#------------------------------------------------------------------------------
#$Date: 2019-10-03 03:01:43 +0300 (Thu, 03 Oct 2019) $
#$Revision: 219043 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/42/7124256.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7124256
loop_
_publ_author_name
'Yang, Xiao-Dong'
'Gao, Na'
'Ma, Shuai'
'Cui, Jing-Wang'
'Jia, Meng-Ze'
'Zhang, Jie'
_publ_section_title
;
 Photoinduced-electron-transfer-driven Surface Modification to Regulate
 Adsorption Behavior in A Pyridinium-decorated Metal−Organic
 Framework
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC06416H
_journal_year                    2019
_chemical_formula_moiety         'C30 H47 Br Eu N5 O22'
_chemical_formula_sum            'C30 H47 Br Eu N5 O22'
_chemical_formula_weight         1061.59
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-07-15 deposited with the CCDC.    2019-10-01 downloaded from the CCDC.
;
_cell_angle_alpha                107.276(4)
_cell_angle_beta                 98.664(3)
_cell_angle_gamma                97.376(3)
_cell_formula_units_Z            2
_cell_length_a                   9.5744(3)
_cell_length_b                   12.8702(6)
_cell_length_c                   18.8207(9)
_cell_measurement_reflns_used    6650
_cell_measurement_temperature    293
_cell_measurement_theta_max      29.4562
_cell_measurement_theta_min      3.1252
_cell_volume                     2152.14(17)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_molecular_graphics    'DIAMOND. Version 3.0. Crystal Impact'
_computing_publication_material  'Windows Word 2010'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXS-2016/6 (Sheldrick, 2016)'
_diffrn_ambient_temperature      293
_diffrn_detector_area_resol_mean 10.4170
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.849
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0316
_diffrn_reflns_av_unetI/netI     0.0526
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.849
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            20984
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.849
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.522
_diffrn_reflns_theta_min         3.131
_exptl_absorpt_coefficient_mu    2.471
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.87206
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1072
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         3.994
_refine_diff_density_min         -2.886
_refine_diff_density_rms         0.145
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         10196
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0688
_refine_ls_R_factor_gt           0.0564
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1005P)²+4.1709P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1566
_refine_ls_wR_factor_ref         0.1673
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8409
_reflns_number_total             10196
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9cc06416h2.cif
_cod_data_source_block           Eu-TPC
_cod_database_code               7124256
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Eu1 Eu 0.23418(2) 0.01062(2) -0.49746(2) 0.03010(10) Uani 1 1 d . .
Br1 Br 1.4856(3) 0.1365(4) 0.1800(2) 0.297(2) Uani 1 1 d . .
O1 O 0.4493(4) 0.0391(4) -0.4117(2) 0.0459(10) Uani 1 1 d . .
O1W O 0.2970(6) -0.1732(5) -0.5117(4) 0.0730(16) Uani 1 1 d . .
O2 O 0.6830(4) 0.0414(4) -0.3851(2) 0.0485(11) Uani 1 1 d . .
O2W O 0.3921(5) 0.1801(4) -0.5004(3) 0.0605(13) Uani 1 1 d . .
O3 O 0.8548(4) 0.0561(4) 0.4024(2) 0.0475(10) Uani 1 1 d . .
O4 O 1.0946(4) 0.0983(4) 0.4324(2) 0.0488(11) Uani 1 1 d . .
O5 O 0.7952(4) 0.8299(4) 0.3980(2) 0.0467(10) Uani 1 1 d . .
O6 O 1.0301(5) 0.8804(4) 0.4286(2) 0.0511(11) Uani 1 1 d . .
N1 N 0.5643(5) 0.1731(4) -0.1309(2) 0.0360(10) Uani 1 1 d . .
N2 N 0.9907(5) 0.1354(4) 0.1779(3) 0.0406(11) Uani 1 1 d . .
N3 N 0.9561(6) 0.5922(4) 0.1788(3) 0.0422(12) Uani 1 1 d . .
C1 C 0.5643(5) 0.0552(5) -0.3675(3) 0.0307(10) Uani 1 1 d . .
C2 C 0.5625(5) 0.0951(4) -0.2834(3) 0.0293(10) Uani 1 1 d . .
C3 C 0.4384(6) 0.1146(5) -0.2578(3) 0.0404(13) Uani 1 1 d . .
H3 H 0.350871 0.101918 -0.293105 0.048 Uiso 1 1 calc R U
C4 C 0.6887(6) 0.1152(5) -0.2301(3) 0.0362(12) Uani 1 1 d . .
H4 H 0.775675 0.100998 -0.246358 0.043 Uiso 1 1 calc R U
C5 C 0.4405(6) 0.1526(6) -0.1811(3) 0.0432(14) Uani 1 1 d . .
H5 H 0.354010 0.164423 -0.163553 0.052 Uiso 1 1 calc R U
C6 C 0.6879(5) 0.1555(5) -0.1540(3) 0.0370(12) Uani 1 1 d . .
H6 H 0.774616 0.171060 -0.117638 0.044 Uiso 1 1 calc R U
C7 C 0.5588(7) 0.2130(7) -0.0477(3) 0.0517(17) Uani 1 1 d . .
H7A H 0.507513 0.151521 -0.034590 0.062 Uiso 1 1 calc R U
H7B H 0.502602 0.273423 -0.038474 0.062 Uiso 1 1 calc R U
C8 C 0.7045(6) 0.2543(5) 0.0041(3) 0.0401(13) Uani 1 1 d . .
C9 C 0.7767(6) 0.1807(5) 0.0286(3) 0.0364(12) Uani 1 1 d . .
C10 C 0.7124(9) 0.0593(6) 0.0026(5) 0.068(2) Uani 1 1 d . .
H10A H 0.609380 0.050240 0.003002 0.102 Uiso 1 1 calc R U
H10B H 0.759622 0.024274 0.036878 0.102 Uiso 1 1 calc R U
H10C H 0.726492 0.024277 -0.049042 0.102 Uiso 1 1 calc R U
C11 C 0.9093(6) 0.2202(4) 0.0785(3) 0.0328(11) Uani 1 1 d . .
C12 C 0.9956(7) 0.1397(5) 0.1005(4) 0.0429(13) Uani 1 1 d . .
H12A H 0.958399 0.064724 0.063524 0.051 Uiso 1 1 calc R U
H12B H 1.096932 0.161059 0.097309 0.051 Uiso 1 1 calc R U
C13 C 0.9687(6) 0.3329(5) 0.1039(3) 0.0366(12) Uani 1 1 d . .
C14 C 1.1112(8) 0.3746(7) 0.1598(5) 0.066(2) Uani 1 1 d . .
H14A H 1.148634 0.311777 0.169765 0.099 Uiso 1 1 calc R U
H14B H 1.097229 0.425502 0.207443 0.099 Uiso 1 1 calc R U
H14C H 1.179953 0.413437 0.138413 0.099 Uiso 1 1 calc R U
C15 C 0.8979(7) 0.4062(5) 0.0776(3) 0.0379(12) Uani 1 1 d . .
C16 C 0.9693(8) 0.5256(5) 0.1008(4) 0.0518(17) Uani 1 1 d . .
H16A H 1.072441 0.529207 0.098687 0.062 Uiso 1 1 calc R U
H16B H 0.926019 0.559152 0.063807 0.062 Uiso 1 1 calc R U
C17 C 0.7654(7) 0.3673(5) 0.0267(3) 0.0422(13) Uani 1 1 d . .
C18 C 0.6864(11) 0.4461(7) -0.0035(5) 0.075(2) Uani 1 1 d . .
H18A H 0.753108 0.515243 0.005613 0.112 Uiso 1 1 calc R U
H18B H 0.606696 0.461847 0.022722 0.112 Uiso 1 1 calc R U
H18C H 0.648769 0.411642 -0.058097 0.112 Uiso 1 1 calc R U
C19 C 1.1090(7) 0.1205(6) 0.2184(4) 0.0509(16) Uani 1 1 d . .
H19 H 1.194512 0.117784 0.198553 0.061 Uiso 1 1 calc R U
C20 C 0.8689(6) 0.1360(6) 0.2033(3) 0.0454(14) Uani 1 1 d . .
H20 H 0.786823 0.148559 0.173992 0.055 Uiso 1 1 calc R U
C21 C 1.1074(6) 0.1090(6) 0.2888(4) 0.0496(16) Uani 1 1 d . .
H21 H 1.193121 0.103211 0.318966 0.060 Uiso 1 1 calc R U
C22 C 0.8591(6) 0.1188(6) 0.2710(3) 0.0442(14) Uani 1 1 d . .
H22 H 0.769655 0.115632 0.287055 0.053 Uiso 1 1 calc R U
C23 C 0.9794(6) 0.1060(5) 0.3155(3) 0.0360(11) Uani 1 1 d . .
C24 C 0.9750(6) 0.0857(5) 0.3901(3) 0.0360(11) Uani 1 1 d . .
C25 C 1.0740(8) 0.6550(6) 0.2277(4) 0.0577(19) Uani 1 1 d . .
H25 H 1.165674 0.650353 0.214836 0.069 Uiso 1 1 calc R U
C26 C 0.8274(7) 0.5972(6) 0.1966(4) 0.0505(16) Uani 1 1 d . .
H26 H 0.745028 0.550740 0.161617 0.061 Uiso 1 1 calc R U
C27 C 1.0635(7) 0.7262(6) 0.2964(4) 0.0542(17) Uani 1 1 d . .
H27 H 1.148050 0.769380 0.331317 0.065 Uiso 1 1 calc R U
C28 C 0.8101(7) 0.6676(5) 0.2641(4) 0.0480(15) Uani 1 1 d . .
H28 H 0.717412 0.670172 0.275941 0.058 Uiso 1 1 calc R U
C29 C 0.9323(6) 0.7353(5) 0.3149(3) 0.0366(12) Uani 1 1 d . .
C30 C 0.9175(6) 0.8204(4) 0.3870(3) 0.0356(11) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O6 145.03(19) . 1_444
O1 Eu1 O4 142.73(17) . 1_454
O6 Eu1 O4 72.18(17) 1_444 1_454
O1 Eu1 O2 100.15(13) . 2_654
O6 Eu1 O2 81.93(15) 1_444 2_654
O4 Eu1 O2 79.14(15) 1_454 2_654
O1 Eu1 O5 80.14(15) . 2_665
O6 Eu1 O5 119.24(15) 1_444 2_665
O4 Eu1 O5 78.69(16) 1_454 2_665
O2 Eu1 O5 142.12(17) 2_654 2_665
O1 Eu1 O3 80.25(15) . 2_655
O6 Eu1 O3 78.85(16) 1_444 2_655
O4 Eu1 O3 121.35(14) 1_454 2_655
O2 Eu1 O3 144.95(18) 2_654 2_655
O5 Eu1 O3 72.83(16) 2_665 2_655
O1 Eu1 O1W 73.42(18) . .
O6 Eu1 O1W 73.60(18) 1_444 .
O4 Eu1 O1W 139.15(18) 1_454 .
O2 Eu1 O1W 74.6(2) 2_654 .
O5 Eu1 O1W 138.81(19) 2_665 .
O3 Eu1 O1W 72.00(19) 2_655 .
O1 Eu1 O2W 72.23(17) . .
O6 Eu1 O2W 139.54(17) 1_444 .
O4 Eu1 O2W 71.92(16) 1_454 .
O2 Eu1 O2W 73.57(17) 2_654 .
O5 Eu1 O2W 70.53(17) 2_665 .
O3 Eu1 O2W 137.08(17) 2_655 .
O1W Eu1 O2W 127.27(18) . .
O1 Eu1 C30 96.99(14) . 2_665
O6 Eu1 C30 99.42(15) 1_444 2_665
O4 Eu1 C30 70.42(15) 1_454 2_665
O2 Eu1 C30 147.28(16) 2_654 2_665
O5 Eu1 C30 19.83(14) 2_665 2_665
O3 Eu1 C30 65.51(15) 2_655 2_665
O1W Eu1 C30 137.47(18) . 2_665
O2W Eu1 C30 85.58(16) . 2_665
O1 Eu1 Eu1 140.11(10) . 2_554
O6 Eu1 Eu1 46.45(11) 1_444 2_554
O4 Eu1 Eu1 58.74(11) 1_454 2_554
O2 Eu1 Eu1 119.22(9) 2_654 2_554
O5 Eu1 Eu1 72.82(10) 2_665 2_554
O3 Eu1 Eu1 64.20(10) 2_655 2_554
O1W Eu1 Eu1 109.36(13) . 2_554
O2W Eu1 Eu1 122.70(12) . 2_554
C30 Eu1 Eu1 53.02(10) 2_665 2_554
C1 O1 Eu1 178.5(4) . .
C1 O2 Eu1 134.6(3) . 2_654
C24 O3 Eu1 135.8(4) . 2_655
C24 O4 Eu1 142.8(4) . 1_656
C30 O5 Eu1 118.7(4) . 2_665
C30 O6 Eu1 173.3(5) . 1_666
C6 N1 C5 121.2(4) . .
C6 N1 C7 121.2(4) . .
C5 N1 C7 117.5(4) . .
C20 N2 C19 121.0(5) . .
C20 N2 C12 120.8(5) . .
C19 N2 C12 117.9(5) . .
C26 N3 C25 120.2(5) . .
C26 N3 C16 120.3(5) . .
C25 N3 C16 119.1(5) . .
O1 C1 O2 126.3(5) . .
O1 C1 C2 117.1(4) . .
O2 C1 C2 116.6(4) . .
C3 C2 C4 118.4(4) . .
C3 C2 C1 121.4(4) . .
C4 C2 C1 120.2(4) . .
C2 C3 C5 120.1(5) . .
C2 C3 H3 119.9 . .
C5 C3 H3 119.9 . .
C6 C4 C2 120.1(5) . .
C6 C4 H4 120.0 . .
C2 C4 H4 120.0 . .
N1 C5 C3 120.3(5) . .
N1 C5 H5 119.9 . .
C3 C5 H5 119.9 . .
N1 C6 C4 120.0(5) . .
N1 C6 H6 120.0 . .
C4 C6 H6 120.0 . .
N1 C7 C8 113.9(5) . .
N1 C7 H7A 108.8 . .
C8 C7 H7A 108.8 . .
N1 C7 H7B 108.8 . .
C8 C7 H7B 108.8 . .
H7A C7 H7B 107.7 . .
C9 C8 C17 120.9(5) . .
C9 C8 C7 119.7(6) . .
C17 C8 C7 119.4(6) . .
C8 C9 C11 119.3(5) . .
C8 C9 C10 120.6(6) . .
C11 C9 C10 120.0(6) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 C13 120.5(5) . .
C9 C11 C12 119.9(5) . .
C13 C11 C12 119.4(5) . .
N2 C12 C11 113.6(5) . .
N2 C12 H12A 108.8 . .
C11 C12 H12A 108.8 . .
N2 C12 H12B 108.8 . .
C11 C12 H12B 108.8 . .
H12A C12 H12B 107.7 . .
C15 C13 C11 120.0(5) . .
C15 C13 C14 120.3(6) . .
C11 C13 C14 119.7(6) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 C17 120.0(5) . .
C13 C15 C16 119.2(6) . .
C17 C15 C16 120.7(6) . .
N3 C16 C15 113.5(5) . .
N3 C16 H16A 108.9 . .
C15 C16 H16A 108.9 . .
N3 C16 H16B 108.9 . .
C15 C16 H16B 108.9 . .
H16A C16 H16B 107.7 . .
C15 C17 C8 119.1(5) . .
C15 C17 C18 120.9(6) . .
C8 C17 C18 119.9(6) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N2 C19 C21 120.2(6) . .
N2 C19 H19 119.9 . .
C21 C19 H19 119.9 . .
N2 C20 C22 121.2(5) . .
N2 C20 H20 119.4 . .
C22 C20 H20 119.4 . .
C19 C21 C23 119.7(5) . .
C19 C21 H21 120.2 . .
C23 C21 H21 120.2 . .
C20 C22 C23 119.7(5) . .
C20 C22 H22 120.2 . .
C23 C22 H22 120.2 . .
C22 C23 C21 118.1(5) . .
C22 C23 C24 122.1(5) . .
C21 C23 C24 119.8(5) . .
O3 C24 O4 127.0(5) . .
O3 C24 C23 117.1(5) . .
O4 C24 C23 115.8(5) . .
N3 C25 C27 120.5(6) . .
N3 C25 H25 119.8 . .
C27 C25 H25 119.8 . .
N3 C26 C28 121.9(6) . .
N3 C26 H26 119.1 . .
C28 C26 H26 119.1 . .
C29 C27 C25 120.2(6) . .
C29 C27 H27 119.9 . .
C25 C27 H27 119.9 . .
C26 C28 C29 118.3(6) . .
C26 C28 H28 120.9 . .
C29 C28 H28 120.9 . .
C27 C29 C28 118.8(5) . .
C27 C29 C30 121.0(5) . .
C28 C29 C30 120.1(5) . .
O5 C30 O6 124.9(5) . .
O5 C30 C29 118.1(5) . .
O6 C30 C29 116.9(5) . .
O5 C30 Eu1 41.5(3) . 2_665
O6 C30 Eu1 83.7(3) . 2_665
C29 C30 Eu1 157.2(4) . 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.331(4) .
Eu1 O6 2.349(4) 1_444
Eu1 O4 2.354(4) 1_454
Eu1 O2 2.397(4) 2_654
Eu1 O5 2.412(4) 2_665
Eu1 O3 2.418(4) 2_655
Eu1 O1W 2.463(6) .
Eu1 O2W 2.509(5) .
Eu1 C30 3.193(6) 2_665
Eu1 Eu1 4.4421(5) 2_554
O1 C1 1.229(6) .
O2 C1 1.251(6) .
O3 C24 1.243(7) .
O4 C24 1.254(6) .
O5 C30 1.234(7) .
O6 C30 1.243(7) .
N1 C6 1.343(7) .
N1 C5 1.342(7) .
N1 C7 1.508(7) .
N2 C20 1.325(8) .
N2 C19 1.334(8) .
N2 C12 1.482(8) .
N3 C26 1.330(8) .
N3 C25 1.336(8) .
N3 C16 1.498(7) .
C1 C2 1.516(7) .
C2 C3 1.373(7) .
C2 C4 1.391(7) .
C3 C5 1.376(7) .
C3 H3 0.9500 .
C4 C6 1.373(7) .
C4 H4 0.9500 .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C8 1.506(8) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.386(9) .
C8 C17 1.406(9) .
C9 C11 1.394(8) .
C9 C10 1.506(9) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C13 1.396(8) .
C11 C12 1.517(8) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C15 1.392(8) .
C13 C14 1.517(8) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C17 1.401(9) .
C15 C16 1.504(8) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C17 C18 1.526(9) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C21 1.379(9) .
C19 H19 0.9500 .
C20 C22 1.371(8) .
C20 H20 0.9500 .
C21 C23 1.393(8) .
C21 H21 0.9500 .
C22 C23 1.377(8) .
C22 H22 0.9500 .
C23 C24 1.508(7) .
C25 C27 1.371(9) .
C25 H25 0.9500 .
C26 C28 1.369(8) .
C26 H26 0.9500 .
C27 C29 1.362(8) .
C27 H27 0.9500 .
C28 C29 1.396(8) .
C28 H28 0.9500 .
C29 C30 1.509(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 O2 C1 O1 3.5(10) 2_654 .
Eu1 O2 C1 C2 -176.9(4) 2_654 .
O1 C1 C2 C3 -1.4(9) . .
O2 C1 C2 C3 178.9(6) . .
O1 C1 C2 C4 -179.9(6) . .
O2 C1 C2 C4 0.4(8) . .
C4 C2 C3 C5 -0.3(9) . .
C1 C2 C3 C5 -178.9(6) . .
C3 C2 C4 C6 -1.2(9) . .
C1 C2 C4 C6 177.4(5) . .
C6 N1 C5 C3 -1.0(10) . .
C7 N1 C5 C3 -179.2(6) . .
C2 C3 C5 N1 1.5(10) . .
C5 N1 C6 C4 -0.5(10) . .
C7 N1 C6 C4 177.5(6) . .
C2 C4 C6 N1 1.6(9) . .
C6 N1 C7 C8 12.9(9) . .
C5 N1 C7 C8 -169.0(6) . .
N1 C7 C8 C9 -87.9(7) . .
N1 C7 C8 C17 92.0(7) . .
C17 C8 C9 C11 2.2(8) . .
C7 C8 C9 C11 -177.9(5) . .
C17 C8 C9 C10 -178.5(6) . .
C7 C8 C9 C10 1.4(8) . .
C8 C9 C11 C13 0.4(8) . .
C10 C9 C11 C13 -179.0(6) . .
C8 C9 C11 C12 -174.7(5) . .
C10 C9 C11 C12 5.9(8) . .
C20 N2 C12 C11 41.7(8) . .
C19 N2 C12 C11 -144.4(6) . .
C9 C11 C12 N2 -104.2(6) . .
C13 C11 C12 N2 80.6(7) . .
C9 C11 C13 C15 -2.2(8) . .
C12 C11 C13 C15 173.0(5) . .
C9 C11 C13 C14 178.3(6) . .
C12 C11 C13 C14 -6.5(8) . .
C11 C13 C15 C17 1.4(8) . .
C14 C13 C15 C17 -179.1(6) . .
C11 C13 C15 C16 -175.2(5) . .
C14 C13 C15 C16 4.3(8) . .
C26 N3 C16 C15 -56.4(9) . .
C25 N3 C16 C15 130.2(7) . .
C13 C15 C16 N3 -79.8(7) . .
C17 C15 C16 N3 103.7(7) . .
C13 C15 C17 C8 1.1(8) . .
C16 C15 C17 C8 177.6(5) . .
C13 C15 C17 C18 -179.5(6) . .
C16 C15 C17 C18 -3.0(9) . .
C9 C8 C17 C15 -2.9(8) . .
C7 C8 C17 C15 177.2(5) . .
C9 C8 C17 C18 177.7(6) . .
C7 C8 C17 C18 -2.3(8) . .
C20 N2 C19 C21 -2.1(11) . .
C12 N2 C19 C21 -176.0(6) . .
C19 N2 C20 C22 -1.6(11) . .
C12 N2 C20 C22 172.1(6) . .
N2 C19 C21 C23 4.1(11) . .
N2 C20 C22 C23 3.3(11) . .
C20 C22 C23 C21 -1.3(10) . .
C20 C22 C23 C24 -179.3(6) . .
C19 C21 C23 C22 -2.3(10) . .
C19 C21 C23 C24 175.8(6) . .
Eu1 O3 C24 O4 -7.1(10) 2_655 .
Eu1 O3 C24 C23 171.2(4) 2_655 .
Eu1 O4 C24 O3 50.0(10) 1_656 .
Eu1 O4 C24 C23 -128.3(5) 1_656 .
C22 C23 C24 O3 15.8(9) . .
C21 C23 C24 O3 -162.3(6) . .
C22 C23 C24 O4 -165.7(6) . .
C21 C23 C24 O4 16.2(9) . .
C26 N3 C25 C27 -0.7(11) . .
C16 N3 C25 C27 172.7(7) . .
C25 N3 C26 C28 1.4(11) . .
C16 N3 C26 C28 -172.0(6) . .
N3 C25 C27 C29 -1.4(12) . .
N3 C26 C28 C29 0.0(11) . .
C25 C27 C29 C28 2.7(11) . .
C25 C27 C29 C30 -174.4(7) . .
C26 C28 C29 C27 -2.0(10) . .
C26 C28 C29 C30 175.1(6) . .
Eu1 O5 C30 O6 8.5(8) 2_665 .
Eu1 O5 C30 C29 -166.9(4) 2_665 .
C27 C29 C30 O5 175.0(6) . .
C28 C29 C30 O5 -2.1(9) . .
C27 C29 C30 O6 -0.7(9) . .
C28 C29 C30 O6 -177.8(6) . .
C27 C29 C30 Eu1 152.2(8) . 2_665
C28 C29 C30 Eu1 -24.9(13) . 2_665
