#------------------------------------------------------------------------------
#$Date: 2022-05-06 17:46:44 +0300 (Fri, 06 May 2022) $
#$Revision: 275106 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/20/28/7202877.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7202877
loop_
_publ_author_name
'Beves, Jonathon E.'
'Constable, Edwin C.'
'Housecroft, Catherine E.'
'Kepert, Cameron J.'
'Price, David J.'
_publ_section_title
;
 The first example of a coordination polymer from the expanded
 4,4'-bipyridine ligand [Ru(pytpy)₂]²⁺(pytpy =
 4'-(4-pyridyl)-2,2':6',2''-terpyridine)
;
_journal_coden_ASTM              CRECF4
_journal_issue                   6
_journal_name_full               CrystEngComm
_journal_page_first              456
_journal_page_last               459
_journal_paper_doi               10.1039/b703622a
_journal_volume                  9
_journal_year                    2007
_chemical_formula_sum            'C44 H36 Ag N13 O10 Ru'
_chemical_formula_weight         1115.80
_chemical_name_common            '[Ru(tpypy)2Ag(NO3)(MeCN)](NO3)2.H2O.MeCN'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.847(6)
_cell_angle_beta                 100.776(6)
_cell_angle_gamma                102.133(6)
_cell_formula_units_Z            2
_cell_length_a                   8.827(3)
_cell_length_b                   11.675(4)
_cell_length_c                   21.160(7)
_cell_measurement_reflns_used    966
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.907
_cell_measurement_theta_min      2.457
_cell_volume                     2065.6(12)
_computing_cell_refinement       'SMART (BrukerAXS, 1997)'
_computing_data_collection       'SMART (BrukerAXS, 1997)'
_computing_data_reduction        'SAINT+ (BrukerAXS, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.954
_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0252
_diffrn_reflns_av_sigmaI/netI    0.0427
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            20550
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.07
_diffrn_reflns_theta_min         0.99
_diffrn_standards_decay_%        0.00
_diffrn_standards_number         166
_exptl_absorpt_coefficient_mu    0.921
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.852750
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker 1995'
_exptl_crystal_colour            'deep red'
_exptl_crystal_density_diffrn    1.794
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1124
_exptl_crystal_size_max          0.286
_exptl_crystal_size_mid          0.254
_exptl_crystal_size_min          0.024
_refine_diff_density_max         1.454
_refine_diff_density_min         -3.626
_refine_diff_density_rms         0.142
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     610
_refine_ls_number_reflns         9540
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0622
_refine_ls_R_factor_gt           0.0465
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0738P)²+6.1178P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1289
_refine_ls_wR_factor_ref         0.1399
_reflns_number_gt                7552
_reflns_number_total             9540
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b703622a.txt
_cod_data_source_block           jb568aab
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2065.7(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7202877
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.24597(4) 0.01611(3) -0.329441(16) 0.02720(11) Uani 1 1 d . . .
Ru1 Ru 0.14049(4) 0.39731(3) 0.206430(15) 0.01418(9) Uani 1 1 d . . .
O1 O -0.4481(4) 0.1509(3) -0.34808(18) 0.0384(8) Uani 1 1 d . . .
O2 O -0.6438(4) 0.1648(3) -0.30077(18) 0.0351(8) Uani 1 1 d . . .
O3 O -0.5262(4) 0.0209(3) -0.28895(18) 0.0358(8) Uani 1 1 d . . .
O5 O -0.5811(9) -0.1413(6) -0.0306(4) 0.100 Uiso 1 1 d . . .
O6 O -0.3139(5) -0.1156(4) -0.0176(2) 0.0512(10) Uiso 1 1 d D . .
O7 O 0.0342(7) 0.7146(4) 0.5053(2) 0.0620(13) Uani 1 1 d . . .
O8 O 0.0665(7) 0.8449(4) 0.5905(2) 0.0686(15) Uani 1 1 d . . .
O9 O 0.0345(8) 0.6615(4) 0.5983(2) 0.0804(18) Uani 1 1 d . . .
O10 O 0.8001(5) 0.5055(4) 0.4556(2) 0.0513(11) Uani 1 1 d . . .
O4 O -0.4559(17) 0.0346(13) -0.0338(7) 0.213(5) Uiso 1 1 d . . .
N1 N 0.3519(4) 0.3435(3) 0.22781(16) 0.0163(6) Uani 1 1 d . . .
N2 N 0.2218(4) 0.4725(3) 0.29902(16) 0.0156(6) Uani 1 1 d . . .
N3 N -0.0414(4) 0.4764(3) 0.22411(16) 0.0171(7) Uani 1 1 d . . .
N4 N 0.6177(5) 0.8653(3) 0.59111(18) 0.0255(8) Uani 1 1 d . . .
N5 N 0.2442(4) 0.5396(3) 0.16611(16) 0.0163(6) Uani 1 1 d . . .
N6 N 0.0721(4) 0.3304(3) 0.11242(16) 0.0160(6) Uani 1 1 d . . .
N7 N 0.0082(4) 0.2287(3) 0.20881(16) 0.0166(7) Uani 1 1 d . . .
N8 N -0.1434(4) 0.0886(3) -0.22342(18) 0.0227(7) Uani 1 1 d . . .
N9 N -0.0498(5) 0.1170(4) -0.3817(2) 0.0376(10) Uani 1 1 d . . .
N10 N -0.5411(4) 0.1117(3) -0.31277(18) 0.0241(8) Uani 1 1 d . . .
N11 N -0.4179(15) -0.0677(11) -0.0176(6) 0.147(4) Uiso 1 1 d D . .
N12 N 0.0490(5) 0.7415(4) 0.5655(2) 0.0333(9) Uani 1 1 d . . .
C1 C 0.4079(5) 0.2697(4) 0.1897(2) 0.0202(8) Uani 1 1 d . . .
H1 H 0.3541 0.2444 0.1453 0.024 Uiso 1 1 calc R . .
C2 C 0.5414(5) 0.2291(4) 0.2125(2) 0.0255(9) Uani 1 1 d . . .
H2 H 0.5782 0.1770 0.1842 0.031 Uiso 1 1 calc R . .
C3 C 0.6198(5) 0.2653(4) 0.2769(2) 0.0263(9) Uani 1 1 d . . .
H3 H 0.7088 0.2359 0.2939 0.032 Uiso 1 1 calc R . .
C4 C 0.5677(5) 0.3450(4) 0.3164(2) 0.0227(9) Uani 1 1 d . . .
H4 H 0.6228 0.3730 0.3604 0.027 Uiso 1 1 calc R . .
C5 C 0.4342(5) 0.3834(3) 0.29106(19) 0.0172(8) Uani 1 1 d . . .
C6 C 0.3683(5) 0.4668(3) 0.32963(19) 0.0167(8) Uani 1 1 d . . .
C7 C 0.4451(5) 0.5386(4) 0.38890(19) 0.0187(8) Uani 1 1 d . . .
H7 H 0.5495 0.5357 0.4092 0.022 Uiso 1 1 calc R . .
C8 C 0.3662(5) 0.6153(4) 0.41831(19) 0.0191(8) Uani 1 1 d . . .
C9 C 0.4500(5) 0.6998(4) 0.4790(2) 0.0205(8) Uani 1 1 d . . .
C10 C 0.5826(5) 0.6812(4) 0.5199(2) 0.0226(9) Uani 1 1 d . . .
H10 H 0.6183 0.6111 0.5105 0.027 Uiso 1 1 calc R . .
C11 C 0.6623(5) 0.7648(4) 0.5742(2) 0.0253(9) Uani 1 1 d . . .
H11 H 0.7532 0.7505 0.6010 0.030 Uiso 1 1 calc R . .
C12 C 0.4876(6) 0.8819(4) 0.5520(2) 0.0326(11) Uani 1 1 d . . .
H12 H 0.4529 0.9518 0.5632 0.039 Uiso 1 1 calc R . .
C13 C 0.4020(6) 0.8035(4) 0.4967(2) 0.0307(10) Uani 1 1 d . . .
H13 H 0.3112 0.8198 0.4709 0.037 Uiso 1 1 calc R . .
C14 C 0.2103(5) 0.6149(4) 0.3875(2) 0.0196(8) Uani 1 1 d . . .
H14 H 0.1525 0.6631 0.4077 0.023 Uiso 1 1 calc R . .
C15 C 0.1418(5) 0.5438(3) 0.3275(2) 0.0180(8) Uani 1 1 d . . .
C16 C -0.0135(5) 0.5392(3) 0.2858(2) 0.0174(8) Uani 1 1 d . . .
C17 C -0.1239(5) 0.5956(4) 0.3056(2) 0.0228(9) Uani 1 1 d . . .
H17 H -0.1040 0.6366 0.3490 0.027 Uiso 1 1 calc R . .
C18 C -0.2636(5) 0.5920(4) 0.2619(3) 0.0285(10) Uani 1 1 d . . .
H18 H -0.3393 0.6317 0.2746 0.034 Uiso 1 1 calc R . .
C19 C -0.2909(5) 0.5300(4) 0.1996(2) 0.0266(9) Uani 1 1 d . . .
H19 H -0.3855 0.5268 0.1687 0.032 Uiso 1 1 calc R . .
C20 C -0.1782(5) 0.4719(4) 0.1824(2) 0.0215(8) Uani 1 1 d . . .
H20 H -0.1988 0.4276 0.1398 0.026 Uiso 1 1 calc R . .
C21 C 0.3331(5) 0.6461(4) 0.1970(2) 0.0199(8) Uani 1 1 d . . .
H21 H 0.3520 0.6626 0.2432 0.024 Uiso 1 1 calc R . .
C22 C 0.3985(5) 0.7331(4) 0.1643(2) 0.0249(9) Uani 1 1 d . . .
H22 H 0.4621 0.8073 0.1878 0.030 Uiso 1 1 calc R . .
C23 C 0.3703(6) 0.7107(4) 0.0965(2) 0.0288(10) Uani 1 1 d . . .
H23 H 0.4145 0.7691 0.0731 0.035 Uiso 1 1 calc R . .
C24 C 0.2763(5) 0.6013(4) 0.0637(2) 0.0233(9) Uani 1 1 d . . .
H24 H 0.2535 0.5843 0.0174 0.028 Uiso 1 1 calc R . .
C25 C 0.2160(4) 0.5171(3) 0.09929(19) 0.0158(7) Uani 1 1 d . . .
C26 C 0.1210(5) 0.3968(3) 0.06860(19) 0.0171(8) Uani 1 1 d . . .
C27 C 0.0839(5) 0.3495(4) 0.0030(2) 0.0192(8) Uani 1 1 d . . .
H27 H 0.1169 0.3969 -0.0277 0.023 Uiso 1 1 calc R . .
C28 C -0.0028(5) 0.2313(4) -0.0182(2) 0.0194(8) Uani 1 1 d . . .
C29 C -0.0448(5) 0.1800(3) -0.08864(19) 0.0179(8) Uani 1 1 d . . .
C30 C 0.0297(5) 0.2317(4) -0.1342(2) 0.0230(9) Uani 1 1 d . . .
H30 H 0.1162 0.2995 -0.1203 0.028 Uiso 1 1 calc R . .
C31 C -0.0220(5) 0.1845(4) -0.2000(2) 0.0245(9) Uani 1 1 d . . .
H31 H 0.0308 0.2217 -0.2301 0.029 Uiso 1 1 calc R . .
C32 C -0.2121(5) 0.0372(4) -0.1791(2) 0.0248(9) Uani 1 1 d . . .
H32 H -0.2969 -0.0315 -0.1944 0.030 Uiso 1 1 calc R . .
C33 C -0.1678(6) 0.0776(4) -0.1130(2) 0.0251(9) Uani 1 1 d . . .
H33 H -0.2201 0.0365 -0.0841 0.030 Uiso 1 1 calc R . .
C34 C -0.0519(5) 0.1653(4) 0.0283(2) 0.0191(8) Uani 1 1 d . . .
H34 H -0.1111 0.0852 0.0153 0.023 Uiso 1 1 calc R . .
C35 C -0.0143(4) 0.2166(3) 0.09338(19) 0.0163(7) Uani 1 1 d . . .
C36 C -0.0566(5) 0.1608(3) 0.14865(19) 0.0170(8) Uani 1 1 d . . .
C37 C -0.1566(5) 0.0489(4) 0.1408(2) 0.0206(8) Uani 1 1 d . . .
H37 H -0.2003 0.0035 0.0986 0.025 Uiso 1 1 calc R . .
C38 C -0.1922(5) 0.0042(4) 0.1958(2) 0.0219(8) Uani 1 1 d . . .
H38 H -0.2625 -0.0714 0.1915 0.026 Uiso 1 1 calc R . .
C39 C -0.1232(5) 0.0719(4) 0.2571(2) 0.0227(9) Uani 1 1 d . . .
H39 H -0.1438 0.0421 0.2953 0.027 Uiso 1 1 calc R . .
C40 C -0.0240(5) 0.1834(4) 0.26184(19) 0.0179(8) Uani 1 1 d . . .
H40 H 0.0227 0.2292 0.3038 0.021 Uiso 1 1 calc R . .
C41 C 0.0458(6) 0.1119(4) -0.4105(2) 0.0290(10) Uani 1 1 d . . .
C42 C 0.1687(6) 0.1032(6) -0.4473(3) 0.0407(13) Uani 1 1 d . . .
H42A H 0.2647 0.1656 -0.4273 0.061 Uiso 1 1 calc R . .
H42B H 0.1306 0.1131 -0.4924 0.061 Uiso 1 1 calc R . .
H42C H 0.1932 0.0252 -0.4470 0.061 Uiso 1 1 calc R . .
C44 C -0.3964(9) 0.5130(7) 0.0471(4) 0.068(2) Uani 1 1 d . . .
C430 C -0.400(2) 0.6061(15) 0.0236(9) 0.041(4) Uiso 0.356(16) 1 d P . .
C431 C -0.409(3) 0.6334(18) -0.0103(12) 0.115(6) Uiso 0.644(16) 1 d P . .
C450 C -0.507(3) 0.3706(19) 0.0656(10) 0.042(6) Uiso 0.356(16) 1 d P . .
C451 C -0.4728(13) 0.4044(10) 0.0417(6) 0.047(3) Uiso 0.644(16) 1 d P . .
C460 C -0.3909(19) 0.3189(13) 0.0593(7) 0.032(4) Uiso 0.356(16) 1 d P . .
C461 C -0.4713(17) 0.3500(12) 0.0595(6) 0.051(3) Uiso 0.644(16) 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N8 150.41(14) 1_444 . ?
N4 Ag1 N9 101.35(15) 1_444 . ?
N8 Ag1 N9 102.77(15) . . ?
N6 Ru1 N2 175.82(13) . . ?
N6 Ru1 N5 79.25(13) . . ?
N2 Ru1 N5 96.89(13) . . ?
N6 Ru1 N7 78.64(13) . . ?
N2 Ru1 N7 105.22(13) . . ?
N5 Ru1 N7 157.89(13) . . ?
N6 Ru1 N1 99.37(13) . . ?
N2 Ru1 N1 79.09(13) . . ?
N5 Ru1 N1 92.47(13) . . ?
N7 Ru1 N1 91.45(13) . . ?
N6 Ru1 N3 103.25(13) . . ?
N2 Ru1 N3 78.38(13) . . ?
N5 Ru1 N3 92.26(13) . . ?
N7 Ru1 N3 92.44(13) . . ?
N1 Ru1 N3 157.38(13) . . ?
N11 O5 O4 68.0(7) . 2_455 ?
N11 O4 O5 112.6(11) . 2_455 ?
N11 O4 N11 105.0(11) . 2_455 ?
O5 O4 N11 50.7(6) 2_455 2_455 ?
C1 N1 C5 118.3(3) . . ?
C1 N1 Ru1 128.2(3) . . ?
C5 N1 Ru1 113.3(2) . . ?
C6 N2 C15 120.6(3) . . ?
C6 N2 Ru1 119.0(3) . . ?
C15 N2 Ru1 119.6(3) . . ?
C20 N3 C16 118.5(3) . . ?
C20 N3 Ru1 127.3(3) . . ?
C16 N3 Ru1 114.1(3) . . ?
C11 N4 C12 116.4(4) . . ?
C11 N4 Ag1 126.1(3) . 1_666 ?
C12 N4 Ag1 117.1(3) . 1_666 ?
C21 N5 C25 118.3(3) . . ?
C21 N5 Ru1 128.3(3) . . ?
C25 N5 Ru1 113.5(3) . . ?
C26 N6 C35 121.2(3) . . ?
C26 N6 Ru1 119.1(3) . . ?
C35 N6 Ru1 119.6(3) . . ?
C40 N7 C36 118.5(3) . . ?
C40 N7 Ru1 127.3(3) . . ?
C36 N7 Ru1 114.2(3) . . ?
C32 N8 C31 116.3(4) . . ?
C32 N8 Ag1 118.3(3) . . ?
C31 N8 Ag1 125.2(3) . . ?
C41 N9 Ag1 148.4(4) . . ?
O2 N10 O3 120.7(4) . . ?
O2 N10 O1 120.3(4) . . ?
O3 N10 O1 119.1(4) . . ?
O6 N11 O4 138.8(14) . . ?
O6 N11 O5 118.3(11) . . ?
O4 N11 O5 97.2(10) . . ?
O6 N11 O4 139.1(13) . 2_455 ?
O4 N11 O4 75.0(11) . 2_455 ?
O5 N11 O4 61.2(7) . 2_455 ?
O8 N12 O9 120.5(5) . . ?
O8 N12 O7 120.5(5) . . ?
O9 N12 O7 118.8(5) . . ?
N1 C1 C2 122.5(4) . . ?
C3 C2 C1 119.0(4) . . ?
C2 C3 C4 119.4(4) . . ?
C3 C4 C5 119.2(4) . . ?
N1 C5 C4 121.5(4) . . ?
N1 C5 C6 115.3(3) . . ?
C4 C5 C6 123.2(4) . . ?
N2 C6 C7 121.3(4) . . ?
N2 C6 C5 112.3(3) . . ?
C7 C6 C5 126.3(4) . . ?
C6 C7 C8 118.9(4) . . ?
C7 C8 C14 118.9(4) . . ?
C7 C8 C9 120.1(4) . . ?
C14 C8 C9 121.0(4) . . ?
C10 C9 C13 116.9(4) . . ?
C10 C9 C8 121.6(4) . . ?
C13 C9 C8 121.4(4) . . ?
C11 C10 C9 120.0(4) . . ?
N4 C11 C10 123.4(4) . . ?
N4 C12 C13 123.9(4) . . ?
C12 C13 C9 119.4(4) . . ?
C15 C14 C8 119.4(4) . . ?
N2 C15 C14 120.7(4) . . ?
N2 C15 C16 112.2(3) . . ?
C14 C15 C16 127.0(4) . . ?
N3 C16 C17 121.3(4) . . ?
N3 C16 C15 115.0(3) . . ?
C17 C16 C15 123.6(4) . . ?
C16 C17 C18 119.7(4) . . ?
C19 C18 C17 119.0(4) . . ?
C18 C19 C20 119.2(4) . . ?
N3 C20 C19 122.2(4) . . ?
N5 C21 C22 122.6(4) . . ?
C21 C22 C23 119.3(4) . . ?
C24 C23 C22 118.7(4) . . ?
C25 C24 C23 119.3(4) . . ?
N5 C25 C24 121.8(4) . . ?
N5 C25 C26 115.3(3) . . ?
C24 C25 C26 122.9(4) . . ?
N6 C26 C27 120.3(4) . . ?
N6 C26 C25 112.8(3) . . ?
C27 C26 C25 126.9(4) . . ?
C26 C27 C28 119.9(4) . . ?
C34 C28 C27 118.3(4) . . ?
C34 C28 C29 121.4(4) . . ?
C27 C28 C29 120.4(4) . . ?
C30 C29 C33 116.3(4) . . ?
C30 C29 C28 122.7(4) . . ?
C33 C29 C28 120.9(4) . . ?
C31 C30 C29 120.2(4) . . ?
N8 C31 C30 123.3(4) . . ?
N8 C32 C33 124.2(4) . . ?
C32 C33 C29 119.6(4) . . ?
C35 C34 C28 120.0(4) . . ?
N6 C35 C34 120.3(4) . . ?
N6 C35 C36 112.4(3) . . ?
C34 C35 C36 127.3(4) . . ?
N7 C36 C37 122.0(4) . . ?
N7 C36 C35 114.9(3) . . ?
C37 C36 C35 123.1(4) . . ?
C36 C37 C38 119.0(4) . . ?
C39 C38 C37 119.0(4) . . ?
C40 C39 C38 119.3(4) . . ?
N7 C40 C39 122.1(4) . . ?
N9 C41 C42 179.0(6) . . ?
C430 C44 C451 142.6(12) . . ?
C430 C44 C450 148.7(12) . . ?
C451 C44 C450 17.3(8) . . ?
C430 C44 C461 157.3(11) . . ?
C451 C44 C461 14.9(6) . . ?
C450 C44 C461 13.6(7) . . ?
C430 C44 C431 14.2(10) . . ?
C451 C44 C431 132.8(9) . . ?
C450 C44 C431 144.1(10) . . ?
C461 C44 C431 147.6(9) . . ?
C431 C430 C44 144(3) . . ?
C431 C430 C451 40.4(19) . 2_465 ?
C44 C430 C451 117.2(13) . 2_465 ?
C431 C430 C450 20.4(19) . 2_465 ?
C44 C430 C450 130.7(14) . 2_465 ?
C451 C430 C450 20.3(7) 2_465 2_465 ?
C430 C431 C451 111(3) . 2_465 ?
C430 C431 C450 147(3) . 2_465 ?
C451 C431 C450 36.2(12) 2_465 2_465 ?
C430 C431 C461 139(3) . 2_465 ?
C451 C431 C461 33.5(10) 2_465 2_465 ?
C450 C431 C461 18.9(11) 2_465 2_465 ?
C430 C431 C44 22.0(17) . . ?
C451 C431 C44 100.6(16) 2_465 . ?
C450 C431 C44 131.9(18) 2_465 . ?
C461 C431 C44 133.7(15) 2_465 . ?
C451 C450 C431 60.3(19) . 2_465 ?
C451 C450 C460 80(2) . . ?
C431 C450 C460 109(2) 2_465 . ?
C451 C450 C44 31.0(15) . . ?
C431 C450 C44 82.3(16) 2_465 . ?
C460 C450 C44 92.2(14) . . ?
C451 C450 C430 47.5(17) . 2_465 ?
C431 C450 C430 13.1(12) 2_465 2_465 ?
C460 C450 C430 105.7(15) . 2_465 ?
C44 C450 C430 69.6(9) . 2_465 ?
C450 C451 C461 35.1(19) . . ?
C450 C451 C431 83(2) . 2_465 ?
C461 C451 C431 95(2) . 2_465 ?
C450 C451 C44 132(2) . . ?
C461 C451 C44 139.8(16) . . ?
C431 C451 C44 123.8(17) 2_465 . ?
C450 C451 C460 68(2) . . ?
C461 C451 C460 33.5(14) . . ?
C431 C451 C460 113.5(16) 2_465 . ?
C44 C451 C460 119.8(11) . . ?
C450 C451 C430 112(2) . 2_465 ?
C461 C451 C430 120.5(16) . 2_465 ?
C431 C451 C430 28.9(13) 2_465 2_465 ?
C44 C451 C430 99.7(10) . 2_465 ?
C460 C451 C430 126.5(11) . 2_465 ?
C461 C460 C450 5.6(16) . . ?
C461 C460 C451 29.8(12) . . ?
C450 C460 C451 31.8(10) . . ?
C451 C461 C460 117(2) . . ?
C451 C461 C431 51.3(14) . 2_465 ?
C460 C461 C431 134(2) . 2_465 ?
C451 C461 C44 25.3(11) . . ?
C460 C461 C44 104.9(15) . . ?
C431 C461 C44 76.0(11) 2_465 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.241(4) 1_444 ?
Ag1 N8 2.244(4) . ?
Ag1 N9 2.404(4) . ?
Ru1 N6 1.978(3) . ?
Ru1 N2 1.981(3) . ?
Ru1 N5 2.078(3) . ?
Ru1 N7 2.079(3) . ?
Ru1 N1 2.080(3) . ?
Ru1 N3 2.083(3) . ?
O1 N10 1.263(5) . ?
O2 N10 1.247(5) . ?
O3 N10 1.248(5) . ?
O5 N11 1.471(13) . ?
O5 O4 1.665(15) 2_455 ?
O6 N11 1.171(11) . ?
O7 N12 1.251(6) . ?
O8 N12 1.225(6) . ?
O9 N12 1.228(6) . ?
O4 N11 1.371(15) . ?
O4 O5 1.665(15) 2_455 ?
O4 N11 1.762(15) 2_455 ?
N1 C1 1.342(5) . ?
N1 C5 1.372(5) . ?
N2 C6 1.352(5) . ?
N2 C15 1.357(5) . ?
N3 C20 1.343(5) . ?
N3 C16 1.370(5) . ?
N4 C11 1.344(6) . ?
N4 C12 1.348(6) . ?
N4 Ag1 2.241(4) 1_666 ?
N5 C21 1.339(5) . ?
N5 C25 1.372(5) . ?
N6 C26 1.352(5) . ?
N6 C35 1.357(5) . ?
N7 C40 1.348(5) . ?
N7 C36 1.369(5) . ?
N8 C32 1.341(6) . ?
N8 C31 1.346(6) . ?
N9 C41 1.136(6) . ?
N11 O4 1.762(15) 2_455 ?
C1 C2 1.387(6) . ?
C2 C3 1.378(7) . ?
C3 C4 1.384(6) . ?
C4 C5 1.386(6) . ?
C5 C6 1.476(5) . ?
C6 C7 1.388(6) . ?
C7 C8 1.402(6) . ?
C8 C14 1.408(6) . ?
C8 C9 1.485(6) . ?
C9 C10 1.392(6) . ?
C9 C13 1.397(6) . ?
C10 C11 1.382(6) . ?
C12 C13 1.379(6) . ?
C14 C15 1.385(6) . ?
C15 C16 1.472(6) . ?
C16 C17 1.384(6) . ?
C17 C18 1.386(6) . ?
C18 C19 1.379(7) . ?
C19 C20 1.394(6) . ?
C21 C22 1.385(6) . ?
C22 C23 1.391(7) . ?
C23 C24 1.390(6) . ?
C24 C25 1.386(6) . ?
C25 C26 1.477(5) . ?
C26 C27 1.382(6) . ?
C27 C28 1.404(6) . ?
C28 C34 1.397(6) . ?
C28 C29 1.484(6) . ?
C29 C30 1.392(6) . ?
C29 C33 1.404(6) . ?
C30 C31 1.387(6) . ?
C32 C33 1.376(6) . ?
C34 C35 1.383(6) . ?
C35 C36 1.475(5) . ?
C36 C37 1.386(6) . ?
C37 C38 1.391(6) . ?
C38 C39 1.391(6) . ?
C39 C40 1.389(6) . ?
C41 C42 1.462(7) . ?
C44 C430 1.251(19) . ?
C44 C451 1.286(13) . ?
C44 C450 1.87(2) . ?
C44 C461 1.945(16) . ?
C44 C431 1.97(2) . ?
C430 C431 0.82(2) . ?
C430 C451 1.58(2) 2_465 ?
C430 C450 1.99(3) 2_465 ?
C431 C451 1.10(2) 2_465 ?
C431 C450 1.25(3) 2_465 ?
C431 C461 1.40(3) 2_465 ?
C450 C451 0.75(2) . ?
C450 C431 1.25(3) 2_465 ?
C450 C460 1.31(3) . ?
C450 C430 1.99(3) 2_465 ?
C451 C461 0.776(15) . ?
C451 C431 1.10(2) 2_465 ?
C451 C460 1.395(19) . ?
C451 C430 1.58(2) 2_465 ?
C460 C461 0.863(16) . ?
C461 C431 1.40(3) 2_465 ?
loop_
_cod_changelog_entry_id
_cod_changelog_entry_author
_cod_changelog_entry_date
_cod_changelog_entry_text
1 'Vaitkus, Antanas' 2022-05-06T17:40:00+03:00
'Updated bibliographic information.'
