#------------------------------------------------------------------------------
#$Date: 2019-11-08 03:46:52 +0200 (Fri, 08 Nov 2019) $
#$Revision: 225182 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/15/68/7156821.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7156821
loop_
_publ_author_name
'Ma, Jiao-Xia'
'Fang, Xu'
'Xue, Min'
'Yang, Yong'
_publ_section_title
;
 Synthesis, structure, and anion binding of functional oxacalix[4]arenes.
;
_journal_issue                   20
_journal_name_full               'Organic & biomolecular chemistry'
_journal_page_first              5075
_journal_page_last               5085
_journal_paper_doi               10.1039/c9ob00613c
_journal_volume                  17
_journal_year                    2019
_chemical_formula_moiety         'C48 H52 N4 O16'
_chemical_formula_sum            'C48 H52 N4 O16'
_chemical_formula_weight         940.94
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-10-15 deposited with the CCDC.    2019-04-24 downloaded from the CCDC.
;
_cell_angle_alpha                94.145(9)
_cell_angle_beta                 105.695(4)
_cell_angle_gamma                103.095(9)
_cell_formula_units_Z            1
_cell_length_a                   8.710(4)
_cell_length_b                   11.844(6)
_cell_length_c                   13.132(6)
_cell_measurement_reflns_used    3991
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      2.2
_cell_volume                     1257.3(10)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0415
_diffrn_reflns_av_sigmaI/netI    0.0622
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15913
_diffrn_reflns_theta_full        27.86
_diffrn_reflns_theta_max         27.86
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    0.094
_exptl_absorpt_correction_T_max  0.9907
_exptl_absorpt_correction_T_min  0.9851
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.243
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             496
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.10
_platon_squeeze_details          ' '
_refine_diff_density_max         0.308
_refine_diff_density_min         -0.268
_refine_diff_density_rms         0.047
_refine_ls_extinction_coef       0.044(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.941
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     321
_refine_ls_number_reflns         5959
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.941
_refine_ls_R_factor_all          0.0559
_refine_ls_R_factor_gt           0.0384
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0607P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0987
_refine_ls_wR_factor_ref         0.1068
_reflns_number_gt                3803
_reflns_number_total             5959
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c9ob00613c2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
'Adding full bibliography for 7156819--7156821.cif.'
_cod_original_cell_volume        1257.4(10)
_cod_database_code               7156821
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O1 O 0.14202(10) 0.29442(7) 0.50972(6) 0.0167(2) Uani 1 1 d .
N1 N 0.41875(13) 0.31454(9) 0.45088(8) 0.0175(2) Uani 1 1 d .
H1A H 0.3621(19) 0.3665(14) 0.4454(12) 0.031(4) Uiso 1 1 d .
C1 C -0.07213(15) 0.13959(11) 0.38848(9) 0.0160(3) Uani 1 1 d .
H1 H -0.0505 0.0852 0.4368 0.019 Uiso 1 1 calc R
O2 O 0.28884(10) 0.01030(7) 0.73845(6) 0.0163(2) Uani 1 1 d .
N2 N 0.56831(13) 0.02596(9) 0.68564(9) 0.0181(2) Uani 1 1 d .
H2 H 0.5310(18) -0.0174(13) 0.7296(12) 0.026(4) Uiso 1 1 d .
C2 C -0.19690(15) 0.10467(10) 0.29301(9) 0.0146(3) Uani 1 1 d .
O3 O -0.50708(11) 0.08125(8) 0.11825(7) 0.0245(2) Uani 1 1 d .
C3 C -0.23157(15) 0.18348(11) 0.22097(9) 0.0157(3) Uani 1 1 d .
O4 O -0.35711(12) 0.21794(8) 0.04949(7) 0.0267(2) Uani 1 1 d .
C4 C -0.13686(15) 0.29852(11) 0.24849(10) 0.0181(3) Uani 1 1 d .
H4 H -0.1594 0.3532 0.2006 0.022 Uiso 1 1 calc R
O5 O 0.23555(11) 0.49337(8) 0.41327(8) 0.0259(2) Uani 1 1 d .
C5 C -0.01001(15) 0.33649(11) 0.34381(10) 0.0168(3) Uani 1 1 d .
O6 O -0.00149(11) 0.53217(8) 0.32824(8) 0.0264(2) Uani 1 1 d .
C6 C 0.02104(14) 0.25469(10) 0.41292(9) 0.0149(3) Uani 1 1 d .
O7 O 0.61623(13) 0.25600(9) 0.39326(8) 0.0338(3) Uani 1 1 d .
C7 C 0.20519(15) 0.14563(10) 0.61917(9) 0.0157(3) Uani 1 1 d .
H7 H 0.1068 0.1392 0.6391 0.019 Uiso 1 1 calc R
O8 O 0.79137(11) 0.08088(8) 0.62297(7) 0.0240(2) Uani 1 1 d .
C8 C 0.24269(15) 0.22037(10) 0.54818(10) 0.0154(3) Uani 1 1 d .
C9 C 0.38730(15) 0.23144(10) 0.51820(9) 0.0155(3) Uani 1 1 d .
C10 C 0.49543(15) 0.16437(10) 0.56047(9) 0.0166(3) Uani 1 1 d .
H10 H 0.5926 0.1694 0.5394 0.020 Uiso 1 1 calc R
C11 C 0.46132(15) 0.09002(10) 0.63359(9) 0.0157(3) Uani 1 1 d .
C12 C 0.31431(15) 0.08079(10) 0.66029(9) 0.0150(3) Uani 1 1 d .
C13 C -0.37906(16) 0.15230(11) 0.12566(10) 0.0185(3) Uani 1 1 d .
C14 C -0.5000(2) 0.20117(13) -0.04287(11) 0.0386(4) Uani 1 1 d .
H14A H -0.5357 0.1189 -0.0754 0.058 Uiso 1 1 calc R
H14B H -0.4713 0.2508 -0.0950 0.058 Uiso 1 1 calc R
H14C H -0.5896 0.2225 -0.0207 0.058 Uiso 1 1 calc R
C15 C 0.08949(16) 0.46006(11) 0.36739(10) 0.0183(3) Uani 1 1 d .
C16 C 0.08771(17) 0.65419(11) 0.34212(12) 0.0265(3) Uani 1 1 d .
H16A H 0.1331 0.6843 0.4185 0.040 Uiso 1 1 calc R
H16B H 0.0124 0.6996 0.3074 0.040 Uiso 1 1 calc R
H16C H 0.1779 0.6611 0.3098 0.040 Uiso 1 1 calc R
C17 C 0.53567(17) 0.32690(11) 0.39825(10) 0.0214(3) Uani 1 1 d .
C18 C 0.55654(18) 0.43507(12) 0.34348(11) 0.0255(3) Uani 1 1 d .
H18A H 0.5063 0.4915 0.3734 0.031 Uiso 1 1 calc R
H18B H 0.6757 0.4726 0.3590 0.031 Uiso 1 1 calc R
C19 C 0.4792(2) 0.40894(15) 0.22436(12) 0.0451(4) Uani 1 1 d .
H19A H 0.3578 0.3819 0.2079 0.054 Uiso 1 1 calc R
H19B H 0.5185 0.3454 0.1949 0.054 Uiso 1 1 calc R
C20 C 0.5235(3) 0.5179(2) 0.17215(16) 0.0778(7) Uani 1 1 d .
H20A H 0.4829 0.5803 0.2005 0.117 Uiso 1 1 calc R
H20B H 0.4724 0.4993 0.0947 0.117 Uiso 1 1 calc R
H20C H 0.6436 0.5440 0.1878 0.117 Uiso 1 1 calc R
C21 C 0.72249(16) 0.02510(11) 0.68027(10) 0.0190(3) Uani 1 1 d .
C22 C 0.80593(17) -0.04876(13) 0.75455(12) 0.0278(3) Uani 1 1 d .
H22A H 0.8376 -0.1080 0.7130 0.033 Uiso 1 1 calc R
H22B H 0.7285 -0.0904 0.7907 0.033 Uiso 1 1 calc R
C23 C 0.9599(2) 0.02863(16) 0.83825(13) 0.0422(4) Uani 1 1 d .
H23A H 1.0177 -0.0217 0.8829 0.051 Uiso 1 1 calc R
H23B H 1.0357 0.0711 0.8014 0.051 Uiso 1 1 calc R
C24 C 0.9195(3) 0.11606(18) 0.90923(14) 0.0598(6) Uani 1 1 d .
H24A H 0.8741 0.1719 0.8666 0.090 Uiso 1 1 calc R
H24B H 1.0201 0.1582 0.9655 0.090 Uiso 1 1 calc R
H24C H 0.8381 0.0750 0.9418 0.090 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 O1 C8 117.23(9) . .
C17 N1 C9 127.03(11) . .
C17 N1 H1A 116.5(10) . .
C9 N1 H1A 116.3(10) . .
C2 C1 C6 119.24(11) . .
C2 C1 H1 120.4 . .
C6 C1 H1 120.4 . .
C2 O2 C12 119.18(9) 2_556 .
C21 N2 C11 129.23(11) . .
C21 N2 H2 116.5(10) . .
C11 N2 H2 114.2(10) . .
C1 C2 O2 122.01(10) . 2_556
C1 C2 C3 121.34(11) . .
O2 C2 C3 116.59(11) 2_556 .
C4 C3 C2 117.91(11) . .
C4 C3 C13 119.43(11) . .
C2 C3 C13 122.05(11) . .
C13 O4 C14 115.32(11) . .
C3 C4 C5 122.22(11) . .
C3 C4 H4 118.9 . .
C5 C4 H4 118.9 . .
C4 C5 C6 117.92(11) . .
C4 C5 C15 119.61(11) . .
C6 C5 C15 122.45(11) . .
C15 O6 C16 115.27(10) . .
O1 C6 C1 121.02(11) . .
O1 C6 C5 117.51(11) . .
C1 C6 C5 121.36(11) . .
C12 C7 C8 118.22(11) . .
C12 C7 H7 120.9 . .
C8 C7 H7 120.9 . .
C7 C8 C9 121.75(11) . .
C7 C8 O1 120.58(11) . .
C9 C8 O1 117.50(11) . .
C10 C9 N1 123.62(11) . .
C10 C9 C8 118.96(11) . .
N1 C9 C8 117.34(11) . .
C11 C10 C9 120.17(11) . .
C11 C10 H10 119.9 . .
C9 C10 H10 119.9 . .
C10 C11 C12 118.84(11) . .
C10 C11 N2 123.98(11) . .
C12 C11 N2 117.15(11) . .
C7 C12 C11 122.02(11) . .
C7 C12 O2 120.65(11) . .
C11 C12 O2 117.09(11) . .
O3 C13 O4 123.31(12) . .
O3 C13 C3 125.26(11) . .
O4 C13 C3 111.33(11) . .
O4 C14 H14A 109.5 . .
O4 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
O4 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
O5 C15 O6 122.86(12) . .
O5 C15 C5 125.70(12) . .
O6 C15 C5 111.41(11) . .
O6 C16 H16A 109.5 . .
O6 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
O6 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O7 C17 N1 123.37(12) . .
O7 C17 C18 121.65(12) . .
N1 C17 C18 114.96(12) . .
C19 C18 C17 112.99(12) . .
C19 C18 H18A 109.0 . .
C17 C18 H18A 109.0 . .
C19 C18 H18B 109.0 . .
C17 C18 H18B 109.0 . .
H18A C18 H18B 107.8 . .
C18 C19 C20 110.55(15) . .
C18 C19 H19A 109.5 . .
C20 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
C20 C19 H19B 109.5 . .
H19A C19 H19B 108.1 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O8 C21 N2 124.20(12) . .
O8 C21 C22 121.72(12) . .
N2 C21 C22 114.06(11) . .
C21 C22 C23 110.13(12) . .
C21 C22 H22A 109.6 . .
C23 C22 H22A 109.6 . .
C21 C22 H22B 109.6 . .
C23 C22 H22B 109.6 . .
H22A C22 H22B 108.1 . .
C24 C23 C22 112.50(14) . .
C24 C23 H23A 109.1 . .
C22 C23 H23A 109.1 . .
C24 C23 H23B 109.1 . .
C22 C23 H23B 109.1 . .
H23A C23 H23B 107.8 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O1 C6 1.3827(15) .
O1 C8 1.4022(15) .
N1 C17 1.3654(18) .
N1 C9 1.3999(15) .
N1 H1A 0.868(16) .
C1 C2 1.3814(17) .
C1 C6 1.3837(18) .
C1 H1 0.9500 .
O2 C2 1.3827(15) 2_556
O2 C12 1.4010(14) .
N2 C21 1.3661(18) .
N2 C11 1.4008(16) .
N2 H2 0.878(15) .
C2 O2 1.3826(15) 2_556
C2 C3 1.3994(16) .
O3 C13 1.2105(16) .
C3 C4 1.3877(18) .
C3 C13 1.4838(18) .
O4 C13 1.3379(15) .
O4 C14 1.4478(16) .
C4 C5 1.3911(17) .
C4 H4 0.9500 .
O5 C15 1.2086(16) .
C5 C6 1.3959(17) .
C5 C15 1.4843(18) .
O6 C15 1.3309(15) .
O6 C16 1.4499(16) .
O7 C17 1.2188(16) .
C7 C12 1.3775(17) .
C7 C8 1.3828(17) .
C7 H7 0.9500 .
O8 C21 1.2244(15) .
C8 C9 1.3999(18) .
C9 C10 1.3951(17) .
C10 C11 1.3942(17) .
C10 H10 0.9500 .
C11 C12 1.3999(18) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.5134(18) .
C18 C19 1.504(2) .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 C20 1.526(2) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.5076(18) .
C22 C23 1.532(2) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.506(3) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O3 0.878(15) 2.232(15) 3.0721(18) 160.1(13) 2_556
N2 H2 O2 0.878(15) 2.238(14) 2.6773(18) 110.7(11) .
N1 H1A O5 0.868(16) 2.059(16) 2.9212(18) 172.2(14) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 O2 176.70(10) . 2_556
C6 C1 C2 C3 -0.43(18) . .
C1 C2 C3 C4 -0.23(18) . .
O2 C2 C3 C4 -177.50(10) 2_556 .
C1 C2 C3 C13 -171.25(11) . .
O2 C2 C3 C13 11.47(17) 2_556 .
C2 C3 C4 C5 0.43(18) . .
C13 C3 C4 C5 171.70(11) . .
C3 C4 C5 C6 0.03(18) . .
C3 C4 C5 C15 178.50(11) . .
C8 O1 C6 C1 41.61(15) . .
C8 O1 C6 C5 -142.12(11) . .
C2 C1 C6 O1 177.03(10) . .
C2 C1 C6 C5 0.91(18) . .
C4 C5 C6 O1 -176.96(10) . .
C15 C5 C6 O1 4.61(17) . .
C4 C5 C6 C1 -0.71(18) . .
C15 C5 C6 C1 -179.14(11) . .
C12 C7 C8 C9 -0.25(18) . .
C12 C7 C8 O1 -175.49(10) . .
C6 O1 C8 C7 -94.77(13) . .
C6 O1 C8 C9 89.79(13) . .
C17 N1 C9 C10 14.81(19) . .
C17 N1 C9 C8 -168.48(12) . .
C7 C8 C9 C10 0.60(18) . .
O1 C8 C9 C10 175.98(10) . .
C7 C8 C9 N1 -176.27(11) . .
O1 C8 C9 N1 -0.89(16) . .
N1 C9 C10 C11 174.96(11) . .
C8 C9 C10 C11 -1.70(17) . .
C9 C10 C11 C12 2.43(17) . .
C9 C10 C11 N2 -175.30(11) . .
C21 N2 C11 C10 2.6(2) . .
C21 N2 C11 C12 -175.13(12) . .
C8 C7 C12 C11 1.02(18) . .
C8 C7 C12 O2 175.23(10) . .
C10 C11 C12 C7 -2.11(18) . .
N2 C11 C12 C7 175.78(11) . .
C10 C11 C12 O2 -176.53(10) . .
N2 C11 C12 O2 1.36(16) . .
C2 O2 C12 C7 89.82(14) 2_556 .
C2 O2 C12 C11 -95.69(13) 2_556 .
C14 O4 C13 O3 1.81(18) . .
C14 O4 C13 C3 -174.67(11) . .
C4 C3 C13 O3 -143.58(13) . .
C2 C3 C13 O3 27.31(19) . .
C4 C3 C13 O4 32.82(16) . .
C2 C3 C13 O4 -156.29(11) . .
C16 O6 C15 O5 1.43(18) . .
C16 O6 C15 C5 -176.59(10) . .
C4 C5 C15 O5 -143.82(13) . .
C6 C5 C15 O5 34.58(19) . .
C4 C5 C15 O6 34.13(15) . .
C6 C5 C15 O6 -147.47(12) . .
C9 N1 C17 O7 9.4(2) . .
C9 N1 C17 C18 -171.87(12) . .
O7 C17 C18 C19 74.86(19) . .
N1 C17 C18 C19 -103.88(15) . .
C17 C18 C19 C20 -172.52(15) . .
C11 N2 C21 O8 -2.6(2) . .
C11 N2 C21 C22 175.61(12) . .
O8 C21 C22 C23 62.61(17) . .
N2 C21 C22 C23 -115.65(13) . .
C21 C22 C23 C24 62.94(17) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.000 0.500 0.000 150.4 32.6
