#------------------------------------------------------------------------------
#$Date: 2019-11-17 05:51:32 +0200 (Sun, 17 Nov 2019) $
#$Revision: 228229 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/19/7121960.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7121960
loop_
_publ_author_name
'Wolf, Benjamin M.'
'Stuhl, Christoph'
'Anwander, Reiner'
_publ_section_title
;
 Synthesis of homometallic divalent lanthanide organoimides from benzyl
 complexes.
;
_journal_issue                   64
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8826
_journal_page_last               8829
_journal_paper_doi               10.1039/c8cc05234d
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C32 H36 Eu2 O'
_chemical_formula_weight         740.53
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-06-28 deposited with the CCDC.
2018-07-12 downloaded from the CCDC.
;
_cell_angle_alpha                94.734(3)
_cell_angle_beta                 94.590(3)
_cell_angle_gamma                90.111(3)
_cell_formula_units_Z            4
_cell_length_a                   12.4889(13)
_cell_length_b                   14.9634(16)
_cell_length_c                   15.0111(16)
_cell_measurement_reflns_used    581
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      30.365
_cell_measurement_theta_min      2.916
_cell_volume                     2786.6(5)
_computing_cell_refinement       'SAINT V8.37A (Bruker AXS Inc., 2015)'
_computing_data_collection       'Bruker Apex3'
_computing_data_reduction        'SAINT V8.37A (Bruker AXS Inc., 2015)'
_computing_molecular_graphics    'POV-Ray v. 3.6/ORTEP3'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'XT, VERSION 2014/5'
_diffrn_ambient_temperature      170(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Smart Apex III Duo'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0695
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            98040
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.102
_diffrn_reflns_theta_min         1.366
_diffrn_source                   Imus-tube
_exptl_absorpt_coefficient_mu    4.482
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5970
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.765
_exptl_crystal_description       plate
_exptl_crystal_F_000             1448
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
_exptl_crystal_size_max          0.191
_exptl_crystal_size_mid          0.127
_exptl_crystal_size_min          0.124
_refine_diff_density_max         3.333
_refine_diff_density_min         -1.118
_refine_diff_density_rms         0.185
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     753
_refine_ls_number_reflns         12272
_refine_ls_number_restraints     132
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0712
_refine_ls_R_factor_gt           0.0432
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0544P)²+15.5120P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1027
_refine_ls_wR_factor_ref         0.1231
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8622
_reflns_number_total             12272
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8cc05234d2.cif
_cod_data_source_block           1-Eu_thf_mo_BW432_0m_pl
_cod_depositor_comments
'Adding full bibliography for 7121956--7121961.cif.'
_cod_database_code               7121960
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.481
_shelx_estimated_absorpt_t_max   0.606
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.23677(3) -0.40752(2) 0.17532(2) 0.02427(9) Uani 1 1 d . . . . .
Eu2 Eu 0.25078(3) -0.03438(2) 0.17459(2) 0.02268(9) Uani 1 1 d . . . . .
Eu3 Eu 0.20293(3) 0.06369(2) -0.17239(2) 0.02284(9) Uani 1 1 d . . . . .
Eu4 Eu 0.21684(3) 0.43652(2) -0.17092(2) 0.02337(9) Uani 1 1 d . . . . .
O1 O 0.3214(5) 0.0799(4) 0.2991(4) 0.0434(14) Uani 1 1 d . . . . .
O2 O 0.2556(5) 0.5294(4) -0.2968(4) 0.0461(14) Uani 1 1 d . . . . .
C1 C 0.2408(6) -0.2248(5) 0.1611(5) 0.0300(16) Uani 1 1 d . . . . .
H1B H 0.303(6) -0.215(4) 0.140(4) 0.016(17) Uiso 1 1 d . . . . .
H1A H 0.179(6) -0.242(5) 0.133(5) 0.03(2) Uiso 1 1 d . . . . .
C2 C 0.2497(5) -0.2105(4) 0.2554(5) 0.0245(14) Uani 1 1 d . . . . .
C3 C 0.1718(6) -0.2419(5) 0.3091(6) 0.0350(17) Uani 1 1 d . . . . .
H3 H 0.1089 -0.2708 0.2805 0.042 Uiso 1 1 calc R U . . .
C4 C 0.1840(7) -0.2318(6) 0.4018(6) 0.046(2) Uani 1 1 d . . . . .
H4 H 0.1309 -0.2557 0.4352 0.055 Uiso 1 1 calc R U . . .
C5 C 0.2726(8) -0.1872(5) 0.4470(5) 0.045(2) Uani 1 1 d . . . . .
H5 H 0.2802 -0.1798 0.5106 0.054 Uiso 1 1 calc R U . . .
C6 C 0.3488(7) -0.1542(5) 0.3968(6) 0.042(2) Uani 1 1 d . . . . .
H6 H 0.4098 -0.1236 0.4268 0.051 Uiso 1 1 calc R U . . .
C7 C 0.3395(6) -0.1641(5) 0.3036(5) 0.0306(16) Uani 1 1 d . . . . .
H7 H 0.4074 -0.1901 0.2821 0.037 Uiso 1 1 calc R U . . .
C8 C 0.5351(6) 0.0614(6) -0.1292(5) 0.0376(18) Uani 1 1 d . . . . .
H8A H 0.5259 0.0305 -0.0745 0.045 Uiso 1 1 calc R U . . .
H8AB H 0.5260 0.1264 -0.1134 0.045 Uiso 1 1 calc R U . . .
C9 C 0.4507(5) 0.0328(5) -0.1939(5) 0.0294(16) Uani 1 1 d . . . . .
C10 C 0.4042(5) 0.0883(5) -0.2593(5) 0.0301(16) Uani 1 1 d . . . . .
H10 H 0.4332 0.1505 -0.2599 0.036 Uiso 1 1 calc R U . . .
C11 C 0.3274(6) 0.0577(6) -0.3270(5) 0.0384(18) Uani 1 1 d . . . . .
H11 H 0.3067 0.0964 -0.3767 0.046 Uiso 1 1 calc R U . . .
C12 C 0.2846(6) -0.0289(6) -0.3300(6) 0.0409(19) Uani 1 1 d . . . . .
H12 H 0.2345 -0.0530 -0.3817 0.049 Uiso 1 1 calc R U . . .
C13 C 0.3253(7) -0.0851(5) -0.2646(6) 0.042(2) Uani 1 1 d . . . . .
H13 H 0.2977 -0.1481 -0.2668 0.051 Uiso 1 1 calc R U . . .
C14 C 0.4033(6) -0.0548(5) -0.1970(6) 0.0365(18) Uani 1 1 d . . . . .
H14 H 0.4269 -0.0953 -0.1496 0.044 Uiso 1 1 calc R U . . .
C15 C 0.0206(6) -0.0599(5) 0.1546(6) 0.0297(16) Uani 1 1 d . . . . .
H15B H 0.002(6) -0.042(5) 0.094(5) 0.024(18) Uiso 1 1 d . . . . .
H15A H 0.045(7) -0.118(6) 0.159(6) 0.06(3) Uiso 1 1 d . . . . .
C16 C 0.0131(5) 0.0069(4) 0.2250(5) 0.0281(15) Uani 1 1 d . . . . .
C17 C -0.0376(5) 0.0906(4) 0.2122(5) 0.0289(15) Uani 1 1 d . . . . .
H17 H -0.0176 0.1165 0.1565 0.035 Uiso 1 1 calc R U . . .
C18 C -0.0464(6) 0.1558(5) 0.2827(5) 0.0373(18) Uani 1 1 d . . . . .
H18 H -0.0792 0.2113 0.2710 0.045 Uiso 1 1 calc R U . . .
C19 C -0.0084(7) 0.1418(6) 0.3695(6) 0.047(2) Uani 1 1 d . . . . .
H19 H -0.0150 0.1866 0.4173 0.057 Uiso 1 1 calc R U . . .
C20 C 0.0397(8) 0.0599(6) 0.3845(6) 0.052(2) Uani 1 1 d . . . . .
H20 H 0.0648 0.0485 0.4439 0.062 Uiso 1 1 calc R U . . .
C21 C 0.0517(7) -0.0049(5) 0.3157(6) 0.042(2) Uani 1 1 d . . . . .
H21 H 0.0866 -0.0591 0.3287 0.051 Uiso 1 1 calc R U . . .
C22 C 0.2292(7) -0.0108(5) -0.0098(5) 0.0317(16) Uani 1 1 d . . . . .
H22B H 0.291(9) -0.035(7) -0.018(7) 0.08(4) Uiso 1 1 d . . . . .
C23 C 0.2404(6) 0.0813(5) 0.0243(5) 0.0293(15) Uani 1 1 d . . . . .
C24 C 0.1538(6) 0.1308(5) 0.0606(5) 0.0349(17) Uani 1 1 d . . . . .
H24 H 0.0873 0.1009 0.0643 0.042 Uiso 1 1 calc R U . . .
C25 C 0.1633(7) 0.2203(5) 0.0906(6) 0.046(2) Uani 1 1 d . . . . .
H25 H 0.1033 0.2508 0.1132 0.055 Uiso 1 1 calc R U . . .
C26 C 0.2588(7) 0.2659(5) 0.0881(6) 0.042(2) Uani 1 1 d . . . . .
H26 H 0.2656 0.3274 0.1096 0.050 Uiso 1 1 calc R U . . .
C27 C 0.3434(7) 0.2209(5) 0.0541(6) 0.043(2) Uani 1 1 d . . . . .
H27 H 0.4093 0.2519 0.0516 0.051 Uiso 1 1 calc R U . . .
C28 C 0.3357(6) 0.1318(5) 0.0234(5) 0.0359(17) Uani 1 1 d . . . . .
H28 H 0.3969 0.1032 0.0007 0.043 Uiso 1 1 calc R U . . .
C29 C 0.2088(6) 0.2492(4) -0.1575(5) 0.0288(15) Uani 1 1 d . . . . .
H29B H 0.151(7) 0.237(5) -0.129(5) 0.03(2) Uiso 1 1 d . . . . .
H29A H 0.271(7) 0.265(5) -0.128(5) 0.04(2) Uiso 1 1 d . . . . .
C30 C 0.1980(5) 0.2474(4) -0.2515(5) 0.0245(14) Uani 1 1 d . . . . .
C31 C 0.2760(6) 0.2859(4) -0.3011(5) 0.0275(15) Uani 1 1 d . . . . .
H31 H 0.3487 0.2635 -0.2812 0.033 Uiso 1 1 calc R U . . .
C32 C 0.2648(6) 0.2810(5) -0.3941(5) 0.0357(17) Uani 1 1 d . . . . .
H32 H 0.3186 0.3070 -0.4254 0.043 Uiso 1 1 calc R U . . .
C33 C 0.1774(7) 0.2392(5) -0.4422(5) 0.042(2) Uani 1 1 d . . . . .
H33 H 0.1707 0.2363 -0.5059 0.051 Uiso 1 1 calc R U . . .
C34 C 0.0994(6) 0.2013(5) -0.3958(5) 0.0368(18) Uani 1 1 d . . . . .
H34 H 0.0392 0.1717 -0.4282 0.044 Uiso 1 1 calc R U . . .
C35 C 0.1079(6) 0.2062(4) -0.3032(5) 0.0293(15) Uani 1 1 d . . . . .
H35 H 0.0522 0.1813 -0.2732 0.035 Uiso 1 1 calc R U . . .
C36 C -0.0106(6) 0.4176(5) -0.1590(6) 0.0357(18) Uani 1 1 d . . . . .
H36B H 0.018(7) 0.351(6) -0.165(6) 0.05(3) Uiso 1 1 d . . . . .
H36A H -0.015(8) 0.440(7) -0.102(7) 0.07(3) Uiso 1 1 d . . . . .
C37 C -0.0344(6) 0.4686(5) -0.2333(6) 0.0347(17) Uani 1 1 d . . . . .
C38 C -0.0807(6) 0.5558(5) -0.2237(5) 0.0330(16) Uani 1 1 d . . . . .
H38 H -0.0488 0.5935 -0.1700 0.040 Uiso 1 1 calc R U . . .
C39 C -0.1065(7) 0.6047(6) -0.2974(7) 0.050(2) Uani 1 1 d . . . . .
H39 H -0.1344 0.6634 -0.2881 0.060 Uiso 1 1 calc R U . . .
C40 C -0.0925(11) 0.5699(7) -0.3834(7) 0.075(3) Uani 1 1 d . . . . .
H40 H -0.1116 0.6031 -0.4335 0.090 Uiso 1 1 calc R U . . .
C41 C -0.0492(12) 0.4841(7) -0.3945(7) 0.084(4) Uani 1 1 d . . . . .
H41 H -0.0398 0.4587 -0.4535 0.100 Uiso 1 1 calc R U . . .
C42 C -0.0198(9) 0.4354(6) -0.3233(7) 0.061(3) Uani 1 1 d . . . . .
H42 H 0.0112 0.3779 -0.3341 0.073 Uiso 1 1 calc R U . . .
C43 C 0.2242(7) 0.4911(5) 0.0132(5) 0.0340(17) Uani 1 1 d . . . . .
H43B H 0.282(8) 0.463(6) 0.017(6) 0.05(3) Uiso 1 1 d . . . . .
H43A H 0.152(6) 0.465(5) 0.009(5) 0.03(2) Uiso 1 1 d . . . . .
C44 C 0.2284(6) 0.5770(5) -0.0204(5) 0.0288(15) Uani 1 1 d . . . . .
C45 C 0.3259(6) 0.6258(5) -0.0237(6) 0.0392(19) Uani 1 1 d . . . . .
H45 H 0.3917 0.5992 -0.0040 0.047 Uiso 1 1 calc R U . . .
C46 C 0.3286(7) 0.7094(6) -0.0542(6) 0.045(2) Uani 1 1 d . . . . .
H46 H 0.3959 0.7391 -0.0548 0.054 Uiso 1 1 calc R U . . .
C47 C 0.2360(7) 0.7519(5) -0.0841(6) 0.0412(19) Uani 1 1 d . . . . .
H47 H 0.2386 0.8098 -0.1054 0.049 Uiso 1 1 calc R U . . .
C48 C 0.1399(7) 0.7073(5) -0.0820(6) 0.043(2) Uani 1 1 d . . . . .
H48 H 0.0752 0.7358 -0.1012 0.052 Uiso 1 1 calc R U . . .
C49 C 0.1345(6) 0.6224(5) -0.0526(6) 0.0395(18) Uani 1 1 d . . . . .
H49 H 0.0666 0.5934 -0.0540 0.047 Uiso 1 1 calc R U . . .
C50 C 0.4389(6) 0.4126(6) -0.1241(6) 0.0398(19) Uani 1 1 d . . . . .
H50A H 0.4591 0.4506 -0.0682 0.048 Uiso 1 1 calc R U . . .
H50B H 0.4500 0.3494 -0.1108 0.048 Uiso 1 1 calc R U . . .
C51 C 0.5096(6) 0.4325(5) -0.1882(5) 0.0336(17) Uani 1 1 d . . . . .
C52 C 0.5420(5) 0.3677(5) -0.2572(5) 0.0307(16) Uani 1 1 d . . . . .
H52 H 0.5143 0.3048 -0.2583 0.037 Uiso 1 1 calc R U . . .
C53 C 0.6023(6) 0.3886(5) -0.3247(5) 0.0349(17) Uani 1 1 d . . . . .
H53 H 0.6122 0.3423 -0.3753 0.042 Uiso 1 1 calc R U . . .
C54 C 0.6427(7) 0.4760(5) -0.3290(6) 0.043(2) Uani 1 1 d . . . . .
H54 H 0.6791 0.4932 -0.3821 0.051 Uiso 1 1 calc R U . . .
C55 C 0.6169(7) 0.5405(5) -0.2603(6) 0.044(2) Uani 1 1 d . . . . .
H55 H 0.6432 0.6035 -0.2617 0.053 Uiso 1 1 calc R U . . .
C56 C 0.5543(6) 0.5207(5) -0.1926(6) 0.0384(19) Uani 1 1 d . . . . .
H56 H 0.5414 0.5686 -0.1442 0.046 Uiso 1 1 calc R U . . .
C57A C 0.3976(10) 0.0735(7) 0.3752(9) 0.045(3) Uani 0.753(16) 1 d . U P A 1
H57A H 0.4573 0.0336 0.3589 0.054 Uiso 0.753(16) 1 calc R U P A 1
H57B H 0.3626 0.0489 0.4249 0.054 Uiso 0.753(16) 1 calc R U P A 1
C58A C 0.4393(13) 0.1665(8) 0.4032(11) 0.057(4) Uani 0.753(16) 1 d . U P A 1
H58A H 0.4310 0.1822 0.4677 0.068 Uiso 0.753(16) 1 calc R U P A 1
H58B H 0.5162 0.1715 0.3926 0.068 Uiso 0.753(16) 1 calc R U P A 1
C59A C 0.3732(13) 0.2270(8) 0.3468(10) 0.067(4) Uani 0.753(16) 1 d . U P A 1
H59A H 0.4163 0.2512 0.3016 0.081 Uiso 0.753(16) 1 calc R U P A 1
H59B H 0.3448 0.2776 0.3843 0.081 Uiso 0.753(16) 1 calc R U P A 1
C60A C 0.2839(13) 0.1684(7) 0.3027(10) 0.059(4) Uani 0.753(16) 1 d . U P A 1
H60A H 0.2200 0.1741 0.3376 0.070 Uiso 0.753(16) 1 calc R U P A 1
H60B H 0.2637 0.1858 0.2414 0.070 Uiso 0.753(16) 1 calc R U P A 1
C61A C 0.3294(12) 0.5156(12) -0.3684(13) 0.049(4) Uani 0.70(3) 1 d . U P B 1
H61A H 0.2961 0.4768 -0.4198 0.058 Uiso 0.70(3) 1 calc R U P B 1
H61B H 0.3973 0.4880 -0.3459 0.058 Uiso 0.70(3) 1 calc R U P B 1
C62A C 0.3491(14) 0.6083(10) -0.3947(12) 0.056(4) Uani 0.70(3) 1 d . U P B 1
H62A H 0.3655 0.6074 -0.4582 0.068 Uiso 0.70(3) 1 calc R U P B 1
H62B H 0.4086 0.6387 -0.3561 0.068 Uiso 0.70(3) 1 calc R U P B 1
C63A C 0.2377(15) 0.6551(11) -0.3792(12) 0.067(4) Uani 0.70(3) 1 d . U P B 1
H63A H 0.2476 0.7205 -0.3649 0.081 Uiso 0.70(3) 1 calc R U P B 1
H63B H 0.1870 0.6447 -0.4332 0.081 Uiso 0.70(3) 1 calc R U P B 1
C64A C 0.1990(14) 0.6144(10) -0.3056(11) 0.055(4) Uani 0.70(3) 1 d . U P B 1
H64A H 0.1207 0.6033 -0.3162 0.067 Uiso 0.70(3) 1 calc R U P B 1
H64B H 0.2126 0.6543 -0.2499 0.067 Uiso 0.70(3) 1 calc R U P B 1
C57B C 0.310(3) 0.072(3) 0.397(3) 0.053(8) Uani 0.247(16) 1 d . U P A 2
H57C H 0.3079 0.0092 0.4133 0.064 Uiso 0.247(16) 1 calc R U P A 2
H57D H 0.2485 0.1061 0.4201 0.064 Uiso 0.247(16) 1 calc R U P A 2
C58B C 0.418(4) 0.118(4) 0.423(3) 0.064(8) Uani 0.247(16) 1 d . U P A 2
H58C H 0.4208 0.1409 0.4871 0.077 Uiso 0.247(16) 1 calc R U P A 2
H58D H 0.4755 0.0738 0.4159 0.077 Uiso 0.247(16) 1 calc R U P A 2
C59B C 0.436(4) 0.193(3) 0.369(3) 0.060(8) Uani 0.247(16) 1 d . U P A 2
H59C H 0.4123 0.2507 0.3978 0.071 Uiso 0.247(16) 1 calc R U P A 2
H59D H 0.5126 0.1982 0.3571 0.071 Uiso 0.247(16) 1 calc R U P A 2
C60B C 0.370(4) 0.168(3) 0.287(3) 0.060(9) Uani 0.247(16) 1 d . U P A 2
H60C H 0.4143 0.1630 0.2352 0.072 Uiso 0.247(16) 1 calc R U P A 2
H60D H 0.3135 0.2128 0.2769 0.072 Uiso 0.247(16) 1 calc R U P A 2
C61B C 0.296(5) 0.513(4) -0.381(5) 0.088(11) Uani 0.30(3) 1 d . U P B 2
H61C H 0.2490 0.4673 -0.4170 0.105 Uiso 0.30(3) 1 calc R U P B 2
H61D H 0.3683 0.4868 -0.3727 0.105 Uiso 0.30(3) 1 calc R U P B 2
C62B C 0.302(4) 0.594(3) -0.431(4) 0.087(10) Uani 0.30(3) 1 d . U P B 2
H62C H 0.2358 0.6031 -0.4706 0.104 Uiso 0.30(3) 1 calc R U P B 2
H62D H 0.3660 0.5946 -0.4661 0.104 Uiso 0.30(3) 1 calc R U P B 2
C63B C 0.312(5) 0.663(3) -0.339(3) 0.088(10) Uani 0.30(3) 1 d . U P B 2
H63C H 0.3879 0.6703 -0.3135 0.106 Uiso 0.30(3) 1 calc R U P B 2
H63D H 0.2821 0.7226 -0.3494 0.106 Uiso 0.30(3) 1 calc R U P B 2
C64B C 0.255(5) 0.621(4) -0.286(4) 0.091(10) Uani 0.30(3) 1 d . U P B 2
H64C H 0.1797 0.6406 -0.2958 0.109 Uiso 0.30(3) 1 calc R U P B 2
H64D H 0.2804 0.6397 -0.2236 0.109 Uiso 0.30(3) 1 calc R U P B 2
H22A H 0.159(7) -0.039(5) -0.004(5) 0.03(2) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C43 Eu1 C1 114.1(2) 1_545 .
C43 Eu1 C36 85.2(3) 1_545 2
C1 Eu1 C36 93.6(2) . 2
C43 Eu1 C53 133.2(2) 1_545 2_655
C1 Eu1 C53 90.6(2) . 2_655
C36 Eu1 C53 134.4(3) 2 2_655
C43 Eu1 C37 96.4(2) 1_545 2
C1 Eu1 C37 112.4(2) . 2
C36 Eu1 C37 28.6(2) 2 2
C53 Eu1 C37 110.3(2) 2_655 2
C43 Eu1 C54 119.0(2) 1_545 2_655
C1 Eu1 C54 117.8(2) . 2_655
C36 Eu1 C54 120.0(3) 2 2_655
C53 Eu1 C54 28.1(2) 2_655 2_655
C37 Eu1 C54 91.7(2) 2 2_655
C43 Eu1 C44 28.8(2) 1_545 1_545
C1 Eu1 C44 85.3(2) . 1_545
C36 Eu1 C44 87.6(2) 2 1_545
C53 Eu1 C44 138.0(2) 2_655 1_545
C37 Eu1 C44 109.8(2) 2 1_545
C54 Eu1 C44 140.1(2) 2_655 1_545
C43 Eu1 C52 115.3(2) 1_545 2_655
C1 Eu1 C52 81.1(2) . 2_655
C36 Eu1 C52 159.3(2) 2 2_655
C53 Eu1 C52 26.9(2) 2_655 2_655
C37 Eu1 C52 137.2(2) 2 2_655
C54 Eu1 C52 48.6(2) 2_655 2_655
C44 Eu1 C52 111.7(2) 1_545 2_655
C43 Eu1 C55 91.6(2) 1_545 2_655
C1 Eu1 C55 135.7(2) . 2_655
C36 Eu1 C55 125.3(2) 2 2_655
C53 Eu1 C55 48.0(2) 2_655 2_655
C37 Eu1 C55 98.7(2) 2 2_655
C54 Eu1 C55 27.5(2) 2_655 2_655
C44 Eu1 C55 113.6(2) 1_545 2_655
C52 Eu1 C55 54.9(2) 2_655 2_655
C43 Eu1 C2 141.3(2) 1_545 .
C1 Eu1 C2 27.1(2) . .
C36 Eu1 C2 95.5(2) 2 .
C53 Eu1 C2 70.00(19) 2_655 .
C37 Eu1 C2 102.41(19) 2 .
C54 Eu1 C2 94.1(2) 2_655 .
C44 Eu1 C2 112.44(19) 1_545 .
C52 Eu1 C2 70.75(18) 2_655 .
C55 Eu1 C2 118.0(2) 2_655 .
C43 Eu1 C38 82.1(2) 1_545 2
C1 Eu1 C38 139.5(2) . 2
C36 Eu1 C38 49.2(2) 2 2
C53 Eu1 C38 104.7(2) 2_655 2
C37 Eu1 C38 27.13(19) 2 2
C54 Eu1 C38 78.7(2) 2_655 2
C44 Eu1 C38 105.2(2) 1_545 2
C52 Eu1 C38 127.0(2) 2_655 2
C55 Eu1 C38 76.2(2) 2_655 2
C2 Eu1 C38 126.62(18) . 2
C43 Eu1 C56 78.3(2) 1_545 2_655
C1 Eu1 C56 122.4(2) . 2_655
C36 Eu1 C56 144.0(2) 2 2_655
C53 Eu1 C56 55.1(2) 2_655 2_655
C37 Eu1 C56 122.0(2) 2 2_655
C54 Eu1 C56 47.8(2) 2_655 2_655
C44 Eu1 C56 92.7(2) 1_545 2_655
C52 Eu1 C56 46.59(19) 2_655 2_655
C55 Eu1 C56 26.0(2) 2_655 2_655
C2 Eu1 C56 117.34(18) . 2_655
C38 Eu1 C56 96.5(2) 2 2_655
C43 Eu1 H1A 104.3(16) 1_545 .
C1 Eu1 H1A 18.4(17) . .
C36 Eu1 H1A 77.0(17) 2 .
C53 Eu1 H1A 108.0(17) 2_655 .
C37 Eu1 H1A 99.5(17) 2 .
C54 Eu1 H1A 133.7(17) 2_655 .
C44 Eu1 H1A 76.8(16) 1_545 .
C52 Eu1 H1A 99.4(17) 2_655 .
C55 Eu1 H1A 154.2(17) 2_655 .
C2 Eu1 H1A 39.6(17) . .
C38 Eu1 H1A 125.5(17) 2 .
C56 Eu1 H1A 138.0(17) 2_655 .
O1 Eu2 C22 126.6(2) . .
O1 Eu2 C8 88.5(2) . 2_655
C22 Eu2 C8 79.0(2) . 2_655
O1 Eu2 C1 132.5(2) . .
C22 Eu2 C1 97.9(2) . .
C8 Eu2 C1 84.0(2) 2_655 .
O1 Eu2 C15 115.9(2) . .
C22 Eu2 C15 84.7(2) . .
C8 Eu2 C15 155.6(2) 2_655 .
C1 Eu2 C15 80.4(2) . .
O1 Eu2 C23 98.8(2) . .
C22 Eu2 C23 28.7(2) . .
C8 Eu2 C23 83.3(2) 2_655 .
C1 Eu2 C23 126.5(2) . .
C15 Eu2 C23 91.0(2) . .
O1 Eu2 C2 106.06(19) . .
C22 Eu2 C2 125.6(2) . .
C8 Eu2 C2 91.0(2) 2_655 .
C1 Eu2 C2 27.8(2) . .
C15 Eu2 C2 83.89(19) . .
C23 Eu2 C2 154.3(2) . .
O1 Eu2 C7 82.42(19) . .
C22 Eu2 C7 140.9(2) . .
C8 Eu2 C7 76.1(2) 2_655 .
C1 Eu2 C7 50.2(2) . .
C15 Eu2 C7 107.1(2) . .
C23 Eu2 C7 159.3(2) . .
C2 Eu2 C7 27.62(18) . .
O1 Eu2 C16 89.64(18) . .
C22 Eu2 C16 100.3(2) . .
C8 Eu2 C16 177.0(2) 2_655 .
C1 Eu2 C16 99.0(2) . .
C15 Eu2 C16 26.23(19) . .
C23 Eu2 C16 94.68(19) . .
C2 Eu2 C16 91.76(17) . .
C7 Eu2 C16 105.96(19) . .
O1 Eu2 H1B 130.5(13) . .
C22 Eu2 H1B 91.1(13) . .
C8 Eu2 H1B 66.4(15) 2_655 .
C1 Eu2 H1B 17.8(14) . .
C15 Eu2 H1B 96.2(15) . .
C23 Eu2 H1B 118.2(14) . .
C2 Eu2 H1B 38.2(14) . .
C7 Eu2 H1B 51.3(13) . .
C16 Eu2 H1B 116.5(15) . .
C22 Eu3 C29 113.8(2) . .
C22 Eu3 C15 87.3(2) . 2
C29 Eu3 C15 92.2(2) . 2
C22 Eu3 C11 133.4(2) . .
C29 Eu3 C11 91.0(2) . .
C15 Eu3 C11 132.5(2) 2 .
C22 Eu3 C12 119.7(2) . .
C29 Eu3 C12 117.8(2) . .
C15 Eu3 C12 118.7(2) 2 .
C11 Eu3 C12 27.9(2) . .
C22 Eu3 C16 96.8(2) . 2
C29 Eu3 C16 112.1(2) . 2
C15 Eu3 C16 28.2(2) 2 2
C11 Eu3 C16 109.9(2) . 2
C12 Eu3 C16 91.2(2) . 2
C22 Eu3 C23 28.9(2) . .
C29 Eu3 C23 85.0(2) . .
C15 Eu3 C23 89.1(2) 2 .
C11 Eu3 C23 138.4(2) . .
C12 Eu3 C23 141.1(2) . .
C16 Eu3 C23 109.9(2) 2 .
C22 Eu3 C10 114.7(2) . .
C29 Eu3 C10 81.9(2) . .
C15 Eu3 C10 157.8(2) 2 .
C11 Eu3 C10 27.4(2) . .
C12 Eu3 C10 48.8(2) . .
C16 Eu3 C10 137.3(2) 2 .
C23 Eu3 C10 111.5(2) . .
C22 Eu3 C13 92.3(2) . .
C29 Eu3 C13 136.6(2) . .
C15 Eu3 C13 124.5(2) 2 .
C11 Eu3 C13 48.0(2) . .
C12 Eu3 C13 27.5(2) . .
C16 Eu3 C13 97.6(2) 2 .
C23 Eu3 C13 114.7(2) . .
C10 Eu3 C13 55.2(2) . .
C22 Eu3 C30 140.9(2) . .
C29 Eu3 C30 27.1(2) . .
C15 Eu3 C30 94.06(19) 2 .
C11 Eu3 C30 69.9(2) . .
C12 Eu3 C30 93.7(2) . .
C16 Eu3 C30 102.64(18) 2 .
C23 Eu3 C30 112.03(19) . .
C10 Eu3 C30 71.08(19) . .
C13 Eu3 C30 117.9(2) . .
C22 Eu3 C17 81.5(2) . 2
C29 Eu3 C17 139.2(2) . 2
C15 Eu3 C17 49.32(19) 2 2
C11 Eu3 C17 105.4(2) . 2
C12 Eu3 C17 79.4(2) . 2
C16 Eu3 C17 27.28(17) 2 2
C23 Eu3 C17 104.4(2) . 2
C10 Eu3 C17 127.6(2) . 2
C13 Eu3 C17 75.8(2) . 2
C30 Eu3 C17 127.52(18) . 2
C22 Eu3 C14 78.2(2) . .
C29 Eu3 C14 123.7(2) . .
C15 Eu3 C14 144.1(2) 2 .
C11 Eu3 C14 55.4(2) . .
C12 Eu3 C14 48.0(2) . .
C16 Eu3 C14 121.0(2) 2 .
C23 Eu3 C14 93.3(2) . .
C10 Eu3 C14 46.73(19) . .
C13 Eu3 C14 26.4(2) . .
C30 Eu3 C14 117.81(19) . .
C17 Eu3 C14 95.70(19) 2 .
C22 Eu3 H29B 104.4(16) . .
C29 Eu3 H29B 18.8(17) . .
C15 Eu3 H29B 75.2(18) 2 .
C11 Eu3 H29B 108.4(17) . .
C12 Eu3 H29B 133.4(17) . .
C16 Eu3 H29B 98.4(17) 2 .
C23 Eu3 H29B 77.0(16) . .
C10 Eu3 H29B 100.7(18) . .
C13 Eu3 H29B 155.3(18) . .
C30 Eu3 H29B 39.7(17) . .
C17 Eu3 H29B 124.2(17) 2 .
C14 Eu3 H29B 140.1(17) . .
O2 Eu4 C43 127.8(2) . .
O2 Eu4 C29 132.5(2) . .
C43 Eu4 C29 97.9(2) . .
O2 Eu4 C50 91.9(2) . .
C43 Eu4 C50 80.5(2) . .
C29 Eu4 C50 82.8(2) . .
O2 Eu4 C36 111.1(2) . .
C43 Eu4 C36 85.1(3) . .
C29 Eu4 C36 81.6(2) . .
C50 Eu4 C36 157.1(3) . .
O2 Eu4 C44 99.9(2) . .
C43 Eu4 C44 28.4(2) . .
C29 Eu4 C44 126.3(2) . .
C50 Eu4 C44 85.5(2) . .
C36 Eu4 C44 90.4(2) . .
O2 Eu4 C30 105.83(19) . .
C43 Eu4 C30 125.6(2) . .
C29 Eu4 C30 27.8(2) . .
C50 Eu4 C30 90.4(2) . .
C36 Eu4 C30 83.5(2) . .
C44 Eu4 C30 154.04(19) . .
O2 Eu4 C31 82.50(19) . .
C43 Eu4 C31 142.6(2) . .
C29 Eu4 C31 50.3(2) . .
C50 Eu4 C31 76.6(2) . .
C36 Eu4 C31 105.4(2) . .
C44 Eu4 C31 162.05(19) . .
C30 Eu4 C31 27.51(18) . .
O2 Eu4 C37 85.3(2) . .
C43 Eu4 C37 101.5(2) . .
C29 Eu4 C37 98.9(2) . .
C50 Eu4 C37 177.1(2) . .
C36 Eu4 C37 25.8(2) . .
C44 Eu4 C37 95.35(19) . .
C30 Eu4 C37 89.99(17) . .
C31 Eu4 C37 102.58(19) . .
O2 Eu4 H29A 134.2(16) . .
C43 Eu4 H29A 89.0(16) . .
C29 Eu4 H29A 18.2(17) . .
C50 Eu4 H29A 65.5(17) . .
C36 Eu4 H29A 96.6(17) . .
C44 Eu4 H29A 116.1(16) . .
C30 Eu4 H29A 40.5(17) . .
C31 Eu4 H29A 54.6(16) . .
C37 Eu4 H29A 116.4(17) . .
O2 Eu4 H36B 121.9(18) . .
C43 Eu4 H36B 91.4(18) . .
C29 Eu4 H36B 60.5(19) . .
C50 Eu4 H36B 141.0(18) . .
C36 Eu4 H36B 21.3(18) . .
C44 Eu4 H36B 105.1(18) . .
C30 Eu4 H36B 63.6(19) . .
C31 Eu4 H36B 88.1(18) . .
C37 Eu4 H36B 41.4(18) . .
H29A Eu4 H36B 76(3) . .
C60A O1 C57A 107.3(8) . .
C60B O1 C57B 109(2) . .
C60A O1 Eu2 120.5(6) . .
C57A O1 Eu2 132.2(5) . .
C60B O1 Eu2 125.9(17) . .
C57B O1 Eu2 124.5(15) . .
C64B O2 C61B 102(3) . .
C64A O2 C61A 109.3(10) . .
C64B O2 Eu4 122(2) . .
C61B O2 Eu4 136(3) . .
C64A O2 Eu4 119.0(7) . .
C61A O2 Eu4 131.7(7) . .
C2 C1 Eu1 89.5(4) . .
C2 C1 Eu2 82.0(4) . .
Eu1 C1 Eu2 171.5(3) . .
C2 C1 H1B 111(4) . .
Eu1 C1 H1B 104(4) . .
Eu2 C1 H1B 78(4) . .
C2 C1 H1A 120(5) . .
Eu1 C1 H1A 76(5) . .
Eu2 C1 H1A 108(5) . .
H1B C1 H1A 130(7) . .
C1 C2 C3 122.7(7) . .
C1 C2 C7 122.0(7) . .
C3 C2 C7 115.4(7) . .
C1 C2 Eu2 70.2(4) . .
C3 C2 Eu2 126.9(4) . .
C7 C2 Eu2 76.7(4) . .
C1 C2 Eu1 63.3(4) . .
C3 C2 Eu1 81.7(4) . .
C7 C2 Eu1 128.1(4) . .
Eu2 C2 Eu1 133.5(2) . .
C4 C3 C2 122.2(8) . .
C4 C3 Eu1 129.1(5) . .
C2 C3 Eu1 72.4(4) . .
C4 C3 H3 118.9 . .
C2 C3 H3 118.9 . .
Eu1 C3 H3 70.1 . .
C3 C4 C5 121.3(8) . .
C3 C4 H4 119.4 . .
C5 C4 H4 119.4 . .
C6 C5 C4 118.1(8) . .
C6 C5 H5 121.0 . .
C4 C5 H5 121.0 . .
C5 C6 C7 122.1(8) . .
C5 C6 H6 119.0 . .
C7 C6 H6 119.0 . .
C6 C7 C2 121.0(7) . .
C6 C7 Eu2 128.6(5) . .
C2 C7 Eu2 75.7(4) . .
C6 C7 H7 109.1 . .
C2 C7 H7 109.1 . .
Eu2 C7 H7 109.1 . .
C9 C8 Eu2 118.1(5) . 2_655
C9 C8 H8A 107.8 . .
Eu2 C8 H8A 107.8 2_655 .
C9 C8 H8AB 107.8 . .
Eu2 C8 H8AB 107.8 2_655 .
H8A C8 H8AB 107.1 . .
C8 C9 C10 123.6(7) . .
C8 C9 C14 121.9(7) . .
C10 C9 C14 114.5(7) . .
C8 C9 Eu3 125.2(5) . .
C10 C9 Eu3 68.5(4) . .
C14 C9 Eu3 74.1(4) . .
C11 C10 C9 123.3(7) . .
C11 C10 Eu3 73.6(4) . .
C9 C10 Eu3 84.9(4) . .
C11 C10 H10 118.2 . .
C9 C10 H10 118.2 . .
Eu3 C10 H10 118.2 . .
C10 C11 C12 120.7(7) . .
C10 C11 Eu3 79.0(4) . .
C12 C11 Eu3 76.4(5) . .
C10 C11 H11 119.6 . .
C12 C11 H11 119.6 . .
Eu3 C11 H11 119.6 . .
C11 C12 C13 117.9(7) . .
C11 C12 Eu3 75.7(4) . .
C13 C12 Eu3 80.6(5) . .
C11 C12 H12 120.8 . .
C13 C12 H12 120.8 . .
Eu3 C12 H12 120.8 . .
C14 C13 C12 121.4(7) . .
C14 C13 Eu3 80.4(4) . .
C12 C13 Eu3 71.9(4) . .
C14 C13 H13 119.3 . .
C12 C13 H13 119.3 . .
Eu3 C13 H13 119.3 . .
C13 C14 C9 121.8(7) . .
C13 C14 Eu3 73.2(4) . .
C9 C14 Eu3 79.5(4) . .
C13 C14 H14 119.1 . .
C9 C14 H14 119.1 . .
Eu3 C14 H14 119.1 . .
C16 C15 Eu3 79.6(4) . 2
C16 C15 Eu2 88.2(4) . .
Eu3 C15 Eu2 167.4(3) 2 .
C16 C15 H15B 117(4) . .
Eu3 C15 H15B 86(4) 2 .
Eu2 C15 H15B 102(4) . .
C16 C15 H15A 127(6) . .
Eu3 C15 H15A 107(6) 2 .
Eu2 C15 H15A 78(6) . .
H15B C15 H15A 116(7) . .
C15 C16 C17 122.4(7) . .
C15 C16 C21 122.9(7) . .
C17 C16 C21 114.7(7) . .
C15 C16 Eu3 72.2(4) . 2
C17 C16 Eu3 82.8(4) . 2
C21 C16 Eu3 114.8(5) . 2
C15 C16 Eu2 65.6(4) . .
C17 C16 Eu2 122.7(5) . .
C21 C16 Eu2 86.5(5) . .
Eu3 C16 Eu2 137.6(2) 2 .
C18 C17 C16 122.0(7) . .
C18 C17 Eu3 121.5(5) . 2
C16 C17 Eu3 70.0(4) . 2
C18 C17 H17 112.4 . .
C16 C17 H17 112.4 . .
Eu3 C17 H17 112.4 2 .
C19 C18 C17 121.6(7) . .
C19 C18 H18 119.2 . .
C17 C18 H18 119.2 . .
C18 C19 C20 117.9(8) . .
C18 C19 H19 121.1 . .
C20 C19 H19 121.1 . .
C21 C20 C19 121.7(8) . .
C21 C20 H20 119.1 . .
C19 C20 H20 119.1 . .
C20 C21 C16 122.1(7) . .
C20 C21 H21 119.0 . .
C16 C21 H21 119.0 . .
C23 C22 Eu3 82.6(4) . .
C23 C22 Eu2 81.0(4) . .
Eu3 C22 Eu2 163.4(3) . .
C23 C22 H22B 112(7) . .
Eu3 C22 H22B 97(7) . .
Eu2 C22 H22B 92(7) . .
C23 C22 H22A 116(4) . .
Eu3 C22 H22A 104(4) . .
Eu2 C22 H22A 81(4) . .
H22B C22 H22A 129(9) . .
C28 C23 C24 114.0(7) . .
C28 C23 C22 123.6(7) . .
C24 C23 C22 122.4(7) . .
C28 C23 Eu3 93.4(5) . .
C24 C23 Eu3 108.6(5) . .
C22 C23 Eu3 68.6(4) . .
C28 C23 Eu2 111.7(5) . .
C24 C23 Eu2 90.9(4) . .
C22 C23 Eu2 70.3(4) . .
Eu3 C23 Eu2 138.8(3) . .
C25 C24 C23 122.5(7) . .
C25 C24 H24 118.8 . .
C23 C24 H24 118.8 . .
C26 C25 C24 120.8(7) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C27 C26 C25 118.5(7) . .
C27 C26 H26 120.8 . .
C25 C26 H26 120.8 . .
C26 C27 C28 121.8(7) . .
C26 C27 H27 119.1 . .
C28 C27 H27 119.1 . .
C27 C28 C23 122.5(7) . .
C27 C28 H28 118.8 . .
C23 C28 H28 118.8 . .
C30 C29 Eu3 89.1(4) . .
C30 C29 Eu4 82.3(4) . .
Eu3 C29 Eu4 171.3(3) . .
C30 C29 H29B 119(5) . .
Eu3 C29 H29B 78(5) . .
Eu4 C29 H29B 108(5) . .
C30 C29 H29A 120(5) . .
Eu3 C29 H29A 106(5) . .
Eu4 C29 H29A 77(5) . .
H29B C29 H29A 122(7) . .
C29 C30 C31 122.4(6) . .
C29 C30 C35 121.8(7) . .
C31 C30 C35 115.8(6) . .
C29 C30 Eu4 69.9(4) . .
C31 C30 Eu4 76.5(4) . .
C35 C30 Eu4 127.3(4) . .
C29 C30 Eu3 63.8(4) . .
C31 C30 Eu3 128.3(4) . .
C35 C30 Eu3 80.9(4) . .
Eu4 C30 Eu3 133.7(2) . .
C32 C31 C30 121.2(7) . .
C32 C31 Eu4 128.4(5) . .
C30 C31 Eu4 76.0(4) . .
C32 C31 H31 109.0 . .
C30 C31 H31 109.0 . .
Eu4 C31 H31 109.0 . .
C33 C32 C31 121.5(7) . .
C33 C32 H32 119.2 . .
C31 C32 H32 119.2 . .
C32 C33 C34 118.7(7) . .
C32 C33 H33 120.7 . .
C34 C33 H33 120.7 . .
C35 C34 C33 121.0(7) . .
C35 C34 H34 119.5 . .
C33 C34 H34 119.5 . .
C34 C35 C30 121.7(7) . .
C34 C35 Eu3 129.3(5) . .
C30 C35 Eu3 72.9(4) . .
C34 C35 H35 119.1 . .
C30 C35 H35 119.1 . .
Eu3 C35 H35 69.6 . .
C37 C36 Eu1 79.2(4) . 2
C37 C36 Eu4 92.1(5) . .
Eu1 C36 Eu4 170.9(4) 2 .
C37 C36 H36B 123(5) . .
Eu1 C36 H36B 107(5) 2 .
Eu4 C36 H36B 75(5) . .
C37 C36 H36A 122(7) . .
Eu1 C36 H36A 88(7) 2 .
Eu4 C36 H36A 99(7) . .
H36B C36 H36A 114(8) . .
C36 C37 C42 122.8(7) . .
C36 C37 C38 122.0(7) . .
C42 C37 C38 115.1(8) . .
C36 C37 Eu1 72.2(4) . 2
C42 C37 Eu1 111.8(5) . 2
C38 C37 Eu1 84.7(4) . 2
C36 C37 Eu4 62.1(4) . .
C42 C37 Eu4 91.7(6) . .
C38 C37 Eu4 121.1(5) . .
Eu1 C37 Eu4 134.2(3) 2 .
C39 C38 C37 121.6(8) . .
C39 C38 Eu1 120.4(5) . 2
C37 C38 Eu1 68.2(4) . 2
C39 C38 H38 113.2 . .
C37 C38 H38 113.2 . .
Eu1 C38 H38 113.2 2 .
C40 C39 C38 121.6(9) . .
C40 C39 H39 119.2 . .
C38 C39 H39 119.2 . .
C39 C40 C41 117.7(10) . .
C39 C40 H40 121.2 . .
C41 C40 H40 121.2 . .
C42 C41 C40 122.2(10) . .
C42 C41 H41 118.9 . .
C40 C41 H41 118.9 . .
C41 C42 C37 121.7(9) . .
C41 C42 H42 119.2 . .
C37 C42 H42 119.2 . .
C44 C43 Eu1 82.1(4) . 1_565
C44 C43 Eu4 81.3(4) . .
Eu1 C43 Eu4 163.4(3) 1_565 .
C44 C43 H43B 116(7) . .
Eu1 C43 H43B 102(6) 1_565 .
Eu4 C43 H43B 85(6) . .
C44 C43 H43A 114(4) . .
Eu1 C43 H43A 103(4) 1_565 .
Eu4 C43 H43A 84(4) . .
H43B C43 H43A 126(8) . .
C43 C44 C45 123.2(7) . .
C43 C44 C49 122.6(7) . .
C45 C44 C49 114.3(7) . .
C43 C44 Eu1 69.0(4) . 1_565
C45 C44 Eu1 94.3(5) . 1_565
C49 C44 Eu1 107.7(5) . 1_565
C43 C44 Eu4 70.3(4) . .
C45 C44 Eu4 107.2(5) . .
C49 C44 Eu4 94.6(5) . .
Eu1 C44 Eu4 139.3(3) 1_565 .
C46 C45 C44 122.6(7) . .
C46 C45 H45 118.7 . .
C44 C45 H45 118.7 . .
C45 C46 C47 121.7(8) . .
C45 C46 H46 119.2 . .
C47 C46 H46 119.2 . .
C48 C47 C46 117.7(7) . .
C48 C47 H47 121.1 . .
C46 C47 H47 121.1 . .
C47 C48 C49 122.1(7) . .
C47 C48 H48 119.0 . .
C49 C48 H48 119.0 . .
C48 C49 C44 121.7(7) . .
C48 C49 H49 119.1 . .
C44 C49 H49 119.1 . .
C51 C50 Eu4 116.6(5) . .
C51 C50 H50A 108.1 . .
Eu4 C50 H50A 108.1 . .
C51 C50 H50B 108.1 . .
Eu4 C50 H50B 108.1 . .
H50A C50 H50B 107.3 . .
C50 C51 C56 122.9(7) . .
C50 C51 C52 123.5(7) . .
C56 C51 C52 113.6(7) . .
C50 C51 Eu1 127.1(5) . 2_655
C56 C51 Eu1 74.3(4) . 2_655
C52 C51 Eu1 68.4(4) . 2_655
C53 C52 C51 123.7(7) . .
C53 C52 Eu1 73.0(4) . 2_655
C51 C52 Eu1 84.8(4) . 2_655
C53 C52 H52 118.1 . .
C51 C52 H52 118.1 . .
Eu1 C52 H52 118.1 2_655 .
C52 C53 C54 121.6(7) . .
C52 C53 Eu1 80.1(4) . 2_655
C54 C53 Eu1 77.0(5) . 2_655
C52 C53 H53 119.1 . .
C54 C53 H53 119.1 . .
Eu1 C53 H53 119.1 2_655 .
C53 C54 C55 116.4(8) . .
C53 C54 Eu1 74.8(4) . 2_655
C55 C54 Eu1 79.6(5) . 2_655
C53 C54 H54 121.5 . .
C55 C54 H54 121.5 . .
Eu1 C54 H54 121.5 2_655 .
C56 C55 C54 122.7(7) . .
C56 C55 Eu1 81.9(5) . 2_655
C54 C55 Eu1 72.9(4) . 2_655
C56 C55 H55 118.7 . .
C54 C55 H55 118.7 . .
Eu1 C55 H55 118.7 2_655 .
C55 C56 C51 121.9(7) . .
C55 C56 Eu1 72.1(4) . 2_655
C51 C56 Eu1 79.3(4) . 2_655
C55 C56 H56 119.0 . .
C51 C56 H56 119.0 . .
Eu1 C56 H56 119.0 2_655 .
O1 C57A C58A 107.1(9) . .
O1 C57A H57A 110.3 . .
C58A C57A H57A 110.3 . .
O1 C57A H57B 110.3 . .
C58A C57A H57B 110.3 . .
H57A C57A H57B 108.6 . .
C59A C58A C57A 105.6(10) . .
C59A C58A H58A 110.6 . .
C57A C58A H58A 110.6 . .
C59A C58A H58B 110.6 . .
C57A C58A H58B 110.6 . .
H58A C58A H58B 108.7 . .
C58A C59A C60A 104.5(10) . .
C58A C59A H59A 110.9 . .
C60A C59A H59A 110.9 . .
C58A C59A H59B 110.9 . .
C60A C59A H59B 110.9 . .
H59A C59A H59B 108.9 . .
O1 C60A C59A 107.1(11) . .
O1 C60A H60A 110.3 . .
C59A C60A H60A 110.3 . .
O1 C60A H60B 110.3 . .
C59A C60A H60B 110.3 . .
H60A C60A H60B 108.6 . .
O2 C61A C62A 103.9(13) . .
O2 C61A H61A 111.0 . .
C62A C61A H61A 111.0 . .
O2 C61A H61B 111.0 . .
C62A C61A H61B 111.0 . .
H61A C61A H61B 109.0 . .
C61A C62A C63A 101.8(12) . .
C61A C62A H62A 111.4 . .
C63A C62A H62A 111.4 . .
C61A C62A H62B 111.4 . .
C63A C62A H62B 111.4 . .
H62A C62A H62B 109.3 . .
C64A C63A C62A 105.0(12) . .
C64A C63A H63A 110.7 . .
C62A C63A H63A 110.7 . .
C64A C63A H63B 110.7 . .
C62A C63A H63B 110.7 . .
H63A C63A H63B 108.8 . .
C63A C64A O2 108.0(12) . .
C63A C64A H64A 110.1 . .
O2 C64A H64A 110.1 . .
C63A C64A H64B 110.1 . .
O2 C64A H64B 110.1 . .
H64A C64A H64B 108.4 . .
O1 C57B C58B 92(3) . .
O1 C57B H57C 113.3 . .
C58B C57B H57C 113.3 . .
O1 C57B H57D 113.3 . .
C58B C57B H57D 113.3 . .
H57C C57B H57D 110.7 . .
C59B C58B C57B 113(4) . .
C59B C58B H58C 109.1 . .
C57B C58B H58C 109.1 . .
C59B C58B H58D 109.1 . .
C57B C58B H58D 109.1 . .
H58C C58B H58D 107.8 . .
C60B C59B C58B 102(4) . .
C60B C59B H59C 111.4 . .
C58B C59B H59C 111.4 . .
C60B C59B H59D 111.4 . .
C58B C59B H59D 111.4 . .
H59C C59B H59D 109.2 . .
C59B C60B O1 107(3) . .
C59B C60B H60C 110.4 . .
O1 C60B H60C 110.4 . .
C59B C60B H60D 110.4 . .
O1 C60B H60D 110.4 . .
H60C C60B H60D 108.6 . .
O2 C61B C62B 114(5) . .
O2 C61B H61C 108.8 . .
C62B C61B H61C 108.8 . .
O2 C61B H61D 108.8 . .
C62B C61B H61D 108.8 . .
H61C C61B H61D 107.7 . .
C61B C62B C63B 93(4) . .
C61B C62B H62C 113.1 . .
C63B C62B H62C 113.1 . .
C61B C62B H62D 113.1 . .
C63B C62B H62D 113.1 . .
H62C C62B H62D 110.5 . .
C64B C63B C62B 101(4) . .
C64B C63B H63C 111.5 . .
C62B C63B H63C 111.5 . .
C64B C63B H63D 111.5 . .
C62B C63B H63D 111.5 . .
H63C C63B H63D 109.4 . .
C63B C64B O2 117(5) . .
C63B C64B H64C 108.0 . .
O2 C64B H64C 108.0 . .
C63B C64B H64D 108.0 . .
O2 C64B H64D 108.0 . .
H64C C64B H64D 107.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 C43 2.753(8) 1_545
Eu1 C1 2.761(7) .
Eu1 C36 2.818(7) 2
Eu1 C53 2.884(7) 2_655
Eu1 C37 2.908(7) 2
Eu1 C54 2.912(8) 2_655
Eu1 C44 2.921(7) 1_545
Eu1 C52 2.971(7) 2_655
Eu1 C55 2.997(8) 2_655
Eu1 C2 3.089(6) .
Eu1 C38 3.118(7) 2
Eu1 C56 3.119(7) 2_655
Eu1 H1A 2.69(7) .
Eu2 O1 2.530(5) .
Eu2 C22 2.812(7) .
Eu2 C8 2.834(7) 2_655
Eu2 C1 2.842(7) .
Eu2 C15 2.888(7) .
Eu2 C23 2.949(7) .
Eu2 C2 2.992(6) .
Eu2 C7 3.005(7) .
Eu2 C16 3.171(7) .
Eu2 H1B 2.80(6) .
Eu3 C22 2.761(8) .
Eu3 C29 2.767(7) .
Eu3 C15 2.826(7) 2
Eu3 C11 2.891(8) .
Eu3 C12 2.899(8) .
Eu3 C16 2.920(6) 2
Eu3 C23 2.942(7) .
Eu3 C10 2.959(7) .
Eu3 C13 3.009(8) .
Eu3 C30 3.083(6) .
Eu3 C17 3.083(7) 2
Eu3 C14 3.098(7) .
Eu3 H29B 2.72(8) .
Eu4 O2 2.512(6) .
Eu4 C43 2.811(8) .
Eu4 C29 2.828(7) .
Eu4 C50 2.837(7) .
Eu4 C36 2.875(7) .
Eu4 C44 2.952(7) .
Eu4 C30 2.985(6) .
Eu4 C31 2.993(7) .
Eu4 C37 3.251(8) .
Eu4 H29A 2.77(8) .
Eu4 H36B 2.80(9) .
O1 C60A 1.403(12) .
O1 C57A 1.437(13) .
O1 C60B 1.48(4) .
O1 C57B 1.50(4) .
O2 C64B 1.36(5) .
O2 C61B 1.40(7) .
O2 C64A 1.467(15) .
O2 C61A 1.473(19) .
C1 C2 1.409(10) .
C1 H1B 0.87(7) .
C1 H1A 0.88(8) .
C2 C3 1.414(10) .
C2 C7 1.431(9) .
C3 C4 1.383(12) .
C3 H3 0.9500 .
C4 C5 1.389(13) .
C4 H4 0.9500 .
C5 C6 1.376(12) .
C5 H5 0.9500 .
C6 C7 1.390(11) .
C6 H6 0.9500 .
C7 H7 1.0000 .
C8 C9 1.415(11) .
C8 Eu2 2.834(7) 2_655
C8 H8A 0.9900 .
C8 H8AB 0.9900 .
C9 C10 1.427(10) .
C9 C14 1.433(10) .
C10 C11 1.388(11) .
C10 H10 1.0000 .
C11 C12 1.397(11) .
C11 H11 1.0000 .
C12 C13 1.409(12) .
C12 H12 1.0000 .
C13 C14 1.396(12) .
C13 H13 1.0000 .
C14 H14 1.0000 .
C15 C16 1.402(10) .
C15 Eu3 2.826(7) 2
C15 H15B 0.98(7) .
C15 H15A 0.93(10) .
C16 C17 1.425(9) .
C16 C21 1.433(11) .
C16 Eu3 2.920(6) 2
C17 C18 1.390(10) .
C17 Eu3 3.083(7) 2
C17 H17 1.0000 .
C18 C19 1.382(12) .
C18 H18 0.9500 .
C19 C20 1.393(12) .
C19 H19 0.9500 .
C20 C21 1.374(12) .
C20 H20 0.9500 .
C21 H21 0.9500 .
C22 C23 1.432(11) .
C22 H22B 0.87(12) .
C22 H22A 0.99(8) .
C23 C28 1.411(10) .
C23 C24 1.430(10) .
C24 C25 1.379(11) .
C24 H24 0.9500 .
C25 C26 1.378(11) .
C25 H25 0.9500 .
C26 C27 1.365(12) .
C26 H26 0.9500 .
C27 C28 1.375(11) .
C27 H27 0.9500 .
C28 H28 0.9500 .
C29 C30 1.405(10) .
C29 H29B 0.90(8) .
C29 H29A 0.89(8) .
C30 C31 1.422(9) .
C30 C35 1.424(9) .
C31 C32 1.387(10) .
C31 H31 1.0000 .
C32 C33 1.379(11) .
C32 H32 0.9500 .
C33 C34 1.388(12) .
C33 H33 0.9500 .
C34 C35 1.381(10) .
C34 H34 0.9500 .
C35 H35 0.9500 .
C36 C37 1.416(12) .
C36 Eu1 2.818(7) 2
C36 H36B 1.05(9) .
C36 H36A 0.90(10) .
C37 C42 1.426(12) .
C37 C38 1.428(10) .
C37 Eu1 2.908(7) 2
C38 C39 1.393(12) .
C38 Eu1 3.118(7) 2
C38 H38 1.0000 .
C39 C40 1.376(14) .
C39 H39 0.9500 .
C40 C41 1.396(16) .
C40 H40 0.9500 .
C41 C42 1.370(15) .
C41 H41 0.9500 .
C42 H42 0.9500 .
C43 C44 1.422(10) .
C43 Eu1 2.753(8) 1_565
C43 H43B 0.83(9) .
C43 H43A 0.98(8) .
C44 C45 1.425(10) .
C44 C49 1.426(10) .
C44 Eu1 2.921(7) 1_565
C45 C46 1.369(11) .
C45 H45 0.9500 .
C46 C47 1.382(12) .
C46 H46 0.9500 .
C47 C48 1.376(11) .
C47 H47 0.9500 .
C48 C49 1.382(11) .
C48 H48 0.9500 .
C49 H49 0.9500 .
C50 C51 1.405(11) .
C50 H50A 0.9900 .
C50 H50B 0.9900 .
C51 C56 1.441(10) .
C51 C52 1.442(10) .
C51 Eu1 3.182(7) 2_655
C52 C53 1.367(11) .
C52 Eu1 2.971(7) 2_655
C52 H52 1.0000 .
C53 C54 1.409(11) .
C53 Eu1 2.884(7) 2_655
C53 H53 1.0000 .
C54 C55 1.409(12) .
C54 Eu1 2.912(8) 2_655
C54 H54 1.0000 .
C55 C56 1.382(12) .
C55 Eu1 2.997(8) 2_655
C55 H55 1.0000 .
C56 Eu1 3.119(7) 2_655
C56 H56 1.0000 .
C57A C58A 1.500(16) .
C57A H57A 0.9900 .
C57A H57B 0.9900 .
C58A C59A 1.495(18) .
C58A H58A 0.9900 .
C58A H58B 0.9900 .
C59A C60A 1.495(18) .
C59A H59A 0.9900 .
C59A H59B 0.9900 .
C60A H60A 0.9900 .
C60A H60B 0.9900 .
C61A C62A 1.50(2) .
C61A H61A 0.9900 .
C61A H61B 0.9900 .
C62A C63A 1.58(2) .
C62A H62A 0.9900 .
C62A H62B 0.9900 .
C63A C64A 1.42(2) .
C63A H63A 0.9900 .
C63A H63B 0.9900 .
C64A H64A 0.9900 .
C64A H64B 0.9900 .
C57B C58B 1.52(6) .
C57B H57C 0.9900 .
C57B H57D 0.9900 .
C58B C59B 1.47(6) .
C58B H58C 0.9900 .
C58B H58D 0.9900 .
C59B C60B 1.44(6) .
C59B H59C 0.9900 .
C59B H59D 0.9900 .
C60B H60C 0.9900 .
C60B H60D 0.9900 .
C61B C62B 1.49(7) .
C61B H61C 0.9900 .
C61B H61D 0.9900 .
C62B C63B 1.67(7) .
C62B H62C 0.9900 .
C62B H62D 0.9900 .
C63B C64B 1.30(6) .
C63B H63C 0.9900 .
C63B H63D 0.9900 .
C64B H64C 0.9900 .
C64B H64D 0.9900 .
