#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:26:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180339 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/08/7200881.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7200881
loop_
_publ_author_name
'Cai, Yue-Peng'
'Yu, Qiong-Yan'
'Zhou, Zheng-Yuan'
'Hu, Zuo-Jun'
'Fang, Hua-Cai'
'Wang, Ning'
'Zhan, Qing-Guang'
'Chen, Li'
'Su, Cheng-Yong'
_publ_section_title
;
 Metal-directed assembly of two 2-D 4d--4f coordination polymers based
 on elliptical triple-deck cylinders hinged by meso-double helical
 chains
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              1006
_journal_paper_doi               10.1039/b823457d
_journal_volume                  11
_journal_year                    2009
_chemical_formula_moiety         'C24 H20 Ag2 Eu N4 O10, N O3, H2 O'
_chemical_formula_sum            'C24 H22 Ag2 Eu N5 O14'
_chemical_formula_weight         972.17
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.162(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.8877(3)
_cell_length_b                   24.7375(6)
_cell_length_c                   6.77160(10)
_cell_measurement_reflns_used    3523
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.53
_cell_measurement_theta_min      2.56
_cell_volume                     2812.56(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0231
_diffrn_reflns_av_sigmaI/netI    0.0248
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            16532
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.43
_exptl_absorpt_coefficient_mu    3.664
_exptl_absorpt_correction_T_max  0.5747
_exptl_absorpt_correction_T_min  0.4493
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.296
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1880
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.002
_refine_diff_density_min         -1.052
_refine_diff_density_rms         0.080
_refine_ls_extinction_coef       0.00094(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     434
_refine_ls_number_reflns         5232
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0238
_refine_ls_R_factor_gt           0.0208
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0202P)²+3.4651P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0478
_refine_ls_wR_factor_ref         0.0489
_reflns_number_gt                4779
_reflns_number_total             5232
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b823457d.txt
_cod_data_source_block           c
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7200881
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.229718(8) 0.662958(6) 0.88333(2) 0.01857(6) Uani 1 1 d . . .
Ag1 Ag -0.271528(15) 0.770907(13) 1.00999(5) 0.04409(9) Uani 1 1 d . . .
Ag2 Ag 0.734820(16) 0.509413(13) 1.09896(5) 0.04829(9) Uani 1 1 d . . .
O1 O 0.32598(12) 0.68536(9) 0.6643(3) 0.0311(5) Uani 1 1 d . . .
O2 O 0.31345(13) 0.76996(10) 0.5536(4) 0.0414(6) Uani 1 1 d . . .
O3 O 0.13905(13) 0.73019(9) 0.9529(4) 0.0405(6) Uani 1 1 d . . .
O4 O 0.14755(12) 0.81379(9) 1.0727(3) 0.0276(5) Uani 1 1 d . . .
O5 O 0.08705(13) 0.55789(10) 0.6255(3) 0.0362(5) Uani 1 1 d . . .
O6 O 0.11534(13) 0.60810(9) 0.8975(3) 0.0318(5) Uani 1 1 d . . .
O7 O 0.33310(14) 0.60473(11) 1.0254(3) 0.0422(6) Uani 1 1 d . . .
O8 O 0.34768(14) 0.58498(10) 1.3483(3) 0.0407(6) Uani 1 1 d . . .
O9 O 0.24105(13) 0.58093(9) 0.6668(3) 0.0300(5) Uani 1 1 d D . .
H9A H 0.1939(8) 0.5715(15) 0.630(4) 0.045 Uiso 1 1 d D . .
H9B H 0.2725(14) 0.5805(15) 0.579(4) 0.045 Uiso 1 1 d D . .
O10 O 0.21542(16) 0.64841(12) 1.2339(3) 0.0427(6) Uani 1 1 d D . .
H10A H 0.2544(17) 0.6306(15) 1.287(5) 0.064 Uiso 1 1 d D . .
H10B H 0.191(2) 0.6672(15) 1.310(4) 0.064 Uiso 1 1 d D . .
O11 O 0.69999(18) 0.54860(16) 0.6754(5) 0.0729(10) Uani 1 1 d . . .
O12 O 0.7412(3) 0.62969(16) 0.7004(6) 0.0868(11) Uani 1 1 d . . .
O13 O 0.7588(2) 0.58357(18) 0.4419(5) 0.0896(13) Uani 1 1 d . . .
O1W O 0.7287(2) 0.65697(12) 0.0966(6) 0.0688(9) Uani 1 1 d D . .
H1WA H 0.728(4) 0.6340(15) 0.187(5) 0.103 Uiso 1 1 d D . .
H1WB H 0.727(4) 0.6453(18) -0.020(3) 0.103 Uiso 1 1 d D . .
N1 N 0.60129(15) 0.72813(11) 0.5180(4) 0.0314(6) Uani 1 1 d . . .
N2 N -0.14445(15) 0.77192(12) 1.0001(4) 0.0329(6) Uani 1 1 d . . .
N3 N -0.14893(15) 0.52864(11) 1.0013(4) 0.0311(6) Uani 1 1 d . . .
N4 N 0.61206(15) 0.53663(11) 1.1252(4) 0.0322(6) Uani 1 1 d . . .
N5 N 0.73260(19) 0.58636(17) 0.6031(6) 0.0534(9) Uani 1 1 d . . .
C1 C 0.35140(17) 0.72763(12) 0.5918(4) 0.0235(6) Uani 1 1 d . . .
C2 C 0.43882(16) 0.72752(12) 0.5565(4) 0.0218(6) Uani 1 1 d . . .
C3 C 0.47950(18) 0.77555(12) 0.5430(4) 0.0249(6) Uani 1 1 d . . .
H3 H 0.4528 0.8084 0.5455 0.030 Uiso 1 1 calc R . .
C4 C 0.56029(19) 0.77442(13) 0.5258(5) 0.0301(7) Uani 1 1 d . . .
H4 H 0.5873 0.8070 0.5193 0.036 Uiso 1 1 calc R . .
C5 C 0.56084(19) 0.68162(14) 0.5251(5) 0.0326(7) Uani 1 1 d . . .
H5 H 0.5882 0.6492 0.5158 0.039 Uiso 1 1 calc R . .
C6 C 0.48081(18) 0.67967(13) 0.5456(5) 0.0267(7) Uani 1 1 d . . .
H6 H 0.4551 0.6466 0.5522 0.032 Uiso 1 1 calc R . .
C7 C 0.11001(17) 0.77231(12) 1.0144(4) 0.0211(6) Uani 1 1 d . . .
C8 C 0.02025(16) 0.77282(12) 1.0084(4) 0.0197(6) Uani 1 1 d . . .
C9 C -0.02186(18) 0.82057(12) 1.0106(4) 0.0257(6) Uani 1 1 d . . .
H9 H 0.0045 0.8536 1.0156 0.031 Uiso 1 1 calc R . .
C10 C -0.10376(18) 0.81860(13) 1.0054(5) 0.0314(7) Uani 1 1 d . . .
H10 H -0.1319 0.8509 1.0056 0.038 Uiso 1 1 calc R . .
C11 C -0.10309(19) 0.72551(13) 0.9972(5) 0.0318(7) Uani 1 1 d . . .
H11 H -0.1306 0.6929 0.9936 0.038 Uiso 1 1 calc R . .
C12 C -0.02150(18) 0.72462(12) 0.9994(4) 0.0263(6) Uani 1 1 d . . .
H12 H 0.0053 0.6919 0.9949 0.032 Uiso 1 1 calc R . .
C13 C 0.07152(18) 0.57691(12) 0.7861(4) 0.0254(6) Uani 1 1 d . . .
C14 C -0.00737(18) 0.56155(12) 0.8596(4) 0.0250(6) Uani 1 1 d . . .
C15 C -0.06142(18) 0.52930(13) 0.7459(5) 0.0301(7) Uani 1 1 d . . .
H15 H -0.0515 0.5184 0.6195 0.036 Uiso 1 1 calc R . .
C16 C -0.13011(19) 0.51347(14) 0.8221(5) 0.0338(7) Uani 1 1 d . . .
H16 H -0.1653 0.4911 0.7452 0.041 Uiso 1 1 calc R . .
C17 C -0.09630(19) 0.56010(13) 1.1104(5) 0.0317(7) Uani 1 1 d . . .
H17 H -0.1081 0.5710 1.2353 0.038 Uiso 1 1 calc R . .
C18 C -0.02577(19) 0.57698(12) 1.0464(5) 0.0283(7) Uani 1 1 d . . .
H18 H 0.0092 0.5985 1.1274 0.034 Uiso 1 1 calc R . .
C19 C 0.37206(18) 0.58835(12) 1.1837(5) 0.0270(7) Uani 1 1 d . . .
C20 C 0.45719(18) 0.57160(12) 1.1646(4) 0.0252(6) Uani 1 1 d . . .
C21 C 0.48930(19) 0.57680(13) 0.9853(5) 0.0306(7) Uani 1 1 d . . .
H21 H 0.4595 0.5918 0.8753 0.037 Uiso 1 1 calc R . .
C22 C 0.5664(2) 0.55922(14) 0.9731(5) 0.0343(7) Uani 1 1 d . . .
H22 H 0.5877 0.5633 0.8529 0.041 Uiso 1 1 calc R . .
C23 C 0.58043(19) 0.53243(14) 1.2987(5) 0.0331(7) Uani 1 1 d . . .
H23 H 0.6110 0.5170 1.4065 0.040 Uiso 1 1 calc R . .
C24 C 0.50479(19) 0.54998(13) 1.3233(5) 0.0299(7) Uani 1 1 d . . .
H24 H 0.4858 0.5473 1.4469 0.036 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O6 81.10(8) . . ?
O3 Eu1 O1 117.70(8) . . ?
O6 Eu1 O1 140.55(8) . . ?
O3 Eu1 O7 144.47(9) . . ?
O6 Eu1 O7 101.67(9) . . ?
O1 Eu1 O7 82.68(8) . . ?
O3 Eu1 O2 77.06(8) . 4_576 ?
O6 Eu1 O2 144.97(8) . 4_576 ?
O1 Eu1 O2 74.41(8) . 4_576 ?
O7 Eu1 O2 81.69(9) . 4_576 ?
O3 Eu1 O10 76.93(9) . . ?
O6 Eu1 O10 73.14(9) . . ?
O1 Eu1 O10 141.86(8) . . ?
O7 Eu1 O10 70.30(8) . . ?
O2 Eu1 O10 75.44(9) 4_576 . ?
O3 Eu1 O4 71.64(8) . 4_575 ?
O6 Eu1 O4 77.36(7) . 4_575 ?
O1 Eu1 O4 76.88(7) . 4_575 ?
O7 Eu1 O4 143.82(7) . 4_575 ?
O2 Eu1 O4 119.96(8) 4_576 4_575 ?
O10 Eu1 O4 139.56(8) . 4_575 ?
O3 Eu1 O9 141.25(8) . . ?
O6 Eu1 O9 71.10(7) . . ?
O1 Eu1 O9 74.07(7) . . ?
O7 Eu1 O9 69.55(8) . . ?
O2 Eu1 O9 139.43(7) 4_576 . ?
O10 Eu1 O9 117.96(8) . . ?
O4 Eu1 O9 76.24(7) 4_575 . ?
N2 Ag1 N1 178.66(11) . 4_476 ?
N3 Ag2 N4 147.04(10) 1_655 . ?
C1 O1 Eu1 136.50(19) . . ?
C1 O2 Eu1 161.9(2) . 4_575 ?
C7 O3 Eu1 162.3(2) . . ?
C7 O4 Eu1 133.12(19) . 4_576 ?
C13 O6 Eu1 138.94(19) . . ?
C19 O7 Eu1 145.9(2) . . ?
Eu1 O9 H9A 105(2) . . ?
Eu1 O9 H9B 121(2) . . ?
H9A O9 H9B 116.1(15) . . ?
Eu1 O10 H10A 110(3) . . ?
Eu1 O10 H10B 129(3) . . ?
H10A O10 H10B 116.5(15) . . ?
H1WA O1W H1WB 116.9(16) . . ?
C5 N1 C4 117.6(3) . . ?
C5 N1 Ag1 121.6(2) . 4_675 ?
C4 N1 Ag1 120.8(2) . 4_675 ?
C10 N2 C11 118.0(3) . . ?
C10 N2 Ag1 121.2(2) . . ?
C11 N2 Ag1 120.7(2) . . ?
C16 N3 C17 116.9(3) . . ?
C16 N3 Ag2 121.3(2) . 1_455 ?
C17 N3 Ag2 121.5(2) . 1_455 ?
C22 N4 C23 117.0(3) . . ?
C22 N4 Ag2 122.2(2) . . ?
C23 N4 Ag2 120.8(2) . . ?
O11 N5 O13 122.7(5) . . ?
O11 N5 O12 118.4(4) . . ?
O13 N5 O12 118.9(4) . . ?
O2 C1 O1 126.6(3) . . ?
O2 C1 C2 117.2(3) . . ?
O1 C1 C2 116.1(3) . . ?
C3 C2 C6 118.1(3) . . ?
C3 C2 C1 120.5(3) . . ?
C6 C2 C1 121.4(3) . . ?
C2 C3 C4 119.4(3) . . ?
C2 C3 H3 120.3 . . ?
C4 C3 H3 120.3 . . ?
N1 C4 C3 122.6(3) . . ?
N1 C4 H4 118.7 . . ?
C3 C4 H4 118.7 . . ?
N1 C5 C6 122.9(3) . . ?
N1 C5 H5 118.5 . . ?
C6 C5 H5 118.5 . . ?
C5 C6 C2 119.3(3) . . ?
C5 C6 H6 120.3 . . ?
C2 C6 H6 120.3 . . ?
O3 C7 O4 126.2(3) . . ?
O3 C7 C8 115.4(3) . . ?
O4 C7 C8 118.4(2) . . ?
C9 C8 C12 118.5(3) . . ?
C9 C8 C7 121.6(3) . . ?
C12 C8 C7 119.9(3) . . ?
C8 C9 C10 119.1(3) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
N2 C10 C9 122.7(3) . . ?
N2 C10 H10 118.7 . . ?
C9 C10 H10 118.7 . . ?
N2 C11 C12 122.3(3) . . ?
N2 C11 H11 118.9 . . ?
C12 C11 H11 118.9 . . ?
C11 C12 C8 119.4(3) . . ?
C11 C12 H12 120.3 . . ?
C8 C12 H12 120.3 . . ?
O5 C13 O6 126.2(3) . . ?
O5 C13 C14 117.9(3) . . ?
O6 C13 C14 115.8(3) . . ?
C15 C14 C18 117.8(3) . . ?
C15 C14 C13 120.8(3) . . ?
C18 C14 C13 121.3(3) . . ?
C16 C15 C14 119.2(3) . . ?
C16 C15 H15 120.4 . . ?
C14 C15 H15 120.4 . . ?
N3 C16 C15 123.4(3) . . ?
N3 C16 H16 118.3 . . ?
C15 C16 H16 118.3 . . ?
N3 C17 C18 123.2(3) . . ?
N3 C17 H17 118.4 . . ?
C18 C17 H17 118.4 . . ?
C17 C18 C14 119.3(3) . . ?
C17 C18 H18 120.3 . . ?
C14 C18 H18 120.3 . . ?
O8 C19 O7 126.6(3) . . ?
O8 C19 C20 118.1(3) . . ?
O7 C19 C20 115.4(3) . . ?
C24 C20 C21 117.9(3) . . ?
C24 C20 C19 121.3(3) . . ?
C21 C20 C19 120.8(3) . . ?
C22 C21 C20 118.8(3) . . ?
C22 C21 H21 120.6 . . ?
C20 C21 H21 120.6 . . ?
N4 C22 C21 123.5(3) . . ?
N4 C22 H22 118.2 . . ?
C21 C22 H22 118.2 . . ?
N4 C23 C24 122.8(3) . . ?
N4 C23 H23 118.6 . . ?
C24 C23 H23 118.6 . . ?
C23 C24 C20 119.9(3) . . ?
C23 C24 H24 120.0 . . ?
C20 C24 H24 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.342(2) . ?
Eu1 O6 2.371(2) . ?
Eu1 O1 2.381(2) . ?
Eu1 O7 2.385(2) . ?
Eu1 O2 2.394(2) 4_576 ?
Eu1 O10 2.439(2) . ?
Eu1 O4 2.461(2) 4_575 ?
Eu1 O9 2.523(2) . ?
Ag1 N2 2.154(3) . ?
Ag1 N1 2.154(2) 4_476 ?
Ag2 N3 2.190(3) 1_655 ?
Ag2 N4 2.205(3) . ?
O1 C1 1.251(4) . ?
O2 C1 1.240(4) . ?
O2 Eu1 2.394(2) 4_575 ?
O3 C7 1.242(4) . ?
O4 C7 1.248(4) . ?
O4 Eu1 2.461(2) 4_576 ?
O5 C13 1.238(4) . ?
O6 C13 1.262(4) . ?
O7 C19 1.263(4) . ?
O8 C19 1.232(4) . ?
O9 H9A 0.841(10) . ?
O9 H9B 0.840(10) . ?
O10 H10A 0.839(10) . ?
O10 H10B 0.839(10) . ?
O11 N5 1.214(4) . ?
O12 N5 1.258(5) . ?
O13 N5 1.223(5) . ?
O1W H1WA 0.835(10) . ?
O1W H1WB 0.839(10) . ?
N1 C5 1.341(4) . ?
N1 C4 1.342(4) . ?
N1 Ag1 2.154(2) 4_675 ?
N2 C10 1.342(4) . ?
N2 C11 1.345(4) . ?
N3 C16 1.341(4) . ?
N3 C17 1.342(4) . ?
N3 Ag2 2.190(2) 1_455 ?
N4 C22 1.340(4) . ?
N4 C23 1.346(4) . ?
C1 C2 1.521(4) . ?
C2 C3 1.380(4) . ?
C2 C6 1.386(4) . ?
C3 C4 1.382(4) . ?
C3 H3 0.9300 . ?
C4 H4 0.9300 . ?
C5 C6 1.374(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.512(4) . ?
C8 C9 1.380(4) . ?
C8 C12 1.383(4) . ?
C9 C10 1.381(4) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.377(4) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.520(4) . ?
C14 C15 1.383(4) . ?
C14 C18 1.388(4) . ?
C15 C16 1.376(4) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 C18 1.375(4) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.515(4) . ?
C20 C24 1.379(4) . ?
C20 C21 1.388(4) . ?
C21 C22 1.384(5) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.376(4) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9A O5 0.841(10) 1.832(11) 2.648(3) 163(3) .
O9 H9B O8 0.840(10) 2.117(11) 2.956(3) 176(4) 1_554
O10 H10A O8 0.839(10) 1.947(11) 2.771(3) 167(3) .
O10 H10B O4 0.839(10) 2.05(2) 2.831(3) 155(3) 4_576
O1W H1WA O13 0.835(10) 2.147(19) 2.961(5) 165(6) .
O1W H1WB O12 0.839(10) 1.971(15) 2.797(6) 168(6) 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Eu1 O1 C1 13.6(3) . . . . ?
O6 Eu1 O1 C1 124.8(3) . . . . ?
O7 Eu1 O1 C1 -135.7(3) . . . . ?
O2 Eu1 O1 C1 -52.3(3) 4_576 . . . ?
O10 Eu1 O1 C1 -91.2(3) . . . . ?
O4 Eu1 O1 C1 74.4(3) 4_575 . . . ?
O9 Eu1 O1 C1 153.6(3) . . . . ?
O6 Eu1 O3 C7 150.7(8) . . . . ?
O1 Eu1 O3 C7 -66.1(8) . . . . ?
O7 Eu1 O3 C7 53.1(8) . . . . ?
O2 Eu1 O3 C7 -1.7(7) 4_576 . . . ?
O10 Eu1 O3 C7 76.1(8) . . . . ?
O4 Eu1 O3 C7 -129.7(8) 4_575 . . . ?
O9 Eu1 O3 C7 -165.2(7) . . . . ?
O3 Eu1 O6 C13 119.2(3) . . . . ?
O1 Eu1 O6 C13 -4.2(4) . . . . ?
O7 Eu1 O6 C13 -96.8(3) . . . . ?
O2 Eu1 O6 C13 171.0(3) 4_576 . . . ?
O10 Eu1 O6 C13 -161.8(3) . . . . ?
O4 Eu1 O6 C13 46.2(3) 4_575 . . . ?
O9 Eu1 O6 C13 -33.4(3) . . . . ?
O3 Eu1 O7 C19 4.4(5) . . . . ?
O6 Eu1 O7 C19 -86.5(4) . . . . ?
O1 Eu1 O7 C19 133.2(4) . . . . ?
O2 Eu1 O7 C19 58.0(4) 4_576 . . . ?
O10 Eu1 O7 C19 -19.4(4) . . . . ?
O4 Eu1 O7 C19 -171.0(4) 4_575 . . . ?
O9 Eu1 O7 C19 -151.1(4) . . . . ?
N1 Ag1 N2 C10 17(5) 4_476 . . . ?
N1 Ag1 N2 C11 -166(4) 4_476 . . . ?
N3 Ag2 N4 C22 47.6(4) 1_655 . . . ?
N3 Ag2 N4 C23 -130.5(3) 1_655 . . . ?
Eu1 O2 C1 O1 -88.1(7) 4_575 . . . ?
Eu1 O2 C1 C2 95.0(7) 4_575 . . . ?
Eu1 O1 C1 O2 -30.1(5) . . . . ?
Eu1 O1 C1 C2 146.9(2) . . . . ?
O2 C1 C2 C3 19.4(4) . . . . ?
O1 C1 C2 C3 -157.8(3) . . . . ?
O2 C1 C2 C6 -163.4(3) . . . . ?
O1 C1 C2 C6 19.3(4) . . . . ?
C6 C2 C3 C4 -2.1(4) . . . . ?
C1 C2 C3 C4 175.2(3) . . . . ?
C5 N1 C4 C3 0.8(5) . . . . ?
Ag1 N1 C4 C3 -176.1(2) 4_675 . . . ?
C2 C3 C4 N1 1.2(5) . . . . ?
C4 N1 C5 C6 -2.0(5) . . . . ?
Ag1 N1 C5 C6 174.9(2) 4_675 . . . ?
N1 C5 C6 C2 1.1(5) . . . . ?
C3 C2 C6 C5 1.0(4) . . . . ?
C1 C2 C6 C5 -176.2(3) . . . . ?
Eu1 O3 C7 O4 15.4(10) . . . . ?
Eu1 O3 C7 C8 -167.2(6) . . . . ?
Eu1 O4 C7 O3 -77.5(4) 4_576 . . . ?
Eu1 O4 C7 C8 105.1(3) 4_576 . . . ?
O3 C7 C8 C9 -159.2(3) . . . . ?
O4 C7 C8 C9 18.4(4) . . . . ?
O3 C7 C8 C12 20.4(4) . . . . ?
O4 C7 C8 C12 -161.9(3) . . . . ?
C12 C8 C9 C10 0.5(4) . . . . ?
C7 C8 C9 C10 -179.8(3) . . . . ?
C11 N2 C10 C9 -0.9(5) . . . . ?
Ag1 N2 C10 C9 176.3(2) . . . . ?
C8 C9 C10 N2 0.7(5) . . . . ?
C10 N2 C11 C12 0.0(5) . . . . ?
Ag1 N2 C11 C12 -177.2(2) . . . . ?
N2 C11 C12 C8 1.2(5) . . . . ?
C9 C8 C12 C11 -1.4(4) . . . . ?
C7 C8 C12 C11 179.0(3) . . . . ?
Eu1 O6 C13 O5 14.0(5) . . . . ?
Eu1 O6 C13 C14 -166.3(2) . . . . ?
O5 C13 C14 C15 -2.9(4) . . . . ?
O6 C13 C14 C15 177.5(3) . . . . ?
O5 C13 C14 C18 173.8(3) . . . . ?
O6 C13 C14 C18 -5.9(4) . . . . ?
C18 C14 C15 C16 -0.7(5) . . . . ?
C13 C14 C15 C16 176.1(3) . . . . ?
C17 N3 C16 C15 -1.2(5) . . . . ?
Ag2 N3 C16 C15 173.0(3) 1_455 . . . ?
C14 C15 C16 N3 1.5(5) . . . . ?
C16 N3 C17 C18 0.2(5) . . . . ?
Ag2 N3 C17 C18 -174.1(2) 1_455 . . . ?
N3 C17 C18 C14 0.6(5) . . . . ?
C15 C14 C18 C17 -0.3(5) . . . . ?
C13 C14 C18 C17 -177.1(3) . . . . ?
Eu1 O7 C19 O8 30.3(6) . . . . ?
Eu1 O7 C19 C20 -149.5(3) . . . . ?
O8 C19 C20 C24 4.0(5) . . . . ?
O7 C19 C20 C24 -176.1(3) . . . . ?
O8 C19 C20 C21 -177.0(3) . . . . ?
O7 C19 C20 C21 2.8(4) . . . . ?
C24 C20 C21 C22 1.2(5) . . . . ?
C19 C20 C21 C22 -177.8(3) . . . . ?
C23 N4 C22 C21 -1.6(5) . . . . ?
Ag2 N4 C22 C21 -179.8(3) . . . . ?
C20 C21 C22 N4 0.9(5) . . . . ?
C22 N4 C23 C24 0.2(5) . . . . ?
Ag2 N4 C23 C24 178.5(2) . . . . ?
N4 C23 C24 C20 1.9(5) . . . . ?
C21 C20 C24 C23 -2.5(5) . . . . ?
C19 C20 C24 C23 176.5(3) . . . . ?
