#------------------------------------------------------------------------------
#$Date: 2021-07-05 21:10:52 +0300 (Mon, 05 Jul 2021) $
#$Revision: 267229 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/15/80/7158046.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7158046
loop_
_publ_author_name
'You, Di'
'Zhou, Benyu'
'Hirai, Masato'
'Gabbaï, François P'
_publ_section_title
;
 Distiboranes based on ortho-phenylene backbones as bidentate Lewis
 acids for fluoride anion chelation.
;
_journal_issue                   22
_journal_name_full               'Organic & biomolecular chemistry'
_journal_page_first              4949
_journal_page_last               4957
_journal_paper_doi               10.1039/d1ob00536g
_journal_volume                  19
_journal_year                    2021
_chemical_formula_moiety         'C32 H15 F8 O2 Sb'
_chemical_formula_sum            'C32 H15 F8 O2 Sb'
_chemical_formula_weight         705.19
_chemical_melting_point          ?
_chemical_name_common            none
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2021-03-15
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_audit_update_record
;
2021-03-17 deposited with the CCDC.	2021-04-30 downloaded from the CCDC.
;
_cell_angle_alpha                96.740(2)
_cell_angle_beta                 92.201(2)
_cell_angle_gamma                91.203(2)
_cell_formula_units_Z            2
_cell_length_a                   8.8626(12)
_cell_length_b                   11.4164(15)
_cell_length_c                   12.8227(17)
_cell_measurement_reflns_used    9953
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      29.63
_cell_measurement_theta_min      2.61
_cell_volume                     1287.0(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0195
_diffrn_reflns_av_unetI/netI     0.0250
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.978
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15233
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.500
_diffrn_reflns_theta_min         1.600
_exptl_absorpt_coefficient_mu    1.161
_exptl_absorpt_correction_T_max  0.6292
_exptl_absorpt_correction_T_min  0.3617
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.820
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             692
_exptl_crystal_preparation
'Upon standing of a mixture of octafluorophenanthra-9,10-quinone and Ph3Sb in Et2O'
_exptl_crystal_size_max          0.196
_exptl_crystal_size_mid          0.168
_exptl_crystal_size_min          0.128
_refine_diff_density_max         0.924
_refine_diff_density_min         -0.854
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         6382
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0253
_refine_ls_R_factor_gt           0.0228
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0276P)²+0.8030P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0558
_refine_ls_wR_factor_ref         0.0571
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5936
_reflns_number_total             6382
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ob00536g2.cif
_cod_data_source_block           i
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_melting_point' value 'none' was changed to '?'
-- the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7158045--7158050.cif.
;
_cod_database_code               7158046
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_max   0.866
_shelx_estimated_absorpt_t_min   0.804
_olex2_refinement_description
;
1.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.63059(2) 0.28951(2) 0.17233(2) 0.01412(4) Uani 1 1 d . . . . .
F1 F 0.43607(14) 0.14452(9) 0.46004(9) 0.0247(2) Uani 1 1 d . . . . .
F2 F 0.30669(15) 0.14528(10) 0.64413(9) 0.0289(3) Uani 1 1 d . . . . .
F3 F 0.17495(14) 0.34228(11) 0.73426(9) 0.0280(3) Uani 1 1 d . . . . .
F4 F 0.17344(13) 0.53672(10) 0.64466(9) 0.0241(2) Uani 1 1 d . . . . .
F5 F 0.06650(13) 0.63939(11) 0.51331(9) 0.0252(2) Uani 1 1 d . . . . .
F6 F 0.09164(15) 0.82944(11) 0.41725(10) 0.0319(3) Uani 1 1 d . . . . .
F7 F 0.30419(15) 0.84984(10) 0.27326(10) 0.0302(3) Uani 1 1 d . . . . .
F8 F 0.48035(13) 0.66838(10) 0.21526(9) 0.0228(2) Uani 1 1 d . . . . .
O1 O 0.52518(15) 0.25698(11) 0.30940(10) 0.0179(3) Uani 1 1 d . . . . .
O2 O 0.54580(15) 0.44892(11) 0.21975(10) 0.0167(2) Uani 1 1 d . . . . .
C1 C 0.8207(2) 0.20852(15) 0.23676(14) 0.0166(3) Uani 1 1 d . . . . .
C2 C 0.9651(2) 0.25190(16) 0.22103(15) 0.0207(4) Uani 1 1 d . . . . .
H2 H 0.9781 0.3155 0.1804 0.025 Uiso 1 1 calc R U . . .
C3 C 1.0905(2) 0.20163(18) 0.26519(17) 0.0263(4) Uani 1 1 d . . . . .
H3 H 1.1890 0.2319 0.2555 0.032 Uiso 1 1 calc R U . . .
C4 C 1.0722(2) 0.10769(19) 0.32324(18) 0.0285(4) Uani 1 1 d . . . . .
H4 H 1.1580 0.0726 0.3521 0.034 Uiso 1 1 calc R U . . .
C5 C 0.9279(2) 0.06490(17) 0.33922(17) 0.0261(4) Uani 1 1 d . . . . .
H5 H 0.9156 0.0006 0.3792 0.031 Uiso 1 1 calc R U . . .
C6 C 0.8016(2) 0.11537(16) 0.29724(16) 0.0214(4) Uani 1 1 d . . . . .
H6 H 0.7031 0.0869 0.3095 0.026 Uiso 1 1 calc R U . . .
C7 C 0.7375(2) 0.36960(16) 0.04987(14) 0.0175(3) Uani 1 1 d . . . . .
C8 C 0.8317(2) 0.29739(16) -0.01274(15) 0.0202(4) Uani 1 1 d . . . . .
H8 H 0.8478 0.2189 0.0021 0.024 Uiso 1 1 calc R U . . .
C9 C 0.9023(2) 0.33890(17) -0.09659(15) 0.0215(4) Uani 1 1 d . . . . .
H9 H 0.9666 0.2892 -0.1386 0.026 Uiso 1 1 calc R U . . .
C10 C 0.8784(2) 0.45358(17) -0.11871(14) 0.0207(4) Uani 1 1 d . . . . .
H10 H 0.9261 0.4823 -0.1761 0.025 Uiso 1 1 calc R U . . .
C11 C 0.7848(2) 0.52592(17) -0.05693(15) 0.0212(4) Uani 1 1 d . . . . .
H11 H 0.7686 0.6042 -0.0723 0.025 Uiso 1 1 calc R U . . .
C12 C 0.7140(2) 0.48491(16) 0.02768(15) 0.0186(4) Uani 1 1 d . . . . .
H12 H 0.6503 0.5350 0.0698 0.022 Uiso 1 1 calc R U . . .
C13 C 0.4660(2) 0.17917(15) 0.08331(14) 0.0162(3) Uani 1 1 d . . . . .
C14 C 0.4257(2) 0.20215(17) -0.01829(15) 0.0216(4) Uani 1 1 d . . . . .
H14 H 0.4793 0.2614 -0.0491 0.026 Uiso 1 1 calc R U . . .
C15 C 0.3074(2) 0.13885(18) -0.07486(16) 0.0253(4) Uani 1 1 d . . . . .
H15 H 0.2796 0.1554 -0.1438 0.030 Uiso 1 1 calc R U . . .
C16 C 0.2301(2) 0.05133(18) -0.03018(16) 0.0250(4) Uani 1 1 d . . . . .
H16 H 0.1484 0.0085 -0.0682 0.030 Uiso 1 1 calc R U . . .
C17 C 0.2726(3) 0.02661(18) 0.07029(16) 0.0279(4) Uani 1 1 d . . . . .
H17 H 0.2209 -0.0343 0.1001 0.033 Uiso 1 1 calc R U . . .
C18 C 0.3898(2) 0.08996(16) 0.12752(15) 0.0217(4) Uani 1 1 d . . . . .
H18 H 0.4180 0.0728 0.1962 0.026 Uiso 1 1 calc R U . . .
C19 C 0.3672(2) 0.24305(15) 0.49869(14) 0.0170(3) Uani 1 1 d . . . . .
C20 C 0.3004(2) 0.24154(16) 0.59284(15) 0.0198(4) Uani 1 1 d . . . . .
C21 C 0.2329(2) 0.34183(17) 0.63874(14) 0.0201(4) Uani 1 1 d . . . . .
C22 C 0.2292(2) 0.44156(16) 0.58840(14) 0.0175(3) Uani 1 1 d . . . . .
C23 C 0.1821(2) 0.64363(17) 0.44884(15) 0.0189(4) Uani 1 1 d . . . . .
C24 C 0.1903(2) 0.74263(17) 0.39763(16) 0.0222(4) Uani 1 1 d . . . . .
C25 C 0.2959(2) 0.75164(16) 0.32157(15) 0.0213(4) Uani 1 1 d . . . . .
C26 C 0.3847(2) 0.65787(15) 0.29307(14) 0.0169(3) Uani 1 1 d . . . . .
C27 C 0.44845(19) 0.34887(15) 0.35144(13) 0.0139(3) Uani 1 1 d . . . . .
C28 C 0.45805(19) 0.45106(15) 0.30460(13) 0.0141(3) Uani 1 1 d . . . . .
C29 C 0.37726(19) 0.55328(15) 0.34190(13) 0.0142(3) Uani 1 1 d . . . . .
C30 C 0.28131(19) 0.54894(15) 0.42929(13) 0.0146(3) Uani 1 1 d . . . . .
C31 C 0.28725(19) 0.44631(15) 0.48769(13) 0.0142(3) Uani 1 1 d . . . . .
C32 C 0.36625(19) 0.34463(15) 0.44513(13) 0.0140(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Sb1 C1 85.36(6) . . ?
O1 Sb1 C7 165.09(6) . . ?
O1 Sb1 C13 89.28(6) . . ?
O2 Sb1 O1 78.40(5) . . ?
O2 Sb1 C1 128.16(6) . . ?
O2 Sb1 C7 87.65(6) . . ?
O2 Sb1 C13 110.84(6) . . ?
C1 Sb1 C7 99.43(7) . . ?
C13 Sb1 C1 117.88(7) . . ?
C13 Sb1 C7 100.71(7) . . ?
C27 O1 Sb1 112.82(10) . . ?
C28 O2 Sb1 114.44(10) . . ?
C2 C1 Sb1 119.16(13) . . ?
C2 C1 C6 120.16(17) . . ?
C6 C1 Sb1 120.64(13) . . ?
C1 C2 H2 120.1 . . ?
C3 C2 C1 119.73(18) . . ?
C3 C2 H2 120.1 . . ?
C2 C3 H3 119.9 . . ?
C4 C3 C2 120.27(19) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 120.1 . . ?
C3 C4 C5 119.89(19) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 119.7 . . ?
C6 C5 C4 120.55(19) . . ?
C6 C5 H5 119.7 . . ?
C1 C6 H6 120.3 . . ?
C5 C6 C1 119.37(18) . . ?
C5 C6 H6 120.3 . . ?
C8 C7 Sb1 115.97(13) . . ?
C8 C7 C12 119.45(16) . . ?
C12 C7 Sb1 124.53(13) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 C7 120.77(17) . . ?
C9 C8 H8 119.6 . . ?
C8 C9 H9 120.2 . . ?
C8 C9 C10 119.67(18) . . ?
C10 C9 H9 120.2 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 119.92(17) . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 119.7 . . ?
C10 C11 C12 120.69(17) . . ?
C12 C11 H11 119.7 . . ?
C7 C12 H12 120.3 . . ?
C11 C12 C7 119.49(17) . . ?
C11 C12 H12 120.3 . . ?
C14 C13 Sb1 119.03(13) . . ?
C14 C13 C18 119.80(17) . . ?
C18 C13 Sb1 120.99(14) . . ?
C13 C14 H14 119.8 . . ?
C15 C14 C13 120.37(18) . . ?
C15 C14 H14 119.8 . . ?
C14 C15 H15 120.1 . . ?
C16 C15 C14 119.79(19) . . ?
C16 C15 H15 120.1 . . ?
C15 C16 H16 120.1 . . ?
C15 C16 C17 119.81(19) . . ?
C17 C16 H16 120.1 . . ?
C16 C17 H17 119.6 . . ?
C18 C17 C16 120.74(19) . . ?
C18 C17 H17 119.6 . . ?
C13 C18 H18 120.3 . . ?
C17 C18 C13 119.47(18) . . ?
C17 C18 H18 120.3 . . ?
F1 C19 C20 117.07(16) . . ?
F1 C19 C32 121.41(16) . . ?
C20 C19 C32 121.51(17) . . ?
F2 C20 C19 120.57(17) . . ?
F2 C20 C21 119.55(16) . . ?
C19 C20 C21 119.79(16) . . ?
F3 C21 C20 119.67(16) . . ?
F3 C21 C22 120.20(17) . . ?
C22 C21 C20 120.10(16) . . ?
F4 C22 C21 114.79(16) . . ?
F4 C22 C31 122.28(16) . . ?
C21 C22 C31 122.83(17) . . ?
F5 C23 C24 115.31(16) . . ?
F5 C23 C30 122.19(16) . . ?
C24 C23 C30 122.34(17) . . ?
F6 C24 C23 120.27(18) . . ?
F6 C24 C25 119.23(17) . . ?
C23 C24 C25 120.43(17) . . ?
F7 C25 C24 119.76(17) . . ?
F7 C25 C26 120.88(18) . . ?
C26 C25 C24 119.27(17) . . ?
F8 C26 C25 117.23(16) . . ?
F8 C26 C29 120.75(15) . . ?
C25 C26 C29 122.02(17) . . ?
O1 C27 C28 117.23(15) . . ?
O1 C27 C32 121.85(15) . . ?
C28 C27 C32 120.82(16) . . ?
O2 C28 C27 116.71(15) . . ?
O2 C28 C29 121.71(15) . . ?
C27 C28 C29 121.57(16) . . ?
C26 C29 C28 121.84(16) . . ?
C26 C29 C30 118.83(15) . . ?
C28 C29 C30 119.30(15) . . ?
C23 C30 C29 116.27(15) . . ?
C23 C30 C31 124.90(16) . . ?
C29 C30 C31 118.76(15) . . ?
C22 C31 C30 124.92(16) . . ?
C22 C31 C32 115.97(15) . . ?
C32 C31 C30 118.96(15) . . ?
C19 C32 C27 120.96(16) . . ?
C19 C32 C31 119.40(16) . . ?
C31 C32 C27 119.59(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 O1 2.0892(12) . ?
Sb1 O2 2.0197(12) . ?
Sb1 C1 2.1246(18) . ?
Sb1 C7 2.1481(17) . ?
Sb1 C13 2.1153(18) . ?
F1 C19 1.344(2) . ?
F2 C20 1.346(2) . ?
F3 C21 1.346(2) . ?
F4 C22 1.345(2) . ?
F5 C23 1.344(2) . ?
F6 C24 1.343(2) . ?
F7 C25 1.345(2) . ?
F8 C26 1.348(2) . ?
O1 C27 1.334(2) . ?
O2 C28 1.360(2) . ?
C1 C2 1.393(3) . ?
C1 C6 1.399(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.392(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.386(3) . ?
C4 H4 0.9500 . ?
C4 C5 1.390(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.389(3) . ?
C6 H6 0.9500 . ?
C7 C8 1.395(3) . ?
C7 C12 1.397(2) . ?
C8 H8 0.9500 . ?
C8 C9 1.390(3) . ?
C9 H9 0.9500 . ?
C9 C10 1.391(3) . ?
C10 H10 0.9500 . ?
C10 C11 1.387(3) . ?
C11 H11 0.9500 . ?
C11 C12 1.396(2) . ?
C12 H12 0.9500 . ?
C13 C14 1.394(3) . ?
C13 C18 1.397(2) . ?
C14 H14 0.9500 . ?
C14 C15 1.391(3) . ?
C15 H15 0.9500 . ?
C15 C16 1.390(3) . ?
C16 H16 0.9500 . ?
C16 C17 1.391(3) . ?
C17 H17 0.9500 . ?
C17 C18 1.388(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.366(2) . ?
C19 C32 1.416(2) . ?
C20 C21 1.383(3) . ?
C21 C22 1.374(3) . ?
C22 C31 1.415(2) . ?
C23 C24 1.374(3) . ?
C23 C30 1.414(2) . ?
C24 C25 1.388(3) . ?
C25 C26 1.366(3) . ?
C26 C29 1.413(2) . ?
C27 C28 1.376(2) . ?
C27 C32 1.434(2) . ?
C28 C29 1.426(2) . ?
C29 C30 1.437(2) . ?
C30 C31 1.464(2) . ?
C31 C32 1.432(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Sb1 O1 C27 C28 -4.35(19) . . . . ?
Sb1 O1 C27 C32 179.24(13) . . . . ?
Sb1 O2 C28 C27 5.00(19) . . . . ?
Sb1 O2 C28 C29 -173.68(13) . . . . ?
Sb1 C1 C2 C3 178.30(14) . . . . ?
Sb1 C1 C6 C5 -179.37(15) . . . . ?
Sb1 C7 C8 C9 177.70(15) . . . . ?
Sb1 C7 C12 C11 -177.22(14) . . . . ?
Sb1 C13 C14 C15 -173.53(15) . . . . ?
Sb1 C13 C18 C17 173.90(15) . . . . ?
F1 C19 C20 F2 1.0(3) . . . . ?
F1 C19 C20 C21 177.41(17) . . . . ?
F1 C19 C32 C27 -4.6(3) . . . . ?
F1 C19 C32 C31 178.03(15) . . . . ?
F2 C20 C21 F3 0.3(3) . . . . ?
F2 C20 C21 C22 178.35(17) . . . . ?
F3 C21 C22 F4 4.0(3) . . . . ?
F3 C21 C22 C31 -179.54(16) . . . . ?
F4 C22 C31 C30 -6.0(3) . . . . ?
F4 C22 C31 C32 169.49(16) . . . . ?
F5 C23 C24 F6 3.2(3) . . . . ?
F5 C23 C24 C25 -173.79(17) . . . . ?
F5 C23 C30 C29 166.30(16) . . . . ?
F5 C23 C30 C31 -10.6(3) . . . . ?
F6 C24 C25 F7 4.0(3) . . . . ?
F6 C24 C25 C26 -172.60(18) . . . . ?
F7 C25 C26 F8 0.2(3) . . . . ?
F7 C25 C26 C29 -179.42(17) . . . . ?
F8 C26 C29 C28 -6.4(3) . . . . ?
F8 C26 C29 C30 175.78(15) . . . . ?
O1 C27 C28 O2 -0.3(2) . . . . ?
O1 C27 C28 C29 178.39(15) . . . . ?
O1 C27 C32 C19 1.9(3) . . . . ?
O1 C27 C32 C31 179.25(16) . . . . ?
O2 C28 C29 C26 -0.3(3) . . . . ?
O2 C28 C29 C30 177.46(15) . . . . ?
C1 C2 C3 C4 1.0(3) . . . . ?
C2 C1 C6 C5 -1.5(3) . . . . ?
C2 C3 C4 C5 -1.3(3) . . . . ?
C3 C4 C5 C6 0.2(3) . . . . ?
C4 C5 C6 C1 1.2(3) . . . . ?
C6 C1 C2 C3 0.4(3) . . . . ?
C7 C8 C9 C10 -0.3(3) . . . . ?
C8 C7 C12 C11 0.2(3) . . . . ?
C8 C9 C10 C11 0.2(3) . . . . ?
C9 C10 C11 C12 0.1(3) . . . . ?
C10 C11 C12 C7 -0.2(3) . . . . ?
C12 C7 C8 C9 0.1(3) . . . . ?
C13 C14 C15 C16 -0.7(3) . . . . ?
C14 C13 C18 C17 -1.2(3) . . . . ?
C14 C15 C16 C17 -0.8(3) . . . . ?
C15 C16 C17 C18 1.3(3) . . . . ?
C16 C17 C18 C13 -0.3(3) . . . . ?
C18 C13 C14 C15 1.7(3) . . . . ?
C19 C20 C21 F3 -176.17(17) . . . . ?
C19 C20 C21 C22 1.9(3) . . . . ?
C20 C19 C32 C27 174.19(17) . . . . ?
C20 C19 C32 C31 -3.2(3) . . . . ?
C20 C21 C22 F4 -174.09(17) . . . . ?
C20 C21 C22 C31 2.4(3) . . . . ?
C21 C22 C31 C30 177.80(17) . . . . ?
C21 C22 C31 C32 -6.7(3) . . . . ?
C22 C31 C32 C19 7.0(2) . . . . ?
C22 C31 C32 C27 -170.44(16) . . . . ?
C23 C24 C25 F7 -178.98(18) . . . . ?
C23 C24 C25 C26 4.4(3) . . . . ?
C23 C30 C31 C22 -19.2(3) . . . . ?
C23 C30 C31 C32 165.44(17) . . . . ?
C24 C23 C30 C29 -8.9(3) . . . . ?
C24 C23 C30 C31 174.20(18) . . . . ?
C24 C25 C26 F8 176.77(17) . . . . ?
C24 C25 C26 C29 -2.8(3) . . . . ?
C25 C26 C29 C28 173.16(17) . . . . ?
C25 C26 C29 C30 -4.6(3) . . . . ?
C26 C29 C30 C23 10.1(2) . . . . ?
C26 C29 C30 C31 -172.78(16) . . . . ?
C27 C28 C29 C26 -178.95(17) . . . . ?
C27 C28 C29 C30 -1.2(3) . . . . ?
C28 C27 C32 C19 -174.38(17) . . . . ?
C28 C27 C32 C31 3.0(2) . . . . ?
C28 C29 C30 C23 -167.72(16) . . . . ?
C28 C29 C30 C31 9.4(2) . . . . ?
C29 C30 C31 C22 163.97(17) . . . . ?
C29 C30 C31 C32 -11.4(2) . . . . ?
C30 C23 C24 F6 178.68(17) . . . . ?
C30 C23 C24 C25 1.7(3) . . . . ?
C30 C31 C32 C19 -177.29(16) . . . . ?
C30 C31 C32 C27 5.3(2) . . . . ?
C32 C19 C20 F2 -177.86(16) . . . . ?
C32 C19 C20 C21 -1.5(3) . . . . ?
C32 C27 C28 O2 176.16(15) . . . . ?
C32 C27 C28 C29 -5.2(3) . . . . ?
