#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:41:24 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180350 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/19/7201947.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7201947
loop_
_publ_author_name
'Li, Fengyan'
'Xu, Lin'
'Bi, Bo'
'Liu, Xizheng'
'Fan, Lihua'
_publ_section_title
;
 1D lanthanide(iii) coordination polymers with disulfide ligand
 generated in situ
;
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              693
_journal_paper_doi               10.1039/b800437b
_journal_volume                  10
_journal_year                    2008
_chemical_formula_sum            'C24 H29 Eu N3 O10 S6'
_chemical_formula_weight         863.82
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.0870(10)
_cell_angle_beta                 94.6990(10)
_cell_angle_gamma                91.9950(10)
_cell_formula_units_Z            2
_cell_length_a                   7.8341(3)
_cell_length_b                   11.8843(5)
_cell_length_c                   17.5342(8)
_cell_measurement_temperature    273(2)
_cell_volume                     1621.50(12)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.924
_diffrn_measured_fraction_theta_max 0.924
_diffrn_measurement_device_type  'SMART CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0336
_diffrn_reflns_av_sigmaI/netI    0.0887
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10161
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         1.72
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    2.377
_exptl_absorpt_correction_T_max  0.8904
_exptl_absorpt_correction_T_min  0.5358
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.769
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             866
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.675
_refine_diff_density_min         -1.011
_refine_diff_density_rms         0.160
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     405
_refine_ls_number_reflns         7454
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.015
_refine_ls_R_factor_all          0.0779
_refine_ls_R_factor_gt           0.0499
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0282P)²+4.1540P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0878
_refine_ls_wR_factor_ref         0.1085
_reflns_number_gt                5512
_reflns_number_total             7454
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b800437b.txt
_cod_data_source_block           2
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7201947
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.22011(4) 0.41156(3) 0.243838(19) 0.02468(10) Uani 1 1 d . . .
O1 O 0.3589(6) 0.3689(4) 0.1271(3) 0.0438(12) Uani 1 1 d . . .
O1W O 0.7661(8) 0.4350(5) 0.3863(3) 0.0540(14) Uani 1 1 d D . .
O2 O 0.1251(6) 0.2658(4) 0.1294(3) 0.0388(11) Uani 1 1 d . . .
O3 O 0.3225(6) 1.3427(4) 0.3739(3) 0.0413(12) Uani 1 1 d . . .
O4 O 0.3407(6) 1.2286(3) 0.2701(3) 0.0344(10) Uani 1 1 d . . .
O5 O 0.5067(5) 0.4993(3) 0.2776(3) 0.0345(11) Uani 1 1 d . . .
O6 O 0.3348(5) 0.6009(3) 0.2087(3) 0.0371(11) Uani 1 1 d . . .
O7 O 0.1386(6) 0.5431(4) 0.3400(2) 0.0366(11) Uani 1 1 d . . .
O8 O -0.0190(5) 0.3083(3) 0.2847(3) 0.0349(11) Uani 1 1 d . . .
O9 O -0.0138(5) 0.4957(4) 0.1762(3) 0.0353(11) Uani 1 1 d . . .
S1 S 0.0257(2) 0.07122(15) 0.03959(11) 0.0396(4) Uani 1 1 d . . .
S2 S 0.3300(2) 0.83212(13) 0.24380(10) 0.0313(4) Uani 1 1 d . . .
S3 S 0.3306(2) 1.00434(13) 0.25599(10) 0.0315(4) Uani 1 1 d . . .
S4 S 0.1686(2) 0.55172(14) 0.42772(10) 0.0363(4) Uani 1 1 d . . .
S5 S -0.0397(3) 0.52072(16) 0.09296(11) 0.0443(5) Uani 1 1 d . . .
S6 S -0.0989(2) 0.19285(14) 0.25612(11) 0.0384(4) Uani 1 1 d . . .
N1 N 0.2772(7) 0.0455(5) -0.0532(3) 0.0375(14) Uani 1 1 d . . .
N2 N 0.6641(7) 0.8879(4) 0.2685(3) 0.0364(13) Uani 1 1 d . . .
N3 N 0.3021(9) 0.9442(5) 0.3986(4) 0.0521(17) Uani 1 1 d . . .
C1 C 0.2242(8) 0.1106(5) 0.0048(3) 0.0293(14) Uani 1 1 d . . .
C2 C 0.3219(8) 0.2071(5) 0.0393(4) 0.0305(14) Uani 1 1 d . . .
C3 C 0.4737(9) 0.2310(6) 0.0105(4) 0.0405(17) Uani 1 1 d . . .
H3 H 0.5387 0.2950 0.0302 0.049 Uiso 1 1 calc R . .
C4 C 0.5344(10) 0.1612(6) -0.0483(4) 0.048(2) Uani 1 1 d . . .
H4 H 0.6413 0.1743 -0.0661 0.058 Uiso 1 1 calc R . .
C5 C 0.4272(9) 0.0724(6) -0.0780(4) 0.0439(18) Uani 1 1 d . . .
H5 H 0.4628 0.0275 -0.1189 0.053 Uiso 1 1 calc R . .
C6 C 0.2613(8) 0.2856(5) 0.1025(4) 0.0305(14) Uani 1 1 d . . .
C7 C 0.3177(8) 1.0328(5) 0.3561(4) 0.0330(15) Uani 1 1 d . . .
C8 C 0.3186(8) 1.1447(5) 0.3879(4) 0.0303(14) Uani 1 1 d . . .
C9 C 0.2976(10) 1.1627(6) 0.4661(4) 0.0477(19) Uani 1 1 d . . .
H9 H 0.2979 1.2361 0.4885 0.057 Uiso 1 1 calc R . .
C10 C 0.2763(13) 1.0727(7) 0.5101(5) 0.067(3) Uani 1 1 d . . .
H10 H 0.2584 1.0830 0.5619 0.080 Uiso 1 1 calc R . .
C11 C 0.2829(15) 0.9661(8) 0.4735(5) 0.088(4) Uani 1 1 d . . .
H11 H 0.2733 0.9048 0.5032 0.105 Uiso 1 1 calc R . .
C12 C 0.3330(8) 1.2449(5) 0.3411(4) 0.0315(15) Uani 1 1 d . . .
C13 C 0.5506(7) 0.8013(5) 0.2587(3) 0.0253(13) Uani 1 1 d . . .
C14 C 0.5971(7) 0.6896(5) 0.2616(3) 0.0256(13) Uani 1 1 d . . .
C15 C 0.7738(8) 0.6683(5) 0.2732(4) 0.0341(15) Uani 1 1 d . . .
H15 H 0.8101 0.5948 0.2749 0.041 Uiso 1 1 calc R . .
C16 C 0.8906(8) 0.7580(6) 0.2820(4) 0.0413(18) Uani 1 1 d . . .
H16 H 1.0069 0.7463 0.2915 0.050 Uiso 1 1 calc R . .
C17 C 0.8339(9) 0.8636(6) 0.2766(5) 0.0452(19) Uani 1 1 d . . .
H17 H 0.9149 0.9231 0.2785 0.054 Uiso 1 1 calc R . .
C18 C 0.4714(8) 0.5908(5) 0.2480(4) 0.0276(14) Uani 1 1 d . . .
C19 C 0.0408(10) 0.6659(6) 0.4588(4) 0.050(2) Uani 1 1 d . . .
H19A H -0.0783 0.6424 0.4515 0.075 Uiso 1 1 calc R . .
H19B H 0.0608 0.7293 0.4292 0.075 Uiso 1 1 calc R . .
H19C H 0.0714 0.6872 0.5121 0.075 Uiso 1 1 calc R . .
C20 C 0.3707(9) 0.6212(7) 0.4480(4) 0.057(2) Uani 1 1 d . . .
H20A H 0.4584 0.5709 0.4344 0.085 Uiso 1 1 calc R . .
H20B H 0.3874 0.6443 0.5018 0.085 Uiso 1 1 calc R . .
H20C H 0.3765 0.6865 0.4189 0.085 Uiso 1 1 calc R . .
C21 C -0.2689(11) 0.5317(8) 0.0746(6) 0.083(3) Uani 1 1 d . . .
H21A H -0.3242 0.4584 0.0750 0.124 Uiso 1 1 calc R . .
H21B H -0.2938 0.5607 0.0253 0.124 Uiso 1 1 calc R . .
H21C H -0.3105 0.5818 0.1137 0.124 Uiso 1 1 calc R . .
C22 C 0.0193(11) 0.6655(7) 0.0886(5) 0.062(2) Uani 1 1 d . . .
H22A H 0.1417 0.6759 0.0971 0.092 Uiso 1 1 calc R . .
H22B H -0.0336 0.7097 0.1274 0.092 Uiso 1 1 calc R . .
H22C H -0.0181 0.6892 0.0390 0.092 Uiso 1 1 calc R . .
C23 C -0.2307(10) 0.1582(6) 0.3318(5) 0.056(2) Uani 1 1 d . . .
H23A H -0.1587 0.1411 0.3761 0.083 Uiso 1 1 calc R . .
H23B H -0.3048 0.0937 0.3145 0.083 Uiso 1 1 calc R . .
H23C H -0.2987 0.2212 0.3449 0.083 Uiso 1 1 calc R . .
C24 C -0.2689(11) 0.2190(8) 0.1861(5) 0.073(3) Uani 1 1 d . . .
H24A H -0.2216 0.2393 0.1399 0.110 Uiso 1 1 calc R . .
H24B H -0.3348 0.2795 0.2056 0.110 Uiso 1 1 calc R . .
H24C H -0.3415 0.1520 0.1752 0.110 Uiso 1 1 calc R . .
H1WA H 0.791(13) 0.398(7) 0.343(3) 0.10(4) Uiso 1 1 d D . .
H1WB H 0.659(9) 0.457(17) 0.386(13) 0.35(12) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Eu1 O9 79.17(15) . . ?
O7 Eu1 O8 80.58(15) . . ?
O9 Eu1 O8 78.74(15) . . ?
O7 Eu1 O1 150.43(15) . . ?
O9 Eu1 O1 92.38(16) . . ?
O8 Eu1 O1 125.87(14) . . ?
O7 Eu1 O5 83.80(15) . . ?
O9 Eu1 O5 125.88(14) . . ?
O8 Eu1 O5 147.49(15) . . ?
O1 Eu1 O5 78.36(15) . . ?
O7 Eu1 O4 123.75(15) . 1_545 ?
O9 Eu1 O4 142.80(15) . 1_545 ?
O8 Eu1 O4 77.29(15) . 1_545 ?
O1 Eu1 O4 79.34(15) . 1_545 ?
O5 Eu1 O4 88.21(14) . 1_545 ?
O7 Eu1 O6 74.97(15) . . ?
O9 Eu1 O6 73.90(14) . . ?
O8 Eu1 O6 146.08(15) . . ?
O1 Eu1 O6 75.45(15) . . ?
O5 Eu1 O6 52.08(14) . . ?
O4 Eu1 O6 136.20(14) 1_545 . ?
O7 Eu1 O3 72.18(15) . 1_545 ?
O9 Eu1 O3 143.17(16) . 1_545 ?
O8 Eu1 O3 74.22(15) . 1_545 ?
O1 Eu1 O3 123.74(16) . 1_545 ?
O5 Eu1 O3 73.90(15) . 1_545 ?
O4 Eu1 O3 52.23(14) 1_545 1_545 ?
O6 Eu1 O3 118.62(14) . 1_545 ?
O7 Eu1 O2 147.76(15) . . ?
O9 Eu1 O2 75.53(15) . . ?
O8 Eu1 O2 75.18(14) . . ?
O1 Eu1 O2 51.12(14) . . ?
O5 Eu1 O2 127.47(14) . . ?
O4 Eu1 O2 71.09(15) 1_545 . ?
O6 Eu1 O2 115.81(15) . . ?
O3 Eu1 O2 119.73(14) 1_545 . ?
O7 Eu1 C12 97.43(18) . 1_545 ?
O9 Eu1 C12 148.14(16) . 1_545 ?
O8 Eu1 C12 69.49(16) . 1_545 ?
O1 Eu1 C12 104.08(18) . 1_545 ?
O5 Eu1 C12 84.60(16) . 1_545 ?
O4 Eu1 C12 26.32(16) 1_545 1_545 ?
O6 Eu1 C12 136.31(16) . 1_545 ?
O3 Eu1 C12 26.67(16) 1_545 1_545 ?
O2 Eu1 C12 93.68(17) . 1_545 ?
O7 Eu1 C18 76.17(16) . . ?
O9 Eu1 C18 99.49(17) . . ?
O8 Eu1 C18 156.57(16) . . ?
O1 Eu1 C18 77.40(16) . . ?
O5 Eu1 C18 26.39(15) . . ?
O4 Eu1 C18 113.59(16) 1_545 . ?
O6 Eu1 C18 25.83(15) . . ?
O3 Eu1 C18 95.68(17) 1_545 . ?
O2 Eu1 C18 127.40(16) . . ?
C12 Eu1 C18 110.52(19) 1_545 . ?
O7 Eu1 C6 164.99(17) . . ?
O9 Eu1 C6 86.17(17) . . ?
O8 Eu1 C6 99.84(16) . . ?
O1 Eu1 C6 26.04(15) . . ?
O5 Eu1 C6 102.48(17) . . ?
O4 Eu1 C6 70.52(16) 1_545 . ?
O6 Eu1 C6 97.95(16) . . ?
O3 Eu1 C6 122.54(16) 1_545 . ?
O2 Eu1 C6 25.43(14) . . ?
C12 Eu1 C6 96.73(19) 1_545 . ?
C18 Eu1 C6 103.36(17) . . ?
C6 O1 Eu1 96.2(4) . . ?
H1WA O1W H1WB 115(10) . . ?
C6 O2 Eu1 88.9(4) . . ?
C12 O3 Eu1 88.6(4) . 1_565 ?
C12 O4 Eu1 93.3(4) . 1_565 ?
C18 O5 Eu1 94.3(3) . . ?
C18 O6 Eu1 91.3(4) . . ?
S4 O7 Eu1 132.8(3) . . ?
S6 O8 Eu1 130.6(3) . . ?
S5 O9 Eu1 130.0(3) . . ?
C1 S1 S1 95.3(2) . 2 ?
C13 S2 S3 103.9(2) . . ?
C7 S3 S2 103.0(2) . . ?
O7 S4 C20 104.9(3) . . ?
O7 S4 C19 104.7(3) . . ?
C20 S4 C19 97.7(4) . . ?
O9 S5 C22 106.7(3) . . ?
O9 S5 C21 104.7(4) . . ?
C22 S5 C21 97.8(4) . . ?
O8 S6 C24 105.8(3) . . ?
O8 S6 C23 103.2(3) . . ?
C24 S6 C23 97.4(4) . . ?
C5 N1 C1 117.7(6) . . ?
C13 N2 C17 117.3(5) . . ?
C7 N3 C11 117.3(6) . . ?
N1 C1 C2 122.4(6) . . ?
N1 C1 S1 117.3(5) . . ?
C2 C1 S1 120.3(5) . . ?
C3 C2 C1 117.0(6) . . ?
C3 C2 C6 119.4(6) . . ?
C1 C2 C6 123.5(6) . . ?
C2 C3 C4 121.4(6) . . ?
C2 C3 H3 119.3 . . ?
C4 C3 H3 119.3 . . ?
C5 C4 C3 116.2(7) . . ?
C5 C4 H4 121.9 . . ?
C3 C4 H4 121.9 . . ?
N1 C5 C4 125.2(7) . . ?
N1 C5 H5 117.4 . . ?
C4 C5 H5 117.4 . . ?
O2 C6 O1 122.2(6) . . ?
O2 C6 C2 120.6(5) . . ?
O1 C6 C2 117.2(6) . . ?
O2 C6 Eu1 65.7(3) . . ?
O1 C6 Eu1 57.8(3) . . ?
C2 C6 Eu1 165.2(5) . . ?
N3 C7 C8 122.2(6) . . ?
N3 C7 S3 117.5(5) . . ?
C8 C7 S3 120.3(5) . . ?
C9 C8 C7 118.2(6) . . ?
C9 C8 C12 118.8(6) . . ?
C7 C8 C12 123.0(6) . . ?
C10 C9 C8 120.4(7) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C9 C10 C11 116.7(8) . . ?
C9 C10 H10 121.7 . . ?
C11 C10 H10 121.7 . . ?
N3 C11 C10 125.2(8) . . ?
N3 C11 H11 117.4 . . ?
C10 C11 H11 117.4 . . ?
O4 C12 O3 122.3(6) . . ?
O4 C12 C8 118.8(6) . . ?
O3 C12 C8 118.6(6) . . ?
O4 C12 Eu1 60.4(3) . 1_565 ?
O3 C12 Eu1 64.7(3) . 1_565 ?
C8 C12 Eu1 157.2(4) . 1_565 ?
N2 C13 C14 122.8(6) . . ?
N2 C13 S2 117.6(4) . . ?
C14 C13 S2 119.6(4) . . ?
C13 C14 C15 118.0(5) . . ?
C13 C14 C18 123.4(5) . . ?
C15 C14 C18 118.5(5) . . ?
C16 C15 C14 118.9(6) . . ?
C16 C15 H15 120.5 . . ?
C14 C15 H15 120.5 . . ?
C17 C16 C15 119.0(6) . . ?
C17 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
C16 C17 N2 123.7(6) . . ?
C16 C17 H17 118.2 . . ?
N2 C17 H17 118.2 . . ?
O6 C18 O5 121.6(5) . . ?
O6 C18 C14 119.2(5) . . ?
O5 C18 C14 119.2(5) . . ?
O6 C18 Eu1 62.8(3) . . ?
O5 C18 Eu1 59.3(3) . . ?
C14 C18 Eu1 171.8(4) . . ?
S4 C19 H19A 109.5 . . ?
S4 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
S4 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
S4 C20 H20A 109.5 . . ?
S4 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
S4 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
S5 C21 H21A 109.5 . . ?
S5 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
S5 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
S5 C22 H22A 109.5 . . ?
S5 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
S5 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
S6 C23 H23A 109.5 . . ?
S6 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
S6 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
S6 C24 H24A 109.5 . . ?
S6 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
S6 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O7 2.359(4) . ?
Eu1 O9 2.388(4) . ?
Eu1 O8 2.391(4) . ?
Eu1 O1 2.426(5) . ?
Eu1 O5 2.452(4) . ?
Eu1 O4 2.459(4) 1_545 ?
Eu1 O6 2.529(4) . ?
Eu1 O3 2.555(5) 1_545 ?
Eu1 O2 2.598(4) . ?
Eu1 C12 2.824(6) 1_545 ?
Eu1 C18 2.842(6) . ?
Eu1 C6 2.851(6) . ?
O1 C6 1.259(7) . ?
O1W H1WA 0.889(10) . ?
O1W H1WB 0.892(10) . ?
O2 C6 1.224(7) . ?
O3 C12 1.268(7) . ?
O3 Eu1 2.555(5) 1_565 ?
O4 C12 1.254(8) . ?
O4 Eu1 2.459(4) 1_565 ?
O5 C18 1.267(7) . ?
O6 C18 1.239(7) . ?
O7 S4 1.533(5) . ?
O8 S6 1.521(4) . ?
O9 S5 1.510(5) . ?
S1 C1 1.776(6) . ?
S1 S1 2.117(3) 2 ?
S2 C13 1.781(6) . ?
S2 S3 2.042(2) . ?
S3 C7 1.775(7) . ?
S4 C20 1.757(7) . ?
S4 C19 1.795(7) . ?
S5 C22 1.775(8) . ?
S5 C21 1.809(9) . ?
S6 C24 1.786(8) . ?
S6 C23 1.808(7) . ?
N1 C5 1.323(8) . ?
N1 C1 1.337(8) . ?
N2 C13 1.329(7) . ?
N2 C17 1.369(8) . ?
N3 C7 1.341(8) . ?
N3 C11 1.343(10) . ?
C1 C2 1.424(8) . ?
C2 C3 1.358(8) . ?
C2 C6 1.515(9) . ?
C3 C4 1.400(10) . ?
C3 H3 0.9300 . ?
C4 C5 1.370(9) . ?
C4 H4 0.9300 . ?
C5 H5 0.9300 . ?
C7 C8 1.404(8) . ?
C8 C9 1.396(9) . ?
C8 C12 1.500(9) . ?
C9 C10 1.377(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.382(12) . ?
C10 H10 0.9300 . ?
C11 H11 0.9300 . ?
C12 Eu1 2.824(6) 1_565 ?
C13 C14 1.392(8) . ?
C14 C15 1.417(8) . ?
C14 C18 1.499(8) . ?
C15 C16 1.371(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.353(9) . ?
C16 H16 0.9300 . ?
C17 H17 0.9300 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
