#------------------------------------------------------------------------------
#$Date: 2025-07-06 16:36:45 +0300 (Sun, 06 Jul 2025) $
#$Revision: 300532 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/43/7134376.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7134376
loop_
_publ_author_name
'Nong, Yan'
'Dai, Juefei'
'Yang, Chao'
'Su, Haifeng'
'Feng, Chengcheng'
'Shi, Chuanhua'
'Zhang, Zhixun'
'Yu, Xianyong'
'Zhang, Xueji'
'Yang, Huayan'
_publ_section_title
;
 Highly stable bidentate thiol-protected Ag5Cu4 nanoclusters: a stable
 catalyst for enhanced Knoevenagel condensation
;
_journal_issue                   38
_journal_name_full               'Chemical Communications'
_journal_page_first              6933
_journal_page_last               6936
_journal_paper_doi               10.1039/D5CC00825E
_journal_volume                  61
_journal_year                    2025
_chemical_absolute_configuration ad
_chemical_formula_moiety
{[Ag5Cu4(SSC6F4)6][2(P(C6H5)4)Cu(C28H28P2)2](C6H14)6}
_chemical_formula_sum            'C176 H180 Ag5 Cu5 F24 P6 S12'
_chemical_formula_weight         4178.78
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_method
;FinalCif V118 by Daniel Kratzert, Freiburg 2025,
https://dkratzert.de/finalcif.html
;
_audit_update_record
;
2025-04-01 deposited with the CCDC.	2025-04-03 downloaded from the CCDC.
;
_cell_angle_alpha                90.711(2)
_cell_angle_beta                 97.321(2)
_cell_angle_gamma                110.931(2)
_cell_formula_units_Z            1
_cell_length_a                   14.1667(9)
_cell_length_b                   15.8384(10)
_cell_length_c                   18.0867(11)
_cell_measurement_reflns_used    9812
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.5685
_cell_measurement_theta_min      2.4235
_cell_volume                     3752.2(4)
_computing_cell_refinement       'SAINT V8.40B'
_computing_data_collection
'Bruker BIS V6.2.16/2021-10-23 && APEX5 2023.9-2'
_computing_data_reduction        'SAINT V8.40B'
_computing_molecular_graphics    Diamond
_computing_publication_material  'Chemical Communications'
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_structure_solution    'SHELXT (G. Sheldrick)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON III'
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE dual wavelength Mo/Cu'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_measurement_specimen_support 'MiTeGen micromount'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0644
_diffrn_reflns_av_unetI/netI     0.0658
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            103133
_diffrn_reflns_point_group_measured_fraction_full 0.899
_diffrn_reflns_point_group_measured_fraction_max 0.880
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.399
_diffrn_reflns_theta_min         1.842
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.4
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50
_exptl_absorpt_coefficient_mu    1.650
_exptl_absorpt_correction_T_max  0.2626
_exptl_absorpt_correction_T_min  0.2162
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.849
_exptl_crystal_description       rod-like
_exptl_crystal_F_000             2114
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.955
_refine_diff_density_min         -1.538
_refine_diff_density_rms         0.150
_refine_ls_abs_structure_details
;
 Flack x determined using traditional methods
;
_refine_ls_abs_structure_Flack   0.085(25)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1529
_refine_ls_number_reflns         33138
_refine_ls_number_restraints     1721
_refine_ls_restrained_S_all      0.967
_refine_ls_R_factor_all          0.0933
_refine_ls_R_factor_gt           0.0753
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0831P)²+28.9121P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1845
_refine_ls_wR_factor_ref         0.1979
_reflns_Friedel_coverage         0.789
_reflns_Friedel_fraction_full    0.809
_reflns_Friedel_fraction_max     0.777
_reflns_number_gt                25530
_reflns_number_total             33138
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5cc00825e3.cif
_cod_data_source_block           mo_Ag5Cu4_S_0m_sq
_cod_depositor_comments
'Adding full bibliography for 7134376--7134377.cif.'
_cod_database_code               7134376
_shelx_shelxl_version_number     2019/2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_diffrn_measurement_ambient_temperature_device_make 'Oxford Cryostream 800'
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.64212(14) 0.26862(11) 0.71067(11) 0.0485(2) Uani 1 1 d . . . . .
Ag2 Ag 0.81844(9) 0.35423(8) 0.82960(8) 0.0427(3) Uani 1 1 d . . . . .
Ag3 Ag 0.67817(8) 0.46019(7) 0.74564(6) 0.0365(3) Uani 1 1 d . . . . .
Ag4 Ag 0.60492(8) 0.07580(7) 0.67553(6) 0.0355(3) Uani 1 1 d . . . . .
Ag5 Ag 0.47288(9) 0.18379(8) 0.58864(8) 0.0449(3) Uani 1 1 d . . . . .
Cu2 Cu 0.84953(13) 0.42634(12) 0.68749(11) 0.0347(4) Uani 1 1 d . . . . .
Cu3 Cu 0.43592(13) 0.11359(12) 0.73438(11) 0.0360(4) Uani 1 1 d . . . . .
Cu4 Cu 0.67541(13) 0.19674(12) 0.55840(11) 0.0344(4) Uani 1 1 d . . . . .
Cu5 Cu 0.14036(13) 0.29187(11) 0.21824(10) 0.0377(4) Uani 1 1 d . . . . .
Cu1 Cu 0.61518(16) 0.33848(13) 0.86513(12) 0.0429(5) Uani 1 1 d . . . . .
C1_1 C 0.3541(9) -0.0626(7) 0.6361(7) 0.042(3) Uani 1 1 d D U . . .
C2_1 C 0.2969(10) -0.0115(7) 0.6050(8) 0.045(4) Uani 1 1 d D U . . .
C3_1 C 0.2271(11) -0.0482(8) 0.5413(8) 0.055(4) Uani 1 1 d D U . . .
C4_1 C 0.2060(11) -0.1351(8) 0.5124(9) 0.057(4) Uani 1 1 d D U . . .
C5_1 C 0.2612(11) -0.1857(7) 0.5429(8) 0.049(4) Uani 1 1 d D U . . .
C6_1 C 0.3354(10) -0.1479(7) 0.6031(7) 0.047(4) Uani 1 1 d D U . . .
F1_1 F 0.1716(10) -0.0025(8) 0.5117(8) 0.090(5) Uani 1 1 d D U . . .
F2_1 F 0.1353(11) -0.1694(9) 0.4522(8) 0.106(6) Uani 1 1 d D U . . .
F3_1 F 0.2479(9) -0.2664(6) 0.5122(7) 0.067(3) Uani 1 1 d D U . . .
F4_1 F 0.3899(8) -0.1974(6) 0.6312(6) 0.056(3) Uani 1 1 d D U . . .
S1_1 S 0.4457(3) -0.0253(2) 0.7173(2) 0.0350(8) Uani 1 1 d D U . . .
S2_1 S 0.3154(3) 0.0986(3) 0.6394(3) 0.0414(9) Uani 1 1 d D U . . .
C1_2 C 0.5732(8) -0.0019(6) 0.5049(7) 0.037(3) Uani 1 1 d D U . . .
C2_2 C 0.5095(10) 0.0382(5) 0.4668(9) 0.048(4) Uani 1 1 d D U . . .
C3_2 C 0.4218(11) -0.0171(6) 0.4214(10) 0.056(4) Uani 1 1 d D U . . .
C4_2 C 0.4029(11) -0.1081(7) 0.4079(10) 0.056(4) Uani 1 1 d D U . . .
C5_2 C 0.4678(11) -0.1473(7) 0.4427(9) 0.054(4) Uani 1 1 d D U . . .
C6_2 C 0.5497(9) -0.0952(6) 0.4933(8) 0.049(4) Uani 1 1 d D U . . .
F1_2 F 0.3610(9) 0.0170(7) 0.3826(8) 0.081(4) Uani 1 1 d D U . . .
F2_2 F 0.3207(10) -0.1596(7) 0.3609(8) 0.088(5) Uani 1 1 d D U . . .
F3_2 F 0.4450(10) -0.2359(5) 0.4315(8) 0.077(4) Uani 1 1 d D U . . .
F4_2 F 0.6113(8) -0.1361(6) 0.5262(6) 0.059(3) Uani 1 1 d D U . . .
S1_2 S 0.6851(3) 0.0597(2) 0.5667(2) 0.0369(8) Uani 1 1 d D U . . .
S2_2 S 0.5358(3) 0.1553(3) 0.4734(3) 0.0464(10) Uani 1 1 d D U . . .
C1_3 C 0.5777(8) 0.1346(8) 0.8803(6) 0.043(4) Uani 1 1 d D U . . .
C2_3 C 0.6666(8) 0.1276(7) 0.8582(6) 0.040(3) Uani 1 1 d D U . . .
C3_3 C 0.7113(9) 0.0743(9) 0.8984(7) 0.048(4) Uani 1 1 d D U . . .
C4_3 C 0.6678(11) 0.0222(11) 0.9540(8) 0.068(5) Uani 1 1 d D U . . .
C5_3 C 0.5782(10) 0.0257(10) 0.9734(8) 0.065(5) Uani 1 1 d D U . . .
C6_3 C 0.5366(10) 0.0834(9) 0.9383(7) 0.053(4) Uani 1 1 d D U . . .
F1_3 F 0.7963(7) 0.0674(7) 0.8806(7) 0.067(3) Uani 1 1 d D U . . .
F2_3 F 0.7140(12) -0.0287(9) 0.9914(8) 0.098(5) Uani 1 1 d D U . . .
F3_3 F 0.5418(11) -0.0187(9) 1.0314(7) 0.092(5) Uani 1 1 d D U . . .
F4_3 F 0.4509(8) 0.0861(7) 0.9617(6) 0.067(3) Uani 1 1 d D U . . .
S1_3 S 0.5092(3) 0.1994(3) 0.8369(2) 0.0374(8) Uani 1 1 d D U . . .
S2_3 S 0.7295(3) 0.1820(3) 0.7850(3) 0.0416(9) Uani 1 1 d D U . . .
C1_4 C 0.6166(7) 0.4054(7) 0.5604(5) 0.044(3) Uani 1 1 d DG U . . .
C2_4 C 0.7077(6) 0.4022(6) 0.5420(5) 0.037(3) Uani 1 1 d DG U . . .
C3_4 C 0.7516(6) 0.4513(7) 0.4841(6) 0.044(3) Uani 1 1 d DG U . . .
C4_4 C 0.7045(8) 0.5036(8) 0.4445(6) 0.061(5) Uani 1 1 d DG U . . .
C5_4 C 0.6134(8) 0.5068(8) 0.4628(6) 0.062(5) Uani 1 1 d DG U . . .
C6_4 C 0.5695(6) 0.4577(8) 0.5208(6) 0.054(4) Uani 1 1 d DG U . . .
F1_4 F 0.8374(6) 0.4507(7) 0.4640(6) 0.059(3) Uani 1 1 d D U . . .
F2_4 F 0.7531(12) 0.5575(9) 0.3938(8) 0.092(5) Uani 1 1 d D U . . .
F3_4 F 0.5691(12) 0.5568(10) 0.4245(8) 0.101(5) Uani 1 1 d D U . . .
F4_4 F 0.4790(8) 0.4598(8) 0.5347(8) 0.072(4) Uani 1 1 d D U . . .
S1_4 S 0.5530(3) 0.3537(3) 0.6360(2) 0.0378(9) Uani 1 1 d D U . . .
S2_4 S 0.7755(3) 0.3384(2) 0.5875(2) 0.0341(8) Uani 1 1 d D U . . .
C1_5 C 0.7234(9) 0.5355(6) 0.9183(8) 0.048(4) Uani 1 1 d D U . . .
C2_5 C 0.7879(9) 0.4948(6) 0.9555(8) 0.051(4) Uani 1 1 d D U . . .
C3_5 C 0.8756(11) 0.5486(7) 1.0014(11) 0.069(5) Uani 1 1 d D U . . .
C4_5 C 0.9039(12) 0.6418(7) 1.0085(11) 0.072(5) Uani 1 1 d D U . . .
C5_5 C 0.8411(10) 0.6824(7) 0.9721(10) 0.061(5) Uani 1 1 d D U . . .
C6_5 C 0.7500(11) 0.6289(6) 0.9296(10) 0.057(4) Uani 1 1 d D U . . .
F1_5 F 0.9420(10) 0.5143(9) 1.0337(8) 0.087(4) Uani 1 1 d D U . . .
F2_5 F 0.9909(10) 0.6922(9) 1.0523(9) 0.101(5) Uani 1 1 d D U . . .
F3_5 F 0.8645(11) 0.7717(6) 0.9820(9) 0.090(4) Uani 1 1 d D U . . .
F4_5 F 0.6895(9) 0.6700(7) 0.8958(7) 0.067(3) Uani 1 1 d D U . . .
S1_5 S 0.6076(3) 0.4761(3) 0.8593(2) 0.0400(9) Uani 1 1 d D U . . .
S2_5 S 0.7607(4) 0.3772(3) 0.9476(3) 0.0534(11) Uani 1 1 d D U . . .
C1_6 C 0.9299(8) 0.6053(6) 0.7812(6) 0.029(3) Uani 1 1 d D U . . .
C2_6 C 0.9897(9) 0.5571(6) 0.8133(6) 0.035(3) Uani 1 1 d D U . . .
C3_6 C 1.0713(10) 0.6022(8) 0.8678(8) 0.050(4) Uani 1 1 d D U . . .
C4_6 C 1.0895(12) 0.6892(8) 0.8953(9) 0.061(5) Uani 1 1 d D U . . .
C5_6 C 1.0263(11) 0.7341(8) 0.8681(8) 0.052(4) Uani 1 1 d D U . . .
C6_6 C 0.9487(9) 0.6923(7) 0.8106(7) 0.036(3) Uani 1 1 d D U . . .
F1_6 F 1.1347(9) 0.5628(8) 0.8964(8) 0.078(4) Uani 1 1 d D U . . .
F2_6 F 1.1635(9) 0.7277(8) 0.9522(7) 0.084(4) Uani 1 1 d D U . . .
F3_6 F 1.0430(10) 0.8167(6) 0.8974(7) 0.068(3) Uani 1 1 d D U . . .
F4_6 F 0.8888(8) 0.7383(6) 0.7864(6) 0.053(3) Uani 1 1 d D U . . .
S1_6 S 0.8350(3) 0.5636(2) 0.7021(2) 0.0336(8) Uani 1 1 d D U . . .
S2_6 S 0.9754(3) 0.4471(3) 0.7795(3) 0.0417(9) Uani 1 1 d D U . . .
C1_7 C 0.3114(7) 0.4614(4) 0.7564(6) 0.032(3) Uani 1 1 d G U . . .
C2_7 C 0.3746(6) 0.4177(6) 0.7363(6) 0.040(3) Uani 1 1 d G U . . .
H2_7 H 0.430424 0.448896 0.710759 0.048 Uiso 1 1 calc R U . . .
C3_7 C 0.3561(7) 0.3285(6) 0.7536(6) 0.038(3) Uani 1 1 d G U . . .
H3_7 H 0.399289 0.298619 0.739801 0.046 Uiso 1 1 calc R U . . .
C4_7 C 0.2744(8) 0.2829(5) 0.7909(6) 0.047(4) Uani 1 1 d G U . . .
H4_7 H 0.261771 0.221881 0.802727 0.056 Uiso 1 1 calc R U . . .
C5_7 C 0.2112(7) 0.3266(6) 0.8111(6) 0.049(4) Uani 1 1 d G U . . .
H5_7 H 0.155386 0.295421 0.836612 0.059 Uiso 1 1 calc R U . . .
C6_7 C 0.2297(7) 0.4158(6) 0.7938(6) 0.037(3) Uani 1 1 d G U . . .
H6_7 H 0.186519 0.445698 0.807571 0.045 Uiso 1 1 calc R U . . .
C7_7 C 0.2220(5) 0.5798(6) 0.6808(5) 0.026(2) Uani 1 1 d G U . . .
C8_7 C 0.1808(7) 0.5185(6) 0.6191(5) 0.039(3) Uani 1 1 d G U . . .
H8_7 H 0.210631 0.475387 0.608947 0.047 Uiso 1 1 calc R U . . .
C9_7 C 0.0959(7) 0.5204(6) 0.5722(5) 0.045(4) Uani 1 1 d G U . . .
H9_7 H 0.067777 0.478508 0.529956 0.054 Uiso 1 1 calc R U . . .
C10_7 C 0.0522(6) 0.5835(7) 0.5870(6) 0.043(4) Uani 1 1 d G U . . .
H10_7 H -0.005747 0.584781 0.554918 0.052 Uiso 1 1 calc R U . . .
C11_7 C 0.0934(6) 0.6448(6) 0.6487(6) 0.040(3) Uani 1 1 d G U . . .
H11_7 H 0.063582 0.687935 0.658871 0.049 Uiso 1 1 calc R U . . .
C12_7 C 0.1783(6) 0.6429(5) 0.6957(5) 0.031(3) Uani 1 1 d G U . . .
H12_7 H 0.206436 0.684816 0.737863 0.038 Uiso 1 1 calc R U . . .
C13_7 C 0.3677(9) 0.6486(6) 0.8186(6) 0.043(3) Uani 1 1 d G U . . .
C14_7 C 0.3653(12) 0.6150(6) 0.8892(7) 0.069(5) Uani 1 1 d G U . . .
H14_7 H 0.347583 0.551771 0.894454 0.083 Uiso 1 1 calc R U . . .
C15_7 C 0.3887(14) 0.6738(9) 0.9522(5) 0.107(8) Uani 1 1 d G U . . .
H15_7 H 0.387012 0.650742 1.000512 0.128 Uiso 1 1 calc R U . . .
C16_7 C 0.4146(13) 0.7662(8) 0.9446(6) 0.080(6) Uani 1 1 d G U . . .
H16_7 H 0.430587 0.806389 0.987681 0.096 Uiso 1 1 calc R U . . .
C17_7 C 0.4170(10) 0.7999(5) 0.8740(7) 0.049(4) Uani 1 1 d G U . . .
H17_7 H 0.434734 0.863066 0.868792 0.059 Uiso 1 1 calc R U . . .
C18_7 C 0.3936(9) 0.7411(7) 0.8110(5) 0.044(4) Uani 1 1 d G U . . .
H18_7 H 0.395305 0.764096 0.762732 0.052 Uiso 1 1 calc R U . . .
C19_7 C 0.4426(6) 0.6168(6) 0.6866(6) 0.033(3) Uani 1 1 d G U . . .
C20_7 C 0.5386(7) 0.6307(7) 0.7256(5) 0.047(4) Uani 1 1 d G U . . .
H20_7 H 0.545957 0.621660 0.777538 0.057 Uiso 1 1 calc R U . . .
C21_7 C 0.6238(5) 0.6578(7) 0.6886(8) 0.062(5) Uani 1 1 d G U . . .
H21_7 H 0.689396 0.667316 0.715241 0.075 Uiso 1 1 calc R U . . .
C22_7 C 0.6130(7) 0.6710(8) 0.6126(8) 0.064(5) Uani 1 1 d G U . . .
H22_7 H 0.671257 0.689542 0.587330 0.077 Uiso 1 1 calc R U . . .
C23_7 C 0.5170(9) 0.6571(8) 0.5736(6) 0.056(4) Uani 1 1 d G U . . .
H23_7 H 0.509680 0.666111 0.521714 0.067 Uiso 1 1 calc R U . . .
C24_7 C 0.4318(6) 0.6300(7) 0.6106(6) 0.045(4) Uani 1 1 d G U . . .
H24_7 H 0.366240 0.620454 0.584009 0.054 Uiso 1 1 calc R U . . .
P1_7 P 0.3349(3) 0.5762(2) 0.7358(2) 0.0282(7) Uani 1 1 d . U . . .
C1_8 C 0.9280(8) 0.8982(6) 0.6061(5) 0.038(3) Uani 1 1 d G U . . .
C2_8 C 0.9418(10) 0.9360(6) 0.5375(6) 0.063(5) Uani 1 1 d G U . . .
H2_8 H 0.963415 0.999798 0.534608 0.075 Uiso 1 1 calc R U . . .
C3_8 C 0.9240(12) 0.8804(9) 0.4732(5) 0.079(6) Uani 1 1 d G U . . .
H3_8 H 0.933426 0.906260 0.426350 0.095 Uiso 1 1 calc R U . . .
C4_8 C 0.8923(11) 0.7870(9) 0.4775(6) 0.077(6) Uani 1 1 d G U . . .
H4_8 H 0.880156 0.749067 0.433540 0.092 Uiso 1 1 calc R U . . .
C5_8 C 0.8785(9) 0.7492(6) 0.5461(7) 0.057(4) Uani 1 1 d G U . . .
H5_8 H 0.856875 0.685412 0.548989 0.068 Uiso 1 1 calc R U . . .
C6_8 C 0.8963(8) 0.8048(7) 0.6104(6) 0.040(3) Uani 1 1 d G U . . .
H6_8 H 0.886863 0.778949 0.657249 0.048 Uiso 1 1 calc R U . . .
C7_8 C 0.8490(6) 0.9257(6) 0.7405(6) 0.036(3) Uani 1 1 d G U . . .
C8_8 C 0.7528(7) 0.9107(7) 0.7015(5) 0.045(4) Uani 1 1 d G U . . .
H8_8 H 0.745669 0.923039 0.650275 0.054 Uiso 1 1 calc R U . . .
C9_8 C 0.6669(5) 0.8775(7) 0.7375(7) 0.057(4) Uani 1 1 d G U . . .
H9_8 H 0.601158 0.867221 0.710848 0.069 Uiso 1 1 calc R U . . .
C10_8 C 0.6773(7) 0.8594(7) 0.8125(7) 0.055(4) Uani 1 1 d G U . . .
H10_8 H 0.618680 0.836761 0.837081 0.065 Uiso 1 1 calc R U . . .
C11_8 C 0.7736(8) 0.8745(7) 0.8515(5) 0.052(4) Uani 1 1 d G U . . .
H11_8 H 0.780713 0.862119 0.902743 0.062 Uiso 1 1 calc R U . . .
C12_8 C 0.8594(6) 0.9076(7) 0.8155(6) 0.040(3) Uani 1 1 d G U . . .
H12_8 H 0.925226 0.917937 0.842170 0.047 Uiso 1 1 calc R U . . .
C13_8 C 1.0685(6) 0.9656(6) 0.7462(6) 0.037(3) Uani 1 1 d G U . . .
C14_8 C 1.1097(7) 0.9013(6) 0.7295(5) 0.037(3) Uani 1 1 d G U . . .
H14_8 H 1.077956 0.858306 0.688345 0.044 Uiso 1 1 calc R U . . .
C15_8 C 1.1974(7) 0.8999(6) 0.7729(6) 0.043(4) Uani 1 1 d G U . . .
H15_8 H 1.225626 0.855984 0.761404 0.052 Uiso 1 1 calc R U . . .
C16_8 C 1.2439(6) 0.9628(7) 0.8330(6) 0.050(4) Uani 1 1 d G U . . .
H16_8 H 1.303892 0.961880 0.862686 0.060 Uiso 1 1 calc R U . . .
C17_8 C 1.2027(8) 1.0271(7) 0.8498(6) 0.054(4) Uani 1 1 d G U . . .
H17_8 H 1.234488 1.070100 0.890910 0.064 Uiso 1 1 calc R U . . .
C18_8 C 1.1150(8) 1.0285(6) 0.8064(6) 0.046(4) Uani 1 1 d G U . . .
H18_8 H 1.086817 1.072424 0.817853 0.055 Uiso 1 1 calc R U . . .
C19_8 C 0.9784(7) 1.0847(5) 0.6735(7) 0.037(3) Uani 1 1 d G U . . .
C20_8 C 1.0670(7) 1.1351(6) 0.6453(7) 0.041(3) Uani 1 1 d G U . . .
H20_8 H 1.112888 1.107157 0.633438 0.049 Uiso 1 1 calc R U . . .
C21_8 C 1.0886(7) 1.2265(6) 0.6343(7) 0.054(4) Uani 1 1 d G U . . .
H21_8 H 1.149179 1.260921 0.615018 0.065 Uiso 1 1 calc R U . . .
C22_8 C 1.0215(8) 1.2674(5) 0.6516(7) 0.051(4) Uani 1 1 d G U . . .
H22_8 H 1.036249 1.329830 0.644117 0.062 Uiso 1 1 calc R U . . .
C23_8 C 0.9329(7) 1.2170(6) 0.6798(7) 0.042(3) Uani 1 1 d G U . . .
H23_8 H 0.887028 1.244975 0.691636 0.050 Uiso 1 1 calc R U . . .
C24_8 C 0.9113(6) 1.1257(6) 0.6908(6) 0.037(3) Uani 1 1 d G U . . .
H24_8 H 0.850736 1.091211 0.710057 0.045 Uiso 1 1 calc R U . . .
P1_8 P 0.9547(3) 0.9684(2) 0.6916(2) 0.0322(8) Uani 1 1 d . U . . .
P1_9 P 0.1123(3) 0.3367(3) 0.3299(2) 0.0465(9) Uani 1 1 d D U . . .
C1_9 C 0.0052(7) 0.2528(6) 0.3671(6) 0.046(3) Uani 1 1 d DG U . . .
C2_9 C -0.0355(8) 0.2704(6) 0.4290(6) 0.055(4) Uani 1 1 d DG U . . .
H2_9 H -0.012249 0.330096 0.451524 0.066 Uiso 1 1 calc R U . . .
C3_9 C -0.1101(8) 0.2006(8) 0.4578(6) 0.069(5) Uani 1 1 d DG U . . .
H3_9 H -0.137921 0.212628 0.500098 0.083 Uiso 1 1 calc R U . . .
C4_9 C -0.1441(8) 0.1133(7) 0.4248(7) 0.070(5) Uani 1 1 d DG U . . .
H4_9 H -0.195140 0.065599 0.444532 0.084 Uiso 1 1 calc R U . . .
C5_9 C -0.1035(9) 0.0957(5) 0.3629(7) 0.062(4) Uani 1 1 d DG U . . .
H5_9 H -0.126687 0.036038 0.340390 0.074 Uiso 1 1 calc R U . . .
C6_9 C -0.0288(8) 0.1655(7) 0.3341(5) 0.048(4) Uani 1 1 d DG U . . .
H6_9 H -0.001015 0.153504 0.291814 0.057 Uiso 1 1 calc R U . . .
C7_9 C 0.1085(8) 0.4491(6) 0.3476(8) 0.061(4) Uani 1 1 d DG U . . .
C8_9 C 0.0167(7) 0.4620(7) 0.3494(8) 0.067(4) Uani 1 1 d DG U . . .
H8_9 H -0.045378 0.411216 0.345293 0.081 Uiso 1 1 calc R U . . .
C9_9 C 0.0159(8) 0.5491(8) 0.3572(9) 0.073(5) Uani 1 1 d DG U . . .
H9_9 H -0.046846 0.557890 0.358418 0.087 Uiso 1 1 calc R U . . .
C10_9 C 0.1068(11) 0.6234(6) 0.3632(10) 0.080(5) Uani 1 1 d DG U . . .
H10_9 H 0.106156 0.682902 0.368555 0.096 Uiso 1 1 calc R U . . .
C11_9 C 0.1985(9) 0.6105(7) 0.3615(10) 0.094(7) Uani 1 1 d DG U . . .
H11_9 H 0.260628 0.661243 0.365568 0.113 Uiso 1 1 calc R U . . .
C12_9 C 0.1994(7) 0.5234(8) 0.3537(9) 0.078(5) Uani 1 1 d DG U . . .
H12_9 H 0.262098 0.514570 0.352443 0.094 Uiso 1 1 calc R U . . .
C13_9 C 0.2223(11) 0.3354(11) 0.3977(8) 0.058(4) Uani 1 1 d D U . . .
H13_9 H 0.284693 0.382093 0.382697 0.070 Uiso 1 1 calc R U . . .
C14_9 C 0.2323(12) 0.2423(11) 0.3838(8) 0.055(4) Uani 1 1 d D U . . .
H14_9 H 0.165770 0.195533 0.392071 0.066 Uiso 1 1 calc R U . . .
C15_9 C 0.2213(17) 0.3588(17) 0.4796(10) 0.084(6) Uani 1 1 d D U . . .
H15A_9 H 0.216483 0.418769 0.484624 0.125 Uiso 1 1 calc R U . . .
H15B_9 H 0.284342 0.359249 0.509334 0.125 Uiso 1 1 calc R U . . .
H15C_9 H 0.162438 0.313503 0.497333 0.125 Uiso 1 1 calc R U . . .
C16_9 C 0.3120(16) 0.2277(15) 0.4391(10) 0.081(6) Uani 1 1 d D U . . .
H16A_9 H 0.305565 0.164024 0.434837 0.121 Uiso 1 1 calc R U . . .
H16B_9 H 0.302835 0.242917 0.489701 0.121 Uiso 1 1 calc R U . . .
H16C_9 H 0.379877 0.266385 0.428986 0.121 Uiso 1 1 calc R U . . .
P2_9 P 0.2435(3) 0.2270(3) 0.2831(2) 0.0507(9) Uani 1 1 d D U . . .
C17_9 C 0.3824(6) 0.2831(8) 0.2797(8) 0.060(4) Uani 1 1 d DG U . . .
C18_9 C 0.4158(8) 0.3749(8) 0.2674(8) 0.063(4) Uani 1 1 d DG U . . .
H18_9 H 0.367664 0.403692 0.256307 0.076 Uiso 1 1 calc R U . . .
C19_9 C 0.5196(9) 0.4246(7) 0.2713(9) 0.077(5) Uani 1 1 d DG U . . .
H19_9 H 0.542404 0.487382 0.262915 0.092 Uiso 1 1 calc R U . . .
C20_9 C 0.5900(6) 0.3825(10) 0.2875(10) 0.098(7) Uani 1 1 d DG U . . .
H20_9 H 0.660949 0.416475 0.290232 0.118 Uiso 1 1 calc R U . . .
C21_9 C 0.5566(8) 0.2907(11) 0.2999(10) 0.089(6) Uani 1 1 d DG U . . .
H21_9 H 0.604754 0.261878 0.310941 0.107 Uiso 1 1 calc R U . . .
C22_9 C 0.4528(10) 0.2410(8) 0.2959(9) 0.080(5) Uani 1 1 d DG U . . .
H22_9 H 0.430014 0.178186 0.304333 0.096 Uiso 1 1 calc R U . . .
C23_9 C 0.2190(13) 0.1059(7) 0.2634(9) 0.084(6) Uani 1 1 d DG U . . .
C24_9 C 0.1551(13) 0.0394(11) 0.3026(9) 0.111(8) Uani 1 1 d DG U . . .
H24_9 H 0.125042 0.056090 0.341686 0.133 Uiso 1 1 calc R U . . .
C25_9 C 0.1351(14) -0.0515(9) 0.2846(12) 0.135(9) Uani 1 1 d DG U . . .
H25_9 H 0.091460 -0.096916 0.311427 0.162 Uiso 1 1 calc R U . . .
C26_9 C 0.1791(16) -0.0759(8) 0.2275(12) 0.133(9) Uani 1 1 d DG U . . .
H26_9 H 0.165489 -0.137979 0.215212 0.159 Uiso 1 1 calc R U . . .
C27_9 C 0.2430(15) -0.0094(12) 0.1883(10) 0.109(7) Uani 1 1 d DG U . . .
H27_9 H 0.273102 -0.026035 0.149255 0.130 Uiso 1 1 calc R U . . .
C28_9 C 0.2630(13) 0.0815(10) 0.2063(9) 0.100(7) Uani 1 1 d DG U . . .
H28_9 H 0.306686 0.126972 0.179513 0.120 Uiso 1 1 calc R U . . .
P1_10 P 0.0033(3) 0.2126(3) 0.1348(2) 0.0522(10) Uani 1 1 d D U . . .
C1_10 C -0.1116(8) 0.2422(9) 0.1405(8) 0.074(5) Uani 1 1 d DG U . . .
C2_10 C -0.2069(9) 0.1894(8) 0.1028(8) 0.083(6) Uani 1 1 d DG U . . .
H2_10 H -0.215786 0.134109 0.076639 0.099 Uiso 1 1 calc R U . . .
C3_10 C -0.2891(7) 0.2177(10) 0.1032(9) 0.095(7) Uani 1 1 d DG U . . .
H3_10 H -0.354239 0.181638 0.077389 0.114 Uiso 1 1 calc R U . . .
C4_10 C -0.2761(8) 0.2986(11) 0.1414(9) 0.093(6) Uani 1 1 d DG U . . .
H4_10 H -0.332262 0.317918 0.141738 0.112 Uiso 1 1 calc R U . . .
C5_10 C -0.1808(10) 0.3513(8) 0.1792(8) 0.080(5) Uani 1 1 d DG U . . .
H5_10 H -0.171831 0.406669 0.205336 0.096 Uiso 1 1 calc R U . . .
C6_10 C -0.0985(7) 0.3231(8) 0.1788(7) 0.064(4) Uani 1 1 d DG U . . .
H6_10 H -0.033376 0.359142 0.204587 0.077 Uiso 1 1 calc R U . . .
C7_10 C -0.0400(12) 0.0901(6) 0.1239(8) 0.074(5) Uani 1 1 d DG U . . .
C8_10 C -0.1164(12) 0.0371(9) 0.1629(8) 0.094(7) Uani 1 1 d DG U . . .
H8_10 H -0.150905 0.064793 0.191106 0.112 Uiso 1 1 calc R U . . .
C9_10 C -0.1422(14) -0.0563(9) 0.1606(10) 0.126(9) Uani 1 1 d DG U . . .
H9_10 H -0.194370 -0.092449 0.187296 0.151 Uiso 1 1 calc R U . . .
C10_10 C -0.0917(16) -0.0967(6) 0.1193(11) 0.122(9) Uani 1 1 d DG U . . .
H10_10 H -0.109326 -0.160550 0.117801 0.147 Uiso 1 1 calc R U . . .
C11_10 C -0.0153(14) -0.0438(9) 0.0803(10) 0.122(8) Uani 1 1 d DG U . . .
H11_10 H 0.019184 -0.071408 0.052115 0.146 Uiso 1 1 calc R U . . .
C12_10 C 0.0105(12) 0.0496(9) 0.0826(9) 0.096(7) Uani 1 1 d DG U . . .
H12_10 H 0.062650 0.085835 0.055925 0.115 Uiso 1 1 calc R U . . .
C13_10 C 0.0371(11) 0.2557(8) 0.0425(6) 0.048(3) Uani 1 1 d D U . . .
H13_10 H 0.090043 0.232282 0.029211 0.058 Uiso 1 1 calc R U . . .
C14_10 C 0.0882(10) 0.3599(9) 0.0548(6) 0.056(4) Uani 1 1 d D U . . .
H14_10 H 0.037547 0.383868 0.071658 0.068 Uiso 1 1 calc R U . . .
C15_10 C -0.0495(15) 0.2287(14) -0.0230(11) 0.092(7) Uani 1 1 d D U . . .
H15A_10 H -0.025607 0.262563 -0.066165 0.139 Uiso 1 1 calc R U . . .
H15B_10 H -0.107220 0.242497 -0.008907 0.139 Uiso 1 1 calc R U . . .
H15C_10 H -0.071359 0.163595 -0.035965 0.139 Uiso 1 1 calc R U . . .
C16_10 C 0.119(2) 0.4025(13) -0.0179(10) 0.109(9) Uani 1 1 d D U . . .
H16A_10 H 0.169707 0.380798 -0.034824 0.163 Uiso 1 1 calc R U . . .
H16B_10 H 0.148088 0.468554 -0.009413 0.163 Uiso 1 1 calc R U . . .
H16C_10 H 0.058563 0.385417 -0.056075 0.163 Uiso 1 1 calc R U . . .
P2_10 P 0.2001(3) 0.3892(3) 0.1302(2) 0.0502(9) Uani 1 1 d D U . . .
C17_10 C 0.2997(11) 0.3677(10) 0.0819(9) 0.073(5) Uani 1 1 d DG U . . .
C18_10 C 0.3065(12) 0.2824(9) 0.0857(8) 0.084(6) Uani 1 1 d DG U . . .
H18_10 H 0.264333 0.238538 0.114513 0.101 Uiso 1 1 calc R U . . .
C19_10 C 0.3750(14) 0.2612(10) 0.0474(10) 0.109(7) Uani 1 1 d DG U . . .
H19_10 H 0.379617 0.202921 0.049982 0.131 Uiso 1 1 calc R U . . .
C20_10 C 0.4367(13) 0.3253(13) 0.0052(10) 0.125(9) Uani 1 1 d DG U . . .
H20_10 H 0.483474 0.310876 -0.021012 0.151 Uiso 1 1 calc R U . . .
C21_10 C 0.4299(13) 0.4106(11) 0.0013(9) 0.113(8) Uani 1 1 d DG U . . .
H21_10 H 0.472047 0.454448 -0.027475 0.136 Uiso 1 1 calc R U . . .
C22_10 C 0.3614(13) 0.4318(9) 0.0397(9) 0.102(7) Uani 1 1 d DG U . . .
H22_10 H 0.356763 0.490067 0.037057 0.123 Uiso 1 1 calc R U . . .
C23_10 C 0.2429(9) 0.5130(6) 0.1490(8) 0.057(4) Uani 1 1 d DG U . . .
C24_10 C 0.1731(8) 0.5564(9) 0.1371(10) 0.090(6) Uani 1 1 d DG U . . .
H24_10 H 0.104509 0.523079 0.115996 0.108 Uiso 1 1 calc R U . . .
C25_10 C 0.2036(11) 0.6485(9) 0.1562(12) 0.105(7) Uani 1 1 d DG U . . .
H25_10 H 0.155930 0.678120 0.148042 0.126 Uiso 1 1 calc R U . . .
C26_10 C 0.3040(13) 0.6971(6) 0.1871(12) 0.112(8) Uani 1 1 d DG U . . .
H26_10 H 0.324868 0.760093 0.200112 0.135 Uiso 1 1 calc R U . . .
C27_10 C 0.3738(9) 0.6537(8) 0.1990(12) 0.113(8) Uani 1 1 d DG U . . .
H27_10 H 0.442387 0.687024 0.220137 0.136 Uiso 1 1 calc R U . . .
C28_10 C 0.3433(8) 0.5616(8) 0.1800(11) 0.096(7) Uani 1 1 d DG U . . .
H28_10 H 0.390968 0.531983 0.188092 0.115 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S2_3 Ag1 S1_4 179.36(19) . . ?
S2_3 Ag1 Ag3 123.57(12) . . ?
S1_4 Ag1 Ag3 56.98(11) . . ?
S2_3 Ag1 Ag5 122.78(12) . . ?
S1_4 Ag1 Ag5 56.64(11) . . ?
Ag3 Ag1 Ag5 113.26(6) . . ?
S2_3 Ag1 Ag4 56.57(11) . . ?
S1_4 Ag1 Ag4 122.88(13) . . ?
Ag3 Ag1 Ag4 179.75(8) . . ?
Ag5 Ag1 Ag4 66.57(5) . . ?
S2_3 Ag1 Ag2 56.91(11) . . ?
S1_4 Ag1 Ag2 123.69(12) . . ?
Ag3 Ag1 Ag2 67.36(5) . . ?
Ag5 Ag1 Ag2 177.76(9) . . ?
Ag4 Ag1 Ag2 112.81(6) . . ?
S2_3 Ag1 Cu1 84.43(12) . . ?
S1_4 Ag1 Cu1 95.73(12) . . ?
Ag3 Ag1 Cu1 57.74(5) . . ?
Ag5 Ag1 Cu1 124.16(8) . . ?
Ag4 Ag1 Cu1 122.16(8) . . ?
Ag2 Ag1 Cu1 58.06(6) . . ?
S2_3 Ag1 Cu4 93.71(12) . . ?
S1_4 Ag1 Cu4 86.14(12) . . ?
Ag3 Ag1 Cu4 123.09(7) . . ?
Ag5 Ag1 Cu4 57.52(5) . . ?
Ag4 Ag1 Cu4 57.02(5) . . ?
Ag2 Ag1 Cu4 120.27(7) . . ?
Cu1 Ag1 Cu4 178.01(9) . . ?
S2_3 Ag1 Cu3 86.58(11) . . ?
S1_4 Ag1 Cu3 92.83(11) . . ?
Ag3 Ag1 Cu3 121.50(7) . . ?
Ag5 Ag1 Cu3 56.79(6) . . ?
Ag4 Ag1 Cu3 58.26(5) . . ?
Ag2 Ag1 Cu3 124.92(8) . . ?
Cu1 Ag1 Cu3 80.88(7) . . ?
Cu4 Ag1 Cu3 99.74(7) . . ?
S2_3 Ag1 Cu2 93.68(11) . . ?
S1_4 Ag1 Cu2 86.91(11) . . ?
Ag3 Ag1 Cu2 57.98(5) . . ?
Ag5 Ag1 Cu2 123.36(8) . . ?
Ag4 Ag1 Cu2 122.26(7) . . ?
Ag2 Ag1 Cu2 54.94(5) . . ?
Cu1 Ag1 Cu2 98.69(7) . . ?
Cu4 Ag1 Cu2 80.70(7) . . ?
Cu3 Ag1 Cu2 179.48(9) . . ?
S2_5 Ag2 S2_6 128.92(17) . . ?
S2_5 Ag2 S2_3 107.93(15) . . ?
S2_6 Ag2 S2_3 119.30(14) . . ?
S2_5 Ag2 Cu2 142.92(12) . . ?
S2_6 Ag2 Cu2 48.34(11) . . ?
S2_3 Ag2 Cu2 98.43(11) . . ?
S2_5 Ag2 Cu1 48.53(13) . . ?
S2_6 Ag2 Cu1 147.43(10) . . ?
S2_3 Ag2 Cu1 84.85(10) . . ?
Cu2 Ag2 Cu1 110.80(7) . . ?
S2_5 Ag2 Ag1 111.02(14) . . ?
S2_6 Ag2 Ag1 112.87(12) . . ?
S2_3 Ag2 Ag1 51.68(10) . . ?
Cu2 Ag2 Ag1 66.31(6) . . ?
Cu1 Ag2 Ag1 63.28(6) . . ?
S2_5 Ag2 Ag3 89.39(12) . . ?
S2_6 Ag2 Ag3 94.33(10) . . ?
S2_3 Ag2 Ag3 106.96(10) . . ?
Cu2 Ag2 Ag3 57.60(5) . . ?
Cu1 Ag2 Ag3 55.66(5) . . ?
Ag1 Ag2 Ag3 55.79(4) . . ?
S1_5 Ag3 S1_6 128.49(14) . . ?
S1_5 Ag3 S1_4 117.16(13) . . ?
S1_6 Ag3 S1_4 111.41(12) . . ?
S1_5 Ag3 Cu1 47.92(10) . . ?
S1_6 Ag3 Cu1 140.18(10) . . ?
S1_4 Ag3 Cu1 97.17(10) . . ?
S1_5 Ag3 Ag1 110.03(11) . . ?
S1_6 Ag3 Ag1 112.56(10) . . ?
S1_4 Ag3 Ag1 52.29(9) . . ?
Cu1 Ag3 Ag1 64.08(6) . . ?
S1_5 Ag3 Cu2 144.01(12) . . ?
S1_6 Ag3 Cu2 48.18(9) . . ?
S1_4 Ag3 Cu2 88.89(9) . . ?
Cu1 Ag3 Cu2 108.10(6) . . ?
Ag1 Ag3 Cu2 65.18(6) . . ?
S1_5 Ag3 Ag2 92.55(11) . . ?
S1_6 Ag3 Ag2 87.44(9) . . ?
S1_4 Ag3 Ag2 108.65(9) . . ?
Cu1 Ag3 Ag2 56.55(5) . . ?
Ag1 Ag3 Ag2 56.84(4) . . ?
Cu2 Ag3 Ag2 53.90(5) . . ?
S1_2 Ag4 S1_1 130.26(14) . . ?
S1_2 Ag4 S2_3 114.45(13) . . ?
S1_1 Ag4 S2_3 111.84(14) . . ?
S1_2 Ag4 Cu4 48.31(10) . . ?
S1_1 Ag4 Cu4 140.93(10) . . ?
S2_3 Ag4 Cu4 96.05(10) . . ?
S1_2 Ag4 Ag1 110.26(10) . . ?
S1_1 Ag4 Ag1 111.88(10) . . ?
S2_3 Ag4 Ag1 52.13(9) . . ?
Cu4 Ag4 Ag1 64.39(6) . . ?
S1_2 Ag4 Cu3 147.68(11) . . ?
S1_1 Ag4 Cu3 48.16(9) . . ?
S2_3 Ag4 Cu3 87.96(10) . . ?
Cu4 Ag4 Cu3 109.35(6) . . ?
Ag1 Ag4 Cu3 64.29(6) . . ?
S1_2 Ag4 Ag5 93.88(10) . . ?
S1_1 Ag4 Ag5 87.96(9) . . ?
S2_3 Ag4 Ag5 108.50(9) . . ?
Cu4 Ag4 Ag5 56.55(5) . . ?
Ag1 Ag4 Ag5 56.66(4) . . ?
Cu3 Ag4 Ag5 55.60(5) . . ?
S2_1 Ag5 S2_2 130.67(15) . . ?
S2_1 Ag5 S1_4 113.88(13) . . ?
S2_2 Ag5 S1_4 111.80(13) . . ?
S2_1 Ag5 Cu3 47.65(11) . . ?
S2_2 Ag5 Cu3 141.84(11) . . ?
S1_4 Ag5 Cu3 95.88(10) . . ?
S2_1 Ag5 Cu4 148.58(10) . . ?
S2_2 Ag5 Cu4 47.99(11) . . ?
S1_4 Ag5 Cu4 87.88(9) . . ?
Cu3 Ag5 Cu4 110.70(6) . . ?
S2_1 Ag5 Ag1 110.49(12) . . ?
S2_2 Ag5 Ag1 111.62(12) . . ?
S1_4 Ag5 Ag1 52.18(10) . . ?
Cu3 Ag5 Ag1 65.19(6) . . ?
Cu4 Ag5 Ag1 64.18(6) . . ?
S2_1 Ag5 Ag4 94.39(10) . . ?
S2_2 Ag5 Ag4 87.91(10) . . ?
S1_4 Ag5 Ag4 108.70(10) . . ?
Cu3 Ag5 Ag4 57.67(4) . . ?
Cu4 Ag5 Ag4 55.90(5) . . ?
Ag1 Ag5 Ag4 56.77(4) . . ?
S2_4 Cu2 S2_6 139.77(16) . . ?
S2_4 Cu2 S1_6 120.91(16) . . ?
S2_6 Cu2 S1_6 97.27(15) . . ?
S2_4 Cu2 Ag2 118.84(13) . . ?
S2_6 Cu2 Ag2 57.03(13) . . ?
S1_6 Cu2 Ag2 102.86(13) . . ?
S2_4 Cu2 Ag3 103.39(11) . . ?
S2_6 Cu2 Ag3 109.55(14) . . ?
S1_6 Cu2 Ag3 54.27(11) . . ?
Ag2 Cu2 Ag3 68.49(5) . . ?
S2_4 Cu2 Ag1 66.73(11) . . ?
S2_6 Cu2 Ag1 113.92(14) . . ?
S1_6 Cu2 Ag1 110.31(12) . . ?
Ag2 Cu2 Ag1 58.75(5) . . ?
Ag3 Cu2 Ag1 56.84(5) . . ?
S1_3 Cu3 S2_1 139.85(16) . . ?
S1_3 Cu3 S1_1 121.56(16) . . ?
S2_1 Cu3 S1_1 96.85(16) . . ?
S1_3 Cu3 Ag5 120.70(13) . . ?
S2_1 Cu3 Ag5 55.38(13) . . ?
S1_1 Cu3 Ag5 100.47(13) . . ?
S1_3 Cu3 Ag4 104.49(12) . . ?
S2_1 Cu3 Ag4 107.72(14) . . ?
S1_1 Cu3 Ag4 54.11(10) . . ?
Ag5 Cu3 Ag4 66.73(5) . . ?
S1_3 Cu3 Ag1 68.25(12) . . ?
S2_1 Cu3 Ag1 110.93(14) . . ?
S1_1 Cu3 Ag1 110.98(11) . . ?
Ag5 Cu3 Ag1 58.01(5) . . ?
Ag4 Cu3 Ag1 57.45(5) . . ?
S2_4 Cu4 S1_2 137.88(16) . . ?
S2_4 Cu4 S2_2 123.55(16) . . ?
S1_2 Cu4 S2_2 96.41(16) . . ?
S2_4 Cu4 Ag4 120.02(14) . . ?
S1_2 Cu4 Ag4 55.11(11) . . ?
S2_2 Cu4 Ag4 101.51(13) . . ?
S2_4 Cu4 Ag5 105.86(11) . . ?
S1_2 Cu4 Ag5 108.07(12) . . ?
S2_2 Cu4 Ag5 55.18(14) . . ?
Ag4 Cu4 Ag5 67.55(5) . . ?
S2_4 Cu4 Ag1 67.86(12) . . ?
S1_2 Cu4 Ag1 111.15(13) . . ?
S2_2 Cu4 Ag1 112.90(15) . . ?
Ag4 Cu4 Ag1 58.59(5) . . ?
Ag5 Cu4 Ag1 58.30(5) . . ?
P1_10 Cu5 P2_10 89.46(16) . . ?
P1_10 Cu5 P1_9 117.91(17) . . ?
P2_10 Cu5 P1_9 122.91(17) . . ?
P1_10 Cu5 P2_9 122.91(17) . . ?
P2_10 Cu5 P2_9 119.98(17) . . ?
P1_9 Cu5 P2_9 87.37(17) . . ?
S1_3 Cu1 S1_5 136.36(18) . . ?
S1_3 Cu1 S2_5 124.26(18) . . ?
S1_5 Cu1 S2_5 97.03(18) . . ?
S1_3 Cu1 Ag3 119.50(15) . . ?
S1_5 Cu1 Ag3 54.70(12) . . ?
S2_5 Cu1 Ag3 102.52(14) . . ?
S1_3 Cu1 Ag2 108.92(12) . . ?
S1_5 Cu1 Ag2 106.65(13) . . ?
S2_5 Cu1 Ag2 53.97(15) . . ?
Ag3 Cu1 Ag2 67.79(5) . . ?
S1_3 Cu1 Ag1 69.28(12) . . ?
S1_5 Cu1 Ag1 110.81(14) . . ?
S2_5 Cu1 Ag1 111.83(15) . . ?
Ag3 Cu1 Ag1 58.17(5) . . ?
Ag2 Cu1 Ag1 58.66(5) . . ?
C6_1 C1_1 C2_1 118.6(7) . . ?
C6_1 C1_1 S1_1 118.1(6) . . ?
C2_1 C1_1 S1_1 123.3(6) . . ?
C3_1 C2_1 C1_1 117.9(7) . . ?
C3_1 C2_1 S2_1 118.7(7) . . ?
C1_1 C2_1 S2_1 123.3(6) . . ?
F1_1 C3_1 C4_1 118.4(9) . . ?
F1_1 C3_1 C2_1 119.2(9) . . ?
C4_1 C3_1 C2_1 122.0(8) . . ?
F2_1 C4_1 C5_1 119.5(9) . . ?
F2_1 C4_1 C3_1 120.3(10) . . ?
C5_1 C4_1 C3_1 120.1(8) . . ?
F3_1 C5_1 C6_1 120.5(9) . . ?
F3_1 C5_1 C4_1 121.0(9) . . ?
C6_1 C5_1 C4_1 118.3(8) . . ?
F4_1 C6_1 C5_1 117.5(8) . . ?
F4_1 C6_1 C1_1 119.8(8) . . ?
C5_1 C6_1 C1_1 122.7(8) . . ?
C1_1 S1_1 Cu3 97.4(3) . . ?
C1_1 S1_1 Ag4 106.3(5) . . ?
Cu3 S1_1 Ag4 77.73(12) . . ?
C2_1 S2_1 Cu3 99.1(3) . . ?
C2_1 S2_1 Ag5 99.5(6) . . ?
Cu3 S2_1 Ag5 76.97(13) . . ?
C2_2 C1_2 C6_2 119.3(7) . . ?
C2_2 C1_2 S1_2 123.3(6) . . ?
C6_2 C1_2 S1_2 117.3(6) . . ?
C3_2 C2_2 C1_2 118.5(7) . . ?
C3_2 C2_2 S2_2 118.6(7) . . ?
C1_2 C2_2 S2_2 122.9(6) . . ?
F1_2 C3_2 C4_2 117.3(9) . . ?
F1_2 C3_2 C2_2 121.1(8) . . ?
C4_2 C3_2 C2_2 121.0(9) . . ?
F2_2 C4_2 C5_2 119.1(9) . . ?
F2_2 C4_2 C3_2 120.3(9) . . ?
C5_2 C4_2 C3_2 120.6(8) . . ?
F3_2 C5_2 C6_2 121.5(9) . . ?
F3_2 C5_2 C4_2 119.3(9) . . ?
C6_2 C5_2 C4_2 118.9(8) . . ?
F4_2 C6_2 C5_2 117.1(8) . . ?
F4_2 C6_2 C1_2 121.5(8) . . ?
C5_2 C6_2 C1_2 121.2(8) . . ?
C1_2 S1_2 Cu4 98.3(3) . . ?
C1_2 S1_2 Ag4 98.4(5) . . ?
Cu4 S1_2 Ag4 76.58(13) . . ?
C2_2 S2_2 Cu4 98.8(3) . . ?
C2_2 S2_2 Ag5 105.4(7) . . ?
Cu4 S2_2 Ag5 76.83(16) . . ?
C6_3 C1_3 C2_3 118.1(7) . . ?
C6_3 C1_3 S1_3 116.7(7) . . ?
C2_3 C1_3 S1_3 125.2(7) . . ?
C3_3 C2_3 C1_3 118.1(8) . . ?
C3_3 C2_3 S2_3 115.5(7) . . ?
C1_3 C2_3 S2_3 126.4(7) . . ?
F1_3 C3_3 C4_3 117.0(9) . . ?
F1_3 C3_3 C2_3 120.1(9) . . ?
C4_3 C3_3 C2_3 122.8(9) . . ?
F2_3 C4_3 C3_3 120.7(11) . . ?
F2_3 C4_3 C5_3 120.1(11) . . ?
C3_3 C4_3 C5_3 119.1(9) . . ?
F3_3 C5_3 C6_3 122.0(11) . . ?
F3_3 C5_3 C4_3 118.4(10) . . ?
C6_3 C5_3 C4_3 119.1(9) . . ?
F4_3 C6_3 C5_3 116.2(9) . . ?
F4_3 C6_3 C1_3 121.1(9) . . ?
C5_3 C6_3 C1_3 122.6(9) . . ?
C1_3 S1_3 Cu1 102.6(5) . . ?
C1_3 S1_3 Cu3 99.7(5) . . ?
Cu1 S1_3 Cu3 136.4(2) . . ?
C2_3 S2_3 Ag1 114.4(4) . . ?
C2_3 S2_3 Ag4 97.5(4) . . ?
Ag1 S2_3 Ag4 71.30(13) . . ?
C2_3 S2_3 Ag2 106.5(4) . . ?
Ag1 S2_3 Ag2 71.41(11) . . ?
Ag4 S2_3 Ag2 141.43(17) . . ?
C2_4 C1_4 C6_4 120.0 . . ?
C2_4 C1_4 S1_4 126.7(4) . . ?
C6_4 C1_4 S1_4 113.1(4) . . ?
C1_4 C2_4 C3_4 120.0 . . ?
C1_4 C2_4 S2_4 124.8(4) . . ?
C3_4 C2_4 S2_4 115.2(4) . . ?
F1_4 C3_4 C2_4 122.8(6) . . ?
F1_4 C3_4 C4_4 117.2(6) . . ?
C2_4 C3_4 C4_4 120.0 . . ?
F2_4 C4_4 C5_4 120.6(7) . . ?
F2_4 C4_4 C3_4 119.0(8) . . ?
C5_4 C4_4 C3_4 120.0 . . ?
F3_4 C5_4 C4_4 119.4(8) . . ?
F3_4 C5_4 C6_4 120.6(8) . . ?
C4_4 C5_4 C6_4 120.0 . . ?
F4_4 C6_4 C5_4 118.0(7) . . ?
F4_4 C6_4 C1_4 122.0(7) . . ?
C5_4 C6_4 C1_4 120.0 . . ?
C1_4 S1_4 Ag1 113.1(3) . . ?
C1_4 S1_4 Ag5 102.4(4) . . ?
Ag1 S1_4 Ag5 71.18(11) . . ?
C1_4 S1_4 Ag3 98.7(4) . . ?
Ag1 S1_4 Ag3 70.73(12) . . ?
Ag5 S1_4 Ag3 141.25(16) . . ?
C2_4 S2_4 Cu2 100.0(4) . . ?
C2_4 S2_4 Cu4 104.3(4) . . ?
Cu2 S2_4 Cu4 138.2(2) . . ?
C6_5 C1_5 C2_5 118.4(8) . . ?
C6_5 C1_5 S1_5 116.8(7) . . ?
C2_5 C1_5 S1_5 124.7(7) . . ?
C3_5 C2_5 C1_5 119.1(8) . . ?
C3_5 C2_5 S2_5 118.3(7) . . ?
C1_5 C2_5 S2_5 122.6(7) . . ?
F1_5 C3_5 C4_5 116.7(10) . . ?
F1_5 C3_5 C2_5 121.2(10) . . ?
C4_5 C3_5 C2_5 121.7(9) . . ?
F2_5 C4_5 C5_5 120.4(10) . . ?
F2_5 C4_5 C3_5 120.0(10) . . ?
C5_5 C4_5 C3_5 119.6(9) . . ?
F3_5 C5_5 C4_5 120.1(10) . . ?
F3_5 C5_5 C6_5 120.3(10) . . ?
C4_5 C5_5 C6_5 119.4(9) . . ?
F4_5 C6_5 C5_5 118.2(9) . . ?
F4_5 C6_5 C1_5 120.1(9) . . ?
C5_5 C6_5 C1_5 121.6(9) . . ?
C1_5 S1_5 Cu1 97.7(4) . . ?
C1_5 S1_5 Ag3 98.7(6) . . ?
Cu1 S1_5 Ag3 77.38(14) . . ?
C2_5 S2_5 Cu1 97.9(4) . . ?
C2_5 S2_5 Ag2 103.7(6) . . ?
Cu1 S2_5 Ag2 77.50(17) . . ?
C6_6 C1_6 C2_6 118.8(7) . . ?
C6_6 C1_6 S1_6 117.4(6) . . ?
C2_6 C1_6 S1_6 123.8(6) . . ?
C3_6 C2_6 C1_6 118.1(7) . . ?
C3_6 C2_6 S2_6 118.4(6) . . ?
C1_6 C2_6 S2_6 123.0(6) . . ?
F1_6 C3_6 C4_6 117.2(9) . . ?
F1_6 C3_6 C2_6 121.0(8) . . ?
C4_6 C3_6 C2_6 121.8(8) . . ?
F2_6 C4_6 C5_6 119.5(9) . . ?
F2_6 C4_6 C3_6 120.2(9) . . ?
C5_6 C4_6 C3_6 120.2(8) . . ?
F3_6 C5_6 C4_6 119.2(9) . . ?
F3_6 C5_6 C6_6 122.2(9) . . ?
C4_6 C5_6 C6_6 118.6(8) . . ?
F4_6 C6_6 C5_6 116.4(8) . . ?
F4_6 C6_6 C1_6 121.3(8) . . ?
C5_6 C6_6 C1_6 122.2(8) . . ?
C1_6 S1_6 Cu2 97.0(3) . . ?
C1_6 S1_6 Ag3 107.8(5) . . ?
Cu2 S1_6 Ag3 77.55(13) . . ?
C2_6 S2_6 Cu2 98.8(3) . . ?
C2_6 S2_6 Ag2 100.9(5) . . ?
Cu2 S2_6 Ag2 74.63(14) . . ?
C2_7 C1_7 C6_7 120.0 . . ?
C2_7 C1_7 P1_7 120.6(5) . . ?
C6_7 C1_7 P1_7 119.4(5) . . ?
C3_7 C2_7 C1_7 120.0 . . ?
C2_7 C3_7 C4_7 120.0 . . ?
C5_7 C4_7 C3_7 120.0 . . ?
C4_7 C5_7 C6_7 120.0 . . ?
C5_7 C6_7 C1_7 120.0 . . ?
C8_7 C7_7 C12_7 120.0 . . ?
C8_7 C7_7 P1_7 117.1(5) . . ?
C12_7 C7_7 P1_7 122.9(5) . . ?
C9_7 C8_7 C7_7 120.0 . . ?
C10_7 C9_7 C8_7 120.0 . . ?
C9_7 C10_7 C11_7 120.0 . . ?
C12_7 C11_7 C10_7 120.0 . . ?
C11_7 C12_7 C7_7 120.0 . . ?
C14_7 C13_7 C18_7 120.0 . . ?
C14_7 C13_7 P1_7 122.0(7) . . ?
C18_7 C13_7 P1_7 118.0(7) . . ?
C13_7 C14_7 C15_7 120.0 . . ?
C16_7 C15_7 C14_7 120.0 . . ?
C17_7 C16_7 C15_7 120.0 . . ?
C16_7 C17_7 C18_7 120.0 . . ?
C17_7 C18_7 C13_7 120.0 . . ?
C20_7 C19_7 C24_7 120.0 . . ?
C20_7 C19_7 P1_7 118.1(6) . . ?
C24_7 C19_7 P1_7 121.8(6) . . ?
C21_7 C20_7 C19_7 120.0 . . ?
C22_7 C21_7 C20_7 120.0 . . ?
C23_7 C22_7 C21_7 120.0 . . ?
C22_7 C23_7 C24_7 120.0 . . ?
C23_7 C24_7 C19_7 120.0 . . ?
C1_7 P1_7 C13_7 111.7(5) . . ?
C1_7 P1_7 C19_7 109.7(4) . . ?
C13_7 P1_7 C19_7 105.6(6) . . ?
C1_7 P1_7 C7_7 107.6(5) . . ?
C13_7 P1_7 C7_7 111.0(5) . . ?
C19_7 P1_7 C7_7 111.3(5) . . ?
C2_8 C1_8 C6_8 120.0 . . ?
C2_8 C1_8 P1_8 121.4(6) . . ?
C6_8 C1_8 P1_8 118.6(6) . . ?
C1_8 C2_8 C3_8 120.0 . . ?
C4_8 C3_8 C2_8 120.0 . . ?
C5_8 C4_8 C3_8 120.0 . . ?
C6_8 C5_8 C4_8 120.0 . . ?
C5_8 C6_8 C1_8 120.0 . . ?
C8_8 C7_8 C12_8 120.0 . . ?
C8_8 C7_8 P1_8 117.6(6) . . ?
C12_8 C7_8 P1_8 122.4(6) . . ?
C7_8 C8_8 C9_8 120.0 . . ?
C10_8 C9_8 C8_8 120.0 . . ?
C11_8 C10_8 C9_8 120.0 . . ?
C10_8 C11_8 C12_8 120.0 . . ?
C11_8 C12_8 C7_8 120.0 . . ?
C14_8 C13_8 C18_8 120.0 . . ?
C14_8 C13_8 P1_8 121.0(5) . . ?
C18_8 C13_8 P1_8 119.0(5) . . ?
C13_8 C14_8 C15_8 120.0 . . ?
C16_8 C15_8 C14_8 120.0 . . ?
C15_8 C16_8 C17_8 120.0 . . ?
C16_8 C17_8 C18_8 120.0 . . ?
C17_8 C18_8 C13_8 120.0 . . ?
C20_8 C19_8 C24_8 120.0 . . ?
C20_8 C19_8 P1_8 119.5(5) . . ?
C24_8 C19_8 P1_8 120.4(5) . . ?
C21_8 C20_8 C19_8 120.0 . . ?
C20_8 C21_8 C22_8 120.0 . . ?
C21_8 C22_8 C23_8 120.0 . . ?
C24_8 C23_8 C22_8 120.0 . . ?
C23_8 C24_8 C19_8 120.0 . . ?
C7_8 P1_8 C19_8 110.2(5) . . ?
C7_8 P1_8 C13_8 110.9(5) . . ?
C19_8 P1_8 C13_8 106.5(5) . . ?
C7_8 P1_8 C1_8 108.1(5) . . ?
C19_8 P1_8 C1_8 111.8(5) . . ?
C13_8 P1_8 C1_8 109.3(5) . . ?
C7_9 P1_9 C1_9 108.7(5) . . ?
C7_9 P1_9 C13_9 103.7(7) . . ?
C1_9 P1_9 C13_9 101.1(6) . . ?
C7_9 P1_9 Cu5 121.9(5) . . ?
C1_9 P1_9 Cu5 113.7(4) . . ?
C13_9 P1_9 Cu5 105.0(5) . . ?
C2_9 C1_9 C6_9 120.0 . . ?
C2_9 C1_9 P1_9 123.8(5) . . ?
C6_9 C1_9 P1_9 116.0(5) . . ?
C3_9 C2_9 C1_9 120.0 . . ?
C4_9 C3_9 C2_9 120.0 . . ?
C5_9 C4_9 C3_9 120.0 . . ?
C4_9 C5_9 C6_9 120.0 . . ?
C5_9 C6_9 C1_9 120.0 . . ?
C8_9 C7_9 C12_9 120.0 . . ?
C8_9 C7_9 P1_9 121.5(6) . . ?
C12_9 C7_9 P1_9 118.3(6) . . ?
C7_9 C8_9 C9_9 120.0 . . ?
C10_9 C9_9 C8_9 120.0 . . ?
C11_9 C10_9 C9_9 120.0 . . ?
C12_9 C11_9 C10_9 120.0 . . ?
C11_9 C12_9 C7_9 120.0 . . ?
C15_9 C13_9 C14_9 113.6(14) . . ?
C15_9 C13_9 P1_9 116.8(12) . . ?
C14_9 C13_9 P1_9 106.4(10) . . ?
C16_9 C14_9 C13_9 112.7(14) . . ?
C16_9 C14_9 P2_9 116.2(13) . . ?
C13_9 C14_9 P2_9 108.8(10) . . ?
C23_9 P2_9 C17_9 103.8(7) . . ?
C23_9 P2_9 C14_9 107.2(7) . . ?
C17_9 P2_9 C14_9 103.4(7) . . ?
C23_9 P2_9 Cu5 119.3(5) . . ?
C17_9 P2_9 Cu5 115.9(4) . . ?
C14_9 P2_9 Cu5 105.9(5) . . ?
C18_9 C17_9 C22_9 120.0 . . ?
C18_9 C17_9 P2_9 115.9(7) . . ?
C22_9 C17_9 P2_9 123.8(7) . . ?
C19_9 C18_9 C17_9 120.0 . . ?
C20_9 C19_9 C18_9 120.0 . . ?
C21_9 C20_9 C19_9 120.0 . . ?
C22_9 C21_9 C20_9 120.0 . . ?
C21_9 C22_9 C17_9 120.0 . . ?
C24_9 C23_9 C28_9 120.0 . . ?
C24_9 C23_9 P2_9 121.4(10) . . ?
C28_9 C23_9 P2_9 118.6(10) . . ?
C25_9 C24_9 C23_9 120.0 . . ?
C24_9 C25_9 C26_9 120.0 . . ?
C27_9 C26_9 C25_9 120.0 . . ?
C26_9 C27_9 C28_9 120.0 . . ?
C27_9 C28_9 C23_9 120.0 . . ?
C7_10 P1_10 C1_10 106.9(7) . . ?
C7_10 P1_10 C13_10 106.6(6) . . ?
C1_10 P1_10 C13_10 101.0(7) . . ?
C7_10 P1_10 Cu5 120.9(5) . . ?
C1_10 P1_10 Cu5 114.3(4) . . ?
C13_10 P1_10 Cu5 105.0(4) . . ?
C2_10 C1_10 C6_10 120.0 . . ?
C2_10 C1_10 P1_10 121.6(7) . . ?
C6_10 C1_10 P1_10 118.2(7) . . ?
C3_10 C2_10 C1_10 120.0 . . ?
C2_10 C3_10 C4_10 120.0 . . ?
C3_10 C4_10 C5_10 120.0 . . ?
C6_10 C5_10 C4_10 120.0 . . ?
C5_10 C6_10 C1_10 120.0 . . ?
C8_10 C7_10 C12_10 120.0 . . ?
C8_10 C7_10 P1_10 120.1(8) . . ?
C12_10 C7_10 P1_10 119.6(8) . . ?
C9_10 C8_10 C7_10 120.0 . . ?
C8_10 C9_10 C10_10 120.0 . . ?
C11_10 C10_10 C9_10 120.0 . . ?
C10_10 C11_10 C12_10 120.0 . . ?
C11_10 C12_10 C7_10 120.0 . . ?
C15_10 C13_10 C14_10 111.2(10) . . ?
C15_10 C13_10 P1_10 116.8(12) . . ?
C14_10 C13_10 P1_10 106.5(8) . . ?
C16_10 C14_10 C13_10 110.8(10) . . ?
C16_10 C14_10 P2_10 111.8(12) . . ?
C13_10 C14_10 P2_10 109.4(8) . . ?
C23_10 P2_10 C14_10 105.4(6) . . ?
C23_10 P2_10 C17_10 106.7(6) . . ?
C14_10 P2_10 C17_10 102.9(8) . . ?
C23_10 P2_10 Cu5 121.6(5) . . ?
C14_10 P2_10 Cu5 103.3(4) . . ?
C17_10 P2_10 Cu5 114.8(5) . . ?
C18_10 C17_10 C22_10 120.0 . . ?
C18_10 C17_10 P2_10 117.7(8) . . ?
C22_10 C17_10 P2_10 122.2(8) . . ?
C17_10 C18_10 C19_10 120.0 . . ?
C20_10 C19_10 C18_10 120.0 . . ?
C19_10 C20_10 C21_10 120.0 . . ?
C22_10 C21_10 C20_10 120.0 . . ?
C21_10 C22_10 C17_10 120.0 . . ?
C24_10 C23_10 C28_10 120.0 . . ?
C24_10 C23_10 P2_10 119.9(7) . . ?
C28_10 C23_10 P2_10 119.9(7) . . ?
C25_10 C24_10 C23_10 120.0 . . ?
C26_10 C25_10 C24_10 120.0 . . ?
C27_10 C26_10 C25_10 120.0 . . ?
C26_10 C27_10 C28_10 120.0 . . ?
C27_10 C28_10 C23_10 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 S2_3 2.462(4) . ?
Ag1 S1_4 2.462(4) . ?
Ag1 Ag3 2.9378(18) . ?
Ag1 Ag5 2.950(2) . ?
Ag1 Ag4 2.9537(18) . ?
Ag1 Ag2 2.974(2) . ?
Ag1 Cu1 3.110(3) . ?
Ag1 Cu4 3.121(3) . ?
Ag1 Cu3 3.157(3) . ?
Ag1 Cu2 3.185(3) . ?
Ag2 S2_5 2.447(5) . ?
Ag2 S2_6 2.477(5) . ?
Ag2 S2_3 2.629(4) . ?
Ag2 Cu2 2.847(2) . ?
Ag2 Cu1 2.954(2) . ?
Ag2 Ag3 3.2785(17) . ?
Ag3 S1_5 2.445(4) . ?
Ag3 S1_6 2.474(4) . ?
Ag3 S1_4 2.609(5) . ?
Ag3 Cu1 2.924(2) . ?
Ag3 Cu2 2.975(2) . ?
Ag4 S1_2 2.448(4) . ?
Ag4 S1_1 2.471(4) . ?
Ag4 S2_3 2.602(5) . ?
Ag4 Cu4 2.903(2) . ?
Ag4 Cu3 2.980(2) . ?
Ag4 Ag5 3.2400(16) . ?
Ag5 S2_1 2.458(5) . ?
Ag5 S2_2 2.466(5) . ?
Ag5 S1_4 2.603(4) . ?
Ag5 Cu3 2.910(2) . ?
Ag5 Cu4 2.925(2) . ?
Cu2 S2_4 2.173(4) . ?
Cu2 S2_6 2.206(5) . ?
Cu2 S1_6 2.271(4) . ?
Cu3 S1_3 2.191(5) . ?
Cu3 S2_1 2.207(5) . ?
Cu3 S1_1 2.272(4) . ?
Cu4 S2_4 2.198(4) . ?
Cu4 S1_2 2.229(4) . ?
Cu4 S2_2 2.232(5) . ?
Cu5 P1_10 2.256(4) . ?
Cu5 P2_10 2.258(4) . ?
Cu5 P1_9 2.261(4) . ?
Cu5 P2_9 2.287(4) . ?
Cu1 S1_3 2.187(4) . ?
Cu1 S1_5 2.224(4) . ?
Cu1 S2_5 2.267(6) . ?
C1_1 C6_1 1.391(9) . ?
C1_1 C2_1 1.411(9) . ?
C1_1 S1_1 1.770(8) . ?
C2_1 C3_1 1.387(9) . ?
C2_1 S2_1 1.762(8) . ?
C3_1 F1_1 1.318(10) . ?
C3_1 C4_1 1.381(10) . ?
C4_1 F2_1 1.343(10) . ?
C4_1 C5_1 1.380(10) . ?
C5_1 F3_1 1.328(9) . ?
C5_1 C6_1 1.376(10) . ?
C6_1 F4_1 1.345(9) . ?
C1_2 C2_2 1.398(9) . ?
C1_2 C6_2 1.401(9) . ?
C1_2 S1_2 1.770(8) . ?
C2_2 C3_2 1.389(9) . ?
C2_2 S2_2 1.755(8) . ?
C3_2 F1_2 1.309(10) . ?
C3_2 C4_2 1.382(10) . ?
C4_2 F2_2 1.339(10) . ?
C4_2 C5_2 1.377(10) . ?
C5_2 F3_2 1.328(9) . ?
C5_2 C6_2 1.376(10) . ?
C6_2 F4_2 1.348(10) . ?
C1_3 C6_3 1.390(9) . ?
C1_3 C2_3 1.408(9) . ?
C1_3 S1_3 1.775(8) . ?
C2_3 C3_3 1.387(9) . ?
C2_3 S2_3 1.753(8) . ?
C3_3 F1_3 1.326(10) . ?
C3_3 C4_3 1.373(10) . ?
C4_3 F2_3 1.346(10) . ?
C4_3 C5_3 1.379(10) . ?
C5_3 F3_3 1.326(10) . ?
C5_3 C6_3 1.375(10) . ?
C6_3 F4_3 1.350(10) . ?
C1_4 C2_4 1.3900 . ?
C1_4 C6_4 1.3900 . ?
C1_4 S1_4 1.779(6) . ?
C2_4 C3_4 1.3900 . ?
C2_4 S2_4 1.769(5) . ?
C3_4 F1_4 1.316(8) . ?
C3_4 C4_4 1.3900 . ?
C4_4 F2_4 1.343(9) . ?
C4_4 C5_4 1.3900 . ?
C5_4 F3_4 1.327(8) . ?
C5_4 C6_4 1.3900 . ?
C6_4 F4_4 1.349(8) . ?
C1_5 C6_5 1.396(9) . ?
C1_5 C2_5 1.406(9) . ?
C1_5 S1_5 1.773(8) . ?
C2_5 C3_5 1.386(10) . ?
C2_5 S2_5 1.763(9) . ?
C3_5 F1_5 1.325(10) . ?
C3_5 C4_5 1.384(10) . ?
C4_5 F2_5 1.347(10) . ?
C4_5 C5_5 1.381(10) . ?
C5_5 F3_5 1.336(10) . ?
C5_5 C6_5 1.386(10) . ?
C6_5 F4_5 1.345(10) . ?
C1_6 C6_6 1.391(9) . ?
C1_6 C2_6 1.409(9) . ?
C1_6 S1_6 1.773(8) . ?
C2_6 C3_6 1.386(9) . ?
C2_6 S2_6 1.771(8) . ?
C3_6 F1_6 1.323(10) . ?
C3_6 C4_6 1.382(10) . ?
C4_6 F2_6 1.336(10) . ?
C4_6 C5_6 1.378(10) . ?
C5_6 F3_6 1.334(9) . ?
C5_6 C6_6 1.378(9) . ?
C6_6 F4_6 1.342(9) . ?
C1_7 C2_7 1.3900 . ?
C1_7 C6_7 1.3900 . ?
C1_7 P1_7 1.781(7) . ?
C2_7 C3_7 1.3900 . ?
C3_7 C4_7 1.3900 . ?
C4_7 C5_7 1.3900 . ?
C5_7 C6_7 1.3900 . ?
C7_7 C8_7 1.3900 . ?
C7_7 C12_7 1.3900 . ?
C7_7 P1_7 1.792(7) . ?
C8_7 C9_7 1.3900 . ?
C9_7 C10_7 1.3900 . ?
C10_7 C11_7 1.3900 . ?
C11_7 C12_7 1.3900 . ?
C13_7 C14_7 1.3900 . ?
C13_7 C18_7 1.3900 . ?
C13_7 P1_7 1.782(9) . ?
C14_7 C15_7 1.3900 . ?
C15_7 C16_7 1.3900 . ?
C16_7 C17_7 1.3900 . ?
C17_7 C18_7 1.3900 . ?
C19_7 C20_7 1.3900 . ?
C19_7 C24_7 1.3900 . ?
C19_7 P1_7 1.787(8) . ?
C20_7 C21_7 1.3900 . ?
C21_7 C22_7 1.3900 . ?
C22_7 C23_7 1.3900 . ?
C23_7 C24_7 1.3900 . ?
C1_8 C2_8 1.3900 . ?
C1_8 C6_8 1.3900 . ?
C1_8 P1_8 1.810(10) . ?
C2_8 C3_8 1.3900 . ?
C3_8 C4_8 1.3900 . ?
C4_8 C5_8 1.3900 . ?
C5_8 C6_8 1.3900 . ?
C7_8 C8_8 1.3900 . ?
C7_8 C12_8 1.3900 . ?
C7_8 P1_8 1.763(8) . ?
C8_8 C9_8 1.3900 . ?
C9_8 C10_8 1.3900 . ?
C10_8 C11_8 1.3900 . ?
C11_8 C12_8 1.3900 . ?
C13_8 C14_8 1.3900 . ?
C13_8 C18_8 1.3900 . ?
C13_8 P1_8 1.796(7) . ?
C14_8 C15_8 1.3900 . ?
C15_8 C16_8 1.3900 . ?
C16_8 C17_8 1.3900 . ?
C17_8 C18_8 1.3900 . ?
C19_8 C20_8 1.3900 . ?
C19_8 C24_8 1.3900 . ?
C19_8 P1_8 1.794(7) . ?
C20_8 C21_8 1.3900 . ?
C21_8 C22_8 1.3900 . ?
C22_8 C23_8 1.3900 . ?
C23_8 C24_8 1.3900 . ?
P1_9 C7_9 1.825(9) . ?
P1_9 C1_9 1.834(7) . ?
P1_9 C13_9 1.863(14) . ?
C1_9 C2_9 1.3900 . ?
C1_9 C6_9 1.3900 . ?
C2_9 C3_9 1.3900 . ?
C3_9 C4_9 1.3900 . ?
C4_9 C5_9 1.3900 . ?
C5_9 C6_9 1.3900 . ?
C7_9 C8_9 1.3900 . ?
C7_9 C12_9 1.3900 . ?
C8_9 C9_9 1.3900 . ?
C9_9 C10_9 1.3900 . ?
C10_9 C11_9 1.3900 . ?
C11_9 C12_9 1.3900 . ?
C13_9 C15_9 1.525(19) . ?
C13_9 C14_9 1.550(19) . ?
C14_9 C16_9 1.494(19) . ?
C14_9 P2_9 1.870(15) . ?
P2_9 C23_9 1.844(11) . ?
P2_9 C17_9 1.856(9) . ?
C17_9 C18_9 1.3900 . ?
C17_9 C22_9 1.3900 . ?
C18_9 C19_9 1.3900 . ?
C19_9 C20_9 1.3900 . ?
C20_9 C21_9 1.3900 . ?
C21_9 C22_9 1.3900 . ?
C23_9 C24_9 1.3900 . ?
C23_9 C28_9 1.3900 . ?
C24_9 C25_9 1.3900 . ?
C25_9 C26_9 1.3900 . ?
C26_9 C27_9 1.3900 . ?
C27_9 C28_9 1.3900 . ?
P1_10 C7_10 1.813(10) . ?
P1_10 C1_10 1.862(8) . ?
P1_10 C13_10 1.865(9) . ?
C1_10 C2_10 1.3900 . ?
C1_10 C6_10 1.3900 . ?
C2_10 C3_10 1.3900 . ?
C3_10 C4_10 1.3900 . ?
C4_10 C5_10 1.3900 . ?
C5_10 C6_10 1.3900 . ?
C7_10 C8_10 1.3900 . ?
C7_10 C12_10 1.3900 . ?
C8_10 C9_10 1.3900 . ?
C9_10 C10_10 1.3900 . ?
C10_10 C11_10 1.3900 . ?
C11_10 C12_10 1.3900 . ?
C13_10 C15_10 1.528(11) . ?
C13_10 C14_10 1.548(11) . ?
C14_10 C16_10 1.526(11) . ?
C14_10 P2_10 1.870(9) . ?
P2_10 C23_10 1.846(10) . ?
P2_10 C17_10 1.878(8) . ?
C17_10 C18_10 1.3900 . ?
C17_10 C22_10 1.3900 . ?
C18_10 C19_10 1.3900 . ?
C19_10 C20_10 1.3900 . ?
C20_10 C21_10 1.3900 . ?
C21_10 C22_10 1.3900 . ?
C23_10 C24_10 1.3900 . ?
C23_10 C28_10 1.3900 . ?
C24_10 C25_10 1.3900 . ?
C25_10 C26_10 1.3900 . ?
C26_10 C27_10 1.3900 . ?
C27_10 C28_10 1.3900 . ?
