#------------------------------------------------------------------------------
#$Date: 2017-03-05 21:59:09 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193981 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/15/15/7151535.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7151535
loop_
_publ_author_name
'Uno, Hidemitsu'
'Inoue, Kentarou'
'Inoue, Takashi'
'Ono, Noboru'
_publ_section_title
;
 Oligocyclization of 2-(hydroxymethyl)pyrroles with
 electron-withdrawing groups at ?-positions: formation and structural
 elucidation of porphyrinogens and hexaphyrinogensElectronic Supporting
 Information Available: Ortep drawings of 3d�2EtOH,
 3d�2DMF, 3e, 3e�2H2O, 3g�2(i-PrOH),
 3g�2DMF�2CHCl3, 4a�4CHCl3, 4a�4PhCl,
 5a�2PhCl, 5d, 5d��PhCl, and 5e; packing diagrams
 of 5d and 5d��PhCl; and their X-ray analyses data in CIF
 format. See http://www.rsc.org/suppdata/ob/b3/b307132d/
;
_journal_issue                   21
_journal_name_full               'Organic &  Biomolecular Chemistry'
_journal_page_first              3857
_journal_paper_doi               10.1039/b307132d
_journal_volume                  1
_journal_year                    2003
_chemical_formula_moiety         'C48 H18 Cl8 F12 N4 '
_chemical_formula_sum            'C48 H18 Cl8 F12 N4'
_chemical_formula_weight         1162.30
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 116.761(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   14.995(3)
_cell_length_b                   12.084(2)
_cell_length_c                   15.045(3)
_cell_measurement_reflns_used    7640
_cell_measurement_temperature    173.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     2434.2(8)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_molecular_graphics    'Ortep-3 and Mercury '
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9874
_diffrn_measured_fraction_theta_max 0.9874
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       w
_diffrn_radiation_type           'Mo Ka'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24573
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.548
_exptl_absorpt_correction_T_max  0.896
_exptl_absorpt_correction_T_min  0.803
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   Coppens_numerical
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.586
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1156
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.350
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.67
_refine_diff_density_min         -0.63
_refine_ls_goodness_of_fit_ref   1.665
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     337
_refine_ls_number_reflns         5506
_refine_ls_R_factor_gt           0.0742
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[s²(Fo²) + (0.05000(Max(Fo²,0) + 2Fc²)/3)²]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1869
_reflns_number_gt                3298
_reflns_number_total             5506
_reflns_threshold_expression     F²>2.0s(F²)
_cod_data_source_file            b307132d.txt
_cod_data_source_block           5e
_cod_depositor_comments
;
The following automatic conversions were performed:
data name '_geom_hbond_site_distance_dh' replaced with
'_geom_hbond_distance_DH' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_hbond_site_distance_ha' replaced with
'_geom_hbond_distance_HA' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_hbond_site_distance_da' replaced with
'_geom_hbond_distance_DA' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 5005 2017-03-03 11:38:54Z antanas 
;
_cod_original_cell_volume        2434.1(9)
_cod_original_sg_symbol_Hall     '-P 2yab '
_cod_original_sg_symbol_H-M      'P 21/a '
_cod_original_formula_sum        'C48 H18 Cl8 F12 N4 '
_cod_database_code               7151535
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
1/2-x,1/2+y,-z
-x,-y,-z
1/2+x,1/2-y,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl(1) Cl 0.83191(8) 0.39921(9) 0.3843(1) 0.1052(4) Uani 1.00 d . . .
Cl(2) Cl 0.7029(1) 0.81981(9) 0.3409(1) 0.1264(6) Uani 1.00 d . . .
Cl(3) Cl 0.1332(1) 0.5772(1) 0.0909(1) 0.1262(6) Uani 1.00 d . . .
Cl(4) Cl 0.3104(1) 0.1824(1) 0.1510(1) 0.1383(6) Uani 1.00 d . . .
F(1) F 0.6498(2) 0.5712(4) 0.1509(2) 0.099(1) Uani 0.80 d P . .
F(1a) F 0.555(2) 0.633(2) 0.127(1) 0.129(6) Uiso 0.20 d P . .
F(2) F 0.4933(3) 0.5897(5) 0.1051(2) 0.115(1) Uani 0.80 d P . .
F(2a) F 0.513(1) 0.483(2) 0.107(1) 0.091(5) Uiso 0.20 d P . .
F(3) F 0.5549(4) 0.4320(3) 0.1272(3) 0.110(1) Uani 0.80 d P . .
F(3a) F 0.641(2) 0.487(2) 0.150(1) 0.131(6) Uiso 0.20 d P . .
F(4) F 0.1110(1) 0.2504(2) 0.3107(2) 0.0878(7) Uani 1.00 d . . .
F(5) F 0.0609(1) 0.4165(2) 0.2757(2) 0.0869(7) Uani 1.00 d . . .
F(6) F 0.0623(1) 0.3112(2) 0.1634(1) 0.0840(7) Uani 1.00 d . . .
N(1) N 0.5633(2) 0.5239(2) 0.4057(2) 0.0437(6) Uani 1.00 d . . .
N(2) N 0.3745(2) 0.4387(2) 0.3804(2) 0.0446(6) Uani 1.00 d . . .
C(1) C 0.6568(2) 0.5653(2) 0.4350(2) 0.0412(7) Uani 1.00 d . . .
C(2) C 0.6769(2) 0.5730(2) 0.3492(2) 0.0438(8) Uani 1.00 d . . .
C(3) C 0.5930(2) 0.5383(2) 0.2695(2) 0.0450(8) Uani 1.00 d . . .
C(4) C 0.5216(2) 0.5060(2) 0.3054(2) 0.0428(8) Uani 1.00 d . . .
C(5) C 0.4268(2) 0.4638(2) 0.2490(2) 0.0472(8) Uani 1.00 d . . .
C(6) C 0.3593(2) 0.4330(2) 0.2843(2) 0.0431(7) Uani 1.00 d . . .
C(7) C 0.2591(2) 0.3922(2) 0.2227(2) 0.0465(8) Uani 1.00 d . . .
C(8) C 0.2168(2) 0.3754(2) 0.2848(2) 0.0450(7) Uani 1.00 d . . .
C(9) C 0.2890(2) 0.4044(2) 0.3846(2) 0.0426(7) Uani 1.00 d . . .
C(10) C 0.2752(2) 0.4023(2) 0.4696(2) 0.0455(8) Uani 1.00 d . . .
C(11) C 0.7739(2) 0.6125(2) 0.3568(2) 0.0469(8) Uani 1.00 d . . .
C(12) C 0.8500(2) 0.5392(3) 0.3716(2) 0.0595(10) Uani 1.00 d . . .
C(13) C 0.9411(3) 0.5756(4) 0.3792(3) 0.080(1) Uani 1.00 d . . .
C(14) C 0.9558(3) 0.6873(4) 0.3745(3) 0.085(1) Uani 1.00 d . . .
C(15) C 0.8849(3) 0.7600(4) 0.3634(3) 0.088(1) Uani 1.00 d . . .
C(16) C 0.7939(3) 0.7239(3) 0.3543(3) 0.068(1) Uani 1.00 d . . .
C(17) C 0.5745(3) 0.5354(3) 0.1644(3) 0.064(1) Uani 1.00 d . . .
C(18) C 0.2175(2) 0.3775(3) 0.1135(2) 0.0569(9) Uani 1.00 d . . .
C(19) C 0.1591(3) 0.4577(4) 0.0460(3) 0.081(1) Uani 1.00 d . . .
C(20) C 0.1213(4) 0.4400(6) -0.0565(4) 0.122(2) Uani 1.00 d . . .
C(21) C 0.1441(5) 0.3448(9) -0.0897(4) 0.145(3) Uani 1.00 d . . .
C(22) C 0.1998(4) 0.2686(6) -0.0287(4) 0.125(2) Uani 1.00 d . . .
C(23) C 0.2370(3) 0.2823(4) 0.0736(3) 0.085(1) Uani 1.00 d . . .
C(24) C 0.1134(2) 0.3369(3) 0.2582(2) 0.0551(9) Uani 1.00 d . . .
H(1N) H 0.5325 0.5098 0.4477 0.0525 Uiso 0.50 calc P . .
H(2N) H 0.4342 0.4624 0.4354 0.0535 Uiso 0.50 calc P . .
H(5) H 0.4059 0.4550 0.1797 0.0566 Uiso 1.00 calc . . .
H(10) H 0.2128 0.3799 0.4657 0.0546 Uiso 1.00 calc . . .
H(13) H 0.9922 0.5242 0.3874 0.0954 Uiso 1.00 calc . . .
H(14) H 1.0177 0.7130 0.3793 0.1024 Uiso 1.00 calc . . .
H(15) H 0.8969 0.8370 0.3616 0.1055 Uiso 1.00 calc . . .
H(20) H 0.0801 0.4942 -0.1024 0.1467 Uiso 1.00 calc . . .
H(21) H 0.1187 0.3334 -0.1594 0.1740 Uiso 1.00 calc . . .
H(22) H 0.2151 0.2033 -0.0543 0.1500 Uiso 1.00 calc . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
H H 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
Cl Cl 0.148 0.159
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
F F 0.017 0.010
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
N N 0.006 0.003
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C(1) N(1) C(4) 107.9(2) . . . yes
C(6) N(2) C(9) 108.7(2) . . . yes
N(1) C(1) C(2) 109.3(2) . . . yes
N(1) C(1) C(10) 127.4(2) . . 3_666 yes
C(2) C(1) C(10) 123.3(2) . . 3_666 yes
C(1) C(2) C(3) 106.5(2) . . . yes
C(1) C(2) C(11) 122.6(2) . . . yes
C(3) C(2) C(11) 130.9(2) . . . yes
C(2) C(3) C(4) 107.4(2) . . . yes
C(2) C(3) C(17) 127.3(2) . . . yes
C(4) C(3) C(17) 125.2(3) . . . yes
N(1) C(4) C(3) 108.8(2) . . . yes
N(1) C(4) C(5) 124.6(2) . . . yes
C(3) C(4) C(5) 126.6(3) . . . yes
C(4) C(5) C(6) 126.0(3) . . . yes
N(2) C(6) C(5) 126.2(2) . . . yes
N(2) C(6) C(7) 109.1(2) . . . yes
C(5) C(6) C(7) 124.7(2) . . . yes
C(6) C(7) C(8) 106.3(2) . . . yes
C(6) C(7) C(18) 123.2(2) . . . yes
C(8) C(7) C(18) 130.5(2) . . . yes
C(7) C(8) C(9) 108.3(2) . . . yes
C(7) C(8) C(24) 127.8(3) . . . yes
C(9) C(8) C(24) 123.9(2) . . . yes
N(2) C(9) C(8) 107.7(2) . . . yes
N(2) C(9) C(10) 125.3(2) . . . yes
C(8) C(9) C(10) 127.0(2) . . . yes
C(1) C(10) C(9) 127.0(2) 3_666 . . yes
C(2) C(11) C(12) 121.0(3) . . . yes
C(2) C(11) C(16) 121.8(3) . . . yes
C(12) C(11) C(16) 117.0(3) . . . yes
Cl(1) C(12) C(11) 118.9(2) . . . yes
Cl(1) C(12) C(13) 119.7(3) . . . yes
C(11) C(12) C(13) 121.4(3) . . . yes
C(12) C(13) C(14) 118.7(3) . . . yes
C(13) C(14) C(15) 121.2(3) . . . yes
C(14) C(15) C(16) 120.2(4) . . . yes
Cl(2) C(16) C(11) 119.0(2) . . . yes
Cl(2) C(16) C(15) 119.5(3) . . . yes
C(11) C(16) C(15) 121.5(3) . . . yes
F(1) C(17) F(2) 109.2(4) . . . yes
F(1) C(17) F(3) 106.5(3) . . . yes
F(1) C(17) C(3) 113.5(3) . . . yes
F(1a) C(17) F(2a) 103(1) . . . yes
F(1a) C(17) F(3a) 113(1) . . . yes
F(2) C(17) F(3) 102.7(4) . . . yes
F(2) C(17) C(3) 112.6(3) . . . yes
F(2a) C(17) F(3a) 92(1) . . . yes
F(3) C(17) C(3) 111.6(3) . . . yes
F(3a) C(17) C(3) 114.2(9) . . . yes
C(7) C(18) C(19) 122.5(3) . . . yes
C(7) C(18) C(23) 120.9(3) . . . yes
C(19) C(18) C(23) 116.6(3) . . . yes
Cl(3) C(19) C(18) 118.6(3) . . . yes
Cl(3) C(19) C(20) 120.8(4) . . . yes
C(18) C(19) C(20) 120.5(5) . . . yes
C(19) C(20) C(21) 119.4(5) . . . yes
C(20) C(21) C(22) 121.8(5) . . . yes
C(21) C(22) C(23) 120.4(6) . . . yes
Cl(4) C(23) C(18) 119.5(3) . . . yes
Cl(4) C(23) C(22) 119.2(4) . . . yes
C(18) C(23) C(22) 121.3(5) . . . yes
F(4) C(24) F(5) 105.9(3) . . . yes
F(4) C(24) F(6) 107.6(3) . . . yes
F(4) C(24) C(8) 113.0(3) . . . yes
F(5) C(24) F(6) 106.0(3) . . . yes
F(5) C(24) C(8) 110.8(2) . . . yes
F(6) C(24) C(8) 113.1(2) . . . yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl(1) C(12) 1.737(4) . . yes
Cl(2) C(16) 1.732(4) . . yes
Cl(3) C(19) 1.711(5) . . yes
Cl(4) C(23) 1.693(5) . . yes
F(1) C(17) 1.309(4) . . yes
F(1a) C(17) 1.28(2) . . yes
F(2) C(17) 1.315(5) . . yes
F(2a) C(17) 1.13(2) . . yes
F(3) C(17) 1.347(5) . . yes
F(3a) C(17) 1.25(2) . . yes
F(4) C(24) 1.321(4) . . yes
F(5) C(24) 1.342(4) . . yes
F(6) C(24) 1.316(3) . . yes
N(1) C(1) 1.361(3) . . yes
N(1) C(4) 1.366(3) . . yes
N(2) C(6) 1.359(3) . . yes
N(2) C(9) 1.375(3) . . yes
C(1) C(2) 1.456(4) . . yes
C(1) C(10) 1.390(4) . 3_666 yes
C(2) C(3) 1.355(4) . . yes
C(2) C(11) 1.486(4) . . yes
C(3) C(4) 1.453(3) . . yes
C(3) C(17) 1.477(4) . . yes
C(4) C(5) 1.384(4) . . yes
C(5) C(6) 1.390(4) . . yes
C(6) C(7) 1.450(4) . . yes
C(7) C(8) 1.361(4) . . yes
C(7) C(18) 1.482(4) . . yes
C(8) C(9) 1.444(4) . . yes
C(8) C(24) 1.490(4) . . yes
C(9) C(10) 1.386(4) . . yes
C(11) C(12) 1.381(4) . . yes
C(11) C(16) 1.384(4) . . yes
C(12) C(13) 1.390(5) . . yes
C(13) C(14) 1.375(6) . . yes
C(14) C(15) 1.331(6) . . yes
C(15) C(16) 1.379(5) . . yes
C(18) C(19) 1.392(5) . . yes
C(18) C(23) 1.388(5) . . yes
C(19) C(20) 1.399(7) . . yes
C(20) C(21) 1.359(9) . . yes
C(21) C(22) 1.302(10) . . yes
C(22) C(23) 1.391(6) . . yes
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_1
_geom_contact_site_symmetry_2
_geom_contact_publ_flag
Cl(1) F(4) 3.488(3) . 4_555 ?
Cl(1) Cl(4) 3.519(2) . 4_555 ?
Cl(2) C(9) 3.527(3) . 4_565 ?
Cl(4) F(3a) 3.26(2) . 4_455 ?
Cl(4) F(5) 3.566(3) . 4_555 ?
F(1) F(2a) 3.59(2) . 3_665 ?
F(1a) F(2a) 3.48(2) . 3_665 ?
F(1a) F(3) 3.50(2) . 3_665 ?
F(2) F(3) 3.246(4) . 3_665 ?
F(2) F(2a) 3.27(2) . 3_665 ?
F(2) C(22) 3.373(7) . 2_555 ?
F(2) F(3a) 3.57(2) . 3_665 ?
F(2a) F(2a) 3.09(3) . 3_665 ?
F(2a) F(3) 3.35(2) . 3_665 ?
F(2a) F(3a) 3.52(3) . 3_665 ?
F(3) F(6) 2.982(5) . 4_555 ?
F(3) F(4) 3.331(5) . 4_555 ?
F(4) C(4) 3.363(4) . 4_455 ?
F(4) C(3) 3.532(4) . 4_455 ?
F(4) C(5) 3.589(3) . 4_455 ?
F(5) C(13) 3.445(4) . 1_455 ?
N(1) C(15) 3.585(4) . 4_465 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N(1) H(1N) N(2) . . . 0.950 2.284 2.872(3) 119.361 no
N(2) H(2N) N(1) . . . 0.950 2.297 2.872(3) 118.304 no
N(1) H(1N) N(2) . . 3_666 0.950 2.404 2.954(3) 116.636 no
N(2) H(2N) N(1) . . 3_666 0.950 2.379 2.954(3) 118.641 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl(1) C(12) C(11) C(2) -1.6(4) . . . . yes
Cl(1) C(12) C(11) C(16) 175.4(2) . . . . yes
Cl(1) C(12) C(13) C(14) -176.4(3) . . . . yes
Cl(2) C(16) C(11) C(2) -0.5(4) . . . . yes
Cl(2) C(16) C(11) C(12) -177.5(2) . . . . yes
Cl(2) C(16) C(15) C(14) 179.5(3) . . . . yes
Cl(3) C(19) C(18) C(7) -0.7(4) . . . . yes
Cl(3) C(19) C(18) C(23) -179.7(3) . . . . yes
Cl(3) C(19) C(20) C(21) 179.3(4) . . . . yes
Cl(4) C(23) C(18) C(7) -0.7(5) . . . . yes
Cl(4) C(23) C(18) C(19) 178.2(3) . . . . yes
Cl(4) C(23) C(22) C(21) -179.2(5) . . . . yes
F(1) C(17) C(3) C(2) 0.0(6) . . . . yes
F(1) C(17) C(3) C(4) 178.4(4) . . . . yes
F(1a) C(17) C(3) C(2) -76(1) . . . . yes
F(1a) C(17) C(3) C(4) 101(1) . . . . yes
F(2) C(17) C(3) C(2) -124.8(4) . . . . yes
F(2) C(17) C(3) C(4) 53.6(5) . . . . yes
F(2a) C(17) C(3) C(2) 162(1) . . . . yes
F(2a) C(17) C(3) C(4) -19(1) . . . . yes
F(3) C(17) C(3) C(2) 120.4(4) . . . . yes
F(3) C(17) C(3) C(4) -61.3(5) . . . . yes
F(3a) C(17) C(3) C(2) 51(1) . . . . yes
F(3a) C(17) C(3) C(4) -129(1) . . . . yes
F(4) C(24) C(8) C(7) 126.9(3) . . . . yes
F(4) C(24) C(8) C(9) -55.0(4) . . . . yes
F(5) C(24) C(8) C(7) -114.5(3) . . . . yes
F(5) C(24) C(8) C(9) 63.6(4) . . . . yes
F(6) C(24) C(8) C(7) 4.3(5) . . . . yes
F(6) C(24) C(8) C(9) -177.6(3) . . . . yes
N(1) C(1) C(2) C(3) 1.5(3) . . . . yes
N(1) C(1) C(2) C(11) -178.3(2) . . . . yes
N(1) C(1) C(10) C(9) -0.7(5) . . 3_666 3_666 yes
N(1) C(4) C(3) C(2) 1.1(3) . . . . yes
N(1) C(4) C(3) C(17) -177.6(3) . . . . yes
N(1) C(4) C(5) C(6) 0.1(5) . . . . yes
N(2) C(6) C(5) C(4) -0.2(5) . . . . yes
N(2) C(6) C(7) C(8) 0.5(3) . . . . yes
N(2) C(6) C(7) C(18) 179.1(3) . . . . yes
N(2) C(9) C(8) C(7) 0.0(3) . . . . yes
N(2) C(9) C(8) C(24) -178.4(3) . . . . yes
N(2) C(9) C(10) C(1) 0.7(5) . . . 3_666 yes
C(1) N(1) C(4) C(3) -0.1(3) . . . . yes
C(1) N(1) C(4) C(5) 179.8(3) . . . . yes
C(1) C(2) C(3) C(4) -1.5(3) . . . . yes
C(1) C(2) C(3) C(17) 177.1(3) . . . . yes
C(1) C(2) C(11) C(12) 91.9(3) . . . . yes
C(1) C(2) C(11) C(16) -84.9(4) . . . . yes
C(1) C(10) C(9) C(8) 177.0(3) . 3_666 3_666 3_666 yes
C(2) C(1) N(1) C(4) -0.9(3) . . . . yes
C(2) C(1) C(10) C(9) 178.4(3) . . 3_666 3_666 yes
C(2) C(3) C(4) C(5) -178.8(3) . . . . yes
C(2) C(11) C(12) C(13) -179.8(3) . . . . yes
C(2) C(11) C(16) C(15) 178.8(3) . . . . yes
C(3) C(2) C(1) C(10) -177.7(3) . . . 3_666 yes
C(3) C(2) C(11) C(12) -87.9(4) . . . . yes
C(3) C(2) C(11) C(16) 95.2(4) . . . . yes
C(3) C(4) C(5) C(6) 179.9(3) . . . . yes
C(4) N(1) C(1) C(10) 178.4(3) . . . 3_666 yes
C(4) C(3) C(2) C(11) 178.3(3) . . . . yes
C(4) C(5) C(6) C(7) 178.0(3) . . . . yes
C(5) C(4) C(3) C(17) 2.6(5) . . . . yes
C(5) C(6) N(2) C(9) 177.9(3) . . . . yes
C(5) C(6) C(7) C(8) -178.0(3) . . . . yes
C(5) C(6) C(7) C(18) 0.7(5) . . . . yes
C(6) N(2) C(9) C(8) 0.3(3) . . . . yes
C(6) N(2) C(9) C(10) -177.8(3) . . . . yes
C(6) C(7) C(8) C(9) -0.3(3) . . . . yes
C(6) C(7) C(8) C(24) 178.1(3) . . . . yes
C(6) C(7) C(18) C(19) -95.4(4) . . . . yes
C(6) C(7) C(18) C(23) 83.5(4) . . . . yes
C(7) C(6) N(2) C(9) -0.5(3) . . . . yes
C(7) C(8) C(9) C(10) 178.1(3) . . . . yes
C(7) C(18) C(19) C(20) -179.9(3) . . . . yes
C(7) C(18) C(23) C(22) -178.8(4) . . . . yes
C(8) C(7) C(18) C(19) 82.9(4) . . . . yes
C(8) C(7) C(18) C(23) -98.2(4) . . . . yes
C(9) C(8) C(7) C(18) -178.8(3) . . . . yes
C(10) C(9) C(8) C(24) -0.3(5) . . . . yes
C(11) C(2) C(3) C(17) -3.1(5) . . . . yes
C(11) C(12) C(13) C(14) 1.9(5) . . . . yes
C(11) C(16) C(15) C(14) 0.2(6) . . . . yes
C(12) C(11) C(16) C(15) 1.8(5) . . . . yes
C(12) C(13) C(14) C(15) 0.2(6) . . . . yes
C(13) C(12) C(11) C(16) -2.8(5) . . . . yes
C(13) C(14) C(15) C(16) -1.3(7) . . . . yes
C(18) C(7) C(8) C(24) -0.4(5) . . . . yes
C(18) C(19) C(20) C(21) -1.5(7) . . . . yes
C(18) C(23) C(22) C(21) -1.1(8) . . . . yes
C(19) C(18) C(23) C(22) 0.1(6) . . . . yes
C(19) C(20) C(21) C(22) 0.5(10) . . . . yes
C(20) C(19) C(18) C(23) 1.2(5) . . . . yes
C(20) C(21) C(22) C(23) 0(1) . . . . yes
C(20) C(21) C(22) C(23) 0(1) . . . . yes
