#------------------------------------------------------------------------------
#$Date: 2021-10-06 16:43:05 +0300 (Wed, 06 Oct 2021) $
#$Revision: 269605 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/87/7128789.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7128789
loop_
_publ_author_name
'Chang, Fei-Fan'
'Feng, Fan-da'
'Geng, Jiao'
'Huang, Wei'
_publ_section_title
;
 Self-assembly and luminescence of trinuclear lanthanide based
 supramolecular circular helicates.
;
_journal_issue                   73
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9220
_journal_page_last               9223
_journal_paper_doi               10.1039/d1cc03376j
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C153 H138 Cl15 Eu3 N12 O18'
_chemical_formula_sum            'C153 H138 Cl15 Eu3 N12 O18'
_chemical_formula_weight         3420.38
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-05-28 deposited with the CCDC.	2021-08-11 downloaded from the CCDC.
;
_cell_angle_alpha                95.6830(10)
_cell_angle_beta                 101.8700(10)
_cell_angle_gamma                101.2750(10)
_cell_formula_units_Z            2
_cell_length_a                   18.1315(7)
_cell_length_b                   21.8847(8)
_cell_length_c                   25.2702(10)
_cell_measurement_reflns_used    9926
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.041
_cell_measurement_theta_min      2.3505
_cell_volume                     9521.7(6)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (BRUKER 2000)'
_computing_data_reduction        'SAINT (BRUKER 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXTL (BRUKER 2000)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker CCD area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0419
_diffrn_reflns_av_unetI/netI     0.0747
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            69172
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         2.178
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    1.240
_exptl_absorpt_correction_T_max  0.928
_exptl_absorpt_correction_T_min  0.906
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker(2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.193
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3456
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.060
_refine_diff_density_max         2.885
_refine_diff_density_min         -2.510
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1810
_refine_ls_number_reflns         33324
_refine_ls_number_restraints     159
_refine_ls_restrained_S_all      1.116
_refine_ls_R_factor_all          0.0891
_refine_ls_R_factor_gt           0.0626
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0973P)²+4.9880P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1698
_refine_ls_wR_factor_ref         0.1811
_reflns_Friedel_coverage         0.000
_reflns_number_gt                23412
_reflns_number_total             33324
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1cc03376j2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7128789--7128791.cif.'
_cod_original_cell_volume        9521.6(6)
_cod_database_code               7128789
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.907
_shelx_estimated_absorpt_t_max   0.929
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.37250(2) 0.10809(2) 0.70012(2) 0.02537(10) Uani 1 1 d . . . . .
Eu2 Eu 0.66552(2) 0.42759(2) 0.67636(2) 0.02699(10) Uani 1 1 d . . . . .
Eu3 Eu 0.82998(2) 0.14827(2) 0.81444(2) 0.02303(9) Uani 1 1 d . . . . .
C1 C 0.1958(5) 0.1384(5) 0.6576(3) 0.061(3) Uani 1 1 d . . . . .
C2 C 0.1551(5) 0.1029(6) 0.6907(4) 0.070(3) Uani 1 1 d . . . . .
C3 C 0.0727(5) 0.0871(7) 0.6792(5) 0.111(5) Uani 1 1 d . . . . .
H3 H 0.0461 0.0647 0.7025 0.133 Uiso 1 1 calc R U . . .
C4 C 0.0323(5) 0.1056(7) 0.6326(5) 0.093(4) Uani 1 1 d . . . . .
C5 C 0.0705(5) 0.1411(7) 0.6005(5) 0.097(4) Uani 1 1 d . . . . .
H5 H 0.0411 0.1548 0.5702 0.117 Uiso 1 1 calc R U . . .
C6 C 0.1536(5) 0.1581(6) 0.6112(4) 0.070(3) Uani 1 1 d . . . . .
C7 C 0.1948(5) 0.0791(5) 0.7355(3) 0.068(3) Uani 1 1 d . . . . .
H7 H 0.1646 0.0605 0.7587 0.082 Uiso 1 1 calc R U . . .
C8 C 0.1986(5) 0.1958(4) 0.5761(3) 0.059(3) Uani 1 1 d . . . . .
H8A H 0.1624 0.2052 0.5445 0.071 Uiso 1 1 calc R U . . .
H8B H 0.2295 0.2362 0.5978 0.071 Uiso 1 1 calc R U . . .
C9 C 0.3127(4) 0.1966(3) 0.5332(3) 0.0406(19) Uani 1 1 d . . . . .
H9A H 0.3344 0.2376 0.5569 0.049 Uiso 1 1 calc R U . . .
H9B H 0.2890 0.2047 0.4964 0.049 Uiso 1 1 calc R U . . .
C10 C 0.3774(4) 0.1624(3) 0.5293(2) 0.0314(16) Uani 1 1 d . . . . .
C11 C 0.4107(4) 0.1376(3) 0.5767(2) 0.0258(14) Uani 1 1 d . . . . .
C12 C 0.4719(4) 0.1074(3) 0.5748(2) 0.0299(16) Uani 1 1 d . . . . .
C13 C 0.4981(4) 0.1017(4) 0.5263(3) 0.0408(19) Uani 1 1 d . . . . .
H13 H 0.5395 0.0814 0.5247 0.049 Uiso 1 1 calc R U . . .
C14 C 0.4651(5) 0.1251(4) 0.4818(3) 0.046(2) Uani 1 1 d . . . . .
C15 C 0.4040(4) 0.1552(3) 0.4826(3) 0.0380(18) Uani 1 1 d . . . . .
H15 H 0.3810 0.1707 0.4508 0.046 Uiso 1 1 calc R U . . .
C16 C 0.2118(5) 0.0970(4) 0.5218(3) 0.049(2) Uani 1 1 d . . . . .
H16A H 0.1765 0.0733 0.5415 0.058 Uiso 1 1 calc R U . . .
H16B H 0.2513 0.0725 0.5178 0.058 Uiso 1 1 calc R U . . .
C17 C 0.1657(7) 0.0997(5) 0.4653(4) 0.094(4) Uani 1 1 d . . . . .
H17A H 0.1958 0.1326 0.4491 0.112 Uiso 1 1 calc R U . . .
H17B H 0.1593 0.0588 0.4422 0.112 Uiso 1 1 calc R U . . .
C18 C 0.0868(8) 0.1133(5) 0.4633(7) 0.160(4) Uani 1 1 d D U . . .
C19 C 0.0652(8) 0.1675(6) 0.4491(7) 0.175(4) Uani 1 1 d D U . . .
H19 H 0.1029 0.1999 0.4414 0.210 Uiso 1 1 calc R U . . .
C20 C -0.0105(8) 0.1771(6) 0.4453(7) 0.175(4) Uani 1 1 d D U . . .
H20 H -0.0264 0.2119 0.4304 0.210 Uiso 1 1 calc R U . . .
C21 C -0.0617(9) 0.1314(6) 0.4654(7) 0.181(5) Uani 1 1 d D U . . .
H21 H -0.1073 0.1420 0.4729 0.217 Uiso 1 1 calc R U . . .
C22 C -0.0491(8) 0.0746(6) 0.4740(7) 0.172(5) Uani 1 1 d D U . . .
H22 H -0.0868 0.0417 0.4810 0.207 Uiso 1 1 calc R U . . .
C23 C 0.0286(7) 0.0689(6) 0.4717(7) 0.163(4) Uani 1 1 d D U . . .
H23 H 0.0400 0.0290 0.4767 0.196 Uiso 1 1 calc R U . . .
C24 C 0.5104(4) 0.0830(3) 0.6218(3) 0.0309(16) Uani 1 1 d . . . . .
H24 H 0.5528 0.0650 0.6176 0.037 Uiso 1 1 calc R U . . .
C25 C 0.5439(3) 0.0614(3) 0.7115(3) 0.0274(15) Uani 1 1 d . . . . .
H25A H 0.5739 0.0348 0.6949 0.033 Uiso 1 1 calc R U . . .
H25B H 0.5130 0.0356 0.7327 0.033 Uiso 1 1 calc R U . . .
C26 C 0.5989(3) 0.1180(3) 0.7494(3) 0.0283(15) Uani 1 1 d . . . . .
H26A H 0.6407 0.1354 0.7316 0.034 Uiso 1 1 calc R U . . .
H26B H 0.5704 0.1513 0.7557 0.034 Uiso 1 1 calc R U . . .
C27 C 0.6338(3) 0.1004(3) 0.8031(3) 0.0281(15) Uani 1 1 d . . . . .
H27A H 0.5935 0.0901 0.8239 0.034 Uiso 1 1 calc R U . . .
H27B H 0.6553 0.0628 0.7969 0.034 Uiso 1 1 calc R U . . .
C28 C 0.6769(3) 0.1929(3) 0.8674(2) 0.0264(15) Uani 1 1 d . . . . .
H28 H 0.6248 0.1832 0.8709 0.032 Uiso 1 1 calc R U . . .
C29 C 0.7260(4) 0.2504(3) 0.8995(2) 0.0261(15) Uani 1 1 d . . . . .
C30 C 0.8020(4) 0.2728(3) 0.8944(3) 0.0288(15) Uani 1 1 d . . . . .
C31 C 0.8461(4) 0.3304(3) 0.9268(3) 0.0331(16) Uani 1 1 d . . . . .
C32 C 0.8166(5) 0.3615(4) 0.9637(3) 0.0427(19) Uani 1 1 d . . . . .
H32 H 0.8473 0.3988 0.9863 0.051 Uiso 1 1 calc R U . . .
C33 C 0.7407(4) 0.3386(4) 0.9687(3) 0.044(2) Uani 1 1 d . . . . .
C34 C 0.6955(4) 0.2844(4) 0.9364(3) 0.0406(19) Uani 1 1 d . . . . .
H34 H 0.6436 0.2702 0.9391 0.049 Uiso 1 1 calc R U . . .
C35 C 0.9258(4) 0.3542(3) 0.9184(3) 0.0373(18) Uani 1 1 d . . . . .
H35A H 0.9534 0.3901 0.9472 0.045 Uiso 1 1 calc R U . . .
H35B H 0.9217 0.3695 0.8826 0.045 Uiso 1 1 calc R U . . .
C36 C 1.0438(4) 0.3219(4) 0.8987(4) 0.058(3) Uani 1 1 d . . . . .
H36A H 1.0834 0.3532 0.9264 0.069 Uiso 1 1 calc R U . . .
H36B H 1.0312 0.3414 0.8653 0.069 Uiso 1 1 calc R U . . .
C37 C 1.0755(4) 0.2639(4) 0.8856(3) 0.051(2) Uani 1 1 d . . . . .
C38 C 1.0232(4) 0.2110(3) 0.8514(3) 0.0365(17) Uani 1 1 d . . . . .
C39 C 1.0515(4) 0.1566(3) 0.8398(3) 0.0361(17) Uani 1 1 d . . . . .
C40 C 1.1308(4) 0.1568(4) 0.8585(3) 0.051(2) Uani 1 1 d . . . . .
H40 H 1.1501 0.1206 0.8497 0.061 Uiso 1 1 calc R U . . .
C41 C 1.1786(4) 0.2093(5) 0.8890(4) 0.071(3) Uani 1 1 d . . . . .
C42 C 1.1510(4) 0.2643(5) 0.9046(4) 0.069(3) Uani 1 1 d . . . . .
H42 H 1.1850 0.2999 0.9277 0.083 Uiso 1 1 calc R U . . .
C43 C 0.9847(7) 0.2802(5) 0.9735(4) 0.096(3) Uani 1 1 d . U . . .
H43A H 1.0119 0.2453 0.9712 0.115 Uiso 1 1 calc R U . . .
H43B H 0.9341 0.2633 0.9816 0.115 Uiso 1 1 calc R U . . .
C44 C 1.0329(8) 0.3323(5) 1.0208(4) 0.117(3) Uani 1 1 d . U . . .
H44A H 1.0864 0.3453 1.0161 0.140 Uiso 1 1 calc R U . . .
H44B H 1.0097 0.3697 1.0209 0.140 Uiso 1 1 calc R U . . .
C45 C 1.0334(11) 0.3054(7) 1.0746(6) 0.143(3) Uani 1 1 d . U . . .
C46 C 1.1022(11) 0.2912(7) 1.1026(6) 0.162(3) Uani 1 1 d . U . . .
H46 H 1.1456 0.2955 1.0866 0.195 Uiso 1 1 calc R U . . .
C47 C 1.1076(11) 0.2700(7) 1.1554(6) 0.163(3) Uani 1 1 d D U . . .
H47 H 1.1535 0.2636 1.1779 0.196 Uiso 1 1 calc R U . . .
C48 C 1.0358(10) 0.2605(7) 1.1685(6) 0.167(4) Uani 1 1 d D U . . .
H48 H 1.0338 0.2391 1.1993 0.200 Uiso 1 1 calc R U . . .
C49 C 0.9672(11) 0.2755(8) 1.1462(7) 0.168(4) Uani 1 1 d D U . . .
H49 H 0.9263 0.2735 1.1647 0.201 Uiso 1 1 calc R U . . .
C50 C 0.9620(12) 0.2936(8) 1.0951(7) 0.160(4) Uani 1 1 d . U . . .
H50 H 0.9142 0.2984 1.0739 0.192 Uiso 1 1 calc R U . . .
C51 C 1.0009(4) 0.0993(3) 0.8113(3) 0.0351(17) Uani 1 1 d . . . . .
H51 H 1.0242 0.0654 0.8029 0.042 Uiso 1 1 calc R U . . .
C52 C 0.9012(4) 0.0920(3) 0.9341(3) 0.0350(17) Uani 1 1 d . . . . .
H52 H 0.9312 0.1011 0.9706 0.042 Uiso 1 1 calc R U . . .
C53 C 0.8718(4) 0.0266(3) 0.9127(3) 0.0326(16) Uani 1 1 d . . . . .
C54 C 0.8179(4) 0.0071(3) 0.8612(3) 0.0317(16) Uani 1 1 d . . . . .
C55 C 0.7958(4) -0.0574(3) 0.8396(3) 0.0378(18) Uani 1 1 d . . . . .
C56 C 0.8244(5) -0.1005(4) 0.8696(4) 0.058(3) Uani 1 1 d . . . . .
H56 H 0.8112 -0.1438 0.8547 0.070 Uiso 1 1 calc R U . . .
C57 C 0.8728(6) -0.0808(4) 0.9219(4) 0.074(3) Uani 1 1 d . . . . .
C58 C 0.8976(4) -0.0192(4) 0.9421(3) 0.050(2) Uani 1 1 d . . . . .
H58 H 0.9329 -0.0067 0.9767 0.060 Uiso 1 1 calc R U . . .
C59 C 0.7405(4) -0.0772(3) 0.7856(3) 0.0402(19) Uani 1 1 d . . . . .
H59A H 0.6885 -0.0724 0.7892 0.048 Uiso 1 1 calc R U . . .
H59B H 0.7372 -0.1222 0.7732 0.048 Uiso 1 1 calc R U . . .
C60 C 0.7029(4) -0.0481(3) 0.6909(3) 0.0398(19) Uani 1 1 d . . . . .
H60A H 0.6519 -0.0506 0.6999 0.048 Uiso 1 1 calc R U . . .
H60B H 0.7015 -0.0884 0.6687 0.048 Uiso 1 1 calc R U . . .
C61 C 0.7182(4) 0.0055(3) 0.6578(3) 0.0302(16) Uani 1 1 d . . . . .
C62 C 0.7457(3) 0.0682(3) 0.6849(2) 0.0248(15) Uani 1 1 d . . . . .
C63 C 0.7564(4) 0.1173(3) 0.6531(3) 0.0295(16) Uani 1 1 d . . . . .
C64 C 0.7373(4) 0.1047(3) 0.5957(3) 0.0371(18) Uani 1 1 d . . . . .
H64 H 0.7433 0.1378 0.5742 0.045 Uiso 1 1 calc R U . . .
C65 C 0.7093(4) 0.0422(4) 0.5714(3) 0.0399(19) Uani 1 1 d . . . . .
C66 C 0.7006(4) -0.0070(4) 0.6014(3) 0.042(2) Uani 1 1 d . . . . .
H66 H 0.6826 -0.0492 0.5835 0.050 Uiso 1 1 calc R U . . .
C67 C 0.8433(4) -0.0434(4) 0.7347(3) 0.042(2) Uani 1 1 d . . . . .
H67A H 0.8808 -0.0299 0.7704 0.051 Uiso 1 1 calc R U . . .
H67B H 0.8578 -0.0127 0.7103 0.051 Uiso 1 1 calc R U . . .
C68 C 0.8536(5) -0.1067(4) 0.7111(4) 0.067(3) Uani 1 1 d . . . . .
H68A H 0.8289 -0.1404 0.7294 0.080 Uiso 1 1 calc R U . . .
H68B H 0.8290 -0.1160 0.6715 0.080 Uiso 1 1 calc R U . . .
C69 C 0.9381(6) -0.1043(5) 0.7200(3) 0.074(3) Uani 1 1 d D U . . .
C70 C 0.9750(7) -0.0862(8) 0.6814(5) 0.154(7) Uani 1 1 d D . . . .
H70 H 0.9428 -0.0760 0.6504 0.185 Uiso 1 1 calc R U . . .
C71 C 1.0500(7) -0.0796(8) 0.6786(7) 0.156(6) Uani 1 1 d D U . . .
H71 H 1.0699 -0.0732 0.6471 0.187 Uiso 1 1 calc R U . . .
C72 C 1.0915(9) -0.0840(7) 0.7287(6) 0.146(6) Uani 1 1 d D U . . .
H72 H 1.1461 -0.0744 0.7332 0.175 Uiso 1 1 calc R U . . .
C73 C 1.0655(6) -0.1004(9) 0.7741(6) 0.167(8) Uani 1 1 d D U . . .
H73 H 1.0992 -0.1033 0.8075 0.201 Uiso 1 1 calc R U . . .
C74 C 0.9848(6) -0.1124(6) 0.7665(4) 0.094(3) Uani 1 1 d D U . . .
H74 H 0.9623 -0.1268 0.7950 0.113 Uiso 1 1 calc R U . . .
C75 C 0.7854(4) 0.1828(3) 0.6775(3) 0.0305(16) Uani 1 1 d . . . . .
H75 H 0.7872 0.2130 0.6530 0.037 Uiso 1 1 calc R U . . .
C76 C 0.8294(4) 0.2738(3) 0.7423(3) 0.0259(14) Uani 1 1 d . . . . .
H76A H 0.8472 0.2928 0.7119 0.031 Uiso 1 1 calc R U . . .
H76B H 0.8720 0.2864 0.7755 0.031 Uiso 1 1 calc R U . . .
C77 C 0.7593(3) 0.2975(3) 0.7523(2) 0.0250(14) Uani 1 1 d . . . . .
H77A H 0.7199 0.2905 0.7175 0.030 Uiso 1 1 calc R U . . .
H77B H 0.7364 0.2729 0.7782 0.030 Uiso 1 1 calc R U . . .
C78 C 0.7796(4) 0.3659(3) 0.7751(3) 0.0308(16) Uani 1 1 d . . . . .
H78A H 0.8074 0.3718 0.8139 0.037 Uiso 1 1 calc R U . . .
H78B H 0.8141 0.3894 0.7548 0.037 Uiso 1 1 calc R U . . .
C79 C 0.6812(4) 0.3926(3) 0.8138(3) 0.0322(16) Uani 1 1 d . . . . .
H79 H 0.7101 0.3802 0.8452 0.039 Uiso 1 1 calc R U . . .
C80 C 0.6107(4) 0.4120(3) 0.8193(3) 0.0303(15) Uani 1 1 d . . . . .
C81 C 0.5597(4) 0.4260(3) 0.7735(2) 0.0266(14) Uani 1 1 d . . . . .
C82 C 0.4914(4) 0.4451(3) 0.7821(3) 0.0283(15) Uani 1 1 d . . . . .
C83 C 0.4762(4) 0.4498(3) 0.8340(3) 0.0363(17) Uani 1 1 d . . . . .
H83 H 0.4313 0.4631 0.8397 0.044 Uiso 1 1 calc R U . . .
C84 C 0.5261(4) 0.4352(3) 0.8766(3) 0.0368(17) Uani 1 1 d . . . . .
C85 C 0.5927(4) 0.4156(3) 0.8698(3) 0.0304(15) Uani 1 1 d . . . . .
H85 H 0.6258 0.4046 0.9000 0.037 Uiso 1 1 calc R U . . .
C86 C 0.4362(4) 0.4581(4) 0.7322(3) 0.0397(18) Uani 1 1 d . . . . .
H86A H 0.4098 0.4178 0.7084 0.048 Uiso 1 1 calc R U . . .
H86B H 0.3963 0.4774 0.7443 0.048 Uiso 1 1 calc R U . . .
C87 C 0.4300(4) 0.4986(4) 0.6433(3) 0.043(2) Uani 1 1 d . . . . .
H87A H 0.4050 0.4542 0.6281 0.052 Uiso 1 1 calc R U . . .
H87B H 0.3887 0.5219 0.6453 0.052 Uiso 1 1 calc R U . . .
C88 C 0.4787(5) 0.5268(4) 0.6060(3) 0.045(2) Uani 1 1 d . . . . .
C89 C 0.5440(5) 0.4995(3) 0.6008(3) 0.0403(18) Uani 1 1 d . . . . .
C90 C 0.5912(5) 0.5246(3) 0.5661(3) 0.0395(18) Uani 1 1 d . . . . .
C91 C 0.5701(5) 0.5705(4) 0.5350(3) 0.051(2) Uani 1 1 d . . . . .
H91 H 0.5994 0.5848 0.5098 0.061 Uiso 1 1 calc R U . . .
C92 C 0.5085(6) 0.5947(4) 0.5404(3) 0.057(2) Uani 1 1 d . . . . .
C93 C 0.4624(5) 0.5725(4) 0.5766(3) 0.054(2) Uani 1 1 d . . . . .
H93 H 0.4194 0.5902 0.5800 0.065 Uiso 1 1 calc R U . . .
C94 C 0.5155(5) 0.5656(4) 0.7289(3) 0.048(2) Uani 1 1 d . . . . .
H94A H 0.5445 0.5883 0.7049 0.058 Uiso 1 1 calc R U . . .
H94B H 0.5535 0.5623 0.7622 0.058 Uiso 1 1 calc R U . . .
C95 C 0.4619(6) 0.6054(4) 0.7458(3) 0.065(3) Uani 1 1 d . . . . .
H95A H 0.4126 0.5951 0.7178 0.078 Uiso 1 1 calc R U . . .
H95B H 0.4857 0.6504 0.7467 0.078 Uiso 1 1 calc R U . . .
C96 C 0.4443(6) 0.5961(4) 0.8018(4) 0.057(2) Uani 1 1 d . . . . .
C97 C 0.5026(7) 0.6097(5) 0.8470(4) 0.075(3) Uani 1 1 d . . . . .
H97 H 0.5538 0.6247 0.8432 0.090 Uiso 1 1 calc R U . . .
C98 C 0.4909(8) 0.6029(6) 0.8987(4) 0.095(4) Uani 1 1 d . . . . .
H98 H 0.5331 0.6140 0.9298 0.114 Uiso 1 1 calc R U . . .
C99 C 0.4176(7) 0.5798(6) 0.9045(5) 0.084(4) Uani 1 1 d . . . . .
H99 H 0.4096 0.5723 0.9395 0.100 Uiso 1 1 calc R U . . .
C100 C 0.3579(7) 0.5677(6) 0.8620(5) 0.091(4) Uani 1 1 d . . . . .
H100 H 0.3070 0.5552 0.8673 0.109 Uiso 1 1 calc R U . . .
C101 C 0.3698(7) 0.5736(5) 0.8069(5) 0.088(4) Uani 1 1 d . . . . .
H101 H 0.3278 0.5623 0.7758 0.105 Uiso 1 1 calc R U . . .
C102 C 0.6571(5) 0.5014(4) 0.5617(3) 0.048(2) Uani 1 1 d . . . . .
H102 H 0.6785 0.5113 0.5314 0.058 Uiso 1 1 calc R U . . .
C103 C 0.7453(4) 0.3276(3) 0.6054(3) 0.0287(15) Uani 1 1 d . . . . .
C104 C 0.6780(4) 0.2841(3) 0.5756(3) 0.0283(15) Uani 1 1 d . . . . .
C105 C 0.6814(5) 0.2417(3) 0.5311(3) 0.0390(18) Uani 1 1 d . . . . .
H105 H 0.6364 0.2118 0.5113 0.047 Uiso 1 1 calc R U . . .
C106 C 0.7507(5) 0.2440(4) 0.5166(3) 0.052(2) Uani 1 1 d . . . . .
C107 C 0.8189(5) 0.2877(4) 0.5452(3) 0.050(2) Uani 1 1 d . . . . .
H107 H 0.8664 0.2886 0.5345 0.060 Uiso 1 1 calc R U . . .
C108 C 0.8149(4) 0.3291(3) 0.5893(3) 0.0360(17) Uani 1 1 d . . . . .
C109 C 0.6035(4) 0.2802(3) 0.5888(3) 0.0279(15) Uani 1 1 d . . . . .
H109 H 0.5631 0.2459 0.5696 0.033 Uiso 1 1 calc R U . . .
C110 C 0.5079(3) 0.3046(3) 0.6325(2) 0.0267(14) Uani 1 1 d . . . . .
H11A H 0.4728 0.2772 0.6000 0.032 Uiso 1 1 calc R U . . .
H11B H 0.4896 0.3440 0.6379 0.032 Uiso 1 1 calc R U . . .
C111 C 0.5078(4) 0.2714(3) 0.6826(2) 0.0270(15) Uani 1 1 d . . . . .
H11C H 0.5523 0.2936 0.7124 0.032 Uiso 1 1 calc R U . . .
H11D H 0.5136 0.2278 0.6737 0.032 Uiso 1 1 calc R U . . .
C112 C 0.4331(4) 0.2698(3) 0.7020(3) 0.0293(15) Uani 1 1 d . . . . .
H11E H 0.4321 0.3126 0.7183 0.035 Uiso 1 1 calc R U . . .
H11F H 0.3880 0.2553 0.6706 0.035 Uiso 1 1 calc R U . . .
C113 C 0.4501(3) 0.2517(3) 0.7926(2) 0.0252(14) Uani 1 1 d . . . . .
H113 H 0.4630 0.2964 0.7992 0.030 Uiso 1 1 calc R U . . .
C114 C 0.4566(3) 0.2197(3) 0.8405(3) 0.0276(15) Uani 1 1 d . . . . .
C115 C 0.4502(3) 0.1540(3) 0.8366(2) 0.0254(14) Uani 1 1 d . . . . .
C116 C 0.4582(3) 0.1253(3) 0.8842(2) 0.0264(14) Uani 1 1 d . . . . .
C117 C 0.4701(4) 0.1618(3) 0.9352(3) 0.0336(16) Uani 1 1 d . . . . .
H117 H 0.4740 0.1426 0.9675 0.040 Uiso 1 1 calc R U . . .
C118 C 0.4763(4) 0.2273(3) 0.9380(3) 0.0362(17) Uani 1 1 d . . . . .
C119 C 0.4695(4) 0.2554(3) 0.8919(3) 0.0323(16) Uani 1 1 d . . . . .
H119 H 0.4736 0.2996 0.8948 0.039 Uiso 1 1 calc R U . . .
C120 C 0.4571(4) 0.0564(3) 0.8803(3) 0.0342(16) Uani 1 1 d . . . . .
H12A H 0.4561 0.0425 0.9163 0.041 Uiso 1 1 calc R U . . .
H12B H 0.5044 0.0484 0.8698 0.041 Uiso 1 1 calc R U . . .
C121 C 0.3940(4) -0.0470(3) 0.8205(3) 0.0374(17) Uani 1 1 d . . . . .
H12C H 0.4467 -0.0457 0.8149 0.045 Uiso 1 1 calc R U . . .
H12D H 0.3867 -0.0726 0.8500 0.045 Uiso 1 1 calc R U . . .
C122 C 0.3354(4) -0.0777(3) 0.7684(3) 0.0361(17) Uani 1 1 d . . . . .
C123 C 0.3307(4) -0.0432(3) 0.7234(3) 0.0331(16) Uani 1 1 d . . . . .
C124 C 0.2738(4) -0.0720(4) 0.6744(3) 0.0358(17) Uani 1 1 d . . . . .
C125 C 0.2304(4) -0.1337(4) 0.6710(3) 0.046(2) Uani 1 1 d . . . . .
H125 H 0.1950 -0.1539 0.6378 0.055 Uiso 1 1 calc R U . . .
C126 C 0.2391(5) -0.1639(4) 0.7145(4) 0.050(2) Uani 1 1 d . . . . .
C127 C 0.2905(4) -0.1364(4) 0.7645(3) 0.0446(19) Uani 1 1 d . . . . .
H127 H 0.2939 -0.1584 0.7951 0.054 Uiso 1 1 calc R U . . .
C128 C 0.3120(4) 0.0214(4) 0.8537(3) 0.0367(17) Uani 1 1 d . . . . .
H12E H 0.2690 -0.0043 0.8244 0.044 Uiso 1 1 calc R U . . .
H12F H 0.3054 0.0654 0.8564 0.044 Uiso 1 1 calc R U . . .
C129 C 0.3063(5) -0.0028(4) 0.9080(3) 0.051(2) Uani 1 1 d . . . . .
H12G H 0.3271 -0.0413 0.9102 0.061 Uiso 1 1 calc R U . . .
H12H H 0.3370 0.0295 0.9390 0.061 Uiso 1 1 calc R U . . .
C130 C 0.2258(8) -0.0167(7) 0.9111(6) 0.140(3) Uani 1 1 d D U . . .
C131 C 0.1866(8) -0.0802(8) 0.9085(7) 0.158(4) Uani 1 1 d D U . . .
H131 H 0.2155 -0.1118 0.9062 0.190 Uiso 1 1 calc R U . . .
C132 C 0.1081(8) -0.0998(8) 0.9092(7) 0.161(4) Uani 1 1 d D U . . .
H132 H 0.0843 -0.1427 0.9086 0.194 Uiso 1 1 calc R U . . .
C133 C 0.0677(8) -0.0515(7) 0.9109(6) 0.141(4) Uani 1 1 d D U . . .
H133 H 0.0140 -0.0630 0.9097 0.169 Uiso 1 1 calc R U . . .
C134 C 0.1003(6) 0.0118(7) 0.9142(5) 0.128(3) Uani 1 1 d D U . . .
H134 H 0.0725 0.0443 0.9157 0.153 Uiso 1 1 calc R U . . .
C135 C 0.1769(6) 0.0218(8) 0.9151(5) 0.132(3) Uani 1 1 d D U . . .
H135 H 0.2012 0.0652 0.9195 0.158 Uiso 1 1 calc R U . . .
C136 C 0.2586(4) -0.0371(4) 0.6298(3) 0.044(2) Uani 1 1 d . . . . .
H136 H 0.2253 -0.0600 0.5968 0.053 Uiso 1 1 calc R U . . .
C137 C 0.8862(4) 0.3748(4) 0.6225(3) 0.047(2) Uani 1 1 d . . . . .
H13A H 0.9300 0.3736 0.6049 0.056 Uiso 1 1 calc R U . . .
H13B H 0.9001 0.3632 0.6595 0.056 Uiso 1 1 calc R U . . .
C138 C 0.9300(4) 0.4873(4) 0.6710(3) 0.056(2) Uani 1 1 d . . . . .
H13C H 0.9384 0.4684 0.7052 0.067 Uiso 1 1 calc R U . . .
H13D H 0.9798 0.4969 0.6599 0.067 Uiso 1 1 calc R U . . .
C139 C 0.9029(5) 0.5463(4) 0.6809(3) 0.057(2) Uani 1 1 d . . . . .
C140 C 0.8291(4) 0.5393(4) 0.6957(3) 0.046(2) Uani 1 1 d . . . . .
C141 C 0.7999(5) 0.5930(4) 0.7038(3) 0.051(2) Uani 1 1 d . . . . .
C142 C 0.8460(5) 0.6527(4) 0.7008(4) 0.063(3) Uani 1 1 d . . . . .
H142 H 0.8281 0.6896 0.7095 0.076 Uiso 1 1 calc R U . . .
C143 C 0.9128(6) 0.6586(4) 0.6864(4) 0.073(3) Uani 1 1 d . . . . .
C144 C 0.9420(6) 0.6049(5) 0.6775(4) 0.078(3) Uani 1 1 d . . . . .
H144 H 0.9912 0.6095 0.6688 0.093 Uiso 1 1 calc R U . . .
C145 C 0.8558(4) 0.4662(4) 0.5721(3) 0.0456(19) Uani 1 1 d . . . . .
H14A H 0.8330 0.5034 0.5769 0.055 Uiso 1 1 calc R U . . .
H14B H 0.8169 0.4337 0.5450 0.055 Uiso 1 1 calc R U . . .
C146 C 0.9268(5) 0.4851(4) 0.5485(4) 0.056(2) Uani 1 1 d . . . . .
H14C H 0.9143 0.5124 0.5205 0.067 Uiso 1 1 calc R U . . .
H14D H 0.9691 0.5109 0.5782 0.067 Uiso 1 1 calc R U . . .
C147 C 0.9563(6) 0.4342(5) 0.5237(5) 0.078(3) Uani 1 1 d . U . . .
C148 C 0.9156(9) 0.4008(5) 0.4730(7) 0.136(4) Uani 1 1 d D U . . .
H148 H 0.8690 0.4100 0.4542 0.163 Uiso 1 1 calc R U . . .
C149 C 0.9473(9) 0.3519(6) 0.4506(7) 0.141(4) Uani 1 1 d D U . . .
H149 H 0.9222 0.3283 0.4158 0.169 Uiso 1 1 calc R U . . .
C150 C 1.0148(10) 0.3392(6) 0.4798(7) 0.140(4) Uani 1 1 d . U . . .
H150 H 1.0323 0.3046 0.4648 0.168 Uiso 1 1 calc R U . . .
C151 C 1.0588(9) 0.3732(6) 0.5294(8) 0.142(4) Uani 1 1 d D U . . .
H151 H 1.1067 0.3652 0.5473 0.171 Uiso 1 1 calc R U . . .
C152 C 1.0264(8) 0.4203(5) 0.5508(6) 0.113(5) Uani 1 1 d D U . . .
H152 H 1.0527 0.4442 0.5853 0.135 Uiso 1 1 calc R U . . .
C153 C 0.7259(5) 0.5894(4) 0.7138(3) 0.051(2) Uani 1 1 d . . . . .
H153 H 0.7134 0.6283 0.7243 0.061 Uiso 1 1 calc R U . . .
Cl1 Cl -0.06887(16) 0.0868(2) 0.61722(16) 0.1441(17) Uani 1 1 d . . . . .
Cl2 Cl 0.49734(14) 0.11584(14) 0.42127(8) 0.0719(7) Uani 1 1 d . . . . .
Cl3 Cl 0.70358(15) 0.37941(13) 1.01604(10) 0.0768(8) Uani 1 1 d . . . . .
Cl4 Cl 1.27804(13) 0.21201(17) 0.91088(14) 0.1081(12) Uani 1 1 d . . . . .
Cl5 Cl 0.9019(2) -0.13775(13) 0.96076(16) 0.148(2) Uani 1 1 d . . . . .
Cl6 Cl 0.68194(14) 0.02650(11) 0.49936(8) 0.0615(6) Uani 1 1 d . . . . .
Cl7 Cl 0.50445(13) 0.43915(11) 0.94146(7) 0.0530(5) Uani 1 1 d . . . . .
Cl8 Cl 0.4819(2) 0.65181(15) 0.50231(11) 0.0969(10) Uani 1 1 d . . . . .
Cl9 Cl 0.75393(16) 0.19300(12) 0.45902(11) 0.0791(8) Uani 1 1 d . . . . .
Cl10 Cl 0.18268(16) -0.24026(11) 0.71005(11) 0.0786(8) Uani 1 1 d . . . . .
Cl11 Cl 0.49066(14) 0.27205(11) 1.00164(7) 0.0584(6) Uani 1 1 d . . . . .
Cl12 Cl 0.9666(2) 0.73188(13) 0.68017(16) 0.1231(14) Uani 1 1 d . . . . .
Cl13 Cl 0.4721(12) 0.1060(11) 0.2395(12) 0.91(2) Uani 1 1 d . . . . .
Cl14 Cl 0.0054(3) 0.4036(3) 0.7751(3) 0.191(2) Uani 1 1 d . . . . .
Cl15 Cl 0.2181(10) 0.3335(8) 0.4620(9) 0.600(13) Uani 1 1 d . . . . .
N1 N 0.2513(3) 0.1577(3) 0.5564(2) 0.0411(16) Uani 1 1 d . . . . .
N2 N 0.4927(3) 0.0834(2) 0.6687(2) 0.0239(12) Uani 1 1 d . . . . .
N3 N 0.6965(3) 0.1540(2) 0.8349(2) 0.0259(12) Uani 1 1 d . . . . .
N4 N 0.9717(3) 0.3035(3) 0.9203(2) 0.0373(15) Uani 1 1 d . . . . .
N5 N 0.7651(3) -0.0383(3) 0.7433(2) 0.0350(14) Uani 1 1 d . . . . .
N6 N 0.8087(3) 0.2040(2) 0.7284(2) 0.0270(12) Uani 1 1 d . . . . .
N7 N 0.7084(3) 0.3906(2) 0.7705(2) 0.0264(12) Uani 1 1 d . . . . .
N8 N 0.4790(3) 0.5015(3) 0.7004(2) 0.0368(14) Uani 1 1 d . . . . .
N9 N 0.5863(3) 0.3188(2) 0.6243(2) 0.0277(12) Uani 1 1 d . . . . .
N10 N 0.4293(3) 0.2266(3) 0.7427(2) 0.0279(12) Uani 1 1 d . . . . .
N11 N 0.3862(3) 0.0195(3) 0.8379(2) 0.0313(13) Uani 1 1 d . . . . .
N12 N 0.8704(3) 0.4410(3) 0.6264(2) 0.0411(15) Uani 1 1 d . . . . .
O1 O 0.2703(3) 0.1534(2) 0.66670(18) 0.0392(12) Uani 1 1 d . . . . .
O2 O 0.3841(2) 0.1449(2) 0.62009(16) 0.0318(11) Uani 1 1 d . . . . .
H2A H 0.3292 0.1431 0.6033 0.048 Uiso 1 1 d R U . . .
O3 O 0.8323(2) 0.24364(19) 0.85980(17) 0.0265(10) Uani 1 1 d . . . . .
O4 O 0.9528(2) 0.2143(2) 0.83120(19) 0.0326(11) Uani 1 1 d . . . . .
H4A H 0.9472 0.2519 0.8539 0.049 Uiso 1 1 d R U . . .
O5 O 0.7883(2) 0.0481(2) 0.83445(17) 0.0276(10) Uani 1 1 d . . . . .
H5A H 0.7648 0.0235 0.7977 0.041 Uiso 1 1 d R U . . .
O6 O 0.7609(2) 0.0794(2) 0.73770(17) 0.0300(11) Uani 1 1 d . . . . .
O7 O 0.5721(2) 0.4210(2) 0.72485(17) 0.0290(10) Uani 1 1 d . . . . .
H7A H 0.5424 0.4506 0.7085 0.044 Uiso 1 1 d R U . . .
O8 O 0.5567(3) 0.4544(2) 0.62829(18) 0.0344(11) Uani 1 1 d . . . . .
H8C H 0.5308 0.4160 0.6018 0.052 Uiso 1 1 d R U . . .
O9 O 0.7444(2) 0.3672(2) 0.64692(17) 0.0303(10) Uani 1 1 d . . . . .
O10 O 0.3764(2) 0.0105(2) 0.72738(17) 0.0303(10) Uani 1 1 d . . . . .
O11 O 0.4384(2) 0.1183(2) 0.78895(17) 0.0284(10) Uani 1 1 d . . . . .
H11H H 0.4202 0.0759 0.7982 0.043 Uiso 1 1 d R U . . .
O12 O 0.7931(3) 0.4833(2) 0.70058(19) 0.0386(12) Uani 1 1 d . . . . .
O13 O 0.2641(3) 0.0800(3) 0.7476(2) 0.0486(14) Uani 1 1 d . . . . .
O14 O 0.8923(3) 0.1378(2) 0.91090(18) 0.0338(11) Uani 1 1 d . . . . .
O15 O 0.9298(3) 0.0892(2) 0.79656(19) 0.0358(11) Uani 1 1 d . . . . .
O16 O 0.6901(3) 0.4699(3) 0.5921(2) 0.0448(13) Uani 1 1 d . . . . .
O17 O 0.2846(3) 0.0207(3) 0.62967(19) 0.0398(12) Uani 1 1 d . . . . .
O18 O 0.6752(3) 0.5413(2) 0.7104(2) 0.0505(14) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Eu1 O2 140.83(16) . . ?
O11 Eu1 O10 68.87(15) . . ?
O2 Eu1 O10 131.47(15) . . ?
O11 Eu1 O1 126.91(15) . . ?
O2 Eu1 O1 68.98(16) . . ?
O10 Eu1 O1 131.92(17) . . ?
O11 Eu1 O13 78.30(16) . . ?
O2 Eu1 O13 135.42(16) . . ?
O10 Eu1 O13 72.58(17) . . ?
O1 Eu1 O13 68.62(18) . . ?
O11 Eu1 O17 136.58(17) . . ?
O2 Eu1 O17 77.68(17) . . ?
O10 Eu1 O17 68.75(16) . . ?
O1 Eu1 O17 77.77(16) . . ?
O13 Eu1 O17 80.58(17) . . ?
O11 Eu1 N2 89.44(15) . . ?
O2 Eu1 N2 68.21(15) . . ?
O10 Eu1 N2 78.04(16) . . ?
O1 Eu1 N2 137.11(17) . . ?
O13 Eu1 N2 150.55(18) . . ?
O17 Eu1 N2 90.79(15) . . ?
O11 Eu1 N10 68.11(16) . . ?
O2 Eu1 N10 83.54(17) . . ?
O10 Eu1 N10 136.89(15) . . ?
O1 Eu1 N10 78.66(16) . . ?
O13 Eu1 N10 101.03(17) . . ?
O17 Eu1 N10 153.90(16) . . ?
N2 Eu1 N10 98.95(16) . . ?
O11 Eu1 H2A 156.9 . . ?
O2 Eu1 H2A 21.6 . . ?
O10 Eu1 H2A 132.4 . . ?
O1 Eu1 H2A 50.0 . . ?
O13 Eu1 H2A 114.0 . . ?
O17 Eu1 H2A 66.4 . . ?
N2 Eu1 H2A 87.4 . . ?
N10 Eu1 H2A 89.8 . . ?
O11 Eu1 H11H 21.4 . . ?
O2 Eu1 H11H 156.9 . . ?
O10 Eu1 H11H 48.9 . . ?
O1 Eu1 H11H 130.7 . . ?
O13 Eu1 H11H 67.5 . . ?
O17 Eu1 H11H 115.3 . . ?
N2 Eu1 H11H 91.7 . . ?
N10 Eu1 H11H 88.7 . . ?
H2A Eu1 H11H 178.1 . . ?
O7 Eu2 O8 68.87(15) . . ?
O7 Eu2 O9 139.70(16) . . ?
O8 Eu2 O9 130.09(15) . . ?
O7 Eu2 O12 129.87(16) . . ?
O8 Eu2 O12 130.16(18) . . ?
O9 Eu2 O12 69.88(16) . . ?
O7 Eu2 O16 137.41(16) . . ?
O8 Eu2 O16 69.25(17) . . ?
O9 Eu2 O16 76.53(16) . . ?
O12 Eu2 O16 75.06(17) . . ?
O7 Eu2 O18 77.99(17) . . ?
O8 Eu2 O18 73.43(17) . . ?
O9 Eu2 O18 137.29(17) . . ?
O12 Eu2 O18 68.73(17) . . ?
O16 Eu2 O18 83.16(18) . . ?
O7 Eu2 N9 85.04(16) . . ?
O8 Eu2 N9 78.62(16) . . ?
O9 Eu2 N9 68.58(16) . . ?
O12 Eu2 N9 138.45(16) . . ?
O16 Eu2 N9 94.11(17) . . ?
O18 Eu2 N9 151.03(17) . . ?
O7 Eu2 N7 67.89(15) . . ?
O8 Eu2 N7 136.75(16) . . ?
O9 Eu2 N7 85.12(15) . . ?
O12 Eu2 N7 80.65(17) . . ?
O16 Eu2 N7 153.39(17) . . ?
O18 Eu2 N7 98.12(17) . . ?
N9 Eu2 N7 96.96(16) . . ?
O7 Eu2 H7A 21.6 . . ?
O8 Eu2 H7A 49.6 . . ?
O9 Eu2 H7A 156.9 . . ?
O12 Eu2 H7A 130.5 . . ?
O16 Eu2 H7A 116.3 . . ?
O18 Eu2 H7A 65.5 . . ?
N9 Eu2 H7A 90.5 . . ?
N7 Eu2 H7A 87.8 . . ?
O7 Eu2 H8C 74.3 . . ?
O8 Eu2 H8C 20.8 . . ?
O9 Eu2 H8C 112.6 . . ?
O12 Eu2 H8C 142.2 . . ?
O16 Eu2 H8C 69.4 . . ?
O18 Eu2 H8C 94.2 . . ?
N9 Eu2 H8C 58.4 . . ?
N7 Eu2 H8C 136.5 . . ?
H7A Eu2 H8C 60.0 . . ?
O3 Eu3 O6 140.32(14) . . ?
O3 Eu3 O5 130.13(16) . . ?
O6 Eu3 O5 68.02(15) . . ?
O3 Eu3 O4 69.03(14) . . ?
O6 Eu3 O4 129.84(16) . . ?
O5 Eu3 O4 131.92(15) . . ?
O3 Eu3 O15 135.41(15) . . ?
O6 Eu3 O15 79.38(15) . . ?
O5 Eu3 O15 74.70(15) . . ?
O4 Eu3 O15 68.05(15) . . ?
O3 Eu3 O14 78.51(15) . . ?
O6 Eu3 O14 135.36(15) . . ?
O5 Eu3 O14 68.53(15) . . ?
O4 Eu3 O14 75.83(16) . . ?
O15 Eu3 O14 79.93(15) . . ?
O3 Eu3 N6 84.09(16) . . ?
O6 Eu3 N6 67.90(16) . . ?
O5 Eu3 N6 135.70(15) . . ?
O4 Eu3 N6 81.93(16) . . ?
O15 Eu3 N6 101.27(15) . . ?
O14 Eu3 N6 155.50(16) . . ?
O3 Eu3 N3 68.25(15) . . ?
O6 Eu3 N3 85.92(16) . . ?
O5 Eu3 N3 78.21(15) . . ?
O4 Eu3 N3 137.27(15) . . ?
O15 Eu3 N3 152.43(16) . . ?
O14 Eu3 N3 94.92(15) . . ?
N6 Eu3 N3 94.49(16) . . ?
O3 Eu3 H4A 48.4 . . ?
O6 Eu3 H4A 145.0 . . ?
O5 Eu3 H4A 139.3 . . ?
O4 Eu3 H4A 20.7 . . ?
O15 Eu3 H4A 87.9 . . ?
O14 Eu3 H4A 72.4 . . ?
N6 Eu3 H4A 83.2 . . ?
N3 Eu3 H4A 116.6 . . ?
O3 Eu3 H5A 145.3 . . ?
O6 Eu3 H5A 47.2 . . ?
O5 Eu3 H5A 20.9 . . ?
O4 Eu3 H5A 138.8 . . ?
O15 Eu3 H5A 71.8 . . ?
O14 Eu3 H5A 88.7 . . ?
N6 Eu3 H5A 115.1 . . ?
N3 Eu3 H5A 81.1 . . ?
H4A Eu3 H5A 154.6 . . ?
O1 C1 C6 117.2(9) . . ?
O1 C1 C2 123.6(7) . . ?
C6 C1 C2 119.2(8) . . ?
C7 C2 C1 121.0(7) . . ?
C7 C2 C3 117.0(9) . . ?
C1 C2 C3 121.9(8) . . ?
C4 C3 C2 118.0(10) . . ?
C4 C3 H3 121.0 . . ?
C2 C3 H3 121.0 . . ?
C5 C4 C3 121.1(9) . . ?
C5 C4 Cl1 119.7(9) . . ?
C3 C4 Cl1 119.1(9) . . ?
C4 C5 C6 122.3(10) . . ?
C4 C5 H5 118.9 . . ?
C6 C5 H5 118.9 . . ?
C1 C6 C5 117.5(10) . . ?
C1 C6 C8 118.2(8) . . ?
C5 C6 C8 124.4(8) . . ?
O13 C7 C2 127.0(9) . . ?
O13 C7 H7 116.5 . . ?
C2 C7 H7 116.5 . . ?
N1 C8 C6 108.7(7) . . ?
N1 C8 H8A 109.9 . . ?
C6 C8 H8A 109.9 . . ?
N1 C8 H8B 109.9 . . ?
C6 C8 H8B 109.9 . . ?
H8A C8 H8B 108.3 . . ?
N1 C9 C10 110.9(6) . . ?
N1 C9 H9A 109.5 . . ?
C10 C9 H9A 109.5 . . ?
N1 C9 H9B 109.5 . . ?
C10 C9 H9B 109.5 . . ?
H9A C9 H9B 108.1 . . ?
C15 C10 C11 120.0(6) . . ?
C15 C10 C9 122.1(6) . . ?
C11 C10 C9 117.8(6) . . ?
O2 C11 C12 122.3(6) . . ?
O2 C11 C10 118.5(6) . . ?
C12 C11 C10 119.2(6) . . ?
C11 C12 C13 119.0(6) . . ?
C11 C12 C24 122.3(6) . . ?
C13 C12 C24 118.7(6) . . ?
C14 C13 C12 120.7(7) . . ?
C14 C13 H13 119.6 . . ?
C12 C13 H13 119.6 . . ?
C13 C14 C15 121.4(7) . . ?
C13 C14 Cl2 119.8(7) . . ?
C15 C14 Cl2 118.8(6) . . ?
C10 C15 C14 119.7(7) . . ?
C10 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
N1 C16 C17 117.0(7) . . ?
N1 C16 H16A 108.0 . . ?
C17 C16 H16A 108.0 . . ?
N1 C16 H16B 108.0 . . ?
C17 C16 H16B 108.0 . . ?
H16A C16 H16B 107.3 . . ?
C18 C17 C16 115.0(10) . . ?
C18 C17 H17A 108.5 . . ?
C16 C17 H17A 108.5 . . ?
C18 C17 H17B 108.5 . . ?
C16 C17 H17B 108.5 . . ?
H17A C17 H17B 107.5 . . ?
C23 C18 C19 114.2(14) . . ?
C23 C18 C17 120.5(10) . . ?
C19 C18 C17 125.1(14) . . ?
C18 C19 C20 123.2(15) . . ?
C18 C19 H19 118.4 . . ?
C20 C19 H19 118.4 . . ?
C19 C20 C21 116.2(13) . . ?
C19 C20 H20 121.9 . . ?
C21 C20 H20 121.9 . . ?
C22 C21 C20 123.6(17) . . ?
C22 C21 H21 118.2 . . ?
C20 C21 H21 118.2 . . ?
C21 C22 C23 112.7(15) . . ?
C21 C22 H22 123.6 . . ?
C23 C22 H22 123.6 . . ?
C18 C23 C22 128.1(13) . . ?
C18 C23 H23 115.9 . . ?
C22 C23 H23 115.9 . . ?
N2 C24 C12 126.4(6) . . ?
N2 C24 H24 116.8 . . ?
C12 C24 H24 116.8 . . ?
N2 C25 C26 109.4(5) . . ?
N2 C25 H25A 109.8 . . ?
C26 C25 H25A 109.8 . . ?
N2 C25 H25B 109.8 . . ?
C26 C25 H25B 109.8 . . ?
H25A C25 H25B 108.2 . . ?
C27 C26 C25 111.6(5) . . ?
C27 C26 H26A 109.3 . . ?
C25 C26 H26A 109.3 . . ?
C27 C26 H26B 109.3 . . ?
C25 C26 H26B 109.3 . . ?
H26A C26 H26B 108.0 . . ?
N3 C27 C26 109.6(5) . . ?
N3 C27 H27A 109.7 . . ?
C26 C27 H27A 109.7 . . ?
N3 C27 H27B 109.7 . . ?
C26 C27 H27B 109.7 . . ?
H27A C27 H27B 108.2 . . ?
N3 C28 C29 126.5(6) . . ?
N3 C28 H28 116.7 . . ?
C29 C28 H28 116.7 . . ?
C34 C29 C30 119.8(6) . . ?
C34 C29 C28 118.0(6) . . ?
C30 C29 C28 122.1(5) . . ?
O3 C30 C29 122.2(6) . . ?
O3 C30 C31 119.1(6) . . ?
C29 C30 C31 118.7(6) . . ?
C32 C31 C30 120.5(7) . . ?
C32 C31 C35 122.3(6) . . ?
C30 C31 C35 117.2(6) . . ?
C31 C32 C33 120.2(7) . . ?
C31 C32 H32 119.9 . . ?
C33 C32 H32 119.9 . . ?
C34 C33 C32 120.7(6) . . ?
C34 C33 Cl3 119.8(6) . . ?
C32 C33 Cl3 119.5(6) . . ?
C33 C34 C29 119.9(7) . . ?
C33 C34 H34 120.0 . . ?
C29 C34 H34 120.0 . . ?
C31 C35 N4 111.8(6) . . ?
C31 C35 H35A 109.3 . . ?
N4 C35 H35A 109.3 . . ?
C31 C35 H35B 109.3 . . ?
N4 C35 H35B 109.3 . . ?
H35A C35 H35B 107.9 . . ?
N4 C36 C37 110.2(7) . . ?
N4 C36 H36A 109.6 . . ?
C37 C36 H36A 109.6 . . ?
N4 C36 H36B 109.6 . . ?
C37 C36 H36B 109.6 . . ?
H36A C36 H36B 108.1 . . ?
C42 C37 C38 122.0(7) . . ?
C42 C37 C36 120.7(7) . . ?
C38 C37 C36 117.2(6) . . ?
O4 C38 C39 122.3(6) . . ?
O4 C38 C37 119.9(6) . . ?
C39 C38 C37 117.8(6) . . ?
C38 C39 C40 120.6(7) . . ?
C38 C39 C51 121.3(6) . . ?
C40 C39 C51 118.1(6) . . ?
C41 C40 C39 118.9(7) . . ?
C41 C40 H40 120.6 . . ?
C39 C40 H40 120.6 . . ?
C40 C41 C42 122.1(7) . . ?
C40 C41 Cl4 120.0(7) . . ?
C42 C41 Cl4 117.9(7) . . ?
C37 C42 C41 118.4(7) . . ?
C37 C42 H42 120.8 . . ?
C41 C42 H42 120.8 . . ?
N4 C43 C44 112.5(10) . . ?
N4 C43 H43A 109.1 . . ?
C44 C43 H43A 109.1 . . ?
N4 C43 H43B 109.1 . . ?
C44 C43 H43B 109.1 . . ?
H43A C43 H43B 107.8 . . ?
C45 C44 C43 107.9(11) . . ?
C45 C44 H44A 110.1 . . ?
C43 C44 H44A 110.1 . . ?
C45 C44 H44B 110.1 . . ?
C43 C44 H44B 110.1 . . ?
H44A C44 H44B 108.4 . . ?
C46 C45 C50 121.6(18) . . ?
C46 C45 C44 118.6(19) . . ?
C50 C45 C44 119.7(14) . . ?
C45 C46 C47 121(2) . . ?
C45 C46 H46 119.5 . . ?
C47 C46 H46 119.5 . . ?
C48 C47 C46 110.1(16) . . ?
C48 C47 H47 125.0 . . ?
C46 C47 H47 125.0 . . ?
C49 C48 C47 133(2) . . ?
C49 C48 H48 113.3 . . ?
C47 C48 H48 113.3 . . ?
C48 C49 C50 115(2) . . ?
C48 C49 H49 122.5 . . ?
C50 C49 H49 122.5 . . ?
C49 C50 C45 117.5(17) . . ?
C49 C50 H50 121.2 . . ?
C45 C50 H50 121.2 . . ?
O15 C51 C39 126.5(6) . . ?
O15 C51 H51 116.7 . . ?
C39 C51 H51 116.7 . . ?
O14 C52 C53 127.9(6) . . ?
O14 C52 H52 116.1 . . ?
C53 C52 H52 116.1 . . ?
C58 C53 C54 119.1(6) . . ?
C58 C53 C52 119.7(6) . . ?
C54 C53 C52 121.2(6) . . ?
O5 C54 C55 120.0(6) . . ?
O5 C54 C53 120.8(6) . . ?
C55 C54 C53 119.1(6) . . ?
C56 C55 C54 119.4(7) . . ?
C56 C55 C59 121.8(6) . . ?
C54 C55 C59 118.8(6) . . ?
C55 C56 C57 120.4(8) . . ?
C55 C56 H56 119.8 . . ?
C57 C56 H56 119.8 . . ?
C58 C57 C56 120.9(8) . . ?
C58 C57 Cl5 120.1(7) . . ?
C56 C57 Cl5 119.0(7) . . ?
C57 C58 C53 120.7(7) . . ?
C57 C58 H58 119.7 . . ?
C53 C58 H58 119.7 . . ?
C55 C59 N5 111.4(6) . . ?
C55 C59 H59A 109.3 . . ?
N5 C59 H59A 109.3 . . ?
C55 C59 H59B 109.3 . . ?
N5 C59 H59B 109.3 . . ?
H59A C59 H59B 108.0 . . ?
N5 C60 C61 111.1(5) . . ?
N5 C60 H60A 109.4 . . ?
C61 C60 H60A 109.4 . . ?
N5 C60 H60B 109.4 . . ?
C61 C60 H60B 109.4 . . ?
H60A C60 H60B 108.0 . . ?
C66 C61 C62 120.6(7) . . ?
C66 C61 C60 119.6(6) . . ?
C62 C61 C60 119.7(6) . . ?
O6 C62 C63 121.5(6) . . ?
O6 C62 C61 120.0(6) . . ?
C63 C62 C61 118.5(6) . . ?
C64 C63 C62 120.9(6) . . ?
C64 C63 C75 116.9(7) . . ?
C62 C63 C75 122.1(6) . . ?
C65 C64 C63 117.9(7) . . ?
C65 C64 H64 121.1 . . ?
C63 C64 H64 121.1 . . ?
C66 C65 C64 122.5(7) . . ?
C66 C65 Cl6 119.4(5) . . ?
C64 C65 Cl6 118.0(6) . . ?
C61 C66 C65 119.5(6) . . ?
C61 C66 H66 120.2 . . ?
C65 C66 H66 120.2 . . ?
N5 C67 C68 118.4(6) . . ?
N5 C67 H67A 107.7 . . ?
C68 C67 H67A 107.7 . . ?
N5 C67 H67B 107.7 . . ?
C68 C67 H67B 107.7 . . ?
H67A C67 H67B 107.1 . . ?
C69 C68 C67 108.1(7) . . ?
C69 C68 H68A 110.1 . . ?
C67 C68 H68A 110.1 . . ?
C69 C68 H68B 110.1 . . ?
C67 C68 H68B 110.1 . . ?
H68A C68 H68B 108.4 . . ?
C70 C69 C74 114.3(11) . . ?
C70 C69 C68 119.2(9) . . ?
C74 C69 C68 126.1(9) . . ?
C69 C70 C71 131.8(14) . . ?
C69 C70 H70 114.1 . . ?
C71 C70 H70 114.1 . . ?
C70 C71 C72 107.8(15) . . ?
C70 C71 H71 126.1 . . ?
C72 C71 H71 126.1 . . ?
C71 C72 C73 129.0(15) . . ?
C71 C72 H72 115.5 . . ?
C73 C72 H72 115.5 . . ?
C72 C73 C74 113.9(12) . . ?
C72 C73 H73 123.0 . . ?
C74 C73 H73 123.0 . . ?
C69 C74 C73 122.3(11) . . ?
C69 C74 H74 118.8 . . ?
C73 C74 H74 118.8 . . ?
N6 C75 C63 126.9(7) . . ?
N6 C75 H75 116.6 . . ?
C63 C75 H75 116.6 . . ?
N6 C76 C77 109.6(5) . . ?
N6 C76 H76A 109.7 . . ?
C77 C76 H76A 109.7 . . ?
N6 C76 H76B 109.7 . . ?
C77 C76 H76B 109.7 . . ?
H76A C76 H76B 108.2 . . ?
C78 C77 C76 112.0(5) . . ?
C78 C77 H77A 109.2 . . ?
C76 C77 H77A 109.2 . . ?
C78 C77 H77B 109.2 . . ?
C76 C77 H77B 109.2 . . ?
H77A C77 H77B 107.9 . . ?
N7 C78 C77 109.9(5) . . ?
N7 C78 H78A 109.7 . . ?
C77 C78 H78A 109.7 . . ?
N7 C78 H78B 109.7 . . ?
C77 C78 H78B 109.7 . . ?
H78A C78 H78B 108.2 . . ?
N7 C79 C80 126.2(6) . . ?
N7 C79 H79 116.9 . . ?
C80 C79 H79 116.9 . . ?
C85 C80 C81 120.0(6) . . ?
C85 C80 C79 118.7(6) . . ?
C81 C80 C79 121.3(6) . . ?
O7 C81 C80 122.6(6) . . ?
O7 C81 C82 119.4(6) . . ?
C80 C81 C82 118.1(6) . . ?
C83 C82 C81 120.3(6) . . ?
C83 C82 C86 122.4(6) . . ?
C81 C82 C86 117.3(5) . . ?
C84 C83 C82 119.7(6) . . ?
C84 C83 H83 120.1 . . ?
C82 C83 H83 120.1 . . ?
C83 C84 C85 121.8(6) . . ?
C83 C84 Cl7 119.1(5) . . ?
C85 C84 Cl7 119.1(5) . . ?
C80 C85 C84 120.0(6) . . ?
C80 C85 H85 120.0 . . ?
C84 C85 H85 120.0 . . ?
N8 C86 C82 111.0(6) . . ?
N8 C86 H86A 109.4 . . ?
C82 C86 H86A 109.4 . . ?
N8 C86 H86B 109.4 . . ?
C82 C86 H86B 109.4 . . ?
H86A C86 H86B 108.0 . . ?
C88 C87 N8 111.0(6) . . ?
C88 C87 H87A 109.4 . . ?
N8 C87 H87A 109.4 . . ?
C88 C87 H87B 109.4 . . ?
N8 C87 H87B 109.4 . . ?
H87A C87 H87B 108.0 . . ?
C93 C88 C89 119.9(8) . . ?
C93 C88 C87 123.9(7) . . ?
C89 C88 C87 116.1(6) . . ?
O8 C89 C90 123.7(7) . . ?
O8 C89 C88 118.4(7) . . ?
C90 C89 C88 117.8(7) . . ?
C91 C90 C102 120.4(7) . . ?
C91 C90 C89 119.7(7) . . ?
C102 C90 C89 119.8(7) . . ?
C92 C91 C90 120.9(8) . . ?
C92 C91 H91 119.6 . . ?
C90 C91 H91 119.6 . . ?
C91 C92 C93 120.6(7) . . ?
C91 C92 Cl8 121.3(7) . . ?
C93 C92 Cl8 118.1(7) . . ?
C88 C93 C92 120.9(8) . . ?
C88 C93 H93 119.5 . . ?
C92 C93 H93 119.5 . . ?
N8 C94 C95 116.7(7) . . ?
N8 C94 H94A 108.1 . . ?
C95 C94 H94A 108.1 . . ?
N8 C94 H94B 108.1 . . ?
C95 C94 H94B 108.1 . . ?
H94A C94 H94B 107.3 . . ?
C94 C95 C96 113.9(7) . . ?
C94 C95 H95A 108.8 . . ?
C96 C95 H95A 108.8 . . ?
C94 C95 H95B 108.8 . . ?
C96 C95 H95B 108.8 . . ?
H95A C95 H95B 107.7 . . ?
C97 C96 C101 119.0(10) . . ?
C97 C96 C95 119.8(10) . . ?
C101 C96 C95 121.3(9) . . ?
C96 C97 C98 122.9(12) . . ?
C96 C97 H97 118.6 . . ?
C98 C97 H97 118.6 . . ?
C99 C98 C97 119.0(12) . . ?
C99 C98 H98 120.5 . . ?
C97 C98 H98 120.5 . . ?
C100 C99 C98 121.0(12) . . ?
C100 C99 H99 119.5 . . ?
C98 C99 H99 119.5 . . ?
C99 C100 C101 120.3(12) . . ?
C99 C100 H100 119.9 . . ?
C101 C100 H100 119.9 . . ?
C96 C101 C100 117.7(11) . . ?
C96 C101 H101 121.1 . . ?
C100 C101 H101 121.1 . . ?
O16 C102 C90 127.7(7) . . ?
O16 C102 H102 116.1 . . ?
C90 C102 H102 116.1 . . ?
O9 C103 C108 118.8(6) . . ?
O9 C103 C104 121.9(6) . . ?
C108 C103 C104 119.3(6) . . ?
C105 C104 C103 120.2(6) . . ?
C105 C104 C109 117.0(6) . . ?
C103 C104 C109 122.8(6) . . ?
C106 C105 C104 119.1(7) . . ?
C106 C105 H105 120.5 . . ?
C104 C105 H105 120.5 . . ?
C105 C106 C107 122.1(7) . . ?
C105 C106 Cl9 118.9(7) . . ?
C107 C106 Cl9 119.0(6) . . ?
C108 C107 C106 118.3(7) . . ?
C108 C107 H107 120.8 . . ?
C106 C107 H107 120.8 . . ?
C107 C108 C103 121.1(7) . . ?
C107 C108 C137 120.6(7) . . ?
C103 C108 C137 118.3(6) . . ?
N9 C109 C104 126.6(6) . . ?
N9 C109 H109 116.7 . . ?
C104 C109 H109 116.7 . . ?
N9 C110 C111 108.9(5) . . ?
N9 C110 H11A 109.9 . . ?
C111 C110 H11A 109.9 . . ?
N9 C110 H11B 109.9 . . ?
C111 C110 H11B 109.9 . . ?
H11A C110 H11B 108.3 . . ?
C110 C111 C112 111.5(5) . . ?
C110 C111 H11C 109.3 . . ?
C112 C111 H11C 109.3 . . ?
C110 C111 H11D 109.3 . . ?
C112 C111 H11D 109.3 . . ?
H11C C111 H11D 108.0 . . ?
N10 C112 C111 108.9(5) . . ?
N10 C112 H11E 109.9 . . ?
C111 C112 H11E 109.9 . . ?
N10 C112 H11F 109.9 . . ?
C111 C112 H11F 109.9 . . ?
H11E C112 H11F 108.3 . . ?
N10 C113 C114 127.4(6) . . ?
N10 C113 H113 116.3 . . ?
C114 C113 H113 116.3 . . ?
C119 C114 C115 119.3(6) . . ?
C119 C114 C113 118.6(6) . . ?
C115 C114 C113 122.1(6) . . ?
O11 C115 C116 118.4(6) . . ?
O11 C115 C114 121.5(6) . . ?
C116 C115 C114 120.1(6) . . ?
C117 C116 C115 119.8(6) . . ?
C117 C116 C120 120.3(6) . . ?
C115 C116 C120 119.9(6) . . ?
C116 C117 C118 119.1(6) . . ?
C116 C117 H117 120.5 . . ?
C118 C117 H117 120.5 . . ?
C119 C118 C117 121.3(6) . . ?
C119 C118 Cl11 120.1(6) . . ?
C117 C118 Cl11 118.6(6) . . ?
C118 C119 C114 120.5(7) . . ?
C118 C119 H119 119.7 . . ?
C114 C119 H119 119.7 . . ?
C116 C120 N11 109.9(5) . . ?
C116 C120 H12A 109.7 . . ?
N11 C120 H12A 109.7 . . ?
C116 C120 H12B 109.7 . . ?
N11 C120 H12B 109.7 . . ?
H12A C120 H12B 108.2 . . ?
C122 C121 N11 111.6(5) . . ?
C122 C121 H12C 109.3 . . ?
N11 C121 H12C 109.3 . . ?
C122 C121 H12D 109.3 . . ?
N11 C121 H12D 109.3 . . ?
H12C C121 H12D 108.0 . . ?
C127 C122 C123 121.7(7) . . ?
C127 C122 C121 121.3(7) . . ?
C123 C122 C121 117.0(6) . . ?
O10 C123 C122 120.4(6) . . ?
O10 C123 C124 122.9(7) . . ?
C122 C123 C124 116.7(7) . . ?
C125 C124 C136 119.8(7) . . ?
C125 C124 C123 120.0(7) . . ?
C136 C124 C123 120.1(7) . . ?
C126 C125 C124 119.8(7) . . ?
C126 C125 H125 120.1 . . ?
C124 C125 H125 120.1 . . ?
C125 C126 C127 122.5(8) . . ?
C125 C126 Cl10 119.2(6) . . ?
C127 C126 Cl10 118.3(7) . . ?
C122 C127 C126 119.1(8) . . ?
C122 C127 H127 120.4 . . ?
C126 C127 H127 120.4 . . ?
N11 C128 C129 114.0(6) . . ?
N11 C128 H12E 108.7 . . ?
C129 C128 H12E 108.7 . . ?
N11 C128 H12F 108.7 . . ?
C129 C128 H12F 108.7 . . ?
H12E C128 H12F 107.6 . . ?
C130 C129 C128 108.9(8) . . ?
C130 C129 H12G 109.9 . . ?
C128 C129 H12G 109.9 . . ?
C130 C129 H12H 109.9 . . ?
C128 C129 H12H 109.9 . . ?
H12G C129 H12H 108.3 . . ?
C135 C130 C131 109.8(14) . . ?
C135 C130 C129 130.6(13) . . ?
C131 C130 C129 119.6(11) . . ?
C132 C131 C130 124.9(15) . . ?
C132 C131 H131 117.6 . . ?
C130 C131 H131 117.6 . . ?
C133 C132 C131 115.1(15) . . ?
C133 C132 H132 122.4 . . ?
C131 C132 H132 122.4 . . ?
C134 C133 C132 124.8(14) . . ?
C134 C133 H133 117.6 . . ?
C132 C133 H133 117.6 . . ?
C135 C134 C133 111.7(14) . . ?
C135 C134 H134 124.2 . . ?
C133 C134 H134 124.2 . . ?
C130 C135 C134 133.6(15) . . ?
C130 C135 H135 113.2 . . ?
C134 C135 H135 113.2 . . ?
O17 C136 C124 127.1(6) . . ?
O17 C136 H136 116.5 . . ?
C124 C136 H136 116.5 . . ?
C108 C137 N12 108.9(6) . . ?
C108 C137 H13A 109.9 . . ?
N12 C137 H13A 109.9 . . ?
C108 C137 H13B 109.9 . . ?
N12 C137 H13B 109.9 . . ?
H13A C137 H13B 108.3 . . ?
C139 C138 N12 110.0(6) . . ?
C139 C138 H13C 109.7 . . ?
N12 C138 H13C 109.7 . . ?
C139 C138 H13D 109.7 . . ?
N12 C138 H13D 109.7 . . ?
H13C C138 H13D 108.2 . . ?
C144 C139 C140 118.9(9) . . ?
C144 C139 C138 125.2(9) . . ?
C140 C139 C138 115.9(8) . . ?
O12 C140 C141 123.3(7) . . ?
O12 C140 C139 118.5(7) . . ?
C141 C140 C139 118.2(8) . . ?
C140 C141 C153 121.6(8) . . ?
C140 C141 C142 118.9(8) . . ?
C153 C141 C142 119.5(8) . . ?
C143 C142 C141 122.3(9) . . ?
C143 C142 H142 118.8 . . ?
C141 C142 H142 118.8 . . ?
C142 C143 C144 119.0(9) . . ?
C142 C143 Cl12 121.7(8) . . ?
C144 C143 Cl12 119.3(8) . . ?
C139 C144 C143 122.5(9) . . ?
C139 C144 H144 118.8 . . ?
C143 C144 H144 118.8 . . ?
N12 C145 C146 115.6(7) . . ?
N12 C145 H14A 108.4 . . ?
C146 C145 H14A 108.4 . . ?
N12 C145 H14B 108.4 . . ?
C146 C145 H14B 108.4 . . ?
H14A C145 H14B 107.4 . . ?
C147 C146 C145 117.3(7) . . ?
C147 C146 H14C 108.0 . . ?
C145 C146 H14C 108.0 . . ?
C147 C146 H14D 108.0 . . ?
C145 C146 H14D 108.0 . . ?
H14C C146 H14D 107.2 . . ?
C148 C147 C152 120.7(10) . . ?
C148 C147 C146 119.3(11) . . ?
C152 C147 C146 120.0(11) . . ?
C147 C148 C149 116.9(15) . . ?
C147 C148 H148 121.6 . . ?
C149 C148 H148 121.6 . . ?
C150 C149 C148 119.9(17) . . ?
C150 C149 H149 120.1 . . ?
C148 C149 H149 120.1 . . ?
C149 C150 C151 124.8(14) . . ?
C149 C150 H150 117.6 . . ?
C151 C150 H150 117.6 . . ?
C150 C151 C152 114.2(17) . . ?
C150 C151 H151 122.9 . . ?
C152 C151 H151 122.9 . . ?
C151 C152 C147 123.4(16) . . ?
C151 C152 H152 118.3 . . ?
C147 C152 H152 118.3 . . ?
O18 C153 C141 127.3(7) . . ?
O18 C153 H153 116.3 . . ?
C141 C153 H153 116.3 . . ?
C16 N1 C8 115.3(6) . . ?
C16 N1 C9 113.6(6) . . ?
C8 N1 C9 112.9(6) . . ?
C24 N2 C25 116.8(5) . . ?
C24 N2 Eu1 131.1(4) . . ?
C25 N2 Eu1 111.9(4) . . ?
C28 N3 C27 116.6(5) . . ?
C28 N3 Eu3 131.5(4) . . ?
C27 N3 Eu3 111.9(4) . . ?
C43 N4 C35 113.2(6) . . ?
C43 N4 C36 114.7(7) . . ?
C35 N4 C36 111.9(6) . . ?
C67 N5 C59 112.9(5) . . ?
C67 N5 C60 114.2(6) . . ?
C59 N5 C60 113.0(5) . . ?
C75 N6 C76 115.5(6) . . ?
C75 N6 Eu3 132.1(5) . . ?
C76 N6 Eu3 112.3(4) . . ?
C79 N7 C78 115.3(6) . . ?
C79 N7 Eu2 131.9(4) . . ?
C78 N7 Eu2 112.7(4) . . ?
C94 N8 C86 115.9(6) . . ?
C94 N8 C87 114.6(6) . . ?
C86 N8 C87 110.4(6) . . ?
C109 N9 C110 117.3(5) . . ?
C109 N9 Eu2 129.7(5) . . ?
C110 N9 Eu2 112.5(4) . . ?
C113 N10 C112 116.4(6) . . ?
C113 N10 Eu1 129.7(5) . . ?
C112 N10 Eu1 113.8(4) . . ?
C128 N11 C120 113.8(5) . . ?
C128 N11 C121 113.0(6) . . ?
C120 N11 C121 111.6(5) . . ?
C138 N12 C145 112.8(6) . . ?
C138 N12 C137 112.7(6) . . ?
C145 N12 C137 114.4(6) . . ?
C1 O1 Eu1 136.9(6) . . ?
C11 O2 Eu1 145.1(4) . . ?
C11 O2 H2A 100.3 . . ?
Eu1 O2 H2A 100.4 . . ?
C30 O3 Eu3 144.2(4) . . ?
C38 O4 Eu3 137.0(5) . . ?
C38 O4 H4A 102.7 . . ?
Eu3 O4 H4A 102.6 . . ?
C54 O5 Eu3 137.8(4) . . ?
C54 O5 H5A 102.4 . . ?
Eu3 O5 H5A 102.5 . . ?
C62 O6 Eu3 145.8(4) . . ?
C81 O7 Eu2 144.3(4) . . ?
C81 O7 H7A 100.6 . . ?
Eu2 O7 H7A 100.6 . . ?
C89 O8 Eu2 134.9(5) . . ?
C89 O8 H8C 103.3 . . ?
Eu2 O8 H8C 103.3 . . ?
C103 O9 Eu2 140.3(4) . . ?
C123 O10 Eu1 138.8(4) . . ?
C115 O11 Eu1 141.1(4) . . ?
C115 O11 H11H 101.5 . . ?
Eu1 O11 H11H 101.5 . . ?
C140 O12 Eu2 135.0(5) . . ?
C7 O13 Eu1 133.5(6) . . ?
C52 O14 Eu3 132.8(4) . . ?
C51 O15 Eu3 134.4(4) . . ?
C102 O16 Eu2 133.0(5) . . ?
C136 O17 Eu1 133.9(5) . . ?
C153 O18 Eu2 132.4(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O11 2.282(4) . ?
Eu1 O2 2.284(4) . ?
Eu1 O10 2.318(5) . ?
Eu1 O1 2.318(4) . ?
Eu1 O13 2.515(5) . ?
Eu1 O17 2.517(5) . ?
Eu1 N2 2.599(5) . ?
Eu1 N10 2.626(5) . ?
Eu1 H2A 2.6478 . ?
Eu1 H11H 2.6632 . ?
Eu2 O7 2.277(4) . ?
Eu2 O8 2.307(4) . ?
Eu2 O9 2.308(4) . ?
Eu2 O12 2.320(5) . ?
Eu2 O16 2.492(5) . ?
Eu2 O18 2.512(5) . ?
Eu2 N9 2.593(5) . ?
Eu2 N7 2.604(5) . ?
Eu2 H7A 2.6452 . ?
Eu2 H8C 2.7116 . ?
Eu3 O3 2.268(4) . ?
Eu3 O6 2.299(4) . ?
Eu3 O5 2.316(4) . ?
Eu3 O4 2.337(4) . ?
Eu3 O15 2.507(4) . ?
Eu3 O14 2.520(4) . ?
Eu3 N6 2.594(6) . ?
Eu3 N3 2.602(5) . ?
Eu3 H4A 2.7296 . ?
Eu3 H5A 2.7084 . ?
C1 O1 1.291(9) . ?
C1 C6 1.417(11) . ?
C1 C2 1.418(13) . ?
C2 C7 1.413(13) . ?
C2 C3 1.427(12) . ?
C3 C4 1.392(14) . ?
C3 H3 0.9500 . ?
C4 C5 1.374(16) . ?
C4 Cl1 1.751(10) . ?
C5 C6 1.441(13) . ?
C5 H5 0.9500 . ?
C6 C8 1.518(13) . ?
C7 O13 1.227(9) . ?
C7 H7 0.9500 . ?
C8 N1 1.511(9) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 N1 1.518(10) . ?
C9 C10 1.523(10) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C15 1.371(9) . ?
C10 C11 1.433(9) . ?
C11 O2 1.295(7) . ?
C11 C12 1.403(9) . ?
C12 C13 1.407(9) . ?
C12 C24 1.453(9) . ?
C13 C14 1.357(11) . ?
C13 H13 0.9500 . ?
C14 C15 1.397(11) . ?
C14 Cl2 1.755(7) . ?
C15 H15 0.9500 . ?
C16 N1 1.477(9) . ?
C16 C17 1.513(11) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.509(18) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C23 1.356(15) . ?
C18 C19 1.376(12) . ?
C19 C20 1.414(14) . ?
C19 H19 0.9500 . ?
C20 C21 1.432(16) . ?
C20 H20 0.9500 . ?
C21 C22 1.338(13) . ?
C21 H21 0.9500 . ?
C22 C23 1.450(15) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C24 N2 1.290(8) . ?
C24 H24 0.9500 . ?
C25 N2 1.460(7) . ?
C25 C26 1.529(8) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.495(8) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 N3 1.493(8) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 N3 1.274(8) . ?
C28 C29 1.448(9) . ?
C28 H28 0.9500 . ?
C29 C34 1.401(9) . ?
C29 C30 1.406(9) . ?
C30 O3 1.303(7) . ?
C30 C31 1.426(9) . ?
C31 C32 1.357(9) . ?
C31 C35 1.501(10) . ?
C32 C33 1.405(11) . ?
C32 H32 0.9500 . ?
C33 C34 1.377(10) . ?
C33 Cl3 1.744(7) . ?
C34 H34 0.9500 . ?
C35 N4 1.511(8) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 N4 1.516(10) . ?
C36 C37 1.528(11) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 C42 1.352(10) . ?
C37 C38 1.422(10) . ?
C38 O4 1.292(7) . ?
C38 C39 1.414(9) . ?
C39 C40 1.419(9) . ?
C39 C51 1.426(10) . ?
C40 C41 1.351(12) . ?
C40 H40 0.9500 . ?
C41 C42 1.441(13) . ?
C41 Cl4 1.760(7) . ?
C42 H42 0.9500 . ?
C43 N4 1.474(12) . ?
C43 C44 1.550(12) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 C45 1.53(2) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.408(19) . ?
C45 C50 1.48(2) . ?
C46 C47 1.45(2) . ?
C46 H46 0.9500 . ?
C47 C48 1.389(16) . ?
C47 H47 0.9500 . ?
C48 C49 1.371(15) . ?
C48 H48 0.9500 . ?
C49 C50 1.38(2) . ?
C49 H49 0.9500 . ?
C50 H50 0.9500 . ?
C51 O15 1.234(8) . ?
C51 H51 0.9500 . ?
C52 O14 1.231(8) . ?
C52 C53 1.433(9) . ?
C52 H52 0.9500 . ?
C53 C58 1.401(10) . ?
C53 C54 1.427(9) . ?
C54 O5 1.306(7) . ?
C54 C55 1.409(9) . ?
C55 C56 1.381(10) . ?
C55 C59 1.486(9) . ?
C56 C57 1.401(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.346(11) . ?
C57 Cl5 1.756(8) . ?
C58 H58 0.9500 . ?
C59 N5 1.514(10) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C60 N5 1.519(8) . ?
C60 C61 1.520(10) . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C61 C66 1.381(9) . ?
C61 C62 1.417(9) . ?
C62 O6 1.293(7) . ?
C62 C63 1.411(10) . ?
C63 C64 1.406(9) . ?
C63 C75 1.452(9) . ?
C64 C65 1.393(10) . ?
C64 H64 0.9500 . ?
C65 C66 1.382(11) . ?
C65 Cl6 1.764(7) . ?
C66 H66 0.9500 . ?
C67 N5 1.501(8) . ?
C67 C68 1.516(10) . ?
C67 H67A 0.9900 . ?
C67 H67B 0.9900 . ?
C68 C69 1.492(12) . ?
C68 H68A 0.9900 . ?
C68 H68B 0.9900 . ?
C69 C70 1.341(9) . ?
C69 C74 1.350(8) . ?
C70 C71 1.356(9) . ?
C70 H70 0.9500 . ?
C71 C72 1.357(9) . ?
C71 H71 0.9500 . ?
C72 C73 1.379(9) . ?
C72 H72 0.9500 . ?
C73 C74 1.403(9) . ?
C73 H73 0.9500 . ?
C74 H74 0.9500 . ?
C75 N6 1.277(8) . ?
C75 H75 0.9500 . ?
C76 N6 1.488(8) . ?
C76 C77 1.520(8) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C77 C78 1.495(8) . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C78 N7 1.481(8) . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?
C79 N7 1.291(8) . ?
C79 C80 1.452(9) . ?
C79 H79 0.9500 . ?
C80 C85 1.380(9) . ?
C80 C81 1.424(9) . ?
C81 O7 1.293(7) . ?
C81 C82 1.432(8) . ?
C82 C83 1.392(9) . ?
C82 C86 1.528(9) . ?
C83 C84 1.363(9) . ?
C83 H83 0.9500 . ?
C84 C85 1.395(9) . ?
C84 Cl7 1.761(7) . ?
C85 H85 0.9500 . ?
C86 N8 1.507(9) . ?
C86 H86A 0.9900 . ?
C86 H86B 0.9900 . ?
C87 C88 1.515(11) . ?
C87 N8 1.519(8) . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C88 C93 1.347(11) . ?
C88 C89 1.451(10) . ?
C89 O8 1.290(8) . ?
C89 C90 1.423(10) . ?
C90 C91 1.399(10) . ?
C90 C102 1.408(11) . ?
C91 C92 1.350(12) . ?
C91 H91 0.9500 . ?
C92 C93 1.419(12) . ?
C92 Cl8 1.734(8) . ?
C93 H93 0.9500 . ?
C94 N8 1.472(9) . ?
C94 C95 1.521(10) . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C95 C96 1.537(12) . ?
C95 H95A 0.9900 . ?
C95 H95B 0.9900 . ?
C96 C97 1.351(13) . ?
C96 C101 1.381(15) . ?
C97 C98 1.383(15) . ?
C97 H97 0.9500 . ?
C98 C99 1.369(16) . ?
C98 H98 0.9500 . ?
C99 C100 1.322(14) . ?
C99 H99 0.9500 . ?
C100 C101 1.469(15) . ?
C100 H100 0.9500 . ?
C101 H101 0.9500 . ?
C102 O16 1.226(9) . ?
C102 H102 0.9500 . ?
C103 O9 1.297(7) . ?
C103 C108 1.398(9) . ?
C103 C104 1.411(9) . ?
C104 C105 1.406(9) . ?
C104 C109 1.444(9) . ?
C105 C106 1.371(11) . ?
C105 H105 0.9500 . ?
C106 C107 1.414(12) . ?
C106 Cl9 1.763(8) . ?
C107 C108 1.390(10) . ?
C107 H107 0.9500 . ?
C108 C137 1.503(10) . ?
C109 N9 1.298(8) . ?
C109 H109 0.9500 . ?
C110 N9 1.456(8) . ?
C110 C111 1.519(9) . ?
C110 H11A 0.9900 . ?
C110 H11B 0.9900 . ?
C111 C112 1.528(9) . ?
C111 H11C 0.9900 . ?
C111 H11D 0.9900 . ?
C112 N10 1.468(8) . ?
C112 H11E 0.9900 . ?
C112 H11F 0.9900 . ?
C113 N10 1.271(8) . ?
C113 C114 1.453(9) . ?
C113 H113 0.9500 . ?
C114 C119 1.400(9) . ?
C114 C115 1.411(9) . ?
C115 O11 1.323(7) . ?
C115 C116 1.405(9) . ?
C116 C117 1.400(9) . ?
C116 C120 1.496(9) . ?
C117 C118 1.410(10) . ?
C117 H117 0.9500 . ?
C118 C119 1.365(10) . ?
C118 Cl11 1.741(7) . ?
C119 H119 0.9500 . ?
C120 N11 1.519(8) . ?
C120 H12A 0.9900 . ?
C120 H12B 0.9900 . ?
C121 C122 1.512(9) . ?
C121 N11 1.520(8) . ?
C121 H12C 0.9900 . ?
C121 H12D 0.9900 . ?
C122 C127 1.361(10) . ?
C122 C123 1.423(10) . ?
C123 O10 1.279(8) . ?
C123 C124 1.436(9) . ?
C124 C125 1.409(11) . ?
C124 C136 1.433(11) . ?
C125 C126 1.335(12) . ?
C125 H125 0.9500 . ?
C126 C127 1.404(11) . ?
C126 Cl10 1.761(8) . ?
C127 H127 0.9500 . ?
C128 N11 1.487(8) . ?
C128 C129 1.535(10) . ?
C128 H12E 0.9900 . ?
C128 H12F 0.9900 . ?
C129 C130 1.450(14) . ?
C129 H12G 0.9900 . ?
C129 H12H 0.9900 . ?
C130 C135 1.350(9) . ?
C130 C131 1.420(9) . ?
C131 C132 1.408(9) . ?
C131 H131 0.9500 . ?
C132 C133 1.402(9) . ?
C132 H132 0.9500 . ?
C133 C134 1.382(9) . ?
C133 H133 0.9500 . ?
C134 C135 1.359(9) . ?
C134 H134 0.9500 . ?
C135 H135 0.9500 . ?
C136 O17 1.261(9) . ?
C136 H136 0.9500 . ?
C137 N12 1.527(9) . ?
C137 H13A 0.9900 . ?
C137 H13B 0.9900 . ?
C138 C139 1.485(12) . ?
C138 N12 1.521(9) . ?
C138 H13C 0.9900 . ?
C138 H13D 0.9900 . ?
C139 C144 1.359(13) . ?
C139 C140 1.446(11) . ?
C140 O12 1.300(9) . ?
C140 C141 1.394(11) . ?
C141 C153 1.404(11) . ?
C141 C142 1.426(12) . ?
C142 C143 1.320(12) . ?
C142 H142 0.9500 . ?
C143 C144 1.399(14) . ?
C143 Cl12 1.747(9) . ?
C144 H144 0.9500 . ?
C145 N12 1.522(10) . ?
C145 C146 1.531(10) . ?
C145 H14A 0.9900 . ?
C145 H14B 0.9900 . ?
C146 C147 1.467(12) . ?
C146 H14C 0.9900 . ?
C146 H14D 0.9900 . ?
C147 C148 1.390(18) . ?
C147 C152 1.419(17) . ?
C148 C149 1.432(9) . ?
C148 H148 0.9500 . ?
C149 C150 1.39(2) . ?
C149 H149 0.9500 . ?
C150 C151 1.39(2) . ?
C150 H150 0.9500 . ?
C151 C152 1.397(9) . ?
C151 H151 0.9500 . ?
C152 H152 0.9500 . ?
C153 O18 1.238(9) . ?
C153 H153 0.9500 . ?
O2 H2A 0.9900 . ?
O4 H4A 0.9900 . ?
O5 H5A 0.9900 . ?
O7 H7A 0.9900 . ?
O8 H8C 0.9900 . ?
O11 H11H 0.9900 . ?
