#------------------------------------------------------------------------------
#$Date: 2020-06-05 14:32:31 +0300 (Fri, 05 Jun 2020) $
#$Revision: 252932 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/15/73/7157384.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7157384
loop_
_publ_author_name
'Liao, Ming-Hong'
'Zhang, Meng'
'Hu, Dai-Hui'
'Zhang, Rui-Han'
'Zhao, Yan'
'Liu, Shan-Shan'
'Li, Yun-Xia'
'Xiao, Wei-Lie'
'Tang, E.'
_publ_section_title
;
 Controlling the selectivity of an intramolecular Friedel-Crafts
 alkylation with alkenes using selenium under mild conditions.
;
_journal_issue                   21
_journal_name_full               'Organic & biomolecular chemistry'
_journal_page_first              4034
_journal_page_last               4045
_journal_paper_doi               10.1039/d0ob00257g
_journal_volume                  18
_journal_year                    2020
_chemical_formula_sum            'C26 H25 F3 O4 Se'
_chemical_formula_weight         537.42
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2019-07-19 deposited with the CCDC.	2020-03-10 downloaded from the CCDC.
;
_cell_angle_alpha                114.9980(10)
_cell_angle_beta                 94.3680(10)
_cell_angle_gamma                94.2510(10)
_cell_formula_units_Z            2
_cell_length_a                   6.9173(8)
_cell_length_b                   13.9163(16)
_cell_length_c                   14.1631(16)
_cell_measurement_reflns_used    2674
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      21.76
_cell_measurement_theta_min      2.73
_cell_volume                     1223.5(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_sigmaI/netI    0.0766
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9448
_diffrn_reflns_theta_full        25.14
_diffrn_reflns_theta_max         25.14
_diffrn_reflns_theta_min         1.60
_exptl_absorpt_coefficient_mu    1.587
_exptl_absorpt_correction_T_max  0.7019
_exptl_absorpt_correction_T_min  0.6306
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.459
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             548
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.24
_refine_diff_density_max         0.750
_refine_diff_density_min         -0.760
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     310
_refine_ls_number_reflns         4325
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.999
_refine_ls_R_factor_all          0.1107
_refine_ls_R_factor_gt           0.0814
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1335P)²+7.5652P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2602
_refine_ls_wR_factor_ref         0.2805
_reflns_number_gt                2960
_reflns_number_total             4325
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d0ob00257g3.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7157384--7157385.cif.
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               7157384
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F -0.3082(15) 0.9911(7) 0.3277(10) 0.151(4) Uani 1 1 d . . .
F2 F -0.5733(14) 0.8985(10) 0.3134(12) 0.184(6) Uani 1 1 d . . .
F3 F -0.407(2) 0.8561(11) 0.1950(9) 0.184(6) Uani 1 1 d . . .
O1 O 0.2671(7) 0.5369(4) 0.4573(4) 0.0437(12) Uani 1 1 d . . .
O2 O -0.2194(7) 0.7753(4) 0.6283(4) 0.0440(13) Uani 1 1 d . . .
O3 O -0.0649(8) 0.8955(5) 0.8377(4) 0.0540(15) Uani 1 1 d . . .
O4 O 0.3009(8) 0.8768(5) 0.9032(4) 0.0567(15) Uani 1 1 d . . .
Se1 Se 0.27964(14) 0.42927(8) 0.22495(7) 0.0647(4) Uani 1 1 d . . .
C1 C 0.250(2) 0.4290(13) 0.0234(10) 0.105(4) Uani 1 1 d . . .
H1 H 0.3632 0.4772 0.0493 0.126 Uiso 1 1 calc R . .
C2 C 0.164(4) 0.3955(18) -0.0773(13) 0.140(7) Uani 1 1 d . . .
H2 H 0.2235 0.4221 -0.1195 0.168 Uiso 1 1 calc R . .
C3 C 0.001(4) 0.3273(15) -0.1196(10) 0.139(8) Uani 1 1 d . . .
H3 H -0.0494 0.3049 -0.1892 0.167 Uiso 1 1 calc R . .
C4 C -0.081(3) 0.2946(13) -0.0583(13) 0.126(6) Uani 1 1 d . . .
H4 H -0.1989 0.2509 -0.0844 0.151 Uiso 1 1 calc R . .
C5 C -0.003(3) 0.3206(12) 0.0459(10) 0.114(5) Uani 1 1 d . . .
H5 H -0.0652 0.2921 0.0861 0.137 Uiso 1 1 calc R . .
C6 C 0.1624(15) 0.3880(7) 0.0851(7) 0.057(2) Uani 1 1 d . . .
C7 C 0.0647(12) 0.4960(7) 0.3022(6) 0.050(2) Uani 1 1 d . . .
H7A H -0.0140 0.5238 0.2619 0.060 Uiso 1 1 calc R . .
H7B H -0.0182 0.4435 0.3136 0.060 Uiso 1 1 calc R . .
C8 C 0.1503(10) 0.5856(6) 0.4062(6) 0.0388(16) Uani 1 1 d . . .
H8 H 0.2332 0.6386 0.3941 0.047 Uiso 1 1 calc R . .
C9 C -0.0101(10) 0.6404(6) 0.4740(5) 0.0388(16) Uani 1 1 d . . .
H9 H -0.1091 0.5848 0.4711 0.047 Uiso 1 1 calc R . .
C10 C 0.0799(10) 0.7045(6) 0.5882(5) 0.0364(16) Uani 1 1 d . . .
C11 C 0.2642(10) 0.6936(6) 0.6227(6) 0.0422(17) Uani 1 1 d . . .
C12 C 0.3860(11) 0.6176(7) 0.5470(6) 0.050(2) Uani 1 1 d . . .
H12A H 0.4771 0.6575 0.5242 0.061 Uiso 1 1 calc R . .
H12B H 0.4611 0.5840 0.5827 0.061 Uiso 1 1 calc R . .
C13 C -0.1054(10) 0.7065(6) 0.4267(5) 0.0365(16) Uani 1 1 d . . .
C14 C -0.0118(12) 0.8032(7) 0.4348(6) 0.0480(19) Uani 1 1 d . . .
H14 H 0.1141 0.8273 0.4695 0.058 Uiso 1 1 calc R . .
C15 C -0.1023(13) 0.8626(7) 0.3926(7) 0.055(2) Uani 1 1 d . . .
H15 H -0.0365 0.9263 0.3993 0.066 Uiso 1 1 calc R . .
C16 C -0.2871(13) 0.8305(7) 0.3407(7) 0.053(2) Uani 1 1 d . . .
C17 C -0.3821(12) 0.7322(7) 0.3279(6) 0.051(2) Uani 1 1 d . . .
H17 H -0.5067 0.7082 0.2914 0.061 Uiso 1 1 calc R . .
C18 C -0.2911(11) 0.6716(7) 0.3693(6) 0.0446(18) Uani 1 1 d . . .
H18 H -0.3544 0.6060 0.3589 0.054 Uiso 1 1 calc R . .
C19 C -0.393(2) 0.8953(12) 0.2981(12) 0.095(4) Uani 1 1 d . . .
C20 C -0.0291(10) 0.7745(6) 0.6621(6) 0.0375(16) Uani 1 1 d . . .
C21 C 0.0502(10) 0.8333(6) 0.7657(6) 0.0409(17) Uani 1 1 d . . .
C22 C 0.2376(11) 0.8194(6) 0.7988(6) 0.0436(18) Uani 1 1 d . . .
C23 C 0.3446(11) 0.7501(6) 0.7266(6) 0.0426(18) Uani 1 1 d . . .
H23 H 0.4702 0.7414 0.7476 0.051 Uiso 1 1 calc R . .
C24 C 0.4807(13) 0.8538(9) 0.9406(7) 0.071(3) Uani 1 1 d . . .
H24A H 0.4725 0.7791 0.9239 0.106 Uiso 1 1 calc R . .
H24B H 0.5059 0.8948 1.0153 0.106 Uiso 1 1 calc R . .
H24C H 0.5847 0.8722 0.9079 0.106 Uiso 1 1 calc R . .
C25 C -0.0078(15) 1.0092(8) 0.8796(8) 0.065(3) Uani 1 1 d . . .
H25A H 0.1229 1.0260 0.9147 0.097 Uiso 1 1 calc R . .
H25B H -0.0953 1.0465 0.9285 0.097 Uiso 1 1 calc R . .
H25C H -0.0132 1.0305 0.8233 0.097 Uiso 1 1 calc R . .
C26 C -0.2834(12) 0.8777(7) 0.6438(7) 0.056(2) Uani 1 1 d . . .
H26A H -0.3655 0.8998 0.6991 0.085 Uiso 1 1 calc R . .
H26B H -0.3553 0.8709 0.5801 0.085 Uiso 1 1 calc R . .
H26C H -0.1716 0.9301 0.6623 0.085 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 O1 C12 109.8(6) . . ?
C20 O2 C26 117.7(6) . . ?
C21 O3 C25 114.7(7) . . ?
C22 O4 C24 116.7(6) . . ?
C6 Se1 C7 99.5(4) . . ?
C2 C1 C6 117.1(16) . . ?
C2 C1 H1 121.4 . . ?
C6 C1 H1 121.4 . . ?
C3 C2 C1 124.9(17) . . ?
C3 C2 H2 117.6 . . ?
C1 C2 H2 117.6 . . ?
C4 C3 C2 116.1(14) . . ?
C4 C3 H3 121.9 . . ?
C2 C3 H3 121.9 . . ?
C3 C4 C5 124.4(17) . . ?
C3 C4 H4 117.8 . . ?
C5 C4 H4 117.8 . . ?
C6 C5 C4 117.6(15) . . ?
C6 C5 H5 121.2 . . ?
C4 C5 H5 121.2 . . ?
C5 C6 C1 119.8(11) . . ?
C5 C6 Se1 121.4(9) . . ?
C1 C6 Se1 118.9(9) . . ?
C8 C7 Se1 108.6(5) . . ?
C8 C7 H7A 110.0 . . ?
Se1 C7 H7A 110.0 . . ?
C8 C7 H7B 110.0 . . ?
Se1 C7 H7B 110.0 . . ?
H7A C7 H7B 108.3 . . ?
O1 C8 C7 105.4(6) . . ?
O1 C8 C9 110.5(6) . . ?
C7 C8 C9 112.1(6) . . ?
O1 C8 H8 109.6 . . ?
C7 C8 H8 109.6 . . ?
C9 C8 H8 109.6 . . ?
C13 C9 C10 113.9(6) . . ?
C13 C9 C8 108.3(6) . . ?
C10 C9 C8 109.4(6) . . ?
C13 C9 H9 108.3 . . ?
C10 C9 H9 108.3 . . ?
C8 C9 H9 108.3 . . ?
C11 C10 C20 117.9(6) . . ?
C11 C10 C9 122.0(6) . . ?
C20 C10 C9 120.1(6) . . ?
C10 C11 C23 122.0(7) . . ?
C10 C11 C12 120.1(6) . . ?
C23 C11 C12 117.9(7) . . ?
O1 C12 C11 111.7(6) . . ?
O1 C12 H12A 109.3 . . ?
C11 C12 H12A 109.3 . . ?
O1 C12 H12B 109.3 . . ?
C11 C12 H12B 109.3 . . ?
H12A C12 H12B 107.9 . . ?
C18 C13 C14 116.9(7) . . ?
C18 C13 C9 120.8(7) . . ?
C14 C13 C9 122.3(6) . . ?
C15 C14 C13 121.2(7) . . ?
C15 C14 H14 119.4 . . ?
C13 C14 H14 119.4 . . ?
C16 C15 C14 121.6(8) . . ?
C16 C15 H15 119.2 . . ?
C14 C15 H15 119.2 . . ?
C15 C16 C17 118.6(8) . . ?
C15 C16 C19 122.9(10) . . ?
C17 C16 C19 118.4(10) . . ?
C18 C17 C16 120.1(8) . . ?
C18 C17 H17 120.0 . . ?
C16 C17 H17 120.0 . . ?
C17 C18 C13 121.5(8) . . ?
C17 C18 H18 119.3 . . ?
C13 C18 H18 119.3 . . ?
F2 C19 F1 109.7(13) . . ?
F2 C19 F3 101.1(13) . . ?
F1 C19 F3 102.7(14) . . ?
F2 C19 C16 114.6(12) . . ?
F1 C19 C16 114.2(12) . . ?
F3 C19 C16 113.2(12) . . ?
O2 C20 C21 122.2(6) . . ?
O2 C20 C10 116.8(6) . . ?
C21 C20 C10 120.8(6) . . ?
O3 C21 C20 119.4(6) . . ?
O3 C21 C22 120.3(6) . . ?
C20 C21 C22 119.8(7) . . ?
O4 C22 C23 124.6(7) . . ?
O4 C22 C21 116.0(7) . . ?
C23 C22 C21 119.4(7) . . ?
C22 C23 C11 119.9(7) . . ?
C22 C23 H23 120.1 . . ?
C11 C23 H23 120.1 . . ?
O4 C24 H24A 109.5 . . ?
O4 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
O4 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
O3 C25 H25A 109.5 . . ?
O3 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
O3 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O2 C26 H26A 109.5 . . ?
O2 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
O2 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C19 1.293(16) . ?
F2 C19 1.284(17) . ?
F3 C19 1.318(18) . ?
O1 C8 1.429(9) . ?
O1 C12 1.432(9) . ?
O2 C20 1.368(8) . ?
O2 C26 1.456(10) . ?
O3 C21 1.380(9) . ?
O3 C25 1.445(11) . ?
O4 C22 1.366(9) . ?
O4 C24 1.425(11) . ?
Se1 C6 1.907(9) . ?
Se1 C7 1.965(8) . ?
C1 C2 1.37(2) . ?
C1 C6 1.381(17) . ?
C1 H1 0.9300 . ?
C2 C3 1.34(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.29(3) . ?
C3 H3 0.9300 . ?
C4 C5 1.413(19) . ?
C4 H4 0.9300 . ?
C5 C6 1.344(17) . ?
C5 H5 0.9300 . ?
C7 C8 1.510(10) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.551(10) . ?
C8 H8 0.9800 . ?
C9 C13 1.508(11) . ?
C9 C10 1.531(10) . ?
C9 H9 0.9800 . ?
C10 C11 1.372(10) . ?
C10 C20 1.407(10) . ?
C11 C23 1.387(10) . ?
C11 C12 1.513(10) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C18 1.401(10) . ?
C13 C14 1.404(11) . ?
C14 C15 1.367(12) . ?
C14 H14 0.9300 . ?
C15 C16 1.367(12) . ?
C15 H15 0.9300 . ?
C16 C17 1.405(13) . ?
C16 C19 1.484(14) . ?
C17 C18 1.376(12) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C20 C21 1.385(10) . ?
C21 C22 1.400(11) . ?
C22 C23 1.383(10) . ?
C23 H23 0.9300 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 1(3) . . . . ?
C1 C2 C3 C4 2(3) . . . . ?
C2 C3 C4 C5 -4(3) . . . . ?
C3 C4 C5 C6 3(3) . . . . ?
C4 C5 C6 C1 0(2) . . . . ?
C4 C5 C6 Se1 179.8(12) . . . . ?
C2 C1 C6 C5 -2(2) . . . . ?
C2 C1 C6 Se1 178.5(12) . . . . ?
C7 Se1 C6 C5 -60.0(11) . . . . ?
C7 Se1 C6 C1 119.8(10) . . . . ?
C6 Se1 C7 C8 -148.0(6) . . . . ?
C12 O1 C8 C7 168.4(6) . . . . ?
C12 O1 C8 C9 -70.3(7) . . . . ?
Se1 C7 C8 O1 -57.9(7) . . . . ?
Se1 C7 C8 C9 -178.1(5) . . . . ?
O1 C8 C9 C13 170.1(6) . . . . ?
C7 C8 C9 C13 -72.7(8) . . . . ?
O1 C8 C9 C10 45.4(8) . . . . ?
C7 C8 C9 C10 162.5(7) . . . . ?
C13 C9 C10 C11 -133.3(8) . . . . ?
C8 C9 C10 C11 -11.9(10) . . . . ?
C13 C9 C10 C20 48.9(9) . . . . ?
C8 C9 C10 C20 170.3(7) . . . . ?
C20 C10 C11 C23 -0.9(12) . . . . ?
C9 C10 C11 C23 -178.7(7) . . . . ?
C20 C10 C11 C12 178.7(7) . . . . ?
C9 C10 C11 C12 0.9(12) . . . . ?
C8 O1 C12 C11 56.8(9) . . . . ?
C10 C11 C12 O1 -22.2(11) . . . . ?
C23 C11 C12 O1 157.4(7) . . . . ?
C10 C9 C13 C18 -133.6(7) . . . . ?
C8 C9 C13 C18 104.4(8) . . . . ?
C10 C9 C13 C14 48.4(9) . . . . ?
C8 C9 C13 C14 -73.6(8) . . . . ?
C18 C13 C14 C15 2.9(12) . . . . ?
C9 C13 C14 C15 -179.0(8) . . . . ?
C13 C14 C15 C16 -0.1(14) . . . . ?
C14 C15 C16 C17 -2.2(14) . . . . ?
C14 C15 C16 C19 177.2(11) . . . . ?
C15 C16 C17 C18 1.5(13) . . . . ?
C19 C16 C17 C18 -177.9(10) . . . . ?
C16 C17 C18 C13 1.4(12) . . . . ?
C14 C13 C18 C17 -3.6(11) . . . . ?
C9 C13 C18 C17 178.3(7) . . . . ?
C15 C16 C19 F2 -137.6(14) . . . . ?
C17 C16 C19 F2 41.8(18) . . . . ?
C15 C16 C19 F1 -9.9(19) . . . . ?
C17 C16 C19 F1 169.5(12) . . . . ?
C15 C16 C19 F3 107.2(15) . . . . ?
C17 C16 C19 F3 -73.5(16) . . . . ?
C26 O2 C20 C21 58.3(10) . . . . ?
C26 O2 C20 C10 -126.4(8) . . . . ?
C11 C10 C20 O2 -173.1(7) . . . . ?
C9 C10 C20 O2 4.7(10) . . . . ?
C11 C10 C20 C21 2.3(11) . . . . ?
C9 C10 C20 C21 -179.8(7) . . . . ?
C25 O3 C21 C20 -113.3(9) . . . . ?
C25 O3 C21 C22 74.4(10) . . . . ?
O2 C20 C21 O3 -0.4(12) . . . . ?
C10 C20 C21 O3 -175.5(7) . . . . ?
O2 C20 C21 C22 172.0(7) . . . . ?
C10 C20 C21 C22 -3.2(12) . . . . ?
C24 O4 C22 C23 -7.1(13) . . . . ?
C24 O4 C22 C21 172.5(8) . . . . ?
O3 C21 C22 O4 -4.7(12) . . . . ?
C20 C21 C22 O4 -177.0(7) . . . . ?
O3 C21 C22 C23 174.9(7) . . . . ?
C20 C21 C22 C23 2.6(12) . . . . ?
O4 C22 C23 C11 178.3(8) . . . . ?
C21 C22 C23 C11 -1.2(12) . . . . ?
C10 C11 C23 C22 0.4(13) . . . . ?
C12 C11 C23 C22 -179.2(8) . . . . ?
