#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:09:43 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180378 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/47/7204753.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7204753
loop_
_publ_author_name
'Afzaal, Mohammad'
'Crouch, David J.'
'O'Brien, Paul'
'Raftery, James'
'Skabara, Peter J.'
'White, Andrew J. P.'
'Williams, David J.'
_publ_section_title
;
 The synthesis, X-ray structures and CVD studies of some group 11
 complexes of iminobis(diisopropylphosphine selenides) and their use in
 the deposition of I/III/VI photovoltaic materials
;
_journal_issue                   2
_journal_name_full               'Journal of Materials Chemistry'
_journal_page_first              233
_journal_paper_doi               10.1039/b311743j
_journal_volume                  14
_journal_year                    2004
_chemical_formula_sum            'C36 H84 Ag3 N3 P6 Se6'
_chemical_formula_weight         1542.25
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                114.918(4)
_cell_angle_beta                 92.242(6)
_cell_angle_gamma                115.042(5)
_cell_formula_units_Z            2
_cell_length_a                   14.0717(11)
_cell_length_b                   14.7803(8)
_cell_length_c                   17.3186(12)
_cell_measurement_reflns_used    27
_cell_measurement_temperature    183(2)
_cell_measurement_theta_max      12.50
_cell_measurement_theta_min      5.11
_cell_volume                     2854.1(4)
_computing_cell_refinement       'Siemens XSCANS'
_computing_data_collection       'Siemens XSCANS'
_computing_data_reduction        'Siemens SHELXTL'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      183(2)
_diffrn_measurement_device       'Siemens P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_sigmaI/netI    0.0541
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            8289
_diffrn_reflns_theta_max         23.50
_diffrn_reflns_theta_min         1.84
_diffrn_standards_decay_%        7.70
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.040
_exptl_absorpt_correction_T_max  0.8526
_exptl_absorpt_correction_T_min  0.5397
_exptl_absorpt_correction_type   Ellipsoidal
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.795
_exptl_crystal_description       'platy prisms'
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.767
_refine_diff_density_min         -0.589
_refine_diff_density_rms         0.112
_refine_ls_extinction_coef       0.00074(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.009
_refine_ls_goodness_of_fit_obs   1.061
_refine_ls_matrix_type           full
_refine_ls_number_parameters     488
_refine_ls_number_reflns         7393
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.109
_refine_ls_restrained_S_obs      1.061
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_obs          0.0382
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0387P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0922
_refine_ls_wR_factor_obs         0.0763
_reflns_number_observed          6030
_reflns_number_total             7910
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b311743j.txt
_cod_data_source_block           POB0211
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2854.1(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7204753
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Ag1 Ag 0.11566(5) 0.50228(5) 0.22236(4) 0.03130(15) Uani 1 d . .
Ag2 Ag 0.39036(5) 0.54041(5) 0.20627(4) 0.03166(15) Uani 1 d . .
Ag3 Ag 0.16328(4) 0.23246(5) 0.18273(4) 0.03000(15) Uani 1 d . .
Se1 Se 0.09067(6) 0.65400(7) 0.34905(5) 0.0324(2) Uani 1 d . .
P1 P 0.24496(15) 0.8006(2) 0.37371(12) 0.0266(4) Uani 1 d . .
N1 N 0.2962(5) 0.8038(5) 0.2935(4) 0.0301(14) Uani 1 d . .
P2 P 0.28143(15) 0.7387(2) 0.19097(12) 0.0256(4) Uani 1 d . .
Se2 Se 0.24541(6) 0.55917(6) 0.12797(4) 0.0261(2) Uani 1 d . .
Se3 Se 0.57597(6) 0.66576(7) 0.31884(5) 0.0340(2) Uani 1 d . .
P3 P 0.64850(13) 0.5587(2) 0.25799(11) 0.0217(4) Uani 1 d . .
N2 N 0.5834(5) 0.4257(5) 0.2288(4) 0.0263(13) Uani 1 d . .
P4 P 0.46428(14) 0.3243(2) 0.20303(12) 0.0245(4) Uani 1 d . .
Se4 Se 0.33119(5) 0.32307(6) 0.13020(5) 0.0248(2) Uani 1 d . .
Se5 Se 0.13021(6) 0.10250(7) 0.25156(6) 0.0376(2) Uani 1 d . .
P5 P -0.04192(14) 0.0462(2) 0.23775(12) 0.0225(4) Uani 1 d . .
N3 N -0.0846(5) 0.1346(5) 0.2561(4) 0.0259(13) Uani 1 d . .
P6 P -0.06265(14) 0.2497(2) 0.25672(12) 0.0234(4) Uani 1 d . .
Se6 Se 0.01262(5) 0.28273(6) 0.15508(4) 0.0236(2) Uani 1 d . .
C1 C 0.3484(6) 0.8191(7) 0.4550(5) 0.034(2) Uani 1 d . .
H1A H 0.4181(6) 0.8865(7) 0.4650(5) 0.041 Uiso 1 calc R .
C2 C 0.3670(8) 0.7175(9) 0.4195(6) 0.054(2) Uani 1 d . .
H2A H 0.3830(8) 0.7030(9) 0.3622(6) 0.081 Uiso 1 calc R .
H2B H 0.3015(8) 0.6505(9) 0.4123(6) 0.081 Uiso 1 calc R .
H2C H 0.4285(8) 0.7331(9) 0.4609(6) 0.081 Uiso 1 calc R .
C3 C 0.3230(9) 0.8443(10) 0.5451(6) 0.064(3) Uani 1 d . .
H3A H 0.3112(9) 0.9106(10) 0.5670(6) 0.096 Uiso 1 calc R .
H3B H 0.3843(9) 0.8605(10) 0.5871(6) 0.096 Uiso 1 calc R .
H3C H 0.2574(9) 0.7779(10) 0.5385(6) 0.096 Uiso 1 calc R .
C4 C 0.2288(6) 0.9287(7) 0.4281(5) 0.038(2) Uani 1 d . .
H4A H 0.1973(6) 0.9273(7) 0.4786(5) 0.045 Uiso 1 calc R .
C5 C 0.3363(8) 1.0380(8) 0.4642(8) 0.071(3) Uani 1 d . .
H5A H 0.3866(8) 1.0389(8) 0.5057(8) 0.106 Uiso 1 calc R .
H5B H 0.3244(8) 1.1036(8) 0.4949(8) 0.106 Uiso 1 calc R .
H5C H 0.3675(8) 1.0423(8) 0.4154(8) 0.106 Uiso 1 calc R .
C6 C 0.1486(7) 0.9253(8) 0.3629(6) 0.049(2) Uani 1 d . .
H6A H 0.0796(7) 0.8542(8) 0.3403(6) 0.074 Uiso 1 calc R .
H6B H 0.1790(7) 0.9291(8) 0.3138(6) 0.074 Uiso 1 calc R .
H6C H 0.1359(7) 0.9904(8) 0.3932(6) 0.074 Uiso 1 calc R .
C7 C 0.4086(7) 0.8227(8) 0.1723(6) 0.045(2) Uani 1 d . .
H7A H 0.4008(7) 0.7869(8) 0.1072(6) 0.054 Uiso 1 calc R .
C8 C 0.5014(8) 0.8235(9) 0.2146(8) 0.068(3) Uani 1 d . .
H8A H 0.4867(8) 0.7448(9) 0.1935(8) 0.102 Uiso 1 calc R .
H8B H 0.5127(8) 0.8613(9) 0.2787(8) 0.102 Uiso 1 calc R .
H8C H 0.5668(8) 0.8648(9) 0.1997(8) 0.102 Uiso 1 calc R .
C9 C 0.4306(8) 0.9461(8) 0.2049(7) 0.064(3) Uani 1 d . .
H9A H 0.3681(8) 0.9448(8) 0.1764(7) 0.096 Uiso 1 calc R .
H9B H 0.4958(8) 0.9877(8) 0.1901(7) 0.096 Uiso 1 calc R .
H9C H 0.4417(8) 0.9842(8) 0.2691(7) 0.096 Uiso 1 calc R .
C10 C 0.1749(7) 0.7400(7) 0.1260(5) 0.037(2) Uani 1 d . .
H10A H 0.1870(7) 0.8200(7) 0.1556(5) 0.044 Uiso 1 calc R .
C11 C 0.1812(9) 0.7103(10) 0.0316(6) 0.060(3) Uani 1 d . .
H11A H 0.2548(9) 0.7597(10) 0.0319(6) 0.090 Uiso 1 calc R .
H11B H 0.1287(9) 0.7217(10) 0.0033(6) 0.090 Uiso 1 calc R .
H11C H 0.1643(9) 0.6304(10) -0.0013(6) 0.090 Uiso 1 calc R .
C12 C 0.0617(7) 0.6649(8) 0.1278(6) 0.047(2) Uani 1 d . .
H12A H 0.0594(7) 0.6854(8) 0.1891(6) 0.071 Uiso 1 calc R .
H12B H 0.0441(7) 0.5847(8) 0.0954(6) 0.071 Uiso 1 calc R .
H12C H 0.0086(7) 0.6760(8) 0.1000(6) 0.071 Uiso 1 calc R .
C13 C 0.6905(6) 0.5759(7) 0.1638(5) 0.032(2) Uani 1 d . .
H13A H 0.7332(6) 0.6597(7) 0.1849(5) 0.038 Uiso 1 calc R .
C14 C 0.5933(7) 0.5269(8) 0.0879(5) 0.046(2) Uani 1 d . .
H14A H 0.5466(7) 0.5604(8) 0.1100(5) 0.069 Uiso 1 calc R .
H14B H 0.5517(7) 0.4439(8) 0.0632(5) 0.069 Uiso 1 calc R .
H14C H 0.6194(7) 0.5449(8) 0.0419(5) 0.069 Uiso 1 calc R .
C15 C 0.7643(7) 0.5266(9) 0.1325(6) 0.050(2) Uani 1 d . .
H15A H 0.8258(7) 0.5594(9) 0.1823(6) 0.074 Uiso 1 calc R .
H15B H 0.7915(7) 0.5446(9) 0.0868(6) 0.074 Uiso 1 calc R .
H15C H 0.7239(7) 0.4436(9) 0.1081(6) 0.074 Uiso 1 calc R .
C16 C 0.7762(6) 0.6181(6) 0.3382(5) 0.030(2) Uani 1 d . .
H16A H 0.8117(6) 0.5709(6) 0.3102(5) 0.036 Uiso 1 calc R .
C17 C 0.8548(6) 0.7400(7) 0.3613(6) 0.042(2) Uani 1 d . .
H17A H 0.8672(6) 0.7436(7) 0.3072(6) 0.064 Uiso 1 calc R .
H17B H 0.9240(6) 0.7658(7) 0.3999(6) 0.064 Uiso 1 calc R .
H17C H 0.8240(6) 0.7894(7) 0.3919(6) 0.064 Uiso 1 calc R .
C18 C 0.7555(7) 0.6102(8) 0.4214(6) 0.055(3) Uani 1 d . .
H18A H 0.7046(7) 0.5310(8) 0.4053(6) 0.083 Uiso 1 calc R .
H18B H 0.7243(7) 0.6590(8) 0.4522(6) 0.083 Uiso 1 calc R .
H18C H 0.8243(7) 0.6354(8) 0.4603(6) 0.083 Uiso 1 calc R .
C19 C 0.4660(6) 0.1923(7) 0.1292(5) 0.038(2) Uani 1 d . .
H19A H 0.5202(6) 0.1862(7) 0.1629(5) 0.046 Uiso 1 calc R .
C20 C 0.5036(8) 0.1968(8) 0.0494(6) 0.059(3) Uani 1 d . .
H20A H 0.5740(8) 0.2656(8) 0.0690(6) 0.089 Uiso 1 calc R .
H20B H 0.4500(8) 0.1983(8) 0.0128(6) 0.089 Uiso 1 calc R .
H20C H 0.5113(8) 0.1292(8) 0.0147(6) 0.089 Uiso 1 calc R .
C21 C 0.3564(7) 0.0857(7) 0.1006(7) 0.054(2) Uani 1 d . .
H21A H 0.3334(7) 0.0843(7) 0.1530(7) 0.080 Uiso 1 calc R .
H21B H 0.3633(7) 0.0176(7) 0.0661(7) 0.080 Uiso 1 calc R .
H21C H 0.3020(7) 0.0868(7) 0.0643(7) 0.080 Uiso 1 calc R .
C22 C 0.4285(6) 0.3103(7) 0.2998(5) 0.037(2) Uani 1 d . .
H22A H 0.3537(6) 0.2437(7) 0.2785(5) 0.045 Uiso 1 calc R .
C23 C 0.5048(8) 0.2828(9) 0.3408(6) 0.057(3) Uani 1 d . .
H23A H 0.5054(8) 0.2154(9) 0.2952(6) 0.085 Uiso 1 calc R .
H23B H 0.4789(8) 0.2675(9) 0.3880(6) 0.085 Uiso 1 calc R .
H23C H 0.5786(8) 0.3479(9) 0.3653(6) 0.085 Uiso 1 calc R .
C24 C 0.4235(7) 0.4140(9) 0.3668(5) 0.051(2) Uani 1 d . .
H24A H 0.3742(7) 0.4281(9) 0.3378(5) 0.077 Uiso 1 calc R .
H24B H 0.4963(7) 0.4806(9) 0.3915(5) 0.077 Uiso 1 calc R .
H24C H 0.3966(7) 0.4002(9) 0.4143(5) 0.077 Uiso 1 calc R .
C25 C -0.1179(7) -0.0764(6) 0.1273(5) 0.034(2) Uani 1 d . .
H25A H -0.1970(7) -0.1015(6) 0.1227(5) 0.041 Uiso 1 calc R .
C26 C -0.0895(7) -0.0405(7) 0.0567(5) 0.046(2) Uani 1 d . .
H26A H -0.1002(7) 0.0252(7) 0.0692(5) 0.069 Uiso 1 calc R .
H26B H -0.1368(7) -0.1041(7) -0.0015(5) 0.069 Uiso 1 calc R .
H26C H -0.0134(7) -0.0197(7) 0.0570(5) 0.069 Uiso 1 calc R .
C27 C -0.1019(8) -0.1784(7) 0.1088(6) 0.051(2) Uani 1 d . .
H27A H -0.1203(8) -0.2007(7) 0.1543(6) 0.076 Uiso 1 calc R .
H27B H -0.0258(8) -0.1579(7) 0.1093(6) 0.076 Uiso 1 calc R .
H27C H -0.1492(8) -0.2424(7) 0.0508(6) 0.076 Uiso 1 calc R .
C28 C -0.0827(6) -0.0111(7) 0.3135(5) 0.031(2) Uani 1 d . .
H28A H -0.0639(6) -0.0736(7) 0.2985(5) 0.037 Uiso 1 calc R .
C29 C -0.2063(6) -0.0633(7) 0.3015(6) 0.041(2) Uani 1 d . .
H29A H -0.2440(6) -0.1209(7) 0.2396(6) 0.061 Uiso 1 calc R .
H29B H -0.2266(6) -0.0032(7) 0.3183(6) 0.061 Uiso 1 calc R .
H29C H -0.2270(6) -0.0991(7) 0.3390(6) 0.061 Uiso 1 calc R .
C30 C -0.0214(7) 0.0795(7) 0.4099(5) 0.041(2) Uani 1 d . .
H30A H 0.0571(7) 0.1117(7) 0.4162(5) 0.062 Uiso 1 calc R .
H30B H -0.0412(7) 0.0444(7) 0.4479(5) 0.062 Uiso 1 calc R .
H30C H -0.0408(7) 0.1403(7) 0.4272(5) 0.062 Uiso 1 calc R .
C31 C -0.1967(6) 0.2386(7) 0.2372(6) 0.039(2) Uani 1 d . .
H31A H -0.2306(6) 0.2253(7) 0.2837(6) 0.047 Uiso 1 calc R .
C32 C -0.2686(7) 0.1361(8) 0.1485(7) 0.057(3) Uani 1 d . .
H32A H -0.2706(7) 0.0677(8) 0.1457(7) 0.085 Uiso 1 calc R .
H32B H -0.2393(7) 0.1484(8) 0.1013(7) 0.085 Uiso 1 calc R .
H32C H -0.3425(7) 0.1261(8) 0.1413(7) 0.085 Uiso 1 calc R .
C33 C -0.1919(7) 0.3479(8) 0.2440(7) 0.055(3) Uani 1 d . .
H33A H -0.1451(7) 0.4130(8) 0.3017(7) 0.083 Uiso 1 calc R .
H33B H -0.2653(7) 0.3390(8) 0.2373(7) 0.083 Uiso 1 calc R .
H33C H -0.1622(7) 0.3613(8) 0.1973(7) 0.083 Uiso 1 calc R .
C34 C 0.0175(7) 0.3752(6) 0.3663(5) 0.034(2) Uani 1 d . .
H34A H 0.0179(7) 0.4429(6) 0.3660(5) 0.040 Uiso 1 calc R .
C35 C -0.0379(9) 0.3561(7) 0.4364(6) 0.058(3) Uani 1 d . .
H35A H -0.1132(9) 0.3400(7) 0.4211(6) 0.087 Uiso 1 calc R .
H35B H 0.0014(9) 0.4247(7) 0.4940(6) 0.087 Uiso 1 calc R .
H35C H -0.0374(9) 0.2912(7) 0.4389(6) 0.087 Uiso 1 calc R .
C36 C 0.1340(7) 0.4003(7) 0.3876(5) 0.044(2) Uani 1 d . .
H36A H 0.1677(7) 0.4123(7) 0.3419(5) 0.065 Uiso 1 calc R .
H36B H 0.1355(7) 0.3357(7) 0.3898(5) 0.065 Uiso 1 calc R .
H36C H 0.1743(7) 0.4692(7) 0.4450(5) 0.065 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Se1 Ag1 Se6 129.63(3) . . ?
Se1 Ag1 Se2 120.26(3) . . ?
Se6 Ag1 Se2 109.74(3) . . ?
Se3 Ag2 Se2 139.92(3) . . ?
Se3 Ag2 Se4 113.17(3) . . ?
Se2 Ag2 Se4 106.47(3) . . ?
Se5 Ag3 Se4 128.27(3) . . ?
Se5 Ag3 Se6 119.18(3) . . ?
Se4 Ag3 Se6 112.53(3) . . ?
P1 Se1 Ag1 97.27(6) . . ?
N1 P1 C1 106.6(3) . . ?
N1 P1 C4 107.9(4) . . ?
C1 P1 C4 105.4(4) . . ?
N1 P1 Se1 119.9(2) . . ?
C1 P1 Se1 108.8(3) . . ?
C4 P1 Se1 107.4(3) . . ?
P2 N1 P1 145.6(4) . . ?
N1 P2 C7 105.4(4) . . ?
N1 P2 C10 112.8(3) . . ?
C7 P2 C10 104.9(4) . . ?
N1 P2 Se2 118.9(2) . . ?
C7 P2 Se2 108.7(3) . . ?
C10 P2 Se2 105.3(3) . . ?
P2 Se2 Ag2 110.11(6) . . ?
P2 Se2 Ag1 95.36(5) . . ?
Ag2 Se2 Ag1 91.07(3) . . ?
P3 Se3 Ag2 98.11(6) . . ?
N2 P3 C16 106.2(3) . . ?
N2 P3 C13 109.3(3) . . ?
C16 P3 C13 104.7(3) . . ?
N2 P3 Se3 119.6(2) . . ?
C16 P3 Se3 106.6(3) . . ?
C13 P3 Se3 109.3(3) . . ?
P4 N2 P3 141.9(4) . . ?
N2 P4 C22 111.4(3) . . ?
N2 P4 C19 106.5(3) . . ?
C22 P4 C19 105.9(4) . . ?
N2 P4 Se4 117.5(2) . . ?
C22 P4 Se4 109.2(3) . . ?
C19 P4 Se4 105.5(3) . . ?
P4 Se4 Ag3 104.87(5) . . ?
P4 Se4 Ag2 101.27(6) . . ?
Ag3 Se4 Ag2 105.25(3) . . ?
P5 Se5 Ag3 96.64(5) . . ?
N3 P5 C28 106.4(3) . . ?
N3 P5 C25 108.9(3) . . ?
C28 P5 C25 104.7(3) . . ?
N3 P5 Se5 119.5(2) . . ?
C28 P5 Se5 107.7(3) . . ?
C25 P5 Se5 108.7(3) . . ?
P5 N3 P6 145.3(4) . . ?
N3 P6 C31 105.2(3) . . ?
N3 P6 C34 111.6(3) . . ?
C31 P6 C34 106.6(4) . . ?
N3 P6 Se6 116.9(2) . . ?
C31 P6 Se6 107.1(3) . . ?
C34 P6 Se6 108.9(2) . . ?
P6 Se6 Ag1 105.55(6) . . ?
P6 Se6 Ag3 94.08(5) . . ?
Ag1 Se6 Ag3 104.12(3) . . ?
C2 C1 C3 110.8(7) . . ?
C2 C1 P1 110.8(6) . . ?
C3 C1 P1 113.5(6) . . ?
C5 C4 C6 110.5(8) . . ?
C5 C4 P1 112.2(6) . . ?
C6 C4 P1 109.6(6) . . ?
C8 C7 C9 110.0(8) . . ?
C8 C7 P2 112.0(6) . . ?
C9 C7 P2 110.9(6) . . ?
C12 C10 C11 110.8(8) . . ?
C12 C10 P2 111.8(5) . . ?
C11 C10 P2 113.7(6) . . ?
C15 C13 C14 111.1(7) . . ?
C15 C13 P3 111.6(5) . . ?
C14 C13 P3 112.3(5) . . ?
C17 C16 C18 110.5(7) . . ?
C17 C16 P3 112.3(5) . . ?
C18 C16 P3 111.5(5) . . ?
C20 C19 C21 110.7(7) . . ?
C20 C19 P4 111.4(6) . . ?
C21 C19 P4 112.6(6) . . ?
C24 C22 C23 112.4(7) . . ?
C24 C22 P4 111.6(5) . . ?
C23 C22 P4 111.4(6) . . ?
C27 C25 C26 110.1(7) . . ?
C27 C25 P5 114.1(6) . . ?
C26 C25 P5 110.2(5) . . ?
C30 C28 C29 110.7(6) . . ?
C30 C28 P5 111.8(5) . . ?
C29 C28 P5 110.9(5) . . ?
C32 C31 C33 110.8(8) . . ?
C32 C31 P6 110.0(6) . . ?
C33 C31 P6 113.2(6) . . ?
C36 C34 C35 111.0(7) . . ?
C36 C34 P6 112.1(5) . . ?
C35 C34 P6 109.2(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Se1 2.5590(10) . ?
Ag1 Se6 2.5863(9) . ?
Ag1 Se2 2.6085(9) . ?
Ag2 Se3 2.5527(10) . ?
Ag2 Se2 2.5798(9) . ?
Ag2 Se4 2.6137(10) . ?
Ag3 Se5 2.5580(9) . ?
Ag3 Se4 2.5923(8) . ?
Ag3 Se6 2.6134(9) . ?
Se1 P1 2.181(2) . ?
P1 N1 1.598(6) . ?
P1 C1 1.831(8) . ?
P1 C4 1.844(8) . ?
N1 P2 1.577(6) . ?
P2 C7 1.830(7) . ?
P2 C10 1.851(8) . ?
P2 Se2 2.206(2) . ?
Se3 P3 2.169(2) . ?
P3 N2 1.600(6) . ?
P3 C16 1.836(7) . ?
P3 C13 1.837(7) . ?
N2 P4 1.583(6) . ?
P4 C22 1.838(7) . ?
P4 C19 1.839(8) . ?
P4 Se4 2.206(2) . ?
Se5 P5 2.167(2) . ?
P5 N3 1.580(6) . ?
P5 C28 1.830(7) . ?
P5 C25 1.834(7) . ?
N3 P6 1.591(6) . ?
P6 C31 1.828(8) . ?
P6 C34 1.846(8) . ?
P6 Se6 2.212(2) . ?
C1 C2 1.506(12) . ?
C1 C3 1.537(11) . ?
C4 C5 1.515(12) . ?
C4 C6 1.535(12) . ?
C7 C8 1.465(13) . ?
C7 C9 1.543(13) . ?
C10 C12 1.519(11) . ?
C10 C11 1.522(11) . ?
C13 C15 1.502(11) . ?
C13 C14 1.529(10) . ?
C16 C17 1.517(11) . ?
C16 C18 1.524(11) . ?
C19 C20 1.516(12) . ?
C19 C21 1.528(11) . ?
C22 C24 1.516(12) . ?
C22 C23 1.540(11) . ?
C25 C27 1.522(11) . ?
C25 C26 1.530(10) . ?
C28 C30 1.533(11) . ?
C28 C29 1.537(10) . ?
C31 C32 1.516(13) . ?
C31 C33 1.541(12) . ?
C34 C36 1.512(12) . ?
C34 C35 1.529(10) . ?
