#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:26:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180339 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/08/7200892.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7200892
loop_
_publ_author_name
'Zhao, Xiao-Qing'
'Zhao, Bin'
'Shi, Wei'
'Cheng, Peng'
_publ_section_title
;
 Structures and luminescent properties of a series of Ln--Ag
 heterometallic coordination polymers
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              1261
_journal_paper_doi               10.1039/b900430k
_journal_volume                  11
_journal_year                    2009
_chemical_formula_sum            'C14 H18 Ag N2 O14 Sm'
_chemical_formula_weight         696.52
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.776(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.621(2)
_cell_length_b                   7.3491(10)
_cell_length_c                   19.765(3)
_cell_measurement_reflns_used    5795
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      26.40
_cell_measurement_theta_min      2.82
_cell_volume                     2098.9(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0431
_diffrn_reflns_av_sigmaI/netI    0.0415
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            11414
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    3.779
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.626759
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADBAS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    2.204
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       PRISM
_exptl_crystal_F_000             1348
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.529
_refine_diff_density_min         -2.722
_refine_diff_density_rms         0.177
_refine_ls_extinction_coef       0.0012(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     296
_refine_ls_number_reflns         4293
_refine_ls_number_restraints     33
_refine_ls_restrained_S_all      1.827
_refine_ls_R_factor_all          0.0540
_refine_ls_R_factor_gt           0.0446
_refine_ls_shift/su_max          0.054
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0568P)²+14.8708P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1085
_refine_ls_wR_factor_ref         0.1143
_reflns_number_gt                3638
_reflns_number_total             4293
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b900430k.txt
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7200892
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sm1 Sm 0.29579(4) 0.45879(7) 0.13841(3) 0.0200(2) Uani 1 1 d U . .
Ag1 Ag 0.37926(11) -0.0024(2) 0.00728(12) 0.0923(6) Uani 1 1 d U . .
O1 O 0.1969(6) 0.7274(11) 0.1381(4) 0.0300(18) Uani 1 1 d . . .
O2 O 0.0954(7) 0.9301(12) 0.0864(5) 0.042(2) Uani 1 1 d . . .
O3 O 0.2936(6) 0.2450(12) 0.0427(4) 0.035(2) Uani 1 1 d . . .
O4 O 0.2371(8) 0.1269(14) -0.0569(5) 0.049(3) Uani 1 1 d . . .
O5 O 0.3693(6) 0.6740(12) 0.0682(4) 0.034(2) Uani 1 1 d . . .
O6 O 0.4945(7) 0.8029(13) 0.0379(6) 0.052(3) Uani 1 1 d . . .
O7 O 0.3676(5) 0.1820(11) 0.1936(4) 0.0304(18) Uani 1 1 d . . .
O8 O 0.4831(6) -0.0184(12) 0.2148(6) 0.047(3) Uani 1 1 d . . .
O9 O 0.1621(6) 0.2546(11) 0.1446(4) 0.0306(18) Uani 1 1 d D . .
H9A H 0.158(9) 0.145(5) 0.131(5) 0.037 Uiso 1 1 d D . .
H9B H 0.133(8) 0.333(10) 0.118(5) 0.037 Uiso 1 1 d D . .
O10 O 0.2473(6) 0.4511(11) 0.2515(4) 0.0299(18) Uani 1 1 d . . .
H10A H 0.2132 0.5334 0.2648 0.036 Uiso 1 1 d R . .
H10B H 0.2773 0.3842 0.2824 0.036 Uiso 1 1 d R . .
O11 O 0.3962(6) 0.6575(11) 0.2201(4) 0.0326(19) Uani 1 1 d . . .
H11A H 0.4080 0.7679 0.2115 0.039 Uiso 1 1 d R . .
H11B H 0.4398 0.5976 0.2439 0.039 Uiso 1 1 d R . .
N1 N 0.1782(6) 0.5181(12) 0.0294(5) 0.0229(19) Uani 1 1 d . . .
N2 N 0.4643(6) 0.3972(13) 0.1265(5) 0.025(2) Uani 1 1 d . . .
C1 C 0.1404(8) 0.7865(16) 0.0883(6) 0.028(2) Uani 1 1 d . . .
C2 C 0.1262(8) 0.6675(15) 0.0247(6) 0.025(2) Uani 1 1 d . . .
C3 C 0.0642(9) 0.7082(18) -0.0329(6) 0.037(3) Uani 1 1 d . . .
H3 H 0.0282 0.8128 -0.0347 0.044 Uiso 1 1 calc R . .
C4 C 0.0564(10) 0.590(2) -0.0883(7) 0.044(3) Uani 1 1 d . . .
H4 H 0.0160 0.6161 -0.1283 0.053 Uiso 1 1 calc R . .
C5 C 0.1098(9) 0.4331(19) -0.0834(7) 0.038(3) Uani 1 1 d . . .
H5 H 0.1047 0.3504 -0.1194 0.045 Uiso 1 1 calc R . .
C6 C 0.1710(8) 0.4024(16) -0.0233(6) 0.026(2) Uani 1 1 d . . .
C7 C 0.2369(9) 0.2461(16) -0.0124(6) 0.031(3) Uani 1 1 d . . .
C8 C 0.4552(9) 0.6770(16) 0.0652(6) 0.032(3) Uani 1 1 d . . .
C9 C 0.5123(9) 0.5183(16) 0.0953(6) 0.030(3) Uani 1 1 d . . .
C10 C 0.6034(10) 0.4953(19) 0.0900(8) 0.044(3) Uani 1 1 d . . .
H10 H 0.6345 0.5813 0.0676 0.053 Uiso 1 1 calc R . .
C11 C 0.6488(10) 0.343(2) 0.1184(9) 0.053(4) Uani 1 1 d . . .
H11 H 0.7113 0.3263 0.1163 0.064 Uiso 1 1 calc R . .
C12 C 0.5999(9) 0.215(2) 0.1503(8) 0.045(4) Uani 1 1 d . . .
H12 H 0.6285 0.1097 0.1687 0.054 Uiso 1 1 calc R . .
C13 C 0.5082(8) 0.2485(16) 0.1540(6) 0.029(3) Uani 1 1 d . . .
C14 C 0.4488(8) 0.1253(16) 0.1906(6) 0.030(3) Uani 1 1 d . . .
O12 O 0.8035(8) 0.9665(16) 0.1914(6) 0.057(3) Uani 1 1 d U . .
H12A H 0.7789 0.9942 0.1461 0.069 Uiso 1 1 d R . .
H12B H 0.8268 0.8504 0.2023 0.069 Uiso 1 1 d R . .
O13 O 0.9914(8) 0.9464(17) 0.1980(7) 0.067(3) Uani 1 1 d U . .
H13A H 0.9997 0.9413 0.1544 0.080 Uiso 1 1 d R . .
H13B H 0.9523 1.0394 0.2123 0.080 Uiso 1 1 d R . .
O14 O 0.8358(10) 0.326(2) 0.2452(7) 0.081(4) Uani 1 1 d U . .
H14A H 0.8843 0.2840 0.2716 0.098 Uiso 1 1 d R . .
H14B H 0.8156 0.2627 0.2093 0.098 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Sm1 O10 76.5(3) . . ?
O1 Sm1 O5 77.8(3) . . ?
O10 Sm1 O5 138.0(3) . . ?
O1 Sm1 O3 125.2(3) . . ?
O10 Sm1 O3 135.9(3) . . ?
O5 Sm1 O3 86.1(3) . . ?
O1 Sm1 O7 151.4(3) . . ?
O10 Sm1 O7 74.9(3) . . ?
O5 Sm1 O7 126.0(3) . . ?
O3 Sm1 O7 76.5(3) . . ?
O1 Sm1 O9 91.1(3) . . ?
O10 Sm1 O9 66.5(3) . . ?
O5 Sm1 O9 146.4(3) . . ?
O3 Sm1 O9 74.5(3) . . ?
O7 Sm1 O9 76.4(3) . . ?
O1 Sm1 O11 79.5(3) . . ?
O10 Sm1 O11 69.2(3) . . ?
O5 Sm1 O11 73.9(3) . . ?
O3 Sm1 O11 144.5(3) . . ?
O7 Sm1 O11 91.6(3) . . ?
O9 Sm1 O11 135.6(3) . . ?
O1 Sm1 N2 136.2(3) . . ?
O10 Sm1 N2 119.9(3) . . ?
O5 Sm1 N2 63.3(3) . . ?
O3 Sm1 N2 73.4(3) . . ?
O7 Sm1 N2 62.8(3) . . ?
O9 Sm1 N2 132.5(3) . . ?
O11 Sm1 N2 71.4(3) . . ?
O1 Sm1 N1 62.8(3) . . ?
O10 Sm1 N1 121.2(3) . . ?
O5 Sm1 N1 73.3(3) . . ?
O3 Sm1 N1 62.4(3) . . ?
O7 Sm1 N1 133.9(3) . . ?
O9 Sm1 N1 73.4(3) . . ?
O11 Sm1 N1 134.1(3) . . ?
N2 Sm1 N1 118.9(3) . . ?
O1 Sm1 H9B 75.7(16) . . ?
O10 Sm1 H9B 75(2) . . ?
O5 Sm1 H9B 128.8(14) . . ?
O3 Sm1 H9B 75(3) . . ?
O7 Sm1 H9B 95.5(8) . . ?
O9 Sm1 H9B 19.6(7) . . ?
O11 Sm1 H9B 140(3) . . ?
N2 Sm1 H9B 145(2) . . ?
N1 Sm1 H9B 55.7(15) . . ?
O6 Ag1 O3 145.6(4) 1_545 . ?
O6 Ag1 O4 159.5(4) 1_545 . ?
O3 Ag1 O4 54.0(3) . . ?
C1 O1 Sm1 126.6(7) . . ?
C7 O3 Ag1 93.2(7) . . ?
C7 O3 Sm1 126.1(7) . . ?
Ag1 O3 Sm1 140.5(4) . . ?
C7 O4 Ag1 90.0(8) . . ?
C8 O5 Sm1 124.1(7) . . ?
C8 O6 Ag1 102.4(8) . 1_565 ?
C14 O7 Sm1 126.1(7) . . ?
Sm1 O9 H9A 126(9) . . ?
Sm1 O9 H9B 83(9) . . ?
H9A O9 H9B 116(4) . . ?
Sm1 O10 H10A 122.1 . . ?
Sm1 O10 H10B 118.7 . . ?
H10A O10 H10B 116.8 . . ?
Sm1 O11 H11A 123.2 . . ?
Sm1 O11 H11B 111.8 . . ?
H11A O11 H11B 116.3 . . ?
C6 N1 C2 119.7(10) . . ?
C6 N1 Sm1 120.4(7) . . ?
C2 N1 Sm1 119.9(7) . . ?
C9 N2 C13 118.4(10) . . ?
C9 N2 Sm1 120.3(7) . . ?
C13 N2 Sm1 121.2(7) . . ?
O2 C1 O1 126.7(11) . . ?
O2 C1 C2 117.4(11) . . ?
O1 C1 C2 115.9(10) . . ?
N1 C2 C3 122.3(10) . . ?
N1 C2 C1 114.4(10) . . ?
C3 C2 C1 123.3(10) . . ?
C2 C3 C4 118.8(12) . . ?
C2 C3 H3 120.6 . . ?
C4 C3 H3 120.6 . . ?
C5 C4 C3 119.1(12) . . ?
C5 C4 H4 120.4 . . ?
C3 C4 H4 120.4 . . ?
C4 C5 C6 118.4(12) . . ?
C4 C5 H5 120.8 . . ?
C6 C5 H5 120.8 . . ?
N1 C6 C5 121.6(11) . . ?
N1 C6 C7 113.9(10) . . ?
C5 C6 C7 124.4(11) . . ?
O4 C7 O3 122.3(12) . . ?
O4 C7 C6 120.7(12) . . ?
O3 C7 C6 117.0(10) . . ?
O6 C8 O5 123.8(11) . . ?
O6 C8 C9 118.7(11) . . ?
O5 C8 C9 117.5(10) . . ?
N2 C9 C10 122.6(11) . . ?
N2 C9 C8 113.6(10) . . ?
C10 C9 C8 123.8(11) . . ?
C9 C10 C11 119.1(12) . . ?
C9 C10 H10 120.4 . . ?
C11 C10 H10 120.5 . . ?
C10 C11 C12 119.0(12) . . ?
C10 C11 H11 120.5 . . ?
C12 C11 H11 120.5 . . ?
C13 C12 C11 118.6(12) . . ?
C13 C12 H12 120.7 . . ?
C11 C12 H12 120.7 . . ?
N2 C13 C12 122.2(11) . . ?
N2 C13 C14 114.0(10) . . ?
C12 C13 C14 123.7(11) . . ?
O8 C14 O7 126.2(11) . . ?
O8 C14 C13 118.0(10) . . ?
O7 C14 C13 115.8(10) . . ?
H12A O12 H12B 119.6 . . ?
H13A O13 H13B 119.4 . . ?
H14A O14 H14B 116.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sm1 O1 2.446(8) . ?
Sm1 O10 2.446(8) . ?
Sm1 O5 2.457(8) . ?
Sm1 O3 2.455(8) . ?
Sm1 O7 2.465(8) . ?
Sm1 O9 2.482(8) . ?
Sm1 O11 2.485(8) . ?
Sm1 N2 2.551(9) . ?
Sm1 N1 2.581(9) . ?
Sm1 H9B 2.52(12) . ?
Ag1 O6 2.223(10) 1_545 ?
Ag1 O3 2.374(8) . ?
Ag1 O4 2.455(10) . ?
O1 C1 1.263(14) . ?
O2 C1 1.240(14) . ?
O3 C7 1.264(15) . ?
O4 C7 1.242(15) . ?
O5 C8 1.267(15) . ?
O6 C8 1.253(15) . ?
O6 Ag1 2.223(10) 1_565 ?
O7 C14 1.269(14) . ?
O8 C14 1.234(14) . ?
O9 H9A 0.852(19) . ?
O9 H9B 0.850(18) . ?
O10 H10A 0.8506 . ?
O10 H10B 0.8517 . ?
O11 H11A 0.8519 . ?
O11 H11B 0.8540 . ?
N1 C6 1.337(14) . ?
N1 C2 1.330(14) . ?
N2 C9 1.341(15) . ?
N2 C13 1.340(15) . ?
C1 C2 1.519(15) . ?
C2 C3 1.376(16) . ?
C3 C4 1.388(18) . ?
C3 H3 0.9300 . ?
C4 C5 1.388(19) . ?
C4 H4 0.9300 . ?
C5 C6 1.393(17) . ?
C5 H5 0.9300 . ?
C6 C7 1.493(16) . ?
C8 C9 1.503(16) . ?
C9 C10 1.363(18) . ?
C10 C11 1.375(19) . ?
C10 H10 0.9300 . ?
C11 C12 1.388(19) . ?
C11 H11 0.9300 . ?
C12 C13 1.376(17) . ?
C12 H12 0.9300 . ?
C13 C14 1.513(15) . ?
O12 H12A 0.9346 . ?
O12 H12B 0.9317 . ?
O13 H13A 0.8901 . ?
O13 H13B 0.9605 . ?
O14 H14A 0.8694 . ?
O14 H14B 0.8623 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O10 Sm1 O1 C1 -141.7(10) . . . . ?
O5 Sm1 O1 C1 71.8(10) . . . . ?
O3 Sm1 O1 C1 -4.4(11) . . . . ?
O7 Sm1 O1 C1 -138.9(9) . . . . ?
O9 Sm1 O1 C1 -76.2(10) . . . . ?
O11 Sm1 O1 C1 147.4(10) . . . . ?
N2 Sm1 O1 C1 98.9(10) . . . . ?
N1 Sm1 O1 C1 -5.5(9) . . . . ?
O6 Ag1 O3 C7 -174.8(7) 1_545 . . . ?
O4 Ag1 O3 C7 -3.6(7) . . . . ?
O6 Ag1 O3 Sm1 8.7(10) 1_545 . . . ?
O4 Ag1 O3 Sm1 179.9(8) . . . . ?
O1 Sm1 O3 C7 -6.1(11) . . . . ?
O10 Sm1 O3 C7 102.5(10) . . . . ?
O5 Sm1 O3 C7 -78.2(10) . . . . ?
O7 Sm1 O3 C7 153.4(10) . . . . ?
O9 Sm1 O3 C7 74.1(10) . . . . ?
O11 Sm1 O3 C7 -133.2(9) . . . . ?
N2 Sm1 O3 C7 -141.4(10) . . . . ?
N1 Sm1 O3 C7 -5.0(9) . . . . ?
O1 Sm1 O3 Ag1 169.6(5) . . . . ?
O10 Sm1 O3 Ag1 -81.9(8) . . . . ?
O5 Sm1 O3 Ag1 97.5(7) . . . . ?
O7 Sm1 O3 Ag1 -31.0(6) . . . . ?
O9 Sm1 O3 Ag1 -110.3(7) . . . . ?
O11 Sm1 O3 Ag1 42.5(9) . . . . ?
N2 Sm1 O3 Ag1 34.2(6) . . . . ?
N1 Sm1 O3 Ag1 170.7(8) . . . . ?
O6 Ag1 O4 C7 169.4(9) 1_545 . . . ?
O3 Ag1 O4 C7 3.7(7) . . . . ?
O1 Sm1 O5 C8 149.1(10) . . . . ?
O10 Sm1 O5 C8 95.7(10) . . . . ?
O3 Sm1 O5 C8 -83.7(10) . . . . ?
O7 Sm1 O5 C8 -13.4(11) . . . . ?
O9 Sm1 O5 C8 -137.9(9) . . . . ?
O11 Sm1 O5 C8 66.6(10) . . . . ?
N2 Sm1 O5 C8 -10.3(9) . . . . ?
N1 Sm1 O5 C8 -145.9(10) . . . . ?
O1 Sm1 O7 C14 -142.1(9) . . . . ?
O10 Sm1 O7 C14 -139.3(10) . . . . ?
O5 Sm1 O7 C14 -0.2(11) . . . . ?
O3 Sm1 O7 C14 74.8(10) . . . . ?
O9 Sm1 O7 C14 151.8(10) . . . . ?
O11 Sm1 O7 C14 -71.4(10) . . . . ?
N2 Sm1 O7 C14 -3.3(10) . . . . ?
N1 Sm1 O7 C14 101.7(10) . . . . ?
O1 Sm1 N1 C6 -178.2(9) . . . . ?
O10 Sm1 N1 C6 -126.3(8) . . . . ?
O5 Sm1 N1 C6 97.2(9) . . . . ?
O3 Sm1 N1 C6 2.8(8) . . . . ?
O7 Sm1 N1 C6 -27.0(10) . . . . ?
O9 Sm1 N1 C6 -78.2(8) . . . . ?
O11 Sm1 N1 C6 143.3(8) . . . . ?
N2 Sm1 N1 C6 51.7(9) . . . . ?
O1 Sm1 N1 C2 3.8(8) . . . . ?
O10 Sm1 N1 C2 55.7(9) . . . . ?
O5 Sm1 N1 C2 -80.8(8) . . . . ?
O3 Sm1 N1 C2 -175.2(9) . . . . ?
O7 Sm1 N1 C2 155.0(7) . . . . ?
O9 Sm1 N1 C2 103.8(8) . . . . ?
O11 Sm1 N1 C2 -34.7(10) . . . . ?
N2 Sm1 N1 C2 -126.3(8) . . . . ?
O1 Sm1 N2 C9 -22.7(11) . . . . ?
O10 Sm1 N2 C9 -125.0(9) . . . . ?
O5 Sm1 N2 C9 7.2(8) . . . . ?
O3 Sm1 N2 C9 101.2(9) . . . . ?
O7 Sm1 N2 C9 -175.6(10) . . . . ?
O9 Sm1 N2 C9 150.6(8) . . . . ?
O11 Sm1 N2 C9 -73.7(9) . . . . ?
N1 Sm1 N2 C9 57.0(10) . . . . ?
O1 Sm1 N2 C13 153.9(8) . . . . ?
O10 Sm1 N2 C13 51.7(10) . . . . ?
O5 Sm1 N2 C13 -176.2(10) . . . . ?
O3 Sm1 N2 C13 -82.1(9) . . . . ?
O7 Sm1 N2 C13 1.0(9) . . . . ?
O9 Sm1 N2 C13 -32.7(11) . . . . ?
O11 Sm1 N2 C13 102.9(9) . . . . ?
N1 Sm1 N2 C13 -126.3(9) . . . . ?
Sm1 O1 C1 O2 -174.0(10) . . . . ?
Sm1 O1 C1 C2 6.4(15) . . . . ?
C6 N1 C2 C3 0.2(17) . . . . ?
Sm1 N1 C2 C3 178.2(9) . . . . ?
C6 N1 C2 C1 179.5(10) . . . . ?
Sm1 N1 C2 C1 -2.5(13) . . . . ?
O2 C1 C2 N1 178.3(11) . . . . ?
O1 C1 C2 N1 -2.1(15) . . . . ?
O2 C1 C2 C3 -2.5(18) . . . . ?
O1 C1 C2 C3 177.2(12) . . . . ?
N1 C2 C3 C4 -1(2) . . . . ?
C1 C2 C3 C4 -180.0(13) . . . . ?
C2 C3 C4 C5 1(2) . . . . ?
C3 C4 C5 C6 -2(2) . . . . ?
C2 N1 C6 C5 -0.5(17) . . . . ?
Sm1 N1 C6 C5 -178.5(9) . . . . ?
C2 N1 C6 C7 176.9(10) . . . . ?
Sm1 N1 C6 C7 -1.1(13) . . . . ?
C4 C5 C6 N1 1(2) . . . . ?
C4 C5 C6 C7 -175.9(12) . . . . ?
Ag1 O4 C7 O3 -6.6(13) . . . . ?
Ag1 O4 C7 C6 170.9(10) . . . . ?
Ag1 O3 C7 O4 6.9(13) . . . . ?
Sm1 O3 C7 O4 -175.9(9) . . . . ?
Ag1 O3 C7 C6 -170.8(9) . . . . ?
Sm1 O3 C7 C6 6.4(15) . . . . ?
N1 C6 C7 O4 179.2(12) . . . . ?
C5 C6 C7 O4 -4(2) . . . . ?
N1 C6 C7 O3 -3.1(16) . . . . ?
C5 C6 C7 O3 174.2(12) . . . . ?
Ag1 O6 C8 O5 2.9(16) 1_565 . . . ?
Ag1 O6 C8 C9 -178.0(9) 1_565 . . . ?
Sm1 O5 C8 O6 -168.7(10) . . . . ?
Sm1 O5 C8 C9 12.2(15) . . . . ?
C13 N2 C9 C10 0.5(19) . . . . ?
Sm1 N2 C9 C10 177.3(11) . . . . ?
C13 N2 C9 C8 178.8(11) . . . . ?
Sm1 N2 C9 C8 -4.5(14) . . . . ?
O6 C8 C9 N2 176.3(12) . . . . ?
O5 C8 C9 N2 -4.5(17) . . . . ?
O6 C8 C9 C10 -5(2) . . . . ?
O5 C8 C9 C10 173.7(14) . . . . ?
N2 C9 C10 C11 -1(2) . . . . ?
C8 C9 C10 C11 -178.8(14) . . . . ?
C9 C10 C11 C12 1(3) . . . . ?
C10 C11 C12 C13 -2(3) . . . . ?
C9 N2 C13 C12 -1.0(19) . . . . ?
Sm1 N2 C13 C12 -177.7(11) . . . . ?
C9 N2 C13 C14 177.4(11) . . . . ?
Sm1 N2 C13 C14 0.7(14) . . . . ?
C11 C12 C13 N2 2(2) . . . . ?
C11 C12 C13 C14 -176.6(14) . . . . ?
Sm1 O7 C14 O8 -175.5(11) . . . . ?
Sm1 O7 C14 C13 4.8(16) . . . . ?
N2 C13 C14 O8 177.0(12) . . . . ?
C12 C13 C14 O8 -5(2) . . . . ?
N2 C13 C14 O7 -3.4(17) . . . . ?
C12 C13 C14 O7 175.0(14) . . . . ?
