#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:07:04 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180412 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/81/7208158.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208158
loop_
_publ_author_name
'Sha, Jing-Quan'
'Sun, Jing-Wen'
'Wang, Cheng'
'Li, Guang-Ming'
'Yan, Peng-Fei'
'Li, Meng-Ting'
'Liu, Ming-Yuan'
_publ_section_title
;
 Syntheses of POM-templated MOFs containing the isomeric pyridyltetrazole
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              5053
_journal_paper_doi               10.1039/c2ce00025c
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'C60 H40 Ag14 Ge2 Mo24 N50 Na2 O81'
_chemical_formula_sum            'C60 H40 Ag14 Ge2 Mo24 N50 Na2 O81'
_chemical_formula_weight         6761.36
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.776(5)
_cell_angle_beta                 105.206(5)
_cell_angle_gamma                104.265(5)
_cell_formula_units_Z            1
_cell_length_a                   12.004(5)
_cell_length_b                   13.943(5)
_cell_length_c                   22.746(5)
_cell_measurement_temperature    293(2)
_cell_volume                     3504(2)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0586
_diffrn_reflns_av_sigmaI/netI    0.1458
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            17391
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.94
_exptl_absorpt_coefficient_mu    4.508
_exptl_absorpt_correction_T_max  0.637
_exptl_absorpt_correction_T_min  0.449
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   adabs(Sheldrick,1996)
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.204
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3150
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.1
_refine_diff_density_max         3.085
_refine_diff_density_min         -1.693
_refine_diff_density_rms         0.320
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1054
_refine_ls_number_reflns         12352
_refine_ls_number_restraints     156
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.1517
_refine_ls_R_factor_gt           0.0660
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1016P)²+6.1097P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1580
_refine_ls_wR_factor_ref         0.2140
_reflns_number_gt                6241
_reflns_number_total             12352
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce00025c.txt
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7208158
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7851(16) 0.3409(14) 0.7425(9) 0.023(4) Uani 1 1 d U
C2 C 0.6952(17) 0.2870(13) 0.6848(9) 0.023(4) Uani 1 1 d U
C3 C 0.7120(18) 0.2224(16) 0.6471(10) 0.035(6) Uani 1 1 d .
H3 H 0.7850 0.2071 0.6572 0.042 Uiso 1 1 calc R
C4 C 0.628(2) 0.1750(19) 0.5928(11) 0.054(7) Uani 1 1 d .
H4 H 0.6472 0.1289 0.5674 0.064 Uiso 1 1 calc R
C5 C 0.501(2) 0.2582(17) 0.6138(10) 0.036(6) Uani 1 1 d .
H5 H 0.4273 0.2718 0.6031 0.043 Uiso 1 1 calc R
C6 C 0.5841(16) 0.3073(15) 0.6690(10) 0.027(5) Uani 1 1 d .
H6 H 0.5667 0.3532 0.6953 0.032 Uiso 1 1 calc R
C7 C 1.0143(19) 0.3526(17) 0.5489(10) 0.039(6) Uani 1 1 d .
C8 C 1.100(2) 0.4525(17) 0.5547(12) 0.055(8) Uani 1 1 d .
C9 C 1.1730(18) 0.4635(17) 0.5126(11) 0.040(6) Uani 1 1 d .
H24 H 1.1629 0.4091 0.4825 0.047 Uiso 1 1 calc R
C10 C 1.252(2) 0.548(2) 0.5163(13) 0.062(8) Uani 1 1 d .
H21 H 1.3014 0.5549 0.4905 0.075 Uiso 1 1 calc R
C11 C 1.1154(19) 0.5330(16) 0.5933(12) 0.043(6) Uani 1 1 d .
H18 H 1.0659 0.5313 0.6187 0.052 Uiso 1 1 calc R
C12 C 1.201(2) 0.6192(16) 0.5977(13) 0.049(7) Uani 1 1 d .
H19 H 1.2152 0.6721 0.6296 0.059 Uiso 1 1 calc R
C13 C 1.3125(19) 0.3253(15) 0.7545(9) 0.033(5) Uani 1 1 d .
C14 C 1.2937(16) 0.2398(14) 0.7085(9) 0.025(5) Uani 1 1 d .
C15 C 1.2200(18) 0.2265(15) 0.6498(10) 0.032(5) Uani 1 1 d .
H8 H 1.1831 0.2753 0.6369 0.038 Uiso 1 1 calc R
C16 C 1.2011(19) 0.1387(15) 0.6096(10) 0.031(5) Uani 1 1 d .
H29 H 1.1532 0.1313 0.5690 0.038 Uiso 1 1 calc R
C17 C 1.359(2) 0.1653(15) 0.7232(11) 0.045(6) Uani 1 1 d .
H30 H 1.4238 0.1760 0.7586 0.054 Uiso 1 1 calc R
C18 C 1.317(2) 0.0807(17) 0.6816(11) 0.047(6) Uani 1 1 d .
H27 H 1.3418 0.0255 0.6935 0.057 Uiso 1 1 calc R
C19 C 1.2211(18) 0.5762(14) 1.0099(9) 0.025(4) Uani 1 1 d U
C20 C 1.1352(17) 0.6405(14) 1.0147(9) 0.021(4) Uani 1 1 d U
C21 C 1.165(2) 0.7237(16) 1.0537(10) 0.044(6) Uani 1 1 d .
H12 H 1.2412 0.7480 1.0822 0.053 Uiso 1 1 calc R
C22 C 1.078(2) 0.7762(19) 1.0516(12) 0.057(7) Uani 1 1 d U
H13 H 1.0977 0.8348 1.0803 0.068 Uiso 1 1 calc R
C23 C 0.9455(18) 0.6625(15) 0.9713(11) 0.033(5) Uani 1 1 d U
H9 H 0.8703 0.6398 0.9417 0.040 Uiso 1 1 calc R
C24 C 1.0229(17) 0.6056(14) 0.9700(9) 0.024(4) Uani 1 1 d U
H23 H 1.0020 0.5471 0.9411 0.028 Uiso 1 1 calc R
C25 C 1.424(2) 0.8242(16) 0.9970(14) 0.051(7) Uani 1 1 d .
C26 C 1.363(2) 0.9088(17) 1.0018(12) 0.043(6) Uani 1 1 d U
C27 C 1.398(2) 0.9785(17) 1.0530(12) 0.048(7) Uani 1 1 d .
H15 H 1.4561 0.9755 1.0882 0.058 Uiso 1 1 calc R
C28 C 1.342(2) 1.0572(19) 1.0516(15) 0.057(8) Uani 1 1 d .
H26 H 1.3645 1.1077 1.0860 0.069 Uiso 1 1 calc R
C29 C 1.279(3) 0.9168(19) 0.9503(15) 0.076(10) Uani 1 1 d .
H25 H 1.2540 0.8669 0.9154 0.091 Uiso 1 1 calc R
C30 C 1.232(2) 0.990(2) 0.9482(15) 0.067(9) Uani 1 1 d .
H28 H 1.1815 0.9967 0.9108 0.081 Uiso 1 1 calc R
N1 N 0.7576(14) 0.3804(12) 0.7933(8) 0.031(4) Uani 1 1 d U
N2 N 0.8663(14) 0.4280(12) 0.8360(7) 0.026(3) Uani 1 1 d U
N3 N 0.9519(13) 0.4170(12) 0.8104(8) 0.029(4) Uani 1 1 d U
N5 N 0.5228(15) 0.1896(13) 0.5737(7) 0.031(4) Uani 1 1 d .
N6 N 0.9741(15) 0.3144(13) 0.5938(8) 0.034(4) Uani 1 1 d .
N7 N 0.8995(15) 0.2235(13) 0.5661(8) 0.034(4) Uani 1 1 d .
N8 N 0.9029(16) 0.2071(12) 0.5089(8) 0.037(5) Uani 1 1 d .
N9 N 0.9778(16) 0.2865(12) 0.4957(8) 0.035(5) Uani 1 1 d .
N10 N 1.2611(18) 0.6308(16) 0.5615(12) 0.058(6) Uani 1 1 d .
N11 N 1.2226(13) 0.3685(11) 0.7572(7) 0.024(4) Uani 1 1 d .
N12 N 1.2660(15) 0.4386(12) 0.8073(9) 0.035(5) Uani 1 1 d .
N13 N 1.3790(15) 0.4405(12) 0.8339(8) 0.028(4) Uani 1 1 d U
N14 N 1.4101(14) 0.3691(12) 0.8024(8) 0.034(5) Uani 1 1 d .
N15 N 1.2447(16) 0.0681(13) 0.6246(8) 0.034(4) Uani 1 1 d .
N16 N 1.2174(14) 0.5186(11) 0.9609(7) 0.025(4) Uani 1 1 d U
N17 N 1.3020(15) 0.4785(12) 0.9785(8) 0.027(4) Uani 1 1 d U
N18 N 1.3614(15) 0.5099(12) 1.0343(8) 0.027(4) Uani 1 1 d .
N19 N 1.3118(14) 0.5773(12) 1.0594(7) 0.026(4) Uani 1 1 d .
N20 N 0.9661(15) 0.7457(12) 1.0100(8) 0.034(4) Uani 1 1 d .
N21 N 1.3992(16) 0.7518(15) 0.9484(10) 0.051(6) Uani 1 1 d .
N22 N 1.4706(19) 0.6973(14) 0.9694(11) 0.046(5) Uani 1 1 d U
N23 N 1.5397(19) 0.7339(15) 1.0258(11) 0.055(6) Uani 1 1 d .
N24 N 1.508(2) 0.8141(14) 1.0472(12) 0.060(6) Uani 1 1 d .
N25 N 1.2540(18) 1.0582(16) 0.9990(11) 0.058(6) Uani 1 1 d .
O1 O 1.6775(11) 0.8156(9) 0.6297(6) 0.026(3) Uani 1 1 d .
O2 O 1.8470(11) 0.7457(9) 0.7092(6) 0.023(3) Uani 1 1 d .
O1W O 1.878(3) 0.745(2) 1.1373(13) 0.043(8) Uani 0.50 1 d PU
O3 O 1.6262(10) 0.7369(9) 0.7339(6) 0.022(3) Uani 1 1 d .
O4 O 1.8344(12) 1.1085(9) 0.7448(6) 0.037(4) Uani 1 1 d .
O5 O 1.7838(11) 1.0341(9) 0.8423(6) 0.025(3) Uani 1 1 d .
O6 O 1.9967(11) 1.0450(9) 0.8229(6) 0.026(3) Uani 1 1 d .
O7 O 1.9616(13) 0.9897(11) 0.9312(6) 0.039(4) Uani 1 1 d .
O8 O 1.8013(10) 0.9255(9) 0.7518(5) 0.017(3) Uani 1 1 d .
O9 O 1.3423(13) 0.8064(11) 0.7542(8) 0.047(4) Uani 1 1 d .
O10 O 1.7647(11) 0.8356(10) 0.8545(6) 0.028(3) Uani 1 1 d .
O11 O 1.8571(12) 1.0018(9) 0.6487(6) 0.028(3) Uani 1 1 d .
O12 O 1.5735(12) 0.9194(10) 0.7706(6) 0.034(4) Uani 1 1 d .
O13 O 1.6299(12) 1.1305(10) 0.7748(6) 0.034(4) Uani 1 1 d .
O14 O 1.6127(12) 0.9894(10) 0.6742(6) 0.033(4) Uani 1 1 d .
O15 O 1.4123(12) 0.9371(10) 0.5695(7) 0.036(4) Uani 1 1 d .
O16 O 1.7140(12) 0.6280(10) 0.5909(6) 0.028(3) Uani 1 1 d .
O17 O 1.6664(12) 0.5566(10) 0.6866(6) 0.035(4) Uani 1 1 d .
O18 O 1.4188(13) 0.4579(10) 0.6632(7) 0.045(4) Uani 1 1 d .
O19 O 1.8477(14) 0.9653(10) 0.5260(7) 0.041(4) Uani 1 1 d .
O20 O 1.6778(12) 0.6659(11) 0.9004(7) 0.035(4) Uani 1 1 d .
O21 O 1.4507(12) 0.8149(9) 0.6590(6) 0.029(3) Uani 1 1 d .
O22 O 1.6367(12) 0.9423(10) 0.5590(6) 0.039(4) Uani 1 1 d .
O23 O 2.0622(13) 1.1428(10) 0.7313(7) 0.043(4) Uani 1 1 d .
O24 O 2.0622(12) 0.6881(11) 0.8577(7) 0.043(4) Uani 1 1 d .
O25 O 2.1391(12) 0.8310(9) 0.6531(7) 0.033(4) Uani 1 1 d .
O26 O 1.5303(11) 0.7468(10) 0.8185(6) 0.033(4) Uani 1 1 d .
O27 O 1.8183(12) 0.6747(10) 0.8166(6) 0.031(3) Uani 1 1 d .
O28 O 1.6889(12) 0.7777(9) 0.5201(6) 0.030(3) Uani 1 1 d .
O29 O 1.4765(12) 0.7631(10) 0.5465(6) 0.042(4) Uani 1 1 d .
O30 O 1.9754(12) 0.8505(10) 0.8334(7) 0.036(4) Uani 1 1 d .
O31 O 1.9120(12) 0.5948(9) 0.7404(6) 0.030(3) Uani 1 1 d .
O32 O 1.5737(11) 0.5750(9) 0.7761(6) 0.029(3) Uani 1 1 d .
O33 O 1.4056(11) 0.6462(9) 0.7059(7) 0.031(4) Uani 1 1 d .
O34 O 2.0740(12) 0.7717(10) 0.7547(6) 0.034(4) Uani 1 1 d .
O35 O 2.0205(12) 0.9371(10) 0.7201(7) 0.038(4) Uani 1 1 d .
O36 O 1.5118(11) 0.6186(9) 0.6105(6) 0.028(3) Uani 1 1 d .
O37 O 1.9003(12) 0.8378(10) 0.6092(6) 0.031(3) Uani 1 1 d .
O38 O 1.9535(12) 0.6650(9) 0.6406(6) 0.029(3) Uani 1 1 d .
O39 O 1.8062(13) 0.4661(10) 0.6277(7) 0.038(4) Uani 1 1 d .
O40 O 1.5153(13) 0.5982(10) 0.4872(7) 0.040(4) Uani 1 1 d .
Na1 Na 1.2905(9) 0.6981(8) 0.8432(4) 0.060(3) Uani 1 1 d .
Ge1 Ge 1.73910(18) 0.80577(14) 0.70606(9) 0.0193(5) Uani 1 1 d .
Mo1 Mo 1.95998(16) 1.03834(13) 0.73604(9) 0.0289(5) Uani 1 1 d .
Mo2 Mo 1.69521(16) 1.04089(13) 0.75912(9) 0.0284(4) Uani 1 1 d .
Mo3 Mo 1.88488(17) 0.94606(14) 0.85493(8) 0.0310(5) Uani 1 1 d .
Mo4 Mo 1.96677(17) 0.72222(14) 0.80043(9) 0.0328(5) Uani 1 1 d .
Mo5 Mo 2.00915(17) 0.79870(14) 0.67065(9) 0.0319(5) Uani 1 1 d .
Mo6 Mo 1.66818(17) 0.69145(14) 0.82828(9) 0.0343(5) Uani 1 1 d .
Mo7 Mo 1.47047(16) 0.79405(14) 0.74420(10) 0.0323(5) Uani 1 1 d .
Mo8 Mo 1.51979(17) 0.88614(14) 0.60316(9) 0.0322(5) Uani 1 1 d .
Mo9 Mo 1.78655(17) 0.91091(13) 0.57724(8) 0.0297(5) Uani 1 1 d .
Mo10 Mo 1.59390(17) 0.68184(13) 0.55161(9) 0.0308(5) Uani 1 1 d .
Mo11 Mo 1.50740(16) 0.57752(13) 0.68452(9) 0.0292(5) Uani 1 1 d .
Mo12 Mo 1.80508(17) 0.58029(13) 0.66271(9) 0.0295(5) Uani 1 1 d .
Ag1 Ag 1.48423(15) 0.56029(12) 0.91739(8) 0.0379(5) Uani 1 1 d .
Ag2 Ag 1.14518(16) 0.51469(16) 0.85412(9) 0.0520(6) Uani 1 1 d .
Ag3 Ag 1.02614(16) 0.34971(17) 0.69648(8) 0.0518(6) Uani 1 1 d .
Ag4 Ag 0.60206(15) 0.38128(14) 0.82580(9) 0.0441(5) Uani 1 1 d .
Ag5 Ag 0.81364(16) 0.07431(12) 0.44105(8) 0.0383(5) Uani 1 1 d .
Ag6 Ag 1.6834(2) 0.67059(17) 1.06598(11) 0.0707(7) Uani 1 1 d .
Ag7 Ag 0.84866(18) 0.83646(14) 1.00157(10) 0.0501(5) Uani 1 1 d .
N4 N 0.9015(13) 0.3661(11) 0.7541(7) 0.021(3) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 C1 N1 108.9(17) . .
N4 C1 C2 127.2(18) . .
N1 C1 C2 123.8(17) . .
C3 C2 C6 117(2) . .
C3 C2 C1 124(2) . .
C6 C2 C1 118.8(18) . .
C2 C3 C4 123(2) . .
N5 C4 C3 124(3) . .
C6 C5 N5 123(2) . .
C5 C6 C2 118(2) . .
N9 C7 N6 113.1(19) . .
N9 C7 C8 120(2) . .
N6 C7 C8 127(2) . .
C11 C8 C9 116(2) . .
C11 C8 C7 126(3) . .
C9 C8 C7 118(2) . .
C10 C9 C8 121(2) . .
C9 C10 N10 117(2) . .
C8 C11 C12 122(2) . .
N10 C12 C11 123(2) . .
N14 C13 N11 109.9(19) . .
N14 C13 C14 128(2) . .
N11 C13 C14 122.1(18) . .
C15 C14 C13 122.4(19) . .
C15 C14 C17 117.6(19) . .
C13 C14 C17 119.9(19) . .
C14 C15 C16 118(2) . .
N15 C16 C15 124(2) . .
C18 C17 C14 114(2) . .
N15 C18 C17 126(2) . .
N16 C19 N19 112.9(17) . .
N16 C19 C20 126.5(19) . .
N19 C19 C20 120.6(18) . .
C21 C20 C24 121.6(19) . .
C21 C20 C19 124.2(19) . .
C24 C20 C19 114.1(17) . .
C20 C21 C22 118(2) . .
N20 C22 C21 124(2) . .
N20 C23 C24 127(2) . .
C23 C24 C20 115.9(18) . .
N21 C25 N24 112(2) . .
N21 C25 C26 128(3) . .
N24 C25 C26 120(2) . .
C27 C26 C29 120(2) . .
C27 C26 C25 122(2) . .
C29 C26 C25 118(3) . .
C26 C27 C28 118(3) . .
N25 C28 C27 119(3) . .
C30 C29 C26 123(3) . .
C29 C30 N25 121(3) . .
N2 N1 C1 105.1(15) . .
N2 N1 Ag4 114.5(12) . .
C1 N1 Ag4 140.3(13) . .
N3 N2 N1 107.5(15) . .
N4 N3 N2 109.3(14) . .
N4 N3 Ag2 128.4(12) . .
N2 N3 Ag2 120.0(12) . .
C4 N5 C5 114(2) . .
N7 N6 C7 104.5(17) . .
N7 N6 Ag3 117.5(13) . .
C7 N6 Ag3 136.5(14) . .
N8 N7 N6 108.5(16) . .
N7 N8 N9 111.8(16) . .
N7 N8 Ag5 127.9(13) . .
N9 N8 Ag5 120.2(12) . .
C7 N9 N8 101.7(16) . .
C12 N10 C10 120(2) . .
N12 N11 C13 106.7(16) . .
N12 N11 Ag3 116.9(11) . .
C13 N11 Ag3 136.3(13) . .
N11 N12 N13 108.0(15) . .
N11 N12 Ag2 124.2(12) . .
N13 N12 Ag2 125.9(13) . .
N12 N13 N14 110.7(16) . .
N12 N13 Ag1 117.1(11) . .
N14 N13 Ag1 132.1(13) . .
C13 N14 N13 104.6(18) . .
C13 N14 Ag4 136.6(16) . 1_655
N13 N14 Ag4 116.2(12) . 1_655
C16 N15 C18 118(2) . .
C16 N15 Ag5 119.2(15) . 2_756
C18 N15 Ag5 122.7(15) . 2_756
N17 N16 C19 105.0(16) . .
N17 N16 Ag2 116.3(13) . .
C19 N16 Ag2 134.8(13) . .
N18 N17 N16 112.7(16) . .
N18 N17 Ag6 116.6(13) . 2_867
N16 N17 Ag6 127.3(13) . 2_867
N17 N18 N19 108.8(16) . .
N17 N18 Ag1 120.6(12) . 2_867
N19 N18 Ag1 130.3(13) . 2_867
C19 N19 N18 100.5(16) . .
C19 N19 Ag4 146.7(13) . 2_767
N18 N19 Ag4 111.0(12) . 2_767
C23 N20 C22 114.2(19) . .
C23 N20 Ag7 123.6(14) . .
C22 N20 Ag7 121.6(15) . .
N22 N21 C25 103(2) . .
N22 N21 Na1 113.5(16) . .
C25 N21 Na1 143.3(18) . .
N23 N22 N21 113(2) . .
N23 N22 Ag1 120.9(15) . .
N21 N22 Ag1 126.1(17) . .
N22 N23 N24 108(2) . .
N22 N23 Ag6 119.9(15) . .
N24 N23 Ag6 132(2) . .
N23 N24 C25 103(2) . .
C30 N25 C28 119(2) . .
C30 N25 Ag7 120.2(19) . 2_777
C28 N25 Ag7 120.8(18) . 2_777
Ge1 O1 Mo10 123.4(6) . .
Ge1 O1 Mo9 122.1(6) . .
Mo10 O1 Mo9 94.8(5) . .
Ge1 O1 Mo8 120.4(7) . .
Mo10 O1 Mo8 95.2(5) . .
Mo9 O1 Mo8 93.7(4) . .
Ge1 O2 Mo4 123.1(6) . .
Ge1 O2 Mo12 122.9(6) . .
Mo4 O2 Mo12 92.9(5) . .
Ge1 O2 Mo5 123.6(6) . .
Mo4 O2 Mo5 93.0(4) . .
Mo12 O2 Mo5 92.8(5) . .
Ge1 O3 Mo7 122.0(6) . .
Ge1 O3 Mo6 122.2(6) . .
Mo7 O3 Mo6 95.2(5) . .
Ge1 O3 Mo11 122.0(6) . .
Mo7 O3 Mo11 94.7(4) . .
Mo6 O3 Mo11 93.3(4) . .
Mo2 O4 Mo1 121.0(6) . .
Mo3 O5 Mo2 119.9(6) . .
Mo1 O6 Mo3 117.9(6) . .
Ge1 O8 Mo3 121.3(6) . .
Ge1 O8 Mo1 120.8(6) . .
Mo3 O8 Mo1 94.9(4) . .
Ge1 O8 Mo2 124.0(6) . .
Mo3 O8 Mo2 94.2(4) . .
Mo1 O8 Mo2 94.2(4) . .
Mo7 O9 Na1 108.7(7) . .
Mo3 O10 Mo6 154.4(7) . .
Mo9 O11 Mo1 150.2(7) . .
Mo7 O12 Mo2 152.4(8) . .
Mo2 O14 Mo8 155.5(7) . .
Mo10 O16 Mo12 153.2(7) . .
Mo12 O17 Mo11 152.2(8) . .
Mo9 O19 Ag5 143.1(8) . 1_665
Mo6 O20 Ag1 116.9(7) . .
Mo8 O21 Mo7 146.6(8) . .
Mo9 O22 Mo8 118.6(6) . .
Mo4 O24 Na1 115.6(7) . 1_655
Mo7 O26 Mo6 119.6(7) . .
Mo7 O26 Na1 93.1(5) . .
Mo6 O26 Na1 138.3(6) . .
Mo4 O27 Mo6 152.5(7) . .
Mo10 O28 Mo9 117.8(7) . .
Mo8 O29 Mo10 119.4(7) . .
Mo4 O30 Mo3 146.8(8) . .
Mo12 O31 Mo4 121.6(6) . .
Mo6 O32 Mo11 119.1(6) . .
Mo11 O33 Mo7 120.0(6) . .
Mo4 O34 Mo5 119.7(7) . .
Mo1 O35 Mo5 152.2(8) . .
Mo11 O36 Mo10 154.5(7) . .
Mo5 O37 Mo9 155.7(8) . .
Mo5 O38 Mo12 118.6(6) . .
N21 Na1 O9 121.9(7) . .
N21 Na1 Ag2 97.4(6) . .
O9 Na1 Ag2 140.5(5) . .
N21 Na1 O24 96.3(6) . 1_455
O9 Na1 O24 113.8(5) . 1_455
Ag2 Na1 O24 60.7(4) . 1_455
N21 Na1 O26 86.4(6) . .
O9 Na1 O26 56.0(4) . .
Ag2 Na1 O26 130.0(5) . .
O24 Na1 O26 168.6(6) 1_455 .
N21 Na1 Ag1 60.5(5) . .
O9 Na1 Ag1 121.5(4) . .
Ag2 Na1 Ag1 72.4(2) . .
O24 Na1 Ag1 124.3(4) 1_455 .
O26 Na1 Ag1 66.6(3) . .
N21 Na1 Mo7 111.5(6) . .
O9 Na1 Mo7 25.6(3) . .
Ag2 Na1 Mo7 138.3(4) . .
O24 Na1 Mo7 139.1(4) 1_455 .
O26 Na1 Mo7 31.5(3) . .
Ag1 Na1 Mo7 95.9(2) . .
O2 Ge1 O1 108.6(6) . .
O2 Ge1 O8 110.3(6) . .
O1 Ge1 O8 109.9(5) . .
O2 Ge1 O3 109.7(6) . .
O1 Ge1 O3 109.7(6) . .
O8 Ge1 O3 108.6(6) . .
O23 Mo1 O35 105.1(6) . .
O23 Mo1 O6 101.4(7) . .
O35 Mo1 O6 97.5(6) . .
O23 Mo1 O11 99.6(6) . .
O35 Mo1 O11 87.3(6) . .
O6 Mo1 O11 156.4(5) . .
O23 Mo1 O4 95.4(6) . .
O35 Mo1 O4 158.2(5) . .
O6 Mo1 O4 85.4(6) . .
O11 Mo1 O4 82.0(5) . .
O23 Mo1 O8 165.8(6) . .
O35 Mo1 O8 89.0(5) . .
O6 Mo1 O8 74.0(5) . .
O11 Mo1 O8 83.0(5) . .
O4 Mo1 O8 70.9(4) . .
O13 Mo2 O4 104.9(7) . .
O13 Mo2 O14 102.3(6) . .
O4 Mo2 O14 94.2(6) . .
O13 Mo2 O5 100.0(6) . .
O4 Mo2 O5 91.0(6) . .
O14 Mo2 O5 154.9(6) . .
O13 Mo2 O12 99.0(6) . .
O4 Mo2 O12 156.0(6) . .
O14 Mo2 O12 82.5(6) . .
O5 Mo2 O12 82.9(5) . .
O13 Mo2 O8 172.0(6) . .
O4 Mo2 O8 73.8(5) . .
O14 Mo2 O8 85.7(5) . .
O5 Mo2 O8 72.2(5) . .
O12 Mo2 O8 82.2(5) . .
O7 Mo3 O10 104.7(6) . .
O7 Mo3 O5 99.5(7) . .
O10 Mo3 O5 95.1(5) . .
O7 Mo3 O6 95.6(6) . .
O10 Mo3 O6 159.2(6) . .
O5 Mo3 O6 85.9(5) . .
O7 Mo3 O30 100.7(7) . .
O10 Mo3 O30 87.4(6) . .
O5 Mo3 O30 158.3(6) . .
O6 Mo3 O30 84.3(5) . .
O7 Mo3 O8 166.7(6) . .
O10 Mo3 O8 87.5(5) . .
O5 Mo3 O8 73.7(5) . .
O6 Mo3 O8 72.8(5) . .
O30 Mo3 O8 84.9(5) . .
O24 Mo4 O30 103.2(7) . .
O24 Mo4 O27 102.1(6) . .
O30 Mo4 O27 89.5(6) . .
O24 Mo4 O34 99.3(6) . .
O30 Mo4 O34 91.4(6) . .
O27 Mo4 O34 157.8(6) . .
O24 Mo4 O31 98.0(7) . .
O30 Mo4 O31 158.8(6) . .
O27 Mo4 O31 84.5(6) . .
O34 Mo4 O31 86.7(6) . .
O24 Mo4 O2 168.1(6) . .
O30 Mo4 O2 87.4(5) . .
O27 Mo4 O2 83.2(5) . .
O34 Mo4 O2 74.6(5) . .
O31 Mo4 O2 71.7(5) . .
O25 Mo5 O38 102.4(6) . .
O25 Mo5 O37 104.4(6) . .
O38 Mo5 O37 96.8(6) . .
O25 Mo5 O34 98.0(6) . .
O38 Mo5 O34 90.3(6) . .
O37 Mo5 O34 154.3(5) . .
O25 Mo5 O35 98.9(6) . .
O38 Mo5 O35 158.2(5) . .
O37 Mo5 O35 81.9(6) . .
O34 Mo5 O35 82.4(6) . .
O25 Mo5 O2 170.5(6) . .
O38 Mo5 O2 76.5(5) . .
O37 Mo5 O2 85.1(5) . .
O34 Mo5 O2 72.7(5) . .
O35 Mo5 O2 81.7(5) . .
O20 Mo6 O32 105.1(7) . .
O20 Mo6 O27 102.6(6) . .
O32 Mo6 O27 94.5(6) . .
O20 Mo6 O26 97.2(6) . .
O32 Mo6 O26 91.3(6) . .
O27 Mo6 O26 157.2(5) . .
O20 Mo6 O10 96.6(6) . .
O32 Mo6 O10 158.3(6) . .
O27 Mo6 O10 82.6(5) . .
O26 Mo6 O10 83.8(5) . .
O20 Mo6 O3 169.2(5) . .
O32 Mo6 O3 76.1(5) . .
O27 Mo6 O3 88.0(5) . .
O26 Mo6 O3 72.0(5) . .
O10 Mo6 O3 82.3(5) . .
O9 Mo7 O12 104.2(7) . .
O9 Mo7 O26 98.9(7) . .
O12 Mo7 O26 94.6(6) . .
O9 Mo7 O21 101.5(7) . .
O12 Mo7 O21 89.1(6) . .
O26 Mo7 O21 157.6(6) . .
O9 Mo7 O33 95.9(6) . .
O12 Mo7 O33 159.7(6) . .
O26 Mo7 O33 84.5(6) . .
O21 Mo7 O33 84.5(6) . .
O9 Mo7 O3 165.5(6) . .
O12 Mo7 O3 88.8(5) . .
O26 Mo7 O3 73.1(5) . .
O21 Mo7 O3 84.9(5) . .
O33 Mo7 O3 71.6(5) . .
O9 Mo7 Na1 45.8(5) . .
O12 Mo7 Na1 117.3(5) . .
O26 Mo7 Na1 55.5(4) . .
O21 Mo7 Na1 140.1(4) . .
O33 Mo7 Na1 78.7(4) . .
O3 Mo7 Na1 122.3(3) . .
O15 Mo8 O29 100.8(7) . .
O15 Mo8 O21 102.3(6) . .
O29 Mo8 O21 89.9(6) . .
O15 Mo8 O14 101.2(7) . .
O29 Mo8 O14 158.0(6) . .
O21 Mo8 O14 86.6(6) . .
O15 Mo8 O22 97.0(6) . .
O29 Mo8 O22 87.3(6) . .
O21 Mo8 O22 160.7(6) . .
O14 Mo8 O22 88.9(6) . .
O15 Mo8 O1 167.7(6) . .
O29 Mo8 O1 72.9(5) . .
O21 Mo8 O1 88.4(5) . .
O14 Mo8 O1 85.3(5) . .
O22 Mo8 O1 72.5(5) . .
O19 Mo9 O11 103.8(6) . .
O19 Mo9 O22 101.4(7) . .
O11 Mo9 O22 95.5(6) . .
O19 Mo9 O37 100.4(6) . .
O11 Mo9 O37 87.3(6) . .
O22 Mo9 O37 156.6(5) . .
O19 Mo9 O28 97.1(6) . .
O11 Mo9 O28 158.6(5) . .
O22 Mo9 O28 84.4(6) . .
O37 Mo9 O28 84.6(6) . .
O19 Mo9 O1 168.6(6) . .
O11 Mo9 O1 87.3(5) . .
O22 Mo9 O1 74.7(5) . .
O37 Mo9 O1 82.2(5) . .
O28 Mo9 O1 71.9(5) . .
O40 Mo10 O16 104.7(7) . .
O40 Mo10 O28 100.6(6) . .
O16 Mo10 O28 97.2(6) . .
O40 Mo10 O29 96.5(7) . .
O16 Mo10 O29 155.8(6) . .
O28 Mo10 O29 89.9(6) . .
O40 Mo10 O36 98.8(6) . .
O16 Mo10 O36 82.7(5) . .
O28 Mo10 O36 159.9(6) . .
O29 Mo10 O36 82.8(5) . .
O40 Mo10 O1 168.1(6) . .
O16 Mo10 O1 87.0(5) . .
O28 Mo10 O1 75.4(5) . .
O29 Mo10 O1 72.4(5) . .
O36 Mo10 O1 84.6(5) . .
O18 Mo11 O36 103.8(6) . .
O18 Mo11 O33 102.5(7) . .
O36 Mo11 O33 99.9(6) . .
O18 Mo11 O17 100.5(7) . .
O36 Mo11 O17 84.1(6) . .
O33 Mo11 O17 155.0(6) . .
O18 Mo11 O32 97.6(6) . .
O36 Mo11 O32 155.3(5) . .
O33 Mo11 O32 87.3(6) . .
O17 Mo11 O32 79.9(5) . .
O18 Mo11 O3 168.2(6) . .
O36 Mo11 O3 87.9(5) . .
O33 Mo11 O3 73.4(5) . .
O17 Mo11 O3 82.2(5) . .
O32 Mo11 O3 71.4(5) . .
O39 Mo12 O31 101.9(7) . .
O39 Mo12 O17 106.0(6) . .
O31 Mo12 O17 97.0(6) . .
O39 Mo12 O16 100.8(6) . .
O31 Mo12 O16 155.3(6) . .
O17 Mo12 O16 86.1(6) . .
O39 Mo12 O38 96.0(6) . .
O31 Mo12 O38 85.3(6) . .
O17 Mo12 O38 156.9(5) . .
O16 Mo12 O38 82.7(5) . .
O39 Mo12 O2 167.3(6) . .
O31 Mo12 O2 73.6(5) . .
O17 Mo12 O2 86.5(5) . .
O16 Mo12 O2 82.2(5) . .
O38 Mo12 O2 72.1(4) . .
N22 Ag1 N13 140.5(7) . .
N22 Ag1 N18 117.3(7) . 2_867
N13 Ag1 N18 101.3(6) . 2_867
N22 Ag1 O20 89.0(6) . .
N13 Ag1 O20 110.2(5) . .
N18 Ag1 O20 74.4(5) 2_867 .
N22 Ag1 Na1 59.7(6) . .
N13 Ag1 Na1 83.3(5) . .
N18 Ag1 Na1 170.8(4) 2_867 .
O20 Ag1 Na1 96.6(3) . .
N3 Ag2 N16 113.5(6) . .
N3 Ag2 N12 106.0(6) . .
N16 Ag2 N12 106.6(6) . .
N3 Ag2 Na1 137.8(5) . .
N16 Ag2 Na1 100.6(4) . .
N12 Ag2 Na1 86.1(4) . .
N6 Ag3 N4 126.0(6) . .
N6 Ag3 N11 121.3(6) . .
N4 Ag3 N11 112.6(6) . .
N14 Ag4 N1 147.8(7) 1_455 .
N14 Ag4 N19 108.2(6) 1_455 2_767
N1 Ag4 N19 103.8(6) . 2_767
N8 Ag5 N15 169.1(7) . 2_756
N8 Ag5 O19 90.2(6) . 1_445
N15 Ag5 O19 85.4(6) 2_756 1_445
N23 Ag6 N17 122.4(8) . 2_867
N23 Ag6 O1W 131.8(10) . .
N17 Ag6 O1W 103.1(9) 2_867 .
N23 Ag6 Ag7 84.8(5) . 1_655
N17 Ag6 Ag7 101.5(4) 2_867 1_655
O1W Ag6 Ag7 70.7(6) . 1_655
N20 Ag7 N25 173.3(8) . 2_777
N20 Ag7 Ag6 86.9(5) . 1_455
N25 Ag7 Ag6 95.6(6) 2_777 1_455
C1 N4 N3 109.2(15) . .
C1 N4 Ag3 133.9(13) . .
N3 N4 Ag3 116.7(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N4 1.30(2) .
C1 N1 1.38(2) .
C1 C2 1.45(3) .
C2 C3 1.27(3) .
C2 C6 1.39(3) .
C3 C4 1.35(3) .
C4 N5 1.30(3) .
C5 C6 1.37(3) .
C5 N5 1.37(3) .
C7 N9 1.34(2) .
C7 N6 1.34(3) .
C7 C8 1.49(3) .
C8 C11 1.30(3) .
C8 C9 1.45(3) .
C9 C10 1.30(3) .
C10 N10 1.43(3) .
C11 C12 1.35(3) .
C12 N10 1.23(3) .
C13 N14 1.33(2) .
C13 N11 1.37(3) .
C13 C14 1.43(3) .
C14 C15 1.36(3) .
C14 C17 1.46(3) .
C15 C16 1.38(3) .
C16 N15 1.26(2) .
C17 C18 1.33(3) .
C18 N15 1.33(3) .
C19 N16 1.29(2) .
C19 N19 1.34(2) .
C19 C20 1.54(2) .
C20 C21 1.30(3) .
C20 C24 1.40(3) .
C21 C22 1.41(3) .
C22 N20 1.36(3) .
C23 N20 1.31(3) .
C23 C24 1.37(3) .
C25 N21 1.34(3) .
C25 N24 1.36(3) .
C25 C26 1.54(3) .
C26 C27 1.34(3) .
C26 C29 1.37(4) .
C27 C28 1.42(3) .
C28 N25 1.38(3) .
C29 C30 1.29(3) .
C30 N25 1.34(3) .
N1 N2 1.37(2) .
N1 Ag4 2.184(16) .
N2 N3 1.34(2) .
N3 N4 1.31(2) .
N3 Ag2 2.277(15) .
N6 N7 1.34(2) .
N6 Ag3 2.223(18) .
N7 N8 1.31(2) .
N8 N9 1.36(2) .
N8 Ag5 2.130(17) .
N11 N12 1.32(2) .
N11 Ag3 2.335(16) .
N12 N13 1.33(2) .
N12 Ag2 2.388(16) .
N13 N14 1.35(2) .
N13 Ag1 2.248(16) .
N14 Ag4 2.183(17) 1_655
N15 Ag5 2.198(17) 2_756
N16 N17 1.27(2) .
N16 Ag2 2.346(16) .
N17 N18 1.25(2) .
N17 Ag6 2.285(16) 2_867
N18 N19 1.38(2) .
N18 Ag1 2.375(17) 2_867
N19 Ag4 2.492(16) 2_767
N20 Ag7 2.100(16) .
N21 N22 1.31(2) .
N21 Na1 2.35(2) .
N22 N23 1.30(3) .
N22 Ag1 2.209(19) .
N23 N24 1.36(2) .
N23 Ag6 2.16(2) .
N25 Ag7 2.14(2) 2_777
O1 Ge1 1.735(13) .
O1 Mo10 2.262(13) .
O1 Mo9 2.277(12) .
O1 Mo8 2.313(13) .
O2 Ge1 1.698(13) .
O2 Mo4 2.298(12) .
O2 Mo12 2.312(12) .
O2 Mo5 2.329(11) .
O1W Ag6 2.38(3) .
O3 Ge1 1.757(12) .
O3 Mo7 2.261(12) .
O3 Mo6 2.266(12) .
O3 Mo11 2.309(12) .
O4 Mo2 1.833(13) .
O4 Mo1 2.028(15) .
O5 Mo3 1.919(12) .
O5 Mo2 1.936(13) .
O6 Mo1 1.895(13) .
O6 Mo3 2.009(12) .
O7 Mo3 1.704(13) .
O8 Ge1 1.748(12) .
O8 Mo3 2.253(12) .
O8 Mo1 2.287(11) .
O8 Mo2 2.304(11) .
O9 Mo7 1.660(14) .
O9 Na1 2.754(17) .
O10 Mo3 1.830(13) .
O10 Mo6 1.997(13) .
O11 Mo9 1.816(13) .
O11 Mo1 1.982(13) .
O12 Mo7 1.811(13) .
O12 Mo2 2.035(13) .
O13 Mo2 1.686(13) .
O14 Mo2 1.897(14) .
O14 Mo8 1.928(14) .
O15 Mo8 1.673(13) .
O16 Mo10 1.853(13) .
O16 Mo12 1.987(13) .
O17 Mo12 1.849(14) .
O17 Mo11 1.989(14) .
O18 Mo11 1.686(13) .
O19 Mo9 1.681(13) .
O19 Ag5 2.588(13) 1_665
O20 Mo6 1.694(13) .
O20 Ag1 2.573(13) .
O21 Mo8 1.920(13) .
O21 Mo7 1.951(13) .
O22 Mo9 1.906(15) .
O22 Mo8 1.987(14) .
O23 Mo1 1.691(13) .
O24 Mo4 1.687(14) .
O24 Na1 2.817(17) 1_655
O25 Mo5 1.677(12) .
O26 Mo7 1.905(13) .
O26 Mo6 1.963(14) .
O26 Na1 3.005(16) .
O27 Mo4 1.887(13) .
O27 Mo6 1.954(13) .
O28 Mo10 1.863(12) .
O28 Mo9 2.038(13) .
O29 Mo8 1.907(15) .
O29 Mo10 2.003(16) .
O30 Mo4 1.836(14) .
O30 Mo3 2.014(14) .
O31 Mo12 1.849(14) .
O31 Mo4 1.980(13) .
O32 Mo6 1.824(13) .
O32 Mo11 2.034(14) .
O33 Mo11 1.855(12) .
O33 Mo7 2.027(13) .
O34 Mo4 1.904(12) .
O34 Mo5 1.977(14) .
O35 Mo1 1.787(14) .
O35 Mo5 2.088(14) .
O36 Mo11 1.840(14) .
O36 Mo10 2.012(13) .
O37 Mo5 1.872(14) .
O37 Mo9 1.935(14) .
O38 Mo5 1.811(13) .
O38 Mo12 2.092(12) .
O39 Mo12 1.712(13) .
O40 Mo10 1.669(14) .
Na1 Ag2 2.792(11) .
Na1 O24 2.817(17) 1_455
Na1 Ag1 3.569(10) .
Na1 Mo7 3.643(9) .
Ag1 N18 2.375(17) 2_867
Ag3 N4 2.268(14) .
Ag4 N14 2.183(17) 1_455
Ag4 N19 2.492(17) 2_767
Ag5 N15 2.198(17) 2_756
Ag5 O19 2.588(13) 1_445
Ag6 N17 2.285(16) 2_867
Ag6 Ag7 3.373(3) 1_655
Ag7 N25 2.14(2) 2_777
Ag7 Ag6 3.373(3) 1_455
