2 . .
C30 C31 H35 109.2 . .
H34 C31 H35 107.9 . .
C17 C16 C15 120.6(6) . .
C17 C16 H12 119.7 . .
C15 C16 H12 119.7 . .
C44 C43 C42 111.6(5) . .
C44 C43 H56 109.3 . .
C42 C43 H56 109.3 . .
C44 C43 H57 109.3 . .
C42 C43 H57 109.3 . .
H56 C43 H57 108.0 . .
C40 C35 C36 110.3(5) . .
C40 C35 P2 117.2(4) . .
C36 C35 P2 109.8(4) . .
C40 C35 H42 106.3 . .
C36 C35 H42 106.3 . .
P2 C35 H42 106.3 . .
C85 B1 C79 109.7(5) . .
C85 B1 C73 113.0(5) . .
C79 B1 C73 112.7(5) . .
C85 B1 H112 103(2) . .
C79 B1 H112 107(2) . .
C73 B1 H112 110(2) . .
C69 C68 C67 112.0(5) . .
C69 C68 H102 109.2 . .
C67 C68 H102 109.2 . .
C69 C68 H103 109.2 . .
C67 C68 H103 109.2 . .
H102 C68 H103 107.9 . .
C67 C72 C71 113.1(5) . .
C67 C72 H110 109.0 . .
C71 C72 H110 109.0 . .
C67 C72 H111 109.0 . .
C71 C72 H111 109.0 . .
H110 C72 H111 107.8 . .
C2 C7 C6 121.0(6) . .
C2 C7 C20 113.2(5) . .
C6 C7 C20 125.8(6) . .
C2 C3 C4 120.7(6) . .
C2 C3 H3 119.7 . .
C4 C3 H3 119.7 . .
C70 C69 C68 111.4(5) . .
C70 C69 H104 109.4 . .
C68 C69 H104 109.4 . .
C70 C69 H105 109.4 . .
C68 C69 H105 109.4 . .
H104 C69 H105 108.0 . .
C5 C4 C3 121.3(6) . .
C5 C4 H4 119.4 . .
C3 C4 H4 119.4 . .
C69 C70 C71 111.3(5) . .
C69 C70 H106 109.4 . .
C71 C70 H106 109.4 . .
C69 C70 H107 109.4 . .
C71 C70 H107 109.4 . .
H106 C70 H107 108.0 . .
C5 C6 C7 119.3(6) . .
C5 C6 H6 120.4 . .
C7 C6 H6 120.4 . .
C13 C20 C7 107.2(5) . .
C13 C20 C19 103.1(5) . .
C7 C20 C19 107.0(5) . .
C13 C20 H15 113.0 . .
C7 C20 H15 113.0 . .
C19 C20 H15 113.0 . .
C4 C5 C6 119.6(6) . .
C4 C5 H5 120.2 . .
C6 C5 H5 120.2 . .
C70 C71 C72 110.1(6) . .
C70 C71 H108 109.6 . .
C72 C71 H108 109.6 . .
C70 C71 H109 109.6 . .
C72 C71 H109 109.6 . .
H108 C71 H109 108.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P3 2.2607(14) .
Pt1 P4 2.3123(15) .
Pt1 Ge1 2.4481(6) .
Pt1 Pt2 2.9276(4) .
Pt1 H2 1.749(10) .
Pt2 P1 2.2543(14) .
Pt2 P2 2.3284(14) .
Pt2 Ge1 2.4527(6) .
Pt2 H2 1.754(10) .
Ge1 C1 2.033(6) .
Ge1 H1 1.5300 .
P2 C22 1.842(5) .
P2 C35 1.843(5) .
P2 C41 1.862(6) .
P3 C47 1.836(6) .
P3 C55 1.844(6) .
P3 C49 1.853(6) .
P1 C23 1.847(6) .
P1 C21 1.849(5) .
P1 C29 1.863(5) .
P4 C48 1.843(5) .
P4 C61 1.851(6) .
P4 C67 1.852(5) .
C67 C72 1.521(8) .
C67 C68 1.545(8) .
C67 H101 1.0000 .
C75 F2 1.335(7) .
C75 C76 1.361(10) .
C75 C74 1.369(9) .
F8 C82 1.353(7) .
F14 C89 1.347(7) .
C88 F13 1.345(7) .
C88 C87 1.366(9) .
C88 C89 1.378(9) .
F15 C90 1.367(7) .
F3 C76 1.349(8) .
F9 C83 1.344(7) .
C2 C3 1.383(8) .
C2 C7 1.394(8) .
C2 C1 1.521(7) .
F6 C80 1.361(7) .
F11 C86 1.358(7) .
F12 C87 1.367(7) .
C24 C23 1.522(7) .
C24 C25 1.526(9) .
C24 H21 0.9900 .
C24 H22 0.9900 .
F10 C84 1.365(7) .
F5 C78 1.354(7) .
C39 C40 1.525(8) .
C39 C38 1.527(9) .
C39 H49 0.9900 .
C39 H50 0.9900 .
C77 F4 1.347(7) .
C77 C76 1.373(9) .
C77 C78 1.375(9) .
C55 C60 1.509(9) .
C55 C56 1.545(8) .
C55 H79 1.0000 .
F1 C74 1.344(7) .
C49 C54 1.510(8) .
C49 C50 1.543(8) .
C49 H68 1.0000 .
C34 C29 1.505(8) .
C34 C33 1.523(8) .
C34 H40 0.9900 .
C34 H41 0.9900 .
C74 C73 1.403(9) .
C50 C51 1.528(9) .
C50 H69 0.9900 .
C50 H70 0.9900 .
C61 C66 1.519(7) .
C61 C62 1.529(7) .
C61 H90 1.0000 .
C63 C64 1.509(8) .
C63 C62 1.537(8) .
C63 H93 0.9900 .
C63 H94 0.9900 .
C23 C28 1.525(7) .
C23 H20 1.0000 .
C73 C78 1.368(9) .
C73 B1 1.662(10) .
C28 C27 1.529(8) .
C28 H29 0.9900 .
C28 H30 0.9900 .
C26 C27 1.497(8) .
C26 C25 1.518(9) .
C26 H25 0.9900 .
C26 H26 0.9900 .
C90 C89 1.380(9) .
C90 C85 1.385(9) .
C66 C65 1.533(8) .
C66 H99 0.9900 .
C66 H100 0.9900 .
C10 C9 1.385(8) .
C10 C11 1.390(9) .
C10 H8 0.9500 .
F7 C81 1.355(8) .
C81 C82 1.368(10) .
C81 C80 1.385(9) .
C86 C87 1.359(9) .
C86 C85 1.384(9) .
C9 C8 1.399(7) .
C9 H7 0.9500 .
C8 C13 1.404(8) .
C8 C1 1.534(8) .
C47 C48 1.541(7) .
C47 H64 0.9900 .
C47 H65 0.9900 .
C62 H91 0.9900 .
C62 H92 0.9900 .
C84 C79 1.375(9) .
C84 C83 1.377(9) .
C65 C64 1.531(9) .
C65 H97 0.9900 .
C65 H98 0.9900 .
C56 C57 1.513(8) .
C56 H80 0.9900 .
C56 H81 0.9900 .
C37 C38 1.486(9) .
C37 C36 1.539(8) .
C37 H45 0.9900 .
C37 H46 0.9900 .
C1 C14 1.546(7) .
C80 C79 1.386(9) .
C32 C31 1.519(9) .
C32 C33 1.520(8) .
C32 H36 0.9900 .
C32 H37 0.9900 .
C41 C42 1.525(8) .
C41 C46 1.530(8) .
C41 H53 1.0000 .
C60 C59 1.551(10) .
C60 H88 0.9900 .
C60 H89 0.9900 .
C85 B1 1.629(10) .
C21 C22 1.539(8) .
C21 H16 0.9900 .
C21 H17 0.9900 .
C58 C57 1.507(10) .
C58 C59 1.516(9) .
C58 H84 0.9900 .
C58 H85 0.9900 .
C19 C18 1.391(8) .
C19 C14 1.413(8) .
C19 C20 1.520(8) .
C82 C83 1.351(10) .
C45 C44 1.495(9) .
C45 C46 1.536(8) .
C45 H60 0.9900 .
C45 H61 0.9900 .
C42 C43 1.533(8) .
C42 H54 0.9900 .
C42 H55 0.9900 .
C51 C52 1.502(9) .
C51 H71 0.9900 .
C51 H72 0.9900 .
C29 C30 1.539(7) .
C29 H31 1.0000 .
C22 H18 0.9900 .
C22 H19 0.9900 .
C52 C53 1.502(9) .
C52 H73 0.9900 .
C52 H74 0.9900 .
C25 H23 0.9900 .
C25 H24 0.9900 .
C14 C15 1.382(8) .
C64 H95 0.9900 .
C64 H96 0.9900 .
C33 H38 0.9900 .
C33 H39 0.9900 .
C46 H62 0.9900 .
C46 H63 0.9900 .
C27 H27 0.9900 .
C27 H28 0.9900 .
C13 C12 1.388(8) .
C13 C20 1.499(8) .
C38 H47 0.9900 .
C38 H48 0.9900 .
C15 C16 1.398(8) .
C15 H11 0.9500 .
C36 C35 1.552(8) .
C36 H43 0.9900 .
C36 H44 0.9900 .
C17 C18 1.364(9) .
C17 C16 1.381(9) .
C17 H13 0.9500 .
C30 C31 1.525(8) .
C30 H32 0.9900 .
C30 H33 0.9900 .
C54 C53 1.544(9) .
C54 H77 0.9900 .
C54 H78 0.9900 .
C79 B1 1.641(9) .
C18 H14 0.9500 .
C12 C11 1.387(8) .
C12 H10 0.9500 .
C44 C43 1.520(9) .
C44 H58 0.9900 .
C44 H59 0.9900 .
C59 H86 0.9900 .
C59 H87 0.9900 .
C53 H75 0.9900 .
C53 H76 0.9900 .
C11 H9 0.9500 .
C57 H82 0.9900 .
C57 H83 0.9900 .
C40 C35 1.506(8) .
C40 H51 0.9900 .
C40 H52 0.9900 .
C48 H66 0.9900 .
C48 H67 0.9900 .
C31 H34 0.9900 .
C31 H35 0.9900 .
C16 H12 0.9500 .
C43 H56 0.9900 .
C43 H57 0.9900 .
C35 H42 1.0000 .
B1 H112 1.13(4) .
C68 C69 1.535(8) .
C68 H102 0.9900 .
C68 H103 0.9900 .
C72 C71 1.521(8) .
C72 H110 0.9900 .
C72 H111 0.9900 .
C7 C6 1.403(8) .
C7 C20 1.511(8) .
C3 C4 1.385(8) .
C3 H3 0.9500 .
C69 C70 1.508(9) .
C69 H104 0.9900 .
C69 H105 0.9900 .
C4 C5 1.364(9) .
C4 H4 0.9500 .
C70 C71 1.515(9) .
C70 H106 0.9900 .
C70 H107 0.9900 .
C6 C5 1.389(9) .
C6 H6 0.9500 .
C20 H15 1.0000 .
C5 H5 0.9500 .
C71 H108 0.9900 .
C71 H109 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
P3 Pt1 Pt2 P1 -11.24(12) . . . .
P4 Pt1 Pt2 P1 158.79(9) . . . .
Ge1 Pt1 Pt2 P1 -16.79(9) . . . .
P3 Pt1 Pt2 P2 173.99(9) . . . .
P4 Pt1 Pt2 P2 -15.98(6) . . . .
Ge1 Pt1 Pt2 P2 168.44(4) . . . .
P3 Pt1 Pt2 Ge1 5.55(9) . . . .
P4 Pt1 Pt2 Ge1 175.59(4) . . . .
P3 Pt1 Ge1 C1 -58.09(19) . . . .
P4 Pt1 Ge1 C1 94.7(3) . . . .
Pt2 Pt1 Ge1 C1 119.42(18) . . . .
P3 Pt1 Ge1 Pt2 -177.51(4) . . . .
P4 Pt1 Ge1 Pt2 -24.7(2) . . . .
P1 Pt2 Ge1 C1 52.23(19) . . . .
P2 Pt2 Ge1 C1 -174.6(2) . . . .
Pt1 Pt2 Ge1 C1 -120.32(18) . . . .
P1 Pt2 Ge1 Pt1 172.55(4) . . . .
P2 Pt2 Ge1 Pt1 -54.25(17) . . . .
P1 Pt2 P2 C22 8.2(2) . . . .
Ge1 Pt2 P2 C22 -126.1(2) . . . .
Pt1 Pt2 P2 C22 -174.10(19) . . . .
P1 Pt2 P2 C35 -111.2(2) . . . .
Ge1 Pt2 P2 C35 114.4(3) . . . .
Pt1 Pt2 P2 C35 66.5(2) . . . .
P1 Pt2 P2 C41 121.7(2) . . . .
Ge1 Pt2 P2 C41 -12.7(3) . . . .
Pt1 Pt2 P2 C41 -60.6(2) . . . .
P4 Pt1 P3 C47 7.39(19) . . . .
Ge1 Pt1 P3 C47 -176.88(19) . . . .
Pt2 Pt1 P3 C47 178.59(18) . . . .
P4 Pt1 P3 C55 125.0(3) . . . .
Ge1 Pt1 P3 C55 -59.3(3) . . . .
Pt2 Pt1 P3 C55 -63.8(3) . . . .
P4 Pt1 P3 C49 -109.9(2) . . . .
Ge1 Pt1 P3 C49 65.8(2) . . . .
Pt2 Pt1 P3 C49 61.3(2) . . . .
P2 Pt2 P1 C23 128.1(2) . . . .
Ge1 Pt2 P1 C23 -61.01(19) . . . .
Pt1 Pt2 P1 C23 -47.3(2) . . . .
P2 Pt2 P1 C21 13.3(2) . . . .
Ge1 Pt2 P1 C21 -175.8(2) . . . .
Pt1 Pt2 P1 C21 -162.15(19) . . . .
P2 Pt2 P1 C29 -105.3(2) . . . .
Ge1 Pt2 P1 C29 65.7(2) . . . .
Pt1 Pt2 P1 C29 79.3(2) . . . .
P3 Pt1 P4 C48 10.9(2) . . . .
Ge1 Pt1 P4 C48 -142.4(3) . . . .
Pt2 Pt1 P4 C48 -164.75(19) . . . .
P3 Pt1 P4 C61 -105.7(2) . . . .
Ge1 Pt1 P4 C61 100.9(3) . . . .
Pt2 Pt1 P4 C61 78.6(2) . . . .
P3 Pt1 P4 C67 126.5(2) . . . .
Ge1 Pt1 P4 C67 -26.8(3) . . . .
Pt2 Pt1 P4 C67 -49.1(2) . . . .
C48 P4 C67 C72 -53.6(5) . . . .
C61 P4 C67 C72 54.0(5) . . . .
Pt1 P4 C67 C72 -171.2(3) . . . .
C48 P4 C67 C68 71.5(4) . . . .
C61 P4 C67 C68 179.1(4) . . . .
Pt1 P4 C67 C68 -46.1(4) . . . .
C47 P3 C55 C60 93.2(5) . . . .
C49 P3 C55 C60 -154.6(5) . . . .
Pt1 P3 C55 C60 -26.3(6) . . . .
C47 P3 C55 C56 -32.2(6) . . . .
C49 P3 C55 C56 80.0(5) . . . .
Pt1 P3 C55 C56 -151.7(4) . . . .
C47 P3 C49 C54 68.0(5) . . . .
C55 P3 C49 C54 -42.8(5) . . . .
Pt1 P3 C49 C54 -173.9(4) . . . .
C47 P3 C49 C50 -59.9(5) . . . .
C55 P3 C49 C50 -170.7(4) . . . .
Pt1 P3 C49 C50 58.2(4) . . . .
F2 C75 C74 F1 0.2(9) . . . .
C76 C75 C74 F1 -179.8(5) . . . .
F2 C75 C74 C73 179.5(5) . . . .
C76 C75 C74 C73 -0.4(10) . . . .
C54 C49 C50 C51 57.1(7) . . . .
P3 C49 C50 C51 -171.1(5) . . . .
C48 P4 C61 C66 173.7(4) . . . .
C67 P4 C61 C66 66.0(4) . . . .
Pt1 P4 C61 C66 -67.8(4) . . . .
C48 P4 C61 C62 -63.1(4) . . . .
C67 P4 C61 C62 -170.9(4) . . . .
Pt1 P4 C61 C62 55.4(4) . . . .
C25 C24 C23 C28 -57.6(6) . . . .
C25 C24 C23 P1 173.1(4) . . . .
C21 P1 C23 C24 62.4(4) . . . .
C29 P1 C23 C24 173.7(4) . . . .
Pt2 P1 C23 C24 -55.1(4) . . . .
C21 P1 C23 C28 -64.9(4) . . . .
C29 P1 C23 C28 46.4(4) . . . .
Pt2 P1 C23 C28 177.6(3) . . . .
F1 C74 C73 C78 179.1(5) . . . .
C75 C74 C73 C78 -0.2(9) . . . .
F1 C74 C73 B1 -4.7(8) . . . .
C75 C74 C73 B1 175.9(6) . . . .
C24 C23 C28 C27 57.0(6) . . . .
P1 C23 C28 C27 -175.2(4) . . . .
C62 C61 C66 C65 58.9(6) . . . .
P4 C61 C66 C65 -176.3(4) . . . .
F13 C88 C89 F14 -0.4(9) . . . .
C87 C88 C89 F14 179.4(6) . . . .
F13 C88 C89 C90 -179.8(6) . . . .
C87 C88 C89 C90 0.1(10) . . . .
F15 C90 C89 F14 -1.2(9) . . . .
C85 C90 C89 F14 -178.7(6) . . . .
F15 C90 C89 C88 178.1(6) . . . .
C85 C90 C89 C88 0.7(10) . . . .
F2 C75 C76 F3 -0.5(10) . . . .
C74 C75 C76 F3 179.5(6) . . . .
F2 C75 C76 C77 -179.2(5) . . . .
C74 C75 C76 C77 0.7(10) . . . .
F4 C77 C76 F3 -0.1(9) . . . .
C78 C77 C76 F3 -179.2(6) . . . .
F4 C77 C76 C75 178.7(6) . . . .
C78 C77 C76 C75 -0.4(10) . . . .
C11 C10 C9 C8 2.1(8) . . . .
C10 C9 C8 C13 -5.4(8) . . . .
C10 C9 C8 C1 -176.4(5) . . . .
C55 P3 C47 C48 -155.2(4) . . . .
C49 P3 C47 C48 92.5(4) . . . .
Pt1 P3 C47 C48 -29.2(4) . . . .
C66 C61 C62 C63 -59.0(6) . . . .
P4 C61 C62 C63 176.4(4) . . . .
C64 C63 C62 C61 58.3(7) . . . .
C61 C66 C65 C64 -56.4(7) . . . .
C60 C55 C56 C57 61.2(8) . . . .
P3 C55 C56 C57 -171.4(5) . . . .
C74 C73 C78 F5 -178.9(5) . . . .
B1 C73 C78 F5 5.3(10) . . . .
C74 C73 C78 C77 0.5(10) . . . .
B1 C73 C78 C77 -175.3(6) . . . .
F4 C77 C78 F5 0.1(9) . . . .
C76 C77 C78 F5 179.2(6) . . . .
F4 C77 C78 C73 -179.3(6) . . . .
C76 C77 C78 C73 -0.2(11) . . . .
C3 C2 C1 C8 131.1(6) . . . .
C7 C2 C1 C8 -50.1(6) . . . .
C3 C2 C1 C14 -124.9(6) . . . .
C7 C2 C1 C14 53.8(6) . . . .
C3 C2 C1 Ge1 4.4(7) . . . .
C7 C2 C1 Ge1 -176.8(4) . . . .
C9 C8 C1 C2 -140.0(5) . . . .
C13 C8 C1 C2 48.7(6) . . . .
C9 C8 C1 C14 110.1(6) . . . .
C13 C8 C1 C14 -61.2(5) . . . .
C9 C8 C1 Ge1 -15.9(7) . . . .
C13 C8 C1 Ge1 172.7(4) . . . .
Pt1 Ge1 C1 C2 -45.1(4) . . . .
Pt2 Ge1 C1 C2 46.7(4) . . . .
Pt1 Ge1 C1 C8 -167.4(3) . . . .
Pt2 Ge1 C1 C8 -75.5(4) . . . .
Pt1 Ge1 C1 C14 77.7(4) . . . .
Pt2 Ge1 C1 C14 169.6(3) . . . .
F11 C86 C87 C88 -178.8(6) . . . .
C85 C86 C87 C88 1.6(11) . . . .
F11 C86 C87 F12 1.3(10) . . . .
C85 C86 C87 F12 -178.3(6) . . . .
F13 C88 C87 C86 178.7(6) . . . .
C89 C88 C87 C86 -1.2(10) . . . .
F13 C88 C87 F12 -1.4(10) . . . .
C89 C88 C87 F12 178.8(6) . . . .
F7 C81 C80 F6 0.9(8) . . . .
C82 C81 C80 F6 178.8(5) . . . .
F7 C81 C80 C79 -178.3(6) . . . .
C82 C81 C80 C79 -0.4(10) . . . .
C22 P2 C41 C42 89.0(4) . . . .
C35 P2 C41 C42 -158.9(4) . . . .
Pt2 P2 C41 C42 -26.4(4) . . . .
C22 P2 C41 C46 -35.8(5) . . . .
C35 P2 C41 C46 76.3(5) . . . .
Pt2 P2 C41 C46 -151.3(4) . . . .
C56 C55 C60 C59 -60.3(8) . . . .
P3 C55 C60 C59 170.7(6) . . . .
F11 C86 C85 C90 179.6(6) . . . .
C87 C86 C85 C90 -0.9(10) . . . .
F11 C86 C85 B1 0.4(10) . . . .
C87 C86 C85 B1 179.9(6) . . . .
F15 C90 C85 C86 -177.6(5) . . . .
C89 C90 C85 C86 -0.3(10) . . . .
F15 C90 C85 B1 1.6(10) . . . .
C89 C90 C85 B1 178.9(6) . . . .
C23 P1 C21 C22 -162.2(4) . . . .
C29 P1 C21 C22 86.7(4) . . . .
Pt2 P1 C21 C22 -37.7(4) . . . .
F7 C81 C82 C83 178.5(6) . . . .
C80 C81 C82 C83 0.6(10) . . . .
F7 C81 C82 F8 -1.0(10) . . . .
C80 C81 C82 F8 -178.9(5) . . . .
C46 C41 C42 C43 -55.1(7) . . . .
P2 C41 C42 C43 176.2(4) . . . .
C49 C50 C51 C52 -57.3(8) . . . .
C33 C34 C29 C30 58.0(6) . . . .
C33 C34 C29 P1 -172.4(4) . . . .
C23 P1 C29 C34 144.6(4) . . . .
C21 P1 C29 C34 -106.8(4) . . . .
Pt2 P1 C29 C34 12.3(5) . . . .
C23 P1 C29 C30 -87.9(5) . . . .
C21 P1 C29 C30 20.7(5) . . . .
Pt2 P1 C29 C30 139.8(4) . . . .
P1 C21 C22 P2 46.1(5) . . . .
C35 P2 C22 C21 93.3(4) . . . .
C41 P2 C22 C21 -154.3(4) . . . .
Pt2 P2 C22 C21 -33.2(4) . . . .
C50 C51 C52 C53 58.2(8) . . . .
C27 C26 C25 C24 -57.3(7) . . . .
C23 C24 C25 C26 57.1(7) . . . .
C18 C19 C14 C15 -5.7(8) . . . .
C20 C19 C14 C15 169.3(5) . . . .
C18 C19 C14 C1 -179.0(5) . . . .
C20 C19 C14 C1 -4.0(7) . . . .
C2 C1 C14 C15 137.1(6) . . . .
C8 C1 C14 C15 -112.0(6) . . . .
Ge1 C1 C14 C15 12.0(7) . . . .
C2 C1 C14 C19 -50.2(6) . . . .
C8 C1 C14 C19 60.7(5) . . . .
Ge1 C1 C14 C19 -175.3(4) . . . .
C62 C63 C64 C65 -55.7(8) . . . .
C66 C65 C64 C63 54.2(8) . . . .
C31 C32 C33 C34 53.0(8) . . . .
C29 C34 C33 C32 -56.2(7) . . . .
C42 C41 C46 C45 56.9(7) . . . .
P2 C41 C46 C45 -178.9(4) . . . .
C44 C45 C46 C41 -58.4(7) . . . .
C25 C26 C27 C28 57.1(7) . . . .
C23 C28 C27 C26 -56.5(6) . . . .
C9 C8 C13 C12 5.5(8) . . . .
C1 C8 C13 C12 177.6(5) . . . .
C9 C8 C13 C20 -167.9(5) . . . .
C1 C8 C13 C20 4.2(7) . . . .
C36 C37 C38 C39 57.7(7) . . . .
C40 C39 C38 C37 -57.1(7) . . . .
C19 C14 C15 C16 3.5(8) . . . .
C1 C14 C15 C16 175.9(5) . . . .
C38 C37 C36 C35 -55.6(7) . . . .
C34 C29 C30 C31 -56.7(7) . . . .
P1 C29 C30 C31 173.8(4) . . . .
C50 C49 C54 C53 -56.8(8) . . . .
P3 C49 C54 C53 175.9(5) . . . .
F10 C84 C79 C80 -177.7(5) . . . .
C83 C84 C79 C80 3.1(9) . . . .
F10 C84 C79 B1 2.8(10) . . . .
C83 C84 C79 B1 -176.4(6) . . . .
F6 C80 C79 C84 179.5(5) . . . .
C81 C80 C79 C84 -1.4(9) . . . .
F6 C80 C79 B1 -0.9(8) . . . .
C81 C80 C79 B1 178.2(5) . . . .
C16 C17 C18 C19 0.7(9) . . . .
C14 C19 C18 C17 3.6(9) . . . .
C20 C19 C18 C17 -170.6(6) . . . .
C8 C13 C12 C11 -2.3(8) . . . .
C20 C13 C12 C11 170.2(5) . . . .
C46 C45 C44 C43 56.6(7) . . . .
C57 C58 C59 C60 -56.6(12) . . . .
C55 C60 C59 C58 58.8(11) . . . .
C51 C52 C53 C54 -57.7(8) . . . .
C49 C54 C53 C52 57.2(8) . . . .
F8 C82 C83 F9 0.3(10) . . . .
C81 C82 C83 F9 -179.1(6) . . . .
F8 C82 C83 C84 -179.5(6) . . . .
C81 C82 C83 C84 1.0(10) . . . .
F10 C84 C83 F9 -2.2(9) . . . .
C79 C84 C83 F9 177.1(6) . . . .
F10 C84 C83 C82 177.7(6) . . . .
C79 C84 C83 C82 -3.1(11) . . . .
C13 C12 C11 C10 -1.1(9) . . . .
C9 C10 C11 C12 1.2(9) . . . .
C59 C58 C57 C56 56.6(10) . . . .
C55 C56 C57 C58 -58.6(8) . . . .
C38 C39 C40 C35 54.4(8) . . . .
P3 C47 C48 P4 39.5(5) . . . .
C61 P4 C48 C47 95.8(4) . . . .
C67 P4 C48 C47 -155.9(4) . . . .
Pt1 P4 C48 C47 -31.1(4) . . . .
C33 C32 C31 C30 -53.1(7) . . . .
C29 C30 C31 C32 54.6(7) . . . .
C18 C17 C16 C15 -2.9(9) . . . .
C14 C15 C16 C17 0.7(9) . . . .
C45 C44 C43 C42 -54.2(7) . . . .
C41 C42 C43 C44 53.8(7) . . . .
C39 C40 C35 C36 -51.2(7) . . . .
C39 C40 C35 P2 -177.8(5) . . . .
C37 C36 C35 C40 51.5(7) . . . .
C37 C36 C35 P2 -177.9(4) . . . .
C22 P2 C35 C40 63.7(5) . . . .
C41 P2 C35 C40 -46.1(5) . . . .
Pt2 P2 C35 C40 -176.9(4) . . . .
C22 P2 C35 C36 -63.1(4) . . . .
C41 P2 C35 C36 -172.9(4) . . . .
Pt2 P2 C35 C36 56.3(4) . . . .
C86 C85 B1 C79 -134.3(6) . . . .
C90 C85 B1 C79 46.6(9) . . . .
C86 C85 B1 C73 99.1(7) . . . .
C90 C85 B1 C73 -80.0(8) . . . .
C84 C79 B1 C85 -106.5(7) . . . .
C80 C79 B1 C85 74.1(7) . . . .
C84 C79 B1 C73 20.3(9) . . . .
C80 C79 B1 C73 -159.2(5) . . . .
C78 C73 B1 C85 -4.3(9) . . . .
C74 C73 B1 C85 -179.8(5) . . . .
C78 C73 B1 C79 -129.3(7) . . . .
C74 C73 B1 C79 55.2(7) . . . .
C72 C67 C68 C69 -51.9(6) . . . .
P4 C67 C68 C69 -179.9(4) . . . .
C68 C67 C72 C71 53.8(7) . . . .
P4 C67 C72 C71 179.1(4) . . . .
C3 C2 C7 C6 0.1(9) . . . .
C1 C2 C7 C6 -178.8(5) . . . .
C3 C2 C7 C20 177.2(5) . . . .
C1 C2 C7 C20 -1.6(7) . . . .
C7 C2 C3 C4 -0.9(9) . . . .
C1 C2 C3 C4 177.8(5) . . . .
C67 C68 C69 C70 54.2(7) . . . .
C2 C3 C4 C5 1.3(10) . . . .
C68 C69 C70 C71 -56.7(7) . . . .
C2 C7 C6 C5 0.4(9) . . . .
C20 C7 C6 C5 -176.3(6) . . . .
C12 C13 C20 C7 130.2(6) . . . .
C8 C13 C20 C7 -56.9(6) . . . .
C12 C13 C20 C19 -117.1(6) . . . .
C8 C13 C20 C19 55.9(6) . . . .
C2 C7 C20 C13 55.7(7) . . . .
C6 C7 C20 C13 -127.3(6) . . . .
C2 C7 C20 C19 -54.3(6) . . . .
C6 C7 C20 C19 122.7(6) . . . .
C18 C19 C20 C13 118.8(6) . . . .
C14 C19 C20 C13 -55.8(6) . . . .
C18 C19 C20 C7 -128.4(6) . . . .
C14 C19 C20 C7 57.1(6) . . . .
C3 C4 C5 C6 -0.7(10) . . . .
C7 C6 C5 C4 -0.1(10) . . . .
C69 C70 C71 C72 57.3(7) . . . .
C67 C72 C71 C70 -56.7(7) . . . .
