#------------------------------------------------------------------------------
#$Date: 2022-02-16 00:52:52 +0200 (Wed, 16 Feb 2022) $
#$Revision: 272973 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/97/7129712.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7129712
loop_
_publ_author_name
'Horiuchi, Shinnosuke'
'Hiroiwa, Hirotaka'
'Sakuda, Eri'
'Arikawa, Yasuhiro'
'Umakoshi, Keisuke'
_publ_section_title
;
 An Asymmetric Pt Diimine Acetylide Complex Providing Unique Luminescent
 Multinuclear Sandwich Complexes with Cu Salts
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/D1CC07108D
_journal_year                    2022
_chemical_formula_moiety         'C143 H130 B3 Cl14 Cu3 F32 N8 Pt4'
_chemical_formula_sum            'C143 H130 B3 Cl14 Cu3 F32 N8 Pt4'
_chemical_formula_weight         4068.37
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2021-12-02 deposited with the CCDC.	2022-02-15 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 106.5884(13)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   17.5253(16)
_cell_length_b                   34.487(3)
_cell_length_c                   25.961(2)
_cell_measurement_reflns_used    47788
_cell_measurement_temperature    93
_cell_measurement_theta_max      29.13
_cell_measurement_theta_min      1.64
_cell_volume                     15038(2)
_computing_cell_refinement       DTREK
_computing_data_collection       DTREK
_computing_data_reduction        DTREK
_computing_molecular_graphics    'CrystalStructure 4.2'
_computing_publication_material  'CrystalStructure 4.2 (Rigaku, 2017)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 29.257
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0613
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       47
_diffrn_reflns_limit_k_min       -47
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            146936
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.161
_diffrn_reflns_theta_min         1.637
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.448
_exptl_absorpt_correction_T_max  0.641
_exptl_absorpt_correction_T_min  0.429
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.797
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             7936.00
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH2Cl2, hexane'
_exptl_crystal_size_max          0.390
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_refine_diff_density_max         2.43
_refine_diff_density_min         -3.55
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     1864
_refine_ls_number_reflns         40041
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0665
_refine_ls_R_factor_gt           0.0504
_refine_ls_shift/su_max          0.006
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0831P)²+4.5501P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1248
_refine_ls_wR_factor_ref         0.1513
_reflns_Friedel_coverage         0.000
_reflns_number_gt                32057
_reflns_number_total             40041
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d1cc07108d2.cif
_cod_data_source_block           2065e
_cod_database_code               7129712
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 1/2-X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 -1/2+X,-1/2-Y,-1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.60474(2) 0.74957(2) 0.47260(2) 0.01653(5) Uani 1 1 d . . . . .
N101 N 0.6648(3) 0.79682(13) 0.45511(18) 0.0196(9) Uani 1 1 d . . . . .
C102 C 0.7279(3) 0.78894(16) 0.4367(2) 0.0180(10) Uani 1 1 d . . . . .
C103 C 0.7730(3) 0.81863(16) 0.4242(2) 0.0210(11) Uani 1 1 d . . . . .
H103 H 0.817877 0.812414 0.412140 0.025 Uiso 1 1 calc R U . . .
C104 C 0.7540(3) 0.85695(17) 0.4290(2) 0.0209(11) Uani 1 1 d . . . . .
C105 C 0.6886(3) 0.86385(17) 0.4489(2) 0.0226(11) Uani 1 1 d . . . . .
H105 H 0.673993 0.889762 0.454122 0.027 Uiso 1 1 calc R U . . .
C106 C 0.6457(3) 0.83385(17) 0.4608(2) 0.0204(11) Uani 1 1 d . . . . .
H106 H 0.601118 0.839396 0.473486 0.024 Uiso 1 1 calc R U . . .
C107 C 0.8034(4) 0.88993(18) 0.4173(3) 0.0297(13) Uani 1 1 d . . . . .
C108 C 0.8643(4) 0.8769(2) 0.3896(3) 0.0349(15) Uani 1 1 d . . . . .
H10A H 0.894454 0.899358 0.383094 0.042 Uiso 1 1 calc R U . . .
H10B H 0.900905 0.858234 0.412587 0.042 Uiso 1 1 calc R U . . .
H10C H 0.837079 0.864523 0.355285 0.042 Uiso 1 1 calc R U . . .
C109 C 0.7491(5) 0.9204(2) 0.3828(4) 0.053(2) Uani 1 1 d . . . . .
H10D H 0.781505 0.941696 0.375392 0.063 Uiso 1 1 calc R U . . .
H10E H 0.718425 0.908645 0.348855 0.063 Uiso 1 1 calc R U . . .
H10F H 0.712633 0.930461 0.402017 0.063 Uiso 1 1 calc R U . . .
C110 C 0.8487(4) 0.9091(2) 0.4704(3) 0.0467(19) Uani 1 1 d . . . . .
H10G H 0.880916 0.930517 0.463217 0.056 Uiso 1 1 calc R U . . .
H10H H 0.810679 0.919055 0.488453 0.056 Uiso 1 1 calc R U . . .
H10I H 0.883524 0.889917 0.493522 0.056 Uiso 1 1 calc R U . . .
N111 N 0.6911(3) 0.72302(14) 0.44500(17) 0.0183(9) Uani 1 1 d . . . . .
C112 C 0.7424(3) 0.74724(16) 0.4312(2) 0.0174(10) Uani 1 1 d . . . . .
C113 C 0.8034(3) 0.73255(17) 0.4125(2) 0.0198(11) Uani 1 1 d . . . . .
H113 H 0.838471 0.749942 0.402287 0.024 Uiso 1 1 calc R U . . .
C114 C 0.8139(3) 0.69267(17) 0.4085(2) 0.0220(11) Uani 1 1 d . . . . .
C115 C 0.7612(3) 0.66907(16) 0.4245(2) 0.0226(11) Uani 1 1 d . . . . .
H115 H 0.766734 0.641700 0.423330 0.027 Uiso 1 1 calc R U . . .
C116 C 0.7003(3) 0.68483(16) 0.4421(2) 0.0210(11) Uani 1 1 d . . . . .
H116 H 0.664374 0.667971 0.452399 0.025 Uiso 1 1 calc R U . . .
C117 C 0.8815(3) 0.67681(17) 0.3883(2) 0.0257(12) Uani 1 1 d . . . . .
C118 C 0.8703(4) 0.6917(3) 0.3312(3) 0.048(2) Uani 1 1 d . . . . .
H11A H 0.870100 0.720106 0.331353 0.057 Uiso 1 1 calc R U . . .
H11B H 0.914034 0.682350 0.317994 0.057 Uiso 1 1 calc R U . . .
H11C H 0.819556 0.682175 0.307770 0.057 Uiso 1 1 calc R U . . .
C119 C 0.9612(4) 0.6909(2) 0.4249(3) 0.049(2) Uani 1 1 d . . . . .
H11D H 0.961189 0.719284 0.426513 0.059 Uiso 1 1 calc R U . . .
H11E H 0.969150 0.680307 0.461100 0.059 Uiso 1 1 calc R U . . .
H11F H 1.004314 0.682128 0.410635 0.059 Uiso 1 1 calc R U . . .
C120 C 0.8813(5) 0.6331(2) 0.3857(4) 0.048(2) Uani 1 1 d . . . . .
H11G H 0.888416 0.622445 0.421828 0.058 Uiso 1 1 calc R U . . .
H11H H 0.830486 0.624078 0.361769 0.058 Uiso 1 1 calc R U . . .
H11I H 0.924964 0.624253 0.371994 0.058 Uiso 1 1 calc R U . . .
C121 C 0.5274(3) 0.77663(16) 0.5011(2) 0.0226(12) Uani 1 1 d . . . . .
C122 C 0.4753(3) 0.78904(17) 0.5194(2) 0.0219(11) Uani 1 1 d . . . . .
C123 C 0.4131(3) 0.80956(17) 0.5339(2) 0.0196(11) Uani 1 1 d . . . . .
C124 C 0.3444(3) 0.79010(17) 0.5379(2) 0.0219(11) Uani 1 1 d . . . . .
H124 H 0.339432 0.763003 0.531234 0.026 Uiso 1 1 calc R U . . .
C125 C 0.2845(4) 0.80964(19) 0.5513(2) 0.0281(13) Uani 1 1 d . . . . .
H125 H 0.238643 0.796047 0.553932 0.034 Uiso 1 1 calc R U . . .
C126 C 0.2911(4) 0.8499(2) 0.5611(2) 0.0311(14) Uani 1 1 d . . . . .
H126 H 0.249515 0.863507 0.570036 0.037 Uiso 1 1 calc R U . . .
C127 C 0.3580(4) 0.86922(18) 0.5578(2) 0.0298(13) Uani 1 1 d . . . . .
H127 H 0.362635 0.896289 0.564751 0.036 Uiso 1 1 calc R U . . .
C128 C 0.4194(3) 0.84941(16) 0.5443(2) 0.0227(11) Uani 1 1 d . . . . .
H128 H 0.465486 0.863096 0.542208 0.027 Uiso 1 1 calc R U . . .
C129 C 0.5527(3) 0.70251(16) 0.4883(2) 0.0206(11) Uani 1 1 d . . . . .
C130 C 0.5192(3) 0.67564(17) 0.5015(2) 0.0202(11) Uani 1 1 d . . . . .
C131 C 0.4903(3) 0.63900(16) 0.5132(2) 0.0204(11) Uani 1 1 d . . . . .
C132 C 0.5321(3) 0.60476(17) 0.5094(2) 0.0221(11) Uani 1 1 d . . . . .
F132 F 0.5989(2) 0.60736(10) 0.49398(14) 0.0296(8) Uani 1 1 d . . . . .
C133 C 0.5080(4) 0.56903(18) 0.5228(2) 0.0267(12) Uani 1 1 d . . . . .
F133 F 0.5508(2) 0.53769(11) 0.51986(16) 0.0363(9) Uani 1 1 d . . . . .
C134 C 0.4417(4) 0.56662(17) 0.5411(2) 0.0269(12) Uani 1 1 d . . . . .
F134 F 0.4199(2) 0.53186(11) 0.55487(16) 0.0403(9) Uani 1 1 d . . . . .
C135 C 0.4006(4) 0.59957(18) 0.5460(2) 0.0265(12) Uani 1 1 d . . . . .
F135 F 0.3366(2) 0.59673(12) 0.56421(16) 0.0399(10) Uani 1 1 d . . . . .
C136 C 0.4247(3) 0.63494(16) 0.5325(2) 0.0213(11) Uani 1 1 d . . . . .
F136 F 0.3842(2) 0.66669(11) 0.53930(15) 0.0307(8) Uani 1 1 d . . . . .
Cu1 Cu 0.52876(4) 0.73109(2) 0.55785(3) 0.01824(13) Uani 1 1 d . . . . .
Pt2 Pt 0.61323(2) 0.65397(2) 0.63259(2) 0.01494(5) Uani 1 1 d . . . . .
N201 N 0.6629(3) 0.60007(12) 0.63186(18) 0.0173(9) Uani 1 1 d . . . . .
C202 C 0.6293(3) 0.57102(15) 0.6530(2) 0.0162(10) Uani 1 1 d . . . . .
C203 C 0.6556(3) 0.53322(16) 0.6534(2) 0.0197(11) Uani 1 1 d . . . . .
H203 H 0.630842 0.513338 0.668279 0.024 Uiso 1 1 calc R U . . .
C204 C 0.7187(3) 0.52383(17) 0.6321(2) 0.0224(11) Uani 1 1 d . . . . .
C205 C 0.7507(3) 0.55450(17) 0.6103(2) 0.0237(12) Uani 1 1 d . . . . .
H205 H 0.792629 0.549693 0.594699 0.028 Uiso 1 1 calc R U . . .
C206 C 0.7228(3) 0.59123(16) 0.6110(2) 0.0205(11) Uani 1 1 d . . . . .
H206 H 0.746568 0.611492 0.596113 0.025 Uiso 1 1 calc R U . . .
C207 C 0.7479(4) 0.48319(19) 0.6296(2) 0.0296(13) Uani 1 1 d . . . . .
C208 C 0.7111(5) 0.4541(2) 0.6595(4) 0.052(2) Uani 1 1 d . . . . .
H20A H 0.732334 0.428195 0.656469 0.062 Uiso 1 1 calc R U . . .
H20B H 0.724016 0.461446 0.697526 0.062 Uiso 1 1 calc R U . . .
H20C H 0.653130 0.453909 0.643908 0.062 Uiso 1 1 calc R U . . .
C209 C 0.7291(6) 0.4717(2) 0.5709(3) 0.060(3) Uani 1 1 d . . . . .
H20D H 0.747636 0.445178 0.568272 0.073 Uiso 1 1 calc R U . . .
H20E H 0.671422 0.473023 0.554229 0.073 Uiso 1 1 calc R U . . .
H20F H 0.755976 0.489487 0.552383 0.073 Uiso 1 1 calc R U . . .
C210 C 0.8392(4) 0.4822(2) 0.6558(3) 0.0423(17) Uani 1 1 d . . . . .
H20G H 0.858878 0.455764 0.654395 0.051 Uiso 1 1 calc R U . . .
H20H H 0.865173 0.499727 0.636307 0.051 Uiso 1 1 calc R U . . .
H20I H 0.851307 0.490577 0.693399 0.051 Uiso 1 1 calc R U . . .
N211 N 0.5425(3) 0.62088(12) 0.66572(17) 0.0165(9) Uani 1 1 d . . . . .
C212 C 0.5618(3) 0.58296(15) 0.6725(2) 0.0153(9) Uani 1 1 d . . . . .
C213 C 0.5218(3) 0.55827(16) 0.6975(2) 0.0193(10) Uani 1 1 d . . . . .
H213 H 0.537696 0.531882 0.702821 0.023 Uiso 1 1 calc R U . . .
C214 C 0.4575(3) 0.57159(16) 0.7155(2) 0.0185(10) Uani 1 1 d . . . . .
C215 C 0.4387(3) 0.61032(16) 0.7070(2) 0.0194(11) Uani 1 1 d . . . . .
H215 H 0.396061 0.620880 0.718268 0.023 Uiso 1 1 calc R U . . .
C216 C 0.4813(3) 0.63397(17) 0.6821(2) 0.0223(11) Uani 1 1 d . . . . .
H216 H 0.466663 0.660485 0.676373 0.027 Uiso 1 1 calc R U . . .
C217 C 0.4153(3) 0.54462(17) 0.7451(2) 0.0247(12) Uani 1 1 d . . . . .
C218 C 0.3940(4) 0.5065(2) 0.7139(3) 0.0401(17) Uani 1 1 d . . . . .
H21A H 0.366951 0.489193 0.732967 0.048 Uiso 1 1 calc R U . . .
H21B H 0.358795 0.511850 0.677857 0.048 Uiso 1 1 calc R U . . .
H21C H 0.442807 0.493970 0.710828 0.048 Uiso 1 1 calc R U . . .
C219 C 0.3387(4) 0.5635(2) 0.7509(3) 0.0392(17) Uani 1 1 d . . . . .
H21D H 0.312483 0.545793 0.770015 0.047 Uiso 1 1 calc R U . . .
H21E H 0.352031 0.587739 0.771282 0.047 Uiso 1 1 calc R U . . .
H21F H 0.302744 0.569095 0.715202 0.047 Uiso 1 1 calc R U . . .
C220 C 0.4719(4) 0.5358(2) 0.8009(3) 0.0362(15) Uani 1 1 d . . . . .
H21G H 0.445415 0.518513 0.820304 0.043 Uiso 1 1 calc R U . . .
H21H H 0.520095 0.523297 0.796945 0.043 Uiso 1 1 calc R U . . .
H21I H 0.486281 0.560080 0.820984 0.043 Uiso 1 1 calc R U . . .
C221 C 0.6889(3) 0.68426(17) 0.6046(2) 0.0216(11) Uani 1 1 d . . . . .
C222 C 0.7375(3) 0.70479(17) 0.5938(2) 0.0210(11) Uani 1 1 d . . . . .
C223 C 0.7881(3) 0.73286(18) 0.5777(2) 0.0222(12) Uani 1 1 d . . . . .
C224 C 0.7762(3) 0.77231(19) 0.5852(2) 0.0283(13) Uani 1 1 d . . . . .
H224 H 0.734390 0.780233 0.599426 0.034 Uiso 1 1 calc R U . . .
C225 C 0.8250(4) 0.80010(18) 0.5719(2) 0.0289(13) Uani 1 1 d . . . . .
H225 H 0.816160 0.826944 0.576032 0.035 Uiso 1 1 calc R U . . .
C226 C 0.8879(4) 0.7876(2) 0.5522(2) 0.0304(14) Uani 1 1 d . . . . .
H226 H 0.922828 0.806093 0.544059 0.036 Uiso 1 1 calc R U . . .
C227 C 0.8991(3) 0.74860(19) 0.5447(2) 0.0279(14) Uani 1 1 d . . . . .
H227 H 0.940418 0.740431 0.530128 0.034 Uiso 1 1 calc R U . . .
C228 C 0.8507(3) 0.72172(18) 0.5584(2) 0.0228(12) Uani 1 1 d . . . . .
H228 H 0.860232 0.694915 0.554439 0.027 Uiso 1 1 calc R U . . .
C229 C 0.5571(3) 0.70272(15) 0.6328(2) 0.0192(10) Uani 1 1 d . . . . .
C230 C 0.5261(3) 0.73415(16) 0.6370(2) 0.0186(10) Uani 1 1 d . . . . .
C231 C 0.4868(3) 0.76490(15) 0.6559(2) 0.0175(10) Uani 1 1 d . . . . .
C232 C 0.4162(3) 0.75866(18) 0.6699(2) 0.0234(12) Uani 1 1 d . . . . .
F232 F 0.3852(2) 0.72280(10) 0.66444(14) 0.0287(8) Uani 1 1 d . . . . .
C233 C 0.3753(4) 0.78776(19) 0.6858(2) 0.0271(13) Uani 1 1 d . . . . .
F233 F 0.3049(2) 0.78085(13) 0.69512(17) 0.0438(10) Uani 1 1 d . . . . .
C234 C 0.4028(4) 0.82534(19) 0.6887(2) 0.0298(14) Uani 1 1 d . . . . .
F234 F 0.3635(3) 0.85461(12) 0.70276(16) 0.0423(10) Uani 1 1 d . . . . .
C235 C 0.4732(4) 0.83294(17) 0.6762(2) 0.0268(12) Uani 1 1 d . . . . .
F235 F 0.5005(3) 0.86917(11) 0.67905(17) 0.0417(10) Uani 1 1 d . . . . .
C236 C 0.5131(3) 0.80280(17) 0.6600(2) 0.0222(11) Uani 1 1 d . . . . .
F236 F 0.5813(2) 0.81137(10) 0.64877(15) 0.0327(8) Uani 1 1 d . . . . .
Cu2 Cu 0.78352(4) 0.67886(2) 0.66926(3) 0.02113(14) Uani 1 1 d . . . . .
Pt3 Pt 0.91762(2) 0.72520(2) 0.71720(2) 0.01516(5) Uani 1 1 d . . . . .
N301 N 0.9972(2) 0.70539(13) 0.67924(17) 0.0158(8) Uani 1 1 d . . . . .
C302 C 1.0382(3) 0.73314(16) 0.6612(2) 0.0175(10) Uani 1 1 d . . . . .
C303 C 1.0944(3) 0.72327(16) 0.6355(2) 0.0187(11) Uani 1 1 d . . . . .
H303 H 1.121733 0.743142 0.622575 0.022 Uiso 1 1 calc R U . . .
C304 C 1.1116(3) 0.68465(16) 0.6282(2) 0.0185(10) Uani 1 1 d . . . . .
C305 C 1.0689(3) 0.65690(16) 0.6474(2) 0.0224(11) Uani 1 1 d . . . . .
H305 H 1.079102 0.630142 0.643765 0.027 Uiso 1 1 calc R U . . .
C306 C 1.0118(3) 0.66797(16) 0.6716(2) 0.0204(11) Uani 1 1 d . . . . .
H306 H 0.982064 0.648549 0.683265 0.024 Uiso 1 1 calc R U . . .
C307 C 1.1767(3) 0.67215(17) 0.6028(2) 0.0209(11) Uani 1 1 d . . . . .
C308 C 1.1428(4) 0.64111(18) 0.5592(3) 0.0299(13) Uani 1 1 d . . . . .
H30A H 1.123214 0.618977 0.575421 0.036 Uiso 1 1 calc R U . . .
H30B H 1.098876 0.652278 0.530792 0.036 Uiso 1 1 calc R U . . .
H30C H 1.184824 0.632429 0.543799 0.036 Uiso 1 1 calc R U . . .
C309 C 1.2455(3) 0.65498(18) 0.6474(3) 0.0282(13) Uani 1 1 d . . . . .
H30D H 1.226010 0.633086 0.664080 0.034 Uiso 1 1 calc R U . . .
H30E H 1.287351 0.645994 0.631959 0.034 Uiso 1 1 calc R U . . .
H30F H 1.267221 0.674881 0.674532 0.034 Uiso 1 1 calc R U . . .
C310 C 1.2068(4) 0.70632(17) 0.5765(2) 0.0258(12) Uani 1 1 d . . . . .
H30G H 1.162612 0.717221 0.548026 0.031 Uiso 1 1 calc R U . . .
H30H H 1.228441 0.726267 0.603629 0.031 Uiso 1 1 calc R U . . .
H30I H 1.248571 0.697380 0.561057 0.031 Uiso 1 1 calc R U . . .
N311 N 0.9605(2) 0.77636(12) 0.69753(17) 0.0153(8) Uani 1 1 d . . . . .
C312 C 1.0179(3) 0.77329(15) 0.6718(2) 0.0150(10) Uani 1 1 d . . . . .
C313 C 1.0543(3) 0.80574(15) 0.6585(2) 0.0184(10) Uani 1 1 d . . . . .
H313 H 1.094575 0.802709 0.640829 0.022 Uiso 1 1 calc R U . . .
C314 C 1.0330(3) 0.84296(16) 0.6705(2) 0.0221(12) Uani 1 1 d . . . . .
C315 C 0.9726(3) 0.84536(16) 0.6954(2) 0.0205(11) Uani 1 1 d . . . . .
H315 H 0.955267 0.870023 0.703964 0.025 Uiso 1 1 calc R U . . .
C316 C 0.9377(3) 0.81215(16) 0.7079(2) 0.0210(11) Uani 1 1 d . . . . .
H316 H 0.896011 0.814591 0.724319 0.025 Uiso 1 1 calc R U . . .
C317 C 1.0730(4) 0.87986(16) 0.6588(3) 0.0264(12) Uani 1 1 d . . . . .
C318 C 1.0116(5) 0.9023(2) 0.6141(3) 0.049(2) Uani 1 1 d . . . . .
H31A H 0.995570 0.886317 0.581560 0.058 Uiso 1 1 calc R U . . .
H31B H 0.964750 0.908263 0.626142 0.058 Uiso 1 1 calc R U . . .
H31C H 1.035523 0.926441 0.606310 0.058 Uiso 1 1 calc R U . . .
C319 C 1.1454(4) 0.8707(2) 0.6390(3) 0.0433(18) Uani 1 1 d . . . . .
H31D H 1.128860 0.854615 0.606640 0.052 Uiso 1 1 calc R U . . .
H31E H 1.168537 0.894963 0.630662 0.052 Uiso 1 1 calc R U . . .
H31F H 1.185217 0.856743 0.667126 0.052 Uiso 1 1 calc R U . . .
C320 C 1.0974(5) 0.9048(2) 0.7090(3) 0.051(2) Uani 1 1 d . . . . .
H31G H 1.123083 0.928515 0.701434 0.061 Uiso 1 1 calc R U . . .
H31H H 1.050089 0.911663 0.720055 0.061 Uiso 1 1 calc R U . . .
H31I H 1.134719 0.890378 0.737978 0.061 Uiso 1 1 calc R U . . .
C321 C 0.8772(3) 0.67474(16) 0.7344(2) 0.0187(10) Uani 1 1 d . . . . .
C322 C 0.8394(3) 0.64695(17) 0.7420(2) 0.0204(11) Uani 1 1 d . . . . .
C323 C 0.7983(3) 0.61479(16) 0.7591(2) 0.0190(10) Uani 1 1 d . . . . .
C324 C 0.7317(3) 0.62359(17) 0.7774(2) 0.0230(11) Uani 1 1 d . . . . .
H324 H 0.713881 0.649610 0.777446 0.028 Uiso 1 1 calc R U . . .
C325 C 0.6927(4) 0.59386(18) 0.7953(2) 0.0261(12) Uani 1 1 d . . . . .
H325 H 0.648073 0.599676 0.807833 0.031 Uiso 1 1 calc R U . . .
C326 C 0.7176(4) 0.55589(19) 0.7952(2) 0.0303(14) Uani 1 1 d . . . . .
H326 H 0.690034 0.535754 0.807420 0.036 Uiso 1 1 calc R U . . .
C327 C 0.7834(4) 0.54723(17) 0.7772(2) 0.0275(13) Uani 1 1 d . . . . .
H327 H 0.801699 0.521239 0.778048 0.033 Uiso 1 1 calc R U . . .
C328 C 0.8219(3) 0.57640(17) 0.7580(2) 0.0226(11) Uani 1 1 d . . . . .
H328 H 0.864903 0.570180 0.743921 0.027 Uiso 1 1 calc R U . . .
C329 C 0.8443(3) 0.74857(17) 0.7533(2) 0.0215(11) Uani 1 1 d . . . . .
C330 C 0.7917(3) 0.76211(17) 0.7695(2) 0.0210(11) Uani 1 1 d . . . . .
C331 C 0.7264(3) 0.78573(18) 0.7745(2) 0.0242(12) Uani 1 1 d . . . . .
C332 C 0.6604(4) 0.76927(19) 0.7860(3) 0.0284(13) Uani 1 1 d . . . . .
F332 F 0.6547(2) 0.73073(13) 0.7891(2) 0.0489(12) Uani 1 1 d . . . . .
C333 C 0.6007(4) 0.7917(2) 0.7939(3) 0.0382(17) Uani 1 1 d . . . . .
F333 F 0.5366(2) 0.77564(16) 0.8045(2) 0.0670(16) Uani 1 1 d . . . . .
C334 C 0.6047(4) 0.8315(2) 0.7911(3) 0.0354(16) Uani 1 1 d . . . . .
F334 F 0.5463(3) 0.85384(15) 0.80004(19) 0.0546(13) Uani 1 1 d . . . . .
C335 C 0.6666(4) 0.8486(2) 0.7778(3) 0.0414(18) Uani 1 1 d . . . . .
F335 F 0.6693(3) 0.88658(13) 0.7735(3) 0.0732(17) Uani 1 1 d . . . . .
C336 C 0.7268(4) 0.8256(2) 0.7706(3) 0.0368(16) Uani 1 1 d . . . . .
F336 F 0.7892(3) 0.84288(11) 0.7600(2) 0.0620(16) Uani 1 1 d . . . . .
Cu3 Cu 0.86162(4) 0.72890(2) 0.83166(3) 0.01860(13) Uani 1 1 d . . . . .
Pt4 Pt 0.87230(2) 0.65600(2) 0.89520(2) 0.01660(5) Uani 1 1 d . . . . .
N401 N 0.7936(3) 0.62191(13) 0.91999(17) 0.0181(9) Uani 1 1 d . . . . .
C402 C 0.8106(3) 0.58368(16) 0.9245(2) 0.0184(10) Uani 1 1 d . . . . .
C403 C 0.7635(3) 0.55793(16) 0.9422(2) 0.0218(11) Uani 1 1 d . . . . .
H403 H 0.777603 0.531273 0.945885 0.026 Uiso 1 1 calc R U . . .
C404 C 0.6947(3) 0.57059(17) 0.9548(2) 0.0228(11) Uani 1 1 d . . . . .
C405 C 0.6781(3) 0.60960(16) 0.9490(2) 0.0220(11) Uani 1 1 d . . . . .
H405 H 0.632257 0.619524 0.957021 0.026 Uiso 1 1 calc R U . . .
C406 C 0.7280(3) 0.63482(16) 0.9315(2) 0.0201(11) Uani 1 1 d . . . . .
H406 H 0.715274 0.661641 0.927654 0.024 Uiso 1 1 calc R U . . .
C407 C 0.6459(3) 0.54242(17) 0.9764(2) 0.0247(12) Uani 1 1 d . . . . .
C408 C 0.6218(4) 0.50703(19) 0.9388(3) 0.0349(15) Uani 1 1 d . . . . .
H40A H 0.590073 0.489096 0.953559 0.042 Uiso 1 1 calc R U . . .
H40B H 0.590166 0.515769 0.903134 0.042 Uiso 1 1 calc R U . . .
H40C H 0.669754 0.493798 0.935698 0.042 Uiso 1 1 calc R U . . .
C409 C 0.6964(4) 0.5275(2) 1.0320(3) 0.0416(17) Uani 1 1 d . . . . .
H40D H 0.664956 0.509182 1.046290 0.050 Uiso 1 1 calc R U . . .
H40E H 0.744146 0.514543 1.028020 0.050 Uiso 1 1 calc R U . . .
H40F H 0.712108 0.549492 1.056699 0.050 Uiso 1 1 calc R U . . .
C410 C 0.5692(4) 0.5612(2) 0.9826(4) 0.056(2) Uani 1 1 d . . . . .
H40G H 0.539090 0.542045 0.996725 0.067 Uiso 1 1 calc R U . . .
H40H H 0.583086 0.583170 1.007486 0.067 Uiso 1 1 calc R U . . .
H40I H 0.536595 0.570392 0.947465 0.067 Uiso 1 1 calc R U . . .
N411 N 0.9201(3) 0.60212(13) 0.89213(18) 0.0199(9) Uani 1 1 d . . . . .
C411 C 0.8812(3) 0.57230(16) 0.9078(2) 0.0184(10) Uani 1 1 d . . . . .
C412 C 0.9075(3) 0.53469(17) 0.9068(2) 0.0230(11) Uani 1 1 d . . . . .
H412 H 0.880348 0.514175 0.918510 0.028 Uiso 1 1 calc R U . . .
C413 C 0.9741(3) 0.52629(18) 0.8885(2) 0.0265(12) Uani 1 1 d . . . . .
C414 C 1.0110(3) 0.55756(18) 0.8727(2) 0.0260(12) Uani 1 1 d . . . . .
H414 H 1.056846 0.553484 0.860744 0.031 Uiso 1 1 calc R U . . .
C415 C 0.9825(3) 0.59442(17) 0.8740(2) 0.0251(12) Uani 1 1 d . . . . .
H415 H 1.008101 0.615242 0.861609 0.030 Uiso 1 1 calc R U . . .
C416 C 1.0016(4) 0.4848(2) 0.8866(3) 0.0364(16) Uani 1 1 d . . . . .
C417 C 0.9346(5) 0.4610(2) 0.8503(3) 0.0462(19) Uani 1 1 d . . . . .
H41A H 0.887344 0.462791 0.863192 0.055 Uiso 1 1 calc R U . . .
H41B H 0.922028 0.471031 0.813515 0.055 Uiso 1 1 calc R U . . .
H41C H 0.951292 0.433852 0.850811 0.055 Uiso 1 1 calc R U . . .
C418 C 1.0736(4) 0.4816(2) 0.8660(3) 0.0398(16) Uani 1 1 d . . . . .
H41D H 1.088941 0.454324 0.865613 0.048 Uiso 1 1 calc R U . . .
H41E H 1.060922 0.492189 0.829535 0.048 Uiso 1 1 calc R U . . .
H41F H 1.117804 0.496304 0.889649 0.048 Uiso 1 1 calc R U . . .
C419 C 1.0237(5) 0.4675(2) 0.9449(3) 0.0470(19) Uani 1 1 d . . . . .
H41G H 0.977573 0.469312 0.958959 0.056 Uiso 1 1 calc R U . . .
H41H H 1.039156 0.440286 0.943888 0.056 Uiso 1 1 calc R U . . .
H41I H 1.068213 0.482188 0.968143 0.056 Uiso 1 1 calc R U . . .
C420 C 0.8263(3) 0.70725(16) 0.8993(2) 0.0202(11) Uani 1 1 d . . . . .
C421 C 0.8088(3) 0.74096(17) 0.9004(2) 0.0200(11) Uani 1 1 d . . . . .
C422 C 0.7842(3) 0.77961(16) 0.9106(2) 0.0212(11) Uani 1 1 d . . . . .
C423 C 0.8281(4) 0.81157(18) 0.9022(2) 0.0257(12) Uani 1 1 d . . . . .
H423 H 0.874256 0.807973 0.890491 0.031 Uiso 1 1 calc R U . . .
C424 C 0.8037(4) 0.84879(18) 0.9112(3) 0.0328(14) Uani 1 1 d . . . . .
H424 H 0.833358 0.870584 0.905403 0.039 Uiso 1 1 calc R U . . .
C425 C 0.7377(4) 0.8543(2) 0.9283(3) 0.0379(16) Uani 1 1 d . . . . .
H425 H 0.721773 0.879793 0.934567 0.046 Uiso 1 1 calc R U . . .
C426 C 0.6941(4) 0.8225(2) 0.9364(2) 0.0325(14) Uani 1 1 d . . . . .
H426 H 0.647973 0.826554 0.948025 0.039 Uiso 1 1 calc R U . . .
C427 C 0.7163(4) 0.78508(18) 0.9281(2) 0.0260(12) Uani 1 1 d . . . . .
H427 H 0.686099 0.763525 0.934046 0.031 Uiso 1 1 calc R U . . .
C428 C 0.9514(3) 0.68474(16) 0.8705(2) 0.0208(11) Uani 1 1 d . . . . .
C429 C 0.9938(3) 0.70426(17) 0.8518(2) 0.0211(11) Uani 1 1 d . . . . .
C430 C 1.0543(3) 0.7178(2) 0.8301(2) 0.0277(13) Uani 1 1 d . . . . .
C431 C 1.1030(4) 0.6915(2) 0.8124(2) 0.0332(15) Uani 1 1 d . . . . .
F431 F 1.0914(2) 0.65360(12) 0.81683(16) 0.0396(10) Uani 1 1 d . . . . .
C432 C 1.1597(4) 0.7035(3) 0.7895(3) 0.043(2) Uani 1 1 d . . . . .
F432 F 1.2045(3) 0.67680(18) 0.77282(17) 0.0654(16) Uani 1 1 d . . . . .
C433 C 1.1712(4) 0.7417(3) 0.7839(3) 0.050(2) Uani 1 1 d . . . . .
F433 F 1.2262(3) 0.75332(19) 0.75995(19) 0.0739(19) Uani 1 1 d . . . . .
C434 C 1.1269(4) 0.7695(2) 0.8012(3) 0.0421(19) Uani 1 1 d . . . . .
F434 F 1.1373(3) 0.80706(16) 0.79469(18) 0.0649(16) Uani 1 1 d . . . . .
C435 C 1.0695(4) 0.7567(2) 0.8245(3) 0.0347(15) Uani 1 1 d . . . . .
F435 F 1.0234(3) 0.78359(12) 0.83958(15) 0.0407(10) Uani 1 1 d . . . . .
B1 B 0.8888(5) 0.6019(3) 0.5517(3) 0.0406(19) Uani 1 1 d . . . . .
F1 F 0.9415(3) 0.62340(19) 0.5320(2) 0.0838(19) Uani 1 1 d . . . . .
F2 F 0.9025(3) 0.56133(15) 0.5494(2) 0.0615(13) Uani 1 1 d . . . . .
F3 F 0.8964(3) 0.61114(16) 0.60427(18) 0.0596(14) Uani 1 1 d . . . . .
F4 F 0.8123(3) 0.60826(14) 0.52046(17) 0.0524(11) Uani 1 1 d . . . . .
B2 B 0.6453(5) 0.4524(2) 0.7904(3) 0.0322(16) Uani 1 1 d . . . . .
F5 F 0.7256(3) 0.46049(14) 0.8013(2) 0.0639(15) Uani 1 1 d . . . . .
F6 F 0.6211(4) 0.4596(2) 0.8344(2) 0.104(3) Uani 1 1 d . . . . .
F7 F 0.6030(2) 0.47592(11) 0.74769(16) 0.0413(10) Uani 1 1 d . . . . .
F8 F 0.6327(3) 0.41413(13) 0.7762(2) 0.0576(13) Uani 1 1 d . . . . .
B3 B 1.0509(4) 0.8047(2) 0.4863(3) 0.0274(14) Uani 1 1 d . . . . .
F9 F 1.0439(3) 0.84320(11) 0.49878(19) 0.0464(11) Uani 1 1 d . . . . .
F10 F 0.9763(2) 0.79175(12) 0.45519(16) 0.0402(10) Uani 1 1 d . . . . .
F11 F 1.0739(2) 0.78310(13) 0.53338(17) 0.0441(10) Uani 1 1 d . . . . .
F12 F 1.1058(2) 0.80059(12) 0.45745(15) 0.0377(9) Uani 1 1 d . . . . .
C1 C 0.4962(4) 0.6931(2) 0.8379(3) 0.0454(18) Uani 1 1 d . . . . .
H13A H 0.495420 0.701244 0.874281 0.055 Uiso 1 1 calc R U . A 1
H13B H 0.535081 0.709601 0.826835 0.055 Uiso 1 1 calc R U . A 1
Cl1 Cl 0.40066(11) 0.69915(6) 0.79226(8) 0.0458(4) Uani 1 1 d . . . . .
Cl2A Cl 0.52610(19) 0.64274(10) 0.83914(12) 0.0372(10) Uiso 0.648(11) 1 d . . P
B 1
Cl2B Cl 0.5453(5) 0.6550(2) 0.8271(3) 0.053(2) Uiso 0.352(11) 1 d . . P B 2
C2 C 0.5312(4) 0.9464(3) 0.9742(3) 0.057(2) Uani 1 1 d . . . . .
H2C H 0.509781 0.929927 0.998098 0.068 Uiso 1 1 calc R U . . .
H2D H 0.570151 0.964582 0.996921 0.068 Uiso 1 1 calc R U . . .
Cl3 Cl 0.57942(12) 0.91679(7) 0.93749(10) 0.0568(5) Uani 1 1 d . . . . .
Cl4 Cl 0.45328(13) 0.97262(6) 0.93091(9) 0.0565(5) Uani 1 1 d . . . . .
C3 C 0.3397(7) 0.9437(3) 0.7713(4) 0.084(3) Uani 1 1 d . . . . .
H3E H 0.316309 0.917395 0.769388 0.101 Uiso 1 1 calc R U . . .
H3F H 0.332936 0.956617 0.803710 0.101 Uiso 1 1 calc R U . . .
Cl5 Cl 0.44213(18) 0.93951(8) 0.77733(11) 0.0762(7) Uani 1 1 d . . . . .
Cl6 Cl 0.28824(15) 0.96994(8) 0.71441(14) 0.0843(9) Uani 1 1 d . . . . .
C4 C 0.2560(6) 0.4654(3) 0.5579(4) 0.061(2) Uani 1 1 d . . . . .
H4G H 0.302261 0.463274 0.543381 0.073 Uiso 1 1 calc R U . . .
H4H H 0.209218 0.454192 0.531140 0.073 Uiso 1 1 calc R U . . .
Cl7 Cl 0.23763(12) 0.51465(6) 0.56731(9) 0.0519(5) Uani 1 1 d . . . . .
Cl8 Cl 0.27519(13) 0.43881(6) 0.61802(9) 0.0575(5) Uani 1 1 d . . . . .
C5 C 0.4958(5) 0.4166(2) 0.6596(3) 0.0423(17) Uani 1 1 d . . . . .
H5A H 0.544457 0.421770 0.689321 0.051 Uiso 1 1 calc R U . . .
H5B H 0.449905 0.416686 0.674729 0.051 Uiso 1 1 calc R U . . .
Cl9 Cl 0.48301(11) 0.45404(5) 0.61081(7) 0.0388(4) Uani 1 1 d . . . . .
Cl10 Cl 0.50345(16) 0.37119(6) 0.63286(9) 0.0642(6) Uani 1 1 d . . . . .
C6 C 0.0323(4) 0.5438(3) 0.6730(3) 0.049(2) Uani 1 1 d . . . . .
H6C H 0.016420 0.516252 0.673116 0.059 Uiso 1 1 calc R U . . .
H6D H -0.007514 0.556988 0.643338 0.059 Uiso 1 1 calc R U . . .
Cl11 Cl 0.03192(17) 0.56518(9) 0.73416(10) 0.0805(8) Uani 1 1 d . . . . .
Cl12 Cl 0.12581(12) 0.54652(6) 0.66157(10) 0.0542(5) Uani 1 1 d . . . . .
C7 C 0.7246(5) 0.9114(2) 0.5898(4) 0.059(2) Uani 1 1 d . . . . .
H7E H 0.774782 0.901540 0.584369 0.070 Uiso 1 1 calc R U . . .
H7F H 0.738000 0.925236 0.624684 0.070 Uiso 1 1 calc R U . . .
Cl13 Cl 0.66196(13) 0.87236(6) 0.59185(9) 0.0543(5) Uani 1 1 d . . . . .
Cl14 Cl 0.67933(14) 0.94452(6) 0.53719(10) 0.0575(6) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
B B 0.0013 0.0007
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cu Cu 0.3201 1.2651
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C121 Pt1 C129 84.4(2) . . ?
C121 Pt1 N101 99.1(2) . . ?
C129 Pt1 N101 176.4(2) . . ?
C121 Pt1 N111 176.9(2) . . ?
C129 Pt1 N111 97.8(2) . . ?
N101 Pt1 N111 78.65(18) . . ?
C121 Pt1 Cu1 46.51(16) . . ?
C129 Pt1 Cu1 48.03(15) . . ?
N101 Pt1 Cu1 134.63(13) . . ?
N111 Pt1 Cu1 134.02(13) . . ?
C106 N101 C102 119.1(5) . . ?
C106 N101 Pt1 124.8(4) . . ?
C102 N101 Pt1 116.1(4) . . ?
N101 C102 C103 120.8(5) . . ?
N101 C102 C112 114.3(5) . . ?
C103 C102 C112 124.9(5) . . ?
C104 C103 C102 121.2(5) . . ?
C104 C103 H103 119.4 . . ?
C102 C103 H103 119.4 . . ?
C103 C104 C105 116.1(5) . . ?
C103 C104 C107 122.5(5) . . ?
C105 C104 C107 121.3(5) . . ?
C106 C105 C104 121.0(5) . . ?
C106 C105 H105 119.5 . . ?
C104 C105 H105 119.5 . . ?
N101 C106 C105 121.8(5) . . ?
N101 C106 H106 119.1 . . ?
C105 C106 H106 119.1 . . ?
C104 C107 C108 113.1(5) . . ?
C104 C107 C109 109.9(5) . . ?
C108 C107 C109 109.4(6) . . ?
C104 C107 C110 108.9(5) . . ?
C108 C107 C110 107.5(5) . . ?
C109 C107 C110 107.9(6) . . ?
C107 C108 H10A 109.5 . . ?
C107 C108 H10B 109.5 . . ?
H10A C108 H10B 109.5 . . ?
C107 C108 H10C 109.5 . . ?
H10A C108 H10C 109.5 . . ?
H10B C108 H10C 109.5 . . ?
C107 C109 H10D 109.5 . . ?
C107 C109 H10E 109.5 . . ?
H10D C109 H10E 109.5 . . ?
C107 C109 H10F 109.5 . . ?
H10D C109 H10F 109.5 . . ?
H10E C109 H10F 109.5 . . ?
C107 C110 H10G 109.5 . . ?
C107 C110 H10H 109.5 . . ?
H10G C110 H10H 109.5 . . ?
C107 C110 H10I 109.5 . . ?
H10G C110 H10I 109.5 . . ?
H10H C110 H10I 109.5 . . ?
C116 N111 C112 119.7(4) . . ?
C116 N111 Pt1 124.9(4) . . ?
C112 N111 Pt1 115.4(4) . . ?
N111 C112 C113 120.3(5) . . ?
N111 C112 C102 115.6(4) . . ?
C113 C112 C102 124.1(5) . . ?
C112 C113 C114 121.1(5) . . ?
C112 C113 H113 119.4 . . ?
C114 C113 H113 119.4 . . ?
C115 C114 C113 116.4(5) . . ?
C115 C114 C117 122.9(5) . . ?
C113 C114 C117 120.7(5) . . ?
C114 C115 C116 120.8(5) . . ?
C114 C115 H115 119.6 . . ?
C116 C115 H115 119.6 . . ?
N111 C116 C115 121.6(5) . . ?
N111 C116 H116 119.2 . . ?
C115 C116 H116 119.2 . . ?
C120 C117 C118 107.2(6) . . ?
C120 C117 C119 109.6(6) . . ?
C118 C117 C119 109.8(6) . . ?
C120 C117 C114 112.4(5) . . ?
C118 C117 C114 108.4(5) . . ?
C119 C117 C114 109.4(5) . . ?
C117 C118 H11A 109.5 . . ?
C117 C118 H11B 109.5 . . ?
H11A C118 H11B 109.5 . . ?
C117 C118 H11C 109.5 . . ?
H11A C118 H11C 109.5 . . ?
H11B C118 H11C 109.5 . . ?
C117 C119 H11D 109.5 . . ?
C117 C119 H11E 109.5 . . ?
H11D C119 H11E 109.5 . . ?
C117 C119 H11F 109.5 . . ?
H11D C119 H11F 109.5 . . ?
H11E C119 H11F 109.5 . . ?
C117 C120 H11G 109.5 . . ?
C117 C120 H11H 109.5 . . ?
H11G C120 H11H 109.5 . . ?
C117 C120 H11I 109.5 . . ?
H11G C120 H11I 109.5 . . ?
H11H C120 H11I 109.5 . . ?
C122 C121 Pt1 172.0(5) . . ?
C122 C121 Cu1 81.5(4) . . ?
Pt1 C121 Cu1 92.2(2) . . ?
C121 C122 C123 169.2(6) . . ?
C121 C122 Cu1 66.9(4) . . ?
C123 C122 Cu1 123.9(4) . . ?
C128 C123 C124 118.4(5) . . ?
C128 C123 C122 120.7(5) . . ?
C124 C123 C122 120.9(5) . . ?
C125 C124 C123 121.1(6) . . ?
C125 C124 H124 119.4 . . ?
C123 C124 H124 119.4 . . ?
C124 C125 C126 120.0(6) . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C127 C126 C125 119.6(6) . . ?
C127 C126 H126 120.2 . . ?
C125 C126 H126 120.2 . . ?
C126 C127 C128 120.6(6) . . ?
C126 C127 H127 119.7 . . ?
C128 C127 H127 119.7 . . ?
C123 C128 C127 120.2(5) . . ?
C123 C128 H128 119.9 . . ?
C127 C128 H128 119.9 . . ?
C130 C129 Pt1 174.0(5) . . ?
C130 C129 Cu1 83.6(4) . . ?
Pt1 C129 Cu1 90.5(2) . . ?
C129 C130 C131 168.3(6) . . ?
C129 C130 Cu1 66.5(4) . . ?
C131 C130 Cu1 123.2(4) . . ?
C136 C131 C132 116.2(5) . . ?
C136 C131 C130 123.2(5) . . ?
C132 C131 C130 120.3(5) . . ?
F132 C132 C133 119.3(5) . . ?
F132 C132 C131 118.6(5) . . ?
C133 C132 C131 122.0(5) . . ?
F133 C133 C132 119.6(5) . . ?
F133 C133 C134 121.0(6) . . ?
C132 C133 C134 119.3(5) . . ?
F134 C134 C135 121.4(5) . . ?
F134 C134 C133 118.6(6) . . ?
C135 C134 C133 120.0(5) . . ?
F135 C135 C136 120.4(6) . . ?
F135 C135 C134 119.2(5) . . ?
C136 C135 C134 120.4(5) . . ?
F136 C136 C135 118.6(5) . . ?
F136 C136 C131 119.3(5) . . ?
C135 C136 C131 122.1(5) . . ?
C230 Cu1 C229 34.2(2) . . ?
C230 Cu1 C121 130.1(2) . . ?
C229 Cu1 C121 157.8(2) . . ?
C230 Cu1 C129 154.2(2) . . ?
C229 Cu1 C129 120.0(2) . . ?
C121 Cu1 C129 74.5(2) . . ?
C230 Cu1 C122 105.3(2) . . ?
C229 Cu1 C122 139.5(2) . . ?
C121 Cu1 C122 31.54(19) . . ?
C129 Cu1 C122 100.5(2) . . ?
C230 Cu1 C130 129.2(2) . . ?
C229 Cu1 C130 98.7(2) . . ?
C121 Cu1 C130 100.4(2) . . ?
C129 Cu1 C130 29.95(19) . . ?
C122 Cu1 C130 118.68(19) . . ?
C230 Cu1 Pt1 150.82(15) . . ?
C229 Cu1 Pt1 138.86(14) . . ?
C121 Cu1 Pt1 41.33(14) . . ?
C129 Cu1 Pt1 41.49(15) . . ?
C122 Cu1 Pt1 72.79(13) . . ?
C130 Cu1 Pt1 71.44(13) . . ?
C229 Pt2 C221 86.4(2) . . ?
C229 Pt2 N211 96.46(19) . . ?
C221 Pt2 N211 175.6(2) . . ?
C229 Pt2 N201 174.9(2) . . ?
C221 Pt2 N201 98.3(2) . . ?
N211 Pt2 N201 78.98(17) . . ?
C229 Pt2 Cu2 102.14(16) . . ?
C221 Pt2 Cu2 41.70(16) . . ?
N211 Pt2 Cu2 134.12(13) . . ?
N201 Pt2 Cu2 82.84(13) . . ?
C206 N201 C202 118.4(4) . . ?
C206 N201 Pt2 126.1(4) . . ?
C202 N201 Pt2 115.5(3) . . ?
N201 C202 C203 121.2(5) . . ?
N201 C202 C212 114.7(4) . . ?
C203 C202 C212 124.1(5) . . ?
C202 C203 C204 120.8(5) . . ?
C202 C203 H203 119.6 . . ?
C204 C203 H203 119.6 . . ?
C205 C204 C203 116.0(5) . . ?
C205 C204 C207 120.7(5) . . ?
C203 C204 C207 123.2(5) . . ?
C206 C205 C204 121.0(5) . . ?
C206 C205 H205 119.5 . . ?
C204 C205 H205 119.5 . . ?
N201 C206 C205 122.7(5) . . ?
N201 C206 H206 118.7 . . ?
C205 C206 H206 118.7 . . ?
C204 C207 C209 108.0(5) . . ?
C204 C207 C208 113.2(5) . . ?
C209 C207 C208 109.8(7) . . ?
C204 C207 C210 108.8(5) . . ?
C209 C207 C210 109.7(6) . . ?
C208 C207 C210 107.3(6) . . ?
C207 C208 H20A 109.5 . . ?
C207 C208 H20B 109.5 . . ?
H20A C208 H20B 109.5 . . ?
C207 C208 H20C 109.5 . . ?
H20A C208 H20C 109.5 . . ?
H20B C208 H20C 109.5 . . ?
C207 C209 H20D 109.5 . . ?
C207 C209 H20E 109.5 . . ?
H20D C209 H20E 109.5 . . ?
C207 C209 H20F 109.5 . . ?
H20D C209 H20F 109.5 . . ?
H20E C209 H20F 109.5 . . ?
C207 C210 H20G 109.5 . . ?
C207 C210 H20H 109.5 . . ?
H20G C210 H20H 109.5 . . ?
C207 C210 H20I 109.5 . . ?
H20G C210 H20I 109.5 . . ?
H20H C210 H20I 109.5 . . ?
C216 N211 C212 118.7(4) . . ?
C216 N211 Pt2 125.5(4) . . ?
C212 N211 Pt2 115.8(3) . . ?
N211 C212 C213 121.1(5) . . ?
N211 C212 C202 115.0(4) . . ?
C213 C212 C202 123.8(5) . . ?
C212 C213 C214 121.0(5) . . ?
C212 C213 H213 119.5 . . ?
C214 C213 H213 119.5 . . ?
C215 C214 C213 116.0(5) . . ?
C215 C214 C217 122.9(5) . . ?
C213 C214 C217 121.0(5) . . ?
C214 C215 C216 120.6(5) . . ?
C214 C215 H215 119.7 . . ?
C216 C215 H215 119.7 . . ?
N211 C216 C215 122.5(5) . . ?
N211 C216 H216 118.8 . . ?
C215 C216 H216 118.8 . . ?
C214 C217 C220 108.7(5) . . ?
C214 C217 C218 109.6(5) . . ?
C220 C217 C218 108.9(5) . . ?
C214 C217 C219 110.7(5) . . ?
C220 C217 C219 109.8(5) . . ?
C218 C217 C219 109.1(5) . . ?
C217 C218 H21A 109.5 . . ?
C217 C218 H21B 109.5 . . ?
H21A C218 H21B 109.5 . . ?
C217 C218 H21C 109.5 . . ?
H21A C218 H21C 109.5 . . ?
H21B C218 H21C 109.5 . . ?
C217 C219 H21D 109.5 . . ?
C217 C219 H21E 109.5 . . ?
H21D C219 H21E 109.5 . . ?
C217 C219 H21F 109.5 . . ?
H21D C219 H21F 109.5 . . ?
H21E C219 H21F 109.5 . . ?
C217 C220 H21G 109.5 . . ?
C217 C220 H21H 109.5 . . ?
H21G C220 H21H 109.5 . . ?
C217 C220 H21I 109.5 . . ?
H21G C220 H21I 109.5 . . ?
H21H C220 H21I 109.5 . . ?
C222 C221 Pt2 171.9(5) . . ?
C222 C221 Cu2 77.2(4) . . ?
Pt2 C221 Cu2 97.2(2) . . ?
C221 C222 C223 172.9(6) . . ?
C221 C222 Cu2 68.8(4) . . ?
C223 C222 Cu2 116.7(4) . . ?
C228 C223 C224 119.0(5) . . ?
C228 C223 C222 122.1(6) . . ?
C224 C223 C222 118.8(5) . . ?
C225 C224 C223 120.6(6) . . ?
C225 C224 H224 119.7 . . ?
C223 C224 H224 119.7 . . ?
C224 C225 C226 118.6(6) . . ?
C224 C225 H225 120.7 . . ?
C226 C225 H225 120.7 . . ?
C227 C226 C225 120.6(6) . . ?
C227 C226 H226 119.7 . . ?
C225 C226 H226 119.7 . . ?
C228 C227 C226 119.9(6) . . ?
C228 C227 H227 120.1 . . ?
C226 C227 H227 120.1 . . ?
C227 C228 C223 121.3(6) . . ?
C227 C228 H228 119.3 . . ?
C223 C228 H228 119.3 . . ?
C230 C229 Pt2 174.7(5) . . ?
C230 C229 Cu1 71.2(4) . . ?
Pt2 C229 Cu1 112.5(2) . . ?
C229 C230 C231 162.5(5) . . ?
C229 C230 Cu1 74.5(4) . . ?
C231 C230 Cu1 121.9(4) . . ?
C236 C231 C232 115.2(5) . . ?
C236 C231 C230 123.1(5) . . ?
C232 C231 C230 121.6(5) . . ?
F232 C232 C233 118.5(5) . . ?
F232 C232 C231 118.4(5) . . ?
C233 C232 C231 123.0(6) . . ?
F233 C233 C232 120.8(6) . . ?
F233 C233 C234 118.8(5) . . ?
C232 C233 C234 120.2(5) . . ?
F234 C234 C233 121.9(6) . . ?
F234 C234 C235 119.0(6) . . ?
C233 C234 C235 119.0(5) . . ?
F235 C235 C236 121.1(6) . . ?
F235 C235 C234 119.5(6) . . ?
C236 C235 C234 119.3(6) . . ?
F236 C236 C231 119.4(5) . . ?
F236 C236 C235 117.4(5) . . ?
C231 C236 C235 123.2(5) . . ?
C321 Cu2 C221 178.6(2) . . ?
C321 Cu2 C222 145.7(2) . . ?
C221 Cu2 C222 34.0(2) . . ?
C321 Cu2 C322 33.6(2) . . ?
C221 Cu2 C322 147.0(2) . . ?
C222 Cu2 C322 172.4(2) . . ?
C321 Cu2 Pt3 44.49(16) . . ?
C221 Cu2 Pt3 134.70(17) . . ?
C222 Cu2 Pt3 102.76(16) . . ?
C322 Cu2 Pt3 77.90(15) . . ?
C321 Cu2 Pt2 138.97(15) . . ?
C221 Cu2 Pt2 41.13(15) . . ?
C222 Cu2 Pt2 75.02(15) . . ?
C322 Cu2 Pt2 107.11(15) . . ?
Pt3 Cu2 Pt2 159.06(3) . . ?
C329 Pt3 C321 85.9(2) . . ?
C329 Pt3 N311 95.9(2) . . ?
C321 Pt3 N311 178.1(2) . . ?
C329 Pt3 N301 175.3(2) . . ?
C321 Pt3 N301 98.7(2) . . ?
N311 Pt3 N301 79.47(17) . . ?
C329 Pt3 Cu2 82.36(17) . . ?
C321 Pt3 Cu2 45.08(15) . . ?
N311 Pt3 Cu2 134.43(12) . . ?
N301 Pt3 Cu2 101.26(13) . . ?
C306 N301 C302 119.0(4) . . ?
C306 N301 Pt3 125.4(4) . . ?
C302 N301 Pt3 115.6(3) . . ?
N301 C302 C303 120.9(5) . . ?
N301 C302 C312 114.7(4) . . ?
C303 C302 C312 124.4(5) . . ?
C302 C303 C304 120.9(5) . . ?
C302 C303 H303 119.5 . . ?
C304 C303 H303 119.5 . . ?
C303 C304 C305 116.8(5) . . ?
C303 C304 C307 123.0(5) . . ?
C305 C304 C307 120.2(5) . . ?
C306 C305 C304 120.5(5) . . ?
C306 C305 H305 119.8 . . ?
C304 C305 H305 119.8 . . ?
N301 C306 C305 121.9(5) . . ?
N301 C306 H306 119.1 . . ?
C305 C306 H306 119.1 . . ?
C310 C307 C309 109.7(5) . . ?
C310 C307 C304 111.6(5) . . ?
C309 C307 C304 107.8(4) . . ?
C310 C307 C308 108.5(5) . . ?
C309 C307 C308 109.9(5) . . ?
C304 C307 C308 109.4(4) . . ?
C307 C308 H30A 109.5 . . ?
C307 C308 H30B 109.5 . . ?
H30A C308 H30B 109.5 . . ?
C307 C308 H30C 109.5 . . ?
H30A C308 H30C 109.5 . . ?
H30B C308 H30C 109.5 . . ?
C307 C309 H30D 109.5 . . ?
C307 C309 H30E 109.5 . . ?
H30D C309 H30E 109.5 . . ?
C307 C309 H30F 109.5 . . ?
H30D C309 H30F 109.5 . . ?
H30E C309 H30F 109.5 . . ?
C307 C310 H30G 109.5 . . ?
C307 C310 H30H 109.5 . . ?
H30G C310 H30H 109.5 . . ?
C307 C310 H30I 109.5 . . ?
H30G C310 H30I 109.5 . . ?
H30H C310 H30I 109.5 . . ?
C316 N311 C312 118.1(4) . . ?
C316 N311 Pt3 126.3(3) . . ?
C312 N311 Pt3 115.6(3) . . ?
N311 C312 C313 121.3(5) . . ?
N311 C312 C302 114.6(4) . . ?
C313 C312 C302 124.1(4) . . ?
C312 C313 C314 121.1(5) . . ?
C312 C313 H313 119.4 . . ?
C314 C313 H313 119.4 . . ?
C315 C314 C313 116.5(5) . . ?
C315 C314 C317 119.8(5) . . ?
C313 C314 C317 123.7(5) . . ?
C316 C315 C314 120.4(5) . . ?
C316 C315 H315 119.8 . . ?
C314 C315 H315 119.8 . . ?
N311 C316 C315 122.6(5) . . ?
N311 C316 H316 118.7 . . ?
C315 C316 H316 118.7 . . ?
C320 C317 C314 109.6(5) . . ?
C320 C317 C319 110.3(6) . . ?
C314 C317 C319 111.5(5) . . ?
C320 C317 C318 109.0(6) . . ?
C314 C317 C318 107.8(5) . . ?
C319 C317 C318 108.5(6) . . ?
C317 C318 H31A 109.5 . . ?
C317 C318 H31B 109.5 . . ?
H31A C318 H31B 109.5 . . ?
C317 C318 H31C 109.5 . . ?
H31A C318 H31C 109.5 . . ?
H31B C318 H31C 109.5 . . ?
C317 C319 H31D 109.5 . . ?
C317 C319 H31E 109.5 . . ?
H31D C319 H31E 109.5 . . ?
C317 C319 H31F 109.5 . . ?
H31D C319 H31F 109.5 . . ?
H31E C319 H31F 109.5 . . ?
C317 C320 H31G 109.5 . . ?
C317 C320 H31H 109.5 . . ?
H31G C320 H31H 109.5 . . ?
C317 C320 H31I 109.5 . . ?
H31G C320 H31I 109.5 . . ?
H31H C320 H31I 109.5 . . ?
C322 C321 Pt3 168.4(5) . . ?
C322 C321 Cu2 80.8(4) . . ?
Pt3 C321 Cu2 90.4(2) . . ?
C321 C322 C323 172.1(6) . . ?
C321 C322 Cu2 65.6(3) . . ?
C323 C322 Cu2 120.8(4) . . ?
C328 C323 C324 119.4(5) . . ?
C328 C323 C322 122.8(5) . . ?
C324 C323 C322 117.8(5) . . ?
C325 C324 C323 119.2(5) . . ?
C325 C324 H324 120.4 . . ?
C323 C324 H324 120.4 . . ?
C326 C325 C324 121.1(6) . . ?
C326 C325 H325 119.5 . . ?
C324 C325 H325 119.5 . . ?
C325 C326 C327 119.7(5) . . ?
C325 C326 H326 120.2 . . ?
C327 C326 H326 120.2 . . ?
C328 C327 C326 120.1(6) . . ?
C328 C327 H327 120.0 . . ?
C326 C327 H327 120.0 . . ?
C327 C328 C323 120.5(5) . . ?
C327 C328 H328 119.8 . . ?
C323 C328 H328 119.8 . . ?
C330 C329 Pt3 171.7(5) . . ?
C330 C329 Cu3 72.4(4) . . ?
Pt3 C329 Cu3 113.5(3) . . ?
C329 C330 C331 162.2(6) . . ?
C329 C330 Cu3 73.6(4) . . ?
C331 C330 Cu3 123.5(4) . . ?
C336 C331 C332 116.2(5) . . ?
C336 C331 C330 122.5(5) . . ?
C332 C331 C330 121.2(6) . . ?
F332 C332 C333 118.8(6) . . ?
F332 C332 C331 119.8(5) . . ?
C333 C332 C331 121.4(6) . . ?
F333 C333 C332 121.2(7) . . ?
F333 C333 C334 118.6(6) . . ?
C332 C333 C334 120.2(6) . . ?
F334 C334 C335 119.5(7) . . ?
F334 C334 C333 120.3(7) . . ?
C335 C334 C333 120.1(6) . . ?
F335 C335 C334 120.2(7) . . ?
F335 C335 C336 121.0(7) . . ?
C334 C335 C336 118.8(7) . . ?
F336 C336 C335 118.3(7) . . ?
F336 C336 C331 118.5(6) . . ?
C335 C336 C331 123.1(6) . . ?
C330 Cu3 C329 33.9(2) . . ?
C330 Cu3 C420 125.7(2) . . ?
C329 Cu3 C420 156.0(2) . . ?
C330 Cu3 C428 157.0(2) . . ?
C329 Cu3 C428 123.7(2) . . ?
C420 Cu3 C428 73.9(2) . . ?
C330 Cu3 C421 103.2(2) . . ?
C329 Cu3 C421 136.9(2) . . ?
C420 Cu3 C421 31.5(2) . . ?
C428 Cu3 C421 99.4(2) . . ?
C330 Cu3 C429 133.7(2) . . ?
C329 Cu3 C429 101.0(2) . . ?
C420 Cu3 C429 100.6(2) . . ?
C428 Cu3 C429 30.06(19) . . ?
C421 Cu3 C429 118.81(19) . . ?
C330 Cu3 Pt4 145.76(16) . . ?
C329 Cu3 Pt4 141.54(16) . . ?
C420 Cu3 Pt4 40.95(15) . . ?
C428 Cu3 Pt4 40.95(15) . . ?
C421 Cu3 Pt4 72.25(14) . . ?
C429 Cu3 Pt4 70.99(14) . . ?
C428 Pt4 C420 84.4(2) . . ?
C428 Pt4 N411 96.3(2) . . ?
C420 Pt4 N411 179.0(2) . . ?
C428 Pt4 N401 175.5(2) . . ?
C420 Pt4 N401 100.2(2) . . ?
N411 Pt4 N401 79.14(18) . . ?
C428 Pt4 Cu3 47.94(16) . . ?
C420 Pt4 Cu3 46.18(15) . . ?
N411 Pt4 Cu3 134.77(12) . . ?
N401 Pt4 Cu3 135.64(13) . . ?
C406 N401 C402 119.1(5) . . ?
C406 N401 Pt4 125.1(4) . . ?
C402 N401 Pt4 115.9(3) . . ?
N401 C402 C403 121.4(5) . . ?
N401 C402 C411 114.6(5) . . ?
C403 C402 C411 124.0(5) . . ?
C402 C403 C404 120.9(5) . . ?
C402 C403 H403 119.6 . . ?
C404 C403 H403 119.6 . . ?
C405 C404 C403 116.5(5) . . ?
C405 C404 C407 123.2(5) . . ?
C403 C404 C407 120.2(5) . . ?
C404 C405 C406 120.8(5) . . ?
C404 C405 H405 119.6 . . ?
C406 C405 H405 119.6 . . ?
N401 C406 C405 121.3(5) . . ?
N401 C406 H406 119.3 . . ?
C405 C406 H406 119.3 . . ?
C404 C407 C410 111.9(5) . . ?
C404 C407 C408 110.8(5) . . ?
C410 C407 C408 108.0(6) . . ?
C404 C407 C409 109.0(5) . . ?
C410 C407 C409 109.1(6) . . ?
C408 C407 C409 107.9(5) . . ?
C407 C408 H40A 109.5 . . ?
C407 C408 H40B 109.5 . . ?
H40A C408 H40B 109.5 . . ?
C407 C408 H40C 109.5 . . ?
H40A C408 H40C 109.5 . . ?
H40B C408 H40C 109.5 . . ?
C407 C409 H40D 109.5 . . ?
C407 C409 H40E 109.5 . . ?
H40D C409 H40E 109.5 . . ?
C407 C409 H40F 109.5 . . ?
H40D C409 H40F 109.5 . . ?
H40E C409 H40F 109.5 . . ?
C407 C410 H40G 109.5 . . ?
C407 C410 H40H 109.5 . . ?
H40G C410 H40H 109.5 . . ?
C407 C410 H40I 109.5 . . ?
H40G C410 H40I 109.5 . . ?
H40H C410 H40I 109.5 . . ?
C415 N411 C411 119.1(5) . . ?
C415 N411 Pt4 125.4(4) . . ?
C411 N411 Pt4 115.4(3) . . ?
N411 C411 C412 120.4(5) . . ?
N411 C411 C402 114.9(5) . . ?
C412 C411 C402 124.6(5) . . ?
C411 C412 C413 120.9(6) . . ?
C411 C412 H412 119.6 . . ?
C413 C412 H412 119.6 . . ?
C414 C413 C412 116.3(5) . . ?
C414 C413 C416 123.2(5) . . ?
C412 C413 C416 120.4(6) . . ?
C415 C414 C413 120.8(5) . . ?
C415 C414 H414 119.6 . . ?
C413 C414 H414 119.6 . . ?
N411 C415 C414 122.3(5) . . ?
N411 C415 H415 118.8 . . ?
C414 C415 H415 118.8 . . ?
C418 C416 C413 112.7(6) . . ?
C418 C416 C417 108.6(6) . . ?
C413 C416 C417 109.5(5) . . ?
C418 C416 C419 108.2(6) . . ?
C413 C416 C419 108.7(6) . . ?
C417 C416 C419 109.1(6) . . ?
C416 C417 H41A 109.5 . . ?
C416 C417 H41B 109.5 . . ?
H41A C417 H41B 109.5 . . ?
C416 C417 H41C 109.5 . . ?
H41A C417 H41C 109.5 . . ?
H41B C417 H41C 109.5 . . ?
C416 C418 H41D 109.5 . . ?
C416 C418 H41E 109.5 . . ?
H41D C418 H41E 109.5 . . ?
C416 C418 H41F 109.5 . . ?
H41D C418 H41F 109.5 . . ?
H41E C418 H41F 109.5 . . ?
C416 C419 H41G 109.5 . . ?
C416 C419 H41H 109.5 . . ?
H41G C419 H41H 109.5 . . ?
C416 C419 H41I 109.5 . . ?
H41G C419 H41I 109.5 . . ?
H41H C419 H41I 109.5 . . ?
C421 C420 Pt4 169.7(5) . . ?
C421 C420 Cu3 79.5(4) . . ?
Pt4 C420 Cu3 92.9(2) . . ?
C420 C421 C422 169.5(6) . . ?
C420 C421 Cu3 69.0(3) . . ?
C422 C421 Cu3 121.5(4) . . ?
C423 C422 C427 120.0(5) . . ?
C423 C422 C421 119.5(5) . . ?
C427 C422 C421 120.5(5) . . ?
C424 C423 C422 119.5(6) . . ?
C424 C423 H423 120.3 . . ?
C422 C423 H423 120.3 . . ?
C425 C424 C423 120.8(6) . . ?
C425 C424 H424 119.6 . . ?
C423 C424 H424 119.6 . . ?
C424 C425 C426 119.6(6) . . ?
C424 C425 H425 120.2 . . ?
C426 C425 H425 120.2 . . ?
C427 C426 C425 121.5(6) . . ?
C427 C426 H426 119.2 . . ?
C425 C426 H426 119.2 . . ?
C426 C427 C422 118.6(6) . . ?
C426 C427 H427 120.7 . . ?
C422 C427 H427 120.7 . . ?
C429 C428 Pt4 173.4(5) . . ?
C429 C428 Cu3 82.6(4) . . ?
Pt4 C428 Cu3 91.1(2) . . ?
C428 C429 C430 164.9(6) . . ?
C428 C429 Cu3 67.3(4) . . ?
C430 C429 Cu3 125.9(4) . . ?
C435 C430 C431 115.9(6) . . ?
C435 C430 C429 123.5(6) . . ?
C431 C430 C429 120.6(6) . . ?
F431 C431 C432 118.9(7) . . ?
F431 C431 C430 118.8(5) . . ?
C432 C431 C430 122.2(7) . . ?
C433 C432 F432 120.7(6) . . ?
C433 C432 C431 119.6(8) . . ?
F432 C432 C431 119.6(8) . . ?
C432 C433 F433 119.3(8) . . ?
C432 C433 C434 121.7(6) . . ?
F433 C433 C434 119.0(8) . . ?
F434 C434 C435 120.7(8) . . ?
F434 C434 C433 121.6(7) . . ?
C435 C434 C433 117.7(7) . . ?
F435 C435 C430 118.9(6) . . ?
F435 C435 C434 118.2(7) . . ?
C430 C435 C434 122.7(7) . . ?
F3 B1 F4 110.6(7) . . ?
F3 B1 F1 110.8(7) . . ?
F4 B1 F1 109.6(7) . . ?
F3 B1 F2 107.6(7) . . ?
F4 B1 F2 106.3(6) . . ?
F1 B1 F2 111.7(7) . . ?
F6 B2 F8 109.9(7) . . ?
F6 B2 F5 109.6(7) . . ?
F8 B2 F5 109.0(6) . . ?
F6 B2 F7 109.9(6) . . ?
F8 B2 F7 109.7(6) . . ?
F5 B2 F7 108.8(6) . . ?
F9 B3 F12 110.4(5) . . ?
F9 B3 F11 109.5(6) . . ?
F12 B3 F11 110.4(6) . . ?
F9 B3 F10 108.2(6) . . ?
F12 B3 F10 109.5(5) . . ?
F11 B3 F10 109.0(5) . . ?
Cl2B C1 Cl1 115.1(5) . . ?
Cl1 C1 Cl2A 109.8(4) . . ?
Cl1 C1 H13A 109.7 . . ?
Cl2A C1 H13A 109.7 . . ?
Cl1 C1 H13B 109.7 . . ?
Cl2A C1 H13B 109.7 . . ?
H13A C1 H13B 108.2 . . ?
Cl4 C2 Cl3 111.0(5) . . ?
Cl4 C2 H2C 109.4 . . ?
Cl3 C2 H2C 109.4 . . ?
Cl4 C2 H2D 109.4 . . ?
Cl3 C2 H2D 109.4 . . ?
H2C C2 H2D 108.0 . . ?
Cl6 C3 Cl5 112.6(5) . . ?
Cl6 C3 H3E 109.1 . . ?
Cl5 C3 H3E 109.1 . . ?
Cl6 C3 H3F 109.1 . . ?
Cl5 C3 H3F 109.1 . . ?
H3E C3 H3F 107.8 . . ?
Cl7 C4 Cl8 112.2(5) . . ?
Cl7 C4 H4G 109.2 . . ?
Cl8 C4 H4G 109.2 . . ?
Cl7 C4 H4H 109.2 . . ?
Cl8 C4 H4H 109.2 . . ?
H4G C4 H4H 107.9 . . ?
Cl10 C5 Cl9 112.3(4) . . ?
Cl10 C5 H5A 109.1 . . ?
Cl9 C5 H5A 109.1 . . ?
Cl10 C5 H5B 109.1 . . ?
Cl9 C5 H5B 109.1 . . ?
H5A C5 H5B 107.9 . . ?
Cl12 C6 Cl11 112.2(5) . . ?
Cl12 C6 H6C 109.2 . . ?
Cl11 C6 H6C 109.2 . . ?
Cl12 C6 H6D 109.2 . . ?
Cl11 C6 H6D 109.2 . . ?
H6C C6 H6D 107.9 . . ?
Cl13 C7 Cl14 111.7(5) . . ?
Cl13 C7 H7E 109.3 . . ?
Cl14 C7 H7E 109.3 . . ?
Cl13 C7 H7F 109.3 . . ?
Cl14 C7 H7F 109.3 . . ?
H7E C7 H7F 107.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C121 1.956(5) . ?
Pt1 C129 1.961(6) . ?
Pt1 N101 2.059(5) . ?
Pt1 N111 2.064(4) . ?
Pt1 Cu1 2.9597(7) . ?
N101 C106 1.339(7) . ?
N101 C102 1.352(6) . ?
C102 C103 1.387(7) . ?
C102 C112 1.474(7) . ?
C103 C104 1.377(8) . ?
C103 H103 0.9500 . ?
C104 C105 1.406(8) . ?
C104 C107 1.511(8) . ?
C105 C106 1.365(8) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C107 C108 1.517(8) . ?
C107 C109 1.524(9) . ?
C107 C110 1.530(10) . ?
C108 H10A 0.9800 . ?
C108 H10B 0.9800 . ?
C108 H10C 0.9800 . ?
C109 H10D 0.9800 . ?
C109 H10E 0.9800 . ?
C109 H10F 0.9800 . ?
C110 H10G 0.9800 . ?
C110 H10H 0.9800 . ?
C110 H10I 0.9800 . ?
N111 C116 1.332(7) . ?
N111 C112 1.349(6) . ?
C112 C113 1.389(7) . ?
C113 C114 1.396(8) . ?
C113 H113 0.9500 . ?
C114 C115 1.380(8) . ?
C114 C117 1.528(7) . ?
C115 C116 1.387(7) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C117 C120 1.510(9) . ?
C117 C118 1.526(9) . ?
C117 C119 1.527(9) . ?
C118 H11A 0.9800 . ?
C118 H11B 0.9800 . ?
C118 H11C 0.9800 . ?
C119 H11D 0.9800 . ?
C119 H11E 0.9800 . ?
C119 H11F 0.9800 . ?
C120 H11G 0.9800 . ?
C120 H11H 0.9800 . ?
C120 H11I 0.9800 . ?
C121 C122 1.222(7) . ?
C121 Cu1 2.149(5) . ?
C122 C123 1.437(8) . ?
C122 Cu1 2.310(6) . ?
C123 C128 1.399(8) . ?
C123 C124 1.407(7) . ?
C124 C125 1.373(8) . ?
C124 H124 0.9500 . ?
C125 C126 1.409(9) . ?
C125 H125 0.9500 . ?
C126 C127 1.372(9) . ?
C126 H126 0.9500 . ?
C127 C128 1.402(8) . ?
C127 H127 0.9500 . ?
C128 H128 0.9500 . ?
C129 C130 1.198(8) . ?
C129 Cu1 2.200(5) . ?
C130 C131 1.426(8) . ?
C130 Cu1 2.384(6) . ?
C131 C136 1.386(7) . ?
C131 C132 1.407(8) . ?
C132 F132 1.344(6) . ?
C132 C133 1.378(8) . ?
C133 F133 1.330(7) . ?
C133 C134 1.379(8) . ?
C134 F134 1.337(7) . ?
C134 C135 1.371(9) . ?
C135 F135 1.339(6) . ?
C135 C136 1.369(8) . ?
C136 F136 1.343(6) . ?
Cu1 C230 2.071(5) . ?
Cu1 C229 2.108(5) . ?
Pt2 C229 1.949(5) . ?
Pt2 C221 1.981(5) . ?
Pt2 N211 2.047(4) . ?
Pt2 N201 2.055(4) . ?
Pt2 Cu2 2.9880(7) . ?
N201 C206 1.346(6) . ?
N201 C202 1.356(6) . ?
C202 C203 1.382(7) . ?
C202 C212 1.471(7) . ?
C203 C204 1.407(7) . ?
C203 H203 0.9500 . ?
C204 C205 1.391(8) . ?
C204 C207 1.500(8) . ?
C205 C206 1.360(8) . ?
C205 H205 0.9500 . ?
C206 H206 0.9500 . ?
C207 C209 1.517(9) . ?
C207 C208 1.520(9) . ?
C207 C210 1.551(8) . ?
C208 H20A 0.9800 . ?
C208 H20B 0.9800 . ?
C208 H20C 0.9800 . ?
C209 H20D 0.9800 . ?
C209 H20E 0.9800 . ?
C209 H20F 0.9800 . ?
C210 H20G 0.9800 . ?
C210 H20H 0.9800 . ?
C210 H20I 0.9800 . ?
N211 C216 1.338(6) . ?
N211 C212 1.350(6) . ?
C212 C213 1.379(7) . ?
C213 C214 1.413(7) . ?
C213 H213 0.9500 . ?
C214 C215 1.379(7) . ?
C214 C217 1.526(7) . ?
C215 C216 1.385(7) . ?
C215 H215 0.9500 . ?
C216 H216 0.9500 . ?
C217 C220 1.533(9) . ?
C217 C218 1.535(9) . ?
C217 C219 1.539(8) . ?
C218 H21A 0.9800 . ?
C218 H21B 0.9800 . ?
C218 H21C 0.9800 . ?
C219 H21D 0.9800 . ?
C219 H21E 0.9800 . ?
C219 H21F 0.9800 . ?
C220 H21G 0.9800 . ?
C220 H21H 0.9800 . ?
C220 H21I 0.9800 . ?
C221 C222 1.201(7) . ?
C221 Cu2 2.003(6) . ?
C222 C223 1.452(7) . ?
C222 Cu2 2.095(5) . ?
C223 C228 1.386(8) . ?
C223 C224 1.398(9) . ?
C224 C225 1.392(8) . ?
C224 H224 0.9500 . ?
C225 C226 1.407(9) . ?
C225 H225 0.9500 . ?
C226 C227 1.380(9) . ?
C226 H226 0.9500 . ?
C227 C228 1.370(8) . ?
C227 H227 0.9500 . ?
C228 H228 0.9500 . ?
C229 C230 1.230(7) . ?
C230 C231 1.426(7) . ?
C231 C236 1.380(7) . ?
C231 C232 1.401(7) . ?
C232 F232 1.342(7) . ?
C232 C233 1.365(8) . ?
C233 F233 1.344(6) . ?
C233 C234 1.377(9) . ?
C234 F234 1.330(7) . ?
C234 C235 1.388(9) . ?
C235 F235 1.332(7) . ?
C235 C236 1.384(8) . ?
C236 F236 1.341(6) . ?
Cu2 C321 1.997(5) . ?
Cu2 C322 2.164(5) . ?
Cu2 Pt3 2.8206(7) . ?
Pt3 C329 1.965(5) . ?
Pt3 C321 1.977(5) . ?
Pt3 N311 2.039(4) . ?
Pt3 N301 2.041(4) . ?
N301 C306 1.341(7) . ?
N301 C302 1.358(7) . ?
C302 C303 1.381(7) . ?
C302 C312 1.475(7) . ?
C303 C304 1.390(7) . ?
C303 H303 0.9500 . ?
C304 C305 1.392(7) . ?
C304 C307 1.534(7) . ?
C305 C306 1.378(7) . ?
C305 H305 0.9500 . ?
C306 H306 0.9500 . ?
C307 C310 1.529(8) . ?
C307 C309 1.533(8) . ?
C307 C308 1.547(8) . ?
C308 H30A 0.9800 . ?
C308 H30B 0.9800 . ?
C308 H30C 0.9800 . ?
C309 H30D 0.9800 . ?
C309 H30E 0.9800 . ?
C309 H30F 0.9800 . ?
C310 H30G 0.9800 . ?
C310 H30H 0.9800 . ?
C310 H30I 0.9800 . ?
N311 C316 1.348(7) . ?
N311 C312 1.361(6) . ?
C312 C313 1.380(7) . ?
C313 C314 1.397(7) . ?
C313 H313 0.9500 . ?
C314 C315 1.393(7) . ?
C314 C317 1.524(8) . ?
C315 C316 1.379(7) . ?
C315 H315 0.9500 . ?
C316 H316 0.9500 . ?
C317 C320 1.518(9) . ?
C317 C319 1.532(8) . ?
C317 C318 1.546(10) . ?
C318 H31A 0.9800 . ?
C318 H31B 0.9800 . ?
C318 H31C 0.9800 . ?
C319 H31D 0.9800 . ?
C319 H31E 0.9800 . ?
C319 H31F 0.9800 . ?
C320 H31G 0.9800 . ?
C320 H31H 0.9800 . ?
C320 H31I 0.9800 . ?
C321 C322 1.213(8) . ?
C322 C323 1.459(7) . ?
C323 C328 1.390(8) . ?
C323 C324 1.414(7) . ?
C324 C325 1.384(8) . ?
C324 H324 0.9500 . ?
C325 C326 1.380(9) . ?
C325 H325 0.9500 . ?
C326 C327 1.396(9) . ?
C326 H326 0.9500 . ?
C327 C328 1.382(8) . ?
C327 H327 0.9500 . ?
C328 H328 0.9500 . ?
C329 C330 1.212(8) . ?
C329 Cu3 2.084(5) . ?
C330 C331 1.440(8) . ?
C330 Cu3 2.071(5) . ?
C331 C336 1.379(9) . ?
C331 C332 1.396(8) . ?
C332 F332 1.337(8) . ?
C332 C333 1.362(8) . ?
C333 F333 1.348(8) . ?
C333 C334 1.378(11) . ?
C334 F334 1.355(7) . ?
C334 C335 1.362(11) . ?
C335 F335 1.317(8) . ?
C335 C336 1.373(9) . ?
C336 F336 1.343(8) . ?
Cu3 C420 2.155(5) . ?
Cu3 C428 2.216(5) . ?
Cu3 C421 2.270(5) . ?
Cu3 C429 2.381(6) . ?
Cu3 Pt4 2.9835(7) . ?
Pt4 C428 1.956(6) . ?
Pt4 C420 1.958(5) . ?
Pt4 N411 2.049(4) . ?
Pt4 N401 2.051(4) . ?
N401 C406 1.343(6) . ?
N401 C402 1.349(7) . ?
C402 C403 1.377(7) . ?
C402 C411 1.477(7) . ?
C403 C404 1.405(7) . ?
C403 H403 0.9500 . ?
C404 C405 1.375(8) . ?
C404 C407 1.506(8) . ?
C405 C406 1.398(7) . ?
C405 H405 0.9500 . ?
C406 H406 0.9500 . ?
C407 C410 1.541(8) . ?
C407 C408 1.546(8) . ?
C407 C409 1.548(9) . ?
C408 H40A 0.9800 . ?
C408 H40B 0.9800 . ?
C408 H40C 0.9800 . ?
C409 H40D 0.9800 . ?
C409 H40E 0.9800 . ?
C409 H40F 0.9800 . ?
C410 H40G 0.9800 . ?
C410 H40H 0.9800 . ?
C410 H40I 0.9800 . ?
N411 C415 1.334(7) . ?
N411 C411 1.359(7) . ?
C411 C412 1.379(8) . ?
C412 C413 1.409(7) . ?
C412 H412 0.9500 . ?
C413 C414 1.380(8) . ?
C413 C416 1.516(9) . ?
C414 C415 1.370(8) . ?
C414 H414 0.9500 . ?
C415 H415 0.9500 . ?
C416 C418 1.508(8) . ?
C416 C417 1.518(10) . ?
C416 C419 1.568(10) . ?
C417 H41A 0.9800 . ?
C417 H41B 0.9800 . ?
C417 H41C 0.9800 . ?
C418 H41D 0.9800 . ?
C418 H41E 0.9800 . ?
C418 H41F 0.9800 . ?
C419 H41G 0.9800 . ?
C419 H41H 0.9800 . ?
C419 H41I 0.9800 . ?
C420 C421 1.205(8) . ?
C421 C422 1.449(8) . ?
C422 C423 1.396(8) . ?
C422 C427 1.403(7) . ?
C423 C424 1.394(8) . ?
C423 H423 0.9500 . ?
C424 C425 1.365(10) . ?
C424 H424 0.9500 . ?
C425 C426 1.387(10) . ?
C425 H425 0.9500 . ?
C426 C427 1.383(8) . ?
C426 H426 0.9500 . ?
C427 H427 0.9500 . ?
C428 C429 1.203(8) . ?
C429 C430 1.415(8) . ?
C430 C435 1.381(10) . ?
C430 C431 1.409(9) . ?
C431 F431 1.334(8) . ?
C431 C432 1.361(8) . ?
C432 C433 1.347(13) . ?
C432 F432 1.358(9) . ?
C433 F433 1.347(7) . ?
C433 C434 1.387(12) . ?
C434 F434 1.326(9) . ?
C434 C435 1.386(9) . ?
C435 F435 1.359(8) . ?
B1 F3 1.370(9) . ?
B1 F4 1.372(9) . ?
B1 F1 1.392(9) . ?
B1 F2 1.422(11) . ?
B2 F6 1.352(9) . ?
B2 F8 1.371(9) . ?
B2 F5 1.382(9) . ?
B2 F7 1.402(8) . ?
B3 F9 1.379(8) . ?
B3 F12 1.385(7) . ?
B3 F11 1.389(8) . ?
B3 F10 1.400(8) . ?
C1 Cl2B 1.638(10) . ?
C1 Cl1 1.766(7) . ?
C1 Cl2A 1.812(8) . ?
C1 H13A 0.9900 . ?
C1 H13B 0.9900 . ?
C2 Cl4 1.752(8) . ?
C2 Cl3 1.767(8) . ?
C2 H2C 0.9900 . ?
C2 H2D 0.9900 . ?
C3 Cl6 1.747(11) . ?
C3 Cl5 1.763(12) . ?
C3 H3E 0.9900 . ?
C3 H3F 0.9900 . ?
C4 Cl7 1.757(10) . ?
C4 Cl8 1.759(9) . ?
C4 H4G 0.9900 . ?
C4 H4H 0.9900 . ?
C5 Cl10 1.732(7) . ?
C5 Cl9 1.779(7) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 Cl12 1.750(7) . ?
C6 Cl11 1.751(8) . ?
C6 H6C 0.9900 . ?
C6 H6D 0.9900 . ?
C7 Cl13 1.748(8) . ?
C7 Cl14 1.783(10) . ?
C7 H7E 0.9900 . ?
C7 H7F 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C106 N101 C102 C103 0.5(8) . . . . ?
Pt1 N101 C102 C103 -179.4(4) . . . . ?
C106 N101 C102 C112 -179.0(5) . . . . ?
Pt1 N101 C102 C112 1.1(6) . . . . ?
N101 C102 C103 C104 -1.5(8) . . . . ?
C112 C102 C103 C104 178.0(5) . . . . ?
C102 C103 C104 C105 2.2(8) . . . . ?
C102 C103 C104 C107 178.1(5) . . . . ?
C103 C104 C105 C106 -2.1(8) . . . . ?
C107 C104 C105 C106 -178.1(5) . . . . ?
C102 N101 C106 C105 -0.5(8) . . . . ?
Pt1 N101 C106 C105 179.4(4) . . . . ?
C104 C105 C106 N101 1.3(9) . . . . ?
C103 C104 C107 C108 11.6(8) . . . . ?
C105 C104 C107 C108 -172.7(6) . . . . ?
C103 C104 C107 C109 134.2(6) . . . . ?
C105 C104 C107 C109 -50.2(8) . . . . ?
C103 C104 C107 C110 -107.8(7) . . . . ?
C105 C104 C107 C110 67.9(7) . . . . ?
C116 N111 C112 C113 2.0(8) . . . . ?
Pt1 N111 C112 C113 179.5(4) . . . . ?
C116 N111 C112 C102 -179.0(5) . . . . ?
Pt1 N111 C112 C102 -1.5(6) . . . . ?
N101 C102 C112 N111 0.3(7) . . . . ?
C103 C102 C112 N111 -179.3(5) . . . . ?
N101 C102 C112 C113 179.2(5) . . . . ?
C103 C102 C112 C113 -0.3(9) . . . . ?
N111 C112 C113 C114 -1.3(8) . . . . ?
C102 C112 C113 C114 179.8(5) . . . . ?
C112 C113 C114 C115 -0.5(8) . . . . ?
C112 C113 C114 C117 -179.6(5) . . . . ?
C113 C114 C115 C116 1.5(8) . . . . ?
C117 C114 C115 C116 -179.4(5) . . . . ?
C112 N111 C116 C115 -1.0(8) . . . . ?
Pt1 N111 C116 C115 -178.2(4) . . . . ?
C114 C115 C116 N111 -0.9(9) . . . . ?
C115 C114 C117 C120 2.3(9) . . . . ?
C113 C114 C117 C120 -178.6(6) . . . . ?
C115 C114 C117 C118 120.6(7) . . . . ?
C113 C114 C117 C118 -60.3(7) . . . . ?
C115 C114 C117 C119 -119.6(7) . . . . ?
C113 C114 C117 C119 59.4(8) . . . . ?
Cu1 C121 C122 C123 -180(100) . . . . ?
C121 C122 C123 C128 -48(3) . . . . ?
Cu1 C122 C123 C128 132.4(5) . . . . ?
C121 C122 C123 C124 132(3) . . . . ?
Cu1 C122 C123 C124 -47.6(7) . . . . ?
C128 C123 C124 C125 0.5(8) . . . . ?
C122 C123 C124 C125 -179.4(5) . . . . ?
C123 C124 C125 C126 0.2(9) . . . . ?
C124 C125 C126 C127 -0.7(9) . . . . ?
C125 C126 C127 C128 0.5(9) . . . . ?
C124 C123 C128 C127 -0.7(8) . . . . ?
C122 C123 C128 C127 179.3(5) . . . . ?
C126 C127 C128 C123 0.2(9) . . . . ?
Cu1 C129 C130 C131 -147(3) . . . . ?
C129 C130 C131 C136 -175(3) . . . . ?
Cu1 C130 C131 C136 42.0(7) . . . . ?
C129 C130 C131 C132 10(3) . . . . ?
Cu1 C130 C131 C132 -133.0(5) . . . . ?
C136 C131 C132 F132 -176.1(5) . . . . ?
C130 C131 C132 F132 -0.8(8) . . . . ?
C136 C131 C132 C133 1.7(8) . . . . ?
C130 C131 C132 C133 177.0(5) . . . . ?
F132 C132 C133 F133 -0.4(8) . . . . ?
C131 C132 C133 F133 -178.2(5) . . . . ?
F132 C132 C133 C134 176.9(5) . . . . ?
C131 C132 C133 C134 -0.9(9) . . . . ?
F133 C133 C134 F134 -1.4(9) . . . . ?
C132 C133 C134 F134 -178.7(5) . . . . ?
F133 C133 C134 C135 177.1(5) . . . . ?
C132 C133 C134 C135 -0.2(9) . . . . ?
F134 C134 C135 F135 -1.1(9) . . . . ?
C133 C134 C135 F135 -179.5(5) . . . . ?
F134 C134 C135 C136 178.8(6) . . . . ?
C133 C134 C135 C136 0.4(9) . . . . ?
F135 C135 C136 F136 1.7(9) . . . . ?
C134 C135 C136 F136 -178.2(5) . . . . ?
F135 C135 C136 C131 -179.6(5) . . . . ?
C134 C135 C136 C131 0.5(9) . . . . ?
C132 C131 C136 F136 177.2(5) . . . . ?
C130 C131 C136 F136 2.0(9) . . . . ?
C132 C131 C136 C135 -1.5(9) . . . . ?
C130 C131 C136 C135 -176.7(6) . . . . ?
C206 N201 C202 C203 0.2(8) . . . . ?
Pt2 N201 C202 C203 178.0(4) . . . . ?
C206 N201 C202 C212 -177.1(5) . . . . ?
Pt2 N201 C202 C212 0.7(6) . . . . ?
N201 C202 C203 C204 0.4(8) . . . . ?
C212 C202 C203 C204 177.5(5) . . . . ?
C202 C203 C204 C205 -1.1(8) . . . . ?
C202 C203 C204 C207 -177.7(5) . . . . ?
C203 C204 C205 C206 1.3(8) . . . . ?
C207 C204 C205 C206 178.0(5) . . . . ?
C202 N201 C206 C205 0.0(8) . . . . ?
Pt2 N201 C206 C205 -177.6(4) . . . . ?
C204 C205 C206 N201 -0.8(9) . . . . ?
C205 C204 C207 C209 -63.0(8) . . . . ?
C203 C204 C207 C209 113.4(7) . . . . ?
C205 C204 C207 C208 175.2(6) . . . . ?
C203 C204 C207 C208 -8.4(9) . . . . ?
C205 C204 C207 C210 56.0(7) . . . . ?
C203 C204 C207 C210 -127.6(6) . . . . ?
C216 N211 C212 C213 -2.5(8) . . . . ?
Pt2 N211 C212 C213 175.8(4) . . . . ?
C216 N211 C212 C202 179.5(5) . . . . ?
Pt2 N211 C212 C202 -2.2(6) . . . . ?
N201 C202 C212 N211 1.0(7) . . . . ?
C203 C202 C212 N211 -176.3(5) . . . . ?
N201 C202 C212 C213 -176.9(5) . . . . ?
C203 C202 C212 C213 5.8(8) . . . . ?
N211 C212 C213 C214 2.0(8) . . . . ?
C202 C212 C213 C214 179.8(5) . . . . ?
C212 C213 C214 C215 -0.7(8) . . . . ?
C212 C213 C214 C217 -177.7(5) . . . . ?
C213 C214 C215 C216 0.1(8) . . . . ?
C217 C214 C215 C216 176.9(5) . . . . ?
C212 N211 C216 C215 1.8(8) . . . . ?
Pt2 N211 C216 C215 -176.3(4) . . . . ?
C214 C215 C216 N211 -0.7(9) . . . . ?
C215 C214 C217 C220 -106.8(6) . . . . ?
C213 C214 C217 C220 69.9(7) . . . . ?
C215 C214 C217 C218 134.3(6) . . . . ?
C213 C214 C217 C218 -49.0(7) . . . . ?
C215 C214 C217 C219 13.8(8) . . . . ?
C213 C214 C217 C219 -169.5(5) . . . . ?
Cu2 C222 C223 C228 78.5(6) . . . . ?
Cu2 C222 C223 C224 -97.5(5) . . . . ?
C228 C223 C224 C225 1.8(8) . . . . ?
C222 C223 C224 C225 178.0(5) . . . . ?
C223 C224 C225 C226 -1.7(9) . . . . ?
C224 C225 C226 C227 2.0(9) . . . . ?
C225 C226 C227 C228 -2.4(9) . . . . ?
C226 C227 C228 C223 2.6(9) . . . . ?
C224 C223 C228 C227 -2.2(8) . . . . ?
C222 C223 C228 C227 -178.3(5) . . . . ?
Cu1 C229 C230 C231 161.1(19) . . . . ?
C229 C230 C231 C236 133.5(18) . . . . ?
Cu1 C230 C231 C236 -68.0(7) . . . . ?
C229 C230 C231 C232 -49(2) . . . . ?
Cu1 C230 C231 C232 109.7(5) . . . . ?
C236 C231 C232 F232 177.0(5) . . . . ?
C230 C231 C232 F232 -0.9(8) . . . . ?
C236 C231 C232 C233 0.8(8) . . . . ?
C230 C231 C232 C233 -177.1(5) . . . . ?
F232 C232 C233 F233 -1.1(9) . . . . ?
C231 C232 C233 F233 175.1(5) . . . . ?
F232 C232 C233 C234 -176.0(5) . . . . ?
C231 C232 C233 C234 0.2(9) . . . . ?
F233 C233 C234 F234 3.2(9) . . . . ?
C232 C233 C234 F234 178.3(6) . . . . ?
F233 C233 C234 C235 -176.4(6) . . . . ?
C232 C233 C234 C235 -1.3(9) . . . . ?
F234 C234 C235 F235 0.7(9) . . . . ?
C233 C234 C235 F235 -179.7(5) . . . . ?
F234 C234 C235 C236 -178.2(5) . . . . ?
C233 C234 C235 C236 1.4(9) . . . . ?
C232 C231 C236 F236 178.3(5) . . . . ?
C230 C231 C236 F236 -3.8(8) . . . . ?
C232 C231 C236 C235 -0.7(8) . . . . ?
C230 C231 C236 C235 177.2(5) . . . . ?
F235 C235 C236 F236 1.7(8) . . . . ?
C234 C235 C236 F236 -179.4(5) . . . . ?
F235 C235 C236 C231 -179.3(5) . . . . ?
C234 C235 C236 C231 -0.4(9) . . . . ?
C306 N301 C302 C303 -0.2(8) . . . . ?
Pt3 N301 C302 C303 179.2(4) . . . . ?
C306 N301 C302 C312 -179.8(5) . . . . ?
Pt3 N301 C302 C312 -0.4(6) . . . . ?
N301 C302 C303 C304 -1.2(8) . . . . ?
C312 C302 C303 C304 178.4(5) . . . . ?
C302 C303 C304 C305 0.8(8) . . . . ?
C302 C303 C304 C307 -176.5(5) . . . . ?
C303 C304 C305 C306 0.9(8) . . . . ?
C307 C304 C305 C306 178.2(5) . . . . ?
C302 N301 C306 C305 1.9(8) . . . . ?
Pt3 N301 C306 C305 -177.4(4) . . . . ?
C304 C305 C306 N301 -2.2(9) . . . . ?
C303 C304 C307 C310 -11.9(7) . . . . ?
C305 C304 C307 C310 171.0(5) . . . . ?
C303 C304 C307 C309 108.7(6) . . . . ?
C305 C304 C307 C309 -68.5(6) . . . . ?
C303 C304 C307 C308 -131.9(6) . . . . ?
C305 C304 C307 C308 50.9(7) . . . . ?
C316 N311 C312 C313 2.7(8) . . . . ?
Pt3 N311 C312 C313 -177.0(4) . . . . ?
C316 N311 C312 C302 -178.9(5) . . . . ?
Pt3 N311 C312 C302 1.4(6) . . . . ?
N301 C302 C312 N311 -0.6(7) . . . . ?
C303 C302 C312 N311 179.8(5) . . . . ?
N301 C302 C312 C313 177.7(5) . . . . ?
C303 C302 C312 C313 -1.9(9) . . . . ?
N311 C312 C313 C314 -0.7(8) . . . . ?
C302 C312 C313 C314 -178.9(5) . . . . ?
C312 C313 C314 C315 -1.1(8) . . . . ?
C312 C313 C314 C317 177.6(5) . . . . ?
C313 C314 C315 C316 1.0(9) . . . . ?
C317 C314 C315 C316 -177.8(5) . . . . ?
C312 N311 C316 C315 -2.9(8) . . . . ?
Pt3 N311 C316 C315 176.8(4) . . . . ?
C314 C315 C316 N311 1.1(9) . . . . ?
C315 C314 C317 C320 49.2(8) . . . . ?
C313 C314 C317 C320 -129.5(7) . . . . ?
C315 C314 C317 C319 171.6(6) . . . . ?
C313 C314 C317 C319 -7.1(9) . . . . ?
C315 C314 C317 C318 -69.4(7) . . . . ?
C313 C314 C317 C318 111.9(7) . . . . ?
Pt3 C321 C322 Cu2 41(2) . . . . ?
Cu2 C322 C323 C328 110.4(5) . . . . ?
Cu2 C322 C323 C324 -69.6(6) . . . . ?
C328 C323 C324 C325 1.8(8) . . . . ?
C322 C323 C324 C325 -178.2(5) . . . . ?
C323 C324 C325 C326 -0.3(9) . . . . ?
C324 C325 C326 C327 0.4(9) . . . . ?
C325 C326 C327 C328 -1.9(9) . . . . ?
C326 C327 C328 C323 3.4(9) . . . . ?
C324 C323 C328 C327 -3.3(8) . . . . ?
C322 C323 C328 C327 176.7(5) . . . . ?
Cu3 C329 C330 C331 165(2) . . . . ?
C329 C330 C331 C336 -48(2) . . . . ?
Cu3 C330 C331 C336 115.1(6) . . . . ?
C329 C330 C331 C332 135(2) . . . . ?
Cu3 C330 C331 C332 -62.0(7) . . . . ?
C336 C331 C332 F332 178.3(6) . . . . ?
C330 C331 C332 F332 -4.4(9) . . . . ?
C336 C331 C332 C333 -1.2(10) . . . . ?
C330 C331 C332 C333 176.1(6) . . . . ?
F332 C332 C333 F333 -0.2(10) . . . . ?
C331 C332 C333 F333 179.3(6) . . . . ?
F332 C332 C333 C334 179.9(6) . . . . ?
C331 C332 C333 C334 -0.6(11) . . . . ?
F333 C333 C334 F334 1.5(10) . . . . ?
C332 C333 C334 F334 -178.6(6) . . . . ?
F333 C333 C334 C335 -176.6(7) . . . . ?
C332 C333 C334 C335 3.2(11) . . . . ?
F334 C334 C335 F335 -0.3(11) . . . . ?
C333 C334 C335 F335 177.9(7) . . . . ?
F334 C334 C335 C336 177.9(6) . . . . ?
C333 C334 C335 C336 -4.0(11) . . . . ?
F335 C335 C336 F336 1.1(12) . . . . ?
C334 C335 C336 F336 -177.0(7) . . . . ?
F335 C335 C336 C331 -179.7(7) . . . . ?
C334 C335 C336 C331 2.2(12) . . . . ?
C332 C331 C336 F336 179.5(6) . . . . ?
C330 C331 C336 F336 2.3(10) . . . . ?
C332 C331 C336 C335 0.4(11) . . . . ?
C330 C331 C336 C335 -176.9(7) . . . . ?
C406 N401 C402 C403 -1.9(8) . . . . ?
Pt4 N401 C402 C403 178.3(4) . . . . ?
C406 N401 C402 C411 176.5(5) . . . . ?
Pt4 N401 C402 C411 -3.3(6) . . . . ?
N401 C402 C403 C404 1.6(9) . . . . ?
C411 C402 C403 C404 -176.7(5) . . . . ?
C402 C403 C404 C405 -0.6(9) . . . . ?
C402 C403 C404 C407 -177.2(5) . . . . ?
C403 C404 C405 C406 -0.1(9) . . . . ?
C407 C404 C405 C406 176.4(5) . . . . ?
C402 N401 C406 C405 1.3(8) . . . . ?
Pt4 N401 C406 C405 -179.0(4) . . . . ?
C404 C405 C406 N401 -0.3(9) . . . . ?
C405 C404 C407 C410 8.9(9) . . . . ?
C403 C404 C407 C410 -174.7(6) . . . . ?
C405 C404 C407 C408 129.5(6) . . . . ?
C403 C404 C407 C408 -54.1(7) . . . . ?
C405 C404 C407 C409 -111.8(7) . . . . ?
C403 C404 C407 C409 64.6(7) . . . . ?
C415 N411 C411 C412 2.1(8) . . . . ?
Pt4 N411 C411 C412 179.2(4) . . . . ?
C415 N411 C411 C402 -176.9(5) . . . . ?
Pt4 N411 C411 C402 0.1(6) . . . . ?
N401 C402 C411 N411 2.1(7) . . . . ?
C403 C402 C411 N411 -179.5(5) . . . . ?
N401 C402 C411 C412 -176.9(5) . . . . ?
C403 C402 C411 C412 1.5(9) . . . . ?
N411 C411 C412 C413 -1.2(9) . . . . ?
C402 C411 C412 C413 177.8(5) . . . . ?
C411 C412 C413 C414 0.8(9) . . . . ?
C411 C412 C413 C416 -179.0(6) . . . . ?
C412 C413 C414 C415 -1.3(9) . . . . ?
C416 C413 C414 C415 178.4(6) . . . . ?
C411 N411 C415 C414 -2.7(9) . . . . ?
Pt4 N411 C415 C414 -179.4(4) . . . . ?
C413 C414 C415 N411 2.4(10) . . . . ?
C414 C413 C416 C418 0.4(9) . . . . ?
C412 C413 C416 C418 -179.9(6) . . . . ?
C414 C413 C416 C417 -120.5(7) . . . . ?
C412 C413 C416 C417 59.2(8) . . . . ?
C414 C413 C416 C419 120.3(7) . . . . ?
C412 C413 C416 C419 -60.0(8) . . . . ?
Pt4 C420 C421 C422 -132(3) . . . . ?
Cu3 C420 C421 C422 -175(3) . . . . ?
Pt4 C420 C421 Cu3 43(3) . . . . ?
C420 C421 C422 C423 139(3) . . . . ?
Cu3 C421 C422 C423 -36.1(7) . . . . ?
C420 C421 C422 C427 -42(4) . . . . ?
Cu3 C421 C422 C427 143.1(5) . . . . ?
C427 C422 C423 C424 -0.2(9) . . . . ?
C421 C422 C423 C424 179.0(6) . . . . ?
C422 C423 C424 C425 0.3(10) . . . . ?
C423 C424 C425 C426 -0.4(11) . . . . ?
C424 C425 C426 C427 0.5(10) . . . . ?
C425 C426 C427 C422 -0.5(10) . . . . ?
C423 C422 C427 C426 0.3(9) . . . . ?
C421 C422 C427 C426 -178.9(6) . . . . ?
Cu3 C428 C429 C430 -153(2) . . . . ?
C428 C429 C430 C435 -167(2) . . . . ?
Cu3 C429 C430 C435 43.7(8) . . . . ?
C428 C429 C430 C431 13(3) . . . . ?
Cu3 C429 C430 C431 -136.0(5) . . . . ?
C435 C430 C431 F431 179.9(5) . . . . ?
C429 C430 C431 F431 -0.3(8) . . . . ?
C435 C430 C431 C432 -2.3(9) . . . . ?
C429 C430 C431 C432 177.5(6) . . . . ?
F431 C431 C432 C433 178.8(6) . . . . ?
C430 C431 C432 C433 1.0(10) . . . . ?
F431 C431 C432 F432 -1.7(9) . . . . ?
C430 C431 C432 F432 -179.4(5) . . . . ?
F432 C432 C433 F433 2.0(10) . . . . ?
C431 C432 C433 F433 -178.5(6) . . . . ?
F432 C432 C433 C434 -179.2(6) . . . . ?
C431 C432 C433 C434 0.3(11) . . . . ?
C432 C433 C434 F434 -178.8(6) . . . . ?
F433 C433 C434 F434 0.0(10) . . . . ?
C432 C433 C434 C435 -0.2(10) . . . . ?
F433 C433 C434 C435 178.5(6) . . . . ?
C431 C430 C435 F435 178.5(5) . . . . ?
C429 C430 C435 F435 -1.3(9) . . . . ?
C431 C430 C435 C434 2.4(9) . . . . ?
C429 C430 C435 C434 -177.4(6) . . . . ?
F434 C434 C435 F435 1.2(10) . . . . ?
C433 C434 C435 F435 -177.3(6) . . . . ?
F434 C434 C435 C430 177.3(6) . . . . ?
C433 C434 C435 C430 -1.2(10) . . . . ?
