#------------------------------------------------------------------------------
#$Date: 2017-04-05 12:17:29 +0300 (Wed, 05 Apr 2017) $
#$Revision: 194974 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/97/7119773.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7119773
loop_
_publ_author_name
'Zhang, Fan'
'Adolf, Cyril R. R.'
'Zigon, Nicolas'
'Ferlay, Sylvie'
'Kyritsakas, Nathalie'
'Hosseini, Mir Wais'
_publ_section_title
;
 Molecular tectonics: hierarchical organization of heterobimetallic
 coordination networks into heterotrimetallic core-shell crystals.
;
_journal_issue                   25
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3587
_journal_page_last               3590
_journal_paper_doi               10.1039/c7cc01455d
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         'C50 H38 Cl2 N2 P2 Pt Zn'
_chemical_formula_sum            'C50 H38 Cl2 N2 P2 Pt Zn'
_chemical_formula_weight         1060.12
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2017-02-22 deposited with the CCDC.
2017-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                95.2473(10)
_cell_angle_beta                 91.6860(10)
_cell_angle_gamma                98.5240(11)
_cell_formula_units_Z            2
_cell_length_a                   9.5502(4)
_cell_length_b                   9.6247(4)
_cell_length_c                   24.0632(8)
_cell_measurement_reflns_used    20000
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.54
_cell_measurement_theta_min      2.54
_cell_volume                     2176.16(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.944
_diffrn_measured_fraction_theta_max 0.886
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0270
_diffrn_reflns_av_unetI/netI     0.0460
_diffrn_reflns_Laue_measured_fraction_full 0.944
_diffrn_reflns_Laue_measured_fraction_max 0.886
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            20373
_diffrn_reflns_point_group_measured_fraction_full 0.944
_diffrn_reflns_point_group_measured_fraction_max 0.886
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.058
_diffrn_reflns_theta_min         2.150
_exptl_absorpt_coefficient_mu    3.995
_exptl_absorpt_correction_T_max  0.825
_exptl_absorpt_correction_T_min  0.767
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.618
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.070
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.050
_refine_diff_density_max         2.072
_refine_diff_density_min         -1.188
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     526
_refine_ls_number_reflns         11327
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0509
_refine_ls_R_factor_gt           0.0363
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0429P)²+0.8384P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0797
_refine_ls_wR_factor_ref         0.0850
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9058
_reflns_number_total             11327
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7cc01455d2.cif
_cod_data_source_block           e3205a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7119770--7119773.cif.
;
_cod_database_code               7119773
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.767
_shelx_estimated_absorpt_t_max   0.825
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pt1 Pt 1.0000 1.0000 0.5000 0.01767(5) Uani 1 2 d S . P
P1 P 0.84293(10) 0.84327(9) 0.44108(4) 0.01772(18) Uani 1 1 d . . .
C1 C 0.9067(4) 0.8130(3) 0.37062(14) 0.0213(7) Uani 1 1 d . . .
C2 C 1.0509(4) 0.8331(4) 0.36305(15) 0.0277(8) Uani 1 1 d . . .
H2 H 1.1153 0.8564 0.3945 0.033 Uiso 1 1 calc R U .
C3 C 1.1023(5) 0.8193(5) 0.30971(17) 0.0362(10) Uani 1 1 d . . .
H3 H 1.2016 0.8340 0.3048 0.043 Uiso 1 1 calc R U .
C4 C 1.0108(5) 0.7849(4) 0.26441(17) 0.0351(10) Uani 1 1 d . . .
H4 H 1.0462 0.7766 0.2280 0.042 Uiso 1 1 calc R U .
C5 C 0.8650(5) 0.7618(5) 0.27152(16) 0.0382(10) Uani 1 1 d . . .
H5 H 0.8009 0.7358 0.2401 0.046 Uiso 1 1 calc R U .
C6 C 0.8143(4) 0.7768(4) 0.32469(15) 0.0293(8) Uani 1 1 d . . .
H6 H 0.7151 0.7621 0.3296 0.035 Uiso 1 1 calc R U .
C7 C 0.6736(4) 0.9042(4) 0.43011(14) 0.0205(7) Uani 1 1 d . . .
C8 C 0.5518(4) 0.8090(4) 0.41240(15) 0.0266(8) Uani 1 1 d . . .
H8 H 0.5551 0.7104 0.4086 0.032 Uiso 1 1 calc R U .
C9 C 0.4274(4) 0.8579(4) 0.40054(17) 0.0318(9) Uani 1 1 d . . .
H9 H 0.3451 0.7930 0.3883 0.038 Uiso 1 1 calc R U .
C10 C 0.4211(5) 1.0017(4) 0.40640(18) 0.0342(9) Uani 1 1 d . . .
H10 H 0.3345 1.0350 0.3986 0.041 Uiso 1 1 calc R U .
C11 C 0.5414(5) 1.0964(4) 0.42366(18) 0.0353(10) Uani 1 1 d . . .
H11 H 0.5376 1.1948 0.4275 0.042 Uiso 1 1 calc R U .
C12 C 0.6670(4) 1.0479(4) 0.43526(16) 0.0269(8) Uani 1 1 d . . .
H12 H 0.7495 1.1134 0.4469 0.032 Uiso 1 1 calc R U .
C13 C 0.7966(4) 0.6698(3) 0.46510(14) 0.0196(7) Uani 1 1 d . . .
C14 C 0.8653(4) 0.5599(4) 0.44589(15) 0.0265(8) Uani 1 1 d . . .
H14 H 0.9315 0.5719 0.4174 0.032 Uiso 1 1 calc R U .
C15 C 0.8372(5) 0.4301(4) 0.46865(18) 0.0373(10) Uani 1 1 d . . .
H15 H 0.8847 0.3543 0.4555 0.045 Uiso 1 1 calc R U .
C16 C 0.7420(5) 0.4120(4) 0.50957(17) 0.0333(9) Uani 1 1 d . . .
H16 H 0.7230 0.3236 0.5247 0.040 Uiso 1 1 calc R U .
C17 C 0.6733(5) 0.5219(4) 0.52901(17) 0.0315(9) Uani 1 1 d . . .
H17 H 0.6070 0.5090 0.5575 0.038 Uiso 1 1 calc R U .
C18 C 0.7006(4) 0.6512(4) 0.50719(16) 0.0270(8) Uani 1 1 d . . .
H18 H 0.6538 0.7270 0.5209 0.032 Uiso 1 1 calc R U .
C19 C 0.9667(4) 0.8795(4) 0.56295(15) 0.0212(7) Uani 1 1 d . . .
C20 C 0.9492(4) 0.8080(4) 0.60105(16) 0.0257(8) Uani 1 1 d . . .
C21 C 0.9235(4) 0.7166(4) 0.64441(14) 0.0216(7) Uani 1 1 d . . .
C22 C 1.0286(4) 0.6524(4) 0.66852(15) 0.0277(8) Uani 1 1 d . . .
H22 H 1.1232 0.6701 0.6569 0.033 Uiso 1 1 calc R U .
C23 C 0.9942(5) 0.5631(4) 0.70930(17) 0.0324(9) Uani 1 1 d . . .
H23 H 1.0648 0.5178 0.7257 0.039 Uiso 1 1 calc R U .
C24 C 0.8574(5) 0.5401(4) 0.72610(17) 0.0312(9) Uani 1 1 d . . .
H24 H 0.8348 0.4787 0.7544 0.037 Uiso 1 1 calc R U .
N1 N 0.7543(4) 0.6015(3) 0.70391(13) 0.0261(7) Uani 1 1 d . . .
C25 C 0.7871(4) 0.6858(4) 0.66367(16) 0.0266(8) Uani 1 1 d . . .
H25 H 0.7136 0.7271 0.6473 0.032 Uiso 1 1 calc R U .
Zn1 Zn 0.55323(5) 0.59349(5) 0.73315(2) 0.02778(10) Uani 1 1 d . . .
Cl1 Cl 0.52782(16) 0.44385(13) 0.79804(5) 0.0511(3) Uani 1 1 d . . .
Cl2 Cl 0.40109(12) 0.58130(12) 0.66145(5) 0.0428(3) Uani 1 1 d . . .
N2 N 0.5842(4) 0.8008(3) 0.76913(13) 0.0269(7) Uani 1 1 d . . .
C26 C 0.5363(5) 0.9068(5) 0.74577(16) 0.0333(9) Uani 1 1 d . . .
H26 H 0.4815 0.8865 0.7116 0.040 Uiso 1 1 calc R U .
C27 C 0.5639(5) 1.0450(4) 0.76970(17) 0.0332(9) Uani 1 1 d . . .
H27 H 0.5266 1.1175 0.7525 0.040 Uiso 1 1 calc R U .
C28 C 0.6463(4) 1.0767(4) 0.81882(16) 0.0285(8) Uani 1 1 d . . .
H28 H 0.6671 1.1712 0.8355 0.034 Uiso 1 1 calc R U .
C29 C 0.6983(4) 0.9678(4) 0.84359(15) 0.0246(8) Uani 1 1 d . . .
C30 C 0.6627(4) 0.8306(4) 0.81683(15) 0.0269(8) Uani 1 1 d . . .
H30 H 0.6960 0.7552 0.8335 0.032 Uiso 1 1 calc R U .
C31 C 0.7857(4) 0.9881(4) 0.89402(15) 0.0256(8) Uani 1 1 d . . .
C32 C 0.8621(4) 0.9936(4) 0.93458(15) 0.0241(8) Uani 1 1 d . . .
Pt2 Pt 1.0000 1.0000 1.0000 0.01930(5) Uani 1 2 d S . P
P2 P 1.16231(10) 1.12471(9) 0.94734(4) 0.01891(18) Uani 1 1 d . . .
C33 C 1.1955(4) 1.0053(3) 0.88763(14) 0.0213(7) Uani 1 1 d . . .
C34 C 1.2826(4) 0.9043(4) 0.89535(16) 0.0272(8) Uani 1 1 d . . .
H34 H 1.3288 0.9024 0.9307 0.033 Uiso 1 1 calc R U .
C35 C 1.3018(5) 0.8065(4) 0.85138(17) 0.0326(9) Uani 1 1 d . . .
H35 H 1.3625 0.7385 0.8565 0.039 Uiso 1 1 calc R U .
C36 C 1.2334(5) 0.8074(4) 0.80012(17) 0.0341(10) Uani 1 1 d . . .
H36 H 1.2481 0.7410 0.7700 0.041 Uiso 1 1 calc R U .
C37 C 1.1447(5) 0.9037(4) 0.79285(17) 0.0344(10) Uani 1 1 d . . .
H37 H 1.0967 0.9030 0.7577 0.041 Uiso 1 1 calc R U .
C38 C 1.1237(4) 1.0036(4) 0.83668(15) 0.0286(8) Uani 1 1 d . . .
H38 H 1.0607 1.0695 0.8315 0.034 Uiso 1 1 calc R U .
C39 C 1.3355(4) 1.2024(4) 0.97799(14) 0.0216(7) Uani 1 1 d . . .
C40 C 1.3421(4) 1.2844(4) 1.02948(15) 0.0265(8) Uani 1 1 d . . .
H40 H 1.2583 1.2892 1.0494 0.032 Uiso 1 1 calc R U .
C41 C 1.4707(5) 1.3588(4) 1.05155(16) 0.0317(9) Uani 1 1 d . . .
H41 H 1.4744 1.4146 1.0864 0.038 Uiso 1 1 calc R U .
C42 C 1.5930(5) 1.3517(5) 1.02291(18) 0.0386(10) Uani 1 1 d . . .
H42 H 1.6806 1.4029 1.0380 0.046 Uiso 1 1 calc R U .
C43 C 1.5880(5) 1.2708(5) 0.97274(19) 0.0398(10) Uani 1 1 d . . .
H43 H 1.6729 1.2647 0.9536 0.048 Uiso 1 1 calc R U .
C44 C 1.4605(4) 1.1978(4) 0.94962(17) 0.0326(9) Uani 1 1 d . . .
H44 H 1.4581 1.1444 0.9143 0.039 Uiso 1 1 calc R U .
C45 C 1.1042(4) 1.2770(4) 0.91909(15) 0.0223(7) Uani 1 1 d . . .
C46 C 1.1825(5) 1.3462(4) 0.87941(15) 0.0284(8) Uani 1 1 d . . .
H46 H 1.2646 1.3117 0.8660 0.034 Uiso 1 1 calc R U .
C47 C 1.1424(5) 1.4641(4) 0.85943(18) 0.0391(11) Uani 1 1 d . . .
H47 H 1.1949 1.5084 0.8312 0.047 Uiso 1 1 calc R U .
C48 C 1.0265(6) 1.5190(5) 0.8799(2) 0.0458(12) Uani 1 1 d . . .
H48 H 1.0004 1.6019 0.8666 0.055 Uiso 1 1 calc R U .
C49 C 0.9493(6) 1.4521(5) 0.9199(2) 0.0500(13) Uani 1 1 d . . .
H49 H 0.8692 1.4892 0.9340 0.060 Uiso 1 1 calc R U .
C50 C 0.9868(5) 1.3313(4) 0.93982(19) 0.0353(10) Uani 1 1 d . . .
H50 H 0.9328 1.2860 0.9674 0.042 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C19 Pt1 C19 180.0 2_776 .
C19 Pt1 P1 91.70(10) 2_776 2_776
C19 Pt1 P1 88.29(10) . 2_776
C19 Pt1 P1 88.30(10) 2_776 .
C19 Pt1 P1 91.71(10) . .
P1 Pt1 P1 180.0 2_776 .
C13 P1 C7 104.48(16) . .
C13 P1 C1 105.86(15) . .
C7 P1 C1 104.30(16) . .
C13 P1 Pt1 114.84(11) . .
C7 P1 Pt1 113.00(11) . .
C1 P1 Pt1 113.36(12) . .
C6 C1 C2 119.2(3) . .
C6 C1 P1 121.6(3) . .
C2 C1 P1 119.1(3) . .
C1 C2 C3 120.4(4) . .
C1 C2 H2 119.8 . .
C3 C2 H2 119.8 . .
C4 C3 C2 120.2(4) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 120.0(4) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 119.6(4) . .
C6 C5 H5 120.2 . .
C4 C5 H5 120.2 . .
C1 C6 C5 120.6(4) . .
C1 C6 H6 119.7 . .
C5 C6 H6 119.7 . .
C12 C7 C8 119.2(4) . .
C12 C7 P1 119.6(3) . .
C8 C7 P1 121.0(3) . .
C9 C8 C7 120.1(3) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C8 C9 C10 120.4(4) . .
C8 C9 H9 119.8 . .
C10 C9 H9 119.8 . .
C11 C10 C9 119.8(4) . .
C11 C10 H10 120.1 . .
C9 C10 H10 120.1 . .
C12 C11 C10 120.1(4) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C7 120.4(4) . .
C11 C12 H12 119.8 . .
C7 C12 H12 119.8 . .
C14 C13 C18 119.7(3) . .
C14 C13 P1 120.6(3) . .
C18 C13 P1 119.5(3) . .
C13 C14 C15 119.7(4) . .
C13 C14 H14 120.1 . .
C15 C14 H14 120.1 . .
C16 C15 C14 120.4(4) . .
C16 C15 H15 119.8 . .
C14 C15 H15 119.8 . .
C15 C16 C17 120.0(4) . .
C15 C16 H16 120.0 . .
C17 C16 H16 120.0 . .
C16 C17 C18 120.3(4) . .
C16 C17 H17 119.9 . .
C18 C17 H17 119.9 . .
C17 C18 C13 119.9(3) . .
C17 C18 H18 120.1 . .
C13 C18 H18 120.1 . .
C20 C19 Pt1 178.8(3) . .
C19 C20 C21 176.7(4) . .
C22 C21 C25 116.9(3) . .
C22 C21 C20 123.2(4) . .
C25 C21 C20 119.8(3) . .
C23 C22 C21 119.6(4) . .
C23 C22 H22 120.2 . .
C21 C22 H22 120.2 . .
C24 C23 C22 119.6(4) . .
C24 C23 H23 120.2 . .
C22 C23 H23 120.2 . .
N1 C24 C23 122.1(4) . .
N1 C24 H24 118.9 . .
C23 C24 H24 118.9 . .
C25 N1 C24 118.3(4) . .
C25 N1 Zn1 116.6(3) . .
C24 N1 Zn1 124.7(3) . .
N1 C25 C21 123.5(4) . .
N1 C25 H25 118.2 . .
C21 C25 H25 118.2 . .
N1 Zn1 N2 95.11(13) . .
N1 Zn1 Cl2 108.80(10) . .
N2 Zn1 Cl2 107.09(10) . .
N1 Zn1 Cl1 108.68(10) . .
N2 Zn1 Cl1 110.86(9) . .
Cl2 Zn1 Cl1 122.77(5) . .
C30 N2 C26 118.5(3) . .
C30 N2 Zn1 117.7(3) . .
C26 N2 Zn1 123.7(3) . .
N2 C26 C27 122.3(4) . .
N2 C26 H26 118.9 . .
C27 C26 H26 118.9 . .
C26 C27 C28 119.5(4) . .
C26 C27 H27 120.2 . .
C28 C27 H27 120.2 . .
C27 C28 C29 119.1(4) . .
C27 C28 H28 120.4 . .
C29 C28 H28 120.4 . .
C28 C29 C30 117.3(3) . .
C28 C29 C31 124.1(3) . .
C30 C29 C31 118.6(3) . .
N2 C30 C29 123.3(3) . .
N2 C30 H30 118.4 . .
C29 C30 H30 118.4 . .
C32 C31 C29 174.1(4) . .
C31 C32 Pt2 176.6(3) . .
C32 Pt2 C32 180.0(2) . 2_777
C32 Pt2 P2 93.91(11) . 2_777
C32 Pt2 P2 86.09(11) 2_777 2_777
C32 Pt2 P2 86.09(11) . .
C32 Pt2 P2 93.91(11) 2_777 .
P2 Pt2 P2 180.00(3) 2_777 .
C39 P2 C45 100.93(17) . .
C39 P2 C33 105.95(17) . .
C45 P2 C33 106.51(16) . .
C39 P2 Pt2 120.09(12) . .
C45 P2 Pt2 115.09(13) . .
C33 P2 Pt2 107.25(12) . .
C38 C33 C34 119.7(3) . .
C38 C33 P2 121.0(3) . .
C34 C33 P2 119.0(3) . .
C35 C34 C33 119.9(4) . .
C35 C34 H34 120.1 . .
C33 C34 H34 120.1 . .
C36 C35 C34 120.4(4) . .
C36 C35 H35 119.8 . .
C34 C35 H35 119.8 . .
C37 C36 C35 119.9(4) . .
C37 C36 H36 120.1 . .
C35 C36 H36 120.1 . .
C36 C37 C38 120.7(4) . .
C36 C37 H37 119.6 . .
C38 C37 H37 119.6 . .
C33 C38 C37 119.3(4) . .
C33 C38 H38 120.3 . .
C37 C38 H38 120.3 . .
C44 C39 C40 118.5(4) . .
C44 C39 P2 122.8(3) . .
C40 C39 P2 118.4(3) . .
C41 C40 C39 120.4(4) . .
C41 C40 H40 119.8 . .
C39 C40 H40 119.8 . .
C42 C41 C40 120.1(4) . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
C43 C42 C41 120.1(4) . .
C43 C42 H42 120.0 . .
C41 C42 H42 120.0 . .
C42 C43 C44 120.7(4) . .
C42 C43 H43 119.7 . .
C44 C43 H43 119.7 . .
C43 C44 C39 120.3(4) . .
C43 C44 H44 119.8 . .
C39 C44 H44 119.8 . .
C46 C45 C50 119.1(4) . .
C46 C45 P2 120.2(3) . .
C50 C45 P2 120.5(3) . .
C47 C46 C45 120.6(4) . .
C47 C46 H46 119.7 . .
C45 C46 H46 119.7 . .
C46 C47 C48 120.6(4) . .
C46 C47 H47 119.7 . .
C48 C47 H47 119.7 . .
C49 C48 C47 119.2(4) . .
C49 C48 H48 120.4 . .
C47 C48 H48 120.4 . .
C48 C49 C50 121.0(4) . .
C48 C49 H49 119.5 . .
C50 C49 H49 119.5 . .
C49 C50 C45 119.5(4) . .
C49 C50 H50 120.3 . .
C45 C50 H50 120.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C19 1.995(4) 2_776
Pt1 C19 1.995(4) .
Pt1 P1 2.3127(9) 2_776
Pt1 P1 2.3127(9) .
P1 C13 1.814(4) .
P1 C7 1.820(4) .
P1 C1 1.831(3) .
C1 C6 1.379(5) .
C1 C2 1.381(5) .
C2 C3 1.390(5) .
C2 H2 0.9500 .
C3 C4 1.362(6) .
C3 H3 0.9500 .
C4 C5 1.395(6) .
C4 H4 0.9500 .
C5 C6 1.384(5) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C12 1.389(5) .
C7 C8 1.400(5) .
C8 C9 1.373(5) .
C8 H8 0.9500 .
C9 C10 1.388(5) .
C9 H9 0.9500 .
C10 C11 1.384(6) .
C10 H10 0.9500 .
C11 C12 1.379(6) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C14 1.377(5) .
C13 C18 1.392(5) .
C14 C15 1.402(5) .
C14 H14 0.9500 .
C15 C16 1.365(6) .
C15 H15 0.9500 .
C16 C17 1.379(6) .
C16 H16 0.9500 .
C17 C18 1.387(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C20 1.197(5) .
C20 C21 1.429(5) .
C21 C22 1.392(5) .
C21 C25 1.395(5) .
C22 C23 1.378(6) .
C22 H22 0.9500 .
C23 C24 1.372(6) .
C23 H23 0.9500 .
C24 N1 1.342(5) .
C24 H24 0.9500 .
N1 C25 1.335(5) .
N1 Zn1 2.058(3) .
C25 H25 0.9500 .
Zn1 N2 2.076(3) .
Zn1 Cl2 2.2062(12) .
Zn1 Cl1 2.2139(12) .
N2 C30 1.337(5) .
N2 C26 1.340(5) .
C26 C27 1.384(6) .
C26 H26 0.9500 .
C27 C28 1.385(6) .
C27 H27 0.9500 .
C28 C29 1.397(5) .
C28 H28 0.9500 .
C29 C30 1.405(5) .
C29 C31 1.434(5) .
C30 H30 0.9500 .
C31 C32 1.194(5) .
C32 Pt2 2.013(4) .
Pt2 C32 2.013(4) 2_777
Pt2 P2 2.3003(9) 2_777
Pt2 P2 2.3003(10) .
P2 C39 1.817(4) .
P2 C45 1.822(4) .
P2 C33 1.822(3) .
C33 C38 1.385(5) .
C33 C34 1.391(5) .
C34 C35 1.385(5) .
C34 H34 0.9500 .
C35 C36 1.380(6) .
C35 H35 0.9500 .
C36 C37 1.365(6) .
C36 H36 0.9500 .
C37 C38 1.400(5) .
C37 H37 0.9500 .
C38 H38 0.9500 .
C39 C44 1.397(5) .
C39 C40 1.401(5) .
C40 C41 1.391(6) .
C40 H40 0.9500 .
C41 C42 1.380(6) .
C41 H41 0.9500 .
C42 C43 1.371(6) .
C42 H42 0.9500 .
C43 C44 1.386(6) .
C43 H43 0.9500 .
C44 H44 0.9500 .
C45 C46 1.388(5) .
C45 C50 1.393(5) .
C46 C47 1.372(6) .
C46 H46 0.9500 .
C47 C48 1.380(7) .
C47 H47 0.9500 .
C48 C49 1.377(7) .
C48 H48 0.9500 .
C49 C50 1.388(6) .
C49 H49 0.9500 .
C50 H50 0.9500 .
