#------------------------------------------------------------------------------
#$Date: 2016-02-13 21:28:24 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176429 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/78/7117861.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7117861
loop_
_publ_author_name
'Julia Weismann'
'Viktoria H. Gessner'
_publ_section_title
;
 Si-H activation by means of metal ligand cooperation in a methandiide
 derived carbene complex
;
_journal_name_full               Chem.Commun.
_journal_page_first              14909
_journal_paper_doi               10.1039/C5cc05201G
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C50.5 H49 O2 P Ru S2 Si'
_chemical_formula_weight         912.15
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2015-03-24T15:10:04-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2015-05-05 deposited with the CCDC.
2015-08-20 downloaded from the CCDC.
;
_cell_angle_alpha                97.379(2)
_cell_angle_beta                 97.740(2)
_cell_angle_gamma                101.302(2)
_cell_formula_units_Z            2
_cell_length_a                   9.3712(7)
_cell_length_b                   13.5265(9)
_cell_length_c                   17.6717(12)
_cell_measurement_temperature    100(2)
_cell_volume                     2148.8(3)
_computing_cell_refinement       'SAINTPLUS 8.18C (Bruker APEX2, 2011)'
_computing_data_collection       'SMART 5.622 (Bruker AXS, 2001)'
_computing_data_reduction        'SAINTPLUS 8.18C (Bruker APEX2, 2011)'
_computing_molecular_graphics    'Ortep-3 V1.08 (Farrugia, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-CCD'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0359
_diffrn_reflns_av_unetI/netI     0.038
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            25734
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         3.11
_exptl_absorpt_coefficient_mu    0.568
_exptl_absorpt_correction_T_max  0.7671
_exptl_absorpt_correction_T_min  0.7123
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Sadabs 2008 (Bruker AXS, 2008)'
_exptl_crystal_density_diffrn    1.41
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cube
_exptl_crystal_F_000             946
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.569
_refine_diff_density_min         -0.524
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     558
_refine_ls_number_reflns         7520
_refine_ls_number_restraints     42
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0287
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0495P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0756
_refine_ls_wR_factor_ref         0.0803
_reflns_number_gt                6510
_reflns_number_total             7520
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc05201g2_a.cif
_cod_data_source_block           sad1
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C50.50 H49 O2 P Ru S2 Si'
_cod_database_code               7117861
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.717201(19) 0.671224(13) 0.855958(10) 0.00941(7) Uani 1 1 d . . .
S1 S 0.93822(6) 0.60039(4) 0.85701(3) 0.01184(13) Uani 1 1 d . . .
S2 S 0.48965(6) 0.51041(4) 0.70035(3) 0.01389(14) Uani 1 1 d . . .
P1 P 0.78347(6) 0.48241(4) 0.79623(3) 0.01048(14) Uani 1 1 d . . .
Si1 Si 0.84352(7) 0.78818(5) 0.78174(4) 0.01210(15) Uani 1 1 d . . .
O1 O 0.38978(17) 0.47099(12) 0.75007(9) 0.0178(4) Uani 1 1 d . . .
O2 O 0.45428(18) 0.58995(12) 0.65837(10) 0.0193(4) Uani 1 1 d . . .
C1 C 0.6694(2) 0.55674(17) 0.75082(13) 0.0111(5) Uani 1 1 d . . .
H1 H 0.727(3) 0.5813(18) 0.7131(14) 0.016(7) Uiso 1 1 d . . .
C2 C 0.8619(3) 0.40097(17) 0.73098(13) 0.0124(5) Uani 1 1 d . . .
C3 C 0.9852(3) 0.44376(19) 0.70175(14) 0.0187(6) Uani 1 1 d . . .
H3 H 1.0269 0.5148 0.7156 0.022 Uiso 1 1 calc R . .
C4 C 1.0481(3) 0.3836(2) 0.65252(14) 0.0216(6) Uani 1 1 d . . .
H4 H 1.1326 0.4136 0.6326 0.026 Uiso 1 1 calc R . .
C5 C 0.9890(3) 0.2808(2) 0.63227(15) 0.0256(6) Uani 1 1 d . . .
H5 H 1.0328 0.2398 0.5985 0.031 Uiso 1 1 calc R . .
C6 C 0.8658(3) 0.2369(2) 0.66108(17) 0.0334(7) Uani 1 1 d . . .
H6 H 0.825 0.1658 0.6471 0.04 Uiso 1 1 calc R . .
C7 C 0.8019(3) 0.29639(19) 0.71011(15) 0.0224(6) Uani 1 1 d . . .
H7 H 0.717 0.2662 0.7297 0.027 Uiso 1 1 calc R . .
C8 C 0.7014(3) 0.39829(17) 0.85802(13) 0.0120(5) Uani 1 1 d . . .
C9 C 0.7871(3) 0.39243(18) 0.92706(14) 0.0157(5) Uani 1 1 d . . .
H9 H 0.8804 0.4379 0.9434 0.019 Uiso 1 1 calc R . .
C10 C 0.7373(3) 0.32052(19) 0.97242(14) 0.0193(6) Uani 1 1 d . . .
H10 H 0.7968 0.3169 1.0195 0.023 Uiso 1 1 calc R . .
C11 C 0.6012(3) 0.25400(18) 0.94918(14) 0.0171(5) Uani 1 1 d . . .
H11 H 0.5676 0.2043 0.9799 0.021 Uiso 1 1 calc R . .
C12 C 0.5147(3) 0.26054(18) 0.88089(15) 0.0186(6) Uani 1 1 d . . .
H12 H 0.4208 0.2156 0.8652 0.022 Uiso 1 1 calc R . .
C13 C 0.5632(3) 0.33169(18) 0.83514(14) 0.0169(5) Uani 1 1 d . . .
H13 H 0.5029 0.3354 0.7883 0.02 Uiso 1 1 calc R . .
C14 C 0.4948(3) 0.40483(19) 0.63005(14) 0.0168(5) Uani 1 1 d . . .
C15 C 0.4075(3) 0.30956(19) 0.63151(15) 0.0221(6) Uani 1 1 d . . .
H15 H 0.3475 0.3005 0.6704 0.026 Uiso 1 1 calc R . .
C16 C 0.4086(3) 0.2281(2) 0.57574(16) 0.0308(7) Uani 1 1 d . . .
H16 H 0.3489 0.1628 0.5762 0.037 Uiso 1 1 calc R . .
C17 C 0.4963(3) 0.2416(2) 0.51953(16) 0.0339(7) Uani 1 1 d . . .
H17 H 0.4977 0.1852 0.4818 0.041 Uiso 1 1 calc R . .
C18 C 0.5822(3) 0.3367(2) 0.51754(16) 0.0317(7) Uani 1 1 d . . .
H18 H 0.6416 0.3455 0.4783 0.038 Uiso 1 1 calc R . .
C19 C 0.5814(3) 0.4189(2) 0.57277(14) 0.0244(6) Uani 1 1 d . . .
H19 H 0.6397 0.4845 0.5715 0.029 Uiso 1 1 calc R . .
C20 C 0.3626(3) 0.7117(2) 0.81780(15) 0.0209(6) Uani 1 1 d . . .
H20A H 0.2913 0.7351 0.8476 0.031 Uiso 1 1 calc R . .
H20B H 0.318 0.644 0.7876 0.031 Uiso 1 1 calc R . .
H20C H 0.3907 0.7599 0.7827 0.031 Uiso 1 1 calc R . .
C21 C 0.4967(3) 0.70548(19) 0.87183(14) 0.0153(5) Uani 1 1 d . . .
C22 C 0.5083(2) 0.61394(18) 0.90262(13) 0.0140(5) Uani 1 1 d . . .
H22 H 0.4416 0.5482 0.8758 0.017 Uiso 1 1 calc R . .
C23 C 0.6246(2) 0.61030(18) 0.95951(13) 0.0131(5) Uani 1 1 d . . .
H23 H 0.6393 0.5422 0.9712 0.016 Uiso 1 1 calc R . .
C24 C 0.7407(2) 0.69816(17) 0.98781(13) 0.0125(5) Uani 1 1 d . . .
C25 C 0.7302(3) 0.79004(18) 0.95860(13) 0.0135(5) Uani 1 1 d . . .
H25 H 0.8166 0.8494 0.9715 0.016 Uiso 1 1 calc R . .
C26 C 0.6105(3) 0.79256(18) 0.90095(13) 0.0147(5) Uani 1 1 d . . .
H26 H 0.6145 0.8542 0.8749 0.018 Uiso 1 1 calc R . .
C27 C 0.8693(3) 0.69282(18) 1.04896(13) 0.0161(5) Uani 1 1 d . . .
H27 H 0.9463 0.6705 1.021 0.019 Uiso 1 1 calc R . .
C28 C 0.8261(3) 0.6144(2) 1.10145(15) 0.0234(6) Uani 1 1 d . . .
H28A H 0.7439 0.6303 1.1261 0.035 Uiso 1 1 calc R . .
H28B H 0.9107 0.6166 1.1413 0.035 Uiso 1 1 calc R . .
H28C H 0.7959 0.546 1.0706 0.035 Uiso 1 1 calc R . .
C29 C 0.9408(3) 0.7956(2) 1.09918(15) 0.0287(7) Uani 1 1 d . . .
H29A H 1.0226 0.7874 1.1369 0.043 Uiso 1 1 calc R . .
H29B H 0.8675 0.8209 1.1265 0.043 Uiso 1 1 calc R . .
H29C H 0.9782 0.8446 1.0664 0.043 Uiso 1 1 calc R . .
C30 C 0.7301(3) 0.88431(18) 0.75369(14) 0.0157(5) Uani 1 1 d . . .
C31 C 0.7706(3) 0.98732(19) 0.78782(16) 0.0229(6) Uani 1 1 d . . .
H31 H 0.8609 1.0108 0.8227 0.027 Uiso 1 1 calc R . .
C32 C 0.6827(3) 1.0558(2) 0.77210(18) 0.0293(7) Uani 1 1 d . . .
H32 H 0.712 1.1248 0.7971 0.035 Uiso 1 1 calc R . .
C33 C 0.5536(3) 1.0243(2) 0.72059(17) 0.0311(7) Uani 1 1 d . . .
H33 H 0.4951 1.0719 0.7086 0.037 Uiso 1 1 calc R . .
C34 C 0.5084(3) 0.9228(2) 0.68599(16) 0.0297(7) Uani 1 1 d . . .
H34 H 0.4185 0.9006 0.6506 0.036 Uiso 1 1 calc R . .
C35 C 0.5952(3) 0.8539(2) 0.70332(15) 0.0220(6) Uani 1 1 d . . .
H35 H 0.5621 0.7842 0.6804 0.026 Uiso 1 1 calc R . .
C36 C 1.0276(3) 0.86957(18) 0.83694(14) 0.0156(5) Uani 1 1 d . . .
C37 C 1.0831(3) 0.86384(18) 0.91291(15) 0.0172(5) Uani 1 1 d . . .
H37 H 1.0259 0.8185 0.9397 0.021 Uiso 1 1 calc R . .
C38 C 1.2200(3) 0.92223(19) 0.95144(16) 0.0251(6) Uani 1 1 d . . .
H38 H 1.2532 0.9179 1.0039 0.03 Uiso 1 1 calc R . .
C39 C 1.3059(3) 0.9861(2) 0.91226(18) 0.0279(7) Uani 1 1 d . . .
H39 H 1.3998 1.0252 0.9372 0.034 Uiso 1 1 calc R . .
C40 C 1.2542(3) 0.9928(2) 0.83619(18) 0.0304(7) Uani 1 1 d . . .
H40 H 1.3132 1.0366 0.809 0.036 Uiso 1 1 calc R . .
C41 C 1.1173(3) 0.93625(19) 0.79963(16) 0.0231(6) Uani 1 1 d . . .
H41 H 1.0832 0.9428 0.7478 0.028 Uiso 1 1 calc R . .
C42 C 0.9027(3) 0.73253(17) 0.68869(14) 0.0134(5) Uani 1 1 d . . .
C43 C 1.0460(3) 0.71593(19) 0.69078(14) 0.0188(6) Uani 1 1 d . . .
H43 H 1.113 0.7353 0.7382 0.023 Uiso 1 1 calc R . .
C44 C 1.0939(3) 0.6721(2) 0.62579(15) 0.0228(6) Uani 1 1 d . . .
H44 H 1.1917 0.6614 0.6295 0.027 Uiso 1 1 calc R . .
C45 C 0.9996(3) 0.6442(2) 0.55610(15) 0.0247(6) Uani 1 1 d . . .
H45 H 1.0318 0.6144 0.5116 0.03 Uiso 1 1 calc R . .
C46 C 0.8578(3) 0.6598(2) 0.55156(15) 0.0227(6) Uani 1 1 d . . .
H46 H 0.7924 0.6407 0.5036 0.027 Uiso 1 1 calc R . .
C47 C 0.8096(3) 0.70327(18) 0.61655(14) 0.0174(5) Uani 1 1 d . . .
H47 H 0.7115 0.7134 0.6121 0.021 Uiso 1 1 calc R . .
C1_1 C 0.1104(9) -0.0244(6) 0.4997(4) 0.037(2) Uani 0.5 1 d PU A -1
C2_1 C 0.0666(9) 0.0401(5) 0.4473(4) 0.0232(14) Uani 0.5 1 d PU A -1
H2_1 H 0.1293 0.0645 0.4126 0.028 Uiso 0.5 1 calc PR A -1
C3_1 C -0.0692(9) 0.0665(5) 0.4477(4) 0.036(2) Uani 0.5 1 d PU A -1
H3_1 H -0.0967 0.109 0.412 0.043 Uiso 0.5 1 calc PR A -1
C4_1 C -0.1644(10) 0.0366(6) 0.4949(5) 0.045(2) Uani 0.5 1 d PU A -1
H4_1 H -0.2561 0.0569 0.4926 0.054 Uiso 0.5 1 calc PR A -1
C5_1 C -0.1229(10) -0.0265(6) 0.5479(5) 0.047(2) Uani 0.5 1 d PU A -1
H5_1 H -0.1862 -0.0482 0.5831 0.056 Uiso 0.5 1 calc PR A -1
C6_1 C 0.0121(11) -0.0570(6) 0.5486(5) 0.041(2) Uani 0.5 1 d PU A -1
H6_1 H 0.0372 -0.1012 0.5835 0.05 Uiso 0.5 1 calc PR A -1
C7_1 C 0.2592(9) -0.0532(6) 0.4999(5) 0.063(2) Uani 0.5 1 d PU A -1
H7_1 H 0.3036 -0.029 0.4567 0.095 Uiso 0.5 1 calc PR A -1
H7B_1 H 0.2458 -0.1276 0.4945 0.095 Uiso 0.5 1 calc PR A -1
H7C_1 H 0.3242 -0.0216 0.5488 0.095 Uiso 0.5 1 calc PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ru1 C26 134.42(9) . .
C1 Ru1 C25 171.24(8) . .
C26 Ru1 C25 37.28(8) . .
C1 Ru1 C21 104.46(8) . .
C26 Ru1 C21 36.96(9) . .
C25 Ru1 C21 66.88(8) . .
C1 Ru1 C22 96.68(9) . .
C26 Ru1 C22 65.75(9) . .
C25 Ru1 C22 77.19(8) . .
C21 Ru1 C22 37.01(8) . .
C1 Ru1 C24 145.79(9) . .
C26 Ru1 C24 66.67(8) . .
C25 Ru1 C24 36.61(8) . .
C21 Ru1 C24 78.97(8) . .
C22 Ru1 C24 65.25(8) . .
C1 Ru1 C23 113.41(9) . .
C26 Ru1 C23 77.19(8) . .
C25 Ru1 C23 65.01(8) . .
C21 Ru1 C23 65.73(8) . .
C22 Ru1 C23 35.50(8) . .
C24 Ru1 C23 36.25(8) . .
C1 Ru1 Si1 86.89(6) . .
C26 Ru1 Si1 88.81(6) . .
C25 Ru1 Si1 94.97(6) . .
C21 Ru1 Si1 110.86(6) . .
C22 Ru1 Si1 147.54(6) . .
C24 Ru1 Si1 124.35(6) . .
C23 Ru1 Si1 159.71(6) . .
C1 Ru1 S1 75.33(6) . .
C26 Ru1 S1 148.86(7) . .
C25 Ru1 S1 113.38(6) . .
C21 Ru1 S1 165.84(6) . .
C22 Ru1 S1 128.87(6) . .
C24 Ru1 S1 93.29(6) . .
C23 Ru1 S1 101.07(6) . .
Si1 Ru1 S1 83.30(2) . .
C1 Ru1 P1 38.83(6) . .
C26 Ru1 P1 165.50(7) . .
C25 Ru1 P1 147.86(6) . .
C21 Ru1 P1 128.76(6) . .
C22 Ru1 P1 100.49(6) . .
C24 Ru1 P1 112.92(6) . .
C23 Ru1 P1 94.25(6) . .
Si1 Ru1 P1 102.22(2) . .
S1 Ru1 P1 43.754(18) . .
P1 S1 Ru1 78.92(3) . .
O1 S2 O2 117.97(10) . .
O1 S2 C1 111.68(11) . .
O2 S2 C1 106.40(11) . .
O1 S2 C14 106.25(11) . .
O2 S2 C14 106.89(11) . .
C1 S2 C14 107.10(11) . .
C1 P1 C8 116.98(11) . .
C1 P1 C2 115.43(11) . .
C8 P1 C2 104.33(10) . .
C1 P1 S1 96.75(8) . .
C8 P1 S1 112.00(8) . .
C2 P1 S1 111.53(8) . .
C1 P1 Ru1 50.32(7) . .
C8 P1 Ru1 101.54(7) . .
C2 P1 Ru1 154.13(8) . .
S1 P1 Ru1 57.32(2) . .
C30 Si1 C36 104.84(11) . .
C30 Si1 C42 106.27(10) . .
C36 Si1 C42 101.08(10) . .
C30 Si1 Ru1 111.50(8) . .
C36 Si1 Ru1 113.57(8) . .
C42 Si1 Ru1 118.27(7) . .
S2 C1 P1 125.73(13) . .
S2 C1 Ru1 121.64(12) . .
P1 C1 Ru1 90.85(10) . .
C3 C2 C7 119.2(2) . .
C3 C2 P1 118.95(18) . .
C7 C2 P1 121.85(18) . .
C4 C3 C2 120.3(2) . .
C5 C4 C3 120.4(2) . .
C4 C5 C6 120.0(2) . .
C7 C6 C5 120.1(3) . .
C6 C7 C2 120.1(2) . .
C9 C8 C13 119.1(2) . .
C9 C8 P1 117.74(18) . .
C13 C8 P1 122.72(18) . .
C8 C9 C10 120.5(2) . .
C11 C10 C9 120.2(2) . .
C12 C11 C10 119.5(2) . .
C13 C12 C11 120.8(2) . .
C12 C13 C8 119.9(2) . .
C19 C14 C15 120.6(2) . .
C19 C14 S2 120.0(2) . .
C15 C14 S2 119.4(2) . .
C16 C15 C14 119.4(3) . .
C17 C16 C15 120.1(3) . .
C16 C17 C18 120.6(3) . .
C19 C18 C17 119.9(3) . .
C18 C19 C14 119.5(3) . .
C26 C21 C22 116.9(2) . .
C26 C21 C20 121.3(2) . .
C22 C21 C20 121.5(2) . .
C26 C21 Ru1 69.70(13) . .
C22 C21 Ru1 71.98(13) . .
C20 C21 Ru1 134.33(17) . .
C23 C22 C21 122.1(2) . .
C23 C22 Ru1 73.94(13) . .
C21 C22 Ru1 71.01(13) . .
C22 C23 C24 120.7(2) . .
C22 C23 Ru1 70.56(13) . .
C24 C23 Ru1 71.11(13) . .
C25 C24 C23 117.9(2) . .
C25 C24 C27 121.7(2) . .
C23 C24 C27 120.3(2) . .
C25 C24 Ru1 69.83(13) . .
C23 C24 Ru1 72.64(13) . .
C27 C24 Ru1 129.85(15) . .
C26 C25 C24 120.6(2) . .
C26 C25 Ru1 70.04(13) . .
C24 C25 Ru1 73.56(13) . .
C21 C26 C25 121.7(2) . .
C21 C26 Ru1 73.34(13) . .
C25 C26 Ru1 72.68(13) . .
C29 C27 C24 113.3(2) . .
C29 C27 C28 108.9(2) . .
C24 C27 C28 112.7(2) . .
C35 C30 C31 116.5(2) . .
C35 C30 Si1 121.59(19) . .
C31 C30 Si1 121.7(2) . .
C32 C31 C30 121.9(3) . .
C33 C32 C31 120.1(3) . .
C32 C33 C34 119.9(3) . .
C33 C34 C35 119.7(3) . .
C34 C35 C30 121.8(3) . .
C37 C36 C41 116.4(2) . .
C37 C36 Si1 123.64(18) . .
C41 C36 Si1 119.90(19) . .
C36 C37 C38 122.6(2) . .
C39 C38 C37 119.2(3) . .
C38 C39 C40 119.6(3) . .
C41 C40 C39 120.4(3) . .
C40 C41 C36 121.8(3) . .
C43 C42 C47 116.0(2) . .
C43 C42 Si1 119.63(18) . .
C47 C42 Si1 124.33(18) . .
C44 C43 C42 122.4(2) . .
C45 C44 C43 120.0(2) . .
C44 C45 C46 119.4(2) . .
C45 C46 C47 120.7(2) . .
C46 C47 C42 121.5(2) . .
C6_1 C1_1 C2_1 117.0(7) . .
C6_1 C1_1 C7_1 123.8(8) . .
C2_1 C1_1 C7_1 119.3(7) . .
C3_1 C2_1 C1_1 118.9(7) . .
C4_1 C3_1 C2_1 124.8(8) . .
C3_1 C4_1 C5_1 117.4(9) . .
C6_1 C5_1 C4_1 119.9(8) . .
C1_1 C6_1 C5_1 122.0(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C1 2.194(2) .
Ru1 C26 2.202(2) .
Ru1 C25 2.237(2) .
Ru1 C21 2.249(2) .
Ru1 C22 2.262(2) .
Ru1 C24 2.285(2) .
Ru1 C23 2.305(2) .
Ru1 Si1 2.4168(7) .
Ru1 S1 2.4454(6) .
Ru1 P1 2.8510(6) .
S1 P1 2.0091(8) .
S2 O1 1.4417(17) .
S2 O2 1.4478(17) .
S2 C1 1.750(2) .
S2 C14 1.781(2) .
P1 C1 1.788(2) .
P1 C8 1.811(2) .
P1 C2 1.817(2) .
Si1 C30 1.906(2) .
Si1 C36 1.915(3) .
Si1 C42 1.916(2) .
C2 C3 1.383(3) .
C2 C7 1.397(3) .
C3 C4 1.382(3) .
C4 C5 1.373(4) .
C5 C6 1.383(4) .
C6 C7 1.380(3) .
C8 C9 1.387(3) .
C8 C13 1.400(3) .
C9 C10 1.389(3) .
C10 C11 1.385(4) .
C11 C12 1.383(4) .
C12 C13 1.383(3) .
C14 C19 1.389(4) .
C14 C15 1.390(4) .
C15 C16 1.384(4) .
C16 C17 1.380(4) .
C17 C18 1.386(4) .
C18 C19 1.384(4) .
C20 C21 1.496(3) .
C21 C26 1.412(3) .
C21 C22 1.432(3) .
C22 C23 1.393(3) .
C23 C24 1.428(3) .
C24 C25 1.421(3) .
C24 C27 1.526(3) .
C25 C26 1.419(3) .
C27 C29 1.526(4) .
C27 C28 1.528(3) .
C30 C35 1.400(4) .
C30 C31 1.402(4) .
C31 C32 1.385(4) .
C32 C33 1.369(4) .
C33 C34 1.387(4) .
C34 C35 1.389(4) .
C36 C37 1.390(3) .
C36 C41 1.400(3) .
C37 C38 1.401(3) .
C38 C39 1.381(4) .
C39 C40 1.387(4) .
C40 C41 1.384(4) .
C42 C43 1.401(3) .
C42 C47 1.407(3) .
C43 C44 1.393(3) .
C44 C45 1.378(4) .
C45 C46 1.379(4) .
C46 C47 1.393(3) .
C1_1 C6_1 1.394(11) .
C1_1 C2_1 1.426(10) .
C1_1 C7_1 1.520(11) .
C2_1 C3_1 1.389(10) .
C3_1 C4_1 1.341(11) .
C4_1 C5_1 1.412(12) .
C5_1 C6_1 1.404(12) .
