#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:26:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180339 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/08/7200883.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7200883
loop_
_publ_author_name
'Cai, Yue-Peng'
'Yu, Qiong-Yan'
'Zhou, Zheng-Yuan'
'Hu, Zuo-Jun'
'Fang, Hua-Cai'
'Wang, Ning'
'Zhan, Qing-Guang'
'Chen, Li'
'Su, Cheng-Yong'
_publ_section_title
;
 Metal-directed assembly of two 2-D 4d--4f coordination polymers based
 on elliptical triple-deck cylinders hinged by meso-double helical
 chains
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              1006
_journal_paper_doi               10.1039/b823457d
_journal_volume                  11
_journal_year                    2009
_chemical_formula_moiety         'C48 H52 Ag4 Eu2 N8 O26, 2(N O3), 4(H2 O)'
_chemical_formula_sum            'C48 H60 Ag4 Eu2 N10 O36'
_chemical_formula_weight         2088.48
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.295(16)
_cell_angle_beta                 92.252(15)
_cell_angle_gamma                100.496(10)
_cell_formula_units_Z            1
_cell_length_a                   7.5268(8)
_cell_length_b                   13.047(3)
_cell_length_c                   17.351(4)
_cell_measurement_reflns_used    3258
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.78
_cell_measurement_theta_min      2.13
_cell_volume                     1658.4(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omga scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0234
_diffrn_reflns_av_sigmaI/netI    0.0391
_diffrn_reflns_limit_h_max       1
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            9298
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         1.60
_exptl_absorpt_coefficient_mu    3.126
_exptl_absorpt_correction_T_max  0.6997
_exptl_absorpt_correction_T_min  0.5147
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.093
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1020
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.452
_refine_diff_density_min         -1.364
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     493
_refine_ls_number_reflns         7569
_refine_ls_number_restraints     21
_refine_ls_restrained_S_all      0.974
_refine_ls_R_factor_all          0.0435
_refine_ls_R_factor_gt           0.0337
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0584P)²+4.4590P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0900
_refine_ls_wR_factor_ref         0.1039
_reflns_number_gt                6551
_reflns_number_total             7569
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b823457d.txt
_cod_data_source_block           compound_3b
_cod_original_cell_volume        1658.5(5)
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7200883
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.87385(3) 0.795961(15) 0.480158(11) 0.02467(7) Uani 1 1 d . . .
Ag1 Ag 1.20819(7) 0.50612(5) 0.03724(3) 0.06045(14) Uani 1 1 d . . .
Ag2 Ag 1.22848(8) 1.05914(4) 0.02509(3) 0.06101(15) Uani 1 1 d . . .
C1 C 0.9227(6) 0.5514(3) 0.3824(3) 0.0323(9) Uani 1 1 d . . .
C2 C 1.0001(6) 0.5402(3) 0.3033(2) 0.0296(9) Uani 1 1 d . . .
C3 C 1.0740(8) 0.6272(4) 0.2691(3) 0.0422(11) Uani 1 1 d . . .
H3 H 1.0832 0.6946 0.2958 0.051 Uiso 1 1 calc R . .
C4 C 1.1332(8) 0.6134(5) 0.1957(3) 0.0483(13) Uani 1 1 d . . .
H4 H 1.1828 0.6729 0.1738 0.058 Uiso 1 1 calc R . .
C5 C 1.0568(8) 0.4356(4) 0.1873(3) 0.0423(11) Uani 1 1 d . . .
H5 H 1.0519 0.3691 0.1595 0.051 Uiso 1 1 calc R . .
C6 C 0.9941(7) 0.4420(4) 0.2613(3) 0.0372(10) Uani 1 1 d . . .
H6 H 0.9486 0.3812 0.2825 0.045 Uiso 1 1 calc R . .
C7 C 1.5418(6) 0.5520(4) -0.2971(3) 0.0340(9) Uani 1 1 d . . .
C8 C 1.4652(6) 0.5417(4) -0.2172(3) 0.0341(9) Uani 1 1 d . . .
C9 C 1.4626(8) 0.6295(5) -0.1638(3) 0.0496(13) Uani 1 1 d . . .
H9 H 1.5090 0.6964 -0.1755 0.059 Uiso 1 1 calc R . .
C10 C 1.3915(9) 0.6173(5) -0.0934(4) 0.0580(16) Uani 1 1 d . . .
H10 H 1.3892 0.6773 -0.0585 0.070 Uiso 1 1 calc R . .
C11 C 1.3248(9) 0.4384(5) -0.1246(4) 0.0546(15) Uani 1 1 d . . .
H11 H 1.2757 0.3723 -0.1120 0.066 Uiso 1 1 calc R . .
C12 C 1.3944(8) 0.4449(4) -0.1965(3) 0.0470(13) Uani 1 1 d . . .
H12 H 1.3934 0.3840 -0.2309 0.056 Uiso 1 1 calc R . .
C13 C 0.9855(6) 0.9958(3) 0.3690(2) 0.0272(8) Uani 1 1 d . . .
C14 C 1.0383(6) 1.0126(3) 0.2879(2) 0.0260(8) Uani 1 1 d . . .
C15 C 1.0933(7) 1.1129(4) 0.2683(3) 0.0373(10) Uani 1 1 d . . .
H15 H 1.0961 1.1721 0.3046 0.045 Uiso 1 1 calc R . .
C16 C 1.1437(8) 1.1225(4) 0.1936(3) 0.0453(12) Uani 1 1 d . . .
H16 H 1.1793 1.1897 0.1802 0.054 Uiso 1 1 calc R . .
C17 C 1.0916(8) 0.9434(4) 0.1591(3) 0.0445(12) Uani 1 1 d . . .
H17 H 1.0926 0.8852 0.1222 0.053 Uiso 1 1 calc R . .
C18 C 1.0369(7) 0.9274(4) 0.2317(3) 0.0365(10) Uani 1 1 d . . .
H18 H 0.9988 0.8594 0.2431 0.044 Uiso 1 1 calc R . .
C19 C 1.5440(6) 1.0541(4) -0.3159(3) 0.0333(9) Uani 1 1 d . . .
C20 C 1.4738(6) 1.0553(4) -0.2344(3) 0.0336(9) Uani 1 1 d . . .
C21 C 1.4734(9) 1.1488(4) -0.1878(3) 0.0505(14) Uani 1 1 d . . .
H21 H 1.5161 1.2124 -0.2059 0.061 Uiso 1 1 calc R . .
C22 C 1.4097(9) 1.1484(5) -0.1141(3) 0.0563(15) Uani 1 1 d . . .
H22 H 1.4114 1.2126 -0.0835 0.068 Uiso 1 1 calc R . .
C23 C 1.3456(9) 0.9694(5) -0.1300(3) 0.0518(14) Uani 1 1 d . . .
H23 H 1.3020 0.9068 -0.1107 0.062 Uiso 1 1 calc R . .
C24 C 1.4064(9) 0.9638(4) -0.2037(3) 0.0485(13) Uani 1 1 d . . .
H24 H 1.4025 0.8985 -0.2331 0.058 Uiso 1 1 calc R . .
N1 N 1.1237(6) 0.5189(4) 0.1537(3) 0.0444(10) Uani 1 1 d . . .
N2 N 1.3247(7) 0.5227(4) -0.0722(3) 0.0497(11) Uani 1 1 d . . .
N3 N 1.1438(7) 1.0395(4) 0.1394(2) 0.0443(10) Uani 1 1 d . . .
N4 N 1.3459(7) 1.0599(4) -0.0849(3) 0.0488(11) Uani 1 1 d . . .
N5 N 1.0139(9) 0.2529(4) 0.0077(3) 0.0537(13) Uani 1 1 d . . .
O1 O 0.8975(6) 0.6410(3) 0.4079(2) 0.0463(9) Uani 1 1 d . . .
O2 O 0.8876(7) 0.4738(3) 0.4152(2) 0.0588(12) Uani 1 1 d . . .
O3 O 1.5468(6) 0.4689(3) -0.3395(2) 0.0490(9) Uani 1 1 d . . .
O4 O 1.5939(6) 0.6433(3) -0.3112(2) 0.0484(9) Uani 1 1 d . . .
O5 O 0.9431(5) 0.9029(2) 0.38188(19) 0.0397(8) Uani 1 1 d . . .
O6 O 0.9875(5) 1.0752(3) 0.41756(19) 0.0400(8) Uani 1 1 d . . .
O7 O 1.5224(6) 0.9681(3) -0.3578(2) 0.0560(11) Uani 1 1 d . . .
O8 O 1.6190(5) 1.1408(3) -0.3329(2) 0.0414(8) Uani 1 1 d . . .
O9 O 0.9228(9) 0.1734(4) 0.0249(3) 0.0919(19) Uani 1 1 d . . .
O10 O 0.9512(12) 0.3137(5) -0.0271(4) 0.111(2) Uani 1 1 d . . .
O11 O 1.1807(9) 0.2730(5) 0.0261(4) 0.0920(18) Uani 1 1 d . . .
O12 O 0.6212(5) 0.7395(3) 0.3821(2) 0.0411(8) Uani 1 1 d D . .
H12A H 0.544(6) 0.776(3) 0.370(4) 0.062 Uiso 1 1 d D . .
H12B H 0.575(7) 0.6740(16) 0.370(4) 0.062 Uiso 1 1 d D . .
O13 O 1.2004(5) 0.8107(3) 0.4615(2) 0.0449(9) Uani 1 1 d D . .
H13A H 1.260(8) 0.831(5) 0.424(3) 0.067 Uiso 1 1 d D . .
H13B H 1.244(8) 0.763(4) 0.480(3) 0.067 Uiso 1 1 d D . .
O14 O 0.6746(5) 0.9272(3) 0.5009(2) 0.0439(8) Uani 1 1 d D . .
H14A H 0.679(9) 0.974(4) 0.471(3) 0.066 Uiso 1 1 d D . .
H14B H 0.605(8) 0.936(5) 0.537(3) 0.066 Uiso 1 1 d D . .
O15 O 0.6369(5) 0.7083(3) 0.5483(2) 0.0454(9) Uani 1 1 d D . .
H15A H 0.542(6) 0.676(5) 0.520(3) 0.068 Uiso 1 1 d D . .
H15B H 0.634(8) 0.683(5) 0.592(2) 0.068 Uiso 1 1 d D . .
O16 O 1.0007(5) 0.7092(3) 0.5782(2) 0.0378(7) Uani 1 1 d D . .
H16A H 1.100(5) 0.737(4) 0.603(3) 0.057 Uiso 1 1 d D . .
H16B H 0.992(8) 0.6418(15) 0.572(4) 0.057 Uiso 1 1 d D . .
O1W O 0.6775(6) 0.2288(3) 0.3410(3) 0.0550(10) Uani 1 1 d D . .
H1WA H 0.614(8) 0.276(4) 0.335(5) 0.082 Uiso 1 1 d D . .
H1WB H 0.608(7) 0.173(3) 0.350(5) 0.082 Uiso 1 1 d D . .
O2W O 0.3177(5) 0.6100(3) 0.4736(2) 0.0445(8) Uani 1 1 d D . .
H2WA H 0.370(8) 0.566(4) 0.445(3) 0.067 Uiso 1 1 d D . .
H2WB H 0.259(8) 0.575(4) 0.507(3) 0.067 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O5 96.63(13) . . ?
O1 Eu1 O6 144.20(14) . 2_776 ?
O5 Eu1 O6 94.99(12) . 2_776 ?
O1 Eu1 O15 90.85(15) . . ?
O5 Eu1 O15 144.95(14) . . ?
O6 Eu1 O15 98.69(13) 2_776 . ?
O1 Eu1 O16 79.51(13) . . ?
O5 Eu1 O16 144.57(13) . . ?
O6 Eu1 O16 71.57(12) 2_776 . ?
O15 Eu1 O16 70.46(13) . . ?
O1 Eu1 O12 69.27(14) . . ?
O5 Eu1 O12 75.04(13) . . ?
O6 Eu1 O12 146.53(13) 2_776 . ?
O15 Eu1 O12 75.81(13) . . ?
O16 Eu1 O12 133.11(12) . . ?
O1 Eu1 O13 75.36(14) . . ?
O5 Eu1 O13 72.68(13) . . ?
O6 Eu1 O13 76.07(14) 2_776 . ?
O15 Eu1 O13 142.03(13) . . ?
O16 Eu1 O13 72.29(12) . . ?
O13 Eu1 O13 128.10(13) . . ?
O1 Eu1 O14 142.83(15) . . ?
O5 Eu1 O14 76.00(12) . . ?
O6 Eu1 O14 72.92(14) 2_776 . ?
O15 Eu1 O14 77.47(14) . . ?
O16 Eu1 O14 126.92(12) . . ?
O12 Eu1 O14 73.66(13) . . ?
O13 Eu1 O14 133.16(13) . . ?
N3 Ag2 N4 169.52(19) . . ?
N1 Ag1 N2 168.9(2) . . ?
N1 Ag1 Ag1 92.29(13) . 2_765 ?
N2 Ag1 Ag1 92.99(14) . 2_765 ?
N2 C10 C9 123.3(6) . . ?
N2 C10 H10 118.4 . . ?
C9 C10 H10 118.4 . . ?
C10 C9 C8 119.5(5) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C9 C8 C12 117.6(5) . . ?
C9 C8 C7 121.2(4) . . ?
C12 C8 C7 121.2(5) . . ?
C11 C12 C8 119.8(5) . . ?
C11 C12 H12 120.1 . . ?
C8 C12 H12 120.1 . . ?
N2 C11 C12 122.9(5) . . ?
N2 C11 H11 118.5 . . ?
C12 C11 H11 118.5 . . ?
O3 C7 O4 127.6(4) . . ?
O3 C7 C8 116.6(4) . . ?
O4 C7 C8 115.8(4) . . ?
N1 C4 C3 123.5(5) . . ?
N1 C4 H4 118.2 . . ?
C3 C4 H4 118.2 . . ?
C4 C3 C2 119.6(5) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C6 C2 C3 117.5(4) . . ?
C6 C2 C1 120.9(4) . . ?
C3 C2 C1 121.6(4) . . ?
C5 C6 C2 118.9(4) . . ?
C5 C6 H6 120.5 . . ?
C2 C6 H6 120.5 . . ?
N1 C5 C6 123.6(5) . . ?
N1 C5 H5 118.2 . . ?
C6 C5 H5 118.2 . . ?
O2 C1 O1 125.5(5) . . ?
O2 C1 C2 118.5(4) . . ?
O1 C1 C2 116.0(4) . . ?
N4 C22 C21 122.9(5) . . ?
N4 C22 H22 118.6 . . ?
C21 C22 H22 118.6 . . ?
C20 C21 C22 120.1(5) . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C24 C20 C21 116.6(5) . . ?
C24 C20 C19 122.5(4) . . ?
C21 C20 C19 120.9(4) . . ?
C20 C24 C23 120.2(5) . . ?
C20 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
N4 C23 C24 123.2(5) . . ?
N4 C23 H23 118.4 . . ?
C24 C23 H23 118.4 . . ?
O8 C19 O7 126.7(4) . . ?
O8 C19 C20 115.9(4) . . ?
O7 C19 C20 117.4(4) . . ?
N3 C16 C15 123.1(5) . . ?
N3 C16 H16 118.5 . . ?
C15 C16 H16 118.5 . . ?
C16 C15 C14 118.4(4) . . ?
C16 C15 H15 120.8 . . ?
C14 C15 H15 120.8 . . ?
C18 C14 C15 118.4(4) . . ?
C18 C14 C13 120.2(4) . . ?
C15 C14 C13 121.4(4) . . ?
C17 C18 C14 119.8(4) . . ?
C17 C18 H18 120.1 . . ?
C14 C18 H18 120.1 . . ?
N3 C17 C18 122.4(5) . . ?
N3 C17 H17 118.8 . . ?
C18 C17 H17 118.8 . . ?
O5 C13 O6 125.3(4) . . ?
O5 C13 C14 116.9(4) . . ?
O6 C13 C14 117.9(4) . . ?
C11 N2 C10 116.9(5) . . ?
C11 N2 Ag1 120.6(4) . . ?
C10 N2 Ag1 122.4(4) . . ?
C5 N1 C4 116.8(4) . . ?
C5 N1 Ag1 122.6(4) . . ?
C4 N1 Ag1 120.6(3) . . ?
C23 N4 C22 117.2(5) . . ?
C23 N4 Ag2 119.8(4) . . ?
C22 N4 Ag2 122.9(4) . . ?
C17 N3 C16 117.9(4) . . ?
C17 N3 Ag2 120.6(4) . . ?
C16 N3 Ag2 121.5(3) . . ?
O10 N5 O9 122.6(8) . . ?
O10 N5 O11 118.2(7) . . ?
O9 N5 O11 119.1(7) . . ?
C1 O1 Eu1 167.3(4) . . ?
C13 O6 Eu1 152.6(3) . 2_776 ?
C13 O5 Eu1 143.9(3) . . ?
Eu1 O13 H13A 129(4) . . ?
Eu1 O13 H13B 112(4) . . ?
H13A O13 H13B 110(3) . . ?
Eu1 O15 H15A 115(4) . . ?
Eu1 O15 H15B 134(4) . . ?
H15A O15 H15B 107(2) . . ?
Eu1 O12 H12A 126(4) . . ?
Eu1 O12 H12B 121(4) . . ?
H12A O12 H12B 109(3) . . ?
Eu1 O16 H16A 121(4) . . ?
Eu1 O16 H16B 121(4) . . ?
H16A O16 H16B 109(2) . . ?
Eu1 O14 H14A 119(4) . . ?
Eu1 O14 H14B 129(4) . . ?
H14A O14 H14B 112(3) . . ?
H1WA O6W H1WB 109(3) . . ?
H2WA O2W H2WB 107(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.278(3) . ?
Eu1 O5 2.351(3) . ?
Eu1 O6 2.349(3) 2_776 ?
Eu1 O15 2.376(3) . ?
Eu1 O16 2.416(3) . ?
Eu1 O12 2.444(4) . ?
Eu1 O13 2.467(4) . ?
Eu1 O14 2.475(3) . ?
Ag2 N3 2.137(4) . ?
Ag2 N4 2.134(4) . ?
Ag1 N1 2.136(4) . ?
Ag1 N2 2.141(4) . ?
Ag1 Ag1 3.3121(11) 2_765 ?
C10 N2 1.346(8) . ?
C10 C9 1.367(8) . ?
C10 H10 0.9300 . ?
C9 C8 1.382(7) . ?
C9 H9 0.9300 . ?
C8 C12 1.376(7) . ?
C8 C7 1.533(6) . ?
C12 C11 1.378(7) . ?
C12 H12 0.9300 . ?
C11 N2 1.334(8) . ?
C11 H11 0.9300 . ?
C7 O3 1.237(6) . ?
C7 O4 1.243(6) . ?
C4 N1 1.338(7) . ?
C4 C3 1.366(7) . ?
C4 H4 0.9300 . ?
C3 C2 1.384(6) . ?
C3 H3 0.9300 . ?
C2 C6 1.383(6) . ?
C2 C1 1.512(6) . ?
C6 C5 1.383(7) . ?
C6 H6 0.9300 . ?
C5 N1 1.326(7) . ?
C5 H5 0.9300 . ?
C1 O2 1.215(6) . ?
C1 O1 1.246(5) . ?
C22 N4 1.336(7) . ?
C22 C21 1.384(8) . ?
C22 H22 0.9300 . ?
C21 C20 1.375(7) . ?
C21 H21 0.9300 . ?
C20 C24 1.388(7) . ?
C20 C19 1.527(6) . ?
C24 C23 1.372(7) . ?
C24 H24 0.9300 . ?
C23 N4 1.330(8) . ?
C23 H23 0.9300 . ?
C19 O8 1.244(6) . ?
C19 O7 1.238(6) . ?
C16 N3 1.341(7) . ?
C16 C15 1.377(7) . ?
C16 H16 0.9300 . ?
C15 C14 1.387(6) . ?
C15 H15 0.9300 . ?
C14 C18 1.379(6) . ?
C14 C13 1.508(5) . ?
C18 C17 1.368(7) . ?
C18 H18 0.9300 . ?
C17 N3 1.335(7) . ?
C17 H17 0.9300 . ?
C13 O5 1.246(5) . ?
C13 O6 1.247(5) . ?
N5 O10 1.205(8) . ?
N5 O9 1.213(7) . ?
N5 O11 1.255(8) . ?
O6 Eu1 2.349(3) 2_776 ?
O13 H13A 0.848(19) . ?
O13 H13B 0.848(19) . ?
O15 H15A 0.86(2) . ?
O15 H15B 0.865(19) . ?
O12 H12A 0.848(19) . ?
O12 H12B 0.858(19) . ?
O16 H16A 0.848(19) . ?
O16 H16B 0.862(19) . ?
O14 H14A 0.839(19) . ?
O14 H14B 0.841(19) . ?
O1W H1WA 0.86(2) . ?
O1W H1WB 0.85(2) . ?
O2W H2WA 0.865(19) . ?
O2W H2WB 0.868(19) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 C10 C9 C8 1.0(10) . . . . ?
C10 C9 C8 C12 0.2(9) . . . . ?
C10 C9 C8 C7 179.3(5) . . . . ?
C9 C8 C12 C11 -0.1(8) . . . . ?
C7 C8 C12 C11 -179.3(5) . . . . ?
C8 C12 C11 N2 -1.0(10) . . . . ?
C9 C8 C7 O3 176.5(5) . . . . ?
C12 C8 C7 O3 -4.4(7) . . . . ?
C9 C8 C7 O4 -2.6(7) . . . . ?
C12 C8 C7 O4 176.5(5) . . . . ?
N1 C4 C3 C2 0.2(9) . . . . ?
C4 C3 C2 C6 1.6(8) . . . . ?
C4 C3 C2 C1 -176.4(5) . . . . ?
C3 C2 C6 C5 -1.7(7) . . . . ?
C1 C2 C6 C5 176.2(5) . . . . ?
C2 C6 C5 N1 0.1(9) . . . . ?
C6 C2 C1 O2 14.2(7) . . . . ?
C3 C2 C1 O2 -167.9(5) . . . . ?
C6 C2 C1 O1 -164.6(5) . . . . ?
C3 C2 C1 O1 13.3(7) . . . . ?
N4 C22 C21 C20 -0.3(11) . . . . ?
C22 C21 C20 C24 0.6(9) . . . . ?
C22 C21 C20 C19 -179.8(6) . . . . ?
C21 C20 C24 C23 -0.7(9) . . . . ?
C19 C20 C24 C23 179.8(5) . . . . ?
C20 C24 C23 N4 0.5(10) . . . . ?
C24 C20 C19 O8 -172.2(5) . . . . ?
C21 C20 C19 O8 8.2(7) . . . . ?
C24 C20 C19 O7 7.2(8) . . . . ?
C21 C20 C19 O7 -172.3(5) . . . . ?
N3 C16 C15 C14 -0.7(9) . . . . ?
C16 C15 C14 C18 0.0(7) . . . . ?
C16 C15 C14 C13 178.5(5) . . . . ?
C15 C14 C18 C17 1.0(7) . . . . ?
C13 C14 C18 C17 -177.5(5) . . . . ?
C14 C18 C17 N3 -1.5(9) . . . . ?
C18 C14 C13 O5 0.6(6) . . . . ?
C15 C14 C13 O5 -177.9(5) . . . . ?
C18 C14 C13 O6 -179.5(4) . . . . ?
C15 C14 C13 O6 2.1(7) . . . . ?
C12 C11 N2 C10 2.1(10) . . . . ?
C12 C11 N2 Ag1 178.6(5) . . . . ?
C9 C10 N2 C11 -2.1(10) . . . . ?
C9 C10 N2 Ag1 -178.5(5) . . . . ?
N1 Ag1 N2 C11 159.6(8) . . . . ?
Ag1 Ag1 N2 C11 -82.0(5) 2_765 . . . ?
N1 Ag1 N2 C10 -24.1(13) . . . . ?
Ag1 Ag1 N2 C10 94.3(5) 2_765 . . . ?
C6 C5 N1 C4 1.6(8) . . . . ?
C6 C5 N1 Ag1 -177.1(4) . . . . ?
C3 C4 N1 C5 -1.8(9) . . . . ?
C3 C4 N1 Ag1 177.0(5) . . . . ?
N2 Ag1 N1 C5 -156.8(9) . . . . ?
Ag1 Ag1 N1 C5 84.8(4) 2_765 . . . ?
N2 Ag1 N1 C4 24.5(12) . . . . ?
Ag1 Ag1 N1 C4 -93.9(4) 2_765 . . . ?
C24 C23 N4 C22 -0.2(10) . . . . ?
C24 C23 N4 Ag2 175.1(5) . . . . ?
C21 C22 N4 C23 0.1(10) . . . . ?
C21 C22 N4 Ag2 -175.0(5) . . . . ?
N3 Ag2 N4 C23 55.0(13) . . . . ?
N3 Ag2 N4 C22 -130.0(10) . . . . ?
C18 C17 N3 C16 0.8(9) . . . . ?
C18 C17 N3 Ag2 179.9(4) . . . . ?
C15 C16 N3 C17 0.3(9) . . . . ?
C15 C16 N3 Ag2 -178.8(4) . . . . ?
N4 Ag2 N3 C17 -52.8(13) . . . . ?
N4 Ag2 N3 C16 126.2(10) . . . . ?
O2 C1 O1 Eu1 40(2) . . . . ?
C2 C1 O1 Eu1 -141.0(15) . . . . ?
O5 Eu1 O1 C1 147.0(17) . . . . ?
O6 Eu1 O1 C1 38.8(18) 2_776 . . . ?
O15 Eu1 O1 C1 -67.3(17) . . . . ?
O16 Eu1 O1 C1 2.6(17) . . . . ?
O12 Eu1 O1 C1 -141.8(17) . . . . ?
O13 Eu1 O1 C1 76.9(17) . . . . ?
O14 Eu1 O1 C1 -137.5(16) . . . . ?
O5 C13 O6 Eu1 84.9(8) . . . 2_776 ?
C14 C13 O6 Eu1 -95.0(7) . . . 2_776 ?
O6 C13 O5 Eu1 -8.1(9) . . . . ?
C14 C13 O5 Eu1 171.8(4) . . . . ?
O1 Eu1 O5 C13 -166.5(6) . . . . ?
O6 Eu1 O5 C13 -20.4(6) 2_776 . . . ?
O15 Eu1 O5 C13 92.5(6) . . . . ?
O16 Eu1 O5 C13 -85.2(6) . . . . ?
O12 Eu1 O5 C13 127.1(6) . . . . ?
O13 Eu1 O5 C13 -94.1(6) . . . . ?
O14 Eu1 O5 C13 50.6(6) . . . . ?
