#------------------------------------------------------------------------------
#$Date: 2017-02-15 13:20:40 +0200 (Wed, 15 Feb 2017) $
#$Revision: 192153 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/84/7118411.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7118411
loop_
_publ_author_name
'Hai-Yang Li'
'Hong Xu'
'Shuang-Quan Zang'
'Thomas C. W. Mak'
_publ_section_title
;
 A viologen-functionalized chiral Eu-MOF as a platform for multifunctional
 switchable material
;
_journal_name_full               Chem.Commun.
_journal_page_first              525
_journal_paper_doi               10.1039/C5CC08168H
_journal_volume                  52
_journal_year                    2016
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C19 H16 Eu N2 O6, N O3, H2 O'
_chemical_formula_sum            'C19 H18 Eu N3 O10'
_chemical_formula_weight         600.33
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-07-29 deposited with the CCDC.
2015-10-29 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 107.90
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.7675(9)
_cell_length_b                   7.1607(6)
_cell_length_c                   15.8901(19)
_cell_measurement_reflns_used    2929
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.7460
_cell_measurement_theta_min      3.5790
_cell_volume                     1057.59(18)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0362
_diffrn_reflns_av_sigmaI/netI    0.1049
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            4721
_diffrn_reflns_theta_full        26.36
_diffrn_reflns_theta_max         26.36
_diffrn_reflns_theta_min         2.90
_exptl_absorpt_coefficient_mu    3.028
_exptl_absorpt_correction_T_max  0.580
_exptl_absorpt_correction_T_min  0.551
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            light-yellow
_exptl_crystal_density_diffrn    1.885
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             592
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.519
_refine_diff_density_min         -1.256
_refine_diff_density_rms         0.165
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.04(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         3269
_refine_ls_number_restraints     476
_refine_ls_restrained_S_all      0.982
_refine_ls_R_factor_all          0.0489
_refine_ls_R_factor_gt           0.0416
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0369P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1043
_refine_ls_wR_factor_ref         0.1102
_reflns_number_gt                2757
_reflns_number_total             4308
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc08168h2.cif
_cod_data_source_block           Eu-MOF
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               7118411
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.01740(4) 0.79195(17) 0.96307(3) 0.01731(15) Uani 1 1 d U . .
O1 O 0.2029(7) 0.7449(10) 0.9232(5) 0.0232(16) Uani 1 1 d U . .
O2 O 0.0993(8) 0.4739(11) 0.9302(6) 0.0275(17) Uani 1 1 d U . .
O3 O 0.7142(6) 0.7554(10) 0.9245(4) 0.0187(17) Uani 1 1 d U . .
O4 O 0.8312(7) 0.4882(10) 0.9379(5) 0.0260(18) Uani 1 1 d U . .
N1 N 0.4483(10) -0.0001(13) 0.7358(7) 0.0252(18) Uani 1 1 d U . .
N2 N 0.5638(14) 0.0229(16) 0.3159(8) 0.043(2) Uani 1 1 d U . .
C8 C 0.7148(10) 0.5809(15) 0.9259(7) 0.0169(18) Uani 1 1 d U . .
C1 C 0.2056(11) 0.5685(15) 0.9206(8) 0.0211(18) Uani 1 1 d U . .
C7 C 0.4597(9) 0.5642(14) 0.9216(7) 0.0147(19) Uani 1 1 d U . .
H7 H 0.4667 0.6899 0.9415 0.018 Uiso 1 1 calc R . .
C5 C 0.5665(8) 0.287(3) 0.8786(5) 0.0163(15) Uani 1 1 d U . .
H5 H 0.6478 0.2239 0.8712 0.020 Uiso 1 1 calc R . .
C9 C 0.4214(12) 0.0020(15) 0.8236(7) 0.0210(19) Uani 1 1 d U . .
H9A H 0.4920 -0.0797 0.8655 0.025 Uiso 1 1 calc R . .
H9B H 0.3238 -0.0468 0.8169 0.025 Uiso 1 1 calc R . .
C13 C 0.6021(12) -0.0492(16) 0.6458(8) 0.026(2) Uani 1 1 d U . .
H13 H 0.6930 -0.0870 0.6418 0.031 Uiso 1 1 calc R . .
C12 C 0.4975(13) 0.0096(17) 0.5708(9) 0.029(2) Uani 1 1 d U . .
C18 C 0.6702(17) 0.057(2) 0.3880(11) 0.042(3) Uani 1 1 d U . .
H18 H 0.7628 0.0839 0.3833 0.051 Uiso 1 1 calc R . .
C2 C 0.3285(10) 0.4665(14) 0.9040(7) 0.0168(18) Uani 1 1 d U . .
C14 C 0.5775(12) -0.0544(17) 0.7276(8) 0.028(2) Uani 1 1 d U . .
H14 H 0.6515 -0.0962 0.7783 0.034 Uiso 1 1 calc R . .
C6 C 0.5777(10) 0.4754(14) 0.9097(7) 0.0150(18) Uani 1 1 d U . .
C15 C 0.5211(14) 0.0168(18) 0.4838(9) 0.030(2) Uani 1 1 d U . .
C3 C 0.3170(8) 0.284(3) 0.8730(5) 0.0157(16) Uani 1 1 d U . .
H3 H 0.2284 0.2183 0.8614 0.019 Uiso 1 1 calc R . .
C4 C 0.4343(10) 0.1975(13) 0.8594(7) 0.0163(18) Uani 1 1 d U . .
C17 C 0.4355(16) -0.0126(19) 0.3254(10) 0.043(3) Uani 1 1 d U . .
H17 H 0.3572 -0.0307 0.2731 0.052 Uiso 1 1 calc R . .
O1W O -0.0983(8) 0.7376(12) 0.8006(5) 0.043(2) Uani 1 1 d U . .
H1WB H -0.1058 0.6209 0.7904 0.051 Uiso 1 1 d R . .
H1WA H -0.0369 0.7836 0.7784 0.051 Uiso 1 1 d R . .
O5 O -0.0594(9) 1.0993(11) 0.9133(6) 0.035(2) Uani 1 1 d U . .
H5A H -0.1002 1.1385 0.8537 0.043 Uiso 1 1 calc R . .
C19 C 0.6504(14) 0.0543(19) 0.4736(10) 0.038(2) Uani 1 1 d U . .
H19 H 0.7301 0.0794 0.5243 0.045 Uiso 1 1 calc R . .
C11 C 0.3601(14) 0.0609(18) 0.5816(10) 0.029(2) Uani 1 1 d U . .
H11 H 0.2837 0.0986 0.5313 0.035 Uiso 1 1 calc R . .
O7 O 0.8789(13) 0.274(3) 0.7503(9) 0.126(4) Uani 1 1 d DU . .
C16 C 0.4075(14) -0.0252(18) 0.4041(9) 0.036(2) Uani 1 1 d U . .
H16 H 0.3149 -0.0609 0.4061 0.043 Uiso 1 1 calc R . .
N3 N 0.955(3) 0.230(2) 0.7032(16) 0.190(6) Uani 1 1 d DU . .
O8 O 0.998(2) 0.066(2) 0.7019(14) 0.184(7) Uani 1 1 d DU . .
O9 O 0.986(2) 0.343(2) 0.6519(13) 0.214(7) Uani 1 1 d DU . .
C10 C 0.3377(14) 0.0560(17) 0.6639(9) 0.028(2) Uani 1 1 d U . .
H10 H 0.2475 0.0908 0.6701 0.033 Uiso 1 1 calc R . .
O2W O 0.979(2) 0.691(3) 0.5168(16) 0.213(11) Uani 1 1 d U . .
H2WA H 0.9439 0.7010 0.5594 0.256 Uiso 1 1 d RD . .
H2WB H 0.9870 0.7995 0.4971 0.256 Uiso 1 1 d RD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O5 145.4(2) 2_547 .
O5 Eu1 O1 93.2(3) 2_547 .
O5 Eu1 O1 96.8(3) . .
O5 Eu1 O4 79.3(3) 2_547 2_657
O5 Eu1 O4 72.2(3) . 2_657
O1 Eu1 O4 72.9(2) . 2_657
O5 Eu1 O2 79.7(3) 2_547 2_557
O5 Eu1 O2 70.9(3) . 2_557
O1 Eu1 O2 138.6(2) . 2_557
O4 Eu1 O2 65.7(2) 2_657 2_557
O5 Eu1 O1W 134.5(3) 2_547 .
O5 Eu1 O1W 80.1(3) . .
O1 Eu1 O1W 74.6(2) . .
O4 Eu1 O1W 133.9(3) 2_657 .
O2 Eu1 O1W 137.0(3) 2_557 .
O5 Eu1 O3 100.7(3) 2_547 1_455
O5 Eu1 O3 87.4(3) . 1_455
O1 Eu1 O3 148.9(2) . 1_455
O4 Eu1 O3 136.8(2) 2_657 1_455
O2 Eu1 O3 71.8(2) 2_557 1_455
O1W Eu1 O3 75.9(2) . 1_455
O5 Eu1 O4 69.7(3) 2_547 1_455
O5 Eu1 O4 135.0(3) . 1_455
O1 Eu1 O4 110.5(2) . 1_455
O4 Eu1 O4 148.94(17) 2_657 1_455
O2 Eu1 O4 105.1(2) 2_557 1_455
O1W Eu1 O4 74.0(3) . 1_455
O3 Eu1 O4 51.1(2) 1_455 1_455
O5 Eu1 O2 67.2(3) 2_547 .
O5 Eu1 O2 141.3(3) . .
O1 Eu1 O2 50.9(2) . .
O4 Eu1 O2 109.7(2) 2_657 .
O2 Eu1 O2 146.7(2) 2_557 .
O1W Eu1 O2 71.5(3) . .
O3 Eu1 O2 109.8(2) 1_455 .
O4 Eu1 O2 60.8(2) 1_455 .
O5 Eu1 C8 84.3(3) 2_547 1_455
O5 Eu1 C8 111.5(3) . 1_455
O1 Eu1 C8 132.9(3) . 1_455
O4 Eu1 C8 150.3(3) 2_657 1_455
O2 Eu1 C8 87.3(3) 2_557 1_455
O1W Eu1 C8 74.3(3) . 1_455
O3 Eu1 C8 25.2(3) 1_455 1_455
O4 Eu1 C8 26.0(2) 1_455 1_455
O2 Eu1 C8 85.9(3) . 1_455
O5 Eu1 C1 78.6(3) 2_547 .
O5 Eu1 C1 120.0(3) . .
O1 Eu1 C1 25.0(3) . .
O4 Eu1 C1 90.2(3) 2_657 .
O2 Eu1 C1 150.1(3) 2_557 .
O1W Eu1 C1 72.5(3) . .
O3 Eu1 C1 132.6(3) 1_455 .
O4 Eu1 C1 86.3(3) 1_455 .
O2 Eu1 C1 25.9(2) . .
C8 Eu1 C1 110.6(3) 1_455 .
O5 Eu1 Eu1 109.1(2) 2_547 2_557
O5 Eu1 Eu1 36.4(2) . 2_557
O1 Eu1 Eu1 102.14(16) . 2_557
O4 Eu1 Eu1 43.40(17) 2_657 2_557
O2 Eu1 Eu1 45.24(17) 2_557 2_557
O1W Eu1 Eu1 116.3(2) . 2_557
O3 Eu1 Eu1 99.37(17) 1_455 2_557
O4 Eu1 Eu1 147.36(16) 1_455 2_557
O2 Eu1 Eu1 150.76(16) . 2_557
C8 Eu1 Eu1 123.1(2) 1_455 2_557
C1 Eu1 Eu1 126.0(2) . 2_557
C1 O1 Eu1 100.1(6) . .
C1 O2 Eu1 143.7(7) . 2_547
C1 O2 Eu1 89.0(6) . .
Eu1 O2 Eu1 93.9(2) 2_547 .
C8 O3 Eu1 95.8(6) . 1_655
C8 O4 Eu1 147.6(7) . 2_647
C8 O4 Eu1 91.5(6) . 1_655
Eu1 O4 Eu1 96.1(2) 2_647 1_655
C14 N1 C10 121.3(11) . .
C14 N1 C9 121.6(9) . .
C10 N1 C9 117.1(10) . .
C18 N2 C17 117.2(13) . .
O3 C8 O4 121.4(9) . .
O3 C8 C6 120.3(9) . .
O4 C8 C6 118.2(9) . .
O3 C8 Eu1 59.0(5) . 1_655
O4 C8 Eu1 62.5(5) . 1_655
C6 C8 Eu1 178.2(7) . 1_655
O1 C1 O2 119.7(9) . .
O1 C1 C2 121.3(9) . .
O2 C1 C2 118.9(9) . .
O1 C1 Eu1 54.9(5) . .
O2 C1 Eu1 65.1(5) . .
C2 C1 Eu1 175.0(8) . .
C6 C7 C2 119.4(9) . .
C6 C7 H7 120.3 . .
C2 C7 H7 120.3 . .
C4 C5 C6 118.5(11) . .
C4 C5 H5 120.8 . .
C6 C5 H5 120.8 . .
N1 C9 C4 110.1(8) . .
N1 C9 H9A 109.6 . .
C4 C9 H9A 109.6 . .
N1 C9 H9B 109.6 . .
C4 C9 H9B 109.6 . .
H9A C9 H9B 108.1 . .
C12 C13 C14 121.4(11) . .
C12 C13 H13 119.3 . .
C14 C13 H13 119.3 . .
C13 C12 C11 116.3(12) . .
C13 C12 C15 122.4(11) . .
C11 C12 C15 121.3(12) . .
N2 C18 C19 121.7(14) . .
N2 C18 H18 119.1 . .
C19 C18 H18 119.1 . .
C3 C2 C7 120.5(9) . .
C3 C2 C1 122.7(9) . .
C7 C2 C1 116.9(9) . .
N1 C14 C13 120.7(11) . .
N1 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
C7 C6 C5 120.3(9) . .
C7 C6 C8 119.2(9) . .
C5 C6 C8 120.5(8) . .
C19 C15 C16 115.7(12) . .
C19 C15 C12 122.9(13) . .
C16 C15 C12 121.3(11) . .
C4 C3 C2 119.8(11) . .
C4 C3 H3 120.1 . .
C2 C3 H3 120.1 . .
C3 C4 C5 121.6(14) . .
C3 C4 C9 120.0(11) . .
C5 C4 C9 118.4(11) . .
N2 C17 C16 125.3(14) . .
N2 C17 H17 117.3 . .
C16 C17 H17 117.3 . .
Eu1 O1W H1WB 109.4 . .
Eu1 O1W H1WA 109.2 . .
H1WB O1W H1WA 109.5 . .
Eu1 O5 Eu1 107.2(4) 2_557 .
Eu1 O5 H5A 126.4 2_557 .
Eu1 O5 H5A 126.4 . .
C15 C19 C18 121.4(14) . .
C15 C19 H19 119.3 . .
C18 C19 H19 119.3 . .
C10 C11 C12 121.5(12) . .
C10 C11 H11 119.3 . .
C12 C11 H11 119.3 . .
C17 C16 C15 118.5(13) . .
C17 C16 H16 120.8 . .
C15 C16 H16 120.8 . .
O7 N3 O9 123.1(10) . .
O7 N3 O8 120.7(10) . .
O9 N3 O8 116.2(9) . .
N1 C10 C11 118.7(12) . .
N1 C10 H10 120.6 . .
C11 C10 H10 120.6 . .
H2WA O2W H2WB 108.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.328(9) 2_547
Eu1 O5 2.332(8) .
Eu1 O1 2.446(6) .
Eu1 O4 2.449(7) 2_657
Eu1 O2 2.459(8) 2_557
Eu1 O1W 2.488(8) .
Eu1 O3 2.516(6) 1_455
Eu1 O4 2.592(7) 1_455
Eu1 O2 2.669(7) .
Eu1 C8 2.920(10) 1_455
Eu1 C1 2.943(10) .
O1 C1 1.264(12) .
O2 C1 1.288(12) .
O2 Eu1 2.459(8) 2_547
O3 C8 1.250(13) .
O3 Eu1 2.516(6) 1_655
O4 C8 1.279(11) .
O4 Eu1 2.449(7) 2_647
O4 Eu1 2.592(7) 1_655
N1 C14 1.364(13) .
N1 C10 1.369(16) .
N1 C9 1.497(14) .
N2 C18 1.311(19) .
N2 C17 1.332(17) .
C8 C6 1.489(14) .
C8 Eu1 2.920(10) 1_655
C1 C2 1.496(14) .
C7 C6 1.380(13) .
C7 C2 1.410(13) .
C7 H7 0.9500 .
C5 C4 1.388(14) .
C5 C6 1.43(2) .
C5 H5 0.9500 .
C9 C4 1.502(14) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C13 C12 1.376(17) .
C13 C14 1.393(16) .
C13 H13 0.9500 .
C12 C11 1.451(17) .
C12 C15 1.470(19) .
C18 C19 1.432(19) .
C18 H18 0.9500 .
C2 C3 1.39(2) .
C14 H14 0.9500 .
C15 C19 1.349(16) .
C15 C16 1.437(19) .
C3 C4 1.376(14) .
C3 H3 0.9500 .
C17 C16 1.362(18) .
C17 H17 0.9500 .
O1W H1WB 0.8501 .
O1W H1WA 0.8501 .
O5 Eu1 2.328(9) 2_557
O5 H5A 0.9500 .
C19 H19 0.9500 .
C11 C10 1.391(17) .
C11 H11 0.9500 .
O7 N3 1.241(8) .
C16 H16 0.9500 .
N3 O9 1.249(9) .
N3 O8 1.253(9) .
C10 H10 0.9500 .
O2W H2WA 0.8500 .
O2W H2WB 0.8501 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O5 Eu1 O1 C1 53.9(7) 2_547 . . .
O5 Eu1 O1 C1 -159.3(7) . . . .
O4 Eu1 O1 C1 131.7(7) 2_657 . . .
O2 Eu1 O1 C1 131.9(7) 2_557 . . .
O1W Eu1 O1 C1 -81.5(7) . . . .
O3 Eu1 O1 C1 -63.0(9) 1_455 . . .
O4 Eu1 O1 C1 -15.6(7) 1_455 . . .
O2 Eu1 O1 C1 -3.1(6) . . . .
C8 Eu1 O1 C1 -31.3(8) 1_455 . . .
Eu1 Eu1 O1 C1 164.2(7) 2_557 . . .
O5 Eu1 O2 C1 -111.8(7) 2_547 . . .
O5 Eu1 O2 C1 42.8(8) . . . .
O1 Eu1 O2 C1 3.0(6) . . . .
O4 Eu1 O2 C1 -43.2(7) 2_657 . . .
O2 Eu1 O2 C1 -118.6(7) 2_557 . . .
O1W Eu1 O2 C1 87.8(6) . . . .
O3 Eu1 O2 C1 154.6(6) 1_455 . . .
O4 Eu1 O2 C1 169.5(7) 1_455 . . .
C8 Eu1 O2 C1 162.7(7) 1_455 . . .
Eu1 Eu1 O2 C1 -23.2(8) 2_557 . . .
O5 Eu1 O2 Eu1 31.9(3) 2_547 . . 2_547
O5 Eu1 O2 Eu1 -173.5(4) . . . 2_547
O1 Eu1 O2 Eu1 146.7(4) . . . 2_547
O4 Eu1 O2 Eu1 100.6(3) 2_657 . . 2_547
O2 Eu1 O2 Eu1 25.2(3) 2_557 . . 2_547
O1W Eu1 O2 Eu1 -128.4(3) . . . 2_547
O3 Eu1 O2 Eu1 -61.6(3) 1_455 . . 2_547
O4 Eu1 O2 Eu1 -46.8(2) 1_455 . . 2_547
C8 Eu1 O2 Eu1 -53.5(3) 1_455 . . 2_547
C1 Eu1 O2 Eu1 143.8(7) . . . 2_547
Eu1 Eu1 O2 Eu1 120.6(3) 2_557 . . 2_547
Eu1 O3 C8 O4 -4.6(11) 1_655 . . .
Eu1 O3 C8 C6 178.0(9) 1_655 . . .
Eu1 O4 C8 O3 108.4(13) 2_647 . . .
Eu1 O4 C8 O3 4.5(11) 1_655 . . .
Eu1 O4 C8 C6 -74.3(16) 2_647 . . .
Eu1 O4 C8 C6 -178.1(9) 1_655 . . .
Eu1 O4 C8 Eu1 103.9(12) 2_647 . . 1_655
Eu1 O1 C1 O2 5.7(12) . . . .
Eu1 O1 C1 C2 -176.1(9) . . . .
Eu1 O2 C1 O1 -100.4(13) 2_547 . . .
Eu1 O2 C1 O1 -5.1(11) . . . .
Eu1 O2 C1 C2 81.4(14) 2_547 . . .
Eu1 O2 C1 C2 176.6(9) . . . .
Eu1 O2 C1 Eu1 -95.2(10) 2_547 . . .
O5 Eu1 C1 O1 -124.6(7) 2_547 . . .
O5 Eu1 C1 O1 23.9(8) . . . .
O4 Eu1 C1 O1 -45.5(7) 2_657 . . .
O2 Eu1 C1 O1 -80.4(9) 2_557 . . .
O1W Eu1 C1 O1 91.0(7) . . . .
O3 Eu1 C1 O1 141.3(6) 1_455 . . .
O4 Eu1 C1 O1 165.3(7) 1_455 . . .
O2 Eu1 C1 O1 174.5(11) . . . .
C8 Eu1 C1 O1 156.0(6) 1_455 . . .
Eu1 Eu1 C1 O1 -19.2(8) 2_557 . . .
O5 Eu1 C1 O2 60.8(6) 2_547 . . .
O5 Eu1 C1 O2 -150.6(6) . . . .
O1 Eu1 C1 O2 -174.5(11) . . . .
O4 Eu1 C1 O2 139.9(6) 2_657 . . .
O2 Eu1 C1 O2 105.0(7) 2_557 . . .
O1W Eu1 C1 O2 -83.6(6) . . . .
O3 Eu1 C1 O2 -33.2(8) 1_455 . . .
O4 Eu1 C1 O2 -9.2(6) 1_455 . . .
C8 Eu1 C1 O2 -18.5(7) 1_455 . . .
Eu1 Eu1 C1 O2 166.2(5) 2_557 . . .
C14 N1 C9 C4 100.7(11) . . . .
C10 N1 C9 C4 -78.9(12) . . . .
C14 C13 C12 C11 -1.5(18) . . . .
C14 C13 C12 C15 179.8(11) . . . .
C17 N2 C18 C19 1(2) . . . .
C6 C7 C2 C3 -1.3(15) . . . .
C6 C7 C2 C1 178.3(9) . . . .
O1 C1 C2 C3 -159.0(11) . . . .
O2 C1 C2 C3 19.3(16) . . . .
O1 C1 C2 C7 21.4(15) . . . .
O2 C1 C2 C7 -160.3(10) . . . .
C10 N1 C14 C13 1.9(17) . . . .
C9 N1 C14 C13 -177.7(10) . . . .
C12 C13 C14 N1 -0.3(19) . . . .
C2 C7 C6 C5 0.8(15) . . . .
C2 C7 C6 C8 178.2(10) . . . .
C4 C5 C6 C7 1.1(15) . . . .
C4 C5 C6 C8 -176.3(10) . . . .
O3 C8 C6 C7 -20.9(15) . . . .
O4 C8 C6 C7 161.6(10) . . . .
O3 C8 C6 C5 156.5(10) . . . .
O4 C8 C6 C5 -21.0(15) . . . .
C13 C12 C15 C19 -32(2) . . . .
C11 C12 C15 C19 149.1(14) . . . .
C13 C12 C15 C16 144.7(14) . . . .
C11 C12 C15 C16 -34.0(18) . . . .
C7 C2 C3 C4 -0.1(15) . . . .
C1 C2 C3 C4 -179.7(10) . . . .
C2 C3 C4 C5 2.2(16) . . . .
C2 C3 C4 C9 -178.3(10) . . . .
C6 C5 C4 C3 -2.7(16) . . . .
C6 C5 C4 C9 177.8(9) . . . .
N1 C9 C4 C3 117.3(10) . . . .
N1 C9 C4 C5 -63.2(13) . . . .
C18 N2 C17 C16 -3(2) . . . .
O5 Eu1 O5 Eu1 4.7(2) 2_547 . . 2_557
O1 Eu1 O5 Eu1 -101.2(3) . . . 2_557
O4 Eu1 O5 Eu1 -31.6(3) 2_657 . . 2_557
O2 Eu1 O5 Eu1 38.1(3) 2_557 . . 2_557
O1W Eu1 O5 Eu1 -174.2(3) . . . 2_557
O3 Eu1 O5 Eu1 109.7(3) 1_455 . . 2_557
O4 Eu1 O5 Eu1 130.6(3) 1_455 . . 2_557
O2 Eu1 O5 Eu1 -131.2(4) . . . 2_557
C8 Eu1 O5 Eu1 117.1(3) 1_455 . . 2_557
C1 Eu1 O5 Eu1 -111.2(4) . . . 2_557
C16 C15 C19 C18 2(2) . . . .
C12 C15 C19 C18 178.9(12) . . . .
N2 C18 C19 C15 0(2) . . . .
C13 C12 C11 C10 1.9(19) . . . .
C15 C12 C11 C10 -179.4(12) . . . .
N2 C17 C16 C15 5(2) . . . .
C19 C15 C16 C17 -4.1(19) . . . .
C12 C15 C16 C17 178.8(12) . . . .
C14 N1 C10 C11 -1.4(18) . . . .
C9 N1 C10 C11 178.2(11) . . . .
C12 C11 C10 N1 -0.5(19) . . . .
