#------------------------------------------------------------------------------
#$Date: 2016-07-01 15:16:33 +0300 (Fri, 01 Jul 2016) $
#$Revision: 184125 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/90/7119094.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7119094
loop_
_publ_author_name
'Jordan Holmes'
'Christopher M. Pask'
'Mark A. Fox'
'Charlotte E. Willans'
_publ_section_title
;
 Tethered N-heterocyclic carbene-carboranes: unique ligands that exhibit
 unprecedented and versatile coordination modes at rhodium
;
_journal_name_full               Chem.Commun.
_journal_page_first              6443
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C29 H52 B9 N3 Rh2, C3 H6 O'
_chemical_formula_sum            'C32 H58 B9 N3 O Rh2'
_chemical_formula_weight         803.92
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2015-09-08
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_audit_update_record
;
2015-12-23 deposited with the CCDC.
2016-04-12 downloaded from the CCDC.
;
_cell_angle_alpha                111.322(4)
_cell_angle_beta                 92.917(4)
_cell_angle_gamma                105.326(4)
_cell_formula_units_Z            2
_cell_length_a                   11.1781(5)
_cell_length_b                   12.5631(5)
_cell_length_c                   14.8258(7)
_cell_measurement_reflns_used    9770
_cell_measurement_temperature    120.01(11)
_cell_measurement_theta_max      30.7360
_cell_measurement_theta_min      3.2670
_cell_volume                     1845.32(16)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      120.01(11)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.3095
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
  1 omega  -12.00   74.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       12.9509   57.0000   60.0000 86

  2 omega   -7.00   83.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       12.9509   37.0000  150.0000 90

  3 omega  -11.00   81.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       12.9509   57.0000 -120.0000 92

  4 omega  -24.00   27.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       12.9509  -57.0000  -60.0000 51

  5 omega  -29.00   -2.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -13.7322  -57.0000    0.0000 27

  6 omega  -42.00   -5.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -13.7322  -65.0000 -147.1798 37

  7 omega  -64.00  -37.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -13.7322  -37.0000  150.0000 27
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0174447000
_diffrn_orient_matrix_UB_12      0.0299218000
_diffrn_orient_matrix_UB_13      0.0517125000
_diffrn_orient_matrix_UB_21      -0.0562772000
_diffrn_orient_matrix_UB_22      -0.0371809000
_diffrn_orient_matrix_UB_23      0.0061953000
_diffrn_orient_matrix_UB_31      0.0313578000
_diffrn_orient_matrix_UB_32      -0.0421671000
_diffrn_orient_matrix_UB_33      0.0004455000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0440
_diffrn_reflns_av_unetI/netI     0.0615
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21395
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         2.99
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.925
_exptl_absorpt_correction_T_max  0.951
_exptl_absorpt_correction_T_min  0.882
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Numerical absorption correction based on gaussian integration over
            a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.447
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             828
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.001
_refine_diff_density_min         -0.936
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         9142
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0490
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0265P)²+1.1205P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0791
_refine_ls_wR_factor_ref         0.0855
_reflns_number_gt                7691
_reflns_number_total             9142
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6cc01650b2.cif
_cod_data_source_block           Complex-4
_cod_original_cell_volume        1845.33(15)
_cod_database_code               7119094
_chemical_oxdiff_formula         'C17 H21 N2 Rh2 B10'
_reflns_odcompleteness_completeness 99.85
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     28.22
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All B(H) groups, All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C12(H12A), C13(H13), C16(H16), C17(H17), C22(H22), C23(H23), C26(H26), C27(H27)
2.b Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C4(H4A,H4B), C14(H14A,H14B), C15(H15A,H15B), C18(H18A,H18B),
 C19(H19A,H19B), C24(H24A,H24B), C25(H25A,H25B), C28(H28A,H28B), C29(H29A,H29B)
2.c Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6)
2.d Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C21(H21A,H21B,
 H21C), C31(H31A,H31B,H31C), C32(H32A,H32B,H32C)
2.e Boron cage BH refined with riding coordinates:
 C1(H1), B4(H4), B8(H8), B7(H7), B6(H6A), B5(H5A), B9(H9), B12(H12), B11(H11),
 B10(H10)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
Rh1 Rh 0.40778(2) 0.908661(18) 0.250735(15) 0.01438(6) Uani 1 d . . .
N1 N 0.2077(2) 0.9873(2) 0.37778(16) 0.0153(5) Uani 1 d . . .
C1 C 0.8016(3) 1.4996(3) 0.3421(2) 0.0195(6) Uani 1 d . . .
H1 H 0.8684 1.5722 0.4050 0.023 Uiso 1 calc . . R
Rh2 Rh 0.889440(19) 1.351558(18) 0.266234(15) 0.01329(6) Uani 1 d . . .
N2 N 0.3754(2) 1.1334(2) 0.40093(16) 0.0137(5) Uani 1 d . . .
C2 C 0.5832(3) 1.3229(2) 0.28094(19) 0.0138(5) Uani 1 d . . .
N3 N 0.3247(2) 0.9423(2) 0.13992(17) 0.0186(5) Uani 1 d . . .
C3 C 0.4669(3) 1.2530(3) 0.3083(2) 0.0175(6) Uani 1 d . . .
H3A H 0.4144 1.3046 0.3315 0.021 Uiso 1 calc . . R
H3B H 0.4191 1.1855 0.2494 0.021 Uiso 1 calc . . R
C4 C 0.4933(3) 1.2060(2) 0.3863(2) 0.0160(5) Uani 1 d . . .
H4A H 0.5494 1.1576 0.3659 0.019 Uiso 1 calc . . R
H4B H 0.5343 1.2728 0.4476 0.019 Uiso 1 calc . . R
B4 B 0.8219(3) 1.4803(3) 0.2239(3) 0.0232(7) Uani 1 d . . .
H4 H 0.9034 1.5360 0.2062 0.028 Uiso 1 calc . . R
C5 C 0.2961(3) 1.1810(3) 0.4607(2) 0.0195(6) Uani 1 d . . .
H5 H 0.3120 1.2607 0.5029 0.023 Uiso 1 calc . . R
B8 B 0.7421(3) 1.3236(3) 0.1437(2) 0.0184(7) Uani 1 d . . .
H8 H 0.7670 1.2770 0.0722 0.022 Uiso 1 calc . . R
C6 C 0.1926(3) 1.0912(3) 0.4467(2) 0.0201(6) Uani 1 d . . .
H6 H 0.1227 1.0968 0.4774 0.024 Uiso 1 calc . . R
B7 B 0.6850(3) 1.2479(3) 0.2206(2) 0.0154(6) Uani 1 d . . .
H7 H 0.6701 1.1515 0.2008 0.019 Uiso 1 calc . . R
C7 C 0.3228(2) 1.0142(2) 0.34923(19) 0.0144(5) Uani 1 d . . .
B6 B 0.6496(3) 1.4702(3) 0.3568(2) 0.0175(6) Uani 1 d . . .
H6A H 0.6174 1.5147 0.4256 0.021 Uiso 1 calc . . R
C8 C 0.1102(3) 0.8678(3) 0.3461(2) 0.0204(6) Uani 1 d . . .
B5 B 0.7057(3) 1.5443(3) 0.2798(3) 0.0237(7) Uani 1 d . . .
H5A H 0.7119 1.6386 0.2969 0.028 Uiso 1 calc . . R
C9 C 0.1324(3) 0.7777(3) 0.2522(2) 0.0293(7) Uani 1 d . . .
H9A H 0.1316 0.8075 0.2011 0.044 Uiso 1 calc . . GR
H9B H 0.0672 0.7027 0.2328 0.044 Uiso 1 calc . . GR
H9C H 0.2125 0.7661 0.2635 0.044 Uiso 1 calc . . GR
B9 B 0.6669(3) 1.4372(3) 0.1579(3) 0.0237(7) Uani 1 d . . .
H9 H 0.6489 1.4631 0.0964 0.028 Uiso 1 calc . . R
C10 C 0.1122(3) 0.8225(3) 0.4283(2) 0.0277(7) Uani 1 d . . .
H10A H 0.1930 0.8130 0.4409 0.042 Uiso 1 calc . . GR
H10B H 0.0483 0.7467 0.4092 0.042 Uiso 1 calc . . GR
H10C H 0.0965 0.8793 0.4867 0.042 Uiso 1 calc . . GR
B12 B 0.5822(3) 1.2961(3) 0.1591(2) 0.0181(6) Uani 1 d . . .
H12 H 0.5060 1.2301 0.0996 0.022 Uiso 1 calc . . R
C11 C -0.0191(3) 0.8815(3) 0.3239(2) 0.0252(7) Uani 1 d . . .
H11A H -0.0355 0.9395 0.3812 0.038 Uiso 1 calc . . GR
H11B H -0.0827 0.8057 0.3058 0.038 Uiso 1 calc . . GR
H11C H -0.0201 0.9080 0.2708 0.038 Uiso 1 calc . . GR
B11 B 0.7342(3) 1.3624(3) 0.3457(2) 0.0146(6) Uani 1 d . . .
H11 H 0.7561 1.3399 0.4085 0.017 Uiso 1 calc . . R
C12 C 0.5505(3) 0.9386(3) 0.3646(2) 0.0212(6) Uani 1 d . . .
H12A H 0.5539 1.0051 0.4263 0.025 Uiso 1 calc . . R
B10 B 0.5600(3) 1.4300(3) 0.2418(2) 0.0186(7) Uani 1 d . . .
H10 H 0.4701 1.4489 0.2353 0.022 Uiso 1 calc . . R
C13 C 0.4561(3) 0.8327(3) 0.3486(2) 0.0202(6) Uani 1 d . . .
H13 H 0.4051 0.8389 0.4011 0.024 Uiso 1 calc . . R
C14 C 0.4661(3) 0.7075(3) 0.2953(3) 0.0335(8) Uani 1 d . . .
H14A H 0.5509 0.7081 0.3135 0.040 Uiso 1 calc . . R
H14B H 0.4095 0.6529 0.3178 0.040 Uiso 1 calc . . R
C15 C 0.4369(5) 0.6605(4) 0.1875(3) 0.0600(14) Uani 1 d . . .
H15A H 0.3522 0.6053 0.1669 0.072 Uiso 1 calc . . R
H15B H 0.4935 0.6147 0.1605 0.072 Uiso 1 calc . . R
C16 C 0.4464(3) 0.7534(3) 0.1427(2) 0.0321(8) Uani 1 d . . .
H16 H 0.3949 0.7220 0.0778 0.039 Uiso 1 calc . . R
C17 C 0.5471(3) 0.8524(3) 0.1601(2) 0.0323(8) Uani 1 d . . .
H17 H 0.5565 0.8792 0.1057 0.039 Uiso 1 calc . . R
C18 C 0.6686(4) 0.8770(5) 0.2247(3) 0.0597(14) Uani 1 d . . .
H18A H 0.6812 0.8008 0.2168 0.072 Uiso 1 calc . . R
H18B H 0.7374 0.9200 0.2018 0.072 Uiso 1 calc . . R
C19 C 0.6750(3) 0.9453(4) 0.3285(3) 0.0369(8) Uani 1 d . . .
H19A H 0.7193 1.0287 0.3431 0.044 Uiso 1 calc . . R
H19B H 0.7247 0.9175 0.3654 0.044 Uiso 1 calc . . R
C20 C 0.2763(3) 0.9545(3) 0.0767(2) 0.0226(6) Uani 1 d . . .
C21 C 0.2131(4) 0.9697(3) -0.0039(2) 0.0390(9) Uani 1 d . . .
H21A H 0.2313 0.9203 -0.0649 0.058 Uiso 1 calc . . GR
H21B H 0.2424 1.0522 0.0042 0.058 Uiso 1 calc . . GR
H21C H 0.1240 0.9467 -0.0044 0.058 Uiso 1 calc . . GR
C22 C 1.0087(3) 1.3482(3) 0.3849(2) 0.0247(7) Uani 1 d . . .
H22 H 0.9808 1.3752 0.4487 0.030 Uiso 1 calc . . R
C23 C 0.9411(3) 1.2302(3) 0.3215(2) 0.0251(7) Uani 1 d . . .
H23 H 0.8750 1.1895 0.3492 0.030 Uiso 1 calc . . R
C24 C 0.9999(3) 1.1473(3) 0.2485(3) 0.0295(7) Uani 1 d . . .
H24A H 0.9341 1.0752 0.2064 0.035 Uiso 1 calc . . R
H24B H 1.0567 1.1240 0.2840 0.035 Uiso 1 calc . . R
C25 C 1.0727(3) 1.2049(3) 0.1844(2) 0.0285(7) Uani 1 d . . .
H25A H 1.1609 1.2395 0.2136 0.034 Uiso 1 calc . . R
H25B H 1.0662 1.1433 0.1200 0.034 Uiso 1 calc . . R
C26 C 1.0232(3) 1.3023(3) 0.1732(2) 0.0234(7) Uani 1 d . . .
H26 H 0.9976 1.2889 0.1048 0.028 Uiso 1 calc . . R
C27 C 1.0725(3) 1.4231(3) 0.2350(2) 0.0247(7) Uani 1 d . . .
H27 H 1.0748 1.4779 0.2016 0.030 Uiso 1 calc . . R
C28 C 1.1742(3) 1.4714(3) 0.3225(3) 0.0322(8) Uani 1 d . . .
H28A H 1.1816 1.5547 0.3605 0.039 Uiso 1 calc . . R
H28B H 1.2537 1.4683 0.3001 0.039 Uiso 1 calc . . R
C29 C 1.1483(3) 1.4014(3) 0.3882(2) 0.0267(7) Uani 1 d . . .
H29A H 1.1866 1.3373 0.3676 0.032 Uiso 1 calc . . R
H29B H 1.1870 1.4544 0.4553 0.032 Uiso 1 calc . . R
O1 O 0.9120(3) 0.8171(3) 0.06361(18) 0.0477(7) Uani 1 d . . .
C30 C 0.8490(4) 0.7124(3) 0.0268(2) 0.0339(8) Uani 1 d . . .
C31 C 0.9015(4) 0.6123(4) 0.0218(3) 0.0436(10) Uani 1 d . . .
H31A H 0.9917 0.6419 0.0343 0.065 Uiso 1 calc . . GR
H31B H 0.8738 0.5490 -0.0422 0.065 Uiso 1 calc . . GR
H31C H 0.8726 0.5821 0.0703 0.065 Uiso 1 calc . . GR
C32 C 0.7139(4) 0.6739(4) -0.0160(3) 0.0442(9) Uani 1 d . . .
H32A H 0.6840 0.7426 0.0018 0.066 Uiso 1 calc . . GR
H32B H 0.6663 0.6180 0.0088 0.066 Uiso 1 calc . . GR
H32C H 0.7041 0.6363 -0.0861 0.066 Uiso 1 calc . . GR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Rh1 C12 155.79(11) . .
N3 Rh1 C13 165.58(11) . .
N3 Rh1 C16 91.02(10) . .
N3 Rh1 C17 90.43(11) . .
C7 Rh1 N3 89.55(9) . .
C7 Rh1 C12 90.88(11) . .
C7 Rh1 C13 93.31(10) . .
C7 Rh1 C16 162.50(13) . .
C7 Rh1 C17 161.12(13) . .
C12 Rh1 C13 38.39(11) . .
C12 Rh1 C16 95.70(12) . .
C12 Rh1 C17 81.54(12) . .
C13 Rh1 C16 82.05(11) . .
C13 Rh1 C17 91.39(12) . .
C16 Rh1 C17 36.38(14) . .
C6 N1 C8 122.4(2) . .
C7 N1 C6 109.3(2) . .
C7 N1 C8 128.3(2) . .
Rh2 C1 H1 110.5 . .
B4 C1 H1 121.1 . .
B4 C1 Rh2 65.39(14) . .
B6 C1 H1 115.4 . .
B6 C1 Rh2 122.59(18) . .
B6 C1 B4 113.1(2) . .
B6 C1 B5 62.59(19) . .
B6 C1 B11 64.54(18) . .
B5 C1 H1 115.3 . .
B5 C1 Rh2 123.20(19) . .
B5 C1 B4 63.00(19) . .
B5 C1 B11 114.4(2) . .
B11 C1 H1 120.8 . .
B11 C1 Rh2 63.17(13) . .
B11 C1 B4 108.9(2) . .
B4 Rh2 C1 44.70(12) . .
B4 Rh2 B8 48.34(13) . .
B4 Rh2 B7 81.16(12) . .
B8 Rh2 C1 78.64(10) . .
B7 Rh2 C1 79.50(11) . .
B7 Rh2 B8 46.65(12) . .
B11 Rh2 C1 45.16(11) . .
B11 Rh2 B4 79.28(12) . .
B11 Rh2 B8 81.14(11) . .
B11 Rh2 B7 49.22(11) . .
B11 Rh2 C22 93.76(11) . .
B11 Rh2 C23 93.86(11) . .
B11 Rh2 C27 153.89(12) . .
C22 Rh2 C1 104.39(11) . .
C22 Rh2 B4 140.04(13) . .
C22 Rh2 B8 169.39(13) . .
C22 Rh2 B7 123.38(12) . .
C23 Rh2 C1 128.59(11) . .
C23 Rh2 B4 172.92(12) . .
C23 Rh2 B8 132.77(13) . .
C23 Rh2 B7 95.74(12) . .
C23 Rh2 C22 37.84(12) . .
C26 Rh2 C1 145.24(11) . .
C26 Rh2 B4 106.65(12) . .
C26 Rh2 B8 95.14(11) . .
C26 Rh2 B7 120.73(12) . .
C26 Rh2 B11 168.22(12) . .
C26 Rh2 C22 88.01(11) . .
C26 Rh2 C23 80.41(11) . .
C26 Rh2 C27 37.82(12) . .
C27 Rh2 C1 111.75(11) . .
C27 Rh2 B4 89.67(12) . .
C27 Rh2 B8 109.00(12) . .
C27 Rh2 B7 152.37(12) . .
C27 Rh2 C22 79.57(12) . .
C27 Rh2 C23 95.88(11) . .
C5 N2 C4 123.8(2) . .
C7 N2 C4 124.7(2) . .
C7 N2 C5 111.0(2) . .
C3 C2 B7 119.3(2) . .
C3 C2 B6 116.9(2) . .
C3 C2 B12 117.0(2) . .
C3 C2 B11 122.0(2) . .
C3 C2 B10 114.6(2) . .
B7 C2 B11 63.16(16) . .
B6 C2 B7 116.3(2) . .
B6 C2 B12 113.6(2) . .
B6 C2 B11 63.22(17) . .
B6 C2 B10 61.86(18) . .
B12 C2 B7 62.16(16) . .
B12 C2 B11 113.0(2) . .
B12 C2 B10 62.28(17) . .
B10 C2 B7 114.7(2) . .
B10 C2 B11 113.5(2) . .
C20 N3 Rh1 176.4(2) . .
C2 C3 H3A 108.5 . .
C2 C3 H3B 108.5 . .
H3A C3 H3B 107.5 . .
C4 C3 C2 115.2(2) . .
C4 C3 H3A 108.5 . .
C4 C3 H3B 108.5 . .
N2 C4 C3 110.1(2) . .
N2 C4 H4A 109.6 . .
N2 C4 H4B 109.6 . .
C3 C4 H4A 109.6 . .
C3 C4 H4B 109.6 . .
H4A C4 H4B 108.2 . .
C1 B4 Rh2 69.92(14) . .
C1 B4 H4 122.8 . .
C1 B4 B8 108.5(2) . .
C1 B4 B5 58.26(18) . .
C1 B4 B9 105.2(2) . .
Rh2 B4 H4 106.5 . .
B8 B4 Rh2 66.79(14) . .
B8 B4 H4 122.5 . .
B5 B4 Rh2 123.1(2) . .
B5 B4 H4 119.9 . .
B5 B4 B8 107.7(2) . .
B5 B4 B9 59.09(19) . .
B9 B4 Rh2 120.9(2) . .
B9 B4 H4 121.5 . .
B9 B4 B8 59.45(19) . .
N2 C5 H5 126.5 . .
C6 C5 N2 107.0(2) . .
C6 C5 H5 126.5 . .
Rh2 B8 H8 110.3 . .
B4 B8 Rh2 64.88(14) . .
B4 B8 H8 124.1 . .
B7 B8 Rh2 66.28(14) . .
B7 B8 B4 106.9(2) . .
B7 B8 H8 121.9 . .
B7 B8 B9 108.6(2) . .
B9 B8 Rh2 118.9(2) . .
B9 B8 B4 59.15(19) . .
B9 B8 H8 119.8 . .
B12 B8 Rh2 119.93(19) . .
B12 B8 B4 106.3(2) . .
B12 B8 H8 120.0 . .
B12 B8 B7 60.39(18) . .
B12 B8 B9 59.97(18) . .
N1 C6 H6 126.1 . .
C5 C6 N1 107.7(2) . .
C5 C6 H6 126.1 . .
Rh2 B7 H7 111.2 . .
C2 B7 Rh2 115.30(18) . .
C2 B7 B8 103.7(2) . .
C2 B7 H7 123.2 . .
C2 B7 B12 58.06(16) . .
C2 B7 B11 58.59(16) . .
B8 B7 Rh2 67.08(15) . .
B8 B7 H7 123.5 . .
B8 B7 B12 59.65(18) . .
B8 B7 B11 105.2(2) . .
B12 B7 Rh2 120.0(2) . .
B12 B7 H7 119.8 . .
B12 B7 B11 106.0(2) . .
B11 B7 Rh2 63.00(14) . .
B11 B7 H7 124.6 . .
N1 C7 Rh1 131.2(2) . .
N2 C7 Rh1 123.89(19) . .
N2 C7 N1 104.9(2) . .
C1 B6 C2 104.2(2) . .
C1 B6 H6A 123.7 . .
C1 B6 B5 59.35(18) . .
C1 B6 B11 58.46(17) . .
C1 B6 B10 107.0(2) . .
C2 B6 H6A 123.9 . .
C2 B6 B5 105.6(2) . .
C2 B6 B11 59.54(16) . .
C2 B6 B10 59.35(17) . .
B5 B6 H6A 122.4 . .
B5 B6 B11 107.0(2) . .
B11 B6 H6A 121.8 . .
B10 B6 H6A 121.3 . .
B10 B6 B5 60.14(19) . .
B10 B6 B11 108.5(2) . .
N1 C8 C9 111.4(2) . .
N1 C8 C10 109.0(2) . .
N1 C8 C11 109.0(2) . .
C9 C8 C11 107.1(3) . .
C10 C8 C9 110.3(2) . .
C10 C8 C11 110.1(2) . .
C1 B5 B4 58.74(18) . .
C1 B5 B6 58.06(18) . .
C1 B5 H5A 123.8 . .
C1 B5 B9 106.6(2) . .
C1 B5 B10 105.8(2) . .
B4 B5 H5A 122.2 . .
B6 B5 B4 106.1(2) . .
B6 B5 H5A 122.7 . .
B6 B5 B9 107.9(2) . .
B6 B5 B10 59.92(19) . .
B9 B5 B4 60.5(2) . .
B9 B5 H5A 121.3 . .
B9 B5 B10 60.5(2) . .
B10 B5 B4 108.0(2) . .
B10 B5 H5A 121.8 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9B 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
B4 B9 B8 61.41(19) . .
B4 B9 H9 121.6 . .
B8 B9 H9 120.5 . .
B5 B9 B4 60.4(2) . .
B5 B9 B8 110.4(2) . .
B5 B9 H9 120.8 . .
B5 B9 B12 108.2(2) . .
B5 B9 B10 59.76(19) . .
B12 B9 B4 107.6(2) . .
B12 B9 B8 59.37(19) . .
B12 B9 H9 122.4 . .
B10 B9 B4 107.4(2) . .
B10 B9 B8 108.2(2) . .
B10 B9 H9 122.3 . .
B10 B9 B12 59.77(18) . .
C8 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
C8 C10 H10C 109.5 . .
H10A C10 H10B 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C2 B12 B8 105.3(2) . .
C2 B12 B7 59.78(16) . .
C2 B12 B9 104.5(2) . .
C2 B12 H12 124.7 . .
C2 B12 B10 59.00(16) . .
B8 B12 B7 59.96(18) . .
B8 B12 B9 60.66(19) . .
B8 B12 H12 121.8 . .
B8 B12 B10 109.4(2) . .
B7 B12 H12 120.4 . .
B9 B12 B7 108.8(2) . .
B9 B12 H12 122.4 . .
B10 B12 B7 110.0(2) . .
B10 B12 B9 60.00(19) . .
B10 B12 H12 120.5 . .
C8 C11 H11A 109.5 . .
C8 C11 H11B 109.5 . .
C8 C11 H11C 109.5 . .
H11A C11 H11B 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C1 B11 Rh2 71.67(14) . .
C1 B11 C2 101.2(2) . .
C1 B11 B7 109.7(2) . .
C1 B11 B6 56.99(17) . .
C1 B11 H11 123.2 . .
Rh2 B11 H11 105.6 . .
C2 B11 Rh2 119.22(17) . .
C2 B11 B7 58.25(16) . .
C2 B11 B6 57.24(16) . .
C2 B11 H11 124.8 . .
B7 B11 Rh2 67.77(14) . .
B7 B11 H11 121.7 . .
B6 B11 Rh2 123.54(19) . .
B6 B11 B7 107.2(2) . .
B6 B11 H11 120.7 . .
Rh1 C12 H12A 114.1 . .
C13 C12 Rh1 71.01(17) . .
C13 C12 H12A 114.1 . .
C13 C12 C19 124.9(3) . .
C19 C12 Rh1 110.5(2) . .
C19 C12 H12A 114.1 . .
C2 B10 B6 58.80(17) . .
C2 B10 B5 105.0(2) . .
C2 B10 B9 104.5(2) . .
C2 B10 B12 58.72(16) . .
C2 B10 H10 124.7 . .
B6 B10 B5 59.9(2) . .
B6 B10 B9 107.3(2) . .
B6 B10 B12 108.1(2) . .
B6 B10 H10 121.7 . .
B5 B10 B9 59.7(2) . .
B5 B10 B12 108.5(2) . .
B5 B10 H10 122.1 . .
B9 B10 H10 122.8 . .
B12 B10 B9 60.23(19) . .
B12 B10 H10 121.1 . .
Rh1 C13 H13 113.8 . .
C12 C13 Rh1 70.59(16) . .
C12 C13 H13 113.8 . .
C12 C13 C14 124.6(3) . .
C14 C13 Rh1 112.5(2) . .
C14 C13 H13 113.8 . .
C13 C14 H14A 108.5 . .
C13 C14 H14B 108.5 . .
H14A C14 H14B 107.5 . .
C15 C14 C13 115.1(3) . .
C15 C14 H14A 108.5 . .
C15 C14 H14B 108.5 . .
C14 C15 H15A 108.3 . .
C14 C15 H15B 108.3 . .
C14 C15 C16 116.1(3) . .
H15A C15 H15B 107.4 . .
C16 C15 H15A 108.3 . .
C16 C15 H15B 108.3 . .
Rh1 C16 H16 113.9 . .
C15 C16 Rh1 107.7(2) . .
C15 C16 H16 113.9 . .
C17 C16 Rh1 72.11(17) . .
C17 C16 C15 126.6(3) . .
C17 C16 H16 113.9 . .
Rh1 C17 H17 115.2 . .
C16 C17 Rh1 71.51(18) . .
C16 C17 H17 115.2 . .
C16 C17 C18 121.6(4) . .
C18 C17 Rh1 110.2(2) . .
C18 C17 H17 115.2 . .
C17 C18 H18A 108.4 . .
C17 C18 H18B 108.4 . .
H18A C18 H18B 107.5 . .
C19 C18 C17 115.4(3) . .
C19 C18 H18A 108.4 . .
C19 C18 H18B 108.4 . .
C12 C19 H19A 108.3 . .
C12 C19 H19B 108.3 . .
C18 C19 C12 115.9(3) . .
C18 C19 H19A 108.3 . .
C18 C19 H19B 108.3 . .
H19A C19 H19B 107.4 . .
N3 C20 C21 179.4(4) . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21B 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
Rh2 C22 H22 114.2 . .
C23 C22 Rh2 70.50(16) . .
C23 C22 H22 114.2 . .
C23 C22 C29 122.4(3) . .
C29 C22 Rh2 114.2(2) . .
C29 C22 H22 114.2 . .
Rh2 C23 H23 114.3 . .
C22 C23 Rh2 71.66(16) . .
C22 C23 H23 114.3 . .
C22 C23 C24 123.1(3) . .
C24 C23 Rh2 111.83(19) . .
C24 C23 H23 114.3 . .
C23 C24 H24A 109.0 . .
C23 C24 H24B 109.0 . .
C23 C24 C25 113.0(2) . .
H24A C24 H24B 107.8 . .
C25 C24 H24A 109.0 . .
C25 C24 H24B 109.0 . .
C24 C25 H25A 109.2 . .
C24 C25 H25B 109.2 . .
H25A C25 H25B 107.9 . .
C26 C25 C24 112.1(2) . .
C26 C25 H25A 109.2 . .
C26 C25 H25B 109.2 . .
Rh2 C26 H26 113.6 . .
C25 C26 Rh2 114.9(2) . .
C25 C26 H26 113.6 . .
C27 C26 Rh2 71.45(16) . .
C27 C26 C25 123.0(3) . .
C27 C26 H26 113.6 . .
Rh2 C27 H27 113.8 . .
C26 C27 Rh2 70.73(18) . .
C26 C27 H27 113.8 . .
C26 C27 C28 124.5(3) . .
C28 C27 Rh2 112.6(2) . .
C28 C27 H27 113.8 . .
C27 C28 H28A 109.1 . .
C27 C28 H28B 109.1 . .
C27 C28 C29 112.5(3) . .
H28A C28 H28B 107.8 . .
C29 C28 H28A 109.1 . .
C29 C28 H28B 109.1 . .
C22 C29 C28 112.2(2) . .
C22 C29 H29A 109.2 . .
C22 C29 H29B 109.2 . .
C28 C29 H29A 109.2 . .
C28 C29 H29B 109.2 . .
H29A C29 H29B 107.9 . .
O1 C30 C31 122.5(4) . .
O1 C30 C32 122.4(3) . .
C32 C30 C31 115.1(3) . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31B 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C30 C32 H32A 109.5 . .
C30 C32 H32B 109.5 . .
C30 C32 H32C 109.5 . .
H32A C32 H32B 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 N3 2.073(2) .
Rh1 C7 2.048(3) .
Rh1 C12 2.118(3) .
Rh1 C13 2.123(3) .
Rh1 C16 2.192(3) .
Rh1 C17 2.199(3) .
N1 C6 1.393(3) .
N1 C7 1.371(3) .
N1 C8 1.493(4) .
C1 H1 1.1000 .
C1 Rh2 2.290(3) .
C1 B4 1.715(4) .
C1 B6 1.683(4) .
C1 B5 1.707(4) .
C1 B11 1.711(4) .
Rh2 B4 2.217(3) .
Rh2 B8 2.250(3) .
Rh2 B7 2.237(3) .
Rh2 B11 2.153(3) .
Rh2 C22 2.173(3) .
Rh2 C23 2.158(3) .
Rh2 C26 2.144(3) .
Rh2 C27 2.153(3) .
N2 C4 1.467(3) .
N2 C5 1.380(3) .
N2 C7 1.353(3) .
C2 C3 1.528(4) .
C2 B7 1.744(4) .
C2 B6 1.707(4) .
C2 B12 1.712(4) .
C2 B11 1.750(4) .
C2 B10 1.717(4) .
N3 C20 1.136(4) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C3 C4 1.527(4) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
B4 H4 1.1000 .
B4 B8 1.829(5) .
B4 B5 1.788(5) .
B4 B9 1.789(5) .
C5 H5 0.9300 .
C5 C6 1.330(4) .
B8 H8 1.1000 .
B8 B7 1.777(5) .
B8 B9 1.794(4) .
B8 B12 1.771(5) .
C6 H6 0.9300 .
B7 H7 1.1000 .
B7 B12 1.784(4) .
B7 B11 1.830(4) .
B6 H6A 1.1000 .
B6 B5 1.761(5) .
B6 B11 1.813(4) .
B6 B10 1.760(5) .
C8 C9 1.523(4) .
C8 C10 1.523(4) .
C8 C11 1.534(4) .
B5 H5A 1.1000 .
B5 B9 1.763(5) .
B5 B10 1.764(5) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
B9 H9 1.1000 .
B9 B12 1.782(5) .
B9 B10 1.778(5) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
B12 H12 1.1000 .
B12 B10 1.774(4) .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
B11 H11 1.1000 .
C12 H12A 0.9800 .
C12 C13 1.394(4) .
C12 C19 1.509(4) .
B10 H10 1.1000 .
C13 H13 0.9800 .
C13 C14 1.520(4) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C14 C15 1.473(5) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C15 C16 1.523(5) .
C16 H16 0.9800 .
C16 C17 1.371(5) .
C17 H17 0.9800 .
C17 C18 1.512(5) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C18 C19 1.451(5) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C21 1.455(4) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22 0.9800 .
C22 C23 1.404(5) .
C22 C29 1.517(4) .
C23 H23 0.9800 .
C23 C24 1.518(4) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C24 C25 1.535(5) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C25 C26 1.526(4) .
C26 H26 0.9800 .
C26 C27 1.393(5) .
C27 H27 0.9800 .
C27 C28 1.502(5) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C28 C29 1.524(5) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
O1 C30 1.213(4) .
C30 C31 1.503(5) .
C30 C32 1.487(5) .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Rh1 N3 C20 C21 70(33) . . . .
Rh1 C12 C13 C14 104.5(3) . . . .
Rh1 C12 C19 C18 -28.8(4) . . . .
Rh1 C13 C14 C15 -2.0(4) . . . .
Rh1 C16 C17 C18 102.8(3) . . . .
Rh1 C17 C18 C19 -8.1(5) . . . .
C1 Rh2 B4 B8 -121.6(2) . . . .
C1 Rh2 B4 B5 -25.0(2) . . . .
C1 Rh2 B4 B9 -96.0(3) . . . .
C1 Rh2 B8 B4 37.65(15) . . . .
C1 Rh2 B8 B7 -86.22(15) . . . .
C1 Rh2 B8 B9 12.7(2) . . . .
C1 Rh2 B8 B12 -57.4(2) . . . .
C1 Rh2 B7 C2 -10.67(18) . . . .
C1 Rh2 B7 B8 84.23(14) . . . .
C1 Rh2 B7 B12 55.6(2) . . . .
C1 Rh2 B7 B11 -38.08(14) . . . .
C1 Rh2 B11 C2 92.8(2) . . . .
C1 Rh2 B11 B7 121.22(19) . . . .
C1 Rh2 B11 B6 24.75(19) . . . .
C1 Rh2 C22 C23 136.01(17) . . . .
C1 Rh2 C22 C29 -106.4(2) . . . .
C1 Rh2 C23 C22 -59.4(2) . . . .
C1 Rh2 C23 C24 -178.55(19) . . . .
C1 Rh2 C26 C25 155.7(2) . . . .
C1 Rh2 C26 C27 37.2(3) . . . .
C1 Rh2 C27 C26 -158.21(17) . . . .
C1 Rh2 C27 C28 81.5(2) . . . .
C1 B4 B8 Rh2 -57.48(17) . . . .
C1 B4 B8 B7 -4.9(3) . . . .
C1 B4 B8 B9 97.0(2) . . . .
C1 B4 B8 B12 58.4(3) . . . .
C1 B4 B5 B6 -35.0(2) . . . .
C1 B4 B5 B9 -136.8(3) . . . .
C1 B4 B5 B10 -97.9(3) . . . .
C1 B4 B9 B8 -102.8(2) . . . .
C1 B4 B9 B5 37.1(2) . . . .
C1 B4 B9 B12 -64.2(3) . . . .
C1 B4 B9 B10 -1.2(3) . . . .
C1 B6 B5 B4 35.2(2) . . . .
C1 B6 B5 B9 98.8(2) . . . .
C1 B6 B5 B10 137.0(2) . . . .
C1 B6 B11 Rh2 -28.3(2) . . . .
C1 B6 B11 C2 -133.9(2) . . . .
C1 B6 B11 B7 -102.6(2) . . . .
C1 B6 B10 C2 96.7(2) . . . .
C1 B6 B10 B5 -37.8(2) . . . .
C1 B6 B10 B9 0.0(3) . . . .
C1 B6 B10 B12 63.5(3) . . . .
C1 B5 B9 B4 -37.7(2) . . . .
C1 B5 B9 B8 -0.6(3) . . . .
C1 B5 B9 B12 62.6(3) . . . .
C1 B5 B9 B10 99.1(2) . . . .
C1 B5 B10 C2 -2.3(3) . . . .
C1 B5 B10 B6 36.9(2) . . . .
C1 B5 B10 B9 -100.5(2) . . . .
C1 B5 B10 B12 -63.8(3) . . . .
Rh2 C1 B4 B8 55.60(17) . . . .
Rh2 C1 B4 B5 155.4(2) . . . .
Rh2 C1 B4 B9 117.9(2) . . . .
Rh2 C1 B6 C2 -13.7(3) . . . .
Rh2 C1 B6 B5 -113.6(2) . . . .
Rh2 C1 B6 B11 26.14(19) . . . .
Rh2 C1 B6 B10 -75.4(2) . . . .
Rh2 C1 B5 B4 -26.9(2) . . . .
Rh2 C1 B5 B6 112.7(2) . . . .
Rh2 C1 B5 B9 11.6(3) . . . .
Rh2 C1 B5 B10 74.9(3) . . . .
Rh2 C1 B11 C2 -117.29(17) . . . .
Rh2 C1 B11 B7 -57.21(16) . . . .
Rh2 C1 B11 B6 -155.42(18) . . . .
Rh2 B4 B8 B7 52.62(16) . . . .
Rh2 B4 B8 B9 154.5(2) . . . .
Rh2 B4 B8 B12 115.93(19) . . . .
Rh2 B4 B5 C1 27.8(2) . . . .
Rh2 B4 B5 B6 -7.2(4) . . . .
Rh2 B4 B5 B9 -109.0(3) . . . .
Rh2 B4 B5 B10 -70.1(3) . . . .
Rh2 B4 B9 B8 -27.4(2) . . . .
Rh2 B4 B9 B5 112.5(2) . . . .
Rh2 B4 B9 B12 11.2(3) . . . .
Rh2 B4 B9 B10 74.2(3) . . . .
Rh2 B8 B7 C2 111.98(18) . . . .
Rh2 B8 B7 B12 151.24(18) . . . .
Rh2 B8 B7 B11 51.29(15) . . . .
Rh2 B8 B9 B4 26.4(2) . . . .
Rh2 B8 B9 B5 -10.2(3) . . . .
Rh2 B8 B9 B12 -109.8(2) . . . .
Rh2 B8 B9 B10 -73.9(3) . . . .
Rh2 B8 B12 C2 9.9(3) . . . .
Rh2 B8 B12 B7 -30.6(2) . . . .
Rh2 B8 B12 B9 108.2(2) . . . .
Rh2 B8 B12 B10 71.9(3) . . . .
Rh2 B7 B12 C2 -102.8(2) . . . .
Rh2 B7 B12 B8 30.8(2) . . . .
Rh2 B7 B12 B9 -6.6(3) . . . .
Rh2 B7 B12 B10 -70.6(3) . . . .
Rh2 B7 B11 C1 59.55(17) . . . .
Rh2 B7 B11 C2 150.81(18) . . . .
Rh2 B7 B11 B6 119.9(2) . . . .
Rh2 C22 C23 C24 104.6(3) . . . .
Rh2 C22 C29 C28 13.1(3) . . . .
Rh2 C23 C24 C25 31.1(3) . . . .
Rh2 C26 C27 C28 104.7(3) . . . .
Rh2 C27 C28 C29 33.2(3) . . . .
N2 C5 C6 N1 0.0(3) . . . .
C2 C3 C4 N2 -175.9(2) . . . .
C2 B7 B12 B8 133.6(2) . . . .
C2 B7 B12 B9 96.2(2) . . . .
C2 B7 B12 B10 32.2(2) . . . .
C2 B7 B11 C1 -91.3(2) . . . .
C2 B7 B11 Rh2 -150.81(18) . . . .
C2 B7 B11 B6 -30.9(2) . . . .
C2 B6 B5 C1 -97.5(2) . . . .
C2 B6 B5 B4 -62.2(3) . . . .
C2 B6 B5 B9 1.3(3) . . . .
C2 B6 B5 B10 39.59(19) . . . .
C2 B6 B11 C1 133.9(2) . . . .
C2 B6 B11 Rh2 105.7(2) . . . .
C2 B6 B11 B7 31.3(2) . . . .
C2 B6 B10 B5 -134.5(2) . . . .
C2 B6 B10 B9 -96.7(2) . . . .
C2 B6 B10 B12 -33.2(2) . . . .
C2 B12 B10 B6 33.2(2) . . . .
C2 B12 B10 B5 96.7(2) . . . .
C2 B12 B10 B9 133.2(2) . . . .
N3 Rh1 C7 N1 88.7(2) . . . .
N3 Rh1 C7 N2 -90.5(2) . . . .
N3 Rh1 C12 C13 -174.9(2) . . . .
N3 Rh1 C12 C19 -53.8(4) . . . .
N3 Rh1 C13 C12 171.6(3) . . . .
N3 Rh1 C13 C14 51.2(5) . . . .
N3 Rh1 C16 C15 -146.9(3) . . . .
N3 Rh1 C16 C17 89.3(2) . . . .
N3 Rh1 C17 C16 -91.1(2) . . . .
N3 Rh1 C17 C18 151.1(3) . . . .
C3 C2 B7 Rh2 -142.1(2) . . . .
C3 C2 B7 B8 147.0(2) . . . .
C3 C2 B7 B12 107.0(3) . . . .
C3 C2 B7 B11 -113.4(3) . . . .
C3 C2 B6 C1 153.4(2) . . . .
C3 C2 B6 B5 -145.0(2) . . . .
C3 C2 B6 B11 114.2(2) . . . .
C3 C2 B6 B10 -105.0(2) . . . .
C3 C2 B12 B8 -151.2(2) . . . .
C3 C2 B12 B7 -110.6(2) . . . .
C3 C2 B12 B9 145.8(2) . . . .
C3 C2 B12 B10 105.1(2) . . . .
C3 C2 B11 C1 -144.4(2) . . . .
C3 C2 B11 Rh2 140.5(2) . . . .
C3 C2 B11 B7 109.3(3) . . . .
C3 C2 B11 B6 -106.4(3) . . . .
C3 C2 B10 B6 108.6(2) . . . .
C3 C2 B10 B5 148.4(2) . . . .
C3 C2 B10 B9 -149.7(2) . . . .
C3 C2 B10 B12 -108.8(3) . . . .
C4 N2 C5 C6 172.5(2) . . . .
C4 N2 C7 Rh1 7.0(3) . . . .
C4 N2 C7 N1 -172.4(2) . . . .
B4 C1 Rh2 B8 -40.45(18) . . . .
B4 C1 Rh2 B7 -88.00(18) . . . .
B4 C1 Rh2 B11 -129.2(2) . . . .
B4 C1 Rh2 C22 149.98(18) . . . .
B4 C1 Rh2 C23 -176.98(18) . . . .
B4 C1 Rh2 C26 42.1(3) . . . .
B4 C1 Rh2 C27 65.66(19) . . . .
B4 C1 B6 C2 61.0(3) . . . .
B4 C1 B6 B5 -38.9(2) . . . .
B4 C1 B6 B11 100.8(2) . . . .
B4 C1 B6 B10 -0.8(3) . . . .
B4 C1 B5 B6 139.6(2) . . . .
B4 C1 B5 B9 38.5(2) . . . .
B4 C1 B5 B10 101.8(3) . . . .
B4 C1 B11 Rh2 48.15(18) . . . .
B4 C1 B11 C2 -69.1(2) . . . .
B4 C1 B11 B7 -9.1(3) . . . .
B4 C1 B11 B6 -107.3(2) . . . .
B4 Rh2 B8 B7 -123.9(2) . . . .
B4 Rh2 B8 B9 -25.0(2) . . . .
B4 Rh2 B8 B12 -95.0(2) . . . .
B4 Rh2 B7 C2 -56.01(19) . . . .
B4 Rh2 B7 B8 38.89(15) . . . .
B4 Rh2 B7 B12 10.2(2) . . . .
B4 Rh2 B7 B11 -83.43(15) . . . .
B4 Rh2 B11 C1 -33.70(16) . . . .
B4 Rh2 B11 C2 59.1(2) . . . .
B4 Rh2 B11 B7 87.52(16) . . . .
B4 Rh2 B11 B6 -9.0(2) . . . .
B4 Rh2 C22 C23 169.23(19) . . . .
B4 Rh2 C22 C29 -73.2(3) . . . .
B4 Rh2 C23 C22 -76.9(11) . . . .
B4 Rh2 C23 C24 164.0(10) . . . .
B4 Rh2 C26 C25 -174.8(2) . . . .
B4 Rh2 C26 C27 66.7(2) . . . .
B4 Rh2 C27 C26 -118.35(19) . . . .
B4 Rh2 C27 C28 121.4(2) . . . .
B4 B8 B7 Rh2 -51.80(17) . . . .
B4 B8 B7 C2 60.2(3) . . . .
B4 B8 B7 B12 99.4(2) . . . .
B4 B8 B7 B11 -0.5(3) . . . .
B4 B8 B9 B5 -36.7(2) . . . .
B4 B8 B9 B12 -136.2(2) . . . .
B4 B8 B9 B10 -100.3(3) . . . .
B4 B8 B12 C2 -60.1(3) . . . .
B4 B8 B12 B7 -100.5(2) . . . .
B4 B8 B12 B9 38.2(2) . . . .
B4 B8 B12 B10 1.9(3) . . . .
B4 B5 B9 B8 37.1(2) . . . .
B4 B5 B9 B12 100.3(2) . . . .
B4 B5 B9 B10 136.7(2) . . . .
B4 B5 B10 C2 59.4(3) . . . .
B4 B5 B10 B6 98.6(2) . . . .
B4 B5 B10 B9 -38.8(2) . . . .
B4 B5 B10 B12 -2.1(3) . . . .
B4 B9 B12 C2 60.1(3) . . . .
B4 B9 B12 B8 -39.6(2) . . . .
B4 B9 B12 B7 -2.5(3) . . . .
B4 B9 B12 B10 100.3(3) . . . .
B4 B9 B10 C2 -60.5(3) . . . .
B4 B9 B10 B6 0.8(3) . . . .
B4 B9 B10 B5 38.7(2) . . . .
B4 B9 B10 B12 -100.6(2) . . . .
C5 N2 C4 C3 -83.0(3) . . . .
C5 N2 C7 Rh1 179.45(18) . . . .
C5 N2 C7 N1 0.1(3) . . . .
B8 Rh2 B4 C1 121.6(2) . . . .
B8 Rh2 B4 B5 96.7(3) . . . .
B8 Rh2 B4 B9 25.6(2) . . . .
B8 Rh2 B7 C2 -94.9(2) . . . .
B8 Rh2 B7 B12 -28.65(18) . . . .
B8 Rh2 B7 B11 -122.31(19) . . . .
B8 Rh2 B11 C1 -82.76(16) . . . .
B8 Rh2 B11 C2 10.1(2) . . . .
B8 Rh2 B11 B7 38.46(15) . . . .
B8 Rh2 B11 B6 -58.0(2) . . . .
B8 Rh2 C22 C23 30.6(6) . . . .
B8 Rh2 C22 C29 148.2(5) . . . .
B8 Rh2 C23 C22 -172.66(17) . . . .
B8 Rh2 C23 C24 68.2(3) . . . .
B8 Rh2 C26 C25 -126.8(2) . . . .
B8 Rh2 C26 C27 114.67(19) . . . .
B8 Rh2 C27 C26 -73.19(19) . . . .
B8 Rh2 C27 C28 166.5(2) . . . .
B8 B4 B5 C1 101.2(2) . . . .
B8 B4 B5 B6 66.2(3) . . . .
B8 B4 B5 B9 -35.6(2) . . . .
B8 B4 B5 B10 3.3(3) . . . .
B8 B4 B9 B5 140.0(2) . . . .
B8 B4 B9 B12 38.6(2) . . . .
B8 B4 B9 B10 101.6(2) . . . .
B8 B7 B12 C2 -133.6(2) . . . .
B8 B7 B12 B9 -37.4(2) . . . .
B8 B7 B12 B10 -101.4(3) . . . .
B8 B7 B11 C1 5.8(3) . . . .
B8 B7 B11 Rh2 -53.76(16) . . . .
B8 B7 B11 C2 97.0(2) . . . .
B8 B7 B11 B6 66.1(3) . . . .
B8 B9 B12 C2 99.6(2) . . . .
B8 B9 B12 B7 37.1(2) . . . .
B8 B9 B12 B10 139.8(2) . . . .
B8 B9 B10 C2 4.3(3) . . . .
B8 B9 B10 B6 65.6(3) . . . .
B8 B9 B10 B5 103.5(3) . . . .
B8 B9 B10 B12 -35.7(2) . . . .
B8 B12 B10 C2 -96.6(2) . . . .
B8 B12 B10 B6 -63.4(3) . . . .
B8 B12 B10 B5 0.1(3) . . . .
B8 B12 B10 B9 36.6(2) . . . .
C6 N1 C7 Rh1 -179.4(2) . . . .
C6 N1 C7 N2 -0.1(3) . . . .
C6 N1 C8 C9 164.5(3) . . . .
C6 N1 C8 C10 -73.6(3) . . . .
C6 N1 C8 C11 46.5(3) . . . .
B7 Rh2 B4 C1 83.97(17) . . . .
B7 Rh2 B4 B8 -37.66(15) . . . .
B7 Rh2 B4 B5 59.0(3) . . . .
B7 Rh2 B4 B9 -12.1(2) . . . .
B7 Rh2 B8 B4 123.9(2) . . . .
B7 Rh2 B8 B9 98.9(3) . . . .
B7 Rh2 B8 B12 28.9(2) . . . .
B7 Rh2 B11 C1 -121.22(19) . . . .
B7 Rh2 B11 C2 -28.37(18) . . . .
B7 Rh2 B11 B6 -96.5(2) . . . .
B7 Rh2 C22 C23 49.2(2) . . . .
B7 Rh2 C22 C29 166.8(2) . . . .
B7 Rh2 C23 C22 -140.54(18) . . . .
B7 Rh2 C23 C24 100.3(2) . . . .
B7 Rh2 C26 C25 -85.3(3) . . . .
B7 Rh2 C26 C27 156.21(17) . . . .
B7 Rh2 C27 C26 -48.4(3) . . . .
B7 Rh2 C27 C28 -168.7(2) . . . .
B7 C2 C3 C4 67.1(3) . . . .
B7 C2 B6 C1 3.8(3) . . . .
B7 C2 B6 B5 65.4(3) . . . .
B7 C2 B6 B11 -35.5(2) . . . .
B7 C2 B6 B10 105.3(2) . . . .
B7 C2 B12 B8 -40.6(2) . . . .
B7 C2 B12 B9 -103.5(2) . . . .
B7 C2 B12 B10 -144.3(2) . . . .
B7 C2 B11 C1 106.3(2) . . . .
B7 C2 B11 Rh2 31.15(19) . . . .
B7 C2 B11 B6 144.3(2) . . . .
B7 C2 B10 B6 -107.9(2) . . . .
B7 C2 B10 B5 -68.1(3) . . . .
B7 C2 B10 B9 -6.2(3) . . . .
B7 C2 B10 B12 34.6(2) . . . .
B7 B8 B9 B4 99.0(2) . . . .
B7 B8 B9 B5 62.4(3) . . . .
B7 B8 B9 B12 -37.2(2) . . . .
B7 B8 B9 B10 -1.3(3) . . . .
B7 B8 B12 C2 40.46(19) . . . .
B7 B8 B12 B9 138.7(2) . . . .
B7 B8 B12 B10 102.4(2) . . . .
B7 B12 B10 C2 -32.5(2) . . . .
B7 B12 B10 B6 0.7(3) . . . .
B7 B12 B10 B5 64.2(3) . . . .
B7 B12 B10 B9 100.7(3) . . . .
C7 Rh1 N3 C20 -122(4) . . . .
C7 Rh1 C12 C13 94.23(18) . . . .
C7 Rh1 C12 C19 -144.6(2) . . . .
C7 Rh1 C13 C12 -87.23(18) . . . .
C7 Rh1 C13 C14 152.4(2) . . . .
C7 Rh1 C16 C15 -55.2(5) . . . .
C7 Rh1 C16 C17 -178.9(3) . . . .
C7 Rh1 C17 C16 179.0(3) . . . .
C7 Rh1 C17 C18 61.3(5) . . . .
C7 N1 C6 C5 0.1(3) . . . .
C7 N1 C8 C9 -17.5(4) . . . .
C7 N1 C8 C10 104.4(3) . . . .
C7 N1 C8 C11 -135.4(3) . . . .
C7 N2 C4 C3 88.5(3) . . . .
C7 N2 C5 C6 0.0(3) . . . .
B6 C1 Rh2 B4 102.7(3) . . . .
B6 C1 Rh2 B8 62.3(2) . . . .
B6 C1 Rh2 B7 14.7(2) . . . .
B6 C1 Rh2 B11 -26.5(2) . . . .
B6 C1 Rh2 C22 -107.3(2) . . . .
B6 C1 Rh2 C23 -74.3(3) . . . .
B6 C1 Rh2 C26 144.8(2) . . . .
B6 C1 Rh2 C27 168.4(2) . . . .
B6 C1 B4 Rh2 -116.7(2) . . . .
B6 C1 B4 B8 -61.0(3) . . . .
B6 C1 B4 B5 38.8(2) . . . .
B6 C1 B4 B9 1.3(3) . . . .
B6 C1 B5 B4 -139.6(2) . . . .
B6 C1 B5 B9 -101.1(3) . . . .
B6 C1 B5 B10 -37.8(2) . . . .
B6 C1 B11 Rh2 155.42(18) . . . .
B6 C1 B11 C2 38.13(19) . . . .
B6 C1 B11 B7 98.2(2) . . . .
B6 C2 C3 C4 -81.7(3) . . . .
B6 C2 B7 Rh2 6.8(3) . . . .
B6 C2 B7 B8 -64.1(3) . . . .
B6 C2 B7 B12 -104.1(3) . . . .
B6 C2 B7 B11 35.5(2) . . . .
B6 C2 B12 B8 67.9(3) . . . .
B6 C2 B12 B7 108.4(2) . . . .
B6 C2 B12 B9 4.9(3) . . . .
B6 C2 B12 B10 -35.8(2) . . . .
B6 C2 B11 C1 -38.00(19) . . . .
B6 C2 B11 Rh2 -113.1(2) . . . .
B6 C2 B11 B7 -144.3(2) . . . .
B6 C2 B10 B5 39.8(2) . . . .
B6 C2 B10 B9 101.7(2) . . . .
B6 C2 B10 B12 142.5(2) . . . .
B6 B5 B9 B4 -98.7(2) . . . .
B6 B5 B9 B8 -61.7(3) . . . .
B6 B5 B9 B12 1.6(3) . . . .
B6 B5 B9 B10 38.0(2) . . . .
B6 B5 B10 C2 -39.19(19) . . . .
B6 B5 B10 B9 -137.4(2) . . . .
B6 B5 B10 B12 -100.7(2) . . . .
C8 N1 C6 C5 178.4(2) . . . .
C8 N1 C7 Rh1 2.4(4) . . . .
C8 N1 C7 N2 -178.3(2) . . . .
B5 C1 Rh2 B4 26.3(2) . . . .
B5 C1 Rh2 B8 -14.2(2) . . . .
B5 C1 Rh2 B7 -61.7(2) . . . .
B5 C1 Rh2 B11 -102.9(3) . . . .
B5 C1 Rh2 C22 176.3(2) . . . .
B5 C1 Rh2 C23 -150.7(2) . . . .
B5 C1 Rh2 C26 68.4(3) . . . .
B5 C1 Rh2 C27 92.0(2) . . . .
B5 C1 B4 Rh2 -155.4(2) . . . .
B5 C1 B4 B8 -99.8(2) . . . .
B5 C1 B4 B9 -37.5(2) . . . .
B5 C1 B6 C2 99.9(2) . . . .
B5 C1 B6 B11 139.8(2) . . . .
B5 C1 B6 B10 38.2(2) . . . .
B5 C1 B11 Rh2 116.4(2) . . . .
B5 C1 B11 C2 -0.9(3) . . . .
B5 C1 B11 B7 59.2(3) . . . .
B5 C1 B11 B6 -39.1(2) . . . .
B5 B4 B8 Rh2 -119.1(2) . . . .
B5 B4 B8 B7 -66.5(3) . . . .
B5 B4 B8 B9 35.4(2) . . . .
B5 B4 B8 B12 -3.2(3) . . . .
B5 B4 B9 B8 -140.0(2) . . . .
B5 B4 B9 B12 -101.3(2) . . . .
B5 B4 B9 B10 -38.3(2) . . . .
B5 B6 B11 C1 35.5(2) . . . .
B5 B6 B11 Rh2 7.3(3) . . . .
B5 B6 B11 C2 -98.4(2) . . . .
B5 B6 B11 B7 -67.1(3) . . . .
B5 B6 B10 C2 134.5(2) . . . .
B5 B6 B10 B9 37.8(2) . . . .
B5 B6 B10 B12 101.3(2) . . . .
B5 B9 B12 C2 -3.8(3) . . . .
B5 B9 B12 B8 -103.4(2) . . . .
B5 B9 B12 B7 -66.3(3) . . . .
B5 B9 B12 B10 36.4(2) . . . .
B5 B9 B10 C2 -99.2(2) . . . .
B5 B9 B10 B6 -37.9(2) . . . .
B5 B9 B10 B12 -139.2(2) . . . .
B9 B4 B8 Rh2 -154.5(2) . . . .
B9 B4 B8 B7 -101.9(2) . . . .
B9 B4 B8 B12 -38.6(2) . . . .
B9 B4 B5 C1 136.8(3) . . . .
B9 B4 B5 B6 101.8(3) . . . .
B9 B4 B5 B10 38.9(2) . . . .
B9 B8 B7 Rh2 -114.2(2) . . . .
B9 B8 B7 C2 -2.2(3) . . . .
B9 B8 B7 B12 37.0(2) . . . .
B9 B8 B7 B11 -62.9(3) . . . .
B9 B8 B12 C2 -98.3(2) . . . .
B9 B8 B12 B7 -138.7(2) . . . .
B9 B8 B12 B10 -36.3(2) . . . .
B9 B5 B10 C2 98.2(2) . . . .
B9 B5 B10 B6 137.4(2) . . . .
B9 B5 B10 B12 36.7(2) . . . .
B9 B12 B10 C2 -133.2(2) . . . .
B9 B12 B10 B6 -100.0(3) . . . .
B9 B12 B10 B5 -36.5(2) . . . .
B12 C2 C3 C4 138.7(2) . . . .
B12 C2 B7 Rh2 110.9(2) . . . .
B12 C2 B7 B8 40.1(2) . . . .
B12 C2 B7 B11 139.6(2) . . . .
B12 C2 B6 C1 -65.6(3) . . . .
B12 C2 B6 B5 -4.0(3) . . . .
B12 C2 B6 B11 -104.9(2) . . . .
B12 C2 B6 B10 36.0(2) . . . .
B12 C2 B11 C1 67.8(2) . . . .
B12 C2 B11 Rh2 -7.3(3) . . . .
B12 C2 B11 B7 -38.5(2) . . . .
B12 C2 B11 B6 105.8(2) . . . .
B12 C2 B10 B6 -142.5(2) . . . .
B12 C2 B10 B5 -102.8(2) . . . .
B12 C2 B10 B9 -40.8(2) . . . .
B12 B8 B7 Rh2 -151.24(18) . . . .
B12 B8 B7 C2 -39.3(2) . . . .
B12 B8 B7 B11 -99.9(2) . . . .
B12 B8 B9 B4 136.2(2) . . . .
B12 B8 B9 B5 99.6(3) . . . .
B12 B8 B9 B10 35.9(2) . . . .
B12 B7 B11 C1 -56.4(3) . . . .
B12 B7 B11 Rh2 -115.9(2) . . . .
B12 B7 B11 C2 34.9(2) . . . .
B12 B7 B11 B6 3.9(3) . . . .
B12 B9 B10 C2 40.1(2) . . . .
B12 B9 B10 B6 101.4(2) . . . .
B12 B9 B10 B5 139.2(2) . . . .
B11 C1 Rh2 B4 129.2(2) . . . .
B11 C1 Rh2 B8 88.75(17) . . . .
B11 C1 Rh2 B7 41.20(15) . . . .
B11 C1 Rh2 C22 -80.82(17) . . . .
B11 C1 Rh2 C23 -47.8(2) . . . .
B11 C1 Rh2 C26 171.32(19) . . . .
B11 C1 Rh2 C27 -165.15(16) . . . .
B11 C1 B4 Rh2 -46.99(18) . . . .
B11 C1 B4 B8 8.6(3) . . . .
B11 C1 B4 B5 108.4(2) . . . .
B11 C1 B4 B9 70.9(3) . . . .
B11 C1 B6 C2 -39.80(19) . . . .
B11 C1 B6 B5 -139.8(2) . . . .
B11 C1 B6 B10 -101.6(2) . . . .
B11 C1 B5 B4 -99.7(3) . . . .
B11 C1 B5 B6 39.9(2) . . . .
B11 C1 B5 B9 -61.2(3) . . . .
B11 C1 B5 B10 2.1(3) . . . .
B11 Rh2 B4 C1 34.01(16) . . . .
B11 Rh2 B4 B8 -87.63(16) . . . .
B11 Rh2 B4 B5 9.0(3) . . . .
B11 Rh2 B4 B9 -62.0(2) . . . .
B11 Rh2 B8 B4 83.50(16) . . . .
B11 Rh2 B8 B7 -40.37(15) . . . .
B11 Rh2 B8 B9 58.5(2) . . . .
B11 Rh2 B8 B12 -11.5(2) . . . .
B11 Rh2 B7 C2 27.42(17) . . . .
B11 Rh2 B7 B8 122.31(19) . . . .
B11 Rh2 B7 B12 93.7(2) . . . .
B11 Rh2 C22 C23 91.45(18) . . . .
B11 Rh2 C22 C29 -151.0(2) . . . .
B11 Rh2 C23 C22 -91.16(18) . . . .
B11 Rh2 C23 C24 149.7(2) . . . .
B11 Rh2 C26 C25 -55.9(6) . . . .
B11 Rh2 C26 C27 -174.4(5) . . . .
B11 Rh2 C27 C26 177.4(2) . . . .
B11 Rh2 C27 C28 57.1(4) . . . .
B11 C2 C3 C4 -7.9(3) . . . .
B11 C2 B7 Rh2 -28.73(17) . . . .
B11 C2 B7 B8 -99.6(2) . . . .
B11 C2 B7 B12 -139.6(2) . . . .
B11 C2 B6 C1 39.27(19) . . . .
B11 C2 B6 B5 100.9(2) . . . .
B11 C2 B6 B10 140.9(2) . . . .
B11 C2 B12 B8 -1.7(3) . . . .
B11 C2 B12 B7 38.9(2) . . . .
B11 C2 B12 B9 -64.7(3) . . . .
B11 C2 B12 B10 -105.4(2) . . . .
B11 C2 B10 B6 -37.9(2) . . . .
B11 C2 B10 B5 1.9(3) . . . .
B11 C2 B10 B9 63.8(3) . . . .
B11 C2 B10 B12 104.6(2) . . . .
B11 B7 B12 C2 -35.1(2) . . . .
B11 B7 B12 B8 98.5(2) . . . .
B11 B7 B12 B9 61.1(3) . . . .
B11 B7 B12 B10 -2.9(3) . . . .
B11 B6 B5 C1 -35.2(2) . . . .
B11 B6 B5 B4 0.1(3) . . . .
B11 B6 B5 B9 63.6(3) . . . .
B11 B6 B5 B10 101.9(2) . . . .
B11 B6 B10 C2 35.0(2) . . . .
B11 B6 B10 B5 -99.5(2) . . . .
B11 B6 B10 B9 -61.7(3) . . . .
B11 B6 B10 B12 1.9(3) . . . .
C12 Rh1 N3 C20 147(4) . . . .
C12 Rh1 C7 N1 -115.5(2) . . . .
C12 Rh1 C7 N2 65.3(2) . . . .
C12 Rh1 C13 C14 -120.4(3) . . . .
C12 Rh1 C16 C15 56.4(3) . . . .
C12 Rh1 C16 C17 -67.4(2) . . . .
C12 Rh1 C17 C16 111.8(2) . . . .
C12 Rh1 C17 C18 -5.9(3) . . . .
C12 C13 C14 C15 -83.3(5) . . . .
B10 C2 C3 C4 -151.2(2) . . . .
B10 C2 B7 Rh2 76.2(2) . . . .
B10 C2 B7 B8 5.4(3) . . . .
B10 C2 B7 B12 -34.7(2) . . . .
B10 C2 B7 B11 105.0(2) . . . .
B10 C2 B6 C1 -101.6(2) . . . .
B10 C2 B6 B5 -40.0(2) . . . .
B10 C2 B6 B11 -140.9(2) . . . .
B10 C2 B12 B8 103.7(2) . . . .
B10 C2 B12 B7 144.3(2) . . . .
B10 C2 B12 B9 40.7(2) . . . .
B10 C2 B11 C1 -0.6(3) . . . .
B10 C2 B11 Rh2 -75.8(2) . . . .
B10 C2 B11 B7 -106.9(2) . . . .
B10 C2 B11 B6 37.4(2) . . . .
B10 B6 B5 C1 -137.0(2) . . . .
B10 B6 B5 B4 -101.8(3) . . . .
B10 B6 B5 B9 -38.3(2) . . . .
B10 B6 B11 C1 99.0(2) . . . .
B10 B6 B11 Rh2 70.7(3) . . . .
B10 B6 B11 C2 -34.9(2) . . . .
B10 B6 B11 B7 -3.6(3) . . . .
B10 B5 B9 B4 -136.7(2) . . . .
B10 B5 B9 B8 -99.7(3) . . . .
B10 B5 B9 B12 -36.4(2) . . . .
B10 B9 B12 C2 -40.2(2) . . . .
B10 B9 B12 B8 -139.8(2) . . . .
B10 B9 B12 B7 -102.8(2) . . . .
C13 Rh1 N3 C20 -20(4) . . . .
C13 Rh1 C7 N1 -77.1(2) . . . .
C13 Rh1 C7 N2 103.6(2) . . . .
C13 Rh1 C12 C19 121.1(3) . . . .
C13 Rh1 C16 C15 20.4(3) . . . .
C13 Rh1 C16 C17 -103.3(2) . . . .
C13 Rh1 C17 C16 74.6(2) . . . .
C13 Rh1 C17 C18 -43.2(3) . . . .
C13 C12 C19 C18 51.9(5) . . . .
C13 C14 C15 C16 20.8(6) . . . .
C14 C15 C16 Rh1 -28.1(5) . . . .
C14 C15 C16 C17 52.4(6) . . . .
C15 C16 C17 Rh1 -99.1(3) . . . .
C15 C16 C17 C18 3.7(5) . . . .
C16 Rh1 N3 C20 41(4) . . . .
C16 Rh1 C7 N1 -3.2(5) . . . .
C16 Rh1 C7 N2 177.5(3) . . . .
C16 Rh1 C12 C13 -69.53(19) . . . .
C16 Rh1 C12 C19 51.6(2) . . . .
C16 Rh1 C13 C12 109.74(19) . . . .
C16 Rh1 C13 C14 -10.7(2) . . . .
C16 Rh1 C17 C18 -117.7(4) . . . .
C16 C17 C18 C19 -88.3(5) . . . .
C17 Rh1 N3 C20 77(4) . . . .
C17 Rh1 C7 N1 178.7(3) . . . .
C17 Rh1 C7 N2 -0.5(5) . . . .
C17 Rh1 C12 C13 -103.13(19) . . . .
C17 Rh1 C12 C19 18.0(2) . . . .
C17 Rh1 C13 C12 74.48(19) . . . .
C17 Rh1 C13 C14 -45.9(2) . . . .
C17 Rh1 C16 C15 123.7(4) . . . .
C17 C18 C19 C12 24.6(6) . . . .
C19 C12 C13 Rh1 -102.2(3) . . . .
C19 C12 C13 C14 2.3(5) . . . .
C22 Rh2 B4 C1 -49.0(2) . . . .
C22 Rh2 B4 B8 -170.62(17) . . . .
C22 Rh2 B4 B5 -74.0(3) . . . .
C22 Rh2 B4 B9 -145.0(2) . . . .
C22 Rh2 B8 B4 145.4(5) . . . .
C22 Rh2 B8 B7 21.5(6) . . . .
C22 Rh2 B8 B9 120.4(6) . . . .
C22 Rh2 B8 B12 50.4(7) . . . .
C22 Rh2 B7 C2 89.7(2) . . . .
C22 Rh2 B7 B8 -175.37(14) . . . .
C22 Rh2 B7 B12 155.98(19) . . . .
C22 Rh2 B7 B11 62.32(17) . . . .
C22 Rh2 B11 C1 106.60(16) . . . .
C22 Rh2 B11 C2 -160.6(2) . . . .
C22 Rh2 B11 B7 -132.18(15) . . . .
C22 Rh2 B11 B6 131.3(2) . . . .
C22 Rh2 C23 C24 -119.1(3) . . . .
C22 Rh2 C26 C25 43.0(2) . . . .
C22 Rh2 C26 C27 -75.48(19) . . . .
C22 Rh2 C27 C26 100.34(19) . . . .
C22 Rh2 C27 C28 -19.9(2) . . . .
C22 C23 C24 C25 -50.7(4) . . . .
C23 Rh2 B4 C1 19.5(11) . . . .
C23 Rh2 B4 B8 -102.1(11) . . . .
C23 Rh2 B4 B5 -5.5(12) . . . .
C23 Rh2 B4 B9 -76.5(11) . . . .
C23 Rh2 B8 B4 170.55(16) . . . .
C23 Rh2 B8 B7 46.7(2) . . . .
C23 Rh2 B8 B9 145.6(2) . . . .
C23 Rh2 B8 B12 75.6(3) . . . .
C23 Rh2 B7 C2 117.57(19) . . . .
C23 Rh2 B7 B8 -147.53(15) . . . .
C23 Rh2 B7 B12 -176.2(2) . . . .
C23 Rh2 B7 B11 90.16(15) . . . .
C23 Rh2 B11 C1 144.53(16) . . . .
C23 Rh2 B11 C2 -122.6(2) . . . .
C23 Rh2 B11 B7 -94.25(15) . . . .
C23 Rh2 B11 B6 169.3(2) . . . .
C23 Rh2 C22 C29 117.6(3) . . . .
C23 Rh2 C26 C25 5.7(2) . . . .
C23 Rh2 C26 C27 -112.78(19) . . . .
C23 Rh2 C27 C26 66.05(19) . . . .
C23 Rh2 C27 C28 -54.2(2) . . . .
C23 C22 C29 C28 94.5(3) . . . .
C23 C24 C25 C26 -26.3(4) . . . .
C24 C25 C26 Rh2 9.4(3) . . . .
C24 C25 C26 C27 92.7(4) . . . .
C25 C26 C27 Rh2 -108.2(3) . . . .
C25 C26 C27 C28 -3.6(5) . . . .
C26 Rh2 B4 C1 -156.48(16) . . . .
C26 Rh2 B4 B8 81.89(17) . . . .
C26 Rh2 B4 B5 178.5(2) . . . .
C26 Rh2 B4 B9 107.5(2) . . . .
C26 Rh2 B8 B4 -107.77(16) . . . .
C26 Rh2 B8 B7 128.37(15) . . . .
C26 Rh2 B8 B9 -132.7(2) . . . .
C26 Rh2 B8 B12 157.2(2) . . . .
C26 Rh2 B7 C2 -160.19(17) . . . .
C26 Rh2 B7 B8 -65.29(17) . . . .
C26 Rh2 B7 B12 -93.9(2) . . . .
C26 Rh2 B7 B11 172.39(14) . . . .
C26 Rh2 B11 C1 -155.1(5) . . . .
C26 Rh2 B11 C2 -62.2(6) . . . .
C26 Rh2 B11 B7 -33.9(6) . . . .
C26 Rh2 B11 B6 -130.3(5) . . . .
C26 Rh2 C22 C23 -76.88(19) . . . .
C26 Rh2 C22 C29 40.7(2) . . . .
C26 Rh2 C23 C22 99.21(19) . . . .
C26 Rh2 C23 C24 -19.9(2) . . . .
C26 Rh2 C27 C28 -120.3(3) . . . .
C26 C27 C28 C29 -48.3(4) . . . .
C27 Rh2 B4 C1 -122.19(17) . . . .
C27 Rh2 B4 B8 116.17(16) . . . .
C27 Rh2 B4 B5 -147.2(3) . . . .
C27 Rh2 B4 B9 141.8(2) . . . .
C27 Rh2 B8 B4 -71.66(17) . . . .
C27 Rh2 B8 B7 164.48(14) . . . .
C27 Rh2 B8 B9 -96.6(2) . . . .
C27 Rh2 B8 B12 -166.7(2) . . . .
C27 Rh2 B7 C2 -128.0(2) . . . .
C27 Rh2 B7 B8 -33.1(3) . . . .
C27 Rh2 B7 B12 -61.7(3) . . . .
C27 Rh2 B7 B11 -155.4(2) . . . .
C27 Rh2 B11 C1 32.7(3) . . . .
C27 Rh2 B11 C2 125.6(3) . . . .
C27 Rh2 B11 B7 154.0(2) . . . .
C27 Rh2 B11 B6 57.5(4) . . . .
C27 Rh2 C22 C23 -114.01(19) . . . .
C27 Rh2 C22 C29 3.6(2) . . . .
C27 Rh2 C23 C22 64.57(19) . . . .
C27 Rh2 C23 C24 -54.6(2) . . . .
C27 Rh2 C26 C25 118.5(3) . . . .
C27 C28 C29 C22 -29.9(4) . . . .
C29 C22 C23 Rh2 -106.9(3) . . . .
C29 C22 C23 C24 -2.3(4) . . . .
