#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:31:29 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180398 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/67/7206723.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7206723
loop_
_publ_author_name
'Hou, Gui-Ge'
'Wu, Yan'
'Ma, Jian-Ping'
'Dong, Yu-Bin'
_publ_section_title
;
 Synthesis, structural characterization and properties of Ag(i)-complexes
 based on double-armed 1,3,4-oxadiazole bridging ligands
;
_journal_issue                   22
_journal_name_full               CrystEngComm
_journal_page_first              6850
_journal_paper_doi               10.1039/c1ce05718a
_journal_volume                  13
_journal_year                    2011
_chemical_formula_sum            'C34 H28 Ag F6 N4 O4 P'
_chemical_formula_weight         809.44
_chemical_name_systematic
;
?
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.037(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.9206(17)
_cell_length_b                   18.112(2)
_cell_length_c                   26.968(3)
_cell_measurement_reflns_used    5944
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.671
_cell_measurement_theta_min      2.243
_cell_volume                     6695.4(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_sigmaI/netI    0.0464
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            17227
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    0.728
_exptl_absorpt_correction_T_max  0.8924
_exptl_absorpt_correction_T_min  0.7643
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3264
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.987
_refine_diff_density_min         -0.416
_refine_diff_density_rms         0.105
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.20(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     902
_refine_ls_number_reflns         10139
_refine_ls_number_restraints     50
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0632
_refine_ls_R_factor_gt           0.0529
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0889P)²+5.7645P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1310
_refine_ls_wR_factor_ref         0.1394
_reflns_number_gt                8706
_reflns_number_total             10139
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1ce05718a.txt
_cod_data_source_block           10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        6695.6(14)
_cod_original_sg_symbol_H-M      Cc
_cod_database_code               7206723
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.06192(3) -0.08723(3) 0.903090(18) 0.04230(15) Uani 1 1 d .
Ag2 Ag 0.05464(3) 0.11363(3) 0.896630(19) 0.04306(15) Uani 1 1 d .
C1 C -0.0210(6) -0.2285(6) 1.3011(3) 0.056(2) Uani 1 1 d .
C2 C -0.0204(6) -0.2855(4) 1.2653(3) 0.0464(18) Uani 1 1 d .
C3 C 0.0037(9) -0.3562(6) 1.2818(4) 0.085(3) Uani 1 1 d .
H3 H 0.0134 -0.3671 1.3168 0.102 Uiso 1 1 calc R
C4 C 0.0139(10) -0.4112(6) 1.2476(4) 0.094(3) Uani 1 1 d U
H4 H 0.0400 -0.4580 1.2587 0.113 Uiso 1 1 calc R
C5 C -0.0144(11) -0.3968(5) 1.1975(4) 0.108(5) Uani 1 1 d .
H5 H -0.0195 -0.4366 1.1742 0.129 Uiso 1 1 calc R
C6 C -0.0356(6) -0.3268(4) 1.1797(3) 0.0478(18) Uani 1 1 d .
C7 C -0.0411(5) -0.2700(4) 1.2134(3) 0.0357(15) Uani 1 1 d .
H7 H -0.0585 -0.2216 1.2017 0.043 Uiso 1 1 calc R
C8 C -0.0582(5) -0.3157(4) 1.1236(3) 0.0424(16) Uani 1 1 d .
H8A H -0.0112 -0.3436 1.1072 0.051 Uiso 1 1 calc R
H8B H -0.1247 -0.3340 1.1102 0.051 Uiso 1 1 calc R
C9 C -0.0683(5) -0.2190(4) 1.0632(2) 0.0356(15) Uani 1 1 d .
C10 C -0.0939(5) -0.2669(4) 1.0239(3) 0.0445(18) Uani 1 1 d .
H10 H -0.1002 -0.3180 1.0306 0.053 Uiso 1 1 calc R
C11 C -0.1108(6) -0.2417(5) 0.9741(3) 0.045(2) Uani 1 1 d .
H11 H -0.1288 -0.2752 0.9470 0.054 Uiso 1 1 calc R
C12 C -0.1010(5) -0.1679(4) 0.9650(3) 0.0389(17) Uani 1 1 d .
H12 H -0.1140 -0.1500 0.9314 0.047 Uiso 1 1 calc R
C13 C -0.0721(5) -0.1190(4) 1.0046(3) 0.0395(18) Uani 1 1 d .
C14 C -0.0567(5) -0.1440(4) 1.0543(3) 0.0381(15) Uani 1 1 d .
H14 H -0.0386 -0.1106 1.0814 0.046 Uiso 1 1 calc R
C15 C -0.0534(5) -0.0436(4) 0.9917(3) 0.0357(16) Uani 1 1 d .
C16 C -0.0496(5) 0.0753(4) 0.9944(3) 0.0333(15) Uani 1 1 d .
C17 C -0.0655(5) 0.1493(4) 1.0117(2) 0.0359(15) Uani 1 1 d .
C18 C -0.0861(5) 0.2056(5) 0.9752(3) 0.0431(18) Uani 1 1 d .
H18 H -0.0908 0.1947 0.9404 0.052 Uiso 1 1 calc R
C19 C -0.0988(6) 0.2743(5) 0.9905(3) 0.0455(19) Uani 1 1 d .
H19 H -0.1136 0.3120 0.9658 0.055 Uiso 1 1 calc R
C20 C -0.0912(6) 0.2930(4) 1.0412(3) 0.0442(18) Uani 1 1 d .
H20 H -0.1006 0.3425 1.0510 0.053 Uiso 1 1 calc R
C21 C -0.0697(5) 0.2380(4) 1.0768(2) 0.0337(14) Uani 1 1 d .
C22 C -0.0589(5) 0.1656(4) 1.0624(3) 0.0355(15) Uani 1 1 d .
H22 H -0.0471 0.1275 1.0870 0.043 Uiso 1 1 calc R
C23 C -0.0663(6) 0.3252(4) 1.1428(3) 0.0423(17) Uani 1 1 d .
H23A H -0.1315 0.3453 1.1287 0.051 Uiso 1 1 calc R
H23B H -0.0165 0.3551 1.1299 0.051 Uiso 1 1 calc R
C24 C -0.0498(6) 0.3294(4) 1.1997(3) 0.0442(17) Uani 1 1 d .
C25 C -0.0370(5) 0.2682(4) 1.2310(3) 0.0401(17) Uani 1 1 d .
H25 H -0.0364 0.2202 1.2168 0.048 Uiso 1 1 calc R
C26 C -0.0251(5) 0.2766(5) 1.2827(3) 0.0471(19) Uani 1 1 d .
C27 C -0.0162(6) 0.2143(5) 1.3157(3) 0.051(2) Uani 1 1 d .
C28 C -0.0274(8) 0.3461(6) 1.3040(3) 0.072(3) Uani 1 1 d .
H28 H -0.0182 0.3515 1.3396 0.086 Uiso 1 1 calc R
C29 C -0.0436(10) 0.4085(6) 1.2727(4) 0.087(4) Uani 1 1 d .
H29 H -0.0494 0.4561 1.2867 0.104 Uiso 1 1 calc R
C30 C -0.0509(10) 0.3998(6) 1.2217(4) 0.087(4) Uani 1 1 d .
H30 H -0.0568 0.4422 1.2007 0.105 Uiso 1 1 calc R
C31 C 0.1583(5) 0.2109(5) 0.4934(3) 0.0465(19) Uani 1 1 d .
C32 C 0.1719(5) 0.2735(4) 0.5265(3) 0.0372(16) Uani 1 1 d .
C33 C 0.1739(5) 0.3429(5) 0.5061(3) 0.0476(19) Uani 1 1 d .
H33 H 0.1648 0.3493 0.4706 0.057 Uiso 1 1 calc R
C34 C 0.1891(6) 0.4030(5) 0.5377(3) 0.0501(19) Uani 1 1 d .
H34 H 0.1903 0.4513 0.5241 0.060 Uiso 1 1 calc R
C35 C 0.2025(6) 0.3929(4) 0.5882(3) 0.0454(18) Uani 1 1 d .
H35 H 0.2121 0.4351 0.6094 0.054 Uiso 1 1 calc R
C36 C 0.2027(5) 0.3234(4) 0.6104(2) 0.0383(15) Uani 1 1 d .
C37 C 0.1845(5) 0.2613(4) 0.5786(3) 0.0409(17) Uani 1 1 d .
H37 H 0.1808 0.2131 0.5920 0.049 Uiso 1 1 calc R
C38 C 0.2220(6) 0.3179(4) 0.6663(3) 0.0453(17) Uani 1 1 d .
H38A H 0.2886 0.3361 0.6795 0.054 Uiso 1 1 calc R
H38B H 0.1750 0.3491 0.6803 0.054 Uiso 1 1 calc R
C39 C 0.2189(5) 0.2318(4) 0.7321(2) 0.0331(14) Uani 1 1 d .
C40 C 0.2361(6) 0.2862(4) 0.7694(3) 0.0456(18) Uani 1 1 d .
H40 H 0.2446 0.3360 0.7599 0.055 Uiso 1 1 calc R
C41 C 0.2410(6) 0.2697(4) 0.8192(3) 0.0412(17) Uani 1 1 d .
H41 H 0.2520 0.3077 0.8439 0.049 Uiso 1 1 calc R
C42 C 0.2296(5) 0.1951(4) 0.8339(3) 0.0344(15) Uani 1 1 d .
H42 H 0.2342 0.1822 0.8684 0.041 Uiso 1 1 calc R
C43 C 0.2118(5) 0.1423(4) 0.7968(2) 0.0316(14) Uani 1 1 d .
C44 C 0.2079(5) 0.1584(4) 0.7458(2) 0.0341(15) Uani 1 1 d .
H44 H 0.1981 0.1205 0.7211 0.041 Uiso 1 1 calc R
C45 C 0.1951(5) 0.0667(4) 0.8128(3) 0.0300(15) Uani 1 1 d .
C46 C 0.1993(5) -0.0507(4) 0.8180(3) 0.0313(15) Uani 1 1 d .
C47 C 0.2176(5) -0.1289(4) 0.8080(3) 0.0316(15) Uani 1 1 d .
C48 C 0.2362(5) -0.1761(4) 0.8492(3) 0.0418(16) Uani 1 1 d .
H48 H 0.2433 -0.1572 0.8825 0.050 Uiso 1 1 calc R
C49 C 0.2442(6) -0.2514(5) 0.8410(3) 0.052(2) Uani 1 1 d .
H49 H 0.2563 -0.2842 0.8689 0.062 Uiso 1 1 calc R
C50 C 0.2350(5) -0.2783(4) 0.7934(3) 0.0426(17) Uani 1 1 d .
H50 H 0.2393 -0.3299 0.7881 0.051 Uiso 1 1 calc R
C51 C 0.2194(5) -0.2313(4) 0.7527(3) 0.0407(16) Uani 1 1 d .
C52 C 0.2103(5) -0.1560(4) 0.7584(3) 0.0365(15) Uani 1 1 d .
H52 H 0.1997 -0.1238 0.7302 0.044 Uiso 1 1 calc R
C53 C 0.1924(5) -0.2208(3) 0.6638(2) 0.0353(14) Uani 1 1 d .
H53A H 0.2435 -0.1827 0.6643 0.042 Uiso 1 1 calc R
H53B H 0.1290 -0.1956 0.6627 0.042 Uiso 1 1 calc R
C54 C 0.1886(5) -0.2696(4) 0.6179(3) 0.0366(14) Uani 1 1 d .
C55 C 0.2000(6) -0.3445(4) 0.6214(3) 0.0494(19) Uani 1 1 d .
H55 H 0.2104 -0.3672 0.6537 0.059 Uiso 1 1 calc R
C56 C 0.1965(7) -0.3889(4) 0.5780(3) 0.053(2) Uani 1 1 d .
H56 H 0.2040 -0.4409 0.5812 0.064 Uiso 1 1 calc R
C57 C 0.1819(6) -0.3556(5) 0.5302(3) 0.0507(19) Uani 1 1 d .
H57 H 0.1812 -0.3841 0.5005 0.061 Uiso 1 1 calc R
C58 C 0.1687(5) -0.2804(4) 0.5278(2) 0.0344(15) Uani 1 1 d .
C59 C 0.1725(5) -0.2372(4) 0.5714(3) 0.0353(15) Uani 1 1 d .
H59 H 0.1638 -0.1853 0.5686 0.042 Uiso 1 1 calc R
C60 C 0.1527(5) -0.2424(4) 0.4805(3) 0.0424(17) Uani 1 1 d .
C61 C 0.9062(8) 0.9954(10) 0.1779(5) 0.152(9) Uani 1 1 d D
H61A H 0.9214 1.0349 0.1550 0.182 Uiso 1 1 calc R
H61B H 0.9134 0.9471 0.1617 0.182 Uiso 1 1 calc R
C62 C 0.9754(11) 1.0000(10) 0.2281(6) 0.143(8) Uani 1 1 d D
H62A H 1.0188 0.9563 0.2335 0.171 Uiso 1 1 calc R
H62B H 1.0158 1.0452 0.2302 0.171 Uiso 1 1 calc R
C63 C 0.9073(11) 1.0020(8) 0.2658(6) 0.128(6) Uani 1 1 d D
H63A H 0.9103 1.0508 0.2826 0.154 Uiso 1 1 calc R
H63B H 0.9254 0.9636 0.2919 0.154 Uiso 1 1 calc R
C64 C 0.8051(10) 0.9878(6) 0.2365(4) 0.106(5) Uani 1 1 d D
H64A H 0.7859 0.9357 0.2400 0.128 Uiso 1 1 calc R
H64B H 0.7568 1.0202 0.2487 0.128 Uiso 1 1 calc R
C67 C 0.3599(16) -0.0095(11) 0.9957(8) 0.185(9) Uani 1 1 d DU
H67A H 0.3322 -0.0507 1.0128 0.222 Uiso 1 1 calc R
H67B H 0.4137 0.0137 1.0195 0.222 Uiso 1 1 calc R
C66 C 0.394(2) -0.0353(11) 0.9474(12) 0.33(2) Uani 1 1 d DU
H66A H 0.4537 -0.0657 0.9548 0.392 Uiso 1 1 calc R
H66B H 0.3423 -0.0632 0.9252 0.392 Uiso 1 1 calc R
C65 C 0.413(2) 0.0388(14) 0.9248(11) 0.239(12) Uani 1 1 d DU
H65A H 0.4786 0.0587 0.9386 0.287 Uiso 1 1 calc R
H65B H 0.4031 0.0379 0.8876 0.287 Uiso 1 1 calc R
O8 O 0.3403(17) 0.0740(13) 0.9429(8) 0.292(11) Uani 1 1 d DU
F1 F 0.2479(6) 0.5015(4) 0.4401(2) 0.104(2) Uani 1 1 d .
F2 F 0.2864(6) 0.5515(4) 0.3713(3) 0.102(2) Uani 1 1 d .
F3 F 0.2873(6) 0.4305(5) 0.3805(4) 0.133(3) Uani 1 1 d .
F4 F 0.1338(6) 0.4299(5) 0.3940(3) 0.130(3) Uani 1 1 d .
F5 F 0.1304(8) 0.5505(6) 0.3816(5) 0.192(5) Uani 1 1 d .
F6 F 0.1731(7) 0.4792(6) 0.3235(3) 0.143(4) Uani 1 1 d .
F7 F 0.1287(8) -0.0662(5) 0.1311(3) 0.140(3) Uani 1 1 d .
F8 F 0.2382(8) 0.0084(5) 0.1720(4) 0.149(4) Uani 1 1 d .
F9 F 0.1128(7) 0.0557(5) 0.1265(4) 0.140(3) Uani 1 1 d .
F10 F 0.2523(6) 0.0643(4) 0.1003(4) 0.132(3) Uani 1 1 d .
F11 F 0.1380(7) -0.0089(6) 0.0594(3) 0.143(4) Uani 1 1 d .
F12 F 0.2685(9) -0.0546(5) 0.1044(5) 0.188(5) Uani 1 1 d .
N1 N 0.1528(4) 0.0489(3) 0.8505(2) 0.0349(13) Uani 1 1 d .
N2 N 0.1545(5) -0.0283(3) 0.8537(2) 0.0365(14) Uani 1 1 d .
N3 N 0.1500(6) 0.1640(5) 0.4651(3) 0.066(2) Uani 1 1 d .
N4 N 0.1391(5) -0.2109(4) 0.4434(2) 0.0585(18) Uani 1 1 d .
N5 N -0.0137(4) 0.0552(3) 0.9556(2) 0.0363(13) Uani 1 1 d .
N6 N -0.0155(5) -0.0221(3) 0.9541(2) 0.0352(14) Uani 1 1 d .
N7 N -0.0215(5) -0.1828(5) 1.3309(3) 0.0589(19) Uani 1 1 d .
N8 N -0.0096(5) 0.1657(5) 1.3431(3) 0.0549(18) Uani 1 1 d .
O1 O 0.2264(4) 0.0060(2) 0.79053(18) 0.0329(11) Uani 1 1 d .
O2 O 0.2131(4) 0.2434(3) 0.68139(17) 0.0447(12) Uani 1 1 d .
O3 O 0.2134(4) -0.2650(3) 0.70714(18) 0.0485(12) Uani 1 1 d .
O4 O -0.0761(4) 0.0145(2) 1.01959(18) 0.0337(11) Uani 1 1 d .
O5 O -0.0518(4) -0.2393(3) 1.11331(17) 0.0439(12) Uani 1 1 d .
O6 O -0.0600(4) 0.2497(3) 1.12755(17) 0.0403(12) Uani 1 1 d .
O7 O 0.8105(6) 1.0036(5) 0.1868(3) 0.093(3) Uani 1 1 d D
C68 C 0.2824(12) 0.0464(9) 0.9747(7) 0.145(6) Uani 1 1 d DU
H68A H 0.2214 0.0236 0.9568 0.174 Uiso 1 1 calc R
H68B H 0.2683 0.0826 0.9999 0.174 Uiso 1 1 calc R
P1 P 0.2075(2) 0.49230(13) 0.38294(9) 0.0655(7) Uani 1 1 d .
P2 P 0.1922(2) -0.00083(11) 0.11392(11) 0.0627(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N6 Ag1 N8 125.2(2) . 2_554
N6 Ag1 N2 119.88(17) . .
N8 Ag1 N2 95.7(2) 2_554 .
N6 Ag1 N3 97.0(3) . 2
N8 Ag1 N3 104.4(3) 2_554 2
N2 Ag1 N3 114.6(3) . 2
N5 Ag2 N7 127.7(2) . 2_554
N5 Ag2 N1 120.06(17) . .
N7 Ag2 N1 95.7(2) 2_554 .
N5 Ag2 N4 101.9(2) . 2
N7 Ag2 N4 97.3(3) 2_554 2
N1 Ag2 N4 112.3(2) . 2
N7 C1 C2 179.1(10) . .
C3 C2 C7 120.2(8) . .
C3 C2 C1 119.1(8) . .
C7 C2 C1 120.6(8) . .
C2 C3 C4 120.1(9) . .
C2 C3 H3 120.0 . .
C4 C3 H3 120.0 . .
C5 C4 C3 118.6(11) . .
C5 C4 H4 120.7 . .
C3 C4 H4 120.7 . .
C4 C5 C6 122.1(10) . .
C4 C5 H5 119.0 . .
C6 C5 H5 119.0 . .
C5 C6 C7 119.4(8) . .
C5 C6 C8 118.1(8) . .
C7 C6 C8 122.4(7) . .
C6 C7 C2 118.7(7) . .
C6 C7 H7 120.6 . .
C2 C7 H7 120.6 . .
O5 C8 C6 108.6(6) . .
O5 C8 H8A 110.0 . .
C6 C8 H8A 110.0 . .
O5 C8 H8B 110.0 . .
C6 C8 H8B 110.0 . .
H8A C8 H8B 108.4 . .
C10 C9 O5 124.4(6) . .
C10 C9 C14 120.5(6) . .
O5 C9 C14 115.1(6) . .
C9 C10 C11 120.9(7) . .
C9 C10 H10 119.6 . .
C11 C10 H10 119.6 . .
C12 C11 C10 119.0(7) . .
C12 C11 H11 120.5 . .
C10 C11 H11 120.5 . .
C11 C12 C13 120.5(7) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C12 C13 C14 120.4(7) . .
C12 C13 C15 117.1(7) . .
C14 C13 C15 122.3(7) . .
C13 C14 C9 118.6(6) . .
C13 C14 H14 120.7 . .
C9 C14 H14 120.7 . .
N6 C15 O4 111.7(6) . .
N6 C15 C13 126.5(7) . .
O4 C15 C13 121.9(7) . .
N5 C16 O4 110.5(6) . .
N5 C16 C17 128.8(7) . .
O4 C16 C17 120.7(6) . .
C22 C17 C18 120.3(7) . .
C22 C17 C16 121.8(6) . .
C18 C17 C16 117.9(6) . .
C19 C18 C17 118.9(7) . .
C19 C18 H18 120.6 . .
C17 C18 H18 120.6 . .
C18 C19 C20 122.5(7) . .
C18 C19 H19 118.7 . .
C20 C19 H19 118.7 . .
C21 C20 C19 118.5(7) . .
C21 C20 H20 120.8 . .
C19 C20 H20 120.8 . .
O6 C21 C20 123.7(6) . .
O6 C21 C22 115.5(6) . .
C20 C21 C22 120.7(6) . .
C21 C22 C17 119.1(6) . .
C21 C22 H22 120.5 . .
C17 C22 H22 120.5 . .
O6 C23 C24 109.5(5) . .
O6 C23 H23A 109.8 . .
C24 C23 H23A 109.8 . .
O6 C23 H23B 109.8 . .
C24 C23 H23B 109.8 . .
H23A C23 H23B 108.2 . .
C25 C24 C30 118.6(8) . .
C25 C24 C23 123.9(7) . .
C30 C24 C23 117.5(8) . .
C26 C25 C24 120.4(7) . .
C26 C25 H25 119.8 . .
C24 C25 H25 119.8 . .
C25 C26 C28 120.7(8) . .
C25 C26 C27 121.6(8) . .
C28 C26 C27 117.7(8) . .
N8 C27 C26 178.2(10) . .
C26 C28 C29 119.6(8) . .
C26 C28 H28 120.2 . .
C29 C28 H28 120.2 . .
C30 C29 C28 119.1(11) . .
C30 C29 H29 120.4 . .
C28 C29 H29 120.4 . .
C29 C30 C24 121.5(11) . .
C29 C30 H30 119.2 . .
C24 C30 H30 119.2 . .
N3 C31 C32 175.5(9) . .
C33 C32 C37 122.5(7) . .
C33 C32 C31 119.0(7) . .
C37 C32 C31 118.5(7) . .
C32 C33 C34 119.2(7) . .
C32 C33 H33 120.4 . .
C34 C33 H33 120.4 . .
C35 C34 C33 119.7(8) . .
C35 C34 H34 120.2 . .
C33 C34 H34 120.2 . .
C34 C35 C36 122.9(8) . .
C34 C35 H35 118.6 . .
C36 C35 H35 118.6 . .
C35 C36 C37 118.3(7) . .
C35 C36 C38 118.8(7) . .
C37 C36 C38 123.0(6) . .
C32 C37 C36 117.4(7) . .
C32 C37 H37 121.3 . .
C36 C37 H37 121.3 . .
O2 C38 C36 110.2(6) . .
O2 C38 H38A 109.6 . .
C36 C38 H38A 109.6 . .
O2 C38 H38B 109.6 . .
C36 C38 H38B 109.6 . .
H38A C38 H38B 108.1 . .
O2 C39 C44 114.8(6) . .
O2 C39 C40 125.6(6) . .
C44 C39 C40 119.6(6) . .
C41 C40 C39 121.8(7) . .
C41 C40 H40 119.1 . .
C39 C40 H40 119.1 . .
C40 C41 C42 119.4(7) . .
C40 C41 H41 120.3 . .
C42 C41 H41 120.3 . .
C43 C42 C41 118.2(6) . .
C43 C42 H42 120.9 . .
C41 C42 H42 120.9 . .
C42 C43 C44 122.8(7) . .
C42 C43 C45 117.0(6) . .
C44 C43 C45 120.2(6) . .
C39 C44 C43 118.2(6) . .
C39 C44 H44 120.9 . .
C43 C44 H44 120.9 . .
N1 C45 O1 111.6(6) . .
N1 C45 C43 125.3(6) . .
O1 C45 C43 123.1(6) . .
N2 C46 O1 112.5(6) . .
N2 C46 C47 123.8(6) . .
O1 C46 C47 123.7(6) . .
C48 C47 C52 121.0(6) . .
C48 C47 C46 117.4(6) . .
C52 C47 C46 121.4(6) . .
C49 C48 C47 119.1(7) . .
C49 C48 H48 120.5 . .
C47 C48 H48 120.5 . .
C50 C49 C48 120.4(7) . .
C50 C49 H49 119.8 . .
C48 C49 H49 119.8 . .
C49 C50 C51 120.5(7) . .
C49 C50 H50 119.7 . .
C51 C50 H50 119.7 . .
O3 C51 C50 114.8(6) . .
O3 C51 C52 123.4(7) . .
C50 C51 C52 121.8(7) . .
C51 C52 C47 117.1(7) . .
C51 C52 H52 121.4 . .
C47 C52 H52 121.4 . .
O3 C53 C54 108.7(5) . .
O3 C53 H53A 110.0 . .
C54 C53 H53A 110.0 . .
O3 C53 H53B 110.0 . .
C54 C53 H53B 110.0 . .
H53A C53 H53B 108.3 . .
C59 C54 C55 119.2(6) . .
C59 C54 C53 118.4(6) . .
C55 C54 C53 122.4(6) . .
C54 C55 C56 121.3(7) . .
C54 C55 H55 119.3 . .
C56 C55 H55 119.3 . .
C57 C56 C55 119.6(7) . .
C57 C56 H56 120.2 . .
C55 C56 H56 120.2 . .
C58 C57 C56 117.6(7) . .
C58 C57 H57 121.2 . .
C56 C57 H57 121.2 . .
C57 C58 C59 121.9(6) . .
C57 C58 C60 121.0(7) . .
C59 C58 C60 117.1(7) . .
C54 C59 C58 120.3(6) . .
C54 C59 H59 119.8 . .
C58 C59 H59 119.8 . .
N4 C60 C58 178.4(8) . .
O7 C61 C62 108.2(11) . .
O7 C61 H61A 110.0 . .
C62 C61 H61A 110.0 . .
O7 C61 H61B 110.0 . .
C62 C61 H61B 110.0 . .
H61A C61 H61B 108.4 . .
C63 C62 C61 103.1(11) . .
C63 C62 H62A 111.1 . .
C61 C62 H62A 111.1 . .
C63 C62 H62B 111.1 . .
C61 C62 H62B 111.1 . .
H62A C62 H62B 109.1 . .
C62 C63 C64 106.6(11) . .
C62 C63 H63A 110.4 . .
C64 C63 H63A 110.4 . .
C62 C63 H63B 110.4 . .
C64 C63 H63B 110.4 . .
H63A C63 H63B 108.6 . .
O7 C64 C63 105.3(10) . .
O7 C64 H64A 110.7 . .
C63 C64 H64A 110.7 . .
O7 C64 H64B 110.7 . .
C63 C64 H64B 110.7 . .
H64A C64 H64B 108.8 . .
C68 C67 C66 100.9(8) . .
C68 C67 H67A 111.6 . .
C66 C67 H67A 111.6 . .
C68 C67 H67B 111.6 . .
C66 C67 H67B 111.6 . .
H67A C67 H67B 109.4 . .
C65 C66 C67 100.1(8) . .
C65 C66 H66A 111.8 . .
C67 C66 H66A 111.8 . .
C65 C66 H66B 111.8 . .
C67 C66 H66B 111.8 . .
H66A C66 H66B 109.5 . .
O8 C65 C66 94.3(16) . .
O8 C65 H65A 112.9 . .
C66 C65 H65A 112.9 . .
O8 C65 H65B 112.9 . .
C66 C65 H65B 112.9 . .
H65A C65 H65B 110.3 . .
C65 O8 C68 128(2) . .
C45 N1 N2 106.8(5) . .
C45 N1 Ag2 133.0(5) . .
N2 N1 Ag2 118.6(4) . .
C46 N2 N1 105.8(5) . .
C46 N2 Ag1 133.0(5) . .
N1 N2 Ag1 119.9(4) . .
C31 N3 Ag1 154.4(7) . 2_554
C60 N4 Ag2 146.7(6) . 2_554
C16 N5 N6 107.3(5) . .
C16 N5 Ag2 135.3(5) . .
N6 N5 Ag2 117.2(4) . .
C15 N6 N5 106.8(5) . .
C15 N6 Ag1 129.6(5) . .
N5 N6 Ag1 122.5(4) . .
C1 N7 Ag2 151.4(7) . 2
C27 N8 Ag1 158.0(7) . 2
C46 O1 C45 103.2(6) . .
C39 O2 C38 116.0(6) . .
C51 O3 C53 117.9(5) . .
C15 O4 C16 103.7(6) . .
C9 O5 C8 116.5(5) . .
C21 O6 C23 115.8(5) . .
C64 O7 C61 111.0(10) . .
O8 C68 C67 91.2(15) . .
O8 C68 H68A 113.4 . .
C67 C68 H68A 113.4 . .
O8 C68 H68B 113.4 . .
C67 C68 H68B 113.4 . .
H68A C68 H68B 110.7 . .
F5 P1 F1 94.8(6) . .
F5 P1 F3 176.3(6) . .
F1 P1 F3 89.0(5) . .
F5 P1 F4 91.2(7) . .
F1 P1 F4 91.4(4) . .
F3 P1 F4 89.2(5) . .
F5 P1 F2 92.1(6) . .
F1 P1 F2 88.8(4) . .
F3 P1 F2 87.5(5) . .
F4 P1 F2 176.6(5) . .
F5 P1 F6 89.5(6) . .
F1 P1 F6 175.6(6) . .
F3 P1 F6 86.8(6) . .
F4 P1 F6 89.5(4) . .
F2 P1 F6 90.0(4) . .
F12 P2 F10 91.5(7) . .
F12 P2 F11 91.1(7) . .
F10 P2 F11 92.3(6) . .
F12 P2 F9 177.5(7) . .
F10 P2 F9 89.1(5) . .
F11 P2 F9 91.3(6) . .
F12 P2 F7 90.7(6) . .
F10 P2 F7 176.6(6) . .
F11 P2 F7 90.1(5) . .
F9 P2 F7 88.6(6) . .
F12 P2 F8 93.5(6) . .
F10 P2 F8 90.7(5) . .
F11 P2 F8 174.4(6) . .
F9 P2 F8 84.1(6) . .
F7 P2 F8 86.6(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N6 2.228(6) .
Ag1 N8 2.251(7) 2_554
Ag1 N2 2.275(7) .
Ag1 N3 2.349(7) 2
Ag2 N5 2.253(6) .
Ag2 N7 2.277(7) 2_554
Ag2 N1 2.319(6) .
Ag2 N4 2.358(7) 2
C1 N7 1.154(11) .
C1 C2 1.415(12) .
C2 C3 1.377(13) .
C2 C7 1.408(10) .
C3 C4 1.382(16) .
C3 H3 0.9500 .
C4 C5 1.365(15) .
C4 H4 0.9500 .
C5 C6 1.370(12) .
C5 H5 0.9500 .
C6 C7 1.384(10) .
C6 C8 1.502(10) .
C7 H7 0.9500 .
C8 O5 1.419(8) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.368(10) .
C9 O5 1.381(8) .
C9 C14 1.394(10) .
C10 C11 1.400(11) .
C10 H10 0.9500 .
C11 C12 1.369(12) .
C11 H11 0.9500 .
C12 C13 1.392(10) .
C12 H12 0.9500 .
C13 C14 1.393(10) .
C13 C15 1.444(11) .
C14 H14 0.9500 .
C15 N6 1.281(10) .
C15 O4 1.363(9) .
C16 N5 1.288(9) .
C16 O4 1.379(8) .
C16 C17 1.448(11) .
C17 C22 1.387(9) .
C17 C18 1.410(10) .
C18 C19 1.332(12) .
C18 H18 0.9500 .
C19 C20 1.395(11) .
C19 H19 0.9500 .
C20 C21 1.380(10) .
C20 H20 0.9500 .
C21 O6 1.369(8) .
C21 C22 1.383(10) .
C22 H22 0.9500 .
C23 O6 1.434(8) .
C23 C24 1.514(9) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.385(11) .
C24 C30 1.407(13) .
C25 C26 1.384(10) .
C25 H25 0.9500 .
C26 C28 1.386(13) .
C26 C27 1.429(13) .
C27 N8 1.142(11) .
C28 C29 1.407(15) .
C28 H28 0.9500 .
C29 C30 1.370(15) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 N3 1.134(11) .
C31 C32 1.434(11) .
C32 C33 1.374(11) .
C32 C37 1.404(10) .
C33 C34 1.376(12) .
C33 H33 0.9500 .
C34 C35 1.355(11) .
C34 H34 0.9500 .
C35 C36 1.394(10) .
C35 H35 0.9500 .
C36 C37 1.409(11) .
C36 C38 1.488(9) .
C37 H37 0.9500 .
C38 O2 1.422(9) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C39 O2 1.372(8) .
C39 C44 1.395(10) .
C39 C40 1.399(10) .
C40 C41 1.367(10) .
C40 H40 0.9500 .
C41 C42 1.425(10) .
C41 H41 0.9500 .
C42 C43 1.374(9) .
C42 H42 0.9500 .
C43 C44 1.398(9) .
C43 C45 1.467(10) .
C44 H44 0.9500 .
C45 N1 1.303(9) .
C45 O1 1.361(8) .
C46 N2 1.300(10) .
C46 O1 1.357(8) .
C46 C47 1.472(10) .
C47 C48 1.391(10) .
C47 C52 1.412(9) .
C48 C49 1.388(11) .
C48 H48 0.9500 .
C49 C50 1.359(11) .
C49 H49 0.9500 .
C50 C51 1.374(10) .
C50 H50 0.9500 .
C51 O3 1.362(8) .
C51 C52 1.381(10) .
C52 H52 0.9500 .
C53 O3 1.405(8) .
C53 C54 1.514(9) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 C59 1.366(9) .
C54 C55 1.367(10) .
C55 C56 1.414(11) .
C55 H55 0.9500 .
C56 C57 1.407(11) .
C56 H56 0.9500 .
C57 C58 1.375(11) .
C57 H57 0.9500 .
C58 C59 1.406(9) .
C58 C60 1.434(9) .
C59 H59 0.9500 .
C60 N4 1.138(9) .
C61 O7 1.402(9) .
C61 C62 1.523(10) .
C61 H61A 0.9900 .
C61 H61B 0.9900 .
C62 C63 1.507(10) .
C62 H62A 0.9900 .
C62 H62B 0.9900 .
C63 C64 1.525(10) .
C63 H63A 0.9900 .
C63 H63B 0.9900 .
C64 O7 1.384(9) .
C64 H64A 0.9900 .
C64 H64B 0.9900 .
C67 C68 1.515(10) .
C67 C66 1.536(10) .
C67 H67A 0.9900 .
C67 H67B 0.9900 .
C66 C65 1.516(10) .
C66 H66A 0.9900 .
C66 H66B 0.9900 .
C65 O8 1.361(10) .
C65 H65A 0.9900 .
C65 H65B 0.9900 .
O8 C68 1.368(10) .
F1 P1 1.556(7) .
F2 P1 1.604(7) .
F3 P1 1.586(9) .
F4 P1 1.589(7) .
F5 P1 1.499(9) .
F6 P1 1.609(8) .
F7 P2 1.594(8) .
F8 P2 1.594(10) .
F9 P2 1.585(9) .
F10 P2 1.528(7) .
F11 P2 1.538(9) .
F12 P2 1.495(9) .
N1 N2 1.400(9) .
N3 Ag1 2.349(7) 2_554
N4 Ag2 2.358(7) 2_554
N5 N6 1.401(9) .
N7 Ag2 2.277(7) 2
N8 Ag1 2.251(7) 2
C68 H68A 0.9900 .
C68 H68B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N7 C1 C2 C3 -15(52) . .
N7 C1 C2 C7 167(100) . .
C7 C2 C3 C4 4.2(16) . .
C1 C2 C3 C4 -173.8(10) . .
C2 C3 C4 C5 -9.6(19) . .
C3 C4 C5 C6 12(2) . .
C4 C5 C6 C7 -9(2) . .
C4 C5 C6 C8 175.2(12) . .
C5 C6 C7 C2 2.7(13) . .
C8 C6 C7 C2 178.8(7) . .
C3 C2 C7 C6 -0.7(12) . .
C1 C2 C7 C6 177.3(7) . .
C5 C6 C8 O5 -164.4(10) . .
C7 C6 C8 O5 19.4(10) . .
O5 C9 C10 C11 179.0(7) . .
C14 C9 C10 C11 -1.3(11) . .
C9 C10 C11 C12 0.3(11) . .
C10 C11 C12 C13 1.7(12) . .
C11 C12 C13 C14 -2.7(12) . .
C11 C12 C13 C15 173.6(7) . .
C12 C13 C14 C9 1.6(11) . .
C15 C13 C14 C9 -174.4(7) . .
C10 C9 C14 C13 0.4(11) . .
O5 C9 C14 C13 -179.9(6) . .
C12 C13 C15 N6 -35.7(11) . .
C14 C13 C15 N6 140.5(8) . .
C12 C13 C15 O4 143.9(7) . .
C14 C13 C15 O4 -39.9(11) . .
N5 C16 C17 C22 -148.2(7) . .
O4 C16 C17 C22 33.6(11) . .
N5 C16 C17 C18 30.4(12) . .
O4 C16 C17 C18 -147.8(7) . .
C22 C17 C18 C19 0.1(11) . .
C16 C17 C18 C19 -178.5(7) . .
C17 C18 C19 C20 0.9(13) . .
C18 C19 C20 C21 0.0(12) . .
C19 C20 C21 O6 179.7(7) . .
C19 C20 C21 C22 -1.9(11) . .
O6 C21 C22 C17 -178.6(6) . .
C20 C21 C22 C17 2.9(10) . .
C18 C17 C22 C21 -2.0(11) . .
C16 C17 C22 C21 176.5(6) . .
O6 C23 C24 C25 -3.7(11) . .
O6 C23 C24 C30 178.4(8) . .
C30 C24 C25 C26 -0.3(13) . .
C23 C24 C25 C26 -178.1(7) . .
C24 C25 C26 C28 1.1(12) . .
C24 C25 C26 C27 177.1(7) . .
C25 C26 C27 N8 -165(28) . .
C28 C26 C27 N8 11(29) . .
C25 C26 C28 C29 1.0(15) . .
C27 C26 C28 C29 -175.1(10) . .
C26 C28 C29 C30 -3.9(19) . .
C28 C29 C30 C24 5(2) . .
C25 C24 C30 C29 -2.7(17) . .
C23 C24 C30 C29 175.3(11) . .
N3 C31 C32 C33 26(12) . .
N3 C31 C32 C37 -153(12) . .
C37 C32 C33 C34 0.3(11) . .
C31 C32 C33 C34 -178.6(7) . .
C32 C33 C34 C35 0.4(12) . .
C33 C34 C35 C36 0.7(13) . .
C34 C35 C36 C37 -2.5(12) . .
C34 C35 C36 C38 177.5(7) . .
C33 C32 C37 C36 -2.1(11) . .
C31 C32 C37 C36 176.9(7) . .
C35 C36 C37 C32 3.0(10) . .
C38 C36 C37 C32 -177.0(7) . .
C35 C36 C38 O2 176.4(6) . .
C37 C36 C38 O2 -3.6(10) . .
O2 C39 C40 C41 -179.8(7) . .
C44 C39 C40 C41 -1.0(12) . .
C39 C40 C41 C42 0.8(12) . .
C40 C41 C42 C43 -1.4(11) . .
C41 C42 C43 C44 2.4(11) . .
C41 C42 C43 C45 -176.8(6) . .
O2 C39 C44 C43 -179.3(6) . .
C40 C39 C44 C43 1.8(10) . .
C42 C43 C44 C39 -2.6(10) . .
C45 C43 C44 C39 176.5(6) . .
C42 C43 C45 N1 33.1(10) . .
C44 C43 C45 N1 -146.1(7) . .
C42 C43 C45 O1 -144.0(7) . .
C44 C43 C45 O1 36.8(10) . .
N2 C46 C47 C48 -34.4(11) . .
O1 C46 C47 C48 146.4(7) . .
N2 C46 C47 C52 141.7(7) . .
O1 C46 C47 C52 -37.6(10) . .
C52 C47 C48 C49 -2.3(11) . .
C46 C47 C48 C49 173.7(7) . .
C47 C48 C49 C50 0.6(12) . .
C48 C49 C50 C51 1.3(13) . .
C49 C50 C51 O3 178.7(7) . .
C49 C50 C51 C52 -1.6(12) . .
O3 C51 C52 C47 179.6(6) . .
C50 C51 C52 C47 -0.1(11) . .
C48 C47 C52 C51 2.0(10) . .
C46 C47 C52 C51 -173.9(7) . .
O3 C53 C54 C59 -177.7(6) . .
O3 C53 C54 C55 2.7(9) . .
C59 C54 C55 C56 0.7(12) . .
C53 C54 C55 C56 -179.7(7) . .
C54 C55 C56 C57 0.6(13) . .
C55 C56 C57 C58 -1.9(12) . .
C56 C57 C58 C59 1.9(11) . .
C56 C57 C58 C60 -179.5(7) . .
C55 C54 C59 C58 -0.7(10) . .
C53 C54 C59 C58 179.7(6) . .
C57 C58 C59 C54 -0.7(11) . .
C60 C58 C59 C54 -179.3(6) . .
C57 C58 C60 N4 159(32) . .
C59 C58 C60 N4 -22(33) . .
O7 C61 C62 C63 6.8(19) . .
C61 C62 C63 C64 7.7(18) . .
C62 C63 C64 O7 -19.8(16) . .
C68 C67 C66 C65 51(2) . .
C67 C66 C65 O8 -33(2) . .
C66 C65 O8 C68 6(4) . .
O1 C45 N1 N2 -0.8(8) . .
C43 C45 N1 N2 -178.1(6) . .
O1 C45 N1 Ag2 -165.6(4) . .
C43 C45 N1 Ag2 17.1(11) . .
N5 Ag2 N1 C45 174.5(6) . .
N7 Ag2 N1 C45 34.4(7) 2_554 .
N4 Ag2 N1 C45 -65.9(7) 2 .
N5 Ag2 N1 N2 11.1(5) . .
N7 Ag2 N1 N2 -129.0(4) 2_554 .
N4 Ag2 N1 N2 130.7(4) 2 .
O1 C46 N2 N1 -1.0(8) . .
C47 C46 N2 N1 179.7(6) . .
O1 C46 N2 Ag1 165.1(5) . .
C47 C46 N2 Ag1 -14.2(11) . .
C45 N1 N2 C46 1.0(7) . .
Ag2 N1 N2 C46 168.4(5) . .
C45 N1 N2 Ag1 -167.2(5) . .
Ag2 N1 N2 Ag1 0.2(6) . .
N6 Ag1 N2 C46 -172.7(6) . .
N8 Ag1 N2 C46 -36.1(7) 2_554 .
N3 Ag1 N2 C46 72.6(7) 2 .
N6 Ag1 N2 N1 -8.2(5) . .
N8 Ag1 N2 N1 128.4(5) 2_554 .
N3 Ag1 N2 N1 -122.9(5) 2 .
C32 C31 N3 Ag1 -103(12) . 2_554
C58 C60 N4 Ag2 -17(33) . 2_554
O4 C16 N5 N6 -0.1(7) . .
C17 C16 N5 N6 -178.4(7) . .
O4 C16 N5 Ag2 -175.9(4) . .
C17 C16 N5 Ag2 5.7(12) . .
N7 Ag2 N5 C16 -74.2(8) 2_554 .
N1 Ag2 N5 C16 159.6(6) . .
N4 Ag2 N5 C16 34.9(7) 2 .
N7 Ag2 N5 N6 110.3(5) 2_554 .
N1 Ag2 N5 N6 -15.9(5) . .
N4 Ag2 N5 N6 -140.6(4) 2 .
O4 C15 N6 N5 -1.2(8) . .
C13 C15 N6 N5 178.4(7) . .
O4 C15 N6 Ag1 167.3(5) . .
C13 C15 N6 Ag1 -13.1(11) . .
C16 N5 N6 C15 0.7(7) . .
Ag2 N5 N6 C15 177.4(5) . .
C16 N5 N6 Ag1 -168.7(5) . .
Ag2 N5 N6 Ag1 8.0(6) . .
N8 Ag1 N6 C15 73.1(7) 2_554 .
N2 Ag1 N6 C15 -163.7(6) . .
N3 Ag1 N6 C15 -40.0(7) 2 .
N8 Ag1 N6 N5 -120.1(5) 2_554 .
N2 Ag1 N6 N5 3.1(6) . .
N3 Ag1 N6 N5 126.8(5) 2 .
C2 C1 N7 Ag2 75(52) . 2
C26 C27 N8 Ag1 -85(29) . 2
N2 C46 O1 C45 0.5(8) . .
C47 C46 O1 C45 179.9(7) . .
N1 C45 O1 C46 0.2(8) . .
C43 C45 O1 C46 177.6(6) . .
C44 C39 O2 C38 178.7(6) . .
C40 C39 O2 C38 -2.5(10) . .
C36 C38 O2 C39 -173.3(6) . .
C50 C51 O3 C53 176.7(6) . .
C52 C51 O3 C53 -3.0(10) . .
C54 C53 O3 C51 -179.6(6) . .
N6 C15 O4 C16 1.1(8) . .
C13 C15 O4 C16 -178.5(7) . .
N5 C16 O4 C15 -0.6(8) . .
C17 C16 O4 C15 177.9(6) . .
C10 C9 O5 C8 2.8(10) . .
C14 C9 O5 C8 -176.9(6) . .
C6 C8 O5 C9 178.5(6) . .
C20 C21 O6 C23 -4.5(10) . .
C22 C21 O6 C23 177.0(6) . .
C24 C23 O6 C21 -177.5(6) . .
C63 C64 O7 C61 25.1(15) . .
C62 C61 O7 C64 -20.7(18) . .
C65 O8 C68 C67 25(4) . .
C66 C67 C68 O8 -42.3(19) . .
