#------------------------------------------------------------------------------
#$Date: 2025-07-06 16:36:45 +0300 (Sun, 06 Jul 2025) $
#$Revision: 300532 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/13/43/7134377.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7134377
loop_
_publ_author_name
'Nong, Yan'
'Dai, Juefei'
'Yang, Chao'
'Su, Haifeng'
'Feng, Chengcheng'
'Shi, Chuanhua'
'Zhang, Zhixun'
'Yu, Xianyong'
'Zhang, Xueji'
'Yang, Huayan'
_publ_section_title
;
 Highly stable bidentate thiol-protected Ag5Cu4 nanoclusters: a stable
 catalyst for enhanced Knoevenagel condensation
;
_journal_issue                   38
_journal_name_full               'Chemical Communications'
_journal_page_first              6933
_journal_page_last               6936
_journal_paper_doi               10.1039/D5CC00825E
_journal_volume                  61
_journal_year                    2025
_chemical_absolute_configuration ad
_chemical_formula_moiety
{[Ag5Cu4(SSC6F4)6][2(P(C6H5)4)Cu(C28H28P2)2](C6H14)6}
_chemical_formula_sum            'C176 H180 Ag5 Cu5 F24 P6 S12'
_chemical_formula_weight         4178.78
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_method
;FinalCif V118 by Daniel Kratzert, Freiburg 2025,
https://dkratzert.de/finalcif.html
;
_audit_update_record
;
2025-04-01 deposited with the CCDC.	2025-04-03 downloaded from the CCDC.
;
_cell_angle_alpha                96.620(3)
_cell_angle_beta                 104.668(4)
_cell_angle_gamma                111.928(3)
_cell_formula_units_Z            1
_cell_length_a                   14.1112(19)
_cell_length_b                   15.576(2)
_cell_length_c                   21.554(3)
_cell_measurement_reflns_used    9922
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      23.685
_cell_measurement_theta_min      2.4625
_cell_volume                     4133.7(10)
_computing_cell_refinement       'SAINT V8.40B'
_computing_data_collection
'Bruker BIS V6.2.16/2021-10-23 && APEX5 2023.9-2'
_computing_data_reduction        'SAINT V8.40B'
_computing_molecular_graphics    Diamond
_computing_publication_material  'Chemical communications'
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_structure_solution    'SHELXT (G. Sheldrick)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON III'
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE dual wavelength Mo/Cu'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_measurement_specimen_support 'MiTeGen micromount'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0784
_diffrn_reflns_av_unetI/netI     0.0811
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            63227
_diffrn_reflns_point_group_measured_fraction_full 0.930
_diffrn_reflns_point_group_measured_fraction_max 0.930
_diffrn_reflns_theta_full        23.787
_diffrn_reflns_theta_max         23.787
_diffrn_reflns_theta_min         1.947
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_exptl_absorpt_coefficient_mu    1.498
_exptl_absorpt_correction_T_max  0.2571
_exptl_absorpt_correction_T_min  0.2167
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_description       Rod-like
_exptl_crystal_F_000             2114
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.1
_refine_diff_density_max         3.490
_refine_diff_density_min         -1.227
_refine_diff_density_rms         0.194
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.20(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1527
_refine_ls_number_reflns         23526
_refine_ls_number_restraints     5349
_refine_ls_restrained_S_all      0.965
_refine_ls_R_factor_all          0.1215
_refine_ls_R_factor_gt           0.0884
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0678P)²+89.9883P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2083
_refine_ls_wR_factor_ref         0.2308
_reflns_Friedel_coverage         0.866
_reflns_Friedel_fraction_full    0.863
_reflns_Friedel_fraction_max     0.863
_reflns_number_gt                16428
_reflns_number_total             23526
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5cc00825e3.cif
_cod_data_source_block           mo_Ag5Cu4_R_0m_sq
_cod_depositor_comments
'Adding full bibliography for 7134376--7134377.cif.'
_cod_database_code               7134377
_shelx_shelxl_version_number     2019/2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_diffrn_measurement_ambient_temperature_device_make 'Oxford Cryostream 800'
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.5971(2) 0.85462(19) 0.19408(14) 0.0387(7) Uani 1 1 d . U . . .
Ag3 Ag 0.4989(4) 0.8105(3) 0.2973(2) 0.0521(5) Uani 1 1 d . U . . .
Ag4 Ag 0.4079(2) 0.77319(19) 0.40385(14) 0.0401(7) Uani 1 1 d . U . . .
Ag5 Ag 0.4931(2) 0.63571(18) 0.33332(13) 0.0345(7) Uani 1 1 d . U . . .
Ag1 Ag 0.5158(2) 0.99218(18) 0.26532(13) 0.0354(7) Uani 1 1 d . U . . .
Cu1 Cu 0.3704(4) 0.8249(3) 0.1612(2) 0.0369(10) Uani 1 1 d . U . . .
Cu2 Cu 0.2807(3) 0.6440(3) 0.2784(2) 0.0328(10) Uani 1 1 d . U . . .
Cu3 Cu 0.6360(4) 0.8054(3) 0.4374(2) 0.0373(10) Uani 1 1 d . U . . .
Cu4 Cu 0.7266(4) 0.9844(3) 0.3199(2) 0.0323(10) Uani 1 1 d . U . . .
C1_1 C 0.4861(17) 0.9555(10) 0.0853(10) 0.041(3) Uani 1 1 d DG U . . .
C2_1 C 0.4440(17) 1.0096(11) 0.1155(10) 0.041(3) Uani 1 1 d DG U . . .
C3_1 C 0.4584(18) 1.0986(11) 0.1033(10) 0.043(3) Uani 1 1 d DG U . . .
C4_1 C 0.5151(17) 1.1335(10) 0.0608(10) 0.047(4) Uani 1 1 d DG U . . .
C5_1 C 0.5572(16) 1.0794(11) 0.0306(9) 0.048(4) Uani 1 1 d DG U . . .
C6_1 C 0.5428(16) 0.9904(11) 0.0428(10) 0.046(3) Uani 1 1 d DG U . . .
F1_1 F 0.4233(15) 1.1527(12) 0.1338(9) 0.046(4) Uani 1 1 d D U . . .
F2_1 F 0.5257(19) 1.2183(12) 0.0469(11) 0.061(5) Uani 1 1 d D U . . .
F3_1 F 0.6148(18) 1.1111(15) -0.0096(10) 0.064(5) Uani 1 1 d D U . . .
F4_1 F 0.5845(17) 0.9411(14) 0.0124(10) 0.056(4) Uani 1 1 d D U . . .
S1_1 S 0.4613(9) 0.8365(7) 0.0896(5) 0.0432(19) Uani 1 1 d D U . . .
S2_1 S 0.3648(8) 0.9674(7) 0.1673(5) 0.0370(18) Uani 1 1 d D U . . .
C1_2 C 0.3318(16) 0.612(2) 0.1505(14) 0.041(3) Uani 1 1 d D U . . .
C2_2 C 0.4366(16) 0.617(2) 0.1678(14) 0.043(3) Uani 1 1 d D U . . .
C3_2 C 0.4642(16) 0.5585(17) 0.1300(12) 0.045(4) Uani 1 1 d D U . . .
C4_2 C 0.3857(16) 0.4905(16) 0.0762(12) 0.048(4) Uani 1 1 d D U . . .
C5_2 C 0.2792(17) 0.4700(19) 0.0665(14) 0.052(4) Uani 1 1 d D U . . .
C6_2 C 0.2554(18) 0.539(2) 0.0974(15) 0.047(4) Uani 1 1 d D U . . .
F1_2 F 0.5651(15) 0.5655(15) 0.1426(11) 0.057(5) Uani 1 1 d D U . . .
F2_2 F 0.4141(18) 0.4300(14) 0.0418(11) 0.071(5) Uani 1 1 d D U . . .
F3_2 F 0.2040(19) 0.4098(15) 0.0085(10) 0.081(6) Uani 1 1 d D U . . .
F4_2 F 0.1526(14) 0.5327(14) 0.0744(10) 0.054(5) Uani 1 1 d D U . . .
S1_2 S 0.2882(8) 0.6910(7) 0.1880(5) 0.0363(17) Uani 1 1 d D U . . .
S2_2 S 0.5459(8) 0.7020(7) 0.2351(5) 0.0403(16) Uani 1 1 d D U . . .
C1_3 C 0.6748(16) 1.015(2) 0.4479(15) 0.044(3) Uani 1 1 d D U . . .
C2_3 C 0.5697(16) 1.008(2) 0.4294(15) 0.046(3) Uani 1 1 d D U . . .
C3_3 C 0.5488(17) 1.0789(16) 0.4597(13) 0.050(4) Uani 1 1 d D U . . .
C4_3 C 0.6266(17) 1.1536(17) 0.5092(13) 0.055(4) Uani 1 1 d D U . . .
C5_3 C 0.7249(18) 1.1518(19) 0.5352(15) 0.058(4) Uani 1 1 d D U . . .
C6_3 C 0.7522(18) 1.091(2) 0.4991(16) 0.053(4) Uani 1 1 d D U . . .
F1_3 F 0.4481(15) 1.0715(16) 0.4477(11) 0.060(5) Uani 1 1 d D U . . .
F2_3 F 0.6027(19) 1.2167(14) 0.5448(11) 0.076(5) Uani 1 1 d D U . . .
F3_3 F 0.8041(18) 1.2349(13) 0.5771(10) 0.071(5) Uani 1 1 d D U . . .
F4_3 F 0.8588(15) 1.1093(15) 0.5154(10) 0.060(5) Uani 1 1 d D U . . .
S1_3 S 0.7204(8) 0.9378(6) 0.4112(5) 0.0371(18) Uani 1 1 d D U . . .
S2_3 S 0.4591(8) 0.9266(7) 0.3604(5) 0.0423(17) Uani 1 1 d D U . . .
C1_4 C 0.523(2) 0.6751(14) 0.5170(14) 0.043(3) Uani 1 1 d D U . . .
C2_4 C 0.567(2) 0.6238(14) 0.4863(13) 0.041(3) Uani 1 1 d D U . . .
C3_4 C 0.553(2) 0.5347(15) 0.4978(14) 0.045(3) Uani 1 1 d D U . . .
C4_4 C 0.491(2) 0.4940(16) 0.5347(14) 0.049(4) Uani 1 1 d D U . . .
C5_4 C 0.451(2) 0.5445(14) 0.5676(12) 0.050(4) Uani 1 1 d D U . . .
C6_4 C 0.459(2) 0.6307(15) 0.5537(14) 0.047(3) Uani 1 1 d D U . . .
F1_4 F 0.5982(16) 0.4845(12) 0.4706(10) 0.047(4) Uani 1 1 d D U . . .
F2_4 F 0.475(2) 0.4064(13) 0.5436(11) 0.064(5) Uani 1 1 d D U . . .
F3_4 F 0.3883(18) 0.5028(15) 0.6033(10) 0.063(5) Uani 1 1 d D U . . .
F4_4 F 0.4077(17) 0.6725(15) 0.5821(11) 0.061(5) Uani 1 1 d D U . . .
S1_4 S 0.5387(9) 0.7910(7) 0.5084(5) 0.0434(19) Uani 1 1 d D U . . .
S2_4 S 0.6414(8) 0.6653(6) 0.4328(5) 0.0353(18) Uani 1 1 d D U . . .
C1_5 C 0.224(3) 0.5644(18) 0.3933(13) 0.037(3) Uani 1 1 d D U . . .
C2_5 C 0.261(3) 0.5025(18) 0.3671(13) 0.034(3) Uani 1 1 d D U . . .
C3_5 C 0.261(3) 0.4278(18) 0.3950(13) 0.037(3) Uani 1 1 d D U . . .
C4_5 C 0.225(2) 0.4115(15) 0.4472(10) 0.041(3) Uani 1 1 d D U . . .
C5_5 C 0.186(3) 0.4694(18) 0.4735(13) 0.042(3) Uani 1 1 d D U . . .
C6_5 C 0.181(3) 0.5430(17) 0.4438(12) 0.042(3) Uani 1 1 d D U . . .
F1_5 F 0.3021(17) 0.3691(13) 0.3733(10) 0.043(4) Uani 1 1 d D U . . .
F2_5 F 0.2347(18) 0.3417(13) 0.4773(10) 0.052(5) Uani 1 1 d D U . . .
F3_5 F 0.1679(18) 0.4630(14) 0.5322(9) 0.059(4) Uani 1 1 d D U . . .
F4_5 F 0.1540(17) 0.6070(14) 0.4742(10) 0.048(4) Uani 1 1 d D U . . .
S1_5 S 0.2172(8) 0.6616(6) 0.3608(5) 0.0359(17) Uani 1 1 d D U . . .
S2_5 S 0.3046(8) 0.5114(6) 0.2968(5) 0.0317(17) Uani 1 1 d D U . . .
C1_6 C 0.784(3) 1.0605(18) 0.2060(13) 0.035(3) Uani 1 1 d D U . . .
C2_6 C 0.743(3) 1.1212(17) 0.2298(12) 0.034(3) Uani 1 1 d D U . . .
C3_6 C 0.742(3) 1.1956(18) 0.2004(13) 0.037(3) Uani 1 1 d D U . . .
C4_6 C 0.7848(18) 1.2110(14) 0.1500(10) 0.039(3) Uani 1 1 d D U . . .
C5_6 C 0.819(3) 1.1488(18) 0.1236(14) 0.040(3) Uani 1 1 d D U . . .
C6_6 C 0.817(3) 1.0721(17) 0.1510(12) 0.040(3) Uani 1 1 d D U . . .
F1_6 F 0.7048(16) 1.2558(13) 0.2216(10) 0.043(4) Uani 1 1 d D U . . .
F2_6 F 0.7819(17) 1.2846(13) 0.1226(10) 0.049(4) Uani 1 1 d D U . . .
F3_6 F 0.8629(14) 1.1667(15) 0.0753(8) 0.049(4) Uani 1 1 d D U . . .
F4_6 F 0.8643(17) 1.0193(15) 0.1290(10) 0.051(4) Uani 1 1 d D U . . .
S1_6 S 0.7903(8) 0.9627(6) 0.2386(5) 0.0353(17) Uani 1 1 d D U . . .
S2_6 S 0.7016(8) 1.1136(7) 0.3015(5) 0.0328(17) Uani 1 1 d D U . . .
C1_7 C 0.6886(10) 0.4615(14) 0.2750(10) 0.035(3) Uani 1 1 d DG U . . .
C2_7 C 0.6506(12) 0.4152(13) 0.2087(10) 0.040(4) Uani 1 1 d DG U . . .
H2_7 H 0.700051 0.416055 0.185713 0.047 Uiso 1 1 calc R U . . .
C3_7 C 0.5402(14) 0.3676(13) 0.1761(8) 0.046(4) Uani 1 1 d DG U . . .
H3_7 H 0.514245 0.335958 0.130873 0.055 Uiso 1 1 calc R U . . .
C4_7 C 0.4679(9) 0.3664(15) 0.2098(11) 0.046(4) Uani 1 1 d DG U . . .
H4_7 H 0.392470 0.333840 0.187537 0.055 Uiso 1 1 calc R U . . .
C5_7 C 0.5059(14) 0.4127(16) 0.2760(11) 0.045(4) Uani 1 1 d DG U . . .
H5_7 H 0.456500 0.411817 0.299043 0.054 Uiso 1 1 calc R U . . .
C6_7 C 0.6163(15) 0.4603(13) 0.3086(8) 0.039(4) Uani 1 1 d DG U . . .
H6_7 H 0.642305 0.491914 0.353885 0.047 Uiso 1 1 calc R U . . .
C7_7 C 0.8595(16) 0.4758(13) 0.3925(8) 0.034(3) Uani 1 1 d DG U . . .
C8_7 C 0.8211(15) 0.3778(12) 0.3852(7) 0.038(4) Uani 1 1 d DG U . . .
H8_7 H 0.783995 0.336560 0.342467 0.045 Uiso 1 1 calc R U . . .
C9_7 C 0.8369(18) 0.3401(11) 0.4403(10) 0.043(5) Uani 1 1 d DG U . . .
H9_7 H 0.810580 0.273159 0.435342 0.052 Uiso 1 1 calc R U . . .
C10_7 C 0.891(2) 0.4005(14) 0.5028(8) 0.048(5) Uani 1 1 d DG U . . .
H10_7 H 0.901923 0.374748 0.540536 0.058 Uiso 1 1 calc R U . . .
C11_7 C 0.9296(18) 0.4985(14) 0.5101(7) 0.049(5) Uani 1 1 d DG U . . .
H11_7 H 0.966681 0.539739 0.552855 0.059 Uiso 1 1 calc R U . . .
C12_7 C 0.9138(17) 0.5362(10) 0.4550(9) 0.044(4) Uani 1 1 d DG U . . .
H12_7 H 0.940098 0.603142 0.459980 0.052 Uiso 1 1 calc R U . . .
C13_7 C 0.8691(14) 0.6466(9) 0.3365(11) 0.035(3) Uani 1 1 d DG U . . .
C14_7 C 0.7916(12) 0.6818(12) 0.3179(11) 0.036(4) Uani 1 1 d DG U . . .
H14_7 H 0.718594 0.639248 0.294901 0.043 Uiso 1 1 calc R U . . .
C15_7 C 0.8210(15) 0.7793(13) 0.3330(11) 0.037(4) Uani 1 1 d DG U . . .
H15_7 H 0.768070 0.803410 0.320329 0.044 Uiso 1 1 calc R U . . .
C16_7 C 0.9278(17) 0.8417(9) 0.3667(11) 0.038(4) Uani 1 1 d DG U . . .
H16_7 H 0.947934 0.908298 0.376983 0.046 Uiso 1 1 calc R U . . .
C17_7 C 1.0053(13) 0.8064(11) 0.3852(10) 0.039(4) Uani 1 1 d DG U . . .
H17_7 H 1.078323 0.849025 0.408211 0.046 Uiso 1 1 calc R U . . .
C18_7 C 0.9759(13) 0.7089(12) 0.3701(10) 0.037(4) Uani 1 1 d DG U . . .
H18_7 H 1.028848 0.684864 0.382784 0.044 Uiso 1 1 calc R U . . .
C19_7 C 0.9027(14) 0.4968(13) 0.2685(9) 0.032(3) Uani 1 1 d DG U . . .
C20_7 C 0.9011(12) 0.5330(12) 0.2125(10) 0.035(4) Uani 1 1 d DG U . . .
H20_7 H 0.861837 0.570247 0.201953 0.042 Uiso 1 1 calc R U . . .
C21_7 C 0.9569(15) 0.5146(14) 0.1718(8) 0.036(4) Uani 1 1 d DG U . . .
H21_7 H 0.955782 0.539335 0.133423 0.043 Uiso 1 1 calc R U . . .
C22_7 C 1.0143(16) 0.4600(14) 0.1871(9) 0.036(4) Uani 1 1 d DG U . . .
H22_7 H 1.052474 0.447492 0.159298 0.043 Uiso 1 1 calc R U . . .
C23_7 C 1.0160(15) 0.4238(13) 0.2432(10) 0.035(4) Uani 1 1 d DG U . . .
H23_7 H 1.055222 0.386560 0.253702 0.042 Uiso 1 1 calc R U . . .
C24_7 C 0.9602(16) 0.4422(13) 0.2839(9) 0.032(3) Uani 1 1 d DG U . . .
H24_7 H 0.961277 0.417471 0.322234 0.038 Uiso 1 1 calc R U . . .
P1_7 P 0.8303(7) 0.5213(6) 0.3186(5) 0.0313(18) Uani 1 1 d D U . . .
C1_8 C 0.1426(15) -0.0133(8) 0.2651(11) 0.036(3) Uani 1 1 d DG U . . .
C2_8 C 0.2202(12) -0.0493(11) 0.2780(11) 0.037(4) Uani 1 1 d DG U . . .
H2_8 H 0.294608 -0.007045 0.295072 0.044 Uiso 1 1 calc R U . . .
C3_8 C 0.1891(15) -0.1471(12) 0.2658(12) 0.038(4) Uani 1 1 d DG U . . .
H3_8 H 0.242130 -0.171700 0.274588 0.046 Uiso 1 1 calc R U . . .
C4_8 C 0.0803(17) -0.2089(9) 0.2408(12) 0.039(4) Uani 1 1 d DG U . . .
H4_8 H 0.058961 -0.275760 0.232434 0.047 Uiso 1 1 calc R U . . .
C5_8 C 0.0026(13) -0.1729(11) 0.2279(11) 0.039(4) Uani 1 1 d DG U . . .
H5_8 H -0.071731 -0.215165 0.210764 0.047 Uiso 1 1 calc R U . . .
C6_8 C 0.0338(13) -0.0751(12) 0.2400(11) 0.039(4) Uani 1 1 d DG U . . .
H6_8 H -0.019255 -0.050509 0.231247 0.046 Uiso 1 1 calc R U . . .
C7_8 C 0.0994(15) 0.1351(13) 0.3274(10) 0.033(3) Uani 1 1 d DG U . . .
C8_8 C 0.0476(16) 0.1945(13) 0.3140(9) 0.035(4) Uani 1 1 d DG U . . .
H8A_8 H 0.050407 0.222230 0.277101 0.042 Uiso 1 1 calc R U . . .
C9_8 C -0.0083(17) 0.2132(14) 0.3545(11) 0.038(4) Uani 1 1 d DG U . . .
H9_8 H -0.043640 0.253810 0.345336 0.046 Uiso 1 1 calc R U . . .
C10_8 C -0.0123(17) 0.1726(15) 0.4085(10) 0.040(4) Uani 1 1 d DG U . . .
H10_8 H -0.050524 0.185434 0.436157 0.048 Uiso 1 1 calc R U . . .
C11_8 C 0.0394(17) 0.1132(15) 0.4219(9) 0.040(4) Uani 1 1 d DG U . . .
H11_8 H 0.036639 0.085477 0.458744 0.049 Uiso 1 1 calc R U . . .
C12_8 C 0.0953(16) 0.0945(13) 0.3813(10) 0.038(4) Uani 1 1 d DG U . . .
H12_8 H 0.130687 0.053896 0.390510 0.046 Uiso 1 1 calc R U . . .
C13_8 C 0.3213(10) 0.1721(13) 0.3219(10) 0.035(3) Uani 1 1 d DG U . . .
C14_8 C 0.3902(15) 0.1706(11) 0.2861(8) 0.037(4) Uani 1 1 d DG U . . .
H14_8 H 0.361479 0.142608 0.240068 0.044 Uiso 1 1 calc R U . . .
C15_8 C 0.5010(14) 0.2100(14) 0.3176(11) 0.041(4) Uani 1 1 d DG U . . .
H15_8 H 0.548017 0.208995 0.293107 0.049 Uiso 1 1 calc R U . . .
C16_8 C 0.5430(10) 0.2510(14) 0.3849(11) 0.044(4) Uani 1 1 d DG U . . .
H16_8 H 0.618694 0.277966 0.406425 0.053 Uiso 1 1 calc R U . . .
C17_8 C 0.4741(15) 0.2526(9) 0.4207(8) 0.045(4) Uani 1 1 d DG U . . .
H17_8 H 0.502835 0.280553 0.466703 0.054 Uiso 1 1 calc R U . . .
C18_8 C 0.3633(14) 0.2131(12) 0.3892(9) 0.038(4) Uani 1 1 d DG U . . .
H18_8 H 0.316297 0.214167 0.413665 0.045 Uiso 1 1 calc R U . . .
C19_8 C 0.1594(16) 0.1489(12) 0.2067(8) 0.035(3) Uani 1 1 d DG U . . .
C20_8 C 0.1864(14) 0.2453(11) 0.2109(7) 0.036(4) Uani 1 1 d DG U . . .
H20_8 H 0.223181 0.289392 0.252597 0.043 Uiso 1 1 calc R U . . .
C21_8 C 0.1598(18) 0.2773(10) 0.1542(9) 0.038(4) Uani 1 1 d DG U . . .
H21_8 H 0.178310 0.343228 0.157098 0.046 Uiso 1 1 calc R U . . .
C22_8 C 0.1061(19) 0.2129(13) 0.0932(8) 0.044(4) Uani 1 1 d DG U . . .
H22_8 H 0.087833 0.234737 0.054467 0.053 Uiso 1 1 calc R U . . .
C23_8 C 0.0790(18) 0.1165(12) 0.0890(7) 0.047(4) Uani 1 1 d DG U . . .
H23_8 H 0.042227 0.072408 0.047334 0.057 Uiso 1 1 calc R U . . .
C24_8 C 0.1056(18) 0.0845(10) 0.1457(9) 0.042(4) Uani 1 1 d DG U . . .
H24_8 H 0.087097 0.018570 0.142832 0.050 Uiso 1 1 calc R U . . .
P1_8 P 0.1808(7) 0.1120(6) 0.2804(5) 0.0318(18) Uani 1 1 d D U . . .
Cu10 Cu 0.9636(4) 0.8027(4) 0.7982(2) 0.0841(14) Uani 1 1 d . U . . .
P1_9 P 0.8320(12) 0.6525(10) 0.7946(6) 0.116(3) Uani 1 1 d D U . . .
C1_9 C 0.784(3) 0.5648(19) 0.7181(10) 0.120(5) Uani 1 1 d DG U . . .
C2_9 C 0.748(2) 0.468(2) 0.7168(11) 0.121(5) Uani 1 1 d DG U . . .
H2_9 H 0.738460 0.446624 0.755262 0.145 Uiso 1 1 calc R U . . .
C3_9 C 0.725(3) 0.4033(16) 0.6593(15) 0.122(6) Uani 1 1 d DG U . . .
H3_9 H 0.700201 0.337267 0.658380 0.146 Uiso 1 1 calc R U . . .
C4_9 C 0.739(3) 0.435(2) 0.6030(12) 0.122(6) Uani 1 1 d DG U . . .
H4_9 H 0.722967 0.390439 0.563713 0.146 Uiso 1 1 calc R U . . .
C5_9 C 0.775(3) 0.531(2) 0.6044(11) 0.122(6) Uani 1 1 d DG U . . .
H5_9 H 0.783994 0.552968 0.565928 0.146 Uiso 1 1 calc R U . . .
C6_9 C 0.797(3) 0.5963(17) 0.6619(14) 0.121(5) Uani 1 1 d DG U . . .
H6_9 H 0.822254 0.662327 0.662810 0.145 Uiso 1 1 calc R U . . .
C7_9 C 0.852(3) 0.603(2) 0.8695(13) 0.133(5) Uani 1 1 d DG U . . .
C8_9 C 0.921(3) 0.559(2) 0.8693(14) 0.134(5) Uani 1 1 d DG U . . .
H8_9 H 0.955315 0.562991 0.836197 0.160 Uiso 1 1 calc R U . . .
C9_9 C 0.941(3) 0.510(2) 0.9174(17) 0.137(6) Uani 1 1 d DG U . . .
H9_9 H 0.988784 0.480501 0.917205 0.165 Uiso 1 1 calc R U . . .
C10_9 C 0.892(3) 0.505(2) 0.9657(15) 0.138(6) Uani 1 1 d DG U . . .
H10_9 H 0.905153 0.471807 0.998629 0.166 Uiso 1 1 calc R U . . .
C11_9 C 0.822(3) 0.549(3) 0.9660(13) 0.138(6) Uani 1 1 d DG U . . .
H11_9 H 0.788051 0.545602 0.999045 0.165 Uiso 1 1 calc R U . . .
C12_9 C 0.802(3) 0.598(2) 0.9179(16) 0.135(6) Uani 1 1 d DG U . . .
H12_9 H 0.754580 0.628093 0.918037 0.163 Uiso 1 1 calc R U . . .
C13_9 C 0.7100(19) 0.672(2) 0.7779(16) 0.119(4) Uani 1 1 d D U . . .
H13_9 H 0.712877 0.703449 0.821921 0.142 Uiso 1 1 calc R U . . .
C14_9 C 0.7053(19) 0.7423(15) 0.7353(15) 0.117(4) Uani 1 1 d D U . . .
H14_9 H 0.707503 0.718086 0.690920 0.140 Uiso 1 1 calc R U . . .
C15_9 C 0.606(2) 0.5798(19) 0.7556(18) 0.139(8) Uani 1 1 d D U . . .
H15A_9 H 0.612921 0.537103 0.784663 0.208 Uiso 1 1 calc R U . . .
H15B_9 H 0.545010 0.595232 0.757810 0.208 Uiso 1 1 calc R U . . .
H15C_9 H 0.592153 0.548514 0.710183 0.208 Uiso 1 1 calc R U . . .
C16_9 C 0.603(3) 0.760(3) 0.7274(19) 0.119(7) Uani 1 1 d D U . . .
H16A_9 H 0.602696 0.806029 0.699744 0.179 Uiso 1 1 calc R U . . .
H16B_9 H 0.538786 0.700349 0.706665 0.179 Uiso 1 1 calc R U . . .
H16C_9 H 0.602342 0.786261 0.770935 0.179 Uiso 1 1 calc R U . . .
P2_9 P 0.8284(10) 0.8476(10) 0.7793(5) 0.103(3) Uani 1 1 d D U . . .
C17_9 C 0.806(2) 0.899(2) 0.8511(10) 0.113(4) Uani 1 1 d DG U . . .
C18_9 C 0.847(2) 0.875(2) 0.9090(13) 0.117(5) Uani 1 1 d DG U . . .
H18_9 H 0.888779 0.838924 0.909301 0.140 Uiso 1 1 calc R U . . .
C19_9 C 0.829(3) 0.905(2) 0.9663(10) 0.120(5) Uani 1 1 d DG U . . .
H19_9 H 0.857622 0.888722 1.005894 0.144 Uiso 1 1 calc R U . . .
C20_9 C 0.769(3) 0.958(2) 0.9658(11) 0.120(5) Uani 1 1 d DG U . . .
H20_9 H 0.755926 0.977985 1.005049 0.144 Uiso 1 1 calc R U . . .
C21_9 C 0.727(3) 0.981(2) 0.9080(14) 0.118(5) Uani 1 1 d DG U . . .
H21_9 H 0.685386 1.017451 0.907610 0.141 Uiso 1 1 calc R U . . .
C22_9 C 0.745(3) 0.952(2) 0.8506(10) 0.116(5) Uani 1 1 d DG U . . .
H22_9 H 0.716542 0.967654 0.811016 0.139 Uiso 1 1 calc R U . . .
C23_9 C 0.837(2) 0.9345(19) 0.7269(12) 0.112(4) Uani 1 1 d DG U . . .
C24_9 C 0.793(2) 0.9015(16) 0.6587(13) 0.115(5) Uani 1 1 d DG U . . .
H24_9 H 0.755472 0.835037 0.639735 0.138 Uiso 1 1 calc R U . . .
C25_9 C 0.805(3) 0.966(2) 0.6184(9) 0.120(6) Uani 1 1 d DG U . . .
H25_9 H 0.774919 0.943063 0.571823 0.144 Uiso 1 1 calc R U . . .
C26_9 C 0.860(3) 1.063(2) 0.6462(13) 0.118(6) Uani 1 1 d DG U . . .
H26_9 H 0.868189 1.106706 0.618610 0.142 Uiso 1 1 calc R U . . .
C27_9 C 0.904(2) 1.0959(16) 0.7143(14) 0.119(6) Uani 1 1 d DG U . . .
H27_9 H 0.942012 1.162324 0.733309 0.143 Uiso 1 1 calc R U . . .
C28_9 C 0.893(2) 1.032(2) 0.7547(9) 0.115(5) Uani 1 1 d DG U . . .
H28_9 H 0.922566 1.054299 0.801221 0.138 Uiso 1 1 calc R U . . .
P1_11 P 1.0674(10) 0.8107(10) 0.7353(5) 0.101(3) Uani 1 1 d D U . . .
C1_11 C 1.094(2) 0.7097(17) 0.7096(13) 0.105(4) Uani 1 1 d DG U . . .
C2_11 C 1.149(2) 0.7122(16) 0.6640(12) 0.108(5) Uani 1 1 d DG U . . .
H2_11 H 1.166194 0.764147 0.643358 0.129 Uiso 1 1 calc R U . . .
C3_11 C 1.179(2) 0.639(2) 0.6487(12) 0.108(5) Uani 1 1 d DG U . . .
H3_11 H 1.215949 0.640462 0.617508 0.130 Uiso 1 1 calc R U . . .
C4_11 C 1.153(2) 0.5628(18) 0.6789(14) 0.110(5) Uani 1 1 d DG U . . .
H4_11 H 1.173684 0.512558 0.668398 0.132 Uiso 1 1 calc R U . . .
C5_11 C 1.099(2) 0.5603(17) 0.7245(13) 0.110(5) Uani 1 1 d DG U . . .
H5_11 H 1.081663 0.508337 0.745139 0.131 Uiso 1 1 calc R U . . .
C6_11 C 1.069(2) 0.634(2) 0.7398(12) 0.108(5) Uani 1 1 d DG U . . .
H6_11 H 1.031907 0.632020 0.770990 0.129 Uiso 1 1 calc R U . . .
C7_11 C 1.039(3) 0.861(2) 0.6616(10) 0.107(5) Uani 1 1 d DG U . . .
C8_11 C 0.965(2) 0.7935(17) 0.6049(14) 0.110(6) Uani 1 1 d DG U . . .
H8_11 H 0.933943 0.728327 0.606063 0.132 Uiso 1 1 calc R U . . .
C9_11 C 0.936(2) 0.821(2) 0.5465(11) 0.111(6) Uani 1 1 d DG U . . .
H9_11 H 0.885414 0.774774 0.507702 0.133 Uiso 1 1 calc R U . . .
C10_11 C 0.981(3) 0.916(2) 0.5447(10) 0.111(6) Uani 1 1 d DG U . . .
H10_11 H 0.961546 0.935331 0.504799 0.133 Uiso 1 1 calc R U . . .
C11_11 C 1.055(3) 0.9843(17) 0.6014(14) 0.113(6) Uani 1 1 d DG U . . .
H11_11 H 1.086209 1.049441 0.600257 0.135 Uiso 1 1 calc R U . . .
C12_11 C 1.084(2) 0.9567(19) 0.6599(11) 0.112(5) Uani 1 1 d DG U . . .
H12_11 H 1.134739 1.002996 0.698619 0.135 Uiso 1 1 calc R U . . .
C13_11 C 1.200(2) 0.885(3) 0.7942(12) 0.099(4) Uani 1 1 d D U . . .
H13_11 H 1.190903 0.945463 0.803077 0.119 Uiso 1 1 calc R U . . .
C14_11 C 1.213(2) 0.865(3) 0.8607(13) 0.091(4) Uani 1 1 d D U . . .
H14_11 H 1.203081 0.797576 0.856666 0.110 Uiso 1 1 calc R U . . .
C15_11 C 1.296(3) 0.921(2) 0.7681(16) 0.113(8) Uani 1 1 d D U . . .
H15A_11 H 1.271431 0.930054 0.723467 0.169 Uiso 1 1 calc R U . . .
H15B_11 H 1.350857 0.982144 0.797189 0.169 Uiso 1 1 calc R U . . .
H15C_11 H 1.327255 0.874670 0.766890 0.169 Uiso 1 1 calc R U . . .
C16_11 C 1.326(3) 0.930(3) 0.9111(17) 0.107(8) Uani 1 1 d D U . . .
H16A_11 H 1.329826 0.913586 0.954049 0.161 Uiso 1 1 calc R U . . .
H16B_11 H 1.381335 0.919676 0.895651 0.161 Uiso 1 1 calc R U . . .
H16C_11 H 1.337680 0.996536 0.915457 0.161 Uiso 1 1 calc R U . . .
P2_11 P 1.1071(9) 0.8774(7) 0.8898(5) 0.075(2) Uani 1 1 d D U . . .
C17_11 C 1.1492(18) 1.0058(10) 0.9143(11) 0.086(4) Uani 1 1 d DG U . . .
C18_11 C 1.1111(18) 1.0470(15) 0.8655(9) 0.085(5) Uani 1 1 d DG U . . .
H18_11 H 1.062205 1.008186 0.823712 0.103 Uiso 1 1 calc R U . . .
C19_11 C 1.145(2) 1.1452(16) 0.8780(11) 0.092(5) Uani 1 1 d DG U . . .
H19_11 H 1.118663 1.173345 0.844684 0.111 Uiso 1 1 calc R U . . .
C20_11 C 1.216(2) 1.2020(11) 0.9392(12) 0.092(5) Uani 1 1 d DG U . . .
H20_11 H 1.239218 1.269068 0.947685 0.110 Uiso 1 1 calc R U . . .
C21_11 C 1.254(2) 1.1608(13) 0.9879(9) 0.088(5) Uani 1 1 d DG U . . .
H21_11 H 1.303320 1.199633 1.029714 0.106 Uiso 1 1 calc R U . . .
C22_11 C 1.2208(19) 1.0627(14) 0.9754(9) 0.090(5) Uani 1 1 d DG U . . .
H22_11 H 1.246864 1.034473 1.008742 0.108 Uiso 1 1 calc R U . . .
C23_11 C 1.117(2) 0.8356(17) 0.9667(10) 0.084(4) Uani 1 1 d DG U . . .
C24_11 C 1.146(2) 0.7598(18) 0.9703(10) 0.085(4) Uani 1 1 d DG U . . .
H24_11 H 1.169690 0.737590 0.936769 0.102 Uiso 1 1 calc R U . . .
C25_11 C 1.141(2) 0.7166(16) 1.0230(12) 0.085(4) Uani 1 1 d DG U . . .
H25_11 H 1.160458 0.664739 1.025467 0.102 Uiso 1 1 calc R U . . .
C26_11 C 1.106(2) 0.7491(16) 1.0721(10) 0.083(5) Uani 1 1 d DG U . . .
H26_11 H 1.102535 0.719514 1.108094 0.100 Uiso 1 1 calc R U . . .
C27_11 C 1.077(2) 0.8249(16) 1.0685(10) 0.082(4) Uani 1 1 d DG U . . .
H27_11 H 1.053843 0.847142 1.102024 0.099 Uiso 1 1 calc R U . . .
C28_11 C 1.083(2) 0.8682(13) 1.0158(11) 0.083(4) Uani 1 1 d DG U . . .
H28_11 H 1.063075 0.919995 1.013326 0.100 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1_6 Ag2 S1_1 129.7(4) . . ?
S1_6 Ag2 S2_2 114.4(3) . . ?
S1_1 Ag2 S2_2 111.3(3) . . ?
S1_6 Ag2 Cu4 48.2(3) . . ?
S1_1 Ag2 Cu4 141.8(3) . . ?
S2_2 Ag2 Cu4 97.3(3) . . ?
S1_6 Ag2 Ag3 112.8(3) . . ?
S1_1 Ag2 Ag3 111.2(3) . . ?
S2_2 Ag2 Ag3 52.0(2) . . ?
Cu4 Ag2 Ag3 67.26(15) . . ?
S1_6 Ag2 Cu1 149.7(2) . . ?
S1_1 Ag2 Cu1 47.7(3) . . ?
S2_2 Ag2 Cu1 88.0(3) . . ?
Cu4 Ag2 Cu1 111.84(16) . . ?
Ag3 Ag2 Cu1 64.20(15) . . ?
S1_6 Ag2 Ag1 96.0(2) . . ?
S1_1 Ag2 Ag1 88.2(2) . . ?
S2_2 Ag2 Ag1 108.6(3) . . ?
Cu4 Ag2 Ag1 58.12(11) . . ?
Ag3 Ag2 Ag1 56.89(11) . . ?
Cu1 Ag2 Ag1 56.04(11) . . ?
S2_2 Ag3 S2_3 177.3(5) . . ?
S2_2 Ag3 Ag5 58.1(3) . . ?
S2_3 Ag3 Ag5 123.6(3) . . ?
S2_2 Ag3 Ag4 125.3(3) . . ?
S2_3 Ag3 Ag4 56.8(3) . . ?
Ag5 Ag3 Ag4 67.55(13) . . ?
S2_2 Ag3 Ag2 56.0(3) . . ?
S2_3 Ag3 Ag2 121.9(3) . . ?
Ag5 Ag3 Ag2 113.39(16) . . ?
Ag4 Ag3 Ag2 177.7(2) . . ?
S2_2 Ag3 Ag1 122.0(3) . . ?
S2_3 Ag3 Ag1 56.2(3) . . ?
Ag5 Ag3 Ag1 177.1(2) . . ?
Ag4 Ag3 Ag1 112.62(16) . . ?
Ag2 Ag3 Ag1 66.32(13) . . ?
S2_2 Ag3 Cu2 89.0(3) . . ?
S2_3 Ag3 Cu2 93.7(3) . . ?
Ag5 Ag3 Cu2 59.84(13) . . ?
Ag4 Ag3 Cu2 56.80(13) . . ?
Ag2 Ag3 Cu2 125.46(18) . . ?
Ag1 Ag3 Cu2 122.80(18) . . ?
S2_2 Ag3 Cu1 86.3(3) . . ?
S2_3 Ag3 Cu1 93.9(3) . . ?
Ag5 Ag3 Cu1 125.39(18) . . ?
Ag4 Ag3 Cu1 123.25(19) . . ?
Ag2 Ag3 Cu1 58.11(14) . . ?
Ag1 Ag3 Cu1 57.11(13) . . ?
Cu2 Ag3 Cu1 81.87(17) . . ?
S2_2 Ag3 Cu3 94.9(3) . . ?
S2_3 Ag3 Cu3 84.8(3) . . ?
Ag5 Ag3 Cu3 56.97(13) . . ?
Ag4 Ag3 Cu3 57.59(14) . . ?
Ag2 Ag3 Cu3 120.96(19) . . ?
Ag1 Ag3 Cu3 120.52(18) . . ?
Cu2 Ag3 Cu3 100.25(18) . . ?
Cu1 Ag3 Cu3 177.6(2) . . ?
S2_2 Ag3 Cu4 91.6(3) . . ?
S2_3 Ag3 Cu4 85.7(3) . . ?
Ag5 Ag3 Cu4 119.80(17) . . ?
Ag4 Ag3 Cu4 122.12(18) . . ?
Ag2 Ag3 Cu4 55.62(13) . . ?
Ag1 Ag3 Cu4 57.53(12) . . ?
Cu2 Ag3 Cu4 178.9(2) . . ?
Cu1 Ag3 Cu4 99.07(17) . . ?
Cu3 Ag3 Cu4 78.80(16) . . ?
S1_4 Ag4 S1_5 127.3(4) . . ?
S1_4 Ag4 S2_3 112.4(3) . . ?
S1_5 Ag4 S2_3 115.8(3) . . ?
S1_4 Ag4 Cu2 142.1(3) . . ?
S1_5 Ag4 Cu2 48.6(3) . . ?
S2_3 Ag4 Cu2 96.4(3) . . ?
S1_4 Ag4 Ag3 114.2(3) . . ?
S1_5 Ag4 Ag3 111.2(3) . . ?
S2_3 Ag4 Ag3 52.5(3) . . ?
Cu2 Ag4 Ag3 64.60(15) . . ?
S1_4 Ag4 Cu3 49.0(3) . . ?
S1_5 Ag4 Cu3 148.8(2) . . ?
S2_3 Ag4 Cu3 87.6(3) . . ?
Cu2 Ag4 Cu3 111.84(16) . . ?
Ag3 Ag4 Cu3 65.64(15) . . ?
S1_4 Ag4 Ag5 88.7(2) . . ?
S1_5 Ag4 Ag5 95.5(2) . . ?
S2_3 Ag4 Ag5 107.9(3) . . ?
Cu2 Ag4 Ag5 58.39(11) . . ?
Ag3 Ag4 Ag5 55.90(11) . . ?
Cu3 Ag4 Ag5 55.92(11) . . ?
S2_4 Ag5 S2_5 128.6(3) . . ?
S2_4 Ag5 S2_2 116.7(3) . . ?
S2_5 Ag5 S2_2 111.7(3) . . ?
S2_4 Ag5 Ag3 112.0(2) . . ?
S2_5 Ag5 Ag3 110.7(2) . . ?
S2_2 Ag5 Ag3 51.8(2) . . ?
S2_4 Ag5 Cu3 47.7(2) . . ?
S2_5 Ag5 Cu3 139.7(3) . . ?
S2_2 Ag5 Cu3 97.5(2) . . ?
Ag3 Ag5 Cu3 66.40(15) . . ?
S2_4 Ag5 Cu2 146.0(3) . . ?
S2_5 Ag5 Cu2 48.0(2) . . ?
S2_2 Ag5 Cu2 87.7(2) . . ?
Ag3 Ag5 Cu2 63.27(14) . . ?
Cu3 Ag5 Cu2 109.26(15) . . ?
S2_4 Ag5 Ag4 93.6(2) . . ?
S2_5 Ag5 Ag4 86.9(2) . . ?
S2_2 Ag5 Ag4 108.1(2) . . ?
Ag3 Ag5 Ag4 56.55(11) . . ?
Cu3 Ag5 Ag4 57.04(12) . . ?
Cu2 Ag5 Ag4 54.57(11) . . ?
S2_6 Ag1 S2_1 128.6(3) . . ?
S2_6 Ag1 S2_3 112.7(3) . . ?
S2_1 Ag1 S2_3 114.7(3) . . ?
S2_6 Ag1 Cu1 140.3(3) . . ?
S2_1 Ag1 Cu1 48.7(2) . . ?
S2_3 Ag1 Cu1 96.9(3) . . ?
S2_6 Ag1 Ag3 113.1(3) . . ?
S2_1 Ag1 Ag3 110.8(3) . . ?
S2_3 Ag1 Ag3 52.5(2) . . ?
Cu1 Ag1 Ag3 64.71(15) . . ?
S2_6 Ag1 Cu4 47.5(2) . . ?
S2_1 Ag1 Cu4 148.1(3) . . ?
S2_3 Ag1 Cu4 89.1(3) . . ?
Cu1 Ag1 Cu4 110.51(15) . . ?
Ag3 Ag1 Cu4 66.04(14) . . ?
S2_6 Ag1 Ag2 87.3(2) . . ?
S2_1 Ag1 Ag2 95.2(2) . . ?
S2_3 Ag1 Ag2 108.9(2) . . ?
Cu1 Ag1 Ag2 57.37(12) . . ?
Ag3 Ag1 Ag2 56.78(11) . . ?
Cu4 Ag1 Ag2 55.40(11) . . ?
S1_2 Cu1 S1_1 123.5(4) . . ?
S1_2 Cu1 S2_1 137.4(4) . . ?
S1_1 Cu1 S2_1 97.4(4) . . ?
S1_2 Cu1 Ag1 118.9(3) . . ?
S1_1 Cu1 Ag1 101.3(3) . . ?
S2_1 Cu1 Ag1 55.7(3) . . ?
S1_2 Cu1 Ag2 105.2(3) . . ?
S1_1 Cu1 Ag2 55.1(3) . . ?
S2_1 Cu1 Ag2 108.2(3) . . ?
Ag1 Cu1 Ag2 66.59(12) . . ?
S1_2 Cu1 Ag3 66.9(3) . . ?
S1_1 Cu1 Ag3 112.1(3) . . ?
S2_1 Cu1 Ag3 111.1(3) . . ?
Ag1 Cu1 Ag3 58.19(13) . . ?
Ag2 Cu1 Ag3 57.69(13) . . ?
S1_2 Cu2 S1_5 140.2(4) . . ?
S1_2 Cu2 S2_5 121.8(4) . . ?
S1_5 Cu2 S2_5 96.1(4) . . ?
S1_2 Cu2 Ag4 120.4(3) . . ?
S1_5 Cu2 Ag4 56.0(3) . . ?
S2_5 Cu2 Ag4 100.7(3) . . ?
S1_2 Cu2 Ag5 104.1(3) . . ?
S1_5 Cu2 Ag5 108.1(3) . . ?
S2_5 Cu2 Ag5 54.4(3) . . ?
Ag4 Cu2 Ag5 67.04(12) . . ?
S1_2 Cu2 Ag3 67.7(3) . . ?
S1_5 Cu2 Ag3 112.4(3) . . ?
S2_5 Cu2 Ag3 110.6(3) . . ?
Ag4 Cu2 Ag3 58.60(13) . . ?
Ag5 Cu2 Ag3 56.89(12) . . ?
S1_3 Cu3 S2_4 137.0(4) . . ?
S1_3 Cu3 S1_4 124.8(4) . . ?
S2_4 Cu3 S1_4 96.4(4) . . ?
S1_3 Cu3 Ag5 119.3(3) . . ?
S2_4 Cu3 Ag5 55.1(3) . . ?
S1_4 Cu3 Ag5 100.3(3) . . ?
S1_3 Cu3 Ag4 106.8(3) . . ?
S2_4 Cu3 Ag4 107.4(3) . . ?
S1_4 Cu3 Ag4 53.8(3) . . ?
Ag5 Cu3 Ag4 67.05(13) . . ?
S1_3 Cu3 Ag3 69.9(3) . . ?
S2_4 Cu3 Ag3 109.6(3) . . ?
S1_4 Cu3 Ag3 110.2(3) . . ?
Ag5 Cu3 Ag3 56.63(13) . . ?
Ag4 Cu3 Ag3 56.77(13) . . ?
S1_3 Cu4 S1_6 138.3(4) . . ?
S1_3 Cu4 S2_6 121.7(4) . . ?
S1_6 Cu4 S2_6 98.1(4) . . ?
S1_3 Cu4 Ag2 120.5(3) . . ?
S1_6 Cu4 Ag2 56.1(3) . . ?
S2_6 Cu4 Ag2 100.1(3) . . ?
S1_3 Cu4 Ag1 104.4(3) . . ?
S1_6 Cu4 Ag1 109.1(3) . . ?
S2_6 Cu4 Ag1 54.0(3) . . ?
Ag2 Cu4 Ag1 66.48(13) . . ?
S1_3 Cu4 Ag3 69.2(3) . . ?
S1_6 Cu4 Ag3 110.6(3) . . ?
S2_6 Cu4 Ag3 109.9(3) . . ?
Ag2 Cu4 Ag3 57.12(13) . . ?
Ag1 Cu4 Ag3 56.43(12) . . ?
C2_1 C1_1 C6_1 120.0 . . ?
C2_1 C1_1 S1_1 124.5(9) . . ?
C6_1 C1_1 S1_1 115.2(9) . . ?
C3_1 C2_1 C1_1 120.0 . . ?
C3_1 C2_1 S2_1 117.3(8) . . ?
C1_1 C2_1 S2_1 122.6(8) . . ?
F1_1 C3_1 C2_1 120.8(12) . . ?
F1_1 C3_1 C4_1 119.1(12) . . ?
C2_1 C3_1 C4_1 120.0 . . ?
F2_1 C4_1 C5_1 119.9(13) . . ?
F2_1 C4_1 C3_1 120.0(13) . . ?
C5_1 C4_1 C3_1 120.0 . . ?
F3_1 C5_1 C4_1 122.1(13) . . ?
F3_1 C5_1 C6_1 117.9(13) . . ?
C4_1 C5_1 C6_1 120.0 . . ?
F4_1 C6_1 C5_1 117.6(12) . . ?
F4_1 C6_1 C1_1 122.4(12) . . ?
C5_1 C6_1 C1_1 120.0 . . ?
C1_1 S1_1 Cu1 97.5(6) . . ?
C1_1 S1_1 Ag2 103.4(9) . . ?
Cu1 S1_1 Ag2 77.2(4) . . ?
C2_1 S2_1 Cu1 97.7(6) . . ?
C2_1 S2_1 Ag1 96.7(9) . . ?
Cu1 S2_1 Ag1 75.7(3) . . ?
C6_2 C1_2 C2_2 116.7(15) . . ?
C6_2 C1_2 S1_2 116.8(13) . . ?
C2_2 C1_2 S1_2 126.5(14) . . ?
C3_2 C2_2 C1_2 121.3(16) . . ?
C3_2 C2_2 S2_2 114.3(13) . . ?
C1_2 C2_2 S2_2 124.2(13) . . ?
F1_2 C3_2 C4_2 117.8(16) . . ?
F1_2 C3_2 C2_2 123.1(16) . . ?
C4_2 C3_2 C2_2 119.1(17) . . ?
C5_2 C4_2 F2_2 120.1(17) . . ?
C5_2 C4_2 C3_2 120.4(17) . . ?
F2_2 C4_2 C3_2 117.9(17) . . ?
C4_2 C5_2 F3_2 119(2) . . ?
C4_2 C5_2 C6_2 117.3(18) . . ?
F3_2 C5_2 C6_2 117.4(19) . . ?
F4_2 C6_2 C1_2 120.5(16) . . ?
F4_2 C6_2 C5_2 117.8(16) . . ?
C1_2 C6_2 C5_2 121.6(17) . . ?
C1_2 S1_2 Cu2 101.0(14) . . ?
C1_2 S1_2 Cu1 103.4(14) . . ?
Cu2 S1_2 Cu1 136.7(5) . . ?
C2_2 S2_2 Ag3 114.1(7) . . ?
C2_2 S2_2 Ag2 103.8(14) . . ?
Ag3 S2_2 Ag2 72.1(3) . . ?
C2_2 S2_2 Ag5 100.1(14) . . ?
Ag3 S2_2 Ag5 70.1(3) . . ?
Ag2 S2_2 Ag5 140.9(4) . . ?
C6_3 C1_3 C2_3 117.5(15) . . ?
C6_3 C1_3 S1_3 116.2(14) . . ?
C2_3 C1_3 S1_3 126.3(14) . . ?
C3_3 C2_3 C1_3 119.1(16) . . ?
C3_3 C2_3 S2_3 113.6(14) . . ?
C1_3 C2_3 S2_3 126.6(14) . . ?
F1_3 C3_3 C4_3 116.1(17) . . ?
F1_3 C3_3 C2_3 121.2(17) . . ?
C4_3 C3_3 C2_3 122.3(17) . . ?
C3_3 C4_3 F2_3 121.9(18) . . ?
C3_3 C4_3 C5_3 118.6(17) . . ?
F2_3 C4_3 C5_3 117.3(18) . . ?
F3_3 C5_3 C4_3 115(2) . . ?
F3_3 C5_3 C6_3 120(2) . . ?
C4_3 C5_3 C6_3 118.3(19) . . ?
F4_3 C6_3 C5_3 116.8(17) . . ?
F4_3 C6_3 C1_3 121.5(17) . . ?
C5_3 C6_3 C1_3 121.6(17) . . ?
C1_3 S1_3 Cu3 101.8(14) . . ?
C1_3 S1_3 Cu4 101.1(14) . . ?
Cu3 S1_3 Cu4 136.2(5) . . ?
C2_3 S2_3 Ag3 114.8(8) . . ?
C2_3 S2_3 Ag1 100.6(14) . . ?
Ag3 S2_3 Ag1 71.3(3) . . ?
C2_3 S2_3 Ag4 100.9(14) . . ?
Ag3 S2_3 Ag4 70.7(3) . . ?
Ag1 S2_3 Ag4 141.5(4) . . ?
C2_4 C1_4 C6_4 117.8(15) . . ?
C2_4 C1_4 S1_4 123.3(14) . . ?
C6_4 C1_4 S1_4 118.9(14) . . ?
C3_4 C2_4 C1_4 118.7(15) . . ?
C3_4 C2_4 S2_4 117.6(13) . . ?
C1_4 C2_4 S2_4 123.7(13) . . ?
F1_4 C3_4 C4_4 118.2(16) . . ?
F1_4 C3_4 C2_4 120.2(16) . . ?
C4_4 C3_4 C2_4 121.6(17) . . ?
F2_4 C4_4 C5_4 118.7(18) . . ?
F2_4 C4_4 C3_4 120.6(18) . . ?
C5_4 C4_4 C3_4 120.4(17) . . ?
F3_4 C5_4 C4_4 119.6(17) . . ?
F3_4 C5_4 C6_4 121.1(18) . . ?
C4_4 C5_4 C6_4 118.2(17) . . ?
F4_4 C6_4 C5_4 115.6(17) . . ?
F4_4 C6_4 C1_4 122.1(17) . . ?
C5_4 C6_4 C1_4 122.1(17) . . ?
C1_4 S1_4 Cu3 97.4(7) . . ?
C1_4 S1_4 Ag4 107.2(11) . . ?
Cu3 S1_4 Ag4 77.3(4) . . ?
C2_4 S2_4 Cu3 99.2(7) . . ?
C2_4 S2_4 Ag5 99.8(11) . . ?
Cu3 S2_4 Ag5 77.3(3) . . ?
C2_5 C1_5 C6_5 117.6(15) . . ?
C2_5 C1_5 S1_5 123.4(13) . . ?
C6_5 C1_5 S1_5 118.7(13) . . ?
C3_5 C2_5 C1_5 119.3(15) . . ?
C3_5 C2_5 S2_5 116.9(13) . . ?
C1_5 C2_5 S2_5 123.8(13) . . ?
F1_5 C3_5 C4_5 117.0(16) . . ?
F1_5 C3_5 C2_5 121.1(16) . . ?
C4_5 C3_5 C2_5 121.9(16) . . ?
C5_5 C4_5 F2_5 118.7(17) . . ?
C5_5 C4_5 C3_5 120.6(16) . . ?
F2_5 C4_5 C3_5 120.5(17) . . ?
C4_5 C5_5 F3_5 120.1(17) . . ?
C4_5 C5_5 C6_5 117.9(16) . . ?
F3_5 C5_5 C6_5 121.5(17) . . ?
F4_5 C6_5 C1_5 118.5(16) . . ?
F4_5 C6_5 C5_5 117.8(16) . . ?
C1_5 C6_5 C5_5 122.2(16) . . ?
C1_5 S1_5 Cu2 99.3(7) . . ?
C1_5 S1_5 Ag4 99.8(13) . . ?
Cu2 S1_5 Ag4 75.4(3) . . ?
C2_5 S2_5 Cu2 97.4(7) . . ?
C2_5 S2_5 Ag5 107.9(12) . . ?
Cu2 S2_5 Ag5 77.6(3) . . ?
C6_6 C1_6 C2_6 119.4(15) . . ?
C6_6 C1_6 S1_6 116.3(13) . . ?
C2_6 C1_6 S1_6 124.2(13) . . ?
C3_6 C2_6 C1_6 118.9(15) . . ?
C3_6 C2_6 S2_6 118.4(13) . . ?
C1_6 C2_6 S2_6 122.5(13) . . ?
F1_6 C3_6 C4_6 118.2(16) . . ?
F1_6 C3_6 C2_6 121.2(16) . . ?
C4_6 C3_6 C2_6 120.5(16) . . ?
F2_6 C4_6 C5_6 120.5(17) . . ?
F2_6 C4_6 C3_6 118.1(16) . . ?
C5_6 C4_6 C3_6 121.0(16) . . ?
F3_6 C5_6 C4_6 119.9(17) . . ?
F3_6 C5_6 C6_6 120.6(17) . . ?
C4_6 C5_6 C6_6 119.2(16) . . ?
F4_6 C6_6 C1_6 121.4(17) . . ?
F4_6 C6_6 C5_6 117.3(17) . . ?
C1_6 C6_6 C5_6 120.5(16) . . ?
C1_6 S1_6 Cu4 97.5(7) . . ?
C1_6 S1_6 Ag2 98.2(12) . . ?
Cu4 S1_6 Ag2 75.6(3) . . ?
C2_6 S2_6 Cu4 97.4(7) . . ?
C2_6 S2_6 Ag1 106.7(12) . . ?
Cu4 S2_6 Ag1 78.5(3) . . ?
C2_7 C1_7 C6_7 120.0 . . ?
C2_7 C1_7 P1_7 121.0(12) . . ?
C6_7 C1_7 P1_7 119.0(12) . . ?
C3_7 C2_7 C1_7 120.0 . . ?
C2_7 C3_7 C4_7 120.0 . . ?
C5_7 C4_7 C3_7 120.0 . . ?
C6_7 C5_7 C4_7 120.0 . . ?
C5_7 C6_7 C1_7 120.0 . . ?
C8_7 C7_7 C12_7 120.0 . . ?
C8_7 C7_7 P1_7 118.1(11) . . ?
C12_7 C7_7 P1_7 121.8(11) . . ?
C9_7 C8_7 C7_7 120.0 . . ?
C8_7 C9_7 C10_7 120.0 . . ?
C11_7 C10_7 C9_7 120.0 . . ?
C12_7 C11_7 C10_7 120.0 . . ?
C11_7 C12_7 C7_7 120.0 . . ?
C14_7 C13_7 C18_7 120.0 . . ?
C14_7 C13_7 P1_7 119.8(10) . . ?
C18_7 C13_7 P1_7 120.2(10) . . ?
C15_7 C14_7 C13_7 120.0 . . ?
C14_7 C15_7 C16_7 120.0 . . ?
C17_7 C16_7 C15_7 120.0 . . ?
C16_7 C17_7 C18_7 120.0 . . ?
C17_7 C18_7 C13_7 120.0 . . ?
C20_7 C19_7 C24_7 120.0 . . ?
C20_7 C19_7 P1_7 118.5(10) . . ?
C24_7 C19_7 P1_7 121.5(10) . . ?
C21_7 C20_7 C19_7 120.0 . . ?
C22_7 C21_7 C20_7 120.0 . . ?
C23_7 C22_7 C21_7 120.0 . . ?
C22_7 C23_7 C24_7 120.0 . . ?
C23_7 C24_7 C19_7 120.0 . . ?
C19_7 P1_7 C13_7 107.8(10) . . ?
C19_7 P1_7 C1_7 109.7(10) . . ?
C13_7 P1_7 C1_7 109.1(9) . . ?
C19_7 P1_7 C7_7 108.3(9) . . ?
C13_7 P1_7 C7_7 113.2(10) . . ?
C1_7 P1_7 C7_7 108.7(11) . . ?
C2_8 C1_8 C6_8 120.0 . . ?
C2_8 C1_8 P1_8 120.7(10) . . ?
C6_8 C1_8 P1_8 119.3(10) . . ?
C3_8 C2_8 C1_8 120.0 . . ?
C4_8 C3_8 C2_8 120.0 . . ?
C3_8 C4_8 C5_8 120.0 . . ?
C4_8 C5_8 C6_8 120.0 . . ?
C5_8 C6_8 C1_8 120.0 . . ?
C8_8 C7_8 C12_8 120.0 . . ?
C8_8 C7_8 P1_8 123.2(10) . . ?
C12_8 C7_8 P1_8 116.7(11) . . ?
C7_8 C8_8 C9_8 120.0 . . ?
C10_8 C9_8 C8_8 120.0 . . ?
C11_8 C10_8 C9_8 120.0 . . ?
C10_8 C11_8 C12_8 120.0 . . ?
C11_8 C12_8 C7_8 120.0 . . ?
C14_8 C13_8 C18_8 120.0 . . ?
C14_8 C13_8 P1_8 117.7(12) . . ?
C18_8 C13_8 P1_8 122.1(12) . . ?
C13_8 C14_8 C15_8 120.0 . . ?
C14_8 C15_8 C16_8 120.0 . . ?
C17_8 C16_8 C15_8 120.0 . . ?
C18_8 C17_8 C16_8 120.0 . . ?
C17_8 C18_8 C13_8 120.0 . . ?
C20_8 C19_8 C24_8 120.0 . . ?
C20_8 C19_8 P1_8 117.5(11) . . ?
C24_8 C19_8 P1_8 122.0(10) . . ?
C19_8 C20_8 C21_8 120.0 . . ?
C20_8 C21_8 C22_8 120.0 . . ?
C23_8 C22_8 C21_8 120.0 . . ?
C22_8 C23_8 C24_8 120.0 . . ?
C23_8 C24_8 C19_8 120.0 . . ?
C19_8 P1_8 C13_8 105.5(11) . . ?
C19_8 P1_8 C1_8 111.1(11) . . ?
C13_8 P1_8 C1_8 109.1(9) . . ?
C19_8 P1_8 C7_8 111.4(10) . . ?
C13_8 P1_8 C7_8 113.8(11) . . ?
C1_8 P1_8 C7_8 106.1(10) . . ?
P1_11 Cu10 P2_9 125.1(5) . . ?
P1_11 Cu10 P2_11 92.1(5) . . ?
P2_9 Cu10 P2_11 119.9(4) . . ?
P1_11 Cu10 P1_9 118.7(5) . . ?
P2_9 Cu10 P1_9 85.4(5) . . ?
P2_11 Cu10 P1_9 118.8(5) . . ?
C1_9 P1_9 C13_9 94.1(15) . . ?
C1_9 P1_9 C7_9 113.6(16) . . ?
C13_9 P1_9 C7_9 110.3(16) . . ?
C1_9 P1_9 Cu10 114.9(13) . . ?
C13_9 P1_9 Cu10 102.5(12) . . ?
C7_9 P1_9 Cu10 117.8(12) . . ?
C2_9 C1_9 C6_9 120.0 . . ?
C2_9 C1_9 P1_9 121.1(18) . . ?
C6_9 C1_9 P1_9 118.3(19) . . ?
C1_9 C2_9 C3_9 120.0 . . ?
C4_9 C3_9 C2_9 120.0 . . ?
C3_9 C4_9 C5_9 120.0 . . ?
C6_9 C5_9 C4_9 120.0 . . ?
C5_9 C6_9 C1_9 120.0 . . ?
C8_9 C7_9 C12_9 120.0 . . ?
C8_9 C7_9 P1_9 109(2) . . ?
C12_9 C7_9 P1_9 130(2) . . ?
C9_9 C8_9 C7_9 120.0 . . ?
C8_9 C9_9 C10_9 120.0 . . ?
C11_9 C10_9 C9_9 120.0 . . ?
C10_9 C11_9 C12_9 120.0 . . ?
C11_9 C12_9 C7_9 120.0 . . ?
C14_9 C13_9 C15_9 112.8(12) . . ?
C14_9 C13_9 P1_9 115(2) . . ?
C15_9 C13_9 P1_9 114.0(18) . . ?
C13_9 C14_9 C16_9 111.8(12) . . ?
C13_9 C14_9 P2_9 102.9(19) . . ?
C16_9 C14_9 P2_9 113(2) . . ?
C17_9 P2_9 C14_9 106.1(16) . . ?
C17_9 P2_9 C23_9 105.0(14) . . ?
C14_9 P2_9 C23_9 106.3(14) . . ?
C17_9 P2_9 Cu10 116.8(11) . . ?
C14_9 P2_9 Cu10 107.3(11) . . ?
C23_9 P2_9 Cu10 114.7(11) . . ?
C18_9 C17_9 C22_9 120.0 . . ?
C18_9 C17_9 P2_9 114.6(16) . . ?
C22_9 C17_9 P2_9 125.2(16) . . ?
C17_9 C18_9 C19_9 120.0 . . ?
C20_9 C19_9 C18_9 120.0 . . ?
C19_9 C20_9 C21_9 120.0 . . ?
C22_9 C21_9 C20_9 120.0 . . ?
C21_9 C22_9 C17_9 120.0 . . ?
C24_9 C23_9 C28_9 120.0 . . ?
C24_9 C23_9 P2_9 119.2(17) . . ?
C28_9 C23_9 P2_9 120.7(17) . . ?
C23_9 C24_9 C25_9 120.0 . . ?
C26_9 C25_9 C24_9 120.0 . . ?
C25_9 C26_9 C27_9 120.0 . . ?
C26_9 C27_9 C28_9 120.0 . . ?
C27_9 C28_9 C23_9 120.0 . . ?
C1_11 P1_11 C13_11 97.6(16) . . ?
C1_11 P1_11 C7_11 107.2(14) . . ?
C13_11 P1_11 C7_11 111.6(16) . . ?
C1_11 P1_11 Cu10 120.8(12) . . ?
C13_11 P1_11 Cu10 101.2(11) . . ?
C7_11 P1_11 Cu10 116.4(12) . . ?
C2_11 C1_11 C6_11 120.0 . . ?
C2_11 C1_11 P1_11 119.8(17) . . ?
C6_11 C1_11 P1_11 119.9(17) . . ?
C1_11 C2_11 C3_11 120.0 . . ?
C2_11 C3_11 C4_11 120.0 . . ?
C5_11 C4_11 C3_11 120.0 . . ?
C6_11 C5_11 C4_11 120.0 . . ?
C5_11 C6_11 C1_11 120.0 . . ?
C8_11 C7_11 C12_11 120.0 . . ?
C8_11 C7_11 P1_11 113.8(17) . . ?
C12_11 C7_11 P1_11 126.2(17) . . ?
C9_11 C8_11 C7_11 120.0 . . ?
C8_11 C9_11 C10_11 120.0 . . ?
C9_11 C10_11 C11_11 120.0 . . ?
C12_11 C11_11 C10_11 120.0 . . ?
C11_11 C12_11 C7_11 120.0 . . ?
C14_11 C13_11 C15_11 122(3) . . ?
C14_11 C13_11 P1_11 113(2) . . ?
C15_11 C13_11 P1_11 118(2) . . ?
C13_11 C14_11 C16_11 113(3) . . ?
C13_11 C14_11 P2_11 109(2) . . ?
C16_11 C14_11 P2_11 111(2) . . ?
C14_11 P2_11 C17_11 104.7(15) . . ?
C14_11 P2_11 C23_11 106.3(13) . . ?
C17_11 P2_11 C23_11 105.8(11) . . ?
C14_11 P2_11 Cu10 100.7(10) . . ?
C17_11 P2_11 Cu10 114.6(8) . . ?
C23_11 P2_11 Cu10 122.8(10) . . ?
C18_11 C17_11 C22_11 120.0 . . ?
C18_11 C17_11 P2_11 115.7(13) . . ?
C22_11 C17_11 P2_11 124.1(12) . . ?
C19_11 C18_11 C17_11 120.0 . . ?
C20_11 C19_11 C18_11 120.0 . . ?
C19_11 C20_11 C21_11 120.0 . . ?
C22_11 C21_11 C20_11 120.0 . . ?
C21_11 C22_11 C17_11 120.0 . . ?
C24_11 C23_11 C28_11 120.0 . . ?
C24_11 C23_11 P2_11 117.3(13) . . ?
C28_11 C23_11 P2_11 122.0(13) . . ?
C23_11 C24_11 C25_11 120.0 . . ?
C26_11 C25_11 C24_11 120.0 . . ?
C25_11 C26_11 C27_11 120.0 . . ?
C28_11 C27_11 C26_11 120.0 . . ?
C27_11 C28_11 C23_11 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 S1_6 2.462(10) . ?
Ag2 S1_1 2.468(10) . ?
Ag2 S2_2 2.546(11) . ?
Ag2 Cu4 2.872(5) . ?
Ag2 Ag3 2.923(5) . ?
Ag2 Cu1 2.936(6) . ?
Ag2 Ag1 3.200(4) . ?
Ag3 S2_2 2.420(10) . ?
Ag3 S2_3 2.452(11) . ?
Ag3 Ag5 2.895(5) . ?
Ag3 Ag4 2.917(6) . ?
Ag3 Ag1 2.926(5) . ?
Ag3 Cu2 3.087(6) . ?
Ag3 Cu1 3.114(7) . ?
Ag3 Cu3 3.176(7) . ?
Ag3 Cu4 3.210(6) . ?
Ag4 S1_4 2.434(11) . ?
Ag4 S1_5 2.448(11) . ?
Ag4 S2_3 2.585(11) . ?
Ag4 Cu2 2.859(5) . ?
Ag4 Cu3 2.944(6) . ?
Ag4 Ag5 3.231(4) . ?
Ag5 S2_4 2.442(10) . ?
Ag5 S2_5 2.487(10) . ?
Ag5 S2_2 2.613(12) . ?
Ag5 Cu3 2.906(5) . ?
Ag5 Cu2 2.988(5) . ?
Ag1 S2_6 2.445(10) . ?
Ag1 S2_1 2.465(10) . ?
Ag1 S2_3 2.566(12) . ?
Ag1 Cu1 2.892(5) . ?
Ag1 Cu4 2.963(5) . ?
Cu1 S1_2 2.199(11) . ?
Cu1 S1_1 2.227(13) . ?
Cu1 S2_1 2.241(11) . ?
Cu2 S1_2 2.172(11) . ?
Cu2 S1_5 2.217(11) . ?
Cu2 S2_5 2.276(10) . ?
Cu3 S1_3 2.184(11) . ?
Cu3 S2_4 2.203(10) . ?
Cu3 S1_4 2.277(12) . ?
Cu4 S1_3 2.185(11) . ?
Cu4 S1_6 2.210(11) . ?
Cu4 S2_6 2.230(10) . ?
C1_1 C2_1 1.3900 . ?
C1_1 C6_1 1.3900 . ?
C1_1 S1_1 1.772(12) . ?
C2_1 C3_1 1.3900 . ?
C2_1 S2_1 1.782(12) . ?
C3_1 F1_1 1.319(15) . ?
C3_1 C4_1 1.3900 . ?
C4_1 F2_1 1.351(15) . ?
C4_1 C5_1 1.3900 . ?
C5_1 F3_1 1.346(15) . ?
C5_1 C6_1 1.3900 . ?
C6_1 F4_1 1.337(15) . ?
C1_2 C6_2 1.383(18) . ?
C1_2 C2_2 1.399(18) . ?
C1_2 S1_2 1.774(16) . ?
C2_2 C3_2 1.378(18) . ?
C2_2 S2_2 1.772(16) . ?
C3_2 F1_2 1.339(18) . ?
C3_2 C4_2 1.371(18) . ?
C4_2 C5_2 1.369(19) . ?
C4_2 F2_2 1.368(18) . ?
C5_2 F3_2 1.372(19) . ?
C5_2 C6_2 1.392(19) . ?
C6_2 F4_2 1.369(18) . ?
C1_3 C6_3 1.390(18) . ?
C1_3 C2_3 1.395(18) . ?
C1_3 S1_3 1.762(16) . ?
C2_3 C3_3 1.377(18) . ?
C2_3 S2_3 1.781(17) . ?
C3_3 F1_3 1.336(18) . ?
C3_3 C4_3 1.366(19) . ?
C4_3 F2_3 1.368(18) . ?
C4_3 C5_3 1.37(2) . ?
C5_3 F3_3 1.370(19) . ?
C5_3 C6_3 1.384(19) . ?
C6_3 F4_3 1.361(19) . ?
C1_4 C2_4 1.390(18) . ?
C1_4 C6_4 1.395(19) . ?
C1_4 S1_4 1.773(16) . ?
C2_4 C3_4 1.386(18) . ?
C2_4 S2_4 1.765(16) . ?
C3_4 F1_4 1.347(18) . ?
C3_4 C4_4 1.364(19) . ?
C4_4 F2_4 1.344(18) . ?
C4_4 C5_4 1.355(19) . ?
C5_4 F3_4 1.351(18) . ?
C5_4 C6_4 1.379(19) . ?
C6_4 F4_4 1.343(18) . ?
C1_5 C2_5 1.383(17) . ?
C1_5 C6_5 1.388(18) . ?
C1_5 S1_5 1.765(15) . ?
C2_5 C3_5 1.372(17) . ?
C2_5 S2_5 1.776(16) . ?
C3_5 F1_5 1.347(17) . ?
C3_5 C4_5 1.364(18) . ?
C4_5 C5_5 1.352(18) . ?
C4_5 F2_5 1.361(17) . ?
C5_5 F3_5 1.362(18) . ?
C5_5 C6_5 1.393(18) . ?
C6_5 F4_5 1.353(18) . ?
C1_6 C6_6 1.385(18) . ?
C1_6 C2_6 1.398(17) . ?
C1_6 S1_6 1.771(16) . ?
C2_6 C3_6 1.384(17) . ?
C2_6 S2_6 1.783(16) . ?
C3_6 F1_6 1.327(17) . ?
C3_6 C4_6 1.372(18) . ?
C4_6 F2_6 1.358(17) . ?
C4_6 C5_6 1.362(18) . ?
C5_6 F3_6 1.346(18) . ?
C5_6 C6_6 1.387(18) . ?
C6_6 F4_6 1.353(18) . ?
C1_7 C2_7 1.3900 . ?
C1_7 C6_7 1.3900 . ?
C1_7 P1_7 1.790(14) . ?
C2_7 C3_7 1.3900 . ?
C3_7 C4_7 1.3900 . ?
C4_7 C5_7 1.3900 . ?
C5_7 C6_7 1.3900 . ?
C7_7 C8_7 1.3900 . ?
C7_7 C12_7 1.3900 . ?
C7_7 P1_7 1.832(16) . ?
C8_7 C9_7 1.3900 . ?
C9_7 C10_7 1.3900 . ?
C10_7 C11_7 1.3900 . ?
C11_7 C12_7 1.3900 . ?
C13_7 C14_7 1.3900 . ?
C13_7 C18_7 1.3900 . ?
C13_7 P1_7 1.784(14) . ?
C14_7 C15_7 1.3900 . ?
C15_7 C16_7 1.3900 . ?
C16_7 C17_7 1.3900 . ?
C17_7 C18_7 1.3900 . ?
C19_7 C20_7 1.3900 . ?
C19_7 C24_7 1.3900 . ?
C19_7 P1_7 1.762(14) . ?
C20_7 C21_7 1.3900 . ?
C21_7 C22_7 1.3900 . ?
C22_7 C23_7 1.3900 . ?
C23_7 C24_7 1.3900 . ?
C1_8 C2_8 1.3900 . ?
C1_8 C6_8 1.3900 . ?
C1_8 P1_8 1.784(14) . ?
C2_8 C3_8 1.3900 . ?
C3_8 C4_8 1.3900 . ?
C4_8 C5_8 1.3900 . ?
C5_8 C6_8 1.3900 . ?
C7_8 C8_8 1.3900 . ?
C7_8 C12_8 1.3900 . ?
C7_8 P1_8 1.815(15) . ?
C8_8 C9_8 1.3900 . ?
C9_8 C10_8 1.3900 . ?
C10_8 C11_8 1.3900 . ?
C11_8 C12_8 1.3900 . ?
C13_8 C14_8 1.3900 . ?
C13_8 C18_8 1.3900 . ?
C13_8 P1_8 1.769(15) . ?
C14_8 C15_8 1.3900 . ?
C15_8 C16_8 1.3900 . ?
C16_8 C17_8 1.3900 . ?
C17_8 C18_8 1.3900 . ?
C19_8 C20_8 1.3900 . ?
C19_8 C24_8 1.3900 . ?
C19_8 P1_8 1.744(16) . ?
C20_8 C21_8 1.3900 . ?
C21_8 C22_8 1.3900 . ?
C22_8 C23_8 1.3900 . ?
C23_8 C24_8 1.3900 . ?
Cu10 P1_11 2.216(13) . ?
Cu10 P2_9 2.228(13) . ?
Cu10 P2_11 2.245(11) . ?
Cu10 P1_9 2.360(17) . ?
P1_9 C1_9 1.807(14) . ?
P1_9 C13_9 1.813(15) . ?
P1_9 C7_9 1.87(2) . ?
C1_9 C2_9 1.3900 . ?
C1_9 C6_9 1.3900 . ?
C2_9 C3_9 1.3900 . ?
C3_9 C4_9 1.3900 . ?
C4_9 C5_9 1.3900 . ?
C5_9 C6_9 1.3900 . ?
C7_9 C8_9 1.3900 . ?
C7_9 C12_9 1.3900 . ?
C8_9 C9_9 1.3900 . ?
C9_9 C10_9 1.3900 . ?
C10_9 C11_9 1.3900 . ?
C11_9 C12_9 1.3900 . ?
C13_9 C14_9 1.519(13) . ?
C13_9 C15_9 1.537(14) . ?
C14_9 C16_9 1.544(14) . ?
C14_9 P2_9 1.813(15) . ?
P2_9 C17_9 1.812(13) . ?
P2_9 C23_9 1.85(2) . ?
C17_9 C18_9 1.3900 . ?
C17_9 C22_9 1.3900 . ?
C18_9 C19_9 1.3900 . ?
C19_9 C20_9 1.3900 . ?
C20_9 C21_9 1.3900 . ?
C21_9 C22_9 1.3900 . ?
C23_9 C24_9 1.3900 . ?
C23_9 C28_9 1.3900 . ?
C24_9 C25_9 1.3900 . ?
C25_9 C26_9 1.3900 . ?
C26_9 C27_9 1.3900 . ?
C27_9 C28_9 1.3900 . ?
P1_11 C1_11 1.810(18) . ?
P1_11 C13_11 1.81(2) . ?
P1_11 C7_11 1.87(2) . ?
C1_11 C2_11 1.3900 . ?
C1_11 C6_11 1.3900 . ?
C2_11 C3_11 1.3900 . ?
C3_11 C4_11 1.3900 . ?
C4_11 C5_11 1.3900 . ?
C5_11 C6_11 1.3900 . ?
C7_11 C8_11 1.3900 . ?
C7_11 C12_11 1.3900 . ?
C8_11 C9_11 1.3900 . ?
C9_11 C10_11 1.3900 . ?
C10_11 C11_11 1.3900 . ?
C11_11 C12_11 1.3900 . ?
C13_11 C14_11 1.48(3) . ?
C13_11 C15_11 1.54(3) . ?
C14_11 C16_11 1.55(3) . ?
C14_11 P2_11 1.82(2) . ?
P2_11 C17_11 1.828(16) . ?
P2_11 C23_11 1.841(17) . ?
C17_11 C18_11 1.3900 . ?
C17_11 C22_11 1.3900 . ?
C18_11 C19_11 1.3900 . ?
C19_11 C20_11 1.3900 . ?
C20_11 C21_11 1.3900 . ?
C21_11 C22_11 1.3900 . ?
C23_11 C24_11 1.3900 . ?
C23_11 C28_11 1.3900 . ?
C24_11 C25_11 1.3900 . ?
C25_11 C26_11 1.3900 . ?
C26_11 C27_11 1.3900 . ?
C27_11 C28_11 1.3900 . ?
