#------------------------------------------------------------------------------
#$Date: 2019-11-28 15:33:49 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244041 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/55/7125565.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7125565
loop_
_publ_author_name
'Berkei, Michael'
'Bickley, Jamie F.'
'Heaton, Brian T.'
'Steiner, Alexander'
_publ_section_title
;
 Polymeric anionic networks using dibromine as a crosslinker; the
 preparation and crystal structure of [(C4H9)4N]2[Pt2Br10].(Br2)7 and
 [(C4H9)4N]2[PtBr4Cl2].(Br2)6.
;
_journal_issue                   18
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2180
_journal_page_last               2181
_journal_paper_doi               10.1039/b205712n
_journal_year                    2002
_chemical_formula_sum            'C32 H72 Br24 N2 Pt2'
_chemical_formula_weight         2792.94
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.257(2)
_cell_angle_beta                 101.864(2)
_cell_angle_gamma                93.605(2)
_cell_formula_units_Z            2
_cell_length_a                   11.3186(12)
_cell_length_b                   17.1659(19)
_cell_length_c                   18.743(2)
_cell_measurement_temperature    150(2)
_cell_volume                     3445.7(6)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SHELXTL (Bruker, 2000)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker Apex CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1990
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8953
_diffrn_reflns_theta_full        22.49
_diffrn_reflns_theta_max         22.49
_diffrn_reflns_theta_min         1.15
_exptl_absorpt_coefficient_mu    17.997
_exptl_absorpt_correction_T_max  0.2942
_exptl_absorpt_correction_T_min  0.0616
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2000)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.692
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2548
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.175
_refine_diff_density_min         -2.529
_refine_diff_density_rms         0.325
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.890
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     534
_refine_ls_number_reflns         8953
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      0.890
_refine_ls_R_factor_all          0.1158
_refine_ls_R_factor_gt           0.0641
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1573
_refine_ls_wR_factor_ref         0.1883
_reflns_number_gt                5409
_reflns_number_total             8953
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b205712n.txt
_cod_data_source_block           mibe5m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        3445.7(7)
_cod_database_code               7125565
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Br1 Br 0.64155(18) 1.05184(12) 0.02961(11) 0.0270(5) Uani 1 1 d .
Br2 Br 0.6137(2) 0.83812(13) -0.01406(11) 0.0360(6) Uani 1 1 d .
Br3 Br 0.7185(2) 0.94636(13) 0.16893(11) 0.0341(6) Uani 1 1 d .
Br4 Br 0.4284(2) 0.84112(13) 0.11132(12) 0.0365(6) Uani 1 1 d .
Br5 Br 0.4620(2) 1.04683(12) 0.16036(11) 0.0302(6) Uani 1 1 d .
Br6 Br 1.0891(2) 0.66212(13) 0.39566(12) 0.0357(6) Uani 1 1 d .
Br7 Br 1.09365(19) 0.45623(13) 0.35336(11) 0.0328(6) Uani 1 1 d .
Br8 Br 0.87010(19) 0.43739(12) 0.45685(11) 0.0290(5) Uani 1 1 d .
Br9 Br 0.82343(19) 0.53384(13) 0.30627(11) 0.0342(6) Uani 1 1 d .
Br10 Br 0.85975(19) 0.64740(13) 0.48776(11) 0.0306(6) Uani 1 1 d .
Br11 Br 0.8110(2) 0.78405(15) 0.40010(13) 0.0468(7) Uani 1 1 d .
Br12 Br 0.7628(3) 0.8819(2) 0.3382(2) 0.0798(10) Uani 1 1 d .
Br13 Br 0.4719(3) 0.95128(19) 0.40913(14) 0.0646(9) Uani 1 1 d .
Br14 Br 0.4683(2) 0.98910(14) 0.29860(12) 0.0395(6) Uani 1 1 d .
Br15 Br 0.1818(2) 0.90482(15) 0.68230(15) 0.0554(8) Uani 1 1 d .
Br16 Br 0.0656(3) 0.79932(17) 0.58968(15) 0.0677(9) Uani 1 1 d .
Br17 Br 0.5782(2) 0.57418(15) 0.43062(14) 0.0475(7) Uani 1 1 d .
Br18 Br 0.3714(2) 0.53105(14) 0.40074(13) 0.0429(7) Uani 1 1 d .
Br19 Br 0.1070(2) 0.49357(13) 0.20576(12) 0.0371(6) Uani 1 1 d .
Br20 Br 0.1236(2) 0.51918(16) 0.09103(14) 0.0542(8) Uani 1 1 d .
Br21 Br -0.0254(3) 0.0362(2) 0.1249(2) 0.0894(12) Uani 1 1 d .
Br22 Br 0.1780(2) 0.03713(16) 0.12613(16) 0.0590(8) Uani 1 1 d .
Br23 Br 0.2079(3) 0.57025(17) 0.91981(19) 0.0826(11) Uani 1 1 d .
Br24 Br 0.3173(2) 0.68735(14) 0.99874(13) 0.0430(7) Uani 1 1 d .
C1 C 0.091(2) 0.8634(13) 0.2403(12) 0.042(7) Uani 1 1 d .
H1A H 0.0270 0.8940 0.2199 0.051 Uiso 1 1 calc R
H1B H 0.1675 0.8831 0.2286 0.051 Uiso 1 1 calc R
C2 C 0.109(2) 0.8848(12) 0.3247(14) 0.056(8) Uani 1 1 d D
H2A H 0.1815 0.8618 0.3472 0.067 Uiso 1 1 calc R
H2B H 0.0376 0.8606 0.3382 0.067 Uiso 1 1 calc R
C3 C 0.125(2) 0.9750(12) 0.3569(12) 0.063(9) Uani 1 1 d D
H3A H 0.1972 0.9988 0.3440 0.076 Uiso 1 1 calc R
H3B H 0.0532 0.9978 0.3335 0.076 Uiso 1 1 calc R
C4 C 0.140(3) 0.9973(18) 0.4391(12) 0.087(11) Uani 1 1 d D
H4A H 0.0640 0.9812 0.4519 0.131 Uiso 1 1 calc R
H4B H 0.1608 1.0558 0.4579 0.131 Uiso 1 1 calc R
H4C H 0.2054 0.9700 0.4623 0.131 Uiso 1 1 calc R
C5 C 0.150(2) 0.7267(13) 0.2325(13) 0.044(7) Uani 1 1 d .
H5A H 0.1438 0.7310 0.2851 0.053 Uiso 1 1 calc R
H5B H 0.1260 0.6697 0.2046 0.053 Uiso 1 1 calc R
C6 C 0.280(2) 0.7474(13) 0.2329(12) 0.049(7) Uani 1 1 d D
H6A H 0.3051 0.8052 0.2575 0.059 Uiso 1 1 calc R
H6B H 0.2907 0.7372 0.1806 0.059 Uiso 1 1 calc R
C7 C 0.3580(19) 0.6966(13) 0.2752(12) 0.039(6) Uani 1 1 d D
H7A H 0.3496 0.7089 0.3280 0.047 Uiso 1 1 calc R
H7B H 0.3291 0.6389 0.2522 0.047 Uiso 1 1 calc R
C8 C 0.487(2) 0.7120(18) 0.2739(19) 0.091(11) Uani 1 1 d D
H8A H 0.4974 0.6933 0.2222 0.137 Uiso 1 1 calc R
H8B H 0.5364 0.6829 0.3062 0.137 Uiso 1 1 calc R
H8C H 0.5141 0.7699 0.2922 0.137 Uiso 1 1 calc R
C9 C -0.0690(19) 0.7509(13) 0.2054(12) 0.040(6) Uani 1 1 d .
H9A H -0.0685 0.7596 0.2596 0.048 Uiso 1 1 calc R
H9B H -0.1250 0.7865 0.1849 0.048 Uiso 1 1 calc R
C10 C -0.1179(19) 0.6676(13) 0.1679(13) 0.045(7) Uani 1 1 d D
H10A H -0.0722 0.6314 0.1945 0.054 Uiso 1 1 calc R
H10B H -0.1061 0.6554 0.1158 0.054 Uiso 1 1 calc R
C11 C -0.2514(17) 0.6513(13) 0.1658(13) 0.045(7) Uani 1 1 d D
H11A H -0.2732 0.5922 0.1540 0.054 Uiso 1 1 calc R
H11B H -0.2645 0.6741 0.2167 0.054 Uiso 1 1 calc R
C12 C -0.335(2) 0.6836(14) 0.1116(15) 0.060(8) Uani 1 1 d D
H12A H -0.3210 0.7426 0.1261 0.089 Uiso 1 1 calc R
H12B H -0.4190 0.6660 0.1115 0.089 Uiso 1 1 calc R
H12C H -0.3201 0.6638 0.0612 0.089 Uiso 1 1 calc R
C13 C 0.065(2) 0.7650(15) 0.1169(13) 0.048(7) Uani 1 1 d .
H13A H 0.0515 0.7065 0.0926 0.058 Uiso 1 1 calc R
H13B H 0.1478 0.7851 0.1146 0.058 Uiso 1 1 calc R
C14 C -0.029(3) 0.8082(18) 0.0714(13) 0.081(11) Uani 1 1 d D
H14A H -0.1116 0.7927 0.0775 0.097 Uiso 1 1 calc R
H14B H -0.0100 0.8673 0.0911 0.097 Uiso 1 1 calc R
C15 C -0.027(3) 0.7851(18) -0.0118(14) 0.101(12) Uiso 1 1 d D
H15A H -0.0620 0.8265 -0.0360 0.122 Uiso 1 1 calc R
H15B H 0.0589 0.7847 -0.0164 0.122 Uiso 1 1 calc R
C16 C -0.093(3) 0.7065(19) -0.0516(16) 0.118(15) Uani 1 1 d D
H16A H -0.0596 0.6652 -0.0276 0.177 Uiso 1 1 calc R
H16B H -0.0860 0.6940 -0.1041 0.177 Uiso 1 1 calc R
H16C H -0.1792 0.7073 -0.0499 0.177 Uiso 1 1 calc R
C17 C 0.505(2) 0.3873(11) 0.2529(12) 0.036(6) Uani 1 1 d .
H17A H 0.5860 0.4183 0.2753 0.043 Uiso 1 1 calc R
H17B H 0.4472 0.4142 0.2807 0.043 Uiso 1 1 calc R
C18 C 0.467(2) 0.3941(11) 0.1694(12) 0.048(7) Uani 1 1 d D
H18A H 0.5222 0.3665 0.1402 0.057 Uiso 1 1 calc R
H18B H 0.3834 0.3664 0.1468 0.057 Uiso 1 1 calc R
C19 C 0.470(2) 0.4792(12) 0.1645(11) 0.041(6) Uani 1 1 d D
H19A H 0.5504 0.5080 0.1926 0.049 Uiso 1 1 calc R
H19B H 0.4081 0.5047 0.1896 0.049 Uiso 1 1 calc R
C20 C 0.447(2) 0.4901(16) 0.0855(12) 0.059(8) Uani 1 1 d D
H20A H 0.5161 0.4751 0.0635 0.089 Uiso 1 1 calc R
H20B H 0.4364 0.5465 0.0866 0.089 Uiso 1 1 calc R
H20C H 0.3730 0.4557 0.0550 0.089 Uiso 1 1 calc R
C21 C 0.590(2) 0.2565(13) 0.2222(13) 0.043(7) Uani 1 1 d .
H21A H 0.5862 0.2022 0.2320 0.052 Uiso 1 1 calc R
H21B H 0.5542 0.2499 0.1680 0.052 Uiso 1 1 calc R
C22 C 0.721(2) 0.2907(13) 0.2388(14) 0.049(7) Uani 1 1 d D
H22A H 0.7265 0.3461 0.2316 0.059 Uiso 1 1 calc R
H22B H 0.7602 0.2935 0.2918 0.059 Uiso 1 1 calc R
C23 C 0.7865(19) 0.2393(12) 0.1879(11) 0.041(6) Uani 1 1 d D
H23A H 0.7524 0.2420 0.1356 0.049 Uiso 1 1 calc R
H23B H 0.7707 0.1827 0.1904 0.049 Uiso 1 1 calc R
C24 C 0.922(2) 0.2624(15) 0.2059(17) 0.077(10) Uani 1 1 d D
H24A H 0.9389 0.3143 0.1945 0.115 Uiso 1 1 calc R
H24B H 0.9593 0.2211 0.1753 0.115 Uiso 1 1 calc R
H24C H 0.9553 0.2667 0.2593 0.115 Uiso 1 1 calc R
C25 C 0.558(2) 0.3203(13) 0.3481(12) 0.040(6) Uani 1 1 d .
H25A H 0.5031 0.3527 0.3743 0.048 Uiso 1 1 calc R
H25B H 0.6386 0.3526 0.3620 0.048 Uiso 1 1 calc R
C26 C 0.571(2) 0.2430(14) 0.3771(10) 0.047(7) Uani 1 1 d D
H26A H 0.4922 0.2087 0.3605 0.057 Uiso 1 1 calc R
H26B H 0.6311 0.2125 0.3541 0.057 Uiso 1 1 calc R
C27 C 0.611(2) 0.2598(15) 0.4600(10) 0.067(9) Uani 1 1 d D
H27A H 0.5518 0.2918 0.4825 0.080 Uiso 1 1 calc R
H27B H 0.6904 0.2934 0.4761 0.080 Uiso 1 1 calc R
C28 C 0.622(3) 0.1861(15) 0.4911(13) 0.064(8) Uani 1 1 d D
H28A H 0.5414 0.1626 0.4916 0.096 Uiso 1 1 calc R
H28B H 0.6725 0.2016 0.5425 0.096 Uiso 1 1 calc R
H28C H 0.6603 0.1464 0.4593 0.096 Uiso 1 1 calc R
C29 C 0.388(2) 0.2581(13) 0.2417(13) 0.045(7) Uani 1 1 d .
H29A H 0.3964 0.2053 0.2538 0.054 Uiso 1 1 calc R
H29B H 0.3636 0.2478 0.1862 0.054 Uiso 1 1 calc R
C30 C 0.284(2) 0.2945(16) 0.2746(13) 0.058(8) Uani 1 1 d D
H30A H 0.3089 0.3532 0.2942 0.069 Uiso 1 1 calc R
H30B H 0.2130 0.2878 0.2319 0.069 Uiso 1 1 calc R
C31 C 0.241(4) 0.2668(17) 0.3330(19) 0.125(14) Uiso 1 1 d D
H31A H 0.1629 0.2884 0.3365 0.151 Uiso 1 1 calc R
H31B H 0.2996 0.2916 0.3812 0.151 Uiso 1 1 calc R
C32 C 0.222(3) 0.1777(15) 0.3264(15) 0.073(9) Uiso 1 1 d D
H32A H 0.1596 0.1520 0.2809 0.109 Uiso 1 1 calc R
H32B H 0.1956 0.1684 0.3707 0.109 Uiso 1 1 calc R
H32C H 0.2984 0.1547 0.3233 0.109 Uiso 1 1 calc R
N1 N 0.0591(16) 0.7772(9) 0.1984(9) 0.031(5) Uani 1 1 d .
N2 N 0.5109(15) 0.3061(10) 0.2669(9) 0.031(5) Uani 1 1 d .
Pt1 Pt 0.53785(7) 0.94341(5) 0.07153(4) 0.0232(3) Uani 1 1 d .
Pt2 Pt 0.97681(7) 0.55083(5) 0.42192(4) 0.0246(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Pt1 Br1 Pt1 94.08(7) 2_675 .
Pt2 Br8 Pt2 94.94(7) . 2_766
N1 C1 C2 118.7(19) . .
C1 C2 C3 112(2) . .
C4 C3 C2 113(2) . .
C6 C5 N1 116.9(19) . .
C5 C6 C7 110(2) . .
C8 C7 C6 112(2) . .
C10 C9 N1 116.2(17) . .
C9 C10 C11 112.4(18) . .
C12 C11 C10 116(2) . .
N1 C13 C14 113.8(19) . .
C15 C14 C13 110(3) . .
C16 C15 C14 113(2) . .
N2 C17 C18 118.4(16) . .
C19 C18 C17 111.9(16) . .
C18 C19 C20 114.5(19) . .
C22 C21 N2 115.6(16) . .
C23 C22 C21 110.2(17) . .
C22 C23 C24 114.6(18) . .
N2 C25 C26 114.8(16) . .
C27 C26 C25 113.1(18) . .
C26 C27 C28 115(2) . .
N2 C29 C30 117.7(19) . .
C31 C30 C29 122(2) . .
C30 C31 C32 119(3) . .
C1 N1 C13 111.6(18) . .
C1 N1 C5 109.4(17) . .
C13 N1 C5 106.7(16) . .
C1 N1 C9 107.6(15) . .
C13 N1 C9 111.1(17) . .
C5 N1 C9 110.5(17) . .
C25 N2 C17 105.1(16) . .
C25 N2 C29 111.8(17) . .
C17 N2 C29 110.9(17) . .
C25 N2 C21 112.2(18) . .
C17 N2 C21 112.5(17) . .
C29 N2 C21 104.6(15) . .
Br4 Pt1 Br3 91.49(8) . .
Br4 Pt1 Br2 90.09(8) . .
Br3 Pt1 Br2 89.11(8) . .
Br4 Pt1 Br5 88.52(7) . .
Br3 Pt1 Br5 89.93(7) . .
Br2 Pt1 Br5 178.30(8) . .
Br4 Pt1 Br1 91.97(8) . 2_675
Br3 Pt1 Br1 176.46(8) . 2_675
Br2 Pt1 Br1 91.64(7) . 2_675
Br5 Pt1 Br1 89.40(7) . 2_675
Br4 Pt1 Br1 177.29(8) . .
Br3 Pt1 Br1 90.60(8) . .
Br2 Pt1 Br1 91.67(8) . .
Br5 Pt1 Br1 89.75(7) . .
Br1 Pt1 Br1 85.92(7) 2_675 .
Br6 Pt2 Br9 91.54(8) . .
Br6 Pt2 Br10 89.11(8) . .
Br9 Pt2 Br10 89.47(8) . .
Br6 Pt2 Br7 89.70(8) . .
Br9 Pt2 Br7 89.54(7) . .
Br10 Pt2 Br7 178.44(9) . .
Br6 Pt2 Br8 176.40(8) . .
Br9 Pt2 Br8 92.05(8) . .
Br10 Pt2 Br8 90.64(7) . .
Br7 Pt2 Br8 90.60(7) . .
Br6 Pt2 Br8 91.36(8) . 2_766
Br9 Pt2 Br8 177.11(8) . 2_766
Br10 Pt2 Br8 90.57(7) . 2_766
Br7 Pt2 Br8 90.47(7) . 2_766
Br8 Pt2 Br8 85.06(7) . 2_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Br1 Pt1 2.496(2) 2_675
Br1 Pt1 2.497(2) .
Br2 Pt1 2.451(2) .
Br3 Pt1 2.434(2) .
Br4 Pt1 2.425(2) .
Br5 Pt1 2.4668(19) .
Br6 Pt2 2.427(2) .
Br7 Pt2 2.459(2) .
Br8 Pt2 2.509(2) .
Br8 Pt2 2.517(2) 2_766
Br9 Pt2 2.428(2) .
Br10 Pt2 2.457(2) .
Br11 Br12 2.283(4) .
Br13 Br14 2.302(4) .
Br15 Br16 2.311(4) .
Br17 Br18 2.322(3) .
Br19 Br20 2.333(3) .
Br21 Br22 2.297(4) .
Br23 Br24 2.309(3) .
C1 N1 1.49(2) .
C1 C2 1.51(3) .
C2 C3 1.512(19) .
C3 C4 1.47(2) .
C5 C6 1.49(3) .
C5 N1 1.52(3) .
C6 C7 1.514(19) .
C7 C8 1.48(2) .
C9 C10 1.46(3) .
C9 N1 1.53(3) .
C10 C11 1.511(19) .
C11 C12 1.47(2) .
C13 N1 1.51(3) .
C13 C14 1.56(4) .
C14 C15 1.52(2) .
C15 C16 1.46(2) .
C17 N2 1.48(3) .
C17 C18 1.57(3) .
C18 C19 1.485(19) .
C19 C20 1.51(2) .
C21 C22 1.51(3) .
C21 N2 1.51(2) .
C22 C23 1.489(19) .
C23 C24 1.51(2) .
C25 N2 1.46(3) .
C25 C26 1.55(3) .
C26 C27 1.480(19) .
C27 C28 1.51(2) .
C29 N2 1.50(3) .
C29 C30 1.54(3) .
C30 C31 1.44(2) .
C31 C32 1.50(2) .
Pt1 Br1 2.496(2) 2_675
Pt2 Br8 2.517(2) 2_766
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 -173(2) . .
C1 C2 C3 C4 179(2) . .
N1 C5 C6 C7 174.7(17) . .
C5 C6 C7 C8 177(2) . .
N1 C9 C10 C11 -169.7(19) . .
C9 C10 C11 C12 75(3) . .
N1 C13 C14 C15 -174(2) . .
C13 C14 C15 C16 80(4) . .
N2 C17 C18 C19 -177.6(18) . .
C17 C18 C19 C20 174(2) . .
N2 C21 C22 C23 -176(2) . .
C21 C22 C23 C24 -173(2) . .
N2 C25 C26 C27 -176(2) . .
C25 C26 C27 C28 179(2) . .
N2 C29 C30 C31 -103(3) . .
C29 C30 C31 C32 -44(5) . .
C2 C1 N1 C13 -171(2) . .
C2 C1 N1 C5 -53(3) . .
C2 C1 N1 C9 67(3) . .
C14 C13 N1 C1 -64(3) . .
C14 C13 N1 C5 176(2) . .
C14 C13 N1 C9 56(3) . .
C6 C5 N1 C1 -59(2) . .
C6 C5 N1 C13 62(2) . .
C6 C5 N1 C9 -177.5(17) . .
C10 C9 N1 C1 -180(2) . .
C10 C9 N1 C13 58(3) . .
C10 C9 N1 C5 -61(2) . .
C26 C25 N2 C17 179.3(19) . .
C26 C25 N2 C29 59(2) . .
C26 C25 N2 C21 -58(2) . .
C18 C17 N2 C25 176(2) . .
C18 C17 N2 C29 -63(2) . .
C18 C17 N2 C21 53(3) . .
C30 C29 N2 C25 61(3) . .
C30 C29 N2 C17 -56(2) . .
C30 C29 N2 C21 -177.4(19) . .
C22 C21 N2 C25 -57(3) . .
C22 C21 N2 C17 61(3) . .
C22 C21 N2 C29 -178(2) . .
Pt1 Br1 Pt1 Br4 -39.0(15) 2_675 .
Pt1 Br1 Pt1 Br3 -179.34(7) 2_675 .
Pt1 Br1 Pt1 Br2 91.53(7) 2_675 .
Pt1 Br1 Pt1 Br5 -89.41(7) 2_675 .
Pt1 Br1 Pt1 Br1 0.0 2_675 2_675
Pt2 Br8 Pt2 Br6 -4.4(12) 2_766 .
Pt2 Br8 Pt2 Br9 179.98(8) 2_766 .
Pt2 Br8 Pt2 Br10 -90.52(7) 2_766 .
Pt2 Br8 Pt2 Br7 90.42(8) 2_766 .
Pt2 Br8 Pt2 Br8 0.0 2_766 2_766
