#------------------------------------------------------------------------------
#$Date: 2019-05-08 01:09:30 +0300 (Wed, 08 May 2019) $
#$Revision: 214972 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/33/7123392.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7123392
loop_
_publ_author_name
'Zhang, Xu'
'Wang, Jin-Yun'
'Huang, Ya-Zi'
'Yang, Ming'
'Chen, Zhong-Ning'
_publ_section_title
;
 Silver(I) Nanoclusters of Carbazole-1,8-Bis(acetylide): from Visible to
 Near-infrared Emission
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC02066G
_journal_year                    2019
_chemical_formula_sum            'C164 H136 Ag8 Cl2 N6 O8 P8'
_chemical_formula_weight         3500.40
_space_group_crystal_system      orthorhombic
_space_group_IT_number           63
_space_group_name_Hall           '-C 2c 2'
_space_group_name_H-M_alt        'C m c m'
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-01-11 deposited with the CCDC.    2019-05-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.3532(8)
_cell_length_b                   27.1392(8)
_cell_length_c                   25.6913(8)
_cell_measurement_reflns_used    9685
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.09
_cell_measurement_theta_min      2.30
_cell_volume                     16282.8(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_unetI/netI     0.0208
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            64310
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.113
_diffrn_reflns_theta_min         2.357
_exptl_absorpt_coefficient_mu    1.107
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.428
_exptl_crystal_description       Bloc
_exptl_crystal_F_000             7024
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.30
_exptl_transmission_factor_max   0.717
_exptl_transmission_factor_min   0.660
_refine_diff_density_max         1.279
_refine_diff_density_min         -0.895
_refine_diff_density_rms         0.147
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     438
_refine_ls_number_reflns         9415
_refine_ls_number_restraints     111
_refine_ls_restrained_S_all      0.962
_refine_ls_R_factor_all          0.0598
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1687P)²+17.6366P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1721
_refine_ls_wR_factor_ref         0.2011
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7608
_reflns_number_total             9415
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9cc02066g2.cif
_cod_data_source_block           2b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_database_code               7123392
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, -z'
'-x, y, -z+1/2'
'-x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'-x, y, z'
'x, -y, z-1/2'
'x, y, -z-1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z-1/2'
'x+1/2, y+1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ag1 Ag 0.56359(2) 0.26777(2) 0.750000 0.03808(14) Uani 1 2 d S T P
Ag2 Ag 0.60568(2) 0.30810(2) 0.64850(2) 0.05772(15) Uani 1 1 d . . .
Ag3 Ag 0.500000 0.35134(2) 0.69223(2) 0.04163(15) Uani 1 2 d S T P
P1 P 0.67271(5) 0.23657(5) 0.64894(5) 0.0522(3) Uani 1 1 d . . .
P2 P 0.61107(5) 0.38367(4) 0.59310(5) 0.0525(3) Uani 1 1 d . . .
N1 N 0.6699(2) 0.22009(18) 0.750000 0.0510(12) Uani 1 2 d S T P
N2 N 0.500000 0.40137(18) 0.5939(2) 0.0519(12) Uani 1 2 d S T P
N3 N 0.500000 0.2063(2) 0.750000 0.0361(12) Uani 1 4 d S T P
N4 N 0.500000 0.4130(2) 0.750000 0.0421(14) Uani 1 4 d S T P
C1 C 0.74819(15) 0.2527(2) 0.6549(2) 0.0815(15) Uani 1 1 d G U .
C2 C 0.7677(2) 0.2927(2) 0.6261(2) 0.110(2) Uani 1 1 d G U .
H2A H 0.742220 0.310917 0.606129 0.132 Uiso 1 1 calc R U .
C3 C 0.8254(2) 0.3053(2) 0.6273(3) 0.121(2) Uani 1 1 d G U .
H3A H 0.838441 0.332101 0.608045 0.145 Uiso 1 1 calc R U .
C4 C 0.86350(16) 0.2781(3) 0.6572(3) 0.138(3) Uani 1 1 d G U .
H4A H 0.902067 0.286544 0.657982 0.166 Uiso 1 1 calc R U .
C5 C 0.84397(19) 0.2381(2) 0.6860(2) 0.125(2) Uani 1 1 d G U .
H5A H 0.869471 0.219802 0.706003 0.150 Uiso 1 1 calc R U .
C6 C 0.7863(2) 0.22537(18) 0.6848(2) 0.106(2) Uani 1 1 d G U .
H6A H 0.773249 0.198617 0.704087 0.127 Uiso 1 1 calc R U .
C7 C 0.67306(18) 0.19496(14) 0.59311(13) 0.0663(12) Uani 1 1 d G U .
C8 C 0.71702(18) 0.16116(17) 0.58567(18) 0.0948(18) Uani 1 1 d G U .
H8A H 0.746370 0.158661 0.609993 0.114 Uiso 1 1 calc R U .
C9 C 0.7171(2) 0.13110(18) 0.5419(2) 0.117(2) Uani 1 1 d G U .
H9A H 0.746544 0.108489 0.536880 0.140 Uiso 1 1 calc R U .
C10 C 0.6733(3) 0.1348(2) 0.50550(17) 0.124(2) Uani 1 1 d G U .
H10A H 0.673335 0.114724 0.476194 0.149 Uiso 1 1 calc R U .
C11 C 0.6293(2) 0.1686(2) 0.51295(17) 0.116(2) Uani 1 1 d G U .
H11A H 0.599951 0.171130 0.488622 0.140 Uiso 1 1 calc R U .
C12 C 0.62919(18) 0.19869(17) 0.55675(17) 0.0874(17) Uani 1 1 d G U .
H12A H 0.599775 0.221303 0.561735 0.105 Uiso 1 1 calc R U .
C13 C 0.66250(18) 0.19535(15) 0.70531(18) 0.0490(9) Uani 1 1 d . . .
C14 C 0.6456(2) 0.14675(16) 0.7037(2) 0.0557(11) Uani 1 1 d . . .
H14A H 0.640600 0.130513 0.672165 0.067 Uiso 1 1 calc R U .
C15 C 0.6364(3) 0.1231(3) 0.750000 0.0626(17) Uani 1 2 d S T P
H15A H 0.623727 0.090607 0.750000 0.075 Uiso 1 2 calc R U P
C16 C 0.6083(2) 0.3703(2) 0.5234(2) 0.0623(12) Uani 1 1 d . . .
C17 C 0.5847(4) 0.4001(3) 0.4873(3) 0.104(2) Uani 1 1 d . . .
H17A H 0.566235 0.428713 0.497991 0.125 Uiso 1 1 calc R U .
C18 C 0.5873(4) 0.3890(4) 0.4348(3) 0.120(3) Uani 1 1 d . . .
H18A H 0.572656 0.411005 0.410447 0.144 Uiso 1 1 calc R U .
C19 C 0.6111(4) 0.3460(4) 0.4191(3) 0.116(3) Uani 1 1 d . . .
H19A H 0.609959 0.337223 0.384099 0.139 Uiso 1 1 calc R U .
C20 C 0.6370(4) 0.3154(3) 0.4544(3) 0.114(3) Uani 1 1 d . . .
H20A H 0.654167 0.286301 0.443434 0.137 Uiso 1 1 calc R U .
C21 C 0.6374(3) 0.3280(3) 0.5059(3) 0.0872(18) Uani 1 1 d . . .
H21A H 0.657047 0.308418 0.529660 0.105 Uiso 1 1 calc R U .
C22 C 0.6746(2) 0.42175(19) 0.5995(2) 0.0644(12) Uani 1 1 d . . .
C23 C 0.6867(4) 0.4590(3) 0.5658(3) 0.111(3) Uani 1 1 d . . .
H23A H 0.661606 0.466792 0.538928 0.134 Uiso 1 1 calc R U .
C24 C 0.7390(5) 0.4858(4) 0.5725(5) 0.150(4) Uani 1 1 d . . .
H24A H 0.747971 0.511457 0.549932 0.180 Uiso 1 1 calc R U .
C25 C 0.7753(4) 0.4742(4) 0.6115(5) 0.133(4) Uani 1 1 d . . .
H25A H 0.809173 0.491824 0.615661 0.160 Uiso 1 1 calc R U .
C26 C 0.7628(3) 0.4372(4) 0.6443(4) 0.115(3) Uani 1 1 d . . .
H26A H 0.788289 0.429197 0.670838 0.138 Uiso 1 1 calc R U .
C27 C 0.7125(2) 0.4109(3) 0.6391(3) 0.0819(17) Uani 1 1 d . . .
H27A H 0.704063 0.385698 0.662417 0.098 Uiso 1 1 calc R U .
C28 C 0.5490(2) 0.42513(15) 0.60131(17) 0.0493(9) Uani 1 1 d . . .
C29 C 0.5506(2) 0.47336(17) 0.6194(2) 0.0618(12) Uani 1 1 d . . .
H29A H 0.585411 0.488852 0.625785 0.074 Uiso 1 1 calc R U .
C30 C 0.500000 0.4977(3) 0.6276(3) 0.0692(19) Uani 1 2 d S T P
H30A H 0.500001 0.530360 0.638551 0.083 Uiso 1 2 calc R U P
C31 C 0.500000 0.2849(2) 0.6484(2) 0.0441(12) Uani 1 2 d S T P
C32 C 0.500000 0.2409(2) 0.6433(2) 0.0406(11) Uani 1 2 d S T P
C33 C 0.500000 0.18843(19) 0.6542(2) 0.0429(12) Uani 1 2 d S T P
C34 C 0.500000 0.1507(2) 0.6169(3) 0.0574(16) Uani 1 2 d S T P
H34A H 0.500000 0.158910 0.581760 0.069 Uiso 1 2 calc R U P
C35 C 0.500000 0.1012(2) 0.6313(3) 0.0681(19) Uani 1 2 d S T P
C36 C 0.500000 0.0882(2) 0.6840(3) 0.0575(16) Uani 1 2 d S T P
H36A H 0.500000 0.055218 0.693785 0.069 Uiso 1 2 calc R U P
C37 C 0.500000 0.12519(19) 0.7220(2) 0.0454(12) Uani 1 2 d S T P
C38 C 0.500000 0.17505(18) 0.7065(2) 0.0390(11) Uani 1 2 d S T P
C39 C 0.500000 0.0606(3) 0.5891(4) 0.110(3) Uani 1 2 d S TU P
C40 C 0.500000 0.0799(5) 0.5359(5) 0.147(5) Uani 1 2 d S TU P
H40A H 0.531990 0.101865 0.532508 0.220 Uiso 0.5 1 d R U P
H40B H 0.500000 0.054245 0.510248 0.220 Uiso 1 2 d R U P
C41 C 0.4468(6) 0.0280(4) 0.5951(5) 0.186(5) Uani 1 1 d . U .
H41A H 0.445603 0.014707 0.629713 0.280 Uiso 1 1 calc R U .
H41B H 0.413077 0.047301 0.588924 0.280 Uiso 1 1 calc R U .
H41C H 0.448485 0.001475 0.570374 0.280 Uiso 1 1 calc R U .
C42 C 0.6105(2) 0.3342(2) 0.750000 0.0455(12) Uani 1 2 d S T P
C43 C 0.6157(2) 0.3786(2) 0.750000 0.0438(12) Uani 1 2 d S T P
C44 C 0.6051(2) 0.4306(2) 0.750000 0.0442(12) Uani 1 2 d S T P
C45 C 0.6457(3) 0.4679(2) 0.750000 0.0497(13) Uani 1 2 d S T P
H45A H 0.684245 0.459157 0.750000 0.060 Uiso 1 2 calc R U P
C46 C 0.6315(3) 0.5182(2) 0.750000 0.0548(15) Uani 1 2 d S T P
C47 C 0.5732(3) 0.5314(2) 0.750000 0.0517(14) Uani 1 2 d S T P
H47A H 0.562669 0.564431 0.750000 0.062 Uiso 1 2 calc R U P
C48 C 0.5307(2) 0.49450(19) 0.750000 0.0453(12) Uani 1 2 d S T P
C49 C 0.5476(2) 0.44449(19) 0.750000 0.0429(12) Uani 1 2 d S T P
C50 C 0.6767(3) 0.5581(2) 0.750000 0.0673(19) Uani 1 2 d S T P
C51 C 0.7376(5) 0.5367(4) 0.750000 0.205(12) Uani 1 2 d S T P
H51A H 0.742950 0.516809 0.719480 0.307 Uiso 0.5 1 d R U P
H51B H 0.764899 0.563129 0.750000 0.307 Uiso 1 2 d R U P
C52 C 0.6700(4) 0.5872(4) 0.7997(4) 0.160(5) Uani 1 1 d . . .
H52A H 0.674963 0.565651 0.829021 0.240 Uiso 1 1 calc R U .
H52B H 0.698397 0.612747 0.800834 0.240 Uiso 1 1 calc R U .
H52C H 0.632532 0.601590 0.800834 0.240 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C42 Ag1 N3 169.62(17) . .
C42 Ag1 Ag1 121.27(14) . 10_655
N3 Ag1 Ag1 48.35(10) . 10_655
C42 Ag1 Ag2 61.129(18) . 12_557
N3 Ag1 Ag2 119.426(10) . 12_557
Ag1 Ag1 Ag2 109.163(10) 10_655 12_557
C42 Ag1 Ag2 61.130(18) . .
N3 Ag1 Ag2 119.426(10) . .
Ag1 Ag1 Ag2 109.164(10) 10_655 .
Ag2 Ag1 Ag2 121.15(2) 12_557 .
C42 Ag1 Ag3 67.81(12) . .
N3 Ag1 Ag3 103.23(9) . .
Ag1 Ag1 Ag3 61.279(8) 10_655 .
Ag2 Ag1 Ag3 107.925(15) 12_557 .
Ag2 Ag1 Ag3 58.078(10) . .
C42 Ag1 Ag3 67.81(12) . 3_656
N3 Ag1 Ag3 103.23(9) . 3_656
Ag1 Ag1 Ag3 61.279(8) 10_655 3_656
Ag2 Ag1 Ag3 58.077(10) 12_557 3_656
Ag2 Ag1 Ag3 107.926(15) . 3_656
Ag3 Ag1 Ag3 57.401(17) . 3_656
P1 Ag2 P2 127.56(4) . .
P1 Ag2 C31 114.55(13) . .
P2 Ag2 C31 104.56(13) . .
P1 Ag2 C42 100.00(12) . .
P2 Ag2 C42 109.38(12) . .
C31 Ag2 C42 96.09(17) . .
P1 Ag2 Ag3 146.29(3) . .
P2 Ag2 Ag3 86.14(3) . .
C31 Ag2 Ag3 44.72(13) . .
C42 Ag2 Ag3 64.15(11) . .
P1 Ag2 Ag1 85.28(3) . .
P2 Ag2 Ag1 144.33(3) . .
C31 Ag2 Ag1 65.94(12) . .
C42 Ag2 Ag1 43.09(11) . .
Ag3 Ag2 Ag1 62.603(13) . .
C31 Ag3 N4 170.39(18) . .
C31 Ag3 Ag2 57.44(2) . 10_655
N4 Ag3 Ag2 123.328(11) . 10_655
C31 Ag3 Ag2 57.44(2) . .
N4 Ag3 Ag2 123.329(11) . .
Ag2 Ag3 Ag2 113.29(2) 10_655 .
C31 Ag3 Ag3 121.96(15) . 3_656
N4 Ag3 Ag3 48.43(10) . 3_656
Ag2 Ag3 Ag3 112.346(11) 10_655 3_656
Ag2 Ag3 Ag3 112.346(11) . 3_656
C31 Ag3 Ag1 68.39(13) . 10_655
N4 Ag3 Ag1 103.31(9) . 10_655
Ag2 Ag3 Ag1 59.320(10) 10_655 10_655
Ag2 Ag3 Ag1 107.006(15) . 10_655
Ag3 Ag3 Ag1 61.299(8) 3_656 10_655
C31 Ag3 Ag1 68.38(13) . .
N4 Ag3 Ag1 103.31(9) . .
Ag2 Ag3 Ag1 107.007(15) 10_655 .
Ag2 Ag3 Ag1 59.319(10) . .
Ag3 Ag3 Ag1 61.300(8) 3_656 .
Ag1 Ag3 Ag1 57.439(15) 10_655 .
C1 P1 C7 102.1(2) . .
C1 P1 C13 101.8(2) . .
C7 P1 C13 104.0(2) . .
C1 P1 Ag2 114.89(18) . .
C7 P1 Ag2 118.74(13) . .
C13 P1 Ag2 113.21(14) . .
C22 P2 C16 103.4(2) . .
C22 P2 C28 106.5(2) . .
C16 P2 C28 101.8(2) . .
C22 P2 Ag2 117.16(19) . .
C16 P2 Ag2 113.14(17) . .
C28 P2 Ag2 113.27(13) . .
C13 N1 C13 117.8(5) . 12_557
C28 N2 C28 119.1(5) . 10_655
C38 N3 C38 105.7(6) 3_656 .
C38 N3 Ag1 116.83(17) 3_656 .
C38 N3 Ag1 116.83(17) . .
C38 N3 Ag1 116.83(17) 3_656 10_655
C38 N3 Ag1 116.83(17) . 10_655
Ag1 N3 Ag1 83.3(2) . 10_655
C49 N4 C49 104.9(6) 10_655 .
C49 N4 Ag3 117.14(18) 10_655 3_656
C49 N4 Ag3 117.14(18) . 3_656
C49 N4 Ag3 117.14(18) 10_655 .
C49 N4 Ag3 117.14(18) . .
Ag3 N4 Ag3 83.1(2) 3_656 .
C2 C1 C6 120.0 . .
C2 C1 P1 117.4(3) . .
C6 C1 P1 122.6(3) . .
C3 C2 C1 120.0 . .
C3 C2 H2A 120.0 . .
C1 C2 H2A 120.0 . .
C2 C3 C4 120.0 . .
C2 C3 H3A 120.0 . .
C4 C3 H3A 120.0 . .
C3 C4 C5 120.0 . .
C3 C4 H4A 120.0 . .
C5 C4 H4A 120.0 . .
C6 C5 C4 120.0 . .
C6 C5 H5A 120.0 . .
C4 C5 H5A 120.0 . .
C5 C6 C1 120.0 . .
C5 C6 H6A 120.0 . .
C1 C6 H6A 120.0 . .
C8 C7 C12 120.0 . .
C8 C7 P1 121.3(2) . .
C12 C7 P1 118.7(2) . .
C7 C8 C9 120.0 . .
C7 C8 H8A 120.0 . .
C9 C8 H8A 120.0 . .
C8 C9 C10 120.0 . .
C8 C9 H9A 120.0 . .
C10 C9 H9A 120.0 . .
C11 C10 C9 120.0 . .
C11 C10 H10A 120.0 . .
C9 C10 H10A 120.0 . .
C10 C11 C12 120.0 . .
C10 C11 H11A 120.0 . .
C12 C11 H11A 120.0 . .
C11 C12 C7 120.0 . .
C11 C12 H12A 120.0 . .
C7 C12 H12A 120.0 . .
N1 C13 C14 122.8(5) . .
N1 C13 P1 110.6(3) . .
C14 C13 P1 126.4(4) . .
C15 C14 C13 117.9(5) . .
C15 C14 H14A 121.0 . .
C13 C14 H14A 121.0 . .
C14 C15 C14 120.7(6) . 12_557
C14 C15 H15A 119.7 . .
C14 C15 H15A 119.7 12_557 .
C17 C16 C21 117.9(6) . .
C17 C16 P2 124.7(5) . .
C21 C16 P2 117.2(4) . .
C16 C17 C18 121.5(7) . .
C16 C17 H17A 119.2 . .
C18 C17 H17A 119.2 . .
C19 C18 C17 119.7(8) . .
C19 C18 H18A 120.1 . .
C17 C18 H18A 120.1 . .
C18 C19 C20 120.3(8) . .
C18 C19 H19A 119.8 . .
C20 C19 H19A 119.8 . .
C21 C20 C19 119.5(7) . .
C21 C20 H20A 120.2 . .
C19 C20 H20A 120.2 . .
C20 C21 C16 120.6(7) . .
C20 C21 H21A 119.7 . .
C16 C21 H21A 119.7 . .
C23 C22 C27 119.6(6) . .
C23 C22 P2 122.3(5) . .
C27 C22 P2 118.0(4) . .
C22 C23 C24 118.6(8) . .
C22 C23 H23A 120.7 . .
C24 C23 H23A 120.7 . .
C25 C24 C23 120.4(8) . .
C25 C24 H24A 119.8 . .
C23 C24 H24A 119.8 . .
C26 C25 C24 120.2(8) . .
C26 C25 H25A 119.9 . .
C24 C25 H25A 119.9 . .
C25 C26 C27 120.7(9) . .
C25 C26 H26A 119.7 . .
C27 C26 H26A 119.7 . .
C22 C27 C26 120.5(7) . .
C22 C27 H27A 119.8 . .
C26 C27 H27A 119.8 . .
N2 C28 C29 121.9(5) . .
N2 C28 P2 111.4(3) . .
C29 C28 P2 126.2(4) . .
C30 C29 C28 118.8(5) . .
C30 C29 H29A 120.6 . .
C28 C29 H29A 120.6 . .
C29 C30 C29 119.2(7) . 10_655
C29 C30 H30A 120.4 . .
C29 C30 H30A 120.4 10_655 .
C32 C31 Ag3 154.3(5) . .
C32 C31 Ag2 104.25(13) . 10_655
Ag3 C31 Ag2 77.84(13) . 10_655
C32 C31 Ag2 104.25(13) . .
Ag3 C31 Ag2 77.85(13) . .
Ag2 C31 Ag2 151.3(3) 10_655 .
C31 C32 C33 162.6(6) . .
C38 C33 C34 118.0(5) . .
C38 C33 C32 116.3(5) . .
C34 C33 C32 125.7(5) . .
C35 C34 C33 121.4(6) . .
C35 C34 H34A 119.3 . .
C33 C34 H34A 119.3 . .
C34 C35 C36 120.0(6) . .
C34 C35 C39 120.0(8) . .
C36 C35 C39 120.0(7) . .
C35 C36 C37 119.6(6) . .
C35 C36 H36A 120.2 . .
C37 C36 H36A 120.2 . .
C36 C37 C38 119.5(6) . .
C36 C37 C37 134.2(4) . 3_656
C38 C37 C37 106.4(3) . 3_656
C33 C38 N3 127.7(5) . .
C33 C38 C37 121.5(5) . .
N3 C38 C37 110.8(5) . .
C40 C39 C41 107.5(7) . 10_655
C40 C39 C41 107.5(7) . .
C41 C39 C41 108.3(12) 10_655 .
C40 C39 C35 113.6(9) . .
C41 C39 C35 109.9(6) 10_655 .
C41 C39 C35 109.9(6) . .
C39 C40 H40A 107.8 . .
C39 C40 H40B 112.4 . .
H40A C40 H40B 113.0 . .
C39 C40 H40A 107.8(3) . 10_655
H40A C40 H40A 102.2 . 10_655
H40B C40 H40A 112.9 . 10_655
C39 C41 H41A 109.5 . .
C39 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C39 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C43 C42 Ag1 154.5(5) . .
C43 C42 Ag2 105.36(11) . 12_557
Ag1 C42 Ag2 75.78(11) . 12_557
C43 C42 Ag2 105.37(11) . .
Ag1 C42 Ag2 75.78(11) . .
Ag2 C42 Ag2 149.2(2) 12_557 .
C42 C43 C44 164.3(6) . .
C45 C44 C49 117.5(5) . .
C45 C44 C43 126.8(5) . .
C49 C44 C43 115.7(5) . .
C44 C45 C46 123.1(5) . .
C44 C45 H45A 118.4 . .
C46 C45 H45A 118.4 . .
C45 C46 C47 118.4(5) . .
C45 C46 C50 122.0(6) . .
C47 C46 C50 119.6(5) . .
C48 C47 C46 120.0(5) . .
C48 C47 H47A 120.0 . .
C46 C47 H47A 120.0 . .
C47 C48 C49 119.1(5) . .
C47 C48 C48 134.7(3) . 10_655
C49 C48 C48 106.2(3) . 10_655
C44 C49 N4 126.7(5) . .
C44 C49 C48 121.9(5) . .
N4 C49 C48 111.4(5) . .
C52 C50 C52 115.5(12) 12_557 .
C52 C50 C46 107.6(5) 12_557 .
C52 C50 C46 107.6(5) . .
C52 C50 C51 107.0(6) 12_557 .
C52 C50 C51 107.0(6) . .
C46 C50 C51 112.1(6) . .
C50 C51 H51A 109.5 . .
C50 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C50 C51 H51A 109.5(2) . 12_557
H51A C51 H51A 109.5 . 12_557
H51B C51 H51A 109.5 . 12_557
C50 C52 H52A 109.5 . .
C50 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C50 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C42 2.110(6) .
Ag1 N3 2.235(4) .
Ag1 Ag1 2.9702(8) 10_655
Ag1 Ag2 2.9937(4) 12_557
Ag1 Ag2 2.9938(4) .
Ag1 Ag3 3.0906(5) .
Ag1 Ag3 3.0906(5) 3_656
Ag2 P1 2.4939(12) .
Ag2 P2 2.4998(12) .
Ag2 C31 2.5472(15) .
Ag2 C42 2.7045(15) .
Ag2 Ag3 2.9546(4) .
Ag3 C31 2.127(6) .
Ag3 N4 2.237(4) .
Ag3 Ag3 2.9684(9) 3_656
P1 C1 1.823(4) .
P1 C7 1.825(3) .
P1 C13 1.845(5) .
P2 C22 1.815(5) .
P2 C16 1.828(6) .
P2 C28 1.847(5) .
N1 C13 1.341(5) .
N1 C13 1.341(5) 12_557
N2 C28 1.327(5) .
N2 C28 1.327(5) 10_655
N3 C38 1.402(6) 3_656
N3 C38 1.402(6) .
N4 C49 1.402(6) 10_655
N4 C49 1.402(6) .
C1 C2 1.3900 .
C1 C6 1.3900 .
C2 C3 1.3900 .
C2 H2A 0.9300 .
C3 C4 1.3900 .
C3 H3A 0.9300 .
C4 C5 1.3900 .
C4 H4A 0.9300 .
C5 C6 1.3900 .
C5 H5A 0.9300 .
C6 H6A 0.9300 .
C7 C8 1.3900 .
C7 C12 1.3900 .
C8 C9 1.3900 .
C8 H8A 0.9300 .
C9 C10 1.3900 .
C9 H9A 0.9300 .
C10 C11 1.3900 .
C10 H10A 0.9300 .
C11 C12 1.3900 .
C11 H11A 0.9300 .
C12 H12A 0.9300 .
C13 C14 1.378(6) .
C14 C15 1.368(6) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C16 C17 1.347(9) .
C16 C21 1.407(8) .
C17 C18 1.383(11) .
C17 H17A 0.9300 .
C18 C19 1.355(12) .
C18 H18A 0.9300 .
C19 C20 1.371(12) .
C19 H19A 0.9300 .
C20 C21 1.366(11) .
C20 H20A 0.9300 .
C21 H21A 0.9300 .
C22 C23 1.361(8) .
C22 C27 1.380(9) .
C23 C24 1.433(11) .
C23 H23A 0.9300 .
C24 C25 1.350(16) .
C24 H24A 0.9300 .
C25 C26 1.343(15) .
C25 H25A 0.9300 .
C26 C27 1.382(10) .
C26 H26A 0.9300 .
C27 H27A 0.9300 .
C28 C29 1.389(6) .
C29 C30 1.370(7) .
C29 H29A 0.9300 .
C30 H30A 0.9300 .
C31 C32 1.202(8) .
C32 C33 1.450(8) .
C33 C38 1.391(8) .
C33 C34 1.403(8) .
C34 C35 1.395(10) .
C34 H34A 0.9300 .
C35 C36 1.398(11) .
C35 C39 1.546(10) .
C36 C37 1.399(8) .
C36 H36A 0.9300 .
C37 C38 1.410(7) .
C37 C37 1.440(13) 3_656
C39 C40 1.465(17) .
C39 C41 1.532(12) 10_655
C39 C41 1.532(12) .
C40 H40A 0.9600 .
C40 H40B 0.9575 .
C40 H40A 0.9600 10_655
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 C43 1.210(8) .
C43 C44 1.433(8) .
C44 C45 1.388(7) .
C44 C49 1.394(8) .
C45 C46 1.405(8) .
C45 H45A 0.9300 .
C46 C47 1.408(9) .
C46 C50 1.512(8) .
C47 C48 1.408(8) .
C47 H47A 0.9300 .
C48 C49 1.413(7) .
C48 C48 1.435(11) 10_655
C50 C52 1.509(10) 12_557
C50 C52 1.509(10) .
C50 C51 1.535(14) .
C51 H51A 0.9602 .
C51 H51B 0.9601 .
C51 H51A 0.9602 12_557
C52 H52A 0.9600 .
C52 H52B 0.9600 .
C52 H52C 0.9600 .
