#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:22:32 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180390 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/59/7205905.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205905
loop_
_publ_author_name
'Chen, Yang'
'Yang, Zhou'
'Wu, Xin-Yi'
'Ni, Chun-Yan'
'Ren, Zhi-Gang'
'Wang, Hui-Fang'
'Lang, Jian-Ping'
_publ_section_title
;
 Iodobismuthates with N-alkyl- or N,N'-dialkyl-4,4'-bipyridinium:
 syntheses, structures and dielectric properties.
;
_journal_issue                   13
_journal_name_full               'Physical chemistry chemical physics : PCCP'
_journal_page_first              5659
_journal_page_last               5667
_journal_paper_doi               10.1039/c0cp02431g
_journal_volume                  13
_journal_year                    2011
_chemical_formula_moiety
'C24 H26 Bi2 I8 N4, C12 H13 N2, 3(I), 0.67(Bi)'
_chemical_formula_sum            'C36 H39 Bi2.67 I11 N6'
_chemical_formula_weight         2508.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.4498(17)
_cell_length_b                   31.165(6)
_cell_length_c                   21.534(4)
_cell_measurement_reflns_used    12414
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.5087
_cell_measurement_theta_min      3.0646
_cell_volume                     5670.7(19)
_computing_cell_refinement       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_collection       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_reduction
'CrystalStructure, Ver. 3.60 (Rigaku/MSC, 2004)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku MercuryCCD area detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0395
_diffrn_reflns_av_sigmaI/netI    0.0502
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            15649
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.06
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    14.277
_exptl_absorpt_correction_T_max  0.077
_exptl_absorpt_correction_T_min  0.025
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Jacobson, R. (1998) Private communication to Rigaku Company, Tokyo, Japan.'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    2.939
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             4408.1
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.432
_refine_diff_density_min         -1.485
_refine_diff_density_rms         0.197
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         5046
_refine_ls_number_restraints     197
_refine_ls_restrained_S_all      1.165
_refine_ls_R_factor_all          0.0767
_refine_ls_R_factor_gt           0.0630
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0994P)²+15.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1736
_refine_ls_wR_factor_ref         0.1842
_reflns_number_gt                4309
_reflns_number_total             5046
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0cp02431g.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_database_code               7205905
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.56011(7) -0.060181(17) 0.93098(3) 0.0480(2) Uani 1 1 d . . .
I1 I 0.57530(12) -0.12076(3) 1.03721(5) 0.0557(3) Uani 1 1 d . . .
I4 I 0.25437(11) -0.01354(3) 0.99319(5) 0.0531(3) Uani 1 1 d . . .
I2 I 0.85541(13) -0.09397(4) 0.87823(6) 0.0649(3) Uani 1 1 d . . .
I3 I 0.34737(15) -0.11299(4) 0.85338(6) 0.0727(4) Uani 1 1 d . . .
Bi2 Bi 0.9566(4) 0.2500 0.74551(12) 0.0632(9) Uani 0.411(4) 2 d SPU . 1
I5 I 1.2079(12) 0.2500 0.6387(3) 0.148(3) Uani 0.616(5) 2 d SPU . 1
I6 I 0.7045(7) 0.18114(8) 0.69023(17) 0.1198(16) Uani 0.616(5) 1 d PU . 1
Bi2' Bi 1.0854(5) 0.2500 0.75301(14) 0.0467(13) Uani 0.256(4) 2 d SPU . 2
I5' I 1.3407(10) 0.2500 0.6453(3) 0.0882(19) Uani 0.384(5) 2 d SPU . 2
I6' I 0.8470(13) 0.18311(13) 0.6824(2) 0.127(3) Uani 0.384(5) 1 d PU . 2
N1 N 0.5536(17) -0.0095(4) 0.8324(7) 0.062(4) Uani 1 1 d . . .
N2 N 0.3981(16) 0.1194(5) 0.5741(5) 0.053(3) Uani 1 1 d . . .
C9 C 0.3471(18) 0.1006(4) 0.6788(7) 0.049(3) Uani 1 1 d . . .
H9 H 0.2885 0.1045 0.7160 0.059 Uiso 1 1 calc R . .
C8 C 0.4565(18) 0.0693(5) 0.6756(8) 0.052(4) Uani 1 1 d . . .
C3 C 0.4928(17) 0.0417(4) 0.7310(6) 0.043(3) Uani 1 1 d . . .
C2 C 0.468(2) 0.0569(5) 0.7898(7) 0.052(4) Uani 1 1 d . . .
H2 H 0.4306 0.0854 0.7962 0.063 Uiso 1 1 calc R . .
C4 C 0.552(2) 0.0004(5) 0.7230(8) 0.059(4) Uani 1 1 d . . .
H4 H 0.5702 -0.0107 0.6825 0.071 Uiso 1 1 calc R . .
C10 C 0.3183(19) 0.1275(5) 0.6281(8) 0.061(4) Uani 1 1 d . . .
H10 H 0.2456 0.1506 0.6311 0.073 Uiso 1 1 calc R . .
C7 C 0.535(2) 0.0628(5) 0.6192(7) 0.056(4) Uani 1 1 d . . .
H7 H 0.6115 0.0406 0.6159 0.067 Uiso 1 1 calc R . .
C6 C 0.502(2) 0.0879(6) 0.5689(8) 0.058(4) Uani 1 1 d . . .
H6 H 0.5539 0.0828 0.5304 0.070 Uiso 1 1 calc R . .
C5 C 0.583(2) -0.0245(6) 0.7752(7) 0.068(5) Uani 1 1 d . . .
H5 H 0.6254 -0.0526 0.7703 0.081 Uiso 1 1 calc R . .
C1 C 0.4977(19) 0.0302(4) 0.8396(7) 0.050(3) Uani 1 1 d . . .
H1 H 0.4777 0.0405 0.8804 0.060 Uiso 1 1 calc R . .
C11 C 0.368(3) 0.1489(7) 0.5193(9) 0.079(6) Uani 1 1 d . . .
H11A H 0.3656 0.1319 0.4805 0.095 Uiso 1 1 calc R . .
H11B H 0.2638 0.1630 0.5242 0.095 Uiso 1 1 calc R . .
C12 C 0.492(3) 0.1819(7) 0.5147(10) 0.094(7) Uani 1 1 d . . .
H12A H 0.4911 0.1997 0.5521 0.141 Uiso 1 1 calc R . .
H12B H 0.4727 0.1999 0.4782 0.141 Uiso 1 1 calc R . .
H12C H 0.5958 0.1680 0.5106 0.141 Uiso 1 1 calc R . .
N4 N 0.856(4) 0.2500 0.4413(17) 0.128(7) Uani 1 2 d SDU . .
N3 N 0.908(4) 0.2500 0.1116(18) 0.138(9) Uani 1 2 d SDU . .
C16 C 0.873(5) 0.2500 0.309(2) 0.123(7) Uani 1 2 d SDU . .
C19 C 0.836(5) 0.2500 0.516(2) 0.136(8) Uani 1 2 d SDU . .
H19A H 0.7838 0.2761 0.5318 0.163 Uiso 0.50 1 calc PR . .
H19B H 0.7838 0.2239 0.5318 0.163 Uiso 0.50 1 calc PR . .
C18 C 0.858(4) 0.2134(11) 0.4081(15) 0.130(6) Uani 1 1 d DU . .
H18 H 0.8501 0.1870 0.4298 0.156 Uiso 1 1 calc R . .
C17 C 0.872(3) 0.2122(11) 0.3431(14) 0.127(6) Uani 1 1 d DU . .
H17 H 0.8798 0.1854 0.3225 0.152 Uiso 1 1 calc R . .
C14 C 0.899(2) 0.2133(11) 0.2131(15) 0.132(7) Uani 1 1 d DU . .
H14 H 0.9025 0.1868 0.2347 0.158 Uiso 1 1 calc R . .
C15 C 0.885(5) 0.2500 0.243(2) 0.123(7) Uani 1 2 d SDU . .
C20 C 1.007(6) 0.2500 0.525(2) 0.146(11) Uani 1 2 d SU . .
H20A H 1.0433 0.2793 0.5338 0.219 Uiso 0.50 1 calc PR . .
H20B H 1.0596 0.2395 0.4872 0.219 Uiso 0.50 1 calc PR . .
H20C H 1.0343 0.2312 0.5598 0.219 Uiso 0.50 1 calc PR . .
C13 C 0.910(2) 0.2153(13) 0.1493(16) 0.142(7) Uani 1 1 d DU . .
H13 H 0.9208 0.1884 0.1289 0.171 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Bi1 I2 85.5(3) . . ?
N1 Bi1 I3 82.3(3) . . ?
I2 Bi1 I3 95.64(4) . . ?
N1 Bi1 I1 176.9(3) . . ?
I2 Bi1 I1 91.91(3) . . ?
I3 Bi1 I1 96.19(4) . . ?
N1 Bi1 I4 89.5(3) . 5_657 ?
I2 Bi1 I4 92.20(4) . 5_657 ?
I3 Bi1 I4 168.16(4) . 5_657 ?
I1 Bi1 I4 92.40(3) . 5_657 ?
N1 Bi1 I4 92.7(3) . . ?
I2 Bi1 I4 173.85(4) . . ?
I3 Bi1 I4 89.92(4) . . ?
I1 Bi1 I4 90.07(3) . . ?
I4 Bi1 I4 81.91(3) 5_657 . ?
Bi1 I4 Bi1 98.09(3) 5_657 . ?
I5 Bi2 I6 100.11(16) . . ?
I5 Bi2 I6 100.11(16) . 7_565 ?
I6 Bi2 I6 82.65(14) . 7_565 ?
I5 Bi2 I5 177.4(3) . 6_557 ?
I6 Bi2 I5 81.81(15) . 6_557 ?
I6 Bi2 I5 81.81(15) 7_565 6_557 ?
I5 Bi2 I6 82.97(16) . 4_556 ?
I6 Bi2 I6 176.69(12) . 4_556 ?
I6 Bi2 I6 98.06(9) 7_565 4_556 ?
I5 Bi2 I6 95.07(12) 6_557 4_556 ?
I5 Bi2 I6 82.97(16) . 6_657 ?
I6 Bi2 I6 98.06(9) . 6_657 ?
I6 Bi2 I6 176.69(12) 7_565 6_657 ?
I5 Bi2 I6 95.07(12) 6_557 6_657 ?
I6 Bi2 I6 81.05(16) 4_556 6_657 ?
Bi2 I5 Bi2 82.84(14) . 6_657 ?
Bi2 I6 Bi2 80.40(7) . 6_557 ?
I5' Bi2' I5' 179.6(3) 6_557 . ?
I5' Bi2' I6' 85.12(18) 6_557 . ?
I5' Bi2' I6' 94.54(17) . . ?
I5' Bi2' I6' 85.12(18) 6_557 7_565 ?
I5' Bi2' I6' 94.54(17) . 7_565 ?
I6' Bi2' I6' 79.1(3) . 7_565 ?
I5' Bi2' I6' 98.72(19) 6_557 4_556 ?
I5' Bi2' I6' 81.6(2) . 4_556 ?
I6' Bi2' I6' 176.1(3) . 4_556 ?
I6' Bi2' I6' 101.73(13) 7_565 4_556 ?
I5' Bi2' I6' 98.72(19) 6_557 6_657 ?
I5' Bi2' I6' 81.6(2) . 6_657 ?
I6' Bi2' I6' 101.73(13) . 6_657 ?
I6' Bi2' I6' 176.1(3) 7_565 6_657 ?
I6' Bi2' I6' 77.2(2) 4_556 6_657 ?
Bi2' I5' Bi2' 86.31(16) 6_657 . ?
Bi2' I6' Bi2' 79.42(9) . 6_557 ?
C5 N1 C1 119.9(14) . . ?
C5 N1 Bi1 121.6(11) . . ?
C1 N1 Bi1 117.9(11) . . ?
C6 N2 C10 122.3(14) . . ?
C6 N2 C11 119.7(15) . . ?
C10 N2 C11 117.9(16) . . ?
C8 C9 C10 121.0(15) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
C9 C8 C7 118.4(15) . . ?
C9 C8 C3 121.0(15) . . ?
C7 C8 C3 120.5(14) . . ?
C2 C3 C4 119.4(14) . . ?
C2 C3 C8 120.2(13) . . ?
C4 C3 C8 120.4(13) . . ?
C3 C2 C1 118.8(14) . . ?
C3 C2 H2 120.6 . . ?
C1 C2 H2 120.6 . . ?
C3 C4 C5 119.0(15) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 H4 120.5 . . ?
N2 C10 C9 117.9(15) . . ?
N2 C10 H10 121.0 . . ?
C9 C10 H10 121.0 . . ?
C6 C7 C8 120.6(16) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
N2 C6 C7 119.6(15) . . ?
N2 C6 H6 120.2 . . ?
C7 C6 H6 120.2 . . ?
N1 C5 C4 120.8(16) . . ?
N1 C5 H5 119.6 . . ?
C4 C5 H5 119.6 . . ?
N1 C1 C2 122.2(14) . . ?
N1 C1 H1 118.9 . . ?
C2 C1 H1 118.9 . . ?
C12 C11 N2 110.8(16) . . ?
C12 C11 H11A 109.5 . . ?
N2 C11 H11A 109.5 . . ?
C12 C11 H11B 109.5 . . ?
N2 C11 H11B 109.5 . . ?
H11A C11 H11B 108.1 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C18 N4 C18 116(4) . 7_565 ?
C18 N4 C19 122(2) . . ?
C18 N4 C19 122(2) 7_565 . ?
C13 N3 C13 106(4) . 7_565 ?
C17 C16 C17 116(4) . 7_565 ?
C17 C16 C15 122(2) . . ?
C17 C16 C15 122(2) 7_565 . ?
C20 C19 N4 92(3) . . ?
C20 C19 H19A 113.3 . . ?
N4 C19 H19A 113.3 . . ?
C20 C19 H19B 113.3 . . ?
N4 C19 H19B 113.3 . . ?
H19A C19 H19B 110.7 . . ?
N4 C18 C17 124(3) . . ?
N4 C18 H18 118.2 . . ?
C17 C18 H18 118.2 . . ?
C16 C17 C18 121(3) . . ?
C16 C17 H17 119.7 . . ?
C18 C17 H17 119.7 . . ?
C15 C14 C13 117(4) . . ?
C15 C14 H14 121.7 . . ?
C13 C14 H14 121.7 . . ?
C14 C15 C14 121(5) . 7_565 ?
C14 C15 C16 119(2) . . ?
C14 C15 C16 119(2) 7_565 . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N3 C13 C14 129(4) . . ?
N3 C13 H13 115.3 . . ?
C14 C13 H13 115.3 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 N1 2.647(14) . ?
Bi1 I2 2.9370(13) . ?
Bi1 I3 2.9552(14) . ?
Bi1 I1 2.9689(12) . ?
Bi1 I4 3.2253(12) 5_657 ?
Bi1 I4 3.2529(12) . ?
I4 Bi1 3.2253(12) 5_657 ?
Bi2 I5 3.130(7) . ?
Bi2 I6 3.250(4) . ?
Bi2 I6 3.250(4) 7_565 ?
Bi2 I5 3.261(10) 6_557 ?
Bi2 I6 3.303(5) 4_556 ?
Bi2 I6 3.303(5) 6_657 ?
I5 Bi2 3.261(10) 6_657 ?
I6 Bi2 3.303(5) 6_557 ?
Bi2' I5' 3.011(8) 6_557 ?
Bi2' I5' 3.167(8) . ?
Bi2' I6' 3.274(8) . ?
Bi2' I6' 3.274(8) 7_565 ?
Bi2' I6' 3.341(8) 4_556 ?
Bi2' I6' 3.341(8) 6_657 ?
I5' Bi2' 3.011(8) 6_657 ?
I6' Bi2' 3.341(8) 6_557 ?
N1 C5 1.34(2) . ?
N1 C1 1.333(19) . ?
N2 C6 1.32(2) . ?
N2 C10 1.37(2) . ?
N2 C11 1.52(2) . ?
C9 C8 1.34(2) . ?
C9 C10 1.40(2) . ?
C9 H9 0.9500 . ?
C8 C7 1.40(2) . ?
C8 C3 1.50(2) . ?
C3 C2 1.37(2) . ?
C3 C4 1.39(2) . ?
C2 C1 1.38(2) . ?
C2 H2 0.9500 . ?
C4 C5 1.39(2) . ?
C4 H4 0.9500 . ?
C10 H10 0.9500 . ?
C7 C6 1.37(2) . ?
C7 H7 0.9500 . ?
C6 H6 0.9500 . ?
C5 H5 0.9500 . ?
C1 H1 0.9500 . ?
C11 C12 1.47(3) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
N4 C18 1.35(3) . ?
N4 C18 1.35(3) 7_565 ?
N4 C19 1.61(5) . ?
N3 C13 1.35(4) . ?
N3 C13 1.35(4) 7_565 ?
C16 C17 1.39(4) . ?
C16 C17 1.39(4) 7_565 ?
C16 C15 1.43(6) . ?
C19 C20 1.46(6) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C18 C17 1.40(4) . ?
C18 H18 0.9500 . ?
C17 H17 0.9500 . ?
C14 C15 1.31(3) . ?
C14 C13 1.38(4) . ?
C14 H14 0.9500 . ?
C15 C14 1.31(3) 7_565 ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C13 H13 0.9500 . ?
