#------------------------------------------------------------------------------
#$Date: 2023-05-05 03:40:41 +0300 (Fri, 05 May 2023) $
#$Revision: 283135 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/11/7131156.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7131156
loop_
_publ_author_name
'Humphreys, Joshua'
'Malagreca, Ferdinando'
'Hume, Paul A.'
'Davies, E. Stephen'
'Argent, Stephen P.'
'Bradshaw, Tracey D.'
'Amabilino, David B.'
_publ_section_title
;
 Highly electron deficient diketopyrrolopyrroles.
;
_journal_issue                   12
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              1613
_journal_page_last               1616
_journal_paper_doi               10.1039/d2cc06770f
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C28 H36 N4 O2, 2(F6 P)'
_chemical_formula_sum            'C28 H36 F12 N4 O2 P2'
_chemical_formula_weight         750.55
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_date             2021-12-10
_audit_creation_method
;
Olex2 1.5
(compiled 2021.11.18 svn.ra9532c28 for OlexSys, GUI svn.r6429)
;
_audit_update_record
;
2022-03-18 deposited with the CCDC.	2023-01-03 downloaded from the CCDC.
;
_cell_angle_alpha                90.0
_cell_angle_beta                 96.9621(18)
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   34.9289(7)
_cell_length_b                   9.64811(19)
_cell_length_c                   9.32463(17)
_cell_measurement_reflns_used    6800
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.5070056337
_cell_measurement_theta_min      2.27018366285
_cell_volume                     3119.21(11)
_computing_cell_refinement
'DIALS 2theta refinement, DIALS 2.1.1-gcdd629a7b-release'
_computing_data_reduction
;
aimless (Evans, P. R. and Murshudov, G. N., 2013)
ccp4 (Winn, M. D. et al., 2011)
DIALS 2.1.1-gcdd629a7b-release (Winter, G. et al., 2018)
pointless (Evans, P., 2006)
XIA2 0.6.366-ga657f9d9-dials-2.1 (Winter, G., 2010)
;
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_environment      'N2 gas'
_diffrn_ambient_temperature      100(2)
_diffrn_crystal_treatment        'flash frozen in gaseous N2'
_diffrn_detector                 'Photon counting pixel array'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'Fixed χ 3-circle diffractometer'
_diffrn_measurement_device_type  'Fluid Film Devices'
_diffrn_measurement_method       'shutterless scans'
_diffrn_measurement_specimen_support 'MiTeGen MicroMount'
_diffrn_radiation_monochromator  'Silicon 111'
_diffrn_radiation_type           Synchrotron
_diffrn_radiation_wavelength     0.6889
_diffrn_reflns_av_R_equivalents  0.0670
_diffrn_reflns_av_unetI/netI     0.0669
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       49
_diffrn_reflns_limit_h_min       -49
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            24129
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        24.415
_diffrn_reflns_theta_max         29.477
_diffrn_reflns_theta_min         2.277
_diffrn_source                   'Diamond Light Source Beamline I19-1'
_exptl_absorpt_coefficient_mu    0.229
_exptl_absorpt_correction_T_max  1.0
_exptl_absorpt_correction_T_min  0.9941388463812154
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
CCP4 7.0.078: AIMLESS, version 0.7.4 : 13/12/18
Scaling & analysis of unmerged intensities, absorption correction using spherical harmonics
;
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.598
_exptl_crystal_description       plank
_exptl_crystal_F_000             1544
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: acetonitrile'
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.005
_refine_diff_density_max         0.571
_refine_diff_density_min         -0.523
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     221
_refine_ls_number_reflns         4749
_refine_ls_number_restraints     175
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0696
_refine_ls_R_factor_gt           0.0456
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0436P)²+1.0726P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1101
_refine_ls_wR_factor_ref         0.1174
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3386
_reflns_number_total             4749
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2cc06770f2.cif
_cod_data_source_block           3-2-2PF6
_cod_depositor_comments
'Adding full bibliography for 7131154--7131156.cif.'
_cod_original_cell_volume        3119.21(7)
_cod_database_code               7131156
_nottingham_internal_coll_name   DPPFMB_C1
_nottingham_internal_coll_number 18572
_nottingham_internal_coll_client FM/DBA
_nottingham_internal_coll_type   custom
_nottingham_internal_coll_frame_method 'fine \w scans'
_nottingham_internal_coll_frame_time 0.2
_nottingham_internal_coll_frame_width 0.01
_nottingham_internal_coll_user   pczspa
_nottingham_internal_coll_date   26/01/2020
_nottingham_internal_coll_location DLS
_nottingham_internal_coll_instrument i19-EH1
_nottingham_internal_process_date 26/01/2020
_nottingham_internal_process_user pczspa
_nottingham_internal_solution_date 26/01/2020
_nottingham_internal_solution_user pczspa
_nottingham_internal_refinement_date 10/12/2021
_nottingham_internal_refinement_user pczspa
_nottingham_internal_validation_date 10/12/2021
_nottingham_internal_validation_user pczspa
_nottingham_internal_archive_date 10/12/2021
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.999
_shelx_estimated_absorpt_t_min   0.982
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N1_$1-H1_$1
 0.88 with sigma of 0.02
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4.a Secondary CH2 refined with riding coordinates:
 C12(H12A,H12B), C13(H13A,H13B), C14(H14A,H14B), C15(H15A,H15B), C16(H16A,H16B)
4.b Aromatic/amide H refined with riding coordinates:
 C7(H7), C9(H9), C10(H10), C11(H11)
4.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_symmetry_equiv_pos_as_xyz
-x,y,-z+1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.45623(4) 0.56409(13) 0.62453(14) 0.0137(3) Uani 1 1 d . . . . .
H1 H 0.4391(5) 0.5921(18) 0.673(2) 0.016 Uiso 1 1 d . U . . .
C2 C 0.47817(4) 0.65934(16) 0.55413(16) 0.0126(3) Uani 1 1 d . . . . .
O3 O 0.47375(3) 0.78493(11) 0.55659(13) 0.0188(2) Uani 1 1 d . . . . .
C4 C 0.49583(4) 0.42982(15) 0.51639(16) 0.0117(3) Uani 1 1 d . . . . .
C5 C 0.46652(4) 0.42785(15) 0.60267(15) 0.0115(3) Uani 1 1 d . . . . .
N6 N 0.40023(4) 0.22270(13) 0.80281(14) 0.0136(3) Uani 1 1 d . . . . .
C7 C 0.41706(4) 0.33056(16) 0.74366(15) 0.0131(3) Uani 1 1 d . . . . .
H7 H 0.407777 0.421761 0.756287 0.016 Uiso 1 1 calc R U . . .
C8 C 0.44778(4) 0.31050(15) 0.66451(15) 0.0117(3) Uani 1 1 d . . . . .
C9 C 0.46015(4) 0.17363(16) 0.64383(16) 0.0142(3) Uani 1 1 d . . . . .
H9 H 0.480456 0.156077 0.587109 0.017 Uiso 1 1 calc R U . . .
C10 C 0.44244(5) 0.06530(16) 0.70688(17) 0.0163(3) Uani 1 1 d . . . . .
H10 H 0.450706 -0.027290 0.694580 0.020 Uiso 1 1 calc R U . . .
C11 C 0.41271(5) 0.09210(16) 0.78779(17) 0.0154(3) Uani 1 1 d . . . . .
H11 H 0.400972 0.017863 0.833199 0.018 Uiso 1 1 calc R U . . .
C12 C 0.36573(5) 0.24957(17) 0.88045(18) 0.0184(3) Uani 1 1 d . . . . .
H12A H 0.368618 0.340677 0.929409 0.022 Uiso 1 1 calc R U . . .
H12B H 0.364217 0.177567 0.955195 0.022 Uiso 1 1 calc R U . . .
C13 C 0.32872(5) 0.24850(17) 0.77590(19) 0.0185(3) Uani 1 1 d . . . . .
H13A H 0.331867 0.311925 0.694684 0.022 Uiso 1 1 calc R U . . .
H13B H 0.307456 0.284854 0.826277 0.022 Uiso 1 1 calc R U . . .
C14 C 0.31742(5) 0.10586(16) 0.71506(18) 0.0173(3) Uani 1 1 d . . . . .
H14A H 0.315719 0.040809 0.796152 0.021 Uiso 1 1 calc R U . . .
H14B H 0.337874 0.071774 0.659187 0.021 Uiso 1 1 calc R U . . .
C15 C 0.27898(5) 0.10606(17) 0.61757(19) 0.0201(3) Uani 1 1 d . . . . .
H15A H 0.258899 0.147012 0.670894 0.024 Uiso 1 1 calc R U . . .
H15B H 0.281319 0.165141 0.532259 0.024 Uiso 1 1 calc R U . . .
C16 C 0.26636(5) -0.03912(17) 0.56660(18) 0.0206(3) Uani 1 1 d . . . . .
H16A H 0.287081 -0.081881 0.517905 0.025 Uiso 1 1 calc R U . . .
H16B H 0.262745 -0.096726 0.651783 0.025 Uiso 1 1 calc R U . . .
C17 C 0.22925(5) -0.0393(2) 0.4636(2) 0.0266(4) Uani 1 1 d . . . . .
H17A H 0.232688 0.016723 0.378394 0.040 Uiso 1 1 calc R U . . .
H17B H 0.208368 -0.000065 0.512184 0.040 Uiso 1 1 calc R U . . .
H17C H 0.222705 -0.134581 0.433596 0.040 Uiso 1 1 calc R U . . .
P1A P 0.36949(2) 0.70957(4) 0.83388(4) 0.01377(11) Uani 1 1 d . . . . .
F2A F 0.41572(3) 0.70005(15) 0.83328(13) 0.0419(3) Uani 1 1 d . . . . .
F3A F 0.37632(3) 0.82708(10) 0.95582(10) 0.0208(2) Uani 1 1 d . . . . .
F4A F 0.32462(3) 0.71890(15) 0.83460(14) 0.0442(3) Uani 1 1 d . . . . .
F5A F 0.36453(3) 0.59195(10) 0.71110(11) 0.0312(3) Uani 1 1 d . . . . .
F6A F 0.36786(4) 0.82454(11) 0.71164(11) 0.0333(3) Uani 1 1 d . . . . .
F7A F 0.37280(4) 0.59373(11) 0.95655(12) 0.0438(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0032 0.0015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0167 0.0096 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0108 0.0057 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0990 0.0908 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 N1 H1 120.4(13) . . ?
C5 N1 H1 126.9(13) . . ?
C5 N1 C2 112.65(12) . . ?
N1 C2 C4 103.19(12) . 5_666 ?
O3 C2 N1 124.12(14) . . ?
O3 C2 C4 132.68(14) . 5_666 ?
C4 C4 C2 107.94(16) 5_666 5_666 ?
C5 C4 C2 143.16(14) . 5_666 ?
C5 C4 C4 108.90(16) . 5_666 ?
N1 C5 C8 122.75(13) . . ?
C4 C5 N1 107.32(13) . . ?
C4 C5 C8 129.93(13) . . ?
C7 N6 C11 121.19(14) . . ?
C7 N6 C12 118.69(13) . . ?
C11 N6 C12 120.05(13) . . ?
N6 C7 H7 119.5 . . ?
N6 C7 C8 120.97(14) . . ?
C8 C7 H7 119.5 . . ?
C7 C8 C5 120.94(13) . . ?
C7 C8 C9 118.22(13) . . ?
C9 C8 C5 120.83(13) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 C8 119.34(14) . . ?
C10 C9 H9 120.3 . . ?
C9 C10 H10 120.1 . . ?
C11 C10 C9 119.75(14) . . ?
C11 C10 H10 120.1 . . ?
N6 C11 C10 120.46(14) . . ?
N6 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
N6 C12 H12A 109.4 . . ?
N6 C12 H12B 109.4 . . ?
N6 C12 C13 111.03(13) . . ?
H12A C12 H12B 108.0 . . ?
C13 C12 H12A 109.4 . . ?
C13 C12 H12B 109.4 . . ?
C12 C13 H13A 108.8 . . ?
C12 C13 H13B 108.8 . . ?
C12 C13 C14 113.99(14) . . ?
H13A C13 H13B 107.6 . . ?
C14 C13 H13A 108.8 . . ?
C14 C13 H13B 108.8 . . ?
C13 C14 H14A 109.0 . . ?
C13 C14 H14B 109.0 . . ?
C13 C14 C15 112.96(13) . . ?
H14A C14 H14B 107.8 . . ?
C15 C14 H14A 109.0 . . ?
C15 C14 H14B 109.0 . . ?
C14 C15 H15A 109.1 . . ?
C14 C15 H15B 109.1 . . ?
H15A C15 H15B 107.8 . . ?
C16 C15 C14 112.58(14) . . ?
C16 C15 H15A 109.1 . . ?
C16 C15 H15B 109.1 . . ?
C15 C16 H16A 109.0 . . ?
C15 C16 H16B 109.0 . . ?
H16A C16 H16B 107.8 . . ?
C17 C16 C15 112.98(15) . . ?
C17 C16 H16A 109.0 . . ?
C17 C16 H16B 109.0 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
F3A P1A F2A 88.84(6) . . ?
F3A P1A F5A 177.61(6) . . ?
F4A P1A F2A 179.94(8) . . ?
F4A P1A F3A 91.11(6) . . ?
F4A P1A F5A 91.26(7) . . ?
F4A P1A F6A 90.82(7) . . ?
F4A P1A F7A 91.30(8) . . ?
F5A P1A F2A 88.79(6) . . ?
F6A P1A F2A 89.19(7) . . ?
F6A P1A F3A 90.25(6) . . ?
F6A P1A F5A 89.46(6) . . ?
F6A P1A F7A 177.88(8) . . ?
F7A P1A F2A 88.69(8) . . ?
F7A P1A F3A 89.73(6) . . ?
F7A P1A F5A 90.48(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 H1 0.838(14) . ?
N1 C2 1.409(2) . ?
N1 C5 1.3844(19) . ?
C2 O3 1.2220(18) . ?
C2 C4 1.464(2) 5_666 ?
C4 C4 1.426(3) 5_666 ?
C4 C5 1.377(2) . ?
C5 C8 1.461(2) . ?
N6 C7 1.346(2) . ?
N6 C11 1.346(2) . ?
N6 C12 1.502(2) . ?
C7 H7 0.9500 . ?
C7 C8 1.388(2) . ?
C8 C9 1.410(2) . ?
C9 H9 0.9500 . ?
C9 C10 1.382(2) . ?
C10 H10 0.9500 . ?
C10 C11 1.380(2) . ?
C11 H11 0.9500 . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C12 C13 1.522(3) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C13 C14 1.522(2) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C14 C15 1.528(2) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.527(2) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C17 1.517(2) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
P1A F2A 1.6182(11) . ?
P1A F3A 1.6030(10) . ?
P1A F4A 1.5707(12) . ?
P1A F5A 1.6063(10) . ?
P1A F6A 1.5866(11) . ?
P1A F7A 1.5934(11) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
N1 H1 F2A 0.838(14) 2.069(15) 2.8599(16) 157.3(18) . yes
C7 H7 F5A 0.95 2.24 3.1120(18) 152.8 . yes
C9 H9 O3 0.95 2.28 3.1669(19) 155.1 5_666 yes
C11 H11 F6A 0.95 2.40 3.0581(19) 125.7 1_545 yes
C12 H12B F6A 0.99 2.38 3.162(2) 135.4 6_566 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C5 C8 C7 3.1(2) . . . . ?
N1 C5 C8 C9 -177.65(14) . . . . ?
C2 N1 C5 C4 0.02(18) . . . . ?
C2 N1 C5 C8 -179.84(13) . . . . ?
C2 C4 C5 N1 179.8(2) 5_666 . . . ?
C2 C4 C5 C8 -0.3(3) 5_666 . . . ?
C4 C4 C5 N1 0.1(2) 5_666 . . . ?
C4 C4 C5 C8 179.94(16) 5_666 . . . ?
C4 C5 C8 C7 -176.69(15) . . . . ?
C4 C5 C8 C9 2.5(2) . . . . ?
C5 N1 C2 O3 178.91(14) . . . . ?
C5 N1 C2 C4 -0.12(17) . . . 5_666 ?
C5 C8 C9 C10 178.36(14) . . . . ?
N6 C7 C8 C5 -178.82(13) . . . . ?
N6 C7 C8 C9 1.9(2) . . . . ?
N6 C12 C13 C14 69.78(17) . . . . ?
C7 N6 C11 C10 -2.1(2) . . . . ?
C7 N6 C12 C13 86.48(16) . . . . ?
C7 C8 C9 C10 -2.4(2) . . . . ?
C8 C9 C10 C11 0.7(2) . . . . ?
C9 C10 C11 N6 1.6(2) . . . . ?
C11 N6 C7 C8 0.3(2) . . . . ?
C11 N6 C12 C13 -90.57(17) . . . . ?
C12 N6 C7 C8 -176.70(14) . . . . ?
C12 N6 C11 C10 174.84(14) . . . . ?
C12 C13 C14 C15 176.57(13) . . . . ?
C13 C14 C15 C16 -175.51(13) . . . . ?
C14 C15 C16 C17 -177.06(14) . . . . ?
