#------------------------------------------------------------------------------
#$Date: 2018-08-16 13:20:49 +0300 (Thu, 16 Aug 2018) $
#$Revision: 209786 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/84/7118473.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7118473
loop_
_publ_author_name
'Chitnis, Saurabh S.'
'Vos, Kevin A.'
'Burford, Neil'
'McDonald, Robert'
'Ferguson, Michael J.'
_publ_section_title
;
 Distinction between coordination and phosphine ligand oxidation:
 interactions of di- and triphosphines with Pn³⁺ (Pn = P, As, Sb, Bi)
;
_journal_coden_ASTM              CHCOFS
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              685
_journal_page_last               688
_journal_paper_doi               10.1039/c5cc08086j
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C29 H24 F9 O9 P2 S3 Sb'
_chemical_formula_sum            'C29 H24 F9 O9 P2 S3 Sb'
_chemical_formula_weight         967.35
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-08-08 deposited with the CCDC.
2015-11-11 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.9604(15)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.3718(4)
_cell_length_b                   17.5496(6)
_cell_length_c                   15.4871(5)
_cell_measurement_reflns_used    9853
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      74.06
_cell_measurement_theta_min      3.86
_cell_volume                     3541.8(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT-2014 (Sheldrick, 2015)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0514
_diffrn_reflns_av_unetI/netI     0.0434
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24895
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         74.213
_diffrn_reflns_theta_min         3.863
_exptl_absorpt_coefficient_mu    9.601
_exptl_absorpt_correction_T_max  0.7029
_exptl_absorpt_correction_T_min  0.3990
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.814
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1920
_exptl_crystal_size_max          0.178
_exptl_crystal_size_mid          0.075
_exptl_crystal_size_min          0.068
_refine_diff_density_max         1.686
_refine_diff_density_min         -1.542
_refine_diff_density_rms         0.121
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     536
_refine_ls_number_reflns         7200
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0481
_refine_ls_R_factor_gt           0.0416
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0637P)²+4.2404P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1055
_refine_ls_wR_factor_ref         0.1119
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6370
_reflns_number_total             7200
_reflns_threshold_expression     'I > 2σ(I)'
_cod_duplicate_entry             7118193
_cod_data_source_file            c5cc08086j2.cif
_cod_data_source_block           vic1501
_cod_database_code               7118473
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.280
_shelx_estimated_absorpt_t_max   0.561
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb Sb 0.37189(2) 0.43331(2) 0.32863(2) 0.02466(9) Uani 1 1 d . . . . .
S1 S 0.14799(6) 0.50751(5) 0.22061(6) 0.02784(18) Uani 1 1 d . . . . .
S2 S 0.60620(7) 0.42164(6) 0.45450(7) 0.0345(2) Uani 1 1 d . . . . .
S3A S 0.47322(17) 0.57199(10) 0.18664(15) 0.0398(5) Uani 0.6 1 d . . P A 1
S3B S 0.5183(3) 0.57501(16) 0.2264(3) 0.0472(7) Uani 0.4 1 d . . P A 2
P1 P 0.28385(6) 0.31241(5) 0.38580(5) 0.02289(17) Uani 1 1 d . . . . .
P2 P 0.38025(6) 0.33361(5) 0.20403(5) 0.02474(17) Uani 1 1 d . . . . .
F1 F 0.0172(2) 0.58938(16) 0.28057(19) 0.0538(7) Uani 1 1 d . . . . .
F2 F 0.0007(2) 0.46890(18) 0.2971(2) 0.0684(9) Uani 1 1 d . . . . .
F3 F 0.1249(3) 0.5286(2) 0.38121(18) 0.0718(10) Uani 1 1 d . . . . .
F4 F 0.7901(2) 0.44849(17) 0.4345(2) 0.0582(8) Uani 1 1 d . . . . .
F5 F 0.73898(19) 0.33384(15) 0.40269(19) 0.0497(6) Uani 1 1 d . . . . .
F6 F 0.6821(2) 0.42444(16) 0.31182(19) 0.0511(6) Uani 1 1 d . . . . .
F7A F 0.6311(8) 0.6513(6) 0.1603(7) 0.092(3) Uani 0.6 1 d . . P A 1
F8A F 0.6535(14) 0.5350(10) 0.1638(12) 0.138(8) Uani 0.6 1 d . . P A 1
F9A F 0.6583(5) 0.5919(5) 0.2865(5) 0.083(2) Uani 0.6 1 d . . P A 1
F7B F 0.6152(11) 0.6356(8) 0.1189(8) 0.061(3) Uani 0.4 1 d . . P A 2
F8B F 0.6722(13) 0.5220(10) 0.1725(8) 0.054(3) Uani 0.4 1 d . . P A 2
F9B F 0.5432(10) 0.5341(5) 0.0717(5) 0.079(3) Uani 0.4 1 d . . P A 2
O1 O 0.19855(19) 0.43401(13) 0.25255(17) 0.0291(5) Uani 1 1 d . . . . .
O2 O 0.2192(2) 0.56974(16) 0.2340(2) 0.0447(7) Uani 1 1 d . . . . .
O3 O 0.0775(2) 0.50152(17) 0.13727(18) 0.0412(6) Uani 1 1 d . . . . .
O4 O 0.51884(18) 0.38006(15) 0.39458(17) 0.0317(5) Uani 1 1 d . . . . .
O5 O 0.5905(2) 0.50223(17) 0.4545(2) 0.0465(7) Uani 1 1 d . . . . .
O6 O 0.6396(2) 0.3838(2) 0.5374(2) 0.0486(7) Uani 1 1 d . . . . .
O7 O 0.4757(3) 0.49607(17) 0.2288(2) 0.0457(7) Uani 1 1 d . . . . .
O8A O 0.4444(16) 0.6338(10) 0.2348(14) 0.095(6) Uani 0.6 1 d . . P A 1
O9A O 0.4329(10) 0.5760(6) 0.0963(6) 0.139(6) Uani 0.6 1 d . . P A 1
O8B O 0.439(3) 0.6226(16) 0.195(2) 0.095(6) Uani 0.4 1 d . . P A 2
O9B O 0.5922(14) 0.6038(8) 0.3010(8) 0.093(5) Uani 0.4 1 d . . P A 2
C1 C 0.2458(3) 0.2556(2) 0.2858(2) 0.0266(7) Uani 1 1 d . . . . .
H1A H 0.2197 0.2055 0.3003 0.032 Uiso 1 1 calc R U . . .
H1B H 0.1902 0.2818 0.2431 0.032 Uiso 1 1 calc R U . . .
C2 C 0.3387(3) 0.2442(2) 0.2444(2) 0.0283(7) Uani 1 1 d . . . . .
H2A H 0.3205 0.2077 0.1946 0.034 Uiso 1 1 calc R U . . .
H2B H 0.3960 0.2221 0.2891 0.034 Uiso 1 1 calc R U . . .
C10 C 0.0680(3) 0.5235(2) 0.2996(3) 0.0401(9) Uani 1 1 d . . . . .
C11 C 0.1718(3) 0.33269(19) 0.4278(2) 0.0260(6) Uani 1 1 d . . . . .
C12 C 0.1817(3) 0.3799(2) 0.5011(3) 0.0363(8) Uani 1 1 d . . . . .
H12 H 0.2453 0.4043 0.5252 0.044 Uiso 1 1 calc R U . . .
C13 C 0.0977(3) 0.3912(3) 0.5389(3) 0.0420(9) Uani 1 1 d . . . . .
H13 H 0.1037 0.4236 0.5890 0.050 Uiso 1 1 calc R U . . .
C14 C 0.0054(3) 0.3552(3) 0.5035(3) 0.0421(9) Uani 1 1 d . . . . .
H14 H -0.0515 0.3625 0.5299 0.051 Uiso 1 1 calc R U . . .
C15 C -0.0044(3) 0.3091(3) 0.4308(3) 0.0455(10) Uani 1 1 d . . . . .
H15 H -0.0682 0.2850 0.4068 0.055 Uiso 1 1 calc R U . . .
C16 C 0.0788(3) 0.2974(2) 0.3918(3) 0.0365(8) Uani 1 1 d . . . . .
H16 H 0.0719 0.2657 0.3411 0.044 Uiso 1 1 calc R U . . .
C20 C 0.7100(3) 0.4065(3) 0.3964(3) 0.0400(9) Uani 1 1 d . . . . .
C21 C 0.3667(3) 0.2553(2) 0.4686(2) 0.0254(7) Uani 1 1 d . . . . .
C22 C 0.4236(3) 0.2914(2) 0.5440(2) 0.0310(7) Uani 1 1 d . . . . .
H22 H 0.4239 0.3454 0.5479 0.037 Uiso 1 1 calc R U . . .
C23 C 0.4798(3) 0.2484(3) 0.6134(3) 0.0401(9) Uani 1 1 d . . . . .
H23 H 0.5177 0.2729 0.6652 0.048 Uiso 1 1 calc R U . . .
C24 C 0.4803(3) 0.1700(3) 0.6067(3) 0.0432(10) Uani 1 1 d . . . . .
H24 H 0.5186 0.1407 0.6544 0.052 Uiso 1 1 calc R U . . .
C25 C 0.4259(3) 0.1332(2) 0.5314(3) 0.0394(9) Uani 1 1 d . . . . .
H25 H 0.4283 0.0792 0.5272 0.047 Uiso 1 1 calc R U . . .
C26 C 0.3680(3) 0.1756(2) 0.4624(2) 0.0319(7) Uani 1 1 d . . . . .
H26 H 0.3293 0.1507 0.4112 0.038 Uiso 1 1 calc R U . . .
C30A C 0.6142(8) 0.5867(5) 0.2041(8) 0.058(2) Uani 0.6 1 d . . P A 1
C30B C 0.5922(9) 0.5682(7) 0.1439(9) 0.040(2) Uani 0.4 1 d . . P A 2
C31 C 0.5045(3) 0.3165(2) 0.1808(2) 0.0286(7) Uani 1 1 d . . . . .
C32 C 0.5311(3) 0.3510(3) 0.1081(3) 0.0385(9) Uani 1 1 d . . . . .
H32 H 0.4846 0.3846 0.0711 0.046 Uiso 1 1 calc R U . . .
C33 C 0.6260(4) 0.3355(3) 0.0903(3) 0.0492(11) Uani 1 1 d . . . . .
H33 H 0.6448 0.3593 0.0412 0.059 Uiso 1 1 calc R U . . .
C34 C 0.6935(4) 0.2865(3) 0.1425(3) 0.0505(11) Uani 1 1 d . . . . .
H34 H 0.7580 0.2760 0.1290 0.061 Uiso 1 1 calc R U . . .
C35 C 0.6673(3) 0.2521(3) 0.2150(3) 0.0477(11) Uani 1 1 d . . . . .
H35 H 0.7141 0.2182 0.2512 0.057 Uiso 1 1 calc R U . . .
C36 C 0.5735(3) 0.2669(2) 0.2349(3) 0.0381(8) Uani 1 1 d . . . . .
H36 H 0.5559 0.2437 0.2848 0.046 Uiso 1 1 calc R U . . .
C41 C 0.2898(3) 0.3573(2) 0.1020(2) 0.0320(7) Uani 1 1 d . . . . .
C42 C 0.2886(4) 0.4307(3) 0.0676(3) 0.0458(10) Uani 1 1 d . . . . .
H42 H 0.3332 0.4690 0.0979 0.055 Uiso 1 1 calc R U . . .
C43 C 0.2202(5) 0.4465(4) -0.0123(3) 0.0650(17) Uani 1 1 d . . . . .
H43 H 0.2191 0.4961 -0.0371 0.078 Uiso 1 1 calc R U . . .
C44 C 0.1540(4) 0.3914(4) -0.0562(3) 0.0667(17) Uani 1 1 d . . . . .
H44 H 0.1076 0.4033 -0.1106 0.080 Uiso 1 1 calc R U . . .
C45 C 0.1554(4) 0.3199(4) -0.0213(3) 0.0628(15) Uani 1 1 d . . . . .
H45 H 0.1093 0.2823 -0.0512 0.075 Uiso 1 1 calc R U . . .
C46 C 0.2235(3) 0.3018(3) 0.0574(3) 0.0456(10) Uani 1 1 d . . . . .
H46 H 0.2250 0.2517 0.0809 0.055 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.0562 5.8946 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Sb O1 155.26(9) . .
O4 Sb O7 85.09(10) . .
O1 Sb O7 107.66(10) . .
O4 Sb P2 82.98(7) . .
O1 Sb P2 80.50(6) . .
O7 Sb P2 73.95(7) . .
O4 Sb P1 85.60(7) . .
O1 Sb P1 73.28(6) . .
O7 Sb P1 152.23(7) . .
P2 Sb P1 78.98(3) . .
O3 S1 O2 118.15(19) . .
O3 S1 O1 113.39(16) . .
O2 S1 O1 112.00(16) . .
O3 S1 C10 104.6(2) . .
O2 S1 C10 104.9(2) . .
O1 S1 C10 101.67(17) . .
O6 S2 O5 118.5(2) . .
O6 S2 O4 111.85(18) . .
O5 S2 O4 112.64(17) . .
O6 S2 C20 104.8(2) . .
O5 S2 C20 105.7(2) . .
O4 S2 C20 101.24(17) . .
O9A S3A O8A 113.8(12) . .
O9A S3A O7 117.2(4) . .
O8A S3A O7 116.0(10) . .
O9A S3A C30A 107.0(7) . .
O8A S3A C30A 101.7(9) . .
O7 S3A C30A 98.0(4) . .
O8B S3B O9B 114.4(12) . .
O8B S3B O7 107.8(13) . .
O9B S3B O7 120.1(6) . .
O8B S3B C30B 107.6(15) . .
O9B S3B C30B 102.0(8) . .
O7 S3B C30B 103.3(5) . .
C11 P1 C21 106.39(15) . .
C11 P1 C1 108.70(16) . .
C21 P1 C1 108.18(16) . .
C11 P1 Sb 115.32(11) . .
C21 P1 Sb 115.57(12) . .
C1 P1 Sb 102.30(11) . .
C31 P2 C41 109.23(16) . .
C31 P2 C2 106.93(17) . .
C41 P2 C2 107.58(18) . .
C31 P2 Sb 116.77(12) . .
C41 P2 Sb 111.00(12) . .
C2 P2 Sb 104.80(11) . .
S1 O1 Sb 119.60(14) . .
S2 O4 Sb 124.49(15) . .
S3A O7 Sb 134.07(19) . .
S3B O7 Sb 132.5(2) . .
C2 C1 P1 109.3(2) . .
C1 C2 P2 111.7(2) . .
F2 C10 F3 108.8(4) . .
F2 C10 F1 108.3(4) . .
F3 C10 F1 107.9(4) . .
F2 C10 S1 111.7(3) . .
F3 C10 S1 110.7(3) . .
F1 C10 S1 109.3(3) . .
C12 C11 C16 120.5(3) . .
C12 C11 P1 118.7(3) . .
C16 C11 P1 120.7(3) . .
C11 C12 C13 119.4(4) . .
C14 C13 C12 119.9(4) . .
C15 C14 C13 120.5(4) . .
C14 C15 C16 120.3(4) . .
C11 C16 C15 119.3(4) . .
F6 C20 F4 109.3(4) . .
F6 C20 F5 108.4(4) . .
F4 C20 F5 107.9(3) . .
F6 C20 S2 112.1(3) . .
F4 C20 S2 109.0(3) . .
F5 C20 S2 110.1(3) . .
C22 C21 C26 119.8(3) . .
C22 C21 P1 118.5(3) . .
C26 C21 P1 121.4(3) . .
C23 C22 C21 120.0(4) . .
C24 C23 C22 119.6(4) . .
C23 C24 C25 121.1(4) . .
C24 C25 C26 119.6(4) . .
C25 C26 C21 119.7(3) . .
F8A C30A F9A 112.8(13) . .
F8A C30A F7A 102.4(11) . .
F9A C30A F7A 110.2(9) . .
F8A C30A S3A 110.1(12) . .
F9A C30A S3A 112.2(7) . .
F7A C30A S3A 108.5(8) . .
F7B C30B F9B 105.5(10) . .
F7B C30B F8B 115.2(14) . .
F9B C30B F8B 102.5(13) . .
F7B C30B S3B 111.0(11) . .
F9B C30B S3B 113.0(9) . .
F8B C30B S3B 109.5(10) . .
C32 C31 C36 119.9(4) . .
C32 C31 P2 120.2(3) . .
C36 C31 P2 119.8(3) . .
C33 C32 C31 119.2(4) . .
C34 C33 C32 121.1(4) . .
C33 C34 C35 119.9(4) . .
C36 C35 C34 120.3(4) . .
C35 C36 C31 119.6(4) . .
C46 C41 C42 120.4(4) . .
C46 C41 P2 119.9(3) . .
C42 C41 P2 119.7(3) . .
C43 C42 C41 118.3(5) . .
C44 C43 C42 121.2(5) . .
C45 C44 C43 119.8(4) . .
C44 C45 C46 120.5(6) . .
C45 C46 C41 119.7(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb O4 2.208(2) .
Sb O1 2.353(3) .
Sb O7 2.548(3) .
Sb P2 2.6257(9) .
Sb P1 2.6718(8) .
S1 O3 1.421(3) .
S1 O2 1.433(3) .
S1 O1 1.489(2) .
S1 C10 1.819(4) .
S2 O6 1.425(3) .
S2 O5 1.430(3) .
S2 O4 1.507(3) .
S2 C20 1.835(4) .
S3A O9A 1.384(8) .
S3A O8A 1.417(10) .
S3A O7 1.481(3) .
S3A C30A 1.862(10) .
S3B O8B 1.35(4) .
S3B O9B 1.432(14) .
S3B O7 1.502(4) .
S3B C30B 1.785(13) .
P1 C11 1.798(3) .
P1 C21 1.800(3) .
P1 C1 1.816(3) .
P2 C31 1.801(4) .
P2 C41 1.810(4) .
P2 C2 1.821(4) .
F1 C10 1.339(5) .
F2 C10 1.309(5) .
F3 C10 1.323(5) .
F4 C20 1.325(5) .
F5 C20 1.330(5) .
F6 C20 1.317(5) .
F7A C30A 1.366(13) .
F8A C30A 1.28(2) .
F9A C30A 1.283(14) .
F7B C30B 1.302(17) .
F8B C30B 1.336(19) .
F9B C30B 1.308(17) .
C1 C2 1.533(5) .
C11 C12 1.387(5) .
C11 C16 1.389(5) .
C12 C13 1.393(5) .
C13 C14 1.386(6) .
C14 C15 1.368(6) .
C15 C16 1.396(5) .
C21 C22 1.395(5) .
C21 C26 1.403(5) .
C22 C23 1.387(5) .
C23 C24 1.381(6) .
C24 C25 1.387(6) .
C25 C26 1.387(5) .
C31 C32 1.393(5) .
C31 C36 1.402(5) .
C32 C33 1.385(6) .
C33 C34 1.371(7) .
C34 C35 1.388(7) .
C35 C36 1.382(6) .
C41 C46 1.392(6) .
C41 C42 1.392(6) .
C42 C43 1.391(7) .
C43 C44 1.382(10) .
C44 C45 1.365(9) .
C45 C46 1.386(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O3 S1 O1 Sb 142.92(18) . . . .
O2 S1 O1 Sb 6.1(2) . . . .
C10 S1 O1 Sb -105.4(2) . . . .
O6 S2 O4 Sb 127.8(2) . . . .
O5 S2 O4 Sb -8.6(3) . . . .
C20 S2 O4 Sb -121.0(2) . . . .
O9A S3A O7 Sb -106.0(8) . . . .
O8A S3A O7 Sb 32.9(10) . . . .
C30A S3A O7 Sb 140.2(4) . . . .
O8B S3B O7 Sb -72.1(14) . . . .
O9B S3B O7 Sb 61.4(9) . . . .
C30B S3B O7 Sb 174.1(5) . . . .
C11 P1 C1 C2 174.7(2) . . . .
C21 P1 C1 C2 -70.1(3) . . . .
Sb P1 C1 C2 52.3(2) . . . .
P1 C1 C2 P2 -66.4(3) . . . .
C31 P2 C2 C1 167.2(2) . . . .
C41 P2 C2 C1 -75.5(3) . . . .
Sb P2 C2 C1 42.7(2) . . . .
O3 S1 C10 F2 57.3(3) . . . .
O2 S1 C10 F2 -177.7(3) . . . .
O1 S1 C10 F2 -60.9(3) . . . .
O3 S1 C10 F3 178.7(3) . . . .
O2 S1 C10 F3 -56.3(3) . . . .
O1 S1 C10 F3 60.5(3) . . . .
O3 S1 C10 F1 -62.6(4) . . . .
O2 S1 C10 F1 62.4(4) . . . .
O1 S1 C10 F1 179.2(3) . . . .
C21 P1 C11 C12 67.9(3) . . . .
C1 P1 C11 C12 -175.8(3) . . . .
Sb P1 C11 C12 -61.6(3) . . . .
C21 P1 C11 C16 -107.4(3) . . . .
C1 P1 C11 C16 8.9(4) . . . .
Sb P1 C11 C16 123.0(3) . . . .
C16 C11 C12 C13 0.6(6) . . . .
P1 C11 C12 C13 -174.8(3) . . . .
C11 C12 C13 C14 0.3(7) . . . .
C12 C13 C14 C15 -0.8(7) . . . .
C13 C14 C15 C16 0.5(7) . . . .
C12 C11 C16 C15 -0.9(6) . . . .
P1 C11 C16 C15 174.4(3) . . . .
C14 C15 C16 C11 0.4(7) . . . .
O6 S2 C20 F6 167.0(3) . . . .
O5 S2 C20 F6 -67.1(3) . . . .
O4 S2 C20 F6 50.6(3) . . . .
O6 S2 C20 F4 -71.9(4) . . . .
O5 S2 C20 F4 54.1(4) . . . .
O4 S2 C20 F4 171.7(3) . . . .
O6 S2 C20 F5 46.3(3) . . . .
O5 S2 C20 F5 172.2(3) . . . .
O4 S2 C20 F5 -70.1(3) . . . .
C11 P1 C21 C22 -77.3(3) . . . .
C1 P1 C21 C22 166.0(3) . . . .
Sb P1 C21 C22 52.1(3) . . . .
C11 P1 C21 C26 96.9(3) . . . .
C1 P1 C21 C26 -19.7(3) . . . .
Sb P1 C21 C26 -133.6(3) . . . .
C26 C21 C22 C23 -1.2(6) . . . .
P1 C21 C22 C23 173.2(3) . . . .
C21 C22 C23 C24 1.1(6) . . . .
C22 C23 C24 C25 0.3(7) . . . .
C23 C24 C25 C26 -1.5(7) . . . .
C24 C25 C26 C21 1.3(6) . . . .
C22 C21 C26 C25 0.0(6) . . . .
P1 C21 C26 C25 -174.2(3) . . . .
O9A S3A C30A F8A -60.1(12) . . . .
O8A S3A C30A F8A -179.6(14) . . . .
O7 S3A C30A F8A 61.6(11) . . . .
O9A S3A C30A F9A 173.3(8) . . . .
O8A S3A C30A F9A 53.8(13) . . . .
O7 S3A C30A F9A -65.0(7) . . . .
O9A S3A C30A F7A 51.3(10) . . . .
O8A S3A C30A F7A -68.3(14) . . . .
O7 S3A C30A F7A 173.0(8) . . . .
O8B S3B C30B F7B 51.3(16) . . . .
O9B S3B C30B F7B -69.5(12) . . . .
O7 S3B C30B F7B 165.2(10) . . . .
O8B S3B C30B F9B -67.0(15) . . . .
O9B S3B C30B F9B 172.2(10) . . . .
O7 S3B C30B F9B 46.9(9) . . . .
O8B S3B C30B F8B 179.5(16) . . . .
O9B S3B C30B F8B 58.7(14) . . . .
O7 S3B C30B F8B -66.6(13) . . . .
C41 P2 C31 C32 26.5(4) . . . .
C2 P2 C31 C32 142.7(3) . . . .
Sb P2 C31 C32 -100.4(3) . . . .
C41 P2 C31 C36 -151.8(3) . . . .
C2 P2 C31 C36 -35.7(4) . . . .
Sb P2 C31 C36 81.2(3) . . . .
C36 C31 C32 C33 -0.1(6) . . . .
P2 C31 C32 C33 -178.4(3) . . . .
C31 C32 C33 C34 0.7(7) . . . .
C32 C33 C34 C35 -0.8(7) . . . .
C33 C34 C35 C36 0.1(7) . . . .
C34 C35 C36 C31 0.5(7) . . . .
C32 C31 C36 C35 -0.5(6) . . . .
P2 C31 C36 C35 177.8(3) . . . .
C31 P2 C41 C46 99.4(3) . . . .
C2 P2 C41 C46 -16.3(4) . . . .
Sb P2 C41 C46 -130.5(3) . . . .
C31 P2 C41 C42 -79.2(4) . . . .
C2 P2 C41 C42 165.0(3) . . . .
Sb P2 C41 C42 50.9(3) . . . .
C46 C41 C42 C43 -0.5(6) . . . .
P2 C41 C42 C43 178.1(3) . . . .
C41 C42 C43 C44 0.9(7) . . . .
C42 C43 C44 C45 -0.3(8) . . . .
C43 C44 C45 C46 -0.7(8) . . . .
C44 C45 C46 C41 1.1(8) . . . .
C42 C41 C46 C45 -0.5(7) . . . .
P2 C41 C46 C45 -179.1(4) . . . .
