#------------------------------------------------------------------------------
#$Date: 2022-10-05 00:56:31 +0300 (Wed, 05 Oct 2022) $
#$Revision: 278335 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/07/7130792.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7130792
loop_
_publ_author_name
'Huffman, Zachary K.'
'Sperling, Joseph M.'
'Windorff, Cory J.'
'Long, Brian N.'
'Cordova, Lucas'
'Ramanantoanina, Harry'
'Celis-Barros, Cristian'
'Albrecht-Schönzart, Thomas E.'
_publ_section_title
;
 Synthesis and characterization of a bimetallic americium(iii)
 pyrithionate coordination complex
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/D2CC03352F
_journal_year                    2022
_chemical_formula_moiety         'C15 H17 Lu N3 O5 S3, H2 O'
_chemical_formula_sum            'C15 H19 Lu N3 O6 S3'
_chemical_formula_weight         608.48
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2021-10-12
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2022-06-14 deposited with the CCDC.	2022-09-15 downloaded from the CCDC.
;
_cell_angle_alpha                111.325(2)
_cell_angle_beta                 94.072(2)
_cell_angle_gamma                91.141(2)
_cell_formula_units_Z            2
_cell_length_a                   7.4092(3)
_cell_length_b                   11.0676(5)
_cell_length_c                   13.0778(6)
_cell_measurement_reflns_used    9959
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      2.760
_cell_volume                     995.25(8)
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      273.15
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0548
_diffrn_reflns_av_unetI/netI     0.0190
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            72598
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.562
_diffrn_reflns_theta_min         2.759
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.312
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.4498
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1220 before and 0.0712 after correction. The Ratio of minimum to maximum transmission is 0.6033. The λ/2 correction factor is Not present.'
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.030
_exptl_crystal_description       block
_exptl_crystal_F_000             594
_exptl_crystal_size_max          0.465
_exptl_crystal_size_mid          0.248
_exptl_crystal_size_min          0.166
_refine_diff_density_max         0.910
_refine_diff_density_min         -0.664
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     264
_refine_ls_number_reflns         4577
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0194
_refine_ls_R_factor_gt           0.0167
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0173P)²+0.9843P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0393
_refine_ls_wR_factor_ref         0.0408
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4314
_reflns_number_total             4577
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2cc03352f2.cif
_cod_data_source_block           a
_cod_database_code               7130792
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.473
_shelx_estimated_absorpt_t_min   0.191
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 Lu1-H5A \\sim Lu1-H5B
 with sigma of 0.02
3.a Free rotating group:
 O5(H5A,H5B), O6(H6A,H6B)
3.b Rotating group:
 O4(H4A,H4B)
3.c Aromatic/amide H refined with riding coordinates:
 C10(H10), C15(H15), C5(H5), C14(H14), C12(H12), C9(H9A), C7(H7), C13(H13),
 C8(H8), C2(H2), C4(H4), C3(H3)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Lu1 Lu 0.72465(2) 0.28436(2) 0.37186(2) 0.02002(4) Uani 1 1 d D . . . .
S3 S 0.52929(9) 0.05861(7) 0.22635(6) 0.03529(15) Uani 1 1 d . . . . .
S1 S 0.68764(11) 0.30537(7) 0.16907(5) 0.03664(15) Uani 1 1 d . . . . .
S2 S 0.73172(12) 0.13721(6) 0.50308(6) 0.03896(16) Uani 1 1 d . . . . .
O2 O 0.7638(3) 0.41360(17) 0.55487(14) 0.0295(4) Uani 1 1 d . . . . .
O1 O 0.7002(2) 0.49798(16) 0.38938(14) 0.0266(4) Uani 1 1 d . . . . .
O4 O 0.4255(2) 0.31183(18) 0.41376(17) 0.0323(4) Uani 1 1 d . . . . .
H4A H 0.381319 0.242449 0.418057 0.048 Uiso 1 1 d R U . . .
H4B H 0.422267 0.368565 0.478229 0.048 Uiso 1 1 d R U . . .
O3 O 0.9122(2) 0.12190(17) 0.28876(15) 0.0323(4) Uani 1 1 d . . . . .
O5 O 1.0220(2) 0.36383(18) 0.38660(18) 0.0345(4) Uani 1 1 d G . . . .
H5A H 1.065348 0.441713 0.412509 0.052 Uiso 1 1 d DG U . . .
H5B H 1.108510 0.319421 0.355509 0.052 Uiso 1 1 d DG U . . .
O6 O 0.2237(3) 0.1065(2) 0.4110(2) 0.0396(5) Uani 1 1 d G . . . .
H6A H 0.112751 0.096848 0.386864 0.059 Uiso 1 1 d G U . . .
H6B H 0.237481 0.049821 0.440390 0.059 Uiso 1 1 d G U . . .
N3 N 0.8772(3) 0.02533(19) 0.19084(17) 0.0270(4) Uani 1 1 d . . . . .
N2 N 0.7201(3) 0.3819(2) 0.64050(17) 0.0253(4) Uani 1 1 d . . . . .
N1 N 0.7568(3) 0.5446(2) 0.31485(17) 0.0253(4) Uani 1 1 d . . . . .
C11 C 0.7014(4) -0.0124(2) 0.1498(2) 0.0293(5) Uani 1 1 d . . . . .
C10 C 0.6956(4) 0.4796(3) 0.7355(2) 0.0336(6) Uani 1 1 d . . . . .
H10 H 0.706794 0.565089 0.739499 0.040 Uiso 1 1 calc R U . . .
C15 C 1.0211(4) -0.0315(3) 0.1375(2) 0.0358(6) Uani 1 1 d . . . . .
H15 H 1.137954 -0.003911 0.169753 0.043 Uiso 1 1 calc R U . . .
C1 C 0.7605(4) 0.4640(3) 0.2075(2) 0.0300(5) Uani 1 1 d . . . . .
C6 C 0.7011(3) 0.2538(3) 0.6276(2) 0.0286(5) Uani 1 1 d . . . . .
C5 C 0.8077(4) 0.6723(3) 0.3507(3) 0.0377(6) Uani 1 1 d . . . . .
H5 H 0.804507 0.723690 0.424702 0.045 Uiso 1 1 calc R U . . .
C14 C 0.9957(5) -0.1290(3) 0.0368(3) 0.0463(8) Uani 1 1 d . . . . .
H14 H 1.094233 -0.169203 0.000511 0.056 Uiso 1 1 calc R U . . .
C12 C 0.6780(5) -0.1109(3) 0.0449(2) 0.0429(7) Uani 1 1 d . . . . .
H12 H 0.561193 -0.138401 0.012505 0.052 Uiso 1 1 calc R U . . .
C9 C 0.6542(4) 0.4544(3) 0.8265(2) 0.0405(7) Uani 1 1 d . . . . .
H9A H 0.640199 0.522139 0.892636 0.049 Uiso 1 1 calc R U . . .
C7 C 0.6553(4) 0.2282(3) 0.7206(3) 0.0417(7) Uani 1 1 d . . . . .
H7 H 0.639303 0.142565 0.715448 0.050 Uiso 1 1 calc R U . . .
C13 C 0.8209(6) -0.1672(3) -0.0104(3) 0.0516(9) Uani 1 1 d . . . . .
H13 H 0.801281 -0.231410 -0.080246 0.062 Uiso 1 1 calc R U . . .
C8 C 0.6336(5) 0.3267(4) 0.8183(3) 0.0447(7) Uani 1 1 d . . . . .
H8 H 0.605190 0.307761 0.879214 0.054 Uiso 1 1 calc R U . . .
C2 C 0.8216(4) 0.5207(4) 0.1352(3) 0.0454(7) Uani 1 1 d . . . . .
H2 H 0.828235 0.468897 0.061570 0.054 Uiso 1 1 calc R U . . .
C4 C 0.8637(5) 0.7261(3) 0.2790(3) 0.0505(8) Uani 1 1 d . . . . .
H4 H 0.896752 0.814203 0.303636 0.061 Uiso 1 1 calc R U . . .
C3 C 0.8711(5) 0.6489(4) 0.1698(3) 0.0541(9) Uani 1 1 d . . . . .
H3 H 0.909639 0.684416 0.120167 0.065 Uiso 1 1 calc R U . . .
H9B H 0.59(3) 0.32(2) 0.791(17) 0.53(13) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Lu Lu -0.4720 5.8584 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 Lu1 S3 72.72(2) . . ?
S1 Lu1 S2 151.12(2) . . ?
S2 Lu1 S3 80.40(2) . . ?
O2 Lu1 S3 141.21(4) . . ?
O2 Lu1 S1 139.97(4) . . ?
O2 Lu1 S2 68.86(4) . . ?
O2 Lu1 O1 71.01(6) . . ?
O2 Lu1 O4 79.37(7) . . ?
O2 Lu1 O5 78.68(7) . . ?
O1 Lu1 S3 130.01(5) . . ?
O1 Lu1 S1 69.25(4) . . ?
O1 Lu1 S2 138.92(4) . . ?
O1 Lu1 O4 80.33(6) . . ?
O1 Lu1 O5 75.37(7) . . ?
O4 Lu1 S3 74.32(5) . . ?
O4 Lu1 S1 98.34(5) . . ?
O4 Lu1 S2 84.09(5) . . ?
O4 Lu1 O5 151.43(7) . . ?
O3 Lu1 S3 68.09(5) . . ?
O3 Lu1 S1 83.91(5) . . ?
O3 Lu1 S2 76.30(5) . . ?
O3 Lu1 O2 123.33(7) . . ?
O3 Lu1 O1 135.76(7) . . ?
O3 Lu1 O4 139.82(7) . . ?
O3 Lu1 O5 68.50(6) . . ?
O5 Lu1 S3 133.51(5) . . ?
O5 Lu1 S1 86.99(6) . . ?
O5 Lu1 S2 104.62(6) . . ?
C11 S3 Lu1 98.14(9) . . ?
C1 S1 Lu1 98.56(9) . . ?
C6 S2 Lu1 100.47(9) . . ?
N2 O2 Lu1 126.81(14) . . ?
N1 O1 Lu1 122.82(13) . . ?
Lu1 O4 H4A 109.5 . . ?
Lu1 O4 H4B 109.2 . . ?
H4A O4 H4B 104.5 . . ?
N3 O3 Lu1 126.39(14) . . ?
Lu1 O5 H5A 129.7 . . ?
Lu1 O5 H5B 125.0 . . ?
H5A O5 H5B 104.5 . . ?
H6A O6 H6B 104.5 . . ?
O3 N3 C11 119.7(2) . . ?
O3 N3 C15 117.2(2) . . ?
C15 N3 C11 123.1(2) . . ?
O2 N2 C6 119.5(2) . . ?
C10 N2 O2 117.5(2) . . ?
C10 N2 C6 123.0(2) . . ?
O1 N1 C1 120.0(2) . . ?
O1 N1 C5 117.5(2) . . ?
C5 N1 C1 122.5(2) . . ?
N3 C11 S3 119.71(19) . . ?
N3 C11 C12 115.7(3) . . ?
C12 C11 S3 124.6(2) . . ?
N2 C10 H10 119.7 . . ?
N2 C10 C9 120.6(3) . . ?
C9 C10 H10 119.7 . . ?
N3 C15 H15 119.8 . . ?
N3 C15 C14 120.4(3) . . ?
C14 C15 H15 119.8 . . ?
N1 C1 S1 119.20(19) . . ?
N1 C1 C2 116.3(3) . . ?
C2 C1 S1 124.5(2) . . ?
N2 C6 S2 119.31(19) . . ?
N2 C6 C7 116.2(2) . . ?
C7 C6 S2 124.4(2) . . ?
N1 C5 H5 119.8 . . ?
N1 C5 C4 120.5(3) . . ?
C4 C5 H5 119.8 . . ?
C15 C14 H14 120.6 . . ?
C15 C14 C13 118.9(3) . . ?
C13 C14 H14 120.6 . . ?
C11 C12 H12 119.1 . . ?
C13 C12 C11 121.9(3) . . ?
C13 C12 H12 119.1 . . ?
C10 C9 H9A 120.5 . . ?
C10 C9 C8 118.9(3) . . ?
C10 C9 H9B 108(8) . . ?
H9A C9 H9B 129.1 . . ?
C8 C9 H9A 120.5 . . ?
C8 C9 H9B 17(8) . . ?
C6 C7 H7 119.3 . . ?
C6 C7 H9B 115(10) . . ?
H7 C7 H9B 122.7 . . ?
C8 C7 C6 121.4(3) . . ?
C8 C7 H7 119.3 . . ?
C8 C7 H9B 18(10) . . ?
C14 C13 H13 120.0 . . ?
C12 C13 C14 120.0(3) . . ?
C12 C13 H13 120.0 . . ?
C9 C8 H8 120.1 . . ?
C9 C8 H9B 92(10) . . ?
C7 C8 C9 119.8(3) . . ?
C7 C8 H8 120.1 . . ?
C7 C8 H9B 59(10) . . ?
H8 C8 H9B 118.5 . . ?
C1 C2 H2 119.1 . . ?
C3 C2 C1 121.8(3) . . ?
C3 C2 H2 119.1 . . ?
C5 C4 H4 120.3 . . ?
C5 C4 C3 119.4(3) . . ?
C3 C4 H4 120.3 . . ?
C2 C3 C4 119.5(3) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Lu1 S3 2.8224(7) . ?
Lu1 S1 2.7405(7) . ?
Lu1 S2 2.7611(7) . ?
Lu1 O2 2.2920(18) . ?
Lu1 O1 2.3029(16) . ?
Lu1 O4 2.3206(17) . ?
Lu1 O3 2.2888(17) . ?
Lu1 O5 2.3243(18) . ?
S3 C11 1.702(3) . ?
S1 C1 1.706(3) . ?
S2 C6 1.704(3) . ?
O2 N2 1.347(3) . ?
O1 N1 1.344(2) . ?
O4 H4A 0.8508 . ?
O4 H4B 0.8509 . ?
O3 N3 1.340(3) . ?
O5 H5A 0.8499 . ?
O5 H5B 0.8499 . ?
O6 H6A 0.8498 . ?
O6 H6B 0.8503 . ?
N3 C11 1.369(3) . ?
N3 C15 1.354(3) . ?
N2 C10 1.345(3) . ?
N2 C6 1.369(3) . ?
N1 C1 1.365(3) . ?
N1 C5 1.354(3) . ?
C11 C12 1.404(4) . ?
C10 H10 0.9300 . ?
C10 C9 1.370(4) . ?
C15 H15 0.9300 . ?
C15 C14 1.363(4) . ?
C1 C2 1.405(4) . ?
C6 C7 1.406(4) . ?
C5 H5 0.9300 . ?
C5 C4 1.362(4) . ?
C14 H14 0.9300 . ?
C14 C13 1.383(5) . ?
C12 H12 0.9300 . ?
C12 C13 1.356(5) . ?
C9 H9A 0.9300 . ?
C9 C8 1.384(5) . ?
C9 H9B 1.5(2) . ?
C7 H7 0.9300 . ?
C7 C8 1.368(5) . ?
C7 H9B 1.2(2) . ?
C13 H13 0.9300 . ?
C8 H8 0.9300 . ?
C8 H9B 0.4(2) . ?
C2 H2 0.9300 . ?
C2 C3 1.357(5) . ?
C4 H4 0.9300 . ?
C4 C3 1.378(6) . ?
C3 H3 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Lu1 S3 C11 N3 19.3(2) . . . . ?
Lu1 S3 C11 C12 -161.5(2) . . . . ?
Lu1 S1 C1 N1 -21.1(2) . . . . ?
Lu1 S1 C1 C2 160.5(2) . . . . ?
Lu1 S2 C6 N2 -13.7(2) . . . . ?
Lu1 S2 C6 C7 165.8(2) . . . . ?
Lu1 O2 N2 C10 -158.13(18) . . . . ?
Lu1 O2 N2 C6 21.4(3) . . . . ?
Lu1 O1 N1 C1 27.4(3) . . . . ?
Lu1 O1 N1 C5 -152.83(19) . . . . ?
Lu1 O3 N3 C11 -24.3(3) . . . . ?
Lu1 O3 N3 C15 156.44(18) . . . . ?
S3 C11 C12 C13 -177.5(2) . . . . ?
S1 C1 C2 C3 177.3(3) . . . . ?
S2 C6 C7 C8 179.7(3) . . . . ?
O2 N2 C10 C9 -178.8(3) . . . . ?
O2 N2 C6 S2 -0.5(3) . . . . ?
O2 N2 C6 C7 -180.0(2) . . . . ?
O1 N1 C1 S1 1.6(3) . . . . ?
O1 N1 C1 C2 -180.0(2) . . . . ?
O1 N1 C5 C4 -179.0(3) . . . . ?
O3 N3 C11 S3 -3.0(3) . . . . ?
O3 N3 C11 C12 177.7(2) . . . . ?
O3 N3 C15 C14 -179.0(2) . . . . ?
N3 C11 C12 C13 1.7(4) . . . . ?
N3 C15 C14 C13 1.0(4) . . . . ?
N2 C10 C9 C8 -1.6(5) . . . . ?
N2 C6 C7 C8 -0.9(4) . . . . ?
N1 C1 C2 C3 -1.1(4) . . . . ?
N1 C5 C4 C3 -1.1(5) . . . . ?
C11 N3 C15 C14 1.7(4) . . . . ?
C11 C12 C13 C14 0.9(5) . . . . ?
C10 N2 C6 S2 179.0(2) . . . . ?
C10 N2 C6 C7 -0.5(4) . . . . ?
C10 C9 C8 C7 0.2(5) . . . . ?
C15 N3 C11 S3 176.3(2) . . . . ?
C15 N3 C11 C12 -3.0(4) . . . . ?
C15 C14 C13 C12 -2.3(5) . . . . ?
C1 N1 C5 C4 0.7(4) . . . . ?
C1 C2 C3 C4 0.8(5) . . . . ?
C6 N2 C10 C9 1.8(4) . . . . ?
C6 C7 C8 C9 1.0(5) . . . . ?
C5 N1 C1 S1 -178.1(2) . . . . ?
C5 N1 C1 C2 0.3(4) . . . . ?
C5 C4 C3 C2 0.3(5) . . . . ?
