#------------------------------------------------------------------------------
#$Date: 2019-05-21 03:39:58 +0300 (Tue, 21 May 2019) $
#$Revision: 215335 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/35/7123503.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7123503
loop_
_publ_author_name
'Li, Bei-Bei'
'Wang, Wenjing'
'Hong, Zixiao'
'M. El-Sayed, El-Sayed'
'Yuan, Daqiang'
_publ_section_title
;
 Ratiometric fluorescent detecting trace water in organic solvent based on
 bimetallic lanthanide metal-organic frameworks
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC02324K
_journal_year                    2019
_chemical_formula_moiety
'C92 H163 Eu5 N8 O88 P6, 2(C4 H9 N O), 44 (H2 O)'
_chemical_formula_sum            'C92 H163 Eu5 N8 O88 P6'
_chemical_formula_weight         3734.91
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-05-17 deposited with the CCDC.    2019-05-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.765(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   33.9147(12)
_cell_length_b                   18.5857(8)
_cell_length_c                   29.5768(10)
_cell_measurement_reflns_used    9988
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      68.50
_cell_measurement_theta_min      2.74
_cell_volume                     17850.7(12)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0491
_diffrn_reflns_av_unetI/netI     0.0542
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            56195
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.625
_diffrn_reflns_theta_min         3.847
_exptl_absorpt_coefficient_mu    13.664
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.82
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.390
_exptl_crystal_description       block
_exptl_crystal_F_000             7520
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.305
_refine_diff_density_min         -1.119
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     711
_refine_ls_number_reflns         16361
_refine_ls_number_restraints     759
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0844
_refine_ls_R_factor_gt           0.0688
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1439P)²+9.1731P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2121
_refine_ls_wR_factor_ref         0.2283
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11818
_reflns_number_total             16361
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9cc02324k2.cif
_cod_data_source_block           Eu
_cod_database_code               7123503
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.105
_shelx_estimated_absorpt_t_max   0.342
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.12290(2) 0.68768(2) 0.42697(2) 0.07584(16) Uani 1 1 d . . . . .
Eu2 Eu 0.04096(2) 0.61697(3) 0.31959(2) 0.09068(18) Uani 1 1 d . . . . .
Eu3 Eu 0.250000 0.750000 0.500000 0.0921(2) Uani 1 2 d S . P . .
P1 P 0.30270(6) 0.51323(15) 0.27718(8) 0.1020(7) Uani 1 1 d . . . . .
P2 P 0.38216(5) 0.49417(11) 0.33322(6) 0.0812(5) Uani 1 1 d . . . . .
P3 P 0.31944(7) 0.40517(14) 0.34238(11) 0.1152(8) Uani 1 1 d . . . . .
O1 O 0.28016(15) 0.5846(4) 0.2869(2) 0.1086(18) Uani 1 1 d . . . . .
O2 O 0.40840(13) 0.5529(3) 0.36792(17) 0.0831(12) Uani 1 1 d . . . . .
O3 O 0.2990(2) 0.3962(4) 0.3839(3) 0.142(3) Uani 1 1 d . . . . .
O4 O 0.28372(17) 0.5092(4) 0.2218(2) 0.129(3) Uani 1 1 d . . . . .
O5 O 0.41683(13) 0.4629(3) 0.31213(16) 0.0867(13) Uani 1 1 d . . . . .
O6 O 0.3200(2) 0.3222(4) 0.3316(4) 0.159(3) Uani 1 1 d . . . . .
O7 O 0.09579(15) 0.5586(4) 0.2958(2) 0.115(2) Uani 1 1 d . . . . .
O8 O 0.11959(13) 0.6452(3) 0.34777(17) 0.0841(13) Uani 1 1 d . . . . .
O11 O 0.2913(3) 0.7497(5) 0.4450(3) 0.1495(19) Uani 1 1 d . . . . .
O12 O 0.3338(3) 0.7391(5) 0.5062(3) 0.1495(19) Uani 1 1 d . U . . .
O13 O 0.2977(4) 0.2675(7) 0.0767(4) 0.197(4) Uani 1 1 d . U . . .
O14 O 0.3593(3) 0.2897(4) 0.1068(2) 0.129(3) Uani 1 1 d . . . . .
O15 O 0.4500(2) 0.1920(4) 0.2372(4) 0.130(3) Uani 1 1 d . . . . .
O16 O 0.47661(19) 0.1606(4) 0.3122(3) 0.139(3) Uani 1 1 d . . . . .
O17 O 0.55758(16) 0.2280(4) 0.3619(3) 0.1132(19) Uani 1 1 d . . . . .
O18 O 0.5672(2) 0.2742(5) 0.4324(3) 0.149(3) Uani 1 1 d . . . . .
O20 O 0.0707(2) 0.5969(5) 0.4044(3) 0.149(3) Uani 1 1 d . . . . .
H21 H 0.063282 0.561608 0.423707 0.179 Uiso 1 1 calc R U . . .
O22 O 0.0127(4) 0.4961(6) 0.3126(7) 0.146(5) Uani 0.5 1 d . U P . .
O23 O 0.000000 0.5486(5) 0.250000 0.114(3) Uani 1 2 d S T P . .
H22 H -0.000001 0.497495 0.250001 0.136 Uiso 1 2 calc R U P . .
N1 N 0.28910(19) 0.4462(4) 0.3002(3) 0.106(2) Uani 1 1 d . . . . .
N2 N 0.35012(16) 0.5317(4) 0.2904(2) 0.0875(17) Uani 1 1 d . . . . .
N3 N 0.36540(19) 0.4364(4) 0.3611(2) 0.0925(17) Uani 1 1 d . . . . .
C1 C 0.24026(18) 0.5848(5) 0.2920(2) 0.094(2) Uani 1 1 d D U . . .
C2 C 0.2103(2) 0.5371(6) 0.2711(3) 0.147(4) Uani 1 1 d D U . . .
H2 H 0.215490 0.499330 0.251914 0.176 Uiso 1 1 calc R U . . .
C3 C 0.1722(2) 0.5450(6) 0.2783(3) 0.131(4) Uani 1 1 d D U . . .
H3 H 0.150410 0.513761 0.262392 0.157 Uiso 1 1 calc R U . . .
C4 C 0.16484(18) 0.5968(4) 0.3077(2) 0.0807(17) Uani 1 1 d D U . . .
C5 C 0.19492(19) 0.6447(4) 0.3280(3) 0.0871(19) Uani 1 1 d D U . . .
H5 H 0.190024 0.681383 0.348085 0.105 Uiso 1 1 calc R U . . .
C6 C 0.2330(2) 0.6398(5) 0.3192(3) 0.090(2) Uani 1 1 d D U . . .
H6 H 0.253780 0.674459 0.332075 0.108 Uiso 1 1 calc R U . . .
C7 C 0.12431(19) 0.5988(4) 0.3182(3) 0.0829(19) Uani 1 1 d . . . . .
C8 C 0.2763(2) 0.4483(4) 0.3988(3) 0.0937(19) Uani 1 1 d D U . . .
C11 C 0.2293(2) 0.5429(4) 0.4313(2) 0.0853(17) Uani 1 1 d D U . . .
C15 C 0.38965(18) 0.5999(4) 0.3922(2) 0.0741(15) Uani 1 1 d D U . . .
C16 C 0.3606(2) 0.6483(4) 0.3679(2) 0.095(2) Uani 1 1 d D U . . .
H16 H 0.353733 0.651657 0.334477 0.114 Uiso 1 1 calc R U . . .
C17 C 0.3415(2) 0.6917(4) 0.3929(2) 0.091(2) Uani 1 1 d D U . . .
H17 H 0.320896 0.724458 0.376268 0.109 Uiso 1 1 calc R U . . .
C18 C 0.35163(19) 0.6888(4) 0.4415(2) 0.0725(15) Uani 1 1 d D U . . .
C19 C 0.3821(3) 0.6422(5) 0.4643(2) 0.101(2) Uani 1 1 d D U . . .
H19 H 0.390367 0.640748 0.497866 0.122 Uiso 1 1 calc R U . . .
C20 C 0.4008(2) 0.5978(5) 0.4402(2) 0.094(2) Uani 1 1 d D U . . .
H20 H 0.421675 0.565413 0.456836 0.113 Uiso 1 1 calc R U . . .
C21 C 0.3270(4) 0.7278(8) 0.4665(5) 0.1495(19) Uani 1 1 d . . . . .
C22 C 0.44997(17) 0.4181(4) 0.3341(2) 0.0778(16) Uani 1 1 d D U . . .
C23 C 0.46454(19) 0.4097(4) 0.3823(2) 0.088(2) Uani 1 1 d D U . . .
H23 H 0.452899 0.435861 0.402866 0.106 Uiso 1 1 calc R U . . .
C24 C 0.4964(2) 0.3624(5) 0.3997(3) 0.101(2) Uani 1 1 d D U . . .
H24 H 0.506254 0.354982 0.432801 0.121 Uiso 1 1 calc R U . . .
C25 C 0.5144(2) 0.3257(4) 0.3706(2) 0.0851(18) Uani 1 1 d D U . . .
C26 C 0.49900(18) 0.3352(4) 0.3216(2) 0.0801(16) Uani 1 1 d D U . . .
H26 H 0.510789 0.309549 0.300885 0.096 Uiso 1 1 calc R U . . .
C27 C 0.46665(18) 0.3819(4) 0.3036(2) 0.0778(16) Uani 1 1 d D U . . .
H27 H 0.456050 0.388856 0.270489 0.093 Uiso 1 1 calc R U . . .
C28 C 0.5484(2) 0.2709(5) 0.3913(4) 0.108(3) Uani 1 1 d . . . . .
C29 C 0.3518(2) 0.2899(5) 0.3163(4) 0.114(3) Uani 1 1 d D U . . .
C30 C 0.3832(3) 0.2594(5) 0.3510(4) 0.129(3) Uani 1 1 d D U . . .
H30 H 0.382836 0.261237 0.382993 0.155 Uiso 1 1 calc R U . . .
C31 C 0.4149(3) 0.2263(5) 0.3394(4) 0.112(2) Uani 1 1 d D U . . .
H31 H 0.436752 0.204807 0.363211 0.135 Uiso 1 1 calc R U . . .
C32 C 0.41468(18) 0.2244(4) 0.2930(3) 0.0919(19) Uani 1 1 d D U . . .
C33 C 0.3828(2) 0.2536(5) 0.2580(3) 0.106(2) Uani 1 1 d D U . . .
H33 H 0.382316 0.249523 0.225870 0.127 Uiso 1 1 calc R U . . .
C34 C 0.3513(2) 0.2889(5) 0.2701(4) 0.118(3) Uani 1 1 d D U . . .
H34 H 0.329913 0.312018 0.246652 0.141 Uiso 1 1 calc R U . . .
C35 C 0.4492(3) 0.1881(5) 0.2799(6) 0.114(3) Uani 1 1 d . . . . .
C36 C 0.29464(19) 0.4545(5) 0.1940(3) 0.102(3) Uani 1 1 d D U . . .
C37 C 0.3340(2) 0.4508(5) 0.1915(3) 0.122(3) Uani 1 1 d D U . . .
H37 H 0.354744 0.482051 0.209532 0.146 Uiso 1 1 calc R U . . .
C38 C 0.3428(2) 0.4000(5) 0.1617(3) 0.111(3) Uani 1 1 d D U . . .
H38 H 0.370213 0.395881 0.160007 0.133 Uiso 1 1 calc R U . . .
C39 C 0.3132(2) 0.3556(5) 0.1346(2) 0.0883(19) Uani 1 1 d D U . . .
C40 C 0.2742(3) 0.3609(7) 0.1394(3) 0.134(4) Uani 1 1 d D U . . .
H40 H 0.253481 0.328961 0.121973 0.161 Uiso 1 1 calc R U . . .
C41 C 0.2641(2) 0.4114(6) 0.1688(3) 0.131(4) Uani 1 1 d D U . . .
H41 H 0.236856 0.415418 0.171097 0.157 Uiso 1 1 calc R U . . .
C42 C 0.3248(4) 0.3042(5) 0.1028(3) 0.111(3) Uani 1 1 d . . . . .
O19A O 0.2641(3) 0.6173(6) 0.5270(3) 0.091(3) Uani 0.5 1 d . . P A 1
O9A O 0.1568(3) 0.5673(7) 0.4368(5) 0.092(4) Uani 0.5 1 d D . P A 1
O10A O 0.2001(3) 0.6603(5) 0.4433(4) 0.080(2) Uani 0.5 1 d D . P A 1
C9A C 0.2857(4) 0.5205(6) 0.4040(4) 0.083(3) Uani 0.5 1 d D U P B 1
H9A H 0.310180 0.537766 0.398306 0.099 Uiso 0.5 1 calc R U P B 1
C10A C 0.2599(3) 0.5674(7) 0.4171(4) 0.075(3) Uani 0.5 1 d D U P B 1
H10A H 0.264335 0.617760 0.416059 0.090 Uiso 0.5 1 calc R U P B 1
C12A C 0.2167(4) 0.4722(7) 0.4239(7) 0.091(4) Uani 0.5 1 d D U P B 1
H12A H 0.190570 0.457292 0.426166 0.110 Uiso 0.5 1 calc R U P B 1
C13A C 0.2435(5) 0.4242(8) 0.4130(8) 0.109(5) Uani 0.5 1 d D U P B 1
H13A H 0.239227 0.373974 0.415408 0.131 Uiso 0.5 1 calc R U P B 1
C14A C 0.1932(6) 0.5914(7) 0.4373(6) 0.079(5) Uani 0.5 1 d D . P A 1
O19B O 0.1106(3) 0.6557(7) 0.4991(3) 0.109(4) Uani 0.5 1 d . . P A 2
O9B O 0.1748(4) 0.5988(8) 0.4430(4) 0.077(3) Uani 0.5 1 d D . P A 2
O10B O 0.2348(3) 0.6471(6) 0.4832(3) 0.087(3) Uani 0.5 1 d D . P A 2
C9B C 0.2966(4) 0.4976(7) 0.4276(5) 0.093(4) Uani 0.5 1 d D U P B 2
H9B H 0.325834 0.500257 0.436460 0.111 Uiso 0.5 1 calc R U P B 2
C10B C 0.2734(4) 0.5454(8) 0.4444(5) 0.088(3) Uani 0.5 1 d D U P B 2
H10B H 0.287233 0.581751 0.465679 0.106 Uiso 0.5 1 calc R U P B 2
C12B C 0.2118(4) 0.4916(8) 0.4006(5) 0.090(5) Uani 0.5 1 d D U P B 2
H12B H 0.182624 0.487801 0.390884 0.108 Uiso 0.5 1 calc R U P B 2
C13B C 0.2341(3) 0.4439(9) 0.3824(6) 0.094(4) Uani 0.5 1 d D U P B 2
H13B H 0.220969 0.409312 0.359348 0.113 Uiso 0.5 1 calc R U P B 2
C14B C 0.2143(5) 0.6002(9) 0.4564(6) 0.101(7) Uani 0.5 1 d D . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 Eu1 O9B 113.0(4) 4 .
O14 Eu1 O19B 137.3(4) 4 .
O9B Eu1 O19B 87.6(4) . .
O14 Eu1 O20 136.3(3) 4 .
O9B Eu1 O20 90.7(5) . .
O19B Eu1 O20 76.5(4) . .
O14 Eu1 O8 78.2(2) 4 .
O9B Eu1 O8 78.0(3) . .
O19B Eu1 O8 144.4(4) . .
O20 Eu1 O8 71.3(2) . .
O14 Eu1 O9A 128.3(4) 4 .
O20 Eu1 O9A 71.3(4) . .
O8 Eu1 O9A 73.4(4) . .
O14 Eu1 O12 74.2(3) 4 7_566
O20 Eu1 O12 145.3(3) . 7_566
O8 Eu1 O12 142.0(2) . 7_566
O9A Eu1 O12 104.5(4) . 7_566
O14 Eu1 O18 78.3(3) 4 3_455
O20 Eu1 O18 87.7(3) . 3_455
O8 Eu1 O18 116.0(2) . 3_455
O9A Eu1 O18 153.3(4) . 3_455
O12 Eu1 O18 83.3(3) 7_566 3_455
O14 Eu1 O10A 82.2(3) 4 .
O20 Eu1 O10A 122.9(3) . .
O8 Eu1 O10A 83.1(2) . .
O9A Eu1 O10A 52.5(3) . .
O12 Eu1 O10A 67.9(3) 7_566 .
O18 Eu1 O10A 148.8(3) 3_455 .
O14 Eu1 O17 73.4(3) 4 3_455
O20 Eu1 O17 65.9(3) . 3_455
O8 Eu1 O17 65.70(17) . 3_455
O9A Eu1 O17 127.8(4) . 3_455
O12 Eu1 O17 127.7(2) 7_566 3_455
O18 Eu1 O17 50.7(2) 3_455 3_455
O10A Eu1 O17 143.4(3) . 3_455
O14 Eu1 C28 73.3(3) 4 3_455
O20 Eu1 C28 77.1(3) . 3_455
O8 Eu1 C28 91.7(2) . 3_455
O9A Eu1 C28 148.0(4) . 3_455
O12 Eu1 C28 104.5(3) 7_566 3_455
O18 Eu1 C28 24.4(2) 3_455 3_455
O10A Eu1 C28 155.5(3) . 3_455
O17 Eu1 C28 26.3(2) 3_455 3_455
O14 Eu1 C42 18.9(3) 4 4
O20 Eu1 C42 148.6(3) . 4
O8 Eu1 C42 79.9(2) . 4
O9A Eu1 C42 112.3(4) . 4
O12 Eu1 C42 65.7(3) 7_566 4
O18 Eu1 C42 94.2(3) 3_455 4
O10A Eu1 C42 63.6(3) . 4
O17 Eu1 C42 91.4(2) 3_455 4
C28 Eu1 C42 92.0(3) 3_455 4
O15 Eu2 O16 92.4(3) 4 3_455
O15 Eu2 O17 78.2(3) 4 3_455
O16 Eu2 O17 79.5(2) 3_455 3_455
O15 Eu2 O7 77.4(3) 4 .
O16 Eu2 O7 157.6(3) 3_455 .
O17 Eu2 O7 116.90(19) 3_455 .
O15 Eu2 O22 129.7(5) 4 .
O16 Eu2 O22 88.7(4) 3_455 .
O17 Eu2 O22 150.4(5) 3_455 .
O7 Eu2 O22 83.0(4) . .
O15 Eu2 O20 138.4(3) 4 .
O16 Eu2 O20 104.6(3) 3_455 .
O17 Eu2 O20 68.3(3) 3_455 .
O7 Eu2 O20 96.1(3) . .
O22 Eu2 O20 89.0(5) . .
O15 Eu2 O23 82.2(3) 4 .
O16 Eu2 O23 79.1(2) 3_455 .
O17 Eu2 O23 150.2(2) 3_455 .
O7 Eu2 O23 79.78(16) . .
O22 Eu2 O23 48.8(5) . .
O20 Eu2 O23 137.8(3) . .
O15 Eu2 O8 76.6(2) 4 .
O16 Eu2 O8 145.3(2) 3_455 .
O17 Eu2 O8 66.09(17) 3_455 .
O7 Eu2 O8 51.97(17) . .
O22 Eu2 O8 123.8(4) . .
O20 Eu2 O8 67.8(2) . .
O23 Eu2 O8 130.22(11) . .
O15 Eu2 C7 73.6(2) 4 .
O16 Eu2 C7 164.7(3) 3_455 .
O17 Eu2 C7 91.4(2) 3_455 .
O7 Eu2 C7 25.7(2) . .
O22 Eu2 C7 104.9(4) . .
O20 Eu2 C7 83.1(2) . .
O23 Eu2 C7 104.32(17) . .
O8 Eu2 C7 26.38(18) . .
O15 Eu2 Eu1 100.6(2) 4 .
O16 Eu2 Eu1 114.0(2) 3_455 .
O17 Eu2 Eu1 42.29(14) 3_455 .
O7 Eu2 Eu1 87.71(14) . .
O22 Eu2 Eu1 124.5(4) . .
O20 Eu2 Eu1 37.86(18) . .
O23 Eu2 Eu1 166.34(15) . .
O8 Eu2 Eu1 39.60(10) . .
C7 Eu2 Eu1 64.22(15) . .
O15 Eu2 Eu2 58.3(2) 4 2
O16 Eu2 Eu2 64.4(2) 3_455 2
O17 Eu2 Eu2 119.72(16) 3_455 2
O7 Eu2 Eu2 93.47(15) . 2
O22 Eu2 Eu2 77.6(4) . 2
O20 Eu2 Eu2 162.48(17) . 2
O23 Eu2 Eu2 30.87(19) . 2
O8 Eu2 Eu2 129.20(11) . 2
C7 Eu2 Eu2 111.04(15) . 2
Eu1 Eu2 Eu2 157.731(12) . 2
O10B Eu3 O10B 180.0 7_566 .
O13 Eu3 O13 180.0 6_566 4
O13 Eu3 O11 74.3(3) 6_566 7_566
O13 Eu3 O11 105.7(3) 4 7_566
O10B Eu3 O11 90.7(4) 7_566 .
O10B Eu3 O11 89.3(4) . .
O13 Eu3 O11 105.7(3) 6_566 .
O13 Eu3 O11 74.3(3) 4 .
O11 Eu3 O11 180.0(3) 7_566 .
O13 Eu3 O19A 64.3(4) 6_566 .
O13 Eu3 O19A 115.7(4) 4 .
O11 Eu3 O19A 83.5(3) 7_566 .
O11 Eu3 O19A 96.5(3) . .
O13 Eu3 O19A 115.7(4) 6_566 7_566
O13 Eu3 O19A 64.3(4) 4 7_566
O11 Eu3 O19A 96.5(3) 7_566 7_566
O11 Eu3 O19A 83.5(3) . 7_566
O19A Eu3 O19A 180.0 . 7_566
O13 Eu3 O10A 131.0(4) 6_566 .
O13 Eu3 O10A 49.0(4) 4 .
O11 Eu3 O10A 92.2(3) 7_566 .
O11 Eu3 O10A 87.8(3) . .
O19A Eu3 O10A 67.5(3) . .
O19A Eu3 O10A 112.5(3) 7_566 .
O13 Eu3 O10A 49.0(4) 6_566 7_566
O13 Eu3 O10A 131.0(4) 4 7_566
O11 Eu3 O10A 87.8(3) 7_566 7_566
O11 Eu3 O10A 92.2(3) . 7_566
O19A Eu3 O10A 112.5(3) . 7_566
O19A Eu3 O10A 67.5(3) 7_566 7_566
O10A Eu3 O10A 180.0 . 7_566
O10B Eu3 O12 82.5(3) 7_566 .
O10B Eu3 O12 97.5(3) . .
O13 Eu3 O12 62.2(3) 6_566 .
O13 Eu3 O12 117.8(3) 4 .
O11 Eu3 O12 136.5(3) 7_566 .
O11 Eu3 O12 43.5(3) . .
O19A Eu3 O12 79.5(3) . .
O19A Eu3 O12 100.5(3) 7_566 .
O10A Eu3 O12 117.0(3) . .
O10A Eu3 O12 63.0(3) 7_566 .
O13 Eu3 O12 117.8(3) 6_566 7_566
O13 Eu3 O12 62.2(3) 4 7_566
O11 Eu3 O12 43.5(3) 7_566 7_566
O11 Eu3 O12 136.5(3) . 7_566
O19A Eu3 O12 100.5(3) . 7_566
O19A Eu3 O12 79.5(3) 7_566 7_566
O10A Eu3 O12 63.0(3) . 7_566
O10A Eu3 O12 117.0(3) 7_566 7_566
O12 Eu3 O12 180.0 . 7_566
N1 P1 N2 118.4(4) . .
N1 P1 O4 109.4(4) . .
N2 P1 O4 110.4(3) . .
N1 P1 O1 111.7(3) . .
N2 P1 O1 106.3(4) . .
O4 P1 O1 98.8(3) . .
N3 P2 N2 117.3(4) . .
N3 P2 O2 110.8(3) . .
N2 P2 O2 110.2(3) . .
N3 P2 O5 112.3(3) . .
N2 P2 O5 105.3(3) . .
O2 P2 O5 99.5(3) . .
N1 P3 O6 111.0(5) . .
N1 P3 O3 109.5(4) . .
O6 P3 O3 95.0(4) . .
N1 P3 N3 116.6(4) . .
O6 P3 N3 110.9(4) . .
O3 P3 N3 111.7(5) . .
C1 O1 P1 123.2(6) . .
C15 O2 P2 120.7(4) . .
C8 O3 P3 125.6(6) . .
C36 O4 P1 122.5(5) . .
C22 O5 P2 128.4(4) . .
C29 O6 P3 122.3(6) . .
C7 O7 Eu2 96.9(4) . .
C7 O8 Eu1 153.9(5) . .
C7 O8 Eu2 87.9(4) . .
Eu1 O8 Eu2 97.55(14) . .
C21 O11 Eu3 108.6(8) . .
C21 O12 Eu1 143.8(11) . 7_566
C21 O12 Eu3 92.6(9) . .
Eu1 O12 Eu3 111.5(2) 7_566 .
C42 O13 Eu3 148.4(10) . 4_545
C42 O13 Eu1 77.7(9) . 4_545
Eu3 O13 Eu1 104.9(4) 4_545 4_545
C42 O14 Eu1 121.6(7) . 4_545
C35 O15 Eu2 138.1(7) . 4_545
C35 O16 Eu2 134.9(8) . 3_545
C28 O17 Eu2 145.4(6) . 3_545
C28 O17 Eu1 90.0(6) . 3_545
Eu2 O17 Eu1 99.3(2) 3_545 3_545
C28 O18 Eu1 95.4(5) . 3_545
Eu1 O20 Eu2 103.4(3) . .
Eu2 O23 Eu2 118.3(4) . 2
P1 N1 P3 122.0(5) . .
P2 N2 P1 121.4(4) . .
P2 N3 P3 122.3(4) . .
C2 C1 C6 121.3(6) . .
C2 C1 O1 124.5(6) . .
C6 C1 O1 114.1(6) . .
C1 C2 C3 118.2(7) . .
C4 C3 C2 121.6(7) . .
C5 C4 C3 119.4(6) . .
C5 C4 C7 120.8(6) . .
C3 C4 C7 119.8(6) . .
C4 C5 C6 119.7(6) . .
C1 C6 C5 119.6(7) . .
O7 C7 O8 122.6(6) . .
O7 C7 C4 119.5(7) . .
O8 C7 C4 117.7(6) . .
O7 C7 Eu2 57.4(4) . .
O8 C7 Eu2 65.7(3) . .
C4 C7 Eu2 168.1(5) . .
C9B C8 C13B 125.0(10) . .
C13A C8 C9A 117.8(9) . .
C9B C8 O3 117.4(8) . .
C13B C8 O3 117.7(9) . .
C13A C8 O3 116.4(8) . .
C9A C8 O3 125.6(8) . .
C10A C11 C12A 121.2(9) . .
C12B C11 C10B 115.5(9) . .
C12B C11 C14B 135.4(9) . .
C10B C11 C14B 109.1(9) . .
C10A C11 C14A 123.6(9) . .
C12A C11 C14A 110.5(9) . .
C20 C15 C16 120.4(6) . .
C20 C15 O2 119.1(5) . .
C16 C15 O2 120.4(5) . .
C15 C16 C17 118.8(6) . .
C16 C17 C18 121.5(6) . .
C19 C18 C17 117.7(6) . .
C19 C18 C21 121.8(8) . .
C17 C18 C21 120.1(8) . .
C20 C19 C18 121.7(6) . .
C15 C20 C19 119.8(6) . .
O12 C21 O11 109.6(10) . .
O12 C21 C18 129.3(12) . .
O11 C21 C18 120.9(10) . .
O12 C21 Eu3 65.4(7) . .
O11 C21 Eu3 48.6(6) . .
C18 C21 Eu3 153.3(9) . .
C27 C22 C23 122.1(6) . .
C27 C22 O5 114.6(5) . .
C23 C22 O5 123.3(5) . .
C24 C23 C22 118.0(6) . .
C25 C24 C23 121.9(7) . .
C24 C25 C26 118.9(6) . .
C24 C25 C28 120.2(7) . .
C26 C25 C28 120.7(7) . .
C27 C26 C25 119.7(6) . .
C22 C27 C26 119.3(6) . .
O18 C28 O17 123.6(8) . .
O18 C28 C25 119.4(8) . .
O17 C28 C25 116.6(9) . .
O18 C28 Eu1 60.2(4) . 3_545
O17 C28 Eu1 63.6(4) . 3_545
C25 C28 Eu1 169.2(7) . 3_545
C34 C29 C30 121.9(8) . .
C34 C29 O6 122.5(9) . .
C30 C29 O6 115.6(9) . .
C31 C30 C29 119.7(9) . .
C30 C31 C32 119.0(8) . .
C31 C32 C33 121.3(7) . .
C31 C32 C35 119.5(9) . .
C33 C32 C35 119.2(9) . .
C32 C33 C34 119.4(8) . .
C29 C34 C33 118.6(8) . .
O16 C35 O15 124.5(9) . .
O16 C35 C32 117.2(12) . .
O15 C35 C32 118.1(11) . .
C41 C36 C37 123.1(7) . .
C41 C36 O4 117.3(6) . .
C37 C36 O4 119.5(7) . .
C36 C37 C38 117.8(7) . .
C39 C38 C37 122.0(7) . .
C38 C39 C40 117.6(7) . .
C38 C39 C42 118.7(8) . .
C40 C39 C42 123.7(8) . .
C39 C40 C41 122.1(8) . .
C36 C41 C40 117.4(8) . .
O14 C42 O13 118.7(12) . .
O14 C42 C39 121.9(8) . .
O13 C42 C39 118.3(13) . .
O14 C42 Eu1 39.5(5) . 4_545
O13 C42 Eu1 79.5(8) . 4_545
C39 C42 Eu1 157.0(7) . 4_545
C14A O9A Eu1 95.5(9) . .
C14A O10A Eu1 92.0(9) . .
C14A O10A Eu3 140.6(11) . .
Eu1 O10A Eu3 115.5(3) . .
C10A C9A C8 120.4(10) . .
C11 C10A C9A 120.0(11) . .
C13A C12A C11 117.5(11) . .
C8 C13A C12A 120.5(11) . .
O10A C14A O9A 118.0(12) . .
O10A C14A C11 117.6(12) . .
O9A C14A C11 124.4(10) . .
C14B O9B Eu1 134.4(13) . .
C14B O10B Eu3 151.8(10) . .
C8 C9B C10B 116.1(11) . .
C9B C10B C11 123.0(11) . .
C11 C12B C13B 122.8(11) . .
C8 C13B C12B 117.4(11) . .
O10B C14B O9B 123.5(14) . .
O10B C14B C11 128.1(13) . .
O9B C14B C11 108.2(12) . .
O10B C14B Eu3 17.5(6) . .
O9B C14B Eu3 112.8(11) . .
C11 C14B Eu3 134.1(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O14 2.303(6) 4
Eu1 O9B 2.360(12) .
Eu1 O19B 2.365(7) .
Eu1 O20 2.397(8) .
Eu1 O8 2.444(5) .
Eu1 O9A 2.493(13) .
Eu1 O12 2.498(9) 7_566
Eu1 O18 2.520(6) 3_455
Eu1 O10A 2.572(9) .
Eu1 O17 2.591(6) 3_455
Eu1 C28 2.891(8) 3_455
Eu1 C42 3.085(13) 4
Eu2 O15 2.270(8) 4
Eu2 O16 2.279(6) 3_455
Eu2 O17 2.395(6) 3_455
Eu2 O7 2.426(5) .
Eu2 O22 2.429(10) .
Eu2 O20 2.446(8) .
Eu2 O23 2.476(5) .
Eu2 O8 2.608(4) .
Eu2 C7 2.859(6) .
Eu2 Eu2 4.2506(10) 2
Eu3 O10B 2.006(11) 7_566
Eu3 O10B 2.006(11) .
Eu3 O13 2.399(11) 6_566
Eu3 O13 2.399(11) 4
Eu3 O11 2.433(8) 7_566
Eu3 O11 2.433(8) .
Eu3 O19A 2.594(11) .
Eu3 O19A 2.594(11) 7_566
Eu3 O10A 2.611(9) .
Eu3 O10A 2.611(9) 7_566
Eu3 O12 2.801(9) .
Eu3 O12 2.801(9) 7_566
P1 N1 1.552(9) .
P1 N2 1.579(6) .
P1 O4 1.579(6) .
P1 O1 1.598(6) .
P2 N3 1.557(7) .
P2 N2 1.574(6) .
P2 O2 1.584(5) .
P2 O5 1.591(4) .
P3 N1 1.567(8) .
P3 O6 1.576(7) .
P3 O3 1.583(7) .
P3 N3 1.605(7) .
O1 C1 1.405(8) .
O2 C15 1.395(7) .
O3 C8 1.387(9) .
O4 C36 1.420(9) .
O5 C22 1.399(7) .
O6 C29 1.418(9) .
O7 C7 1.250(9) .
O8 C7 1.271(9) .
O11 C21 1.260(15) .
O12 C21 1.150(13) .
O13 C42 1.223(13) .
O14 C42 1.174(13) .
O15 C35 1.274(15) .
O16 C35 1.235(15) .
O17 C28 1.282(11) .
O18 C28 1.201(12) .
C1 C2 1.356(9) .
C1 C6 1.366(9) .
C2 C3 1.379(9) .
C3 C4 1.368(8) .
C4 C5 1.357(8) .
C4 C7 1.494(9) .
C5 C6 1.391(8) .
C8 C9B 1.306(12) .
C8 C13B 1.372(11) .
C8 C13A 1.373(12) .
C8 C9A 1.377(12) .
C11 C10A 1.309(11) .
C11 C12B 1.333(12) .
C11 C12A 1.379(12) .
C11 C10B 1.436(11) .
C11 C14B 1.470(15) .
C11 C14A 1.571(13) .
C15 C20 1.361(8) .
C15 C16 1.374(8) .
C16 C17 1.374(8) .
C17 C18 1.381(8) .
C18 C19 1.367(8) .
C18 C21 1.458(12) .
C19 C20 1.364(9) .
C22 C27 1.371(8) .
C22 C23 1.376(8) .
C23 C24 1.372(8) .
C24 C25 1.372(8) .
C25 C26 1.404(8) .
C25 C28 1.526(11) .
C26 C27 1.380(8) .
C29 C34 1.361(10) .
C29 C30 1.371(10) .
C30 C31 1.365(10) .
C31 C32 1.372(10) .
C32 C33 1.374(9) .
C32 C35 1.497(11) .
C33 C34 1.384(9) .
C36 C41 1.351(9) .
C36 C37 1.361(8) .
C37 C38 1.379(9) .
C38 C39 1.367(9) .
C39 C40 1.371(9) .
C39 C42 1.472(13) .
C40 C41 1.388(10) .
O9A C14A 1.310(15) .
O10A C14A 1.304(14) .
C9A C10A 1.368(12) .
C12A C13A 1.375(13) .
O9B C14B 1.283(15) .
O10B C14B 1.246(15) .
C9B C10B 1.370(13) .
C12B C13B 1.372(13) .
