#------------------------------------------------------------------------------
#$Date: 2023-04-13 15:19:33 +0300 (Thu, 13 Apr 2023) $
#$Revision: 282621 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/10/7131044.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7131044
loop_
_publ_author_name
'Litle, Elishua D.'
'Gabbaï, François P.'
_publ_section_title
;
 A cationic gold-fluorenyl complex with a dative Au → C+ bond:
 synthesis, structure, and carbophilic reactivity
;
_journal_issue                   5
_journal_name_full               'Chemical Communications'
_journal_page_first              603
_journal_page_last               606
_journal_paper_doi               10.1039/D2CC05436A
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C31 H23 Au Cl O P, C H2 Cl2'
_chemical_formula_sum            'C32 H25 Au Cl3 O P'
_chemical_formula_weight         759.80
_chemical_name_systematic        C32H25AuCl3OP
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2022-11-11
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_audit_update_record
;
2022-11-12 deposited with the CCDC.	2022-11-28 downloaded from the CCDC.
;
_cell_angle_alpha                96.709(2)
_cell_angle_beta                 109.916(2)
_cell_angle_gamma                110.821(2)
_cell_formula_units_Z            2
_cell_length_a                   10.8459(10)
_cell_length_b                   12.2003(12)
_cell_length_c                   12.4897(12)
_cell_measurement_reflns_used    9825
_cell_measurement_temperature    110.0
_cell_measurement_theta_max      72.31
_cell_measurement_theta_min      4.03
_cell_volume                     1398.1(2)
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_diffrn_ambient_temperature      110.0
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_av_unetI/netI     0.0366
_diffrn_reflns_Laue_measured_fraction_full 0.971
_diffrn_reflns_Laue_measured_fraction_max 0.960
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            18139
_diffrn_reflns_point_group_measured_fraction_full 0.971
_diffrn_reflns_point_group_measured_fraction_max 0.960
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         72.298
_diffrn_reflns_theta_min         4.027
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    13.260
_exptl_absorpt_correction_T_max  0.4243
_exptl_absorpt_correction_T_min  0.2383
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1125 before and 0.0529 after correction. The Ratio of minimum to maximum transmission is 0.5616. The λ/2 correction factor is Not present.'
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.805
_exptl_crystal_description       block
_exptl_crystal_F_000             740
_exptl_crystal_size_max          0.139
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.109
_refine_diff_density_min         -0.847
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     344
_refine_ls_number_reflns         5320
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.0260
_refine_ls_R_factor_gt           0.0254
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0354P)²+3.1817P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0700
_refine_ls_wR_factor_ref         0.0712
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5197
_reflns_number_total             5320
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2cc05436a2.cif
_cod_data_source_block           eli85_0m_a
_cod_depositor_comments
'Adding full bibliography for 7131043--7131047.cif.'
_cod_database_code               7131044
#BEGIN Tags that were not found in dictionaries:
_shelxl_version_number           2013-3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.692
_shelx_estimated_absorpt_t_min   0.260
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H) groups
2.a Secondary CH2 refined with riding coordinates:
 C32(H32A,H32B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C22(H22), C23(H23), C24(H24),
  C25(H25), C28(H28), C29(H29), C30(H30), C31(H31)
2.c Idealised tetrahedral OH refined as rotating group:
 O1(H1)
;
_olex2_submission_original_sample_id Eli85
_olex2_submission_special_instructions 'No special instructions were received'
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.58080(2) 0.80597(2) 0.46417(2) 0.01618(7) Uani 1 1 d . . . . .
Cl1 Cl 0.75501(10) 0.94349(8) 0.63814(8) 0.02448(18) Uani 1 1 d . . . . .
Cl2 Cl 0.69114(15) 0.91908(13) 0.92198(14) 0.0544(3) Uani 1 1 d . . . . .
Cl3 Cl 0.96812(15) 1.12350(14) 1.07385(10) 0.0504(3) Uani 1 1 d . . . . .
P1 P 0.41348(9) 0.65734(8) 0.30244(7) 0.01446(16) Uani 1 1 d . . . . .
O1 O 0.2836(3) 0.8057(2) 0.3293(2) 0.0179(5) Uani 1 1 d . . . . .
H1 H 0.3017 0.8799 0.3476 0.027 Uiso 1 1 calc R U . . .
C1 C 0.2492(4) 0.5637(3) 0.3191(3) 0.0156(6) Uani 1 1 d . . . . .
C2 C 0.1565(4) 0.6080(3) 0.3464(3) 0.0150(6) Uani 1 1 d . . . . .
C3 C 0.0407(4) 0.5263(3) 0.3651(3) 0.0165(6) Uani 1 1 d . . . . .
H3 H -0.0228 0.5549 0.3829 0.020 Uiso 1 1 calc R U . . .
C4 C 0.0166(4) 0.4069(3) 0.3585(3) 0.0196(7) Uani 1 1 d . . . . .
H4 H -0.0614 0.3548 0.3732 0.024 Uiso 1 1 calc R U . . .
C5 C 0.1064(4) 0.3620(3) 0.3304(3) 0.0196(7) Uani 1 1 d . . . . .
H5 H 0.0898 0.2792 0.3248 0.023 Uiso 1 1 calc R U . . .
C6 C 0.2207(4) 0.4403(3) 0.3105(3) 0.0174(7) Uani 1 1 d . . . . .
H6 H 0.2814 0.4096 0.2904 0.021 Uiso 1 1 calc R U . . .
C7 C 0.4926(4) 0.5523(3) 0.2764(3) 0.0164(6) Uani 1 1 d . . . . .
C8 C 0.5803(4) 0.5314(4) 0.3754(3) 0.0226(7) Uani 1 1 d . . . . .
H8 H 0.5957 0.5703 0.4523 0.027 Uiso 1 1 calc R U . . .
C9 C 0.6452(4) 0.4540(4) 0.3621(3) 0.0253(8) Uani 1 1 d . . . . .
H9 H 0.7040 0.4392 0.4297 0.030 Uiso 1 1 calc R U . . .
C10 C 0.6239(4) 0.3984(4) 0.2499(4) 0.0258(8) Uani 1 1 d . . . . .
H10 H 0.6674 0.3448 0.2407 0.031 Uiso 1 1 calc R U . . .
C11 C 0.5398(5) 0.4208(4) 0.1514(3) 0.0265(8) Uani 1 1 d . . . . .
H11 H 0.5272 0.3839 0.0748 0.032 Uiso 1 1 calc R U . . .
C12 C 0.4735(4) 0.4978(4) 0.1645(3) 0.0217(7) Uani 1 1 d . . . . .
H12 H 0.4153 0.5129 0.0968 0.026 Uiso 1 1 calc R U . . .
C13 C 0.3534(4) 0.6923(3) 0.1615(3) 0.0187(7) Uani 1 1 d . . . . .
C14 C 0.4398(4) 0.7960(3) 0.1489(3) 0.0226(8) Uani 1 1 d . . . . .
H14 H 0.5274 0.8505 0.2139 0.027 Uiso 1 1 calc R U . . .
C15 C 0.3998(4) 0.8244(4) 0.0372(3) 0.0249(8) Uani 1 1 d . . . . .
H15 H 0.4614 0.8963 0.0268 0.030 Uiso 1 1 calc R U . . .
C16 C 0.2691(4) 0.7447(4) -0.0553(3) 0.0251(8) Uani 1 1 d . . . . .
H16 H 0.2401 0.7629 -0.1294 0.030 Uiso 1 1 calc R U . . .
C17 C 0.1813(4) 0.6391(4) -0.0401(3) 0.0241(8) Uani 1 1 d . . . . .
H17 H 0.0922 0.5849 -0.1038 0.029 Uiso 1 1 calc R U . . .
C18 C 0.2228(4) 0.6119(4) 0.0677(3) 0.0219(7) Uani 1 1 d . . . . .
H18 H 0.1627 0.5389 0.0778 0.026 Uiso 1 1 calc R U . . .
C19 C 0.1684(4) 0.7373(3) 0.3587(3) 0.0166(6) Uani 1 1 d . . . . .
C20 C 0.0256(4) 0.7392(3) 0.2817(3) 0.0176(7) Uani 1 1 d . . . . .
C21 C -0.0301(4) 0.7874(3) 0.3522(3) 0.0194(7) Uani 1 1 d . . . . .
C22 C -0.1582(4) 0.7987(4) 0.2993(4) 0.0251(8) Uani 1 1 d . . . . .
H22 H -0.1992 0.8278 0.3458 0.030 Uiso 1 1 calc R U . . .
C23 C -0.2254(4) 0.7662(4) 0.1762(4) 0.0286(8) Uani 1 1 d . . . . .
H23 H -0.3129 0.7742 0.1385 0.034 Uiso 1 1 calc R U . . .
C24 C -0.1669(4) 0.7223(4) 0.1073(4) 0.0277(8) Uani 1 1 d . . . . .
H24 H -0.2137 0.7024 0.0236 0.033 Uiso 1 1 calc R U . . .
C25 C -0.0406(4) 0.7072(3) 0.1599(3) 0.0221(7) Uani 1 1 d . . . . .
H25 H -0.0011 0.6759 0.1133 0.026 Uiso 1 1 calc R U . . .
C26 C 0.1899(4) 0.7974(3) 0.4831(3) 0.0172(7) Uani 1 1 d . . . . .
C27 C 0.0723(4) 0.8242(3) 0.4772(3) 0.0185(7) Uani 1 1 d . . . . .
C28 C 0.0726(4) 0.8847(3) 0.5789(3) 0.0231(7) Uani 1 1 d . . . . .
H28 H -0.0056 0.9046 0.5754 0.028 Uiso 1 1 calc R U . . .
C29 C 0.1902(5) 0.9154(3) 0.6859(3) 0.0251(8) Uani 1 1 d . . . . .
H29 H 0.1913 0.9555 0.7564 0.030 Uiso 1 1 calc R U . . .
C30 C 0.3063(4) 0.8884(3) 0.6916(3) 0.0239(8) Uani 1 1 d . . . . .
H30 H 0.3859 0.9110 0.7656 0.029 Uiso 1 1 calc R U . . .
C31 C 0.3065(4) 0.8282(3) 0.5889(3) 0.0203(7) Uani 1 1 d . . . . .
H31 H 0.3852 0.8091 0.5923 0.024 Uiso 1 1 calc R U . . .
C32 C 0.8353(5) 1.0511(5) 0.9278(4) 0.0355(10) Uani 1 1 d . . . . .
H32A H 0.8800 1.0280 0.8771 0.043 Uiso 1 1 calc R U . . .
H32B H 0.7968 1.1086 0.8966 0.043 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Cl1 174.38(3) . . ?
C1 P1 Au1 114.12(11) . . ?
C7 P1 Au1 106.62(12) . . ?
C7 P1 C1 104.89(16) . . ?
C13 P1 Au1 119.79(13) . . ?
C13 P1 C1 106.63(16) . . ?
C13 P1 C7 103.28(15) . . ?
C19 O1 H1 109.5 . . ?
C2 C1 P1 125.0(3) . . ?
C6 C1 P1 116.3(3) . . ?
C6 C1 C2 118.6(3) . . ?
C1 C2 C19 126.5(3) . . ?
C3 C2 C1 118.1(3) . . ?
C3 C2 C19 115.3(3) . . ?
C2 C3 H3 118.9 . . ?
C4 C3 C2 122.3(3) . . ?
C4 C3 H3 118.9 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 120.0(3) . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.6 . . ?
C6 C5 C4 118.9(3) . . ?
C6 C5 H5 120.6 . . ?
C1 C6 H6 119.0 . . ?
C5 C6 C1 122.1(3) . . ?
C5 C6 H6 119.0 . . ?
C8 C7 P1 117.2(3) . . ?
C12 C7 P1 123.1(3) . . ?
C12 C7 C8 119.6(3) . . ?
C7 C8 H8 119.9 . . ?
C9 C8 C7 120.2(3) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 120.1 . . ?
C10 C9 C8 119.8(3) . . ?
C10 C9 H9 120.1 . . ?
C9 C10 H10 119.9 . . ?
C11 C10 C9 120.3(4) . . ?
C11 C10 H10 119.9 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 119.9(3) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 120.0(3) . . ?
C7 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C14 C13 P1 118.2(3) . . ?
C14 C13 C18 121.0(3) . . ?
C18 C13 P1 120.8(3) . . ?
C13 C14 H14 120.0 . . ?
C13 C14 C15 120.0(3) . . ?
C15 C14 H14 120.0 . . ?
C14 C15 H15 120.6 . . ?
C16 C15 C14 118.8(3) . . ?
C16 C15 H15 120.6 . . ?
C15 C16 H16 119.9 . . ?
C17 C16 C15 120.3(3) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 119.9 . . ?
C16 C17 C18 120.3(4) . . ?
C18 C17 H17 119.9 . . ?
C13 C18 H18 120.2 . . ?
C17 C18 C13 119.7(3) . . ?
C17 C18 H18 120.2 . . ?
O1 C19 C2 108.4(3) . . ?
O1 C19 C20 111.6(3) . . ?
O1 C19 C26 111.8(3) . . ?
C2 C19 C20 111.6(3) . . ?
C2 C19 C26 112.1(3) . . ?
C20 C19 C26 101.4(3) . . ?
C21 C20 C19 110.7(3) . . ?
C25 C20 C19 127.4(3) . . ?
C25 C20 C21 121.8(3) . . ?
C20 C21 C27 108.7(3) . . ?
C22 C21 C20 119.9(3) . . ?
C22 C21 C27 131.3(3) . . ?
C21 C22 H22 120.8 . . ?
C21 C22 C23 118.4(4) . . ?
C23 C22 H22 120.8 . . ?
C22 C23 H23 119.4 . . ?
C24 C23 C22 121.2(4) . . ?
C24 C23 H23 119.4 . . ?
C23 C24 H24 119.7 . . ?
C23 C24 C25 120.7(4) . . ?
C25 C24 H24 119.7 . . ?
C20 C25 C24 118.0(4) . . ?
C20 C25 H25 121.0 . . ?
C24 C25 H25 121.0 . . ?
C27 C26 C19 110.6(3) . . ?
C31 C26 C19 128.0(3) . . ?
C31 C26 C27 121.3(3) . . ?
C26 C27 C21 108.6(3) . . ?
C28 C27 C21 130.9(3) . . ?
C28 C27 C26 120.3(3) . . ?
C27 C28 H28 120.8 . . ?
C29 C28 C27 118.3(4) . . ?
C29 C28 H28 120.8 . . ?
C28 C29 H29 119.4 . . ?
C28 C29 C30 121.2(3) . . ?
C30 C29 H29 119.4 . . ?
C29 C30 H30 119.8 . . ?
C29 C30 C31 120.5(4) . . ?
C31 C30 H30 119.8 . . ?
C26 C31 C30 118.3(3) . . ?
C26 C31 H31 120.9 . . ?
C30 C31 H31 120.9 . . ?
Cl2 C32 H32A 109.4 . . ?
Cl2 C32 H32B 109.4 . . ?
Cl3 C32 Cl2 111.3(2) . . ?
Cl3 C32 H32A 109.4 . . ?
Cl3 C32 H32B 109.4 . . ?
H32A C32 H32B 108.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Cl1 2.2811(9) . ?
Au1 P1 2.2292(9) . ?
Cl2 C32 1.775(5) . ?
Cl3 C32 1.764(5) . ?
P1 C1 1.840(3) . ?
P1 C7 1.833(3) . ?
P1 C13 1.816(3) . ?
O1 H1 0.8400 . ?
O1 C19 1.427(4) . ?
C1 C2 1.413(5) . ?
C1 C6 1.407(5) . ?
C2 C3 1.410(5) . ?
C2 C19 1.521(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.373(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.392(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.391(5) . ?
C6 H6 0.9500 . ?
C7 C8 1.395(5) . ?
C7 C12 1.387(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.389(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.387(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.383(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.397(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.344(5) . ?
C13 C18 1.398(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.436(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.389(6) . ?
C16 H16 0.9500 . ?
C16 C17 1.383(6) . ?
C17 H17 0.9500 . ?
C17 C18 1.388(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.530(5) . ?
C19 C26 1.540(4) . ?
C20 C21 1.408(5) . ?
C20 C25 1.378(5) . ?
C21 C22 1.384(5) . ?
C21 C27 1.475(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.394(6) . ?
C23 H23 0.9500 . ?
C23 C24 1.391(6) . ?
C24 H24 0.9500 . ?
C24 C25 1.392(5) . ?
C25 H25 0.9500 . ?
C26 C27 1.406(5) . ?
C26 C31 1.376(5) . ?
C27 C28 1.391(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.391(6) . ?
C29 H29 0.9500 . ?
C29 C30 1.392(6) . ?
C30 H30 0.9500 . ?
C30 C31 1.404(5) . ?
C31 H31 0.9500 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C1 C2 60.4(3) . . . . ?
Au1 P1 C1 C6 -115.7(2) . . . . ?
Au1 P1 C7 C8 37.5(3) . . . . ?
Au1 P1 C7 C12 -139.9(3) . . . . ?
Au1 P1 C13 C14 20.6(3) . . . . ?
Au1 P1 C13 C18 -161.2(2) . . . . ?
P1 C1 C2 C3 -175.3(2) . . . . ?
P1 C1 C2 C19 4.4(5) . . . . ?
P1 C1 C6 C5 175.0(3) . . . . ?
P1 C7 C8 C9 -179.2(3) . . . . ?
P1 C7 C12 C11 178.5(3) . . . . ?
P1 C13 C14 C15 177.1(3) . . . . ?
P1 C13 C18 C17 -178.2(3) . . . . ?
O1 C19 C20 C21 -121.8(3) . . . . ?
O1 C19 C20 C25 54.1(5) . . . . ?
O1 C19 C26 C27 121.4(3) . . . . ?
O1 C19 C26 C31 -56.2(5) . . . . ?
C1 P1 C7 C8 -83.9(3) . . . . ?
C1 P1 C7 C12 98.7(3) . . . . ?
C1 P1 C13 C14 152.1(3) . . . . ?
C1 P1 C13 C18 -29.7(3) . . . . ?
C1 C2 C3 C4 0.5(5) . . . . ?
C1 C2 C19 O1 4.3(4) . . . . ?
C1 C2 C19 C20 127.5(3) . . . . ?
C1 C2 C19 C26 -119.5(3) . . . . ?
C2 C1 C6 C5 -1.4(5) . . . . ?
C2 C3 C4 C5 -1.3(5) . . . . ?
C2 C19 C20 C21 116.8(3) . . . . ?
C2 C19 C20 C25 -67.3(4) . . . . ?
C2 C19 C26 C27 -116.7(3) . . . . ?
C2 C19 C26 C31 65.7(4) . . . . ?
C3 C2 C19 O1 -176.0(3) . . . . ?
C3 C2 C19 C20 -52.8(4) . . . . ?
C3 C2 C19 C26 60.1(4) . . . . ?
C3 C4 C5 C6 0.7(5) . . . . ?
C4 C5 C6 C1 0.7(5) . . . . ?
C6 C1 C2 C3 0.8(5) . . . . ?
C6 C1 C2 C19 -179.5(3) . . . . ?
C7 P1 C1 C2 176.8(3) . . . . ?
C7 P1 C1 C6 0.6(3) . . . . ?
C7 P1 C13 C14 -97.7(3) . . . . ?
C7 P1 C13 C18 80.6(3) . . . . ?
C7 C8 C9 C10 0.7(6) . . . . ?
C8 C7 C12 C11 1.1(6) . . . . ?
C8 C9 C10 C11 0.7(6) . . . . ?
C9 C10 C11 C12 -1.3(6) . . . . ?
C10 C11 C12 C7 0.3(6) . . . . ?
C12 C7 C8 C9 -1.7(6) . . . . ?
C13 P1 C1 C2 -74.1(3) . . . . ?
C13 P1 C1 C6 109.7(3) . . . . ?
C13 P1 C7 C8 164.6(3) . . . . ?
C13 P1 C7 C12 -12.8(3) . . . . ?
C13 C14 C15 C16 1.8(5) . . . . ?
C14 C13 C18 C17 0.0(5) . . . . ?
C14 C15 C16 C17 -1.2(6) . . . . ?
C15 C16 C17 C18 0.1(6) . . . . ?
C16 C17 C18 C13 0.5(6) . . . . ?
C18 C13 C14 C15 -1.2(5) . . . . ?
C19 C2 C3 C4 -179.2(3) . . . . ?
C19 C20 C21 C22 179.1(3) . . . . ?
C19 C20 C21 C27 2.1(4) . . . . ?
C19 C20 C25 C24 -176.4(3) . . . . ?
C19 C26 C27 C21 -1.3(4) . . . . ?
C19 C26 C27 C28 -176.7(3) . . . . ?
C19 C26 C31 C30 176.7(3) . . . . ?
C20 C19 C26 C27 2.4(3) . . . . ?
C20 C19 C26 C31 -175.2(3) . . . . ?
C20 C21 C22 C23 -2.7(5) . . . . ?
C20 C21 C27 C26 -0.5(4) . . . . ?
C20 C21 C27 C28 174.2(4) . . . . ?
C21 C20 C25 C24 -1.0(5) . . . . ?
C21 C22 C23 C24 0.6(6) . . . . ?
C21 C27 C28 C29 -175.5(3) . . . . ?
C22 C21 C27 C26 -177.0(4) . . . . ?
C22 C21 C27 C28 -2.3(7) . . . . ?
C22 C23 C24 C25 1.3(6) . . . . ?
C23 C24 C25 C20 -1.2(6) . . . . ?
C25 C20 C21 C22 3.0(5) . . . . ?
C25 C20 C21 C27 -174.1(3) . . . . ?
C26 C19 C20 C21 -2.7(4) . . . . ?
C26 C19 C20 C25 173.2(3) . . . . ?
C26 C27 C28 C29 -1.3(5) . . . . ?
C27 C21 C22 C23 173.5(4) . . . . ?
C27 C26 C31 C30 -0.6(5) . . . . ?
C27 C28 C29 C30 1.1(5) . . . . ?
C28 C29 C30 C31 -0.6(6) . . . . ?
C29 C30 C31 C26 0.4(5) . . . . ?
C31 C26 C27 C21 176.5(3) . . . . ?
C31 C26 C27 C28 1.1(5) . . . . ?
