#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/72/7207238.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7207238
loop_
_publ_author_name
'Maekawa, Masahiko'
'Tominaga, Toshi'
'Sugimoto, Kunihisa'
'Okubo, Takashi'
'Kuroda-Sowa, Takayoshi'
'Munakata, Megumu'
'Kitagawa, Susumu'
_publ_section_title
;
 Framework dimensionality of copper(i) coordination polymers of
 4,4′-bipyrimidine controlled by anions and solvents
;
_journal_issue                   4
_journal_name_full               CrystEngComm
_journal_page_first              1345
_journal_paper_doi               10.1039/c1ce06328f
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C20 H20 Cl2 Cu3 N8 O8, Cl O4'
_chemical_formula_sum            'C20 H20 Cl3 Cu3 N8 O12'
_chemical_formula_weight         861.44
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 132.126(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.8073(9)
_cell_length_b                   13.2133(18)
_cell_length_c                   15.3486(11)
_cell_measurement_reflns_used    11447
_cell_measurement_temperature    108(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.78
_cell_volume                     3129.7(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      108(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_av_sigmaI/netI    0.0513
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            11447
_diffrn_reflns_theta_full        27.46
_diffrn_reflns_theta_max         27.46
_diffrn_reflns_theta_min         3.08
_exptl_absorpt_coefficient_mu    2.347
_exptl_absorpt_correction_T_max  0.9445
_exptl_absorpt_correction_T_min  0.7610
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.828
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1720
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.009
_refine_diff_density_min         -1.245
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     198
_refine_ls_number_reflns         3561
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0870
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0690P)²+14.6926P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1320
_refine_ls_wR_factor_ref         0.1475
_reflns_number_gt                2606
_reflns_number_total             3561
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c1ce06328f.txt
_cod_data_source_block
{[Cu3(bpm)2(C2H4)2](ClO4)3}n_Complex-2-CCDC829824
_cod_original_sg_symbol_Hall     '-C 2yc '
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7207238
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 'x, y, z'
2 '-x, y, -z+1/2'
3 'x+1/2, y+1/2, z'
4 '-x+1/2, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x, -y, z-1/2'
7 '-x+1/2, -y+1/2, -z'
8 'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
N4 N 0.1646(3) 0.3260(3) 0.2606(3) 0.0248(8) Uani 1 1 d .
C7 C 0.2427(3) 0.3553(4) 0.3599(4) 0.0266(10) Uani 1 1 d .
H7 H 0.2916 0.3200 0.3863 0.032 Uiso 1 1 calc R
C8 C 0.0965(3) 0.3789(3) 0.2263(4) 0.0241(10) Uani 1 1 d .
H8 H 0.0424 0.3596 0.1563 0.029 Uiso 1 1 calc R
C9 C 0.0943(5) 0.0952(5) 0.1791(6) 0.0518(18) Uani 1 1 d .
H9A H 0.1333 0.0551 0.2501 0.062 Uiso 1 1 calc R
H9B H 0.0387 0.1080 0.1559 0.062 Uiso 1 1 calc R
C10 C 0.0933(5) 0.0743(5) 0.0897(6) 0.0540(18) Uani 1 1 d .
H10A H 0.0370 0.0738 0.0104 0.065 Uiso 1 1 calc R
H10B H 0.1316 0.0209 0.1046 0.065 Uiso 1 1 calc R
Cu1 Cu 0.14767(4) 0.21149(4) 0.15983(5) 0.02428(18) Uani 1 1 d .
Cu2 Cu 0.0000 0.53414(6) 0.2500 0.0244(2) Uani 1 2 d S
N1 N 0.1648(2) 0.2854(3) 0.0621(3) 0.0213(8) Uani 1 1 d .
N3 N 0.0989(2) 0.4568(3) 0.2830(3) 0.0222(8) Uani 1 1 d .
C6 C 0.2521(3) 0.4366(4) 0.4240(4) 0.0266(10) Uani 1 1 d .
H6 H 0.3066 0.4575 0.4922 0.032 Uiso 1 1 calc R
C2 C 0.0960(3) 0.3261(4) -0.0402(4) 0.0231(9) Uani 1 1 d .
H2 H 0.0415 0.3034 -0.0727 0.028 Uiso 1 1 calc R
C5 C 0.1778(3) 0.4861(3) 0.3834(4) 0.0205(9) Uani 1 1 d .
N2 N 0.0991(2) 0.3963(3) -0.0994(3) 0.0218(8) Uani 1 1 d .
C4 C 0.1777(3) 0.5712(3) 0.4465(4) 0.0200(9) Uani 1 1 d .
C3 C 0.2521(3) 0.6130(4) 0.5484(4) 0.0258(10) Uani 1 1 d .
H3 H 0.3065 0.5935 0.5779 0.031 Uiso 1 1 calc R
C1 C 0.2432(3) 0.3148(4) 0.1055(4) 0.0240(10) Uani 1 1 d .
H1 H 0.2925 0.2864 0.1751 0.029 Uiso 1 1 calc R
Cl1 Cl 0.0000 0.10211(13) 0.7500 0.0259(4) Uani 1 2 d S
O2 O 0.0589(2) 0.0388(3) 0.8513(3) 0.0389(9) Uani 1 1 d .
O1 O 0.0485(2) 0.1639(3) 0.7352(4) 0.0521(12) Uani 1 1 d .
Cl2 Cl 0.35630(8) 0.10995(10) 0.39363(11) 0.0327(3) Uani 1 1 d .
O3 O 0.3026(4) 0.1759(5) 0.2960(6) 0.0327(3) Uani 0.621(4) 1 d P
O4 O 0.3587(4) 0.1336(5) 0.4853(5) 0.0327(3) Uani 0.621(4) 1 d P
O5 O 0.3250(4) 0.0039(4) 0.3536(5) 0.0327(3) Uani 0.621(4) 1 d P
O6 O 0.4434(4) 0.1114(4) 0.4381(5) 0.0327(3) Uani 0.621(4) 1 d P
O7 O 0.2887(7) 0.1445(8) 0.2711(9) 0.0327(3) Uani 0.379(4) 1 d P
O8 O 0.3175(7) 0.1281(8) 0.4467(9) 0.0327(3) Uani 0.379(4) 1 d P
O9 O 0.3815(7) 0.0168(7) 0.4032(8) 0.0327(3) Uani 0.379(4) 1 d P
O10 O 0.4255(6) 0.1892(7) 0.4475(8) 0.0327(3) Uani 0.379(4) 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C8 N4 C7 117.1(4) . .
C8 N4 Cu1 119.9(3) . .
C7 N4 Cu1 122.9(3) . .
N4 C7 C6 121.3(4) . .
N4 C7 H7 119.3 . .
C6 C7 H7 119.3 . .
N3 C8 N4 125.9(4) . .
N3 C8 H8 117.1 . .
N4 C8 H8 117.1 . .
C10 C9 Cu1 69.7(3) . .
C10 C9 H9A 116.7 . .
Cu1 C9 H9A 116.7 . .
C10 C9 H9B 116.7 . .
Cu1 C9 H9B 116.7 . .
H9A C9 H9B 113.7 . .
C9 C10 Cu1 70.3(3) . .
C9 C10 H10A 116.6 . .
Cu1 C10 H10A 116.6 . .
C9 C10 H10B 116.6 . .
Cu1 C10 H10B 116.6 . .
H10A C10 H10B 113.6 . .
N1 Cu1 N4 100.39(15) . .
N1 Cu1 C10 110.8(2) . .
N4 Cu1 C10 145.8(2) . .
N1 Cu1 C9 149.7(2) . .
N4 Cu1 C9 106.7(2) . .
C10 Cu1 C9 40.0(2) . .
N1 Cu1 O7 88.1(3) . .
N4 Cu1 O7 103.5(3) . .
C10 Cu1 O7 91.7(3) . .
C9 Cu1 O7 98.4(4) . .
N1 Cu1 O3 86.51(19) . .
N4 Cu1 O3 92.13(19) . .
C10 Cu1 O3 103.3(3) . .
C9 Cu1 O3 105.5(3) . .
O7 Cu1 O3 11.9(3) . .
N2 Cu2 N2 125.6(2) 6_566 5_565
N2 Cu2 N3 127.01(15) 6_566 2
N2 Cu2 N3 81.80(15) 5_565 2
N2 Cu2 N3 81.80(15) 6_566 .
N2 Cu2 N3 127.01(15) 5_565 .
N3 Cu2 N3 119.7(2) 2 .
C2 N1 C1 117.0(4) . .
C2 N1 Cu1 119.1(3) . .
C1 N1 Cu1 122.3(3) . .
C8 N3 C5 116.9(4) . .
C8 N3 Cu2 129.8(3) . .
C5 N3 Cu2 113.1(3) . .
C7 C6 C5 117.8(4) . .
C7 C6 H6 121.1 . .
C5 C6 H6 121.1 . .
N2 C2 N1 125.4(4) . .
N2 C2 H2 117.3 . .
N1 C2 H2 117.3 . .
N3 C5 C6 121.0(4) . .
N3 C5 C4 115.4(4) . .
C6 C5 C4 123.6(4) . .
C2 N2 C4 117.6(4) . 6_565
C2 N2 Cu2 128.5(3) . 5_565
C4 N2 Cu2 114.0(3) 6_565 5_565
N2 C4 C3 120.9(4) 6_566 .
N2 C4 C5 115.6(4) 6_566 .
C3 C4 C5 123.5(4) . .
C4 C3 C1 117.8(4) . 6_566
C4 C3 H3 121.1 . .
C1 C3 H3 121.1 6_566 .
N1 C1 C3 121.2(4) . 6_565
N1 C1 H1 119.4 . .
C3 C1 H1 119.4 6_565 .
O1 Cl1 O1 110.4(4) . 2_556
O1 Cl1 O2 109.9(3) . 2_556
O1 Cl1 O2 108.9(2) 2_556 2_556
O1 Cl1 O2 108.9(2) . .
O1 Cl1 O2 109.9(3) 2_556 .
O2 Cl1 O2 108.8(4) 2_556 .
O9 Cl2 O4 110.7(5) . .
O9 Cl2 O3 132.1(5) . .
O4 Cl2 O3 113.2(4) . .
O9 Cl2 O6 71.2(5) . .
O4 Cl2 O6 109.4(4) . .
O3 Cl2 O6 109.9(4) . .
O9 Cl2 O7 113.8(6) . .
O4 Cl2 O7 124.7(5) . .
O3 Cl2 O7 19.9(4) . .
O6 Cl2 O7 114.9(5) . .
O9 Cl2 O5 36.3(4) . .
O4 Cl2 O5 109.4(3) . .
O3 Cl2 O5 109.0(3) . .
O6 Cl2 O5 105.6(3) . .
O7 Cl2 O5 89.2(5) . .
O9 Cl2 O10 115.5(6) . .
O4 Cl2 O10 85.3(4) . .
O3 Cl2 O10 86.4(5) . .
O6 Cl2 O10 45.2(4) . .
O7 Cl2 O10 103.2(6) . .
O5 Cl2 O10 150.9(4) . .
O9 Cl2 O8 114.3(6) . .
O4 Cl2 O8 25.2(4) . .
O3 Cl2 O8 98.4(5) . .
O6 Cl2 O8 134.5(5) . .
O7 Cl2 O8 104.0(6) . .
O5 Cl2 O8 97.4(5) . .
O10 Cl2 O8 104.8(6) . .
O7 O3 Cl2 86.5(18) . .
O7 O3 Cu1 75.6(18) . .
Cl2 O3 Cu1 132.5(4) . .
O8 O4 Cl2 85.6(12) . .
O9 O5 Cl2 60.4(7) . .
O10 O6 Cl2 70.0(6) . .
O10 O6 O9 119.3(7) . .
Cl2 O6 O9 50.4(4) . .
O3 O7 Cl2 73.6(17) . .
O3 O7 Cu1 92.5(19) . .
Cl2 O7 Cu1 134.3(6) . .
O4 O8 Cl2 69.2(11) . .
O5 O9 Cl2 83.3(8) . .
O5 O9 O6 137.6(10) . .
Cl2 O9 O6 58.4(4) . .
O6 O10 Cl2 64.8(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N4 C8 1.332(6) .
N4 C7 1.338(6) .
N4 Cu1 2.019(4) .
C7 C6 1.380(7) .
C7 H7 0.9300 .
C8 N3 1.326(6) .
C8 H8 0.9300 .
C9 C10 1.385(8) .
C9 Cu1 2.030(5) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 Cu1 2.023(6) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
Cu1 N1 2.012(4) .
Cu1 O7 2.363(11) .
Cu1 O3 2.438(7) .
Cu2 N2 2.011(4) 6_566
Cu2 N2 2.011(4) 5_565
Cu2 N3 2.034(4) 2
Cu2 N3 2.034(4) .
N1 C2 1.337(6) .
N1 C1 1.341(6) .
N3 C5 1.351(6) .
C6 C5 1.383(6) .
C6 H6 0.9300 .
C2 N2 1.330(6) .
C2 H2 0.9300 .
C5 C4 1.485(6) .
N2 C4 1.346(6) 6_565
N2 Cu2 2.011(4) 5_565
C4 N2 1.346(6) 6_566
C4 C3 1.377(6) .
C3 C1 1.391(7) 6_566
C3 H3 0.9300 .
C1 C3 1.391(7) 6_565
C1 H1 0.9300 .
Cl1 O1 1.431(4) .
Cl1 O1 1.431(4) 2_556
Cl1 O2 1.436(4) 2_556
Cl1 O2 1.436(4) .
Cl2 O9 1.307(10) .
Cl2 O4 1.409(6) .
Cl2 O3 1.417(7) .
Cl2 O6 1.446(6) .
Cl2 O7 1.474(11) .
Cl2 O5 1.493(6) .
Cl2 O10 1.502(10) .
Cl2 O8 1.503(10) .
O3 O7 0.503(11) .
O4 O8 0.641(10) .
O5 O9 0.890(10) .
O6 O10 1.134(11) .
O6 O9 1.606(12) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C8 N4 C7 C6 0.1(7) . .
Cu1 N4 C7 C6 177.2(4) . .
C7 N4 C8 N3 -1.5(7) . .
Cu1 N4 C8 N3 -178.7(4) . .
C8 N4 Cu1 N1 92.3(4) . .
C7 N4 Cu1 N1 -84.7(4) . .
C8 N4 Cu1 C10 -63.3(6) . .
C7 N4 Cu1 C10 119.7(5) . .
C8 N4 Cu1 C9 -74.0(4) . .
C7 N4 Cu1 C9 109.0(4) . .
C8 N4 Cu1 O7 -177.2(4) . .
C7 N4 Cu1 O7 5.8(5) . .
C8 N4 Cu1 O3 179.1(4) . .
C7 N4 Cu1 O3 2.1(4) . .
C9 C10 Cu1 N1 -170.3(4) . .
C9 C10 Cu1 N4 -16.1(7) . .
C9 C10 Cu1 O7 101.1(5) . .
C9 C10 Cu1 O3 98.4(5) . .
C10 C9 Cu1 N1 18.2(8) . .
C10 C9 Cu1 N4 170.6(4) . .
C10 C9 Cu1 O7 -82.5(5) . .
C10 C9 Cu1 O3 -92.3(5) . .
N4 Cu1 N1 C2 -90.7(3) . .
C10 Cu1 N1 C2 74.9(4) . .
C9 Cu1 N1 C2 62.5(6) . .
O7 Cu1 N1 C2 166.0(4) . .
O3 Cu1 N1 C2 177.8(4) . .
N4 Cu1 N1 C1 74.4(4) . .
C10 Cu1 N1 C1 -120.0(4) . .
C9 Cu1 N1 C1 -132.4(5) . .
O7 Cu1 N1 C1 -28.9(4) . .
O3 Cu1 N1 C1 -17.1(4) . .
N4 C8 N3 C5 1.5(7) . .
N4 C8 N3 Cu2 -172.8(3) . .
N2 Cu2 N3 C8 175.1(4) 6_566 .
N2 Cu2 N3 C8 -56.0(5) 5_565 .
N3 Cu2 N3 C8 46.9(4) 2 .
N2 Cu2 N3 C5 0.6(3) 6_566 .
N2 Cu2 N3 C5 129.6(3) 5_565 .
N3 Cu2 N3 C5 -127.5(3) 2 .
N4 C7 C6 C5 1.2(7) . .
C1 N1 C2 N2 -3.2(7) . .
Cu1 N1 C2 N2 162.7(4) . .
C8 N3 C5 C6 0.0(7) . .
Cu2 N3 C5 C6 175.2(4) . .
C8 N3 C5 C4 -178.0(4) . .
Cu2 N3 C5 C4 -2.8(5) . .
C7 C6 C5 N3 -1.3(7) . .
C7 C6 C5 C4 176.6(4) . .
N1 C2 N2 C4 0.6(7) . 6_565
N1 C2 N2 Cu2 -177.4(3) . 5_565
N3 C5 C4 N2 4.5(6) . 6_566
C6 C5 C4 N2 -173.5(4) . 6_566
N3 C5 C4 C3 -178.1(4) . .
C6 C5 C4 C3 3.9(7) . .
N2 C4 C3 C1 3.7(7) 6_566 6_566
C5 C4 C3 C1 -173.5(4) . 6_566
C2 N1 C1 C3 2.2(7) . 6_565
Cu1 N1 C1 C3 -163.2(4) . 6_565
O9 Cl2 O3 O7 26(2) . .
O4 Cl2 O3 O7 -129.2(18) . .
O6 Cl2 O3 O7 108.2(18) . .
O5 Cl2 O3 O7 -7.1(19) . .
O10 Cl2 O3 O7 147.5(19) . .
O8 Cl2 O3 O7 -108.0(19) . .
O9 Cl2 O3 Cu1 92.6(8) . .
O4 Cl2 O3 Cu1 -62.5(6) . .
O6 Cl2 O3 Cu1 174.9(4) . .
O7 Cl2 O3 Cu1 66.7(18) . .
O5 Cl2 O3 Cu1 59.6(6) . .
O10 Cl2 O3 Cu1 -145.7(6) . .
O8 Cl2 O3 Cu1 -41.3(7) . .
N1 Cu1 O3 O7 -97.2(18) . .
N4 Cu1 O3 O7 162.5(18) . .
C10 Cu1 O3 O7 13.3(18) . .
C9 Cu1 O3 O7 54.6(18) . .
N1 Cu1 O3 Cl2 -168.4(5) . .
N4 Cu1 O3 Cl2 91.3(5) . .
C10 Cu1 O3 Cl2 -57.9(6) . .
C9 Cu1 O3 Cl2 -16.6(6) . .
O7 Cu1 O3 Cl2 -71.2(18) . .
O9 Cl2 O4 O8 -103.2(13) . .
O3 Cl2 O4 O8 57.3(13) . .
O6 Cl2 O4 O8 -179.7(12) . .
O7 Cl2 O4 O8 38.6(14) . .
O5 Cl2 O4 O8 -64.5(13) . .
O10 Cl2 O4 O8 141.4(13) . .
O4 Cl2 O5 O9 -98.9(8) . .
O3 Cl2 O5 O9 136.8(8) . .
O6 Cl2 O5 O9 18.8(8) . .
O7 Cl2 O5 O9 134.4(9) . .
O10 Cl2 O5 O9 18.0(12) . .
O8 Cl2 O5 O9 -121.6(9) . .
O9 Cl2 O6 O10 -167.9(7) . .
O4 Cl2 O6 O10 -61.8(6) . .
O3 Cl2 O6 O10 63.1(6) . .
O7 Cl2 O6 O10 84.0(7) . .
O5 Cl2 O6 O10 -179.5(6) . .
O8 Cl2 O6 O10 -62.0(8) . .
O4 Cl2 O6 O9 106.1(5) . .
O3 Cl2 O6 O9 -129.0(5) . .
O7 Cl2 O6 O9 -108.1(6) . .
O5 Cl2 O6 O9 -11.6(5) . .
O10 Cl2 O6 O9 167.9(7) . .
O8 Cl2 O6 O9 105.9(7) . .
Cu1 O3 O7 Cl2 -135.7(4) . .
Cl2 O3 O7 Cu1 135.7(4) . .
O9 Cl2 O7 O3 -159.2(17) . .
O4 Cl2 O7 O3 60(2) . .
O6 Cl2 O7 O3 -79.9(19) . .
O5 Cl2 O7 O3 173.2(18) . .
O10 Cl2 O7 O3 -33.4(19) . .
O8 Cl2 O7 O3 75.9(19) . .
O9 Cl2 O7 Cu1 123.6(8) . .
O4 Cl2 O7 Cu1 -17.1(11) . .
O3 Cl2 O7 Cu1 -77.1(18) . .
O6 Cl2 O7 Cu1 -157.0(7) . .
O5 Cl2 O7 Cu1 96.1(8) . .
O10 Cl2 O7 Cu1 -110.5(8) . .
O8 Cl2 O7 Cu1 -1.3(10) . .
N1 Cu1 O7 O3 82.2(18) . .
N4 Cu1 O7 O3 -18.0(19) . .
C10 Cu1 O7 O3 -167.1(18) . .
C9 Cu1 O7 O3 -127.5(18) . .
N1 Cu1 O7 Cl2 151.6(8) . .
N4 Cu1 O7 Cl2 51.4(9) . .
C10 Cu1 O7 Cl2 -97.6(9) . .
C9 Cu1 O7 Cl2 -58.1(9) . .
O3 Cu1 O7 Cl2 69.4(17) . .
O9 Cl2 O8 O4 87.3(13) . .
O3 Cl2 O8 O4 -128.6(12) . .
O6 Cl2 O8 O4 0.4(16) . .
O7 Cl2 O8 O4 -148.1(12) . .
O5 Cl2 O8 O4 120.9(12) . .
O10 Cl2 O8 O4 -40.1(13) . .
Cl2 O5 O9 O6 -24.5(11) . .
O4 Cl2 O9 O5 94.9(7) . .
O3 Cl2 O9 O5 -60.7(10) . .
O6 Cl2 O9 O5 -160.9(8) . .
O7 Cl2 O9 O5 -51.3(9) . .
O10 Cl2 O9 O5 -170.4(7) . .
O8 Cl2 O9 O5 67.9(9) . .
O4 Cl2 O9 O6 -104.2(4) . .
O3 Cl2 O9 O6 100.2(6) . .
O7 Cl2 O9 O6 109.6(6) . .
O5 Cl2 O9 O6 160.9(8) . .
O10 Cl2 O9 O6 -9.5(6) . .
O8 Cl2 O9 O6 -131.2(5) . .
O10 O6 O9 O5 41.9(17) . .
Cl2 O6 O9 O5 28.9(13) . .
O10 O6 O9 Cl2 13.1(8) . .
O9 O6 O10 Cl2 -10.7(6) . .
O9 Cl2 O10 O6 12.7(7) . .
O4 Cl2 O10 O6 123.4(5) . .
O3 Cl2 O10 O6 -122.9(6) . .
O7 Cl2 O10 O6 -112.0(6) . .
O5 Cl2 O10 O6 1.0(11) . .
O8 Cl2 O10 O6 139.4(6) . .
