#------------------------------------------------------------------------------
#$Date: 2016-03-05 10:07:15 +0200 (Sat, 05 Mar 2016) $
#$Revision: 177676 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/86/7118683.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7118683
loop_
_publ_author_name
'Khan, Shabana'
'Pal, Shiv'
'Kathewad, Neha'
'Purushothaman, Indu'
'De, Susmita'
'Parameswaran, Pattiyil'
_publ_section_title
;
 Stepwise isolation of an unprecedented silylene supported dinuclear
 gold(i) cation with aurophilic interaction.
;
_journal_issue                   20
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3880
_journal_page_last               3882
_journal_paper_doi               10.1039/c6cc00597g
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C80 H104 Au2 Cl4 F12 N6 P2 Sb2 Si2'
_chemical_formula_sum            'C80 H104 Au2 Cl4 F12 N6 P2 Sb2 Si2'
_chemical_formula_weight         2275.04
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2015-11-13 deposited with the CCDC.
2016-02-02 downloaded from the CCDC.
;
_cell_angle_alpha                116.997(14)
_cell_angle_beta                 104.713(14)
_cell_angle_gamma                95.716(14)
_cell_formula_units_Z            1
_cell_length_a                   12.058(6)
_cell_length_b                   14.762(9)
_cell_length_c                   15.001(9)
_cell_measurement_reflns_used    9404
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.005
_cell_measurement_theta_min      2.351
_cell_volume                     2229(2)
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.891
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART X2S benchtop diffractometer'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2448
_diffrn_reflns_av_unetI/netI     0.0971
_diffrn_reflns_laue_measured_fraction_full 0.891
_diffrn_reflns_laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            89255
_diffrn_reflns_point_group_measured_fraction_full 0.891
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         24.248
_diffrn_reflns_theta_min         2.306
_exptl_absorpt_coefficient_mu    4.133
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Sheldrick,G.M.(2012)SADABS.BrukerAXS Inc.,Madison, Wisconsin, USA.'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.695
_exptl_crystal_description       block
_exptl_crystal_F_000             1120
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   0.1525
_exptl_transmission_factor_min   0.1129
_refine_diff_density_max         1.321
_refine_diff_density_min         -1.030
_refine_diff_density_rms         0.176
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     494
_refine_ls_number_reflns         7185
_refine_ls_number_restraints     90
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0571
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0344P)²+19.4861P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1046
_refine_ls_wR_factor_ref         0.1210
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5264
_reflns_number_total             7185
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6cc00597g2.cif
_cod_data_source_block           SINP_4
_cod_depositor_comments
'Adding full bibliography for 7118681--7118683.cif.'
_cod_original_cell_volume        2228(2)
_cod_database_code               7118683
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2014/6
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C7 C 0.7168(4) 0.7703(5) 0.7094(4) 0.026(2) Uani 1 1 d G .
C2 C 0.6343(5) 0.8300(4) 0.7263(4) 0.031(2) Uani 1 1 d G .
C3 C 0.5291(5) 0.8019(5) 0.6443(6) 0.043(3) Uani 1 1 d G .
H3 H 0.4727 0.8427 0.6558 0.052 Uiso 1 1 calc R U
C4 C 0.5064(5) 0.7140(6) 0.5455(5) 0.053(3) Uani 1 1 d G .
H4 H 0.4345 0.6948 0.4895 0.063 Uiso 1 1 calc R U
C5 C 0.5890(6) 0.6543(5) 0.5287(4) 0.046(3) Uani 1 1 d G .
H5 H 0.5735 0.5943 0.4611 0.055 Uiso 1 1 calc R U
C6 C 0.6942(5) 0.6824(5) 0.6106(5) 0.035(3) Uani 1 1 d G .
C1 C 1.0374(9) 0.8340(7) 0.6581(8) 0.030(2) Uani 1 1 d . .
C8 C 0.9202(9) 0.7121(7) 0.9210(7) 0.028(2) Uani 1 1 d . .
C9 C 1.0324(10) 0.7511(9) 0.9948(9) 0.044(3) Uani 1 1 d . .
H9 H 1.0648 0.8248 1.0361 0.053 Uiso 1 1 calc R U
C10 C 0.8742(10) 0.6037(8) 0.8612(9) 0.042(3) Uani 1 1 d . .
H10 H 0.7973 0.5750 0.8091 0.051 Uiso 1 1 calc R U
C11 C 1.1521(9) 0.7475(8) 0.7548(8) 0.034(3) Uani 1 1 d . .
C12 C 1.1169(9) 0.8438(9) 0.5992(9) 0.038(3) Uani 1 1 d . .
C13 C 0.4928(10) 0.6741(11) 0.9277(11) 0.057(4) Uani 1 1 d . .
H13 H 0.4244 0.6456 0.9360 0.069 Uiso 1 1 calc R U
C14 C 1.2092(10) 0.9312(9) 0.6512(10) 0.044(3) Uani 1 1 d . .
H14 H 1.2194 0.9830 0.7218 0.053 Uiso 1 1 calc R U
C15 C 0.7789(10) 0.6116(8) 0.5875(9) 0.043(3) Uani 1 1 d . .
H15 H 0.8523 0.6451 0.6514 0.052 Uiso 1 1 calc R U
C16 C 1.2305(10) 0.8241(10) 0.8662(10) 0.058(4) Uani 1 1 d . .
H16A H 1.1838 0.8397 0.9137 0.086 Uiso 1 1 calc R U
H16B H 1.2657 0.8889 0.8697 0.086 Uiso 1 1 calc R U
H16C H 1.2936 0.7938 0.8881 0.086 Uiso 1 1 calc R U
C17 C 1.0532(11) 0.5787(10) 0.9523(10) 0.055(3) Uani 1 1 d . U
H17 H 1.0987 0.5334 0.9633 0.066 Uiso 1 1 calc R U
C18 C 0.6113(9) 0.6658(8) 0.8217(9) 0.038(3) Uani 1 1 d . .
H18 H 0.6235 0.6317 0.7553 0.046 Uiso 1 1 calc R U
C19 C 0.5112(10) 0.6253(10) 0.8327(11) 0.051(3) Uani 1 1 d . .
H19 H 0.4552 0.5636 0.7745 0.061 Uiso 1 1 calc R U
C20 C 0.6497(9) 0.9285(8) 0.8320(9) 0.039(3) Uani 1 1 d . .
H20 H 0.7195 0.9321 0.8874 0.047 Uiso 1 1 calc R U
C21 C 0.8152(11) 0.5987(9) 0.4927(9) 0.053(3) Uani 1 1 d . .
H21A H 0.8400 0.6679 0.5004 0.080 Uiso 1 1 calc R U
H21B H 0.7478 0.5553 0.4269 0.080 Uiso 1 1 calc R U
H21C H 0.8810 0.5648 0.4901 0.080 Uiso 1 1 calc R U
C22 C 1.2264(11) 0.7149(10) 0.6806(10) 0.055(3) Uani 1 1 d . U
H22A H 1.2665 0.7772 0.6824 0.083 Uiso 1 1 calc R U
H22B H 1.1743 0.6646 0.6078 0.083 Uiso 1 1 calc R U
H22C H 1.2855 0.6824 0.7043 0.083 Uiso 1 1 calc R U
C23 C 0.7271(12) 0.5019(9) 0.5689(10) 0.056(4) Uani 1 1 d . .
H23A H 0.7895 0.4642 0.5695 0.084 Uiso 1 1 calc R U
H23B H 0.6632 0.4622 0.5000 0.084 Uiso 1 1 calc R U
H23C H 0.6956 0.5098 0.6255 0.084 Uiso 1 1 calc R U
C24 C 0.8927(9) 0.9351(8) 0.6138(8) 0.034(3) Uani 1 1 d . .
C25 C 0.6746(9) 0.8048(9) 0.9998(9) 0.039(3) Uani 1 1 d . .
H25 H 0.7299 0.8670 1.0578 0.047 Uiso 1 1 calc R U
C26 C 0.9417(13) 0.5367(10) 0.8782(11) 0.061(4) Uani 1 1 d . .
H26 H 0.9100 0.4628 0.8384 0.073 Uiso 1 1 calc R U
C27 C 1.0996(11) 0.6844(11) 1.0104(10) 0.058(4) Uani 1 1 d . .
H27 H 1.1772 0.7126 1.0613 0.070 Uiso 1 1 calc R U
C28 C 0.6953(9) 0.7559(8) 0.9057(9) 0.032(3) Uani 1 1 d . .
C29 C 1.0904(11) 0.6468(9) 0.7467(10) 0.055(3) Uani 1 1 d . U
H29A H 1.0395 0.5983 0.6730 0.083 Uiso 1 1 calc R U
H29B H 1.0422 0.6640 0.7930 0.083 Uiso 1 1 calc R U
H29C H 1.1501 0.6138 0.7688 0.083 Uiso 1 1 calc R U
C30 C 0.6721(12) 1.0320(9) 0.8312(10) 0.060(4) Uani 1 1 d . .
H30A H 0.6086 1.0283 0.7730 0.089 Uiso 1 1 calc R U
H30B H 0.7482 1.0442 0.8210 0.089 Uiso 1 1 calc R U
H30C H 0.6740 1.0898 0.8990 0.089 Uiso 1 1 calc R U
C31 C 1.2693(12) 0.8682(11) 0.5023(11) 0.067(4) Uani 1 1 d . U
H31 H 1.3233 0.8757 0.4682 0.081 Uiso 1 1 calc R U
C32 C 1.2889(12) 0.9459(11) 0.6026(11) 0.066(4) Uani 1 1 d . U
H32 H 1.3527 1.0067 0.6378 0.079 Uiso 1 1 calc R U
C33 C 0.5401(10) 0.9204(11) 0.8667(10) 0.064(4) Uani 1 1 d . .
H33A H 0.5170 0.8502 0.8574 0.097 Uiso 1 1 calc R U
H33B H 0.4743 0.9324 0.8230 0.097 Uiso 1 1 calc R U
H33C H 0.5597 0.9733 0.9416 0.097 Uiso 1 1 calc R U
C34 C 0.5728(10) 0.7643(10) 1.0118(10) 0.053(3) Uani 1 1 d . .
H34 H 0.5590 0.7989 1.0774 0.064 Uiso 1 1 calc R U
C35 C 1.1011(12) 0.7688(11) 0.4973(10) 0.059(4) Uani 1 1 d . .
H35 H 1.0369 0.7082 0.4604 0.071 Uiso 1 1 calc R U
C36 C 0.7652(14) 0.9242(14) 0.6066(14) 0.103(6) Uani 1 1 d . U
H36A H 0.7343 0.9750 0.5887 0.155 Uiso 1 1 calc R U
H36B H 0.7587 0.9375 0.6751 0.155 Uiso 1 1 calc R U
H36C H 0.7192 0.8529 0.5513 0.155 Uiso 1 1 calc R U
C37 C 0.8870(14) 0.8872(12) 0.5002(12) 0.085(5) Uani 1 1 d . U
H37A H 0.9660 0.9054 0.4975 0.127 Uiso 1 1 calc R U
H37B H 0.8322 0.9142 0.4638 0.127 Uiso 1 1 calc R U
H37C H 0.8590 0.8107 0.4652 0.127 Uiso 1 1 calc R U
C38 C 1.1807(12) 0.7825(11) 0.4479(12) 0.067(4) Uani 1 1 d . U
H38 H 1.1714 0.7315 0.3771 0.081 Uiso 1 1 calc R U
C39 C 0.9617(14) 1.0450(12) 0.6760(13) 0.087(5) Uani 1 1 d . U
H39A H 0.9259 1.0851 0.6445 0.130 Uiso 1 1 calc R U
H39B H 1.0432 1.0483 0.6758 0.130 Uiso 1 1 calc R U
H39C H 0.9619 1.0750 0.7493 0.130 Uiso 1 1 calc R U
C40 C 0.2542(13) 0.3818(13) 0.8559(14) 0.091(5) Uani 1 1 d . .
H40A H 0.3100 0.3380 0.8345 0.109 Uiso 1 1 calc R U
H40B H 0.2964 0.4415 0.9286 0.109 Uiso 1 1 calc R U
P1 P 0.8402(2) 0.8056(2) 0.9089(2) 0.0256(6) Uani 1 1 d . .
Si1 Si 0.9579(2) 0.8705(2) 0.7869(2) 0.0230(6) Uani 1 1 d . .
N2 N 1.0557(7) 0.7946(6) 0.7245(6) 0.0267(19) Uani 1 1 d . .
N3 N 0.8321(7) 0.8030(6) 0.7915(6) 0.0235(19) Uani 1 1 d . .
N1 N 0.9418(7) 0.8725(6) 0.6644(6) 0.026(2) Uani 1 1 d . .
Au1 Au 1.06126(4) 1.02722(3) 0.94152(3) 0.02452(13) Uani 1 1 d . .
Sb02 Sb 0.42934(10) 0.70560(9) 0.24559(9) 0.0740(3) Uani 1 1 d . .
F1 F 0.3648(16) 0.6044(13) 0.1100(10) 0.211(7) Uani 1 1 d . U
F2 F 0.3541(13) 0.6255(11) 0.2860(10) 0.186(6) Uani 1 1 d . U
F3 F 0.2992(14) 0.7615(15) 0.2415(13) 0.227(7) Uani 1 1 d . U
F4 F 0.4963(19) 0.7875(13) 0.2098(13) 0.254(8) Uani 1 1 d . U
F5 F 0.5473(14) 0.6528(13) 0.2670(16) 0.243(8) Uani 1 1 d . U
F6 F 0.4867(9) 0.8138(8) 0.3872(8) 0.119(3) Uani 1 1 d . U
Cl1 Cl 0.1357(5) 0.3084(4) 0.8571(5) 0.1250(19) Uani 1 1 d . .
Cl2 Cl 0.2115(4) 0.4297(4) 0.7695(4) 0.0965(14) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C7 C6 120.0 . .
C2 C7 N3 121.0(5) . .
C6 C7 N3 118.8(5) . .
C7 C2 C3 120.0 . .
C7 C2 C20 124.6(6) . .
C3 C2 C20 115.4(6) . .
C4 C3 C2 120.0 . .
C4 C3 H3 120.0 . .
C2 C3 H3 120.0 . .
C3 C4 C5 120.0 . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C4 C5 C6 120.0 . .
C4 C5 H5 120.0 . .
C6 C5 H5 120.0 . .
C5 C6 C7 120.0 . .
C5 C6 C15 117.1(6) . .
C7 C6 C15 122.8(6) . .
N1 C1 N2 106.6(8) . .
N1 C1 C12 126.9(10) . .
N2 C1 C12 126.2(9) . .
N1 C1 Si1 53.8(5) . .
N2 C1 Si1 55.1(5) . .
C12 C1 Si1 161.3(7) . .
C9 C8 C10 118.5(10) . .
C9 C8 P1 117.7(8) . .
C10 C8 P1 123.8(8) . .
C8 C9 C27 121.4(11) . .
C8 C9 H9 119.3 . .
C27 C9 H9 119.3 . .
C8 C10 C26 120.0(11) . .
C8 C10 H10 120.0 . .
C26 C10 H10 120.0 . .
N2 C11 C16 108.3(8) . .
N2 C11 C29 105.9(8) . .
C16 C11 C29 111.2(10) . .
N2 C11 C22 114.6(9) . .
C16 C11 C22 110.0(9) . .
C29 C11 C22 106.7(9) . .
C14 C12 C35 119.8(10) . .
C14 C12 C1 117.7(10) . .
C35 C12 C1 122.5(10) . .
C19 C13 C34 120.4(10) . .
C19 C13 H13 119.8 . .
C34 C13 H13 119.8 . .
C12 C14 C32 121.4(12) . .
C12 C14 H14 119.3 . .
C32 C14 H14 119.3 . .
C6 C15 C21 112.9(10) . .
C6 C15 C23 112.0(9) . .
C21 C15 C23 109.2(9) . .
C6 C15 H15 107.5 . .
C21 C15 H15 107.5 . .
C23 C15 H15 107.5 . .
C11 C16 H16A 109.5 . .
C11 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C11 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C27 C17 C26 120.9(13) . .
C27 C17 H17 119.6 . .
C26 C17 H17 119.6 . .
C19 C18 C28 121.6(11) . .
C19 C18 H18 119.2 . .
C28 C18 H18 119.2 . .
C13 C19 C18 119.5(12) . .
C13 C19 H19 120.2 . .
C18 C19 H19 120.2 . .
C30 C20 C2 114.7(9) . .
C30 C20 C33 108.3(10) . .
C2 C20 C33 110.9(8) . .
C30 C20 H20 107.6 . .
C2 C20 H20 107.6 . .
C33 C20 H20 107.6 . .
C15 C21 H21A 109.5 . .
C15 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C15 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C11 C22 H22A 109.5 . .
C11 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C11 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C15 C23 H23A 109.5 . .
C15 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C15 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C39 C24 C37 111.2(11) . .
C39 C24 C36 112.5(12) . .
C37 C24 C36 103.7(11) . .
C39 C24 N1 110.7(10) . .
C37 C24 N1 111.9(10) . .
C36 C24 N1 106.6(9) . .
C28 C25 C34 120.7(11) . .
C28 C25 H25 119.6 . .
C34 C25 H25 119.6 . .
C17 C26 C10 119.7(12) . .
C17 C26 H26 120.1 . .
C10 C26 H26 120.1 . .
C17 C27 C9 119.6(12) . .
C17 C27 H27 120.2 . .
C9 C27 H27 120.2 . .
C25 C28 C18 118.1(9) . .
C25 C28 P1 115.3(8) . .
C18 C28 P1 126.0(8) . .
C11 C29 H29A 109.5 . .
C11 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C11 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C20 C30 H30A 109.5 . .
C20 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C20 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C38 C31 C32 125.1(15) . .
C38 C31 H31 117.5 . .
C32 C31 H31 117.5 . .
C31 C32 C14 115.9(13) . .
C31 C32 H32 122.0 . .
C14 C32 H32 122.0 . .
C20 C33 H33A 109.5 . .
C20 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C20 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C13 C34 C25 119.6(11) . .
C13 C34 H34 120.2 . .
C25 C34 H34 120.2 . .
C12 C35 C38 119.3(13) . .
C12 C35 H35 120.3 . .
C38 C35 H35 120.3 . .
C24 C36 H36A 109.5 . .
C24 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C24 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C24 C37 H37A 109.5 . .
C24 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C24 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C31 C38 C35 118.4(14) . .
C31 C38 H38 120.8 . .
C35 C38 H38 120.8 . .
C24 C39 H39A 109.5 . .
C24 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C24 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
Cl1 C40 Cl2 112.1(9) . .
Cl1 C40 H40A 109.2 . .
Cl2 C40 H40A 109.2 . .
Cl1 C40 H40B 109.2 . .
Cl2 C40 H40B 109.2 . .
H40A C40 H40B 107.9 . .
N3 P1 C28 110.8(4) . .
N3 P1 C8 109.4(4) . .
C28 P1 C8 102.9(5) . .
N3 P1 Au1 112.2(3) . 2_777
C28 P1 Au1 113.0(4) . 2_777
C8 P1 Au1 108.1(3) . 2_777
N3 Si1 N1 116.2(4) . .
N3 Si1 N2 118.7(4) . .
N1 Si1 N2 72.3(4) . .
N3 Si1 C1 132.1(4) . .
N1 Si1 C1 36.7(4) . .
N2 Si1 C1 36.9(4) . .
N3 Si1 Au1 114.8(3) . .
N1 Si1 Au1 115.4(3) . .
N2 Si1 Au1 112.9(3) . .
C1 Si1 Au1 113.1(3) . .
C1 N2 C11 130.8(8) . .
C1 N2 Si1 88.0(6) . .
C11 N2 Si1 137.1(7) . .
C7 N3 P1 119.8(5) . .
C7 N3 Si1 120.4(5) . .
P1 N3 Si1 117.9(4) . .
C1 N1 C24 127.0(8) . .
C1 N1 Si1 89.5(6) . .
C24 N1 Si1 137.5(6) . .
Si1 Au1 P1 175.03(10) . 2_777
Si1 Au1 Au1 91.10(8) . 2_777
P1 Au1 Au1 91.50(8) 2_777 2_777
F5 Sb02 F4 96.0(10) . .
F5 Sb02 F1 92.7(8) . .
F4 Sb02 F1 91.2(8) . .
F5 Sb02 F2 87.0(9) . .
F4 Sb02 F2 176.5(8) . .
F1 Sb02 F2 90.3(7) . .
F5 Sb02 F3 170.6(9) . .
F4 Sb02 F3 91.4(9) . .
F1 Sb02 F3 92.8(8) . .
F2 Sb02 F3 85.4(8) . .
F5 Sb02 F6 91.0(7) . .
F4 Sb02 F6 89.7(6) . .
F1 Sb02 F6 176.0(7) . .
F2 Sb02 F6 88.6(5) . .
F3 Sb02 F6 83.3(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C7 C2 1.3900 .
C7 C6 1.3900 .
C7 N3 1.462(9) .
C2 C3 1.3900 .
C2 C20 1.538(11) .
C3 C4 1.3900 .
C3 H3 0.9500 .
C4 C5 1.3900 .
C4 H4 0.9500 .
C5 C6 1.3900 .
C5 H5 0.9500 .
C6 C15 1.524(12) .
C1 N1 1.341(12) .
C1 N2 1.348(12) .
C1 C12 1.498(14) .
C1 Si1 2.245(10) .
C8 C9 1.376(14) .
C8 C10 1.393(14) .
C8 P1 1.809(10) .
C9 C27 1.397(16) .
C9 H9 0.9500 .
C10 C26 1.410(16) .
C10 H10 0.9500 .
C11 N2 1.491(13) .
C11 C16 1.494(15) .
C11 C29 1.531(15) .
C11 C22 1.543(15) .
C12 C14 1.367(15) .
C12 C35 1.368(16) .
C13 C19 1.364(17) .
C13 C34 1.377(17) .
C13 H13 0.9500 .
C14 C32 1.400(16) .
C14 H14 0.9500 .
C15 C21 1.528(15) .
C15 C23 1.546(15) .
C15 H15 1.0000 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C27 1.360(17) .
C17 C26 1.370(17) .
C17 H17 0.9500 .
C18 C19 1.374(14) .
C18 C28 1.394(14) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C30 1.532(15) .
C20 C33 1.552(15) .
C20 H20 1.0000 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 C39 1.468(17) .
C24 C37 1.498(17) .
C24 C36 1.501(18) .
C24 N1 1.516(12) .
C25 C28 1.366(14) .
C25 C34 1.399(15) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 H27 0.9500 .
C28 P1 1.806(10) .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C38 1.326(17) .
C31 C32 1.354(18) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34 0.9500 .
C35 C38 1.404(17) .
C35 H35 0.9500 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 H38 0.9500 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 Cl1 1.714(15) .
C40 Cl2 1.735(16) .
C40 H40A 0.9900 .
C40 H40B 0.9900 .
P1 N3 1.721(8) .
P1 Au1 2.361(3) 2_777
Si1 N3 1.764(8) .
Si1 N1 1.812(8) .
Si1 N2 1.842(8) .
Si1 Au1 2.317(3) .
Au1 P1 2.361(3) 2_777
Au1 Au1 2.8753(14) 2_777
Sb02 F5 1.718(14) .
Sb02 F4 1.736(12) .
Sb02 F1 1.783(14) .
Sb02 F2 1.818(11) .
Sb02 F3 1.844(14) .
Sb02 F6 1.869(10) .
